CN101434878B - Nano emulsification agent, biodiesel and alcohol diesel - Google Patents
Nano emulsification agent, biodiesel and alcohol diesel Download PDFInfo
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- CN101434878B CN101434878B CN200810244584A CN200810244584A CN101434878B CN 101434878 B CN101434878 B CN 101434878B CN 200810244584 A CN200810244584 A CN 200810244584A CN 200810244584 A CN200810244584 A CN 200810244584A CN 101434878 B CN101434878 B CN 101434878B
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- emulsification agent
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Abstract
The invention discloses a stagnation causing agent, a biodiesel and an alcohol diesel, and the stagnation causing agent consists of the following components by weight percentage: 8-10 percent of sodium hydroxide, 20-25 percent of naphthenic acid, 2 percent of ethanolamine, 0.4-0.8 percent of cyclohexyl nitrate, 0.3-0.6 percent of boron trifluoride, 0.3-0.6 percent of dialkyl phosphate, 4-6 percent of Tween 60, 40-50 percent of No.200 solvent oil and 13-15 percent of water, all the components are weighed and added in a kettle for stirring for 30-50 minutes, and then the stagnation causing agent is obtained by even mixing. The production method of the biodiesel is as follows: all the components are weighed and added in a stirrer for stirring for 30-40 minutes, and the biodiesel is obtained by static mixing and high-speed shearing. The production method of the alcohol diesel is as follows: all the components are weighed and added in the stirrer for stirring for 30-40 minutes, and the alcohol diesel is obtained by static mixing and high-speed shearing. The invention utilizes the production methods for producing the biodiesel and the alcohol diesel, and has simple production technology, low production cost, stable performance, energy conservation and emission reduction.
Description
Technical field
The present invention relates to power fuel, be specifically related to a kind of nano emulsification agent and biofuel and alcohol diesel.
Background technology
For a long time; The bio-fuel-oil technology is paid much attention to by people always; The new and high technology that be regarded as save energy, reduces environmental pollution, increases economic efficiency; Therefore, many R&D institutions both domestic and external have the scientific and technical personnel of speciality and expert these to be made number of research projects, in the hope of reaching the purpose of energy-saving and emission-reduction.One Chinese patent application (application number: 87106204) a kind of diesel oil emulsifier is provided, according to the diesel oil emulsification of this emulsifying agent production, though can practice thrift fuel oil, raw materials used costing an arm and a leg, production cost is higher relatively, and the diesel oil emulsification poor stability is combustion powered low.
Summary of the invention
The objective of the invention is to: a kind of nano emulsification agent and biofuel and alcohol diesel are provided, utilize nano emulsification agent production biofuel and alcohol diesel, production technique is simple, and production cost is low, stable performance, energy-saving and emission-reduction.
Technical solution of the present invention is that this nano emulsification agent is made up of following composition weight percent: sodium hydroxid 8-10%, naphthenic acid 20-25%, thanomin 2%, nitric acid hexamethylene fat 0.4-0.8%, boron trifluoride 0.3-0.6%, two alkylphosphonic acid carboxylic acid 0.3-0.6%, polysorbate60 4-6%, 200# solvent oil 40-50% and water 13-15%; The working method of this nano emulsification agent: by above-mentioned each component weighing, add in the reaction kettle and stirred 30-50 minute, uniform mixing gets nano emulsification agent.
Ring of the present invention is received in the agent, in the winter time, adds EGME 0.3-0.5% according to nano emulsification agent weight meter.
Biofuel of the present invention is made up of following composition: diesel oil, water and nano emulsification agent, its weight ratio are 60-80: 19.5-39.5: 0.5; The working method of this biofuel: by above-mentioned each component weighing, add in the stirrer and stirred 30-40 minute, static mixing, high speed shear gets biofuel.
Alcohol diesel of the present invention is made up of following composition: diesel oil, methyl alcohol or ethanol, water and nano emulsification agent, its weight ratio are 50-65: 25-30: 9.5-19.5: 0.5; The working method of this biofuel: by above-mentioned each composition weighing, add in the stirrer and stirred 30-40 minute, static mixing, high speed shear gets alcohol diesel.
The present invention has the following advantages: 1, nano emulsification agent its hydrotropy, dispersion, emulsifying effect are arranged; The composite use of the cationic and anionic surfactant of this nano emulsification agent can impel the quick formation of microemulsion; Making wherein, the particle diameter of the particulate of water reaches nano level (in the scope of 50～100nm); The emulsifying product that forms presents bright outward appearance fully, becomes thermodynamic stable system, and many-sided indexs such as this impression to the raising product, stability, flowability, mutual solubility have all played very important effect; 2, add boron trifluoride in the nano emulsification agent and strengthen microexplosion and secondary-atomizing; Promote fully burning; And the efficient of enhancing water-gas reaction, impel reaction to produce more hydrogen, so just fully eject the energy in the water; Effectively replenished and add the calorific loss on year-on-year basis that water causes, the thermo-efficiency that makes the biofuel after the emulsification is no less than pure diesel oil; 3, nano emulsification agent and biofuel and alcohol diesel, stable performance, production cost is low, save energy, the oil engine working power is big, and exhaust smoke is low, and atmospheric pollution is few.
Embodiment
Below in conjunction with concrete instance, the present invention is described in further detail.Should be understood that these embodiment just in order to demonstrate the invention, but not limit scope of the present invention by any way.
Instance 1:
Take off the row composition respectively according to weight percent: sodium hydroxid 8%, naphthenic acid 20%, thanomin 2%, nitric acid hexamethylene fat 0.4%, boron trifluoride 0.3%, two alkylphosphonic acid carboxylic acid 0.3%, polysorbate60 4%, 200# solvent oil 50%, water 13%; Add in the reaction kettle and stirred 30 minutes, uniform mixing gets nano emulsification agent.
In the winter time, nano emulsification agent weight meter adds EGME 0.3%.
Take off the row composition respectively according to weight percent: diesel oil 60%, water 39.5%, nano emulsification agent 0.5%, add and stir 30 minutes static mixing in the stirrer, high speed shear gets biofuel.
Take off the row composition respectively according to weight percent: diesel oil 50%, methyl alcohol 30%, water 19.5%, nano emulsification agent 0.5%, add in the stirrer and stirred 30 minutes, static mixing, high speed shear, uniform mixing gets alcohol diesel.
Get alcohol diesel 5kg and be positioned on the 30kw type diesel oil three-phase generator and burn, active power 55%, the load water resistance, measured parameter is following: rotating speed is 1500r/min+3, power 15kw, 0.02 minute working hour.
Instance 2:
Take off the row composition respectively according to weight percent: sodium hydroxid 9%, naphthenic acid 22.5%, thanomin 2%, nitric acid hexamethylene fat 0.6%, boron trifluoride 0.45%, two alkylphosphonic acid carboxylic acid 0.45%, polysorbate60 5%, 200# solvent oil 45%, water 14%; Add in the reaction kettle and stirred 40 minutes, uniform mixing gets nano emulsification agent.
In the winter time, nano emulsification agent weight meter adds EGME 0.4%.
Take off the row composition respectively according to weight percent: diesel oil 70%, water 29.5% and nano emulsification agent 0.5%, add in the stirrer and stirred 35 minutes, static mixing, high speed shear gets biofuel.
Take off the row composition respectively according to weight percent: diesel oil 57.5%, methyl alcohol 27.5%, water 14.5%, nano emulsification agent 0.5%, add in the stirrer and stirred 35 minutes, static mixing, high speed shear, uniform mixing gets alcohol diesel.
Get alcohol diesel 5kg and be positioned on the 30kw495 type diesel oil three-phase generator and burn, active power 76%, load B resistance, measured parameter is following: rotating speed is 1500r/min+2, power 23.5kw, 35 minutes working hours.
Instance 3:
Take off the row composition respectively according to weight percent: sodium hydroxid 10%, naphthenic acid 25%, thanomin 2%, nitric acid hexamethylene fat 0.8%, boron trifluoride 0.6%, two alkylphosphonic acid carboxylic acid 0.6%, polysorbate60 6%, 200# solvent oil 40%, water 15%; Add in the reaction kettle and stirred 50 minutes, uniform mixing gets nano emulsification agent.
In the winter time, nano emulsification agent adds EGME 0.5% according to the weight meter.
Get respectively by following composition according to weight percent: diesel oil 80%, water 19.5%, nano emulsification agent 0.5%, add and stir 40 minutes static mixing in the stirrer, high speed shear gets biofuel.
Take off the row composition respectively according to weight percent: diesel oil 65%, methyl alcohol 25%, water 9.5%, nano emulsification agent 0.5%, add in the stirrer and stirred 40 minutes, static mixing, high speed shear gets alcohol diesel.
Get alcohol diesel 5kg and be positioned on the 30kw495 type diesel oil three-phase generator and burn, active power 90%, load B resistance, measured parameter is following: rotating speed is 1502r/min+3, power 31kw, 28.5 minutes working hours.
Instance 4:
Take off the row composition respectively according to weight percent: sodium hydroxid 8%, naphthenic acid 20%, thanomin 2%, nitric acid hexamethylene fat 0.4%, boron trifluoride 0.3%, two alkylphosphonic acid carboxylic acid 0.3%, polysorbate60 4%, 200# solvent oil 50%, water 13%; Add in the reaction kettle and stirred 30 minutes, uniform mixing gets nano emulsification agent.
In the winter time, nano emulsification agent weight meter adds EGME 0.3%.
Take off the row composition respectively according to weight percent: diesel oil 60%, water 39.5%, nano emulsification agent 0.5%, add and stir 30 minutes static mixing in the stirrer, high speed shear gets biofuel.
Take off the row composition respectively according to weight percent: diesel oil 50%, ethanol 30%, water 19.5%, nano emulsification agent 0.5%, add in the stirrer and stirred 30 minutes, static mixing, high speed shear, uniform mixing gets alcohol diesel.
Get alcohol diesel 5kg and be positioned on the 30kw495 type diesel oil three-phase generator and burn, active power 70%, load B resistance, measured parameter is following: rotating speed is 1501r/min+3, power 33kw, 38.5 minutes working hours.
Instance 5:
Take off the row composition respectively according to weight percent: sodium hydroxid 9%, naphthenic acid 22.5%, thanomin 2%, nitric acid hexamethylene fat 0.6%, boron trifluoride 0.45%, two alkylphosphonic acid carboxylic acid 0.45%, polysorbate60 5%, 200# solvent oil 45%, water 14%; Add in the reaction kettle and stirred 40 minutes, uniform mixing gets nano emulsification agent.
In the winter time, nano emulsification agent weight meter adds EGME 0.4%.
Take off the row composition respectively according to weight percent: diesel oil 70%, water 29.5% and nano emulsification agent 0.5%, add in the stirrer and stirred 35 minutes, static mixing, high speed shear gets biofuel.
Take off the row composition respectively according to weight percent: diesel oil 57.5%, ethanol 27.5%, water 14.5%, nano emulsification agent 0.5%, add in the stirrer and stirred 35 minutes, static mixing, high speed shear, uniform mixing gets alcohol diesel.
Get alcohol diesel 5kg and be positioned on the 30kw495 type diesel oil three-phase generator and burn, active power 78%, load B resistance, measured parameter is following: rotating speed is 1502r/min+3, power 37kw, 40 minutes working hours.
Instance 6:
Take off the row composition respectively according to weight percent: sodium hydroxid 10%, naphthenic acid 25%, thanomin 2%, nitric acid hexamethylene fat 0.8%, boron trifluoride 0.6%, two alkylphosphonic acid carboxylic acid 0.6%, polysorbate60 6%, 200# solvent oil 40%, water 15%; Add in the reaction kettle and stirred 50 minutes, uniform mixing gets nano emulsification agent.
In the winter time, nano emulsification agent adds EGME 0.5% according to the weight meter.
Get respectively by following composition according to weight percent: diesel oil 80%, water 19.5%, nano emulsification agent 0.5%, add and stir 40 minutes static mixing in the stirrer, high speed shear gets biofuel.
Take off the row composition respectively according to weight percent: diesel oil 65%, ethanol 25%, water 9.5%, nano emulsification agent 0.5%, add in the stirrer and stirred 40 minutes, static mixing, high speed shear gets alcohol diesel.
Get alcohol diesel 5kg and be positioned on the 30kw495 type diesel oil three-phase generator and burn, active power 85%, load B resistance, measured parameter is following: rotating speed is 1502r/min+3, power 39kw, 45 minutes working hours.
Claims (3)
1. nano emulsification agent; This nano emulsification agent is made up of following composition by weight percentage: 8-10% sodium hydroxide, 20-25% naphthenic acid, 2% thanomin, 0.4-0.8% nitric acid hexamethylene fat, 0.3-0.6% boron trifluoride, the two alkylphosphonic acid carboxylic acids of 0.3-0.6%, 4-6% polysorbate60,40-50%200# solvent oil, 13-15% water; The working method of this nano emulsification agent: by above-mentioned each component weighing; Add in the reaction kettle and stirred 30-50 minute, uniform mixing gets nano emulsification agent; It is characterized in that: in the winter time, nano emulsification agent adds EGME 0.3-0.5% by weight.
2. biofuel; It is characterized in that: biofuel is made up of following composition: diesel oil 60-80%, water 19.5-39.5%, the described nano emulsification agent 0.5% of claim 1; The working method of this biofuel:, add in the stirrer and stirred static mixing 30-40 minute by above-mentioned each component weighing; High speed shear gets biofuel.
3. alcohol diesel; It is characterized in that: alcohol diesel is made up of following composition: diesel oil 50-65%, methyl alcohol or ethanol 25-30%, water 9.5-19.5%, the described nano emulsification agent 0.5% of claim 1; The working method of this alcohol diesel:, add in the stirrer and stirred static mixing 30-40 minute by above-mentioned each composition weighing; High speed shear gets alcohol diesel.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200810244584A CN101434878B (en) | 2008-12-11 | 2008-12-11 | Nano emulsification agent, biodiesel and alcohol diesel |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200810244584A CN101434878B (en) | 2008-12-11 | 2008-12-11 | Nano emulsification agent, biodiesel and alcohol diesel |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101434878A CN101434878A (en) | 2009-05-20 |
| CN101434878B true CN101434878B (en) | 2012-09-05 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN200810244584A Expired - Fee Related CN101434878B (en) | 2008-12-11 | 2008-12-11 | Nano emulsification agent, biodiesel and alcohol diesel |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4695293A (en) * | 1985-09-20 | 1987-09-22 | Saul Kessler | Fuel additive |
| CN1293231A (en) * | 1999-10-15 | 2001-05-02 | 深圳彩虹气雾剂制造有限公司 | Additive for increasing octane number of fuel oil and its preparing process |
| CN101058747A (en) * | 2007-06-21 | 2007-10-24 | 刘同元 | Emulsification diesel fuel additive, emulsification diesel fuel using the same and preparation method thereof |
-
2008
- 2008-12-11 CN CN200810244584A patent/CN101434878B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4695293A (en) * | 1985-09-20 | 1987-09-22 | Saul Kessler | Fuel additive |
| CN1293231A (en) * | 1999-10-15 | 2001-05-02 | 深圳彩虹气雾剂制造有限公司 | Additive for increasing octane number of fuel oil and its preparing process |
| CN101058747A (en) * | 2007-06-21 | 2007-10-24 | 刘同元 | Emulsification diesel fuel additive, emulsification diesel fuel using the same and preparation method thereof |
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| Publication number | Publication date |
|---|---|
| CN101434878A (en) | 2009-05-20 |
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Granted publication date: 20120905 Termination date: 20121211 |