CN101332690A - Decorating material and decoration - Google Patents

Decorating material and decoration Download PDF

Info

Publication number
CN101332690A
CN101332690A CNA2008101265447A CN200810126544A CN101332690A CN 101332690 A CN101332690 A CN 101332690A CN A2008101265447 A CNA2008101265447 A CN A2008101265447A CN 200810126544 A CN200810126544 A CN 200810126544A CN 101332690 A CN101332690 A CN 101332690A
Authority
CN
China
Prior art keywords
ornament materials
transparent base
light
trickle jog
trickle
Prior art date
Application number
CNA2008101265447A
Other languages
Chinese (zh)
Other versions
CN101332690B (en
Inventor
村山秀弥
Original Assignee
株式会社Hitec
日本精工油墨股份有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to JP2008106655 priority Critical
Priority to JP2008-106655 priority
Priority to JP2008106655A priority patent/JP5236342B2/en
Application filed by 株式会社Hitec, 日本精工油墨股份有限公司 filed Critical 株式会社Hitec
Publication of CN101332690A publication Critical patent/CN101332690A/en
Application granted granted Critical
Publication of CN101332690B publication Critical patent/CN101332690B/en

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44CPRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C5/00Processes for producing special ornamental bodies
    • B44C5/08Leaded lights
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44CPRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • B44C1/22Removing surface-material, e.g. by engraving, by etching
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44CPRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C3/00Processes, not specifically provided for elsewhere, for producing ornamental structures
    • B44C3/02Superimposing layers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44CPRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C5/00Processes for producing special ornamental bodies
    • B44C5/04Ornamental plaques, e.g. decorative panels, decorative veneers
    • B44C5/0469Ornamental plaques, e.g. decorative panels, decorative veneers comprising a decorative sheet and a core formed by one or more resin impregnated sheets of paper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44FSPECIAL DESIGNS OR PICTURES
    • B44F1/00Designs or pictures characterised by special or unusual light effects
    • B44F1/02Designs or pictures characterised by special or unusual light effects produced by reflected light, e.g. matt surfaces, lustrous surfaces
    • B44F1/04Designs or pictures characterised by special or unusual light effects produced by reflected light, e.g. matt surfaces, lustrous surfaces after passage through surface layers, e.g. pictures with mirrors on the back
    • B44F1/045Designs or pictures characterised by special or unusual light effects produced by reflected light, e.g. matt surfaces, lustrous surfaces after passage through surface layers, e.g. pictures with mirrors on the back having mirrors or metallic or reflective layers at the back side
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44FSPECIAL DESIGNS OR PICTURES
    • B44F1/00Designs or pictures characterised by special or unusual light effects
    • B44F1/08Designs or pictures characterised by special or unusual light effects characterised by colour effects
    • B44F1/10Changing, amusing, or secret pictures

Abstract

The invention provides an ornament and decorating materials acquiring bright colorful graphics with black as background color. In the decorating material 100, the fine concave-convex part 40 is formed on the interface of the transparent substrate 10 and the colorful transparent layer 20; part of the incident light from transparent substrate 10 to the decorating material 100 is reflected by the fine concave-convex part 40; the bright graphic pattern is acquired on the fine concave-convex part 40; because the light is absorbed by the black layer 30, the abstruse black can be acquired. Accordingly, the bright colorful graphic pattern can be acquired with black as the background color, gaining the unprecedented sense of beauty.

Description

Ornament materials and ornament
Technical field
The present invention relates to ornament materials and ornament.
Background technology
The technology of relevant pitch-dark covering with paint has the record in the patent documentation 1 to 3.
Record in patent documentation 1, on base material, cover with paint, lacquer, colour wash, etc. the 1st base coating that contains the specified quantitative carbon black pigment, obtain film on cover with paint, lacquer, colour wash, etc. the 2nd base coating contain black dyes, again obtain film on cover with paint, lacquer, colour wash, etc. the clear dope contain specific gloss conditioning agent, obtain to have thus to film as the lacquer style of lacquer texture.
A plurality of surface roughness controls that are coated with membrane interface are carried out in record in patent documentation 2, the scattered light in filming with reduction.
Put down in writing the control of carrying out a plurality of contained amount of carbon blacks of filming in patent documentation 3, making films presents the method for feeling of high class.
Technology about compound colour colour developing is on the books in patent documentation 4 to 6.
Record in patent documentation 4: in order to give new intention, by allowing the different macromolecular compound intermeshing more than 2 kinds of refractive index, cause the reflection interference of interlayer, the angle difference changes tone according to the observation, makes it to have the method for high brightness sense.
In addition, record in patent documentation 5: 2 kinds of macromolecular compound intermeshings that refractive index is different, the reflection interference by interlayer make its colour developing, and obtain more bright-coloured tone by contain carbon black in matrix.
In patent documentation 6, form buckle layer at the back side of transparent sheet-like base material, outside it, in the manufacture method of the ornament materials of stacked reflection layer, put down in writing the manufacture method that can show ornament materials three-dimensional, clear pattern by light and shade.
In addition, as the technology that forms buckle layer at the back side of transparent sheet-like base material, put down in writing a kind of cosmetic sheet in patent documentation 7, this cosmetic sheet is to have two sheets of convex-concave pattern to fit together one or both sides, is laminated into the binding face that convex-concave pattern becomes two sheets.
[patent documentation 1] TOHKEMY 2006-239519 communique
[patent documentation 2] Japanese kokai publication hei 6-15223 communique
[patent documentation 3] TOHKEMY 2001-179176 communique
[patent documentation 4] TOHKEMY 2001-347798 communique
[patent documentation 5] TOHKEMY 2002-67239 communique
[patent documentation 6] TOHKEMY 2007-216088 communique
[patent documentation 7] Japanese kokai publication hei 10-34780 communique
Summary of the invention
Yet, in the technology of patent documentation 4 to 6 records, be the reflection interference light that is used to from interlayer, therefore the flickering that has scattering of light to bring accompanies, and is not suitable for building the pitch-dark sedate atmosphere of bringing.And in the ornament materials of patent documentation 6, though record can be used the background layer of black, this ornament materials is to form reflection layer with metallic film, and what therefore obtain is the metallochrome of blackout.
In the technology of patent documentation 7 records, because be cosmetic sheet, so must guarantee the transparency, when existing use pitch-dark uncomfortable problem can take place in addition.
The inventor is the pattern of the distinctness of background in order to obtain to have the pitch-dark of feeling of high class, has carried out deep discussion.The new conclusion that obtains is, the reason that can not obtain to have more the pitch-dark look of feeling of high class is that light is absorbed the cause that is reflected by black layer.Therefore find: in incident light, by using the light and the absorbed light of reflection simultaneously, the color graphics of the pitch-dark distinctness for background colour with feeling of high class that can obtain in the past not have.
The invention provides a kind of ornament materials, it comprises: the transparent base that trickle jog is arranged in the above; The colourful transparent layer that on above-mentioned transparent base, forms; The black layer that on above-mentioned colourful transparent layer, forms.
Its architectural feature is in pitch-dark background colour, to appear multicolour pattern in one's mind in the pairing position of above-mentioned trickle jog.
In this ornament materials, between transparent base and colourful transparent layer, be formed with trickle jog.Therefore, incide the light of ornament materials from the transparent base side, a part obtains distinct pattern in trickle jog reflection in the position of the trickle jog of correspondence.In addition, because black layer with light absorption, can obtain deep and present the pitch-dark of feeling of high class.For this reason, unexistent in the past aesthetic feeling can be obtained, the ornament materials that obtains distinct color graphics in the background colour with pitch-dark sense can be implemented in.
According to the present invention, can be implemented in the ornament materials and the ornament that obtain distinct color graphics in the background colour with pitch-dark sense.
Description of drawings
Fig. 1 is the sectional view of the principle of explanation light when inciding ornament materials of the present invention;
Fig. 2 is the outside drawing of expression ornament materials of the present invention;
Fig. 3 is the schematic diagram of spectral-transmission favtor distribution (L2);
Fig. 4 is the spectral reflectivity distribution (schematic diagram of L3 (o)+L6);
Fig. 5 is spectral reflectivity distribution (L3 (o)) schematic diagram of the present invention;
Fig. 6 is the schematic diagram of dichroism;
Fig. 7 is the schematic diagram of the dichroism of trying to achieve by calculating;
Fig. 8 is the sectional view of the trickle jog of amplification;
The sectional view of the principle when Fig. 9 is the laminate of explanation light incident transparent base and colourful transparent layer;
Figure 10 is the definition diagram of arithmetic mean roughness (Ra);
Figure 11 is the definition diagram of maximum height (Ry).
[symbol description]
1 ornament materials
10 transparent bases
20 colourful transparent layers
30 black layers
40 trickle jogs
41 big recesses
100 ornament materials
300 laminates
401 first areas
402 second areas
The L1 incident light
The L2 transmitted light
The L3 reverberation
L4 absorbs light
The L5 irradiates light
The L6 transmitted light
L7 absorbs light
The specific embodiment
Below, the most preferred embodiment of the ornament materials that present invention will be described in detail with reference to the accompanying.In addition, in the description of the drawings, same key element is enclosed prosign, and the repetitive description thereof will be omitted.In the present embodiment, the direction about having stipulated all around as shown in the figure illustrates.But the facility regulation that this just does for the relativeness of simple declaration inscape does not limit the direction when implementing product of the present invention during fabrication with use.
Arithmetic average roughness Ra calculates according to the method for the B0601 of Japanese Industrial Standards regulation among the embodiment, and it is defined as follows:
Ra is meant that the direction along average line from roughness curve is chosen datum length, and the direction of the average line of this selected part is as X-axis, vertically the multiplying power direction is as Y-axis, during with the coarse curve of Y=f (x) expression, as shown in figure 10, represent with micron (μ m) with the value that following formula is tried to achieve
Ra = 1 l ∫ 0 l | f ( x ) | dx
L: fundamental length
Maximum height (Ry) is defined as follows:
Ry is meant that the direction along average line from roughness curve is chosen datum length, measures the mountain peak line of this selected part and the interval between the valley line on vertical multiplying power direction of roughness curve, micron (μ m) expression of this value, and with reference to Figure 11,
Ry=Rp+Rv
Annotate: when asking Ry, the part that does not have high mountain and low ebb that is regarded as scratching, a usefulness of choosing as datum length.
Fig. 1 is the sectional view of the principle of explanation light when inciding ornament materials of the present invention.
Ornament materials 100 is included in the back side (among Fig. 1 following) has the transparent base 10 of trickle jog 40 and the colourful transparent layer 20 that forms and forms below transparent base 10 black layer 30 below colourful transparent layer 20.Have as above the ornament materials 100 that constitutes, when from top observation transparent base 10, in pitch-dark background colour, appear colored figure in one's mind in the position of the trickle jog 40 of correspondence.
The surface of transparent base 10 (among Fig. 1 following) can form trickle jog 40 at whole, perhaps can only form on a part.Formation zone according to trickle jog 40 can increase the variation of pattern, can obtain utilizing the aesthetic that contrast produced with background colour in addition.In addition, by only forming at the trickle jog 40 of a part, can the limiting pattern zone, performance pattern, font, drawing etc.
There is no particular limitation for the lower limit of transparent base 10 thickness, but be preferably more than the 0.05mm, more preferably more than the 0.1mm.In addition, the upper limit of transparent base 10 thickness also is not particularly limited, preferably below 10mm, more preferably below 3mm.
Transparent base 10 can use at least a in transparent resin plate, glass plate and the crystalline ceramics plate.Transparent base 10 can be a single or multiple lift in addition, also can comprise film.
In addition, transparent base 10 can be colourless also can be coloured.Can obtain the pattern of various tones thus.
Trickle jog 40 is recess or protuberance, and also comprising for the surface of transparent base 10 is any form of recess or protuberance.Trickle jog 40 also comprises by the surface of transparent base 10 being carried out groove, hole or the cave that asperities processing etc. obtains.In addition, to be preferably be at least a shape in inferior light shape, thin-line-shaped, channel form, granular convex and the diffraction light palisade to trickle jog 40.In addition, trickle jog 40 can form with ultraviolet curing resin.Thus, can obtain the jog of desired shape or size, the pattern that can realize having various functions easily.
Trickle jog 40 becomes area of the pattern (being provided with trickle concavo-convex zone), makes top (transparent base 10 among Fig. 1 following) of ornament materials 100 appear the plane or three-dimensional figure in one's mind.Trickle jog 40 can be with the reflection of the part from the light of transparent base 10 side incidents, and another part sees through simultaneously.In addition, can bring into play the effect of the scattering object of scattered light.
The shape of trickle jog 40 is not particularly limited, for example among Fig. 8 for example.Fig. 8 is the amplification sectional view in the cross section of trickle jog 40.
Shown in Fig. 8 (a), trickle jog 40 is that the normal to a surface direction at transparent base 10 almost forms recessed or protruding abreast.
The arithmetic average roughness Ra of trickle jog 40 (JIS B0601) is preferably more than the 0.05 μ m, more preferably more than the 0.1 μ m.In addition, Ra is preferably below the 5 μ m, more preferably below the 3 μ m.Can obtain a large amount of reflection light quantities thus.In other words, the trickle jog 40 (scattering object) of this scope size though also interdependent its shape of scattering power and with on every side refringence, but that records and narrates in the Mie scattering usually can be 2~3 scope to visible scattering of light, scattering power 2 when bigger than scattering object has bigger scattering power, therefore can obtain bigger reflection light quantity.
The distance that each of small jog is concavo-convex is preferably the degree of arithmetic average roughness Ra.Thus, reflection light quantity is also very big.In other words, the reflection light quantity that is present in the trickle jog 40 (scattering object) in the face is relevant with the number of the trickle jog 40 (scattering object) of the scattering power of each trickle jog 40 (scattering object) and unit are, certainly, they big more its reflection light quantity is big more as a result.For this reason, during preferably with the average-size of trickle jog 40 (scattering object) spaced apart, scattering object density is maximum, and reflection light quantity is also very big.
In addition, with the relation of arithmetic average roughness Ra in, for example, when Ra is 1 μ m, the trickle jog 40 of fine and closely woven filling (scattering object), when being 3 μ m with Ra relatively, the trickle jog 40 (scattering object) of similar shape, its number may be 9 times.For this reason, comparison is long-pending with the scattering power energy, and reflection light quantity might become big when Ra was 1 μ m.
In addition, shown in Fig. 8 (b), it is the first area 401 of the above big recess of 5 μ m and the second area 402 that does not form big recess that trickle jog 40 can have the degree of depth of forming.
The arithmetic average roughness Ra of the trickle jog 40 in the second area 402 in this case (JIS B0601) is preferably more than the 0.05 μ m, more preferably more than the 0.1 μ m.In addition, Ra is preferably below the 5 μ m, more preferably below the 3 μ m.
Big recess 41 is bigger than the recess of trickle jog 40, and the degree of depth of big recess 41 is below 50 μ m more than the 5 μ m.In addition, the A/F of big recess 41 is not particularly limited, but is preferably more than the 1 μ m.
Internal face at big recess 41 can further be provided with trickle jog 40 (Fig. 8 (b)).For this reason, because the normal direction in the formation zone of trickle jog 40 is different with the normal direction of the face of its transparent base 10, therefore for the incident light that comes from same direction, the catoptrical reflection direction difference of its surface reflection and superficial reflex can be looked from different directions and be recognized different patterns.
In addition, the internal face of big recess 41 is inclined-planes, and the normal direction on this inclined-plane can to form the normal direction in zone different with the area of the pattern that is provided with in shiny surface beyond area of the pattern or the shiny surface concavo-convex.Thus, can be from the specific reflection direction, control can be looked the direction of recognizing pattern.
Moreover, the directionality or the angle of the internal face of the big recess 41 by making up trickle jog 40, control can be looked from specific direction respectively and recognize a plurality of patterns from the catoptrical directionality of trickle jog 40 (area of the pattern).
Have, by limiting small relief region as area of the pattern, trickle jog 40 and big recess 41 can show pattern, font, drawing etc. again.
When big recess 41 loop cycle ground formed, its equispaced (spacing) do not limit especially, can set arbitrarily.The equispaced (spacing) of big recess 41 can be calculated the average period of big recess 41 and measure with the surface configuration of electron microscope observation ornament materials 100.The spacing of big recess 41 is preferably more than the 1 μ m, below the 50 μ m, more preferably below the 20 μ m.
As the formation method of trickle jog 40, can use the asperities method for processing.Especially preferably adopt at least a method in honed pattern processing, thread pattern processing, channel patterns processing, the processing of granular pattern projection and the diffraction grating pattern processing to form.Can obtain the reflection enhancement structure of trickle jog 40 thus.In addition, by the machine direction of combination, can obtain in the interface of colourful transparent layer and transparent base, being distributed with the structure of small trickle jog 40 by these methods.
Moreover, be wire by making small trickle jog 40, its distribution has directionality, the catoptrical reflection direction of surface reflection and superficial reflex can strong reflection to the line prescription in vertical face.
Material as colourful transparent layer 20 for example has: vinyl chloride-based resin, vinyl chloride vinyl acetate copolymer resin, acrylic ester resin, polycarbonate-based resin, amorphous mylar, acrylic resin, acrylonitrile-butadiene-styrene (ABS) as resin binder are resin, polyacrylonitrile based resin etc.Coloring printing inks etc. are not particularly limited, preferred organic pigment.Colourful transparent layer 20 is that colourful transparent is filmed, and has transparent painted.The tone of tinting is not particularly limited, and for example can be sky blue, blueness, yellow etc.
The thickness of colourful transparent layer 20 is not particularly limited, and is preferably below the above 30 μ m of 1 μ m.
There is no particular limitation for the tone of colourful transparent layer 20, and the combination of the shape of the trickle jog 40 of color harmony by colourful transparent layer 20 can be looked the pattern of recognizing the regulation color.
As the material of black layer 30, it is resin, polyacrylonitrile based resin etc. that vinyl chloride-based resin, vinyl chloride vinyl acetate copolymer resin, acrylic ester resin, polycarbonate-based resin, amorphous mylar, acrylic resin, acrylonitrile-butadiene-styrene (ABS) as resin binder are for example arranged.Colorize method is not particularly limited, and can be colored as black by carbon black etc.
The thickness of black layer 30 is not particularly limited, but is preferably below the above 60 μ m of 1 μ m.
Black layer 30 is fast black base bottom coatings, and performance is as the effect that absorbs photosphere.
The following describes the effect of ornament materials 100.
In this ornament materials 100, form trickle jog 40 at the interface of transparent base 10 and colourful transparent layer 20.Therefore, a light part that incides ornament materials 100 from transparent base 10 sides is reflected at trickle jog 40, thereby obtains distinct pattern in the position of the trickle jog 40 of correspondence.In addition, black layer 30 absorbs light, can obtain to have the pitch-dark of deep sense and feeling of high class thus.Obtain unexistent in the past aesthetic feeling thus, be implemented in the ornament materials 100 that obtains distinct color graphics in the background colour with pitch-dark sense.
With reference to Fig. 1,9, further describe.
Fig. 1 is the sectional view of the principle of explanation light when inciding in the ornament materials of present embodiment.Fig. 9 be explanation light incide in the past transparent base and the laminate of colourful transparent layer in the time the sectional view of principle.
As shown in Figure 9, the top white light L1 of transparent base 10 that incides laminate 300 is divided into transmitted light L2 through colourful transparent layer 20, surface reflection and superficial reflex light L3 (o) or the absorption light L4 that is absorbed in the colourful transparent layer 20 of small reflection is several on colourful transparent layer 20 after seeing through transparent base 10.
Opposite in addition, the following irradiates light L5 that incides colourful transparent layer 20 is also same with white light L1, after seeing through colourful transparent layer 20, be divided into transmitted light L6, surface reflection and superficial reflex light (not have diagram) or the absorption light (less than illustrating) that is absorbed into transparent base 10 in of small reflection is several below transparent base 10 through transparent base 10.
In other words, when above transparent base 10, seeing laminate 300, by transmitted light L2, reverberation L3 (o), transmitted light L6, form the tone of colourful transparent layer 20, and looked and recognize.Yet the luminous energy of reverberation L3 (o) is about 1%, compares very for a short time with transmitted light L2, transmitted light L6, even its wavelength region may is different with transmitted light L2, transmitted light L6, also is difficult to be looked usually recognizes.Therefore, transmitted light L2, transmitted light L6 are looked as dominant hue and are recognized.
To this, ornament materials 100 its cross-sectional configuration adopt structure as shown in Figure 1.In other words, ornament materials 100 following formations: in incident above transparent base 10, through the incident light of transparent base 10, a part reflects at trickle jog 40, the outside of directive transparent base 10, and a part sees through colourful transparent layer 20 arrival black layer 30 and is absorbed in addition simultaneously.Below describe in detail.
As shown in Figure 1, ornament materials 100 is provided with black layer 30 below colourful transparent layer 20, and the part on colourful transparent layer 20 forms trickle jog 40.The top white light L1 that incides transparent base 10 be divided into after by transparent base 10 through colourful transparent layer 20 and the absorption light L7 that is absorbed by black layer 30, on colourful transparent layer 20 surface reflection of small reflection and superficial reflex light L3 (o), several at the reverberation L3 (eo) of trickle jog 40 reflections or the absorption light L4 that is absorbed in the colourful transparent layer 20.This occasion, transmitted light L2=shown in Figure 9 absorbs light L7.
Opposite in addition, so incide the following irradiates light L5 of black layer 30 owing to absorbed no longer existence by black layer 30.
Here, the part on colourful transparent layer 20 forms trickle jog 40.By trickle jog 40, the reflection light quantity of the reverberation L3 (eo) that can make in trickle jog 40 reflections is than the remarkable enhancing of reverberation L3 (o).So just can look and recognize the reverberation L3 (eo) that light quantity strengthens.
For this reason, when seeing ornament materials 100 above transparent base 10, among incident light (white light) L1, a part becomes reverberation L3 (eo) in trickle jog 40 reflections, can see trickle jog 40 brightly.On the other hand, reverberation L3 (o) is owing to looked and recognized hardly, and the black with pitch-dark sense is looked thinks the substrate of pattern.
So just can realize obtaining unexistent in the past attractive in appearance, be background colour with pitch-dark, look and think the ornament materials 100 that appears distinct relief pattern in one's mind.
Below, describe with regard to the manufacture method of the ornament materials in the present embodiment 100.
Ornament materials 100 for example can be made in accordance with the following methods.
At first, smooth transparent base 10 above preparing, the trickle jog of formation on transparent base 10.Next, painted transparent ink of coating or coating on transparent base 10 form colourful transparent layer 20, and then painting black printing ink or coating form black layer 30 successively and makes.
The method that forms trickle jog 40 can adopt the asperities method for processing.At least a method in preferred especially honed pattern processing, thread pattern processing, channel patterns processing, the processing of granular pattern projection and the diffraction grating pattern processing.
And, can obtain the ornament that the surface possesses ornament materials 100.For example, because can to obtain with pitch-dark be the dark-toned pattern of background, can be applied to begin recently in the senior covering with paint product such as framework of the high mobile phone of requirement decorative surface, PC, LCD TV.And then also be used for senior household electrical appliance.In addition, also be diverted to the covering with paint of automobile, special wallpaper etc., also can be used as the ornament materials that upholstery with feeling of high class uses and use.
Ornament materials of the present invention with and manufacture method be not defined as the foregoing description, various distortion can be arranged.
In the above-described embodiments, exemplified in the first area 401 examples that form big recess 41, also can form in first area 401 highly is big protuberance more than the 5 μ m.This occasion, big protuberance is bigger than the protuberance of trickle jog 40, and preferred maximum wide cut is more than the 1 μ m.In addition, the outside wall surface at big protuberance can also be provided with trickle jog 40.Also can access the effect same by so big protuberance with above-mentioned big recess 41.
In the first area 401, can form the either party or two sides of big recess 41 and big protuberance.
Below exemplify embodiments of the invention, describe the present invention in detail.
[experiment 1]
Carry out following experiment with embodiment 1.
(embodiment 1)
On the transparency carrier that uses Merlon, be processed to form pattern (jog), and serigraphy stacks gradually blue colourful transparent layer (the SEIKO ADVANCE of Co., Ltd. system KKY 440 bluenesss) and black layer (the SEIKO ADVANCE of Co., Ltd. system KKY 710 black) is filmed by fine rule.Pattern is with ultraviolet curing resin the fine rule shape to be covered with to film, and it is arranged on the transparency carrier, obtains ornament materials 1.
Appearance images during from ornament materials 1 irradiates light that the transparency carrier side direction obtains as shown in Figure 2.In Fig. 2, in pitch-dark background colour, appeared the mottled pattern (aubergine) of white expression in one's mind, can look three-dimensionally and recognize.
Next, measured the trickle concavo-convex state that forms on the transparency carrier surface of ornament materials 1.Adopt the KEYENCE of Co., Ltd. system laser microscope VK-9500, the surface configuration of observing ornament materials 1, the result, the equispaced that can calculate the big recess of periodic cycle formation is approximately 50 μ m spacings.In addition, " the maximum height Ry " that is equivalent to look among trickle concavo-convex " datum length " 250 μ m of the position of recognizing pattern is~0.3 μ m for~1.5 μ m, " arithmetic average height Ra ".
(reference example 1)
Prepare colourful transparent layer, measure spectral transmittance distribution (spatial distribution of L2) with the SEIKO ADVANCE of Co., Ltd. system KKY 440 blue stains.This occasion, determined spectrum is equivalent to the spectrum of L2 shown in Figure 9.
Its result is shown in Figure 3.
As shown in Figure 3, spectrum has peak value (transmission 50%) at the 490nm place, and the FWHM (half range overall with) that with 490nm is the center is for about 120nm.
As can be seen from Figure 3, (370nm~610nm) see through does not almost see through in the zone from 580nm to 740nm in the FWHM120nm zone that with 490nm is the center to incide the light of colourful transparent layer.The peak value of transmissivity is approximately 50%, is transparent tone.
(reference example 2)
Measured spectral reflectivity with two layers of body of blue-colored colourful transparent layer of the SEIKO ADVANCE of Co., Ltd. system KKY 440 and white reflecting plate distribute (spatial distribution of L6).This occasion, determined spectrum is equivalent to the spectrum of L6 shown in Figure 9.In this was measured, the L2 of Fig. 1 and L5 almost were equivalent to same occasion, back and forth transmission.
Its result is shown in Figure 4.
As shown in Figure 4, spectrum has peak value (reflection 53%, to be set at 100% from the reflectivity of white reflecting plate at the 470nm place.), be that the FWHM at center is about 90nm with 470nm.In addition, from 560nm, at long wavelength side some reflection light quantities are arranged, near 620nm, 720nm, mild peak value is arranged, reflectivity rises after 740nm.
We see that different with the occasion of Fig. 3, the half range overall with roughly is reduced to 90nm, at long wavelength side reverberation is arranged from 560nm.In addition, such reflection light quantity is corresponding with L3 (o) among Fig. 9, generation a small amount of surface reflection, superficial reflex on the colourful transparent layer.
(reference example 3)
Measured spectral reflectivity with two layers of body of blue-colored colourful transparent layer of the SEIKO ADVANCE of Co., Ltd. system KKY 440 and black layer distribute (spatial distribution of L3 (o) or L3 (eo)).This occasion, determined spectrum are equivalent to the spectrum of L3 shown in Figure 1 (o) or L3 (eo).In this is measured,, do not exist fully from the incident light at the back side (following) of black layer as with Fig. 1 explanation.
Its result illustrates at Fig. 5.
As shown in Figure 5, reflectivity is greatly about 1% front and back.In addition, near near near the 420nm, the 620nm, the 720nm and the later zone of 740nm the big relatively peak value of reflectivity is arranged.Near this 420nm peak value occupies main wavelength region may blue region.
The synthetic result of this peak light of 4 is an aubergine.This is and the identical color of representing with the white among Fig. 2 of mottled figure.
Shown in Fig. 3~5, absorb at the transmitted light of black layer the colourful transparent layer, the people is looked recognize pitch-dark background colour, can look simultaneously the surface reflection recognized on the colourful transparent layer, superficial reflex be strengthened and the pattern of the distinctness that presents, obtain being fit to realizing having the ornament materials of the decoration of feeling of high class at trickle jog.
[experiment 2]
Carry out following experiment with the embodiment 2 shown in following.
(embodiment 2)
Used with the painted colourful transparent layer of navy blue transparent ink (the SEIKO ADVANCE of Co., Ltd. system VIC concentrates 400 navy blues) to replace the colourful transparent layer of the blueness of the foregoing description 1 use, other and embodiment 1 carry out the same film-stack that is coated with.In addition, Fig. 6 duplicates the fine rule machining state (trickle jog) that forms straight line with ultraviolet curing resin, it is arranged on the transparency carrier and obtains ornament materials.
The spectral reflectivity distribution (spatial distribution of L3 (o) or L3 (eo)) of the ornament materials that mensuration obtains (to call " black credit coloured light " in the following text).This occasion, determined spectrum is with suitable at the spectrum of L3 shown in Figure 1 (o) or L3 (eo).
Its result illustrates as " black credit look " at Fig. 6.
(reference example 4)
Spectral-transmission favtor distribution (spatial distribution of L2) (to call " transmitted light " in the following text) and spectral reflectivity distribution (spatial distribution of L6) (to call " reverberation " in the following text) have been measured with navy blue transparent ink (the SEIKO ADVANCE of Co., Ltd. system VIC concentrates 400 navy blues) the colourful transparent layer of tinting and two layers of body of transparency carrier.This occasion, the spectrum of the spectrum of mensuration and L2 shown in Figure 9 and L6 is suitable.
Its result is shown in Figure 6.
As shown in Figure 6, the wavelength of transmitted light beyond the wavelength region may that shows mass tone almost do not have light quantity, but because color is very dark, even on peak value, this transmissivity as the longitudinal axis in left side is represented, is about 10% also.The scope of reverberation beyond in the dominant wavelength zone is approximately the reflectivity about 1% shown in the longitudinal axis in left side.This is the surface reflection of colourful transparent layer and the reverberation of superficial reflex.
As shown in Figure 6, shown in the longitudinal axis on right side, the spatial distribution of black credit coloured light is extremely low reflectivity (%).But, have the peak value same with the catoptrical spectrum of colourful transparent layer.
Learn from above, because the reverberation of reflection of the surface of colourful transparent layer and superficial reflex strengthens, looked the color of the area of the pattern of recognizing is visual thinks aubergine, it is the center with near blueness the 480nm and the very dark-toned redness more than the 730nm, has mixed near near the orange of the redness of the orange and overlapping 660nm of the having 580nm.
From measured value shown in Figure 6, try to achieve the spectrophotometric spectra of L3 (o) and L3 (eo) with calculating formula.
Its result is shown in Figure 7.
Transmissivity among Fig. 6 distributes, and is the spectrophotometric spectra of the transmitted light L2 among Fig. 9, provides by following formula (1).
The transmissivity distribution (1) of the transmissivity distribution * colourful transparent layer of Wavelength distribution * transparency carrier of the transmissivity distribution=incident light L1 of transmitted light L2
Equally, the distribute rear that is the colourful transparent layer in Fig. 9 of reflectivity among Fig. 6 is provided with that white reflecting plate measures, and provides by following formula (2).
The transmissivity distribution (2) of the reflectivity distribution * transmitted light L2 of the transmissivity distribution * white reflecting plate of the reflectivity distribution+transmitted light L2 of the reverberation L3 (o) of the transmissivity distribution=colourful transparent layer of the reflectivity distribution+transmitted light L6 of the reverberation L3 (o) of the reflectivity distribution=colourful transparent layer of Fig. 6
From above formula (1), formula (2), reverberation L3 (o) shown in Figure 1 and the spectrophotometric spectra of L3 (eo) are by providing with following formula (3).
The transmissivity distribution (3) of the reflectivity distribution * transmitted light L2 of the transmissivity distribution * white reflecting plate of the reflectivity distribution-transmitted light L2 of transmissivity distribution=Fig. 6 of the reflectivity distribution-transmitted light L6 of reflectivity distribution=Fig. 6 of reverberation L3 (eo)
Reflectivity with measured value shown in Figure 6 and white reflecting plate distributes, and the result that aforementioned calculation is tried to achieve is shown in Figure 7.Result of calculation is almost consistent with measurement result, as Fig. 1 and colour developing principle illustrated in fig. 9.

Claims (9)

1, a kind of ornament materials is characterized in that it comprises:
One transparent base is formed with trickle jog on one of them face of described transparent base;
One colourful transparent layer is formed at the one side that has trickle jog on the described transparent base;
One black layer is formed on the described colourful transparent layer;
When incident light irradiation another side, in pitch-dark background color, appear multicolour pattern in one's mind in the pairing position of described trickle jog at described transparent base.
2, the described ornament materials of claim 1 is characterized in that: the arithmetic average roughness Ra of described trickle jog is calculated as 0.05 μ m~5 μ m according to the method for the B0601 of Japanese Industrial Standards regulation.
3, the described ornament materials of claim 2, it is characterized in that described trickle jog further to form the degree of depth be the above big recess of 5 μ m with and/or highly be the first area of the big protuberance more than the 5 μ m, do not form described big recess with and/or the second area of described big protuberance
The arithmetic average roughness Ra of above-mentioned second area is calculated as 0.05 μ m~5 μ m according to the method for the B0601 of Japanese Industrial Standards regulation.
4, the described ornament materials of claim 3, it is characterized in that the internal face of described big recess with and/or the outside wall surface of described big protuberance further be formed with described trickle jog.
5, the described ornament materials of claim 1, it is characterized in that: described trickle jog is formed at the part surface of described transparent base.
6, the described ornament materials of claim 1 is characterized in that described transparent base is at least a for being selected from transparent resin plate, glass plate and the crystalline ceramics plate.
7, the described ornament materials of claim 1 is characterized in that described trickle jog forms to be selected from any pattern or shape in inferior light shape, thin-line-shaped, channel form, granular convex or the diffraction light palisade on transparent base.
8, the described ornament materials of claim 1 is characterized in that described trickle jog forms on the surface of described transparent base by using ultraviolet curing resin.
9, a kind of ornament, the surface of this ornament have each described ornament materials of claim 1 to 8.
CN2008101265447A 2008-04-16 2008-07-01 Decorating material and decoration CN101332690B (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
JP2008106655 2008-04-16
JP2008-106655 2008-04-16
JP2008106655A JP5236342B2 (en) 2008-04-16 2008-04-16 Decorative materials and decorative articles

Publications (2)

Publication Number Publication Date
CN101332690A true CN101332690A (en) 2008-12-31
CN101332690B CN101332690B (en) 2012-09-05

Family

ID=40195685

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2008101265447A CN101332690B (en) 2008-04-16 2008-07-01 Decorating material and decoration

Country Status (4)

Country Link
JP (1) JP5236342B2 (en)
KR (1) KR101452507B1 (en)
CN (1) CN101332690B (en)
TW (1) TW200944394A (en)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102416738A (en) * 2010-08-11 2012-04-18 三星康宁精密素材株式会社 Multi-layered article and method of fabricating the same
CN102442092A (en) * 2011-09-08 2012-05-09 Tcl王牌电器(惠州)有限公司 Appearance treating process for flat television shell, flat television shell and flat television
CN102909923A (en) * 2011-08-03 2013-02-06 株式会社石井表记 Decorative film structure and decorative member
CN102910022A (en) * 2011-08-03 2013-02-06 株式会社石井表记 Decorative film structure and decorative member
CN102922814A (en) * 2012-11-22 2013-02-13 昆山市大金机械设备厂 Artificial pattern slate and preparation method thereof
CN103374724A (en) * 2012-04-12 2013-10-30 钜永真空科技股份有限公司 Coloured film and manufacturing method thereof
US9062366B2 (en) 2010-08-11 2015-06-23 Corning Precision Materials Co., Ltd. Multi-layered article and method of fabricating the same
CN105708110A (en) * 2014-12-22 2016-06-29 株式会社精工技研 Decorative plastic molded article and manufacturing method thereof
CN108688279A (en) * 2017-03-29 2018-10-23 丰田合成株式会社 Decoration panel
CN110035890A (en) * 2017-07-14 2019-07-19 日本精工油墨有限公司 Cosmetic sheet and decorated molded article

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5585147B2 (en) * 2010-03-23 2014-09-10 凸版印刷株式会社 Bezel decoration
CN102233692B (en) * 2010-05-07 2014-10-08 究理荣富株式会社 Decorated printed matter and manufacturing method thereof
JP5259685B2 (en) * 2010-11-30 2013-08-07 日本プライ株式会社 Colored laminated film
JP2013028075A (en) * 2011-07-28 2013-02-07 Daikyonishikawa Corp Decoration panel
JP2021504192A (en) * 2017-12-15 2021-02-15 エルジー・ケム・リミテッド Decorative members and their manufacturing methods
KR102201575B1 (en) * 2017-12-15 2021-01-12 주식회사 엘지화학 Decoration element

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3089781B2 (en) * 1991-12-09 2000-09-18 凸版印刷株式会社 Embossed decorative material and method for producing the same
JP2876437B2 (en) * 1992-07-06 1999-03-31 マツダ株式会社 Coating structure
JPH06190999A (en) * 1992-12-25 1994-07-12 Dainippon Printing Co Ltd Decorative sheet
JPH0852849A (en) * 1994-08-12 1996-02-27 Dainippon Printing Co Ltd Decorative sheet and manufacture thereof
JPH1034780A (en) * 1996-07-19 1998-02-10 Dainippon Printing Co Ltd Decorative sheet which has uneven pattern inside
JP4486191B2 (en) * 1999-10-21 2010-06-23 ロンシール工業株式会社 Decorative sheet
JP2001246693A (en) 1999-12-28 2001-09-11 Japan Tobacco Inc Thin sheet and manufacturing method for the same
JP4187433B2 (en) * 2001-10-31 2008-11-26 株式会社ピーアンドエム Linear actuator
CN2661820Y (en) * 2003-10-21 2004-12-08 王�华 Floating pattern glass marble
WO2007040339A1 (en) * 2005-10-06 2007-04-12 Minuta Technology Manufacturing process of pattern ornament through molding ultraviolet-curing resin
JP2007216088A (en) * 2006-02-14 2007-08-30 Kiyootec:Kk Manufacturing method for decorated material
CN100387545C (en) * 2006-09-29 2008-05-14 霍镰泉 Preparation method of glazed ceramic brink with stone imitation pattern based on fused block wrapping pigment

Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102416738A (en) * 2010-08-11 2012-04-18 三星康宁精密素材株式会社 Multi-layered article and method of fabricating the same
CN102416738B (en) * 2010-08-11 2016-08-31 康宁精密素材株式会社 Multi-layer product and preparation method thereof
US9062366B2 (en) 2010-08-11 2015-06-23 Corning Precision Materials Co., Ltd. Multi-layered article and method of fabricating the same
CN102909923A (en) * 2011-08-03 2013-02-06 株式会社石井表记 Decorative film structure and decorative member
CN102910022A (en) * 2011-08-03 2013-02-06 株式会社石井表记 Decorative film structure and decorative member
US9079375B2 (en) 2011-08-03 2015-07-14 Ishii Hyoko Co., Ltd. Decorative film structure and decorative member
US9067387B2 (en) 2011-08-03 2015-06-30 Ishii Hyoki Co., Ltd. Decorative film structure and decorative member
CN102910022B (en) * 2011-08-03 2015-01-14 株式会社石井表记 Decorative film structure and decorative member
CN102909923B (en) * 2011-08-03 2015-05-06 株式会社石井表记 Decorative film structure and decorative member
CN102442092B (en) * 2011-09-08 2014-08-20 Tcl王牌电器(惠州)有限公司 Appearance treating process for flat television shell, flat television shell and flat television
CN102442092A (en) * 2011-09-08 2012-05-09 Tcl王牌电器(惠州)有限公司 Appearance treating process for flat television shell, flat television shell and flat television
CN103374724A (en) * 2012-04-12 2013-10-30 钜永真空科技股份有限公司 Coloured film and manufacturing method thereof
CN102922814A (en) * 2012-11-22 2013-02-13 昆山市大金机械设备厂 Artificial pattern slate and preparation method thereof
CN105708110A (en) * 2014-12-22 2016-06-29 株式会社精工技研 Decorative plastic molded article and manufacturing method thereof
CN108688279A (en) * 2017-03-29 2018-10-23 丰田合成株式会社 Decoration panel
CN110035890A (en) * 2017-07-14 2019-07-19 日本精工油墨有限公司 Cosmetic sheet and decorated molded article
CN110035890B (en) * 2017-07-14 2020-07-03 日本精工油墨有限公司 Decorative sheet and decorative molded article

Also Published As

Publication number Publication date
TW200944394A (en) 2009-11-01
KR101452507B1 (en) 2014-10-21
JP2009255373A (en) 2009-11-05
CN101332690B (en) 2012-09-05
JP5236342B2 (en) 2013-07-17
KR20090110195A (en) 2009-10-21

Similar Documents

Publication Publication Date Title
CN105705341B (en) Optically variable element
CN104884265B (en) Multilayer body and method for producing a security element
CN201998920U (en) Decorating insert of luminous decorative vehicle
US6749777B2 (en) Diffractive pigment flakes and compositions
JP4431392B2 (en) Colorless multilayer diffractive pigments and foils
CN104797430B (en) security element and security document
CN101249773B (en) Decoration panel
EP3795367A1 (en) Optical products
US7901120B2 (en) Decorative unit with illuminable decorative elements
JP6237759B2 (en) Display and labeled goods
EP1852754B1 (en) Display plate for solar cell apparatus
US6841238B2 (en) Chromatic diffractive pigments and foils
CN106462782A (en) Transaction and ID cards having selected texture and coloring
US8153270B2 (en) Decorative casing and manufacturing method thereof
TWI458794B (en) Security image coated with a single coating having visually distinct regions
JP5775529B2 (en) Dichroic glass to make cosmetics attractive for electronic devices
CN104428694B (en) Utilize the decorative film product of Fresnel Lenses film
US7727618B2 (en) Decorative molded body, key top for a pushbutton switch, and key sheet for the pushbutton switch
CN100406274C (en) Multilayer image particularly multiple color image
US20090122575A1 (en) Surface Light Emitting Apparatus and Method of Light Emission for Surface Light Emitting Apparatus
CN102905909B (en) Security element, value document comprising such a security element, and method for producing such a security element
WO2017184581A1 (en) Optical switch devices
JP3365760B2 (en) Colored structure
KR100445291B1 (en) Structure for layer of silk screen in lcd windows and printing method thereof
CN101164021B (en) Instrument indication board and method for manufacturing instrument indication board

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
TR01 Transfer of patent right
TR01 Transfer of patent right

Effective date of registration: 20200805

Address after: No.5, No.27, No.2, Dingmu, Nanchi, Toyoshima, Tokyo, Japan

Patentee after: NSK INK Co.,Ltd.

Address before: 603-40 kojihara, Tokyo, Japan

Co-patentee before: NSK INK Co.,Ltd.

Patentee before: HITEC Kabushiki Kaisha