CN101468907A - SiO2 enriched nano composite heat preserving and thermal insulating paste and preparing process thereof - Google Patents

SiO2 enriched nano composite heat preserving and thermal insulating paste and preparing process thereof Download PDF

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Publication number
CN101468907A
CN101468907A CNA2007101734248A CN200710173424A CN101468907A CN 101468907 A CN101468907 A CN 101468907A CN A2007101734248 A CNA2007101734248 A CN A2007101734248A CN 200710173424 A CN200710173424 A CN 200710173424A CN 101468907 A CN101468907 A CN 101468907A
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China
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insulating paste
nano composite
percent
heat preserving
composite heat
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CNA2007101734248A
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Chinese (zh)
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CN101468907B (en
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汪培庆
汪庆锋
汪国庆
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上海暄洋化工材料科技有限公司
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/34Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing cold phosphate binders
    • C04B28/344Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing cold phosphate binders the phosphate binder being present in the starting composition solely as one or more phosphates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/04Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/06Acrylates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/04Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/08Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing halogen
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/30Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Other silicon-containing organic compounds; Boron-organic compounds
    • C04B26/32Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Other silicon-containing organic compounds; Boron-organic compounds containing silicon
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00008Obtaining or using nanotechnology related materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/28Fire resistance, i.e. materials resistant to accidental fires or high temperatures

Abstract

The invention relates to SiO2 nano composite thermal insulation paste, which is characterized in that the form of the SiO2 nano composite thermal insulation paste is a paste mixture, and the dried paste mixture becomes micro pores, nano holes and a fiber structure compound. The paste comprises the following components by weight percentage: 20 to 50 percent of SiO2 nano aerogel, 0 to 30 percent of inorganic closed-hole micro-bead material, 7 to 15 percent of expanded pearlite, 0 to 1 percent of bentonite, 2 to 6 percent of penetrating agent, 10 to 20 percent of adhesive, 3 to 6 percent of calcium silicate fiber, 0 to 5 percent of magnesium aluminum silicate fiber, 0 to 5 percent of aluminum silicate fiber, 0 to 40 percent of water, 0.1 to 2 percent of flame retardant, and 3 to 7 percent of pigment. A preparation device is a vacuum intake and stirring device.

Description

A kind of SiO 2Nano composite heat preserving and thermal insulating paste and preparation technology thereof
Technical field
The present invention relates to a kind of SiO 2Nano composite heat preserving and thermal insulating paste and preparation technology thereof belong to heat-insulation and heat-preservation and heat reflection technical field, are suitable for the heat-insulation and heat-preservation of various pipelines, tank body, equipment, building inside and outside wall, doors and windows sealing.
Background technology
Existing lotion lagging material, compound heat-insulating silicate material of announcing as CN87102864A and preparation method thereof, compound insulating paste that CN1105380A announces and preparation method thereof all adopts the asbestos with hazardness to do aggregate.The drying shrinkage height, dry body density is big, the thermal conductivity height, heat insulation effect is not ideal enough.
The objective of the invention is to overcome above-mentioned weak point of the prior art, a kind of this objectionable impurities of asbestos that do not adopt is provided, dry body density is little, drying shrinkage is little, thermal conductivity is low, and internal stress is little, and ageing-resistant performance is good, color tunable, and have the compound ointment material and the preparation technology thereof of reflected sunlight energy.
Summary of the invention
The object of the present invention is achieved like this: a kind of SiO 2Nano composite heat preserving and thermal insulating paste and preparation technology thereof is characterized in that this compound insulating paste is an organic-inorganic composite body, and dry back is nanoporous, micron hole, the reticulin fiber mixture of sealing.Composition is: SiO 2Nanoporous aerogel 20-50%; Inorganic closed pore microballon material 0-30%, pearlstone 7-15%, wilkinite 0-1%, permeate agent 2-6%, tackiness agent 10-20%, ca silicate fibre 3-6%, magnesium aluminum silicate fiber 0-5%, aluminum silicate fiber 0-5%, water 0-40%, fire retardant 0.1-2%, pigment 3-7%.Its preparation technology's flow process is: permeate agent, tackiness agent, fire retardant and water are mixed the back ball milling mix, under the stirring at low speed situation, progressively add filamentary material then, disperse to add after 20 minutes the inorganic closed pore microballon material and the pearlstone of half amount, add wilkinite and pigment again, the back that is uniformly dispersed adds half SiO 2Nanoporous aerogel adds remaining inorganic closed pore microballon material, pearlstone and remaining SiO after evenly again 2Nanoporous aerogel, static froth breaking 2 hours is finished product.
Described SiO 2Thermal conductivity is lower than 0.03w/m.k under the nanoporous aerogel normal temperature, and density is lower than 0.1g/cm 3
Described inorganic closed pore microballon material can be glass microballon, ceramic fine bead and float pearl that its normal temperature thermal conductivity is lower than 0.04w/m.k.
Described tackiness agent is fluorine carbon emulsion, ACRYLIC EMULSION, organosilicon composite emulsion, phosphoric acid aluminium liquid, one or more of water glass; Permeate agent is sulfosuccinate fat sodium sulfate and hyper-dispersant; Fire retardant can be one or more of aluminium hydroxide, melamine cyanurate, ammonium polyphosphate; Pigment is one or more of titanium dioxide, red iron oxide, ultramarine, phthalocyanine blue etc.
Described hyper-dispersant is the CH series product of ShangHai SanZheng polymer Materials Co., Ltd.
The equipment that described preparation technology adopted is vacuum absorption device and whipping appts, can avoid the dust from flying in the production environment, minimizing is to the harm of workman and environment, and can effectively remove the air pocket in the lotion, produces big open pore in order to avoid solidify the back at lotion.
The present invention adopts the extremely low SiO of thermal conductivity 2Nanoporous aerogel makes that as material of main part the heat-insulating property of insulating paste is very excellent, and thermal conductivity is very low, and the interpolation of various filamentary materials makes this insulating paste have good intensity, the light (density<0.25g/cm of the adiabatic lotion of the present invention simultaneously 3), technology is simple, does not adopt objectionable impuritiess such as asbestos, does not produce dust, helps environmental protection, can be widely used in the heat-insulation and heat-preservation of various pipelines, tank body, equipment, building inside and outside wall, doors and windows sealing.
Embodiment
Below further specify this explanation by concrete case study on implementation, but case study on implementation only be used for the explanation, can not limit the scope of the invention.
Case 1
Get 0.5 part in aluminium hydroxide, 0.6 part of ACRYLIC EMULSION, 0.6 part of organosilicon composite emulsion, 0.2 part of CH-3 hyper-dispersant adds behind the ball milling in 4 parts of water, adds 0.6 part of ca silicate fibre in stirring, 0.4 part aluminum silicate fiber, add 1 part of inorganic closed pore microballon material, 0.55 part of pearlstone, 0.06 part of wilkinite after 20 minutes, 0.5 part titanium dioxide stirs the back and adds 3 parts of SiO 2Nanoporous aerogel after continuing to stir, adds 1 part of inorganic closed pore microballon material, 0.55 part of pearlstone, 3 parts of SiO 2Nanoporous aerogel.After stirring, static froth breaking 2 hours can obtain finished product.
Record through glass ear solid-state physics institute of Tongji University, lotion records 230 kilograms/m of density after solidifying 3, thermal conductivity is 0.052w/m.k, total reflectivity is 82%.
Case 2
Get 0.5 part of melamine cyanurate, 1 part of fluorine carbon emulsion, 0.2 part in sulfosuccinate fat sodium sulfate, add behind the ball milling in 3 parts of water, in stirring, add 0.6 part of ca silicate fibre, 0.5 part of neusilin fiber, 0.4 part aluminum silicate fiber, add 1 part of pearlstone, 0.06 part of wilkinite, 0.3 part of titanium dioxide after 20 minutes, 0.2 part red iron oxide stirs the back and adds 2 parts of SiO 2Nanoporous aerogel after continuing to stir, adds 1 part of pearlstone, 2 parts of SiO 2Nanoporous aerogel.After stirring, static froth breaking 2 hours can obtain finished product.
Record through glass ear solid-state physics institute of Tongji University, lotion records 180 kilograms/m of density after solidifying 3, thermal conductivity is 0.039w/m.k.
Case 3
Get 0.5 part of ammonium polyphosphate, 0.6 part of phosphoric acid aluminium liquid, 0.6 part of organosilicon composite emulsion, 0.2 part of CH hyper-dispersant adds behind the ball milling in 4 parts of water, adds 1 part of neusilin fiber in stirring, 0.4 part aluminum silicate fiber, add 1 part of inorganic closed pore microballon material, 0.06 part of wilkinite, 0.3 part of titanium dioxide after 20 minutes, 0.2 part phthalocyanine blue stirs the back and adds 1.95 parts of SiO 2Nanoporous aerogel after continuing to stir, adds 1 part of inorganic closed pore microballon material, 1.95 parts of SiO 2Nanoporous aerogel.After stirring, static froth breaking 2 hours can obtain finished product.
Record through glass ear solid-state physics institute of Tongji University, lotion records 240 kilograms/m of density after solidifying 3, thermal conductivity is 0.056w/m.k.

Claims (9)

1, a kind of SiO 2Nano combined insulating paste is characterized in that: the form of thing of the present invention is a paste mixture, and dry back is micropore, nanoporous and fibrous texture mixture.Its one-tenth is grouped into: SiO 2Nanoporous aerogel 20-50%; Inorganic closed pore microballon material 0-30%, pearlstone 7-15%, wilkinite 0-1%, permeate agent 2-6%, tackiness agent 10-20%, ca silicate fibre 3-6%, magnesium aluminum silicate fiber 0-5%, aluminum silicate fiber 0-5%, water 0-40%, fire retardant 0.1-2%, pigment 3-7%.
2, nano composite heat preserving and thermal insulating paste according to claim 1 is characterized in that: the optimum proportion of its component content is: SiO 2Nanoporous aerogel 33%; Inorganic closed pore microballon material 15%, pearlstone 11%, wilkinite 0.6%, permeate agent 4%, tackiness agent 12%, ca silicate fibre 6%, magnesium aluminum silicate fiber 5%, water 8.9%, fire retardant 0.5%, titanium dioxide 4%.
3, nano composite heat preserving and thermal insulating paste according to claim 1 is characterized in that: tackiness agent is fluorine carbon emulsion, ACRYLIC EMULSION, organosilicon composite emulsion, phosphoric acid aluminium liquid, one or more of water glass; Permeate agent is sulfosuccinate fat sodium sulfate and hyper-dispersant; Fire retardant can be one or more of aluminium hydroxide, melamine cyanurate, ammonium polyphosphate; Pigment is one or more of titanium dioxide, red iron oxide, ultramarine, phthalocyanine blue etc.
4, the preparation technology of nano composite heat preserving and thermal insulating paste as claimed in claim 1: permeate agent, tackiness agent, fire retardant and water are mixed the back ball milling, under the stirring at low speed situation, progressively add filamentary material then, disperse to add after 20 minutes the inorganic closed pore microballon material and the pearlstone of half amount, add wilkinite and pigment again, the back that is uniformly dispersed adds half SiO 2Nanoporous aerogel adds remaining inorganic closed pore microballon material, pearlstone and remaining SiO after evenly again 2Nanoporous aerogel, static froth breaking 2 hours is finished product.
5, the preparation equipment of nano composite heat preserving and thermal insulating paste as claimed in claim 1 is vacuum intake and whipping appts, can avoid the dust from flying in the production environment, minimizing is effectively removed the air pocket in the lotion to the harm of workman and environment, produces big open pore in order to avoid solidify the back at lotion.
6, the used SiO of nano composite heat preserving and thermal insulating paste as claimed in claim 1 2Aerogel can be supercritical drying or the preparation of constant pressure and dry method, and its normal temperature thermal conductivity is lower than 0.03w/m.k.
7, the used inorganic closed pore microballon material of nano composite heat preserving and thermal insulating paste as claimed in claim 1 can be glass microballon, ceramic fine bead and float pearl that its normal temperature thermal conductivity is lower than 0.04w/m.k.
8, the normal temperature thermal conductivity of nano composite heat preserving and thermal insulating paste as claimed in claim 1 is lower than 0.04w/m.k, and dry body density is less than 0.25g/cm 3, can long term operation under 140 ℃, ageing-resistant performance is good, and white lotion then has the effect of reflected sunlight, and its total reflectivity is greater than 82%.
9, nano composite heat preserving and thermal insulating paste according to claim 3 is characterized in that, described hyper-dispersant is the CH series product of ShangHai SanZheng polymer Materials Co., Ltd.
CN2007101734248A 2007-12-27 2007-12-27 SiO2 nano composite heat preserving and thermal insulating paste and preparing process thereof CN101468907B (en)

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Cited By (24)

* Cited by examiner, † Cited by third party
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CN102627947A (en) * 2012-03-22 2012-08-08 陕西盟创纳米新型材料股份有限公司 Preparation method of inorganic thermal insulating powder
CN102795826A (en) * 2012-08-20 2012-11-28 宁波荣山新型材料有限公司 Aerogel/inorganic lightweight aggregate composite thermal insulation material and preparation method thereof
CN103146275A (en) * 2013-03-05 2013-06-12 北京国泰瑞华精藻硅特种材料有限公司 Grey heat-insulation flame-retardant external wall paint
CN103319111A (en) * 2013-05-10 2013-09-25 张洋 Novel composite heat resistance material
EP2749548A2 (en) 2012-12-28 2014-07-02 Gerardo Forgione Low density surface coating paste for plaster
WO2014110892A1 (en) * 2013-01-15 2014-07-24 Zhao Feng Inorganic thermal insulation material and preparation method thereof
CN104609825A (en) * 2015-02-05 2015-05-13 泉州三欣新材料科技有限公司 Heat insulation inorganic coating and preparation method thereof
CN105399380A (en) * 2015-12-09 2016-03-16 重庆兴渝涂料股份有限公司 Single-component efficient light external wall thermal insulation material and preparation method thereof
CN105481339A (en) * 2015-12-25 2016-04-13 山东鲁阳节能材料股份有限公司 Vacuum insulation board core veneer for buildings and preparation method thereof
GB2531328A (en) * 2014-10-17 2016-04-20 Kirkstyles Innovation Ltd Insulated liquid storage vessels
CN105503037A (en) * 2015-12-29 2016-04-20 葛宏盛 Nano thermal insulation material and preparing method thereof
CN105524507A (en) * 2015-12-09 2016-04-27 重庆兴渝涂料股份有限公司 Single-component high-efficiency lightweight interior-wall insulation putty and preparation method thereof
CN105753388A (en) * 2009-04-27 2016-07-13 卡博特公司 Aerogel compositions and methods of making and using them
CN106244172A (en) * 2016-07-12 2016-12-21 伊科纳诺(北京)科技发展有限公司 A kind of preparation method of the fire-retardant aerosil of Halogen synergistic
CN106316329A (en) * 2015-06-17 2017-01-11 天津城建大学 Inorganic foamed building heat insulation board and making method thereof
JP2017502916A (en) * 2013-12-20 2017-01-26 インターブラン システムズ アーゲー Dry building material mixture and thermal insulation gypsum formed therefrom
CN106752139A (en) * 2016-12-13 2017-05-31 无锡市明江保温材料有限公司 A kind of heat power equipment and pipeline nano-thermal-insulating coating and preparation method thereof
CN107089818A (en) * 2017-04-25 2017-08-25 郑善 A kind of silica aerogel fire prevention, waterproof, environment-friendly insulating cream and preparation method thereof
CN107880626A (en) * 2017-11-07 2018-04-06 上海亚澎新材料科技有限公司 Inorganic multifunctional putty and preparation method thereof
CN108706951A (en) * 2018-07-18 2018-10-26 合肥择浚电气设备有限公司 A kind of pipe insulation material and preparation method thereof
CN108840596A (en) * 2018-04-25 2018-11-20 重庆交通大学 Pavement cooling material
CN108930356A (en) * 2018-08-02 2018-12-04 广东金意陶陶瓷集团有限公司 Wallboard and its preparation method and application
CN109354444A (en) * 2018-09-30 2019-02-19 宁波运通新材料科技有限公司 Utilize the ecological heat preservation material of discarded calcium silicates, preparation process and the construction method on hot pipeline
CN110194640A (en) * 2019-04-25 2019-09-03 长兴贝斯德邦建材科技有限公司 A kind of aeroge inorganic heat preservation creme and application method

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DE19541715A1 (en) * 1995-11-09 1997-05-15 Hoechst Ag Process for the production of organically modified aerogels, in which the salts formed are precipitated
CN1238303C (en) * 2004-07-01 2006-01-25 上海交通大学 Negative thermal-expansion coefficient adjustable laminated ceramic matrix composite and preparing method thereof
CN1329333C (en) * 2004-11-29 2007-08-01 北京科技大学 Prepn process of super heat insulating material of composite nanometer pore calcium silicate

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CN105753388A (en) * 2009-04-27 2016-07-13 卡博特公司 Aerogel compositions and methods of making and using them
CN102627947A (en) * 2012-03-22 2012-08-08 陕西盟创纳米新型材料股份有限公司 Preparation method of inorganic thermal insulating powder
CN102627947B (en) * 2012-03-22 2014-03-26 陕西盟创纳米新型材料股份有限公司 Preparation method of inorganic thermal insulating powder
CN102795826A (en) * 2012-08-20 2012-11-28 宁波荣山新型材料有限公司 Aerogel/inorganic lightweight aggregate composite thermal insulation material and preparation method thereof
CN102795826B (en) * 2012-08-20 2014-08-13 宁波荣山新型材料有限公司 Aerogel/inorganic lightweight aggregate composite thermal insulation material and preparation method thereof
EP2749548A2 (en) 2012-12-28 2014-07-02 Gerardo Forgione Low density surface coating paste for plaster
WO2014110892A1 (en) * 2013-01-15 2014-07-24 Zhao Feng Inorganic thermal insulation material and preparation method thereof
CN103146275A (en) * 2013-03-05 2013-06-12 北京国泰瑞华精藻硅特种材料有限公司 Grey heat-insulation flame-retardant external wall paint
CN103319111A (en) * 2013-05-10 2013-09-25 张洋 Novel composite heat resistance material
JP2017502916A (en) * 2013-12-20 2017-01-26 インターブラン システムズ アーゲー Dry building material mixture and thermal insulation gypsum formed therefrom
GB2531328A (en) * 2014-10-17 2016-04-20 Kirkstyles Innovation Ltd Insulated liquid storage vessels
WO2016059434A3 (en) * 2014-10-17 2016-06-23 Kirkstyles Innovations Limited Insulated liquid storage vessels
CN104609825A (en) * 2015-02-05 2015-05-13 泉州三欣新材料科技有限公司 Heat insulation inorganic coating and preparation method thereof
CN104609825B (en) * 2015-02-05 2016-09-28 泉州三欣新材料科技有限公司 A kind of heat-insulation and heat-preservation inorganic coating and preparation method thereof
CN106316329A (en) * 2015-06-17 2017-01-11 天津城建大学 Inorganic foamed building heat insulation board and making method thereof
CN107698227A (en) * 2015-06-17 2018-02-16 天津城建大学 A kind of preparation method of inorganic foamed insulating board for building
CN107698227B (en) * 2015-06-17 2020-08-21 天津城建大学 Preparation method of inorganic foaming building insulation board
CN105399380B (en) * 2015-12-09 2017-09-22 重庆兴渝涂料股份有限公司 One pack system efficient light external-wall heat-insulation material and preparation method thereof
CN105399380A (en) * 2015-12-09 2016-03-16 重庆兴渝涂料股份有限公司 Single-component efficient light external wall thermal insulation material and preparation method thereof
CN105524507A (en) * 2015-12-09 2016-04-27 重庆兴渝涂料股份有限公司 Single-component high-efficiency lightweight interior-wall insulation putty and preparation method thereof
CN105481339A (en) * 2015-12-25 2016-04-13 山东鲁阳节能材料股份有限公司 Vacuum insulation board core veneer for buildings and preparation method thereof
CN105503037A (en) * 2015-12-29 2016-04-20 葛宏盛 Nano thermal insulation material and preparing method thereof
CN106244172A (en) * 2016-07-12 2016-12-21 伊科纳诺(北京)科技发展有限公司 A kind of preparation method of the fire-retardant aerosil of Halogen synergistic
CN106752139A (en) * 2016-12-13 2017-05-31 无锡市明江保温材料有限公司 A kind of heat power equipment and pipeline nano-thermal-insulating coating and preparation method thereof
CN107089818A (en) * 2017-04-25 2017-08-25 郑善 A kind of silica aerogel fire prevention, waterproof, environment-friendly insulating cream and preparation method thereof
CN108530011A (en) * 2017-04-25 2018-09-14 郑善 A kind of silica aerogel fire prevention, waterproof, environment-friendly insulating cream
CN107880626A (en) * 2017-11-07 2018-04-06 上海亚澎新材料科技有限公司 Inorganic multifunctional putty and preparation method thereof
CN108840596A (en) * 2018-04-25 2018-11-20 重庆交通大学 Pavement cooling material
CN108706951A (en) * 2018-07-18 2018-10-26 合肥择浚电气设备有限公司 A kind of pipe insulation material and preparation method thereof
CN108930356A (en) * 2018-08-02 2018-12-04 广东金意陶陶瓷集团有限公司 Wallboard and its preparation method and application
CN109354444A (en) * 2018-09-30 2019-02-19 宁波运通新材料科技有限公司 Utilize the ecological heat preservation material of discarded calcium silicates, preparation process and the construction method on hot pipeline
CN110194640A (en) * 2019-04-25 2019-09-03 长兴贝斯德邦建材科技有限公司 A kind of aeroge inorganic heat preservation creme and application method

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