CN101319126A - Inorganic adhesive agent, preparation and application thereof - Google Patents
Inorganic adhesive agent, preparation and application thereof Download PDFInfo
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- CN101319126A CN101319126A CNA2008101166668A CN200810116666A CN101319126A CN 101319126 A CN101319126 A CN 101319126A CN A2008101166668 A CNA2008101166668 A CN A2008101166668A CN 200810116666 A CN200810116666 A CN 200810116666A CN 101319126 A CN101319126 A CN 101319126A
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- inorganic adhesive
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Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B12/00—Cements not provided for in groups C04B7/00 - C04B11/00
- C04B12/02—Phosphate cements
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/34—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing cold phosphate binders
- C04B28/342—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing cold phosphate binders the phosphate binder being present in the starting composition as a mixture of free acid and one or more reactive oxides
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
The invention provides an inorganic adhesive and a preparation method and an application thereof. The inorganic adhesive is characterized in that the adhesive comprises a first group of material and a second group of material, wherein the first group of material comprises one or more than one oxide or hydroxide; and the second group of material comprises one or more than one phosphorus-containing acid or salt. The inorganic adhesive can play an important role in emission treatment and resource regeneration; for example, a high-grade efficient covering proposal, etc. is provided for the reuse of harmless wastes and the treatment of harmful wastes.
Description
Technical field
The present invention relates to tackiness agent and technology of preparing thereof, a kind of inorganic adhesive and its production and application particularly, adopt described inorganic adhesive, can play a significant role aspect emissions processes and the renewable resources, for example, provide high-quality and efficient spreadability scheme or the like to harmless waste recycle or to the processing of bazardous waste.
Background technology
Along with the fast-developing and economic rapid growth of Chinese society, problems such as maximum discharge, high energy consumption, high pollution are also increasingly serious.Especially the contradiction of inadequate resources such as soil, the energy, mineral products is more and more outstanding.Therefore, energy-saving and emission-reduction, raising resource utilization, emissions processes and renewable resources are the great problem in science that influences national sustainable development.For example, China is manufacture of cement and uses first big country.Annual about 1,000,000,000 tons of cement of producing discharge about 800,000,000 tons CO in the limestone resource of 1,100,000,000 tons of consumption
2, 800,000 tons SO
3, 1,600,000 tons NO
xDust with 8,000,000 tons.And for example, China only the annual production of various solid waste wherein except a large amount of harmless nontoxic wastes, originate from addition just up to more than 1,000,000,000 tons in the bazardous waste in fields such as nuclear power, scientific research, medicine, chemical industry.These wastes have not only taken a large amount of land resources, and serious environment pollution, influence the people's quality of life even life security.Obviously, improve highly energy-consuming maximum discharge production technology, be significant to the renewable resources of harmless waste with to the safe handling of poisonous waste.With regard to the processing of waste, in particular for regard to its solidified bonding agent, comprise conventional cement, coagulate in the patent documentation of stone technology etc. disclosure is arranged more, for example: CN1415567A, CN1424275A, CN1067707A, CN1223636A, CN1273222A, CN1252781A, CN1887763A, CN1887764A, CN1939861A etc.Yet product and technology related in above-mentioned document all have its limitation.And novel inorganic binding agent described in the invention can be used for bonding nearly all known material.And its zero release, chilling process, need not extraneous provide additional energy and high features such as adhesion efficiency, will be in energy-saving and emission-reduction, improve and play a significant role aspect resource utilization, emissions processes and the renewable resources.For example, the present invention will be for providing high-quality and efficient spreadability scheme to all harmless waste recycle or to the processing of all bazardous wastes.
Summary of the invention
The present invention is directed to the defective or the deficiency that exist in the prior art, a kind of inorganic adhesive and its production and application is provided, adopt described inorganic adhesive, can play a significant role aspect emissions processes and the renewable resources, for example, provide high-quality and efficient spreadability scheme or the like to harmless waste recycle or to the processing of bazardous waste.
Technical scheme of the present invention is as follows:
Inorganic adhesive is characterized in that: comprise first group of material and second group of material, first group of material comprises one or more oxide compound or oxyhydroxide; Second group of material comprises one or more phosphorated acid or phosphorated salt.
Described oxide compound is basic oxide.
Described phosphorated acid comprises phosphoric acid, high phosphoric acid or Hypophosporous Acid, 50.
Described phosphorated salt comprises phosphoric acid salt, high phosphate or hypophosphite.
The weight ratio of described first group of material and second group of material is 1: (0.2～9.5).
The weight ratio of described first group of material and second group of material is 1: (0.5～3.5).
The weight ratio of described first group of material and second group of material is 1: (0.75～1.5).
Described oxide compound is meant the oxide compound that belongs to first, second, third and fourth cycle main group metal in the periodic table of elements, and the oxide compound of fourth, fifth, six cycle transition metals.
Described oxyhydroxide is meant in the periodic table of elements it is the oxyhydroxide of first, second, third and fourth cycle main group metal, and the oxyhydroxide of fourth, fifth, six cycle transition metals.
The application of above-mentioned inorganic adhesive in material is bonding.
Described application comprises curing schedule, and described curing schedule is meant that described tackiness agent and bonded material cause chemical curing reaction by adding a certain amount of water.
Described a certain amount of water accounts for 3～60% of gross weight.
Described a certain amount of water accounts for 5～40% of gross weight.
Described application is included in and adds building pigment in the tackiness agent, perhaps adds building pigment in curing schedule.
Described application is included in and adds fiber in the tackiness agent, perhaps adds fiber in curing schedule.
The preparation method of inorganic adhesive is characterized in that: comprise following two groups of material's proportion are mixed that first group of material comprises one or more oxide compound or oxyhydroxide; Second group of material comprises one or more phosphorated acid or phosphorated salt.
Described first group of material is prepared into powder.
Described first group of material is prepared into powder by pulverizing and/or ball milling pretreatment.
With pulverous first group of material and mixed first mixture that obtains of weak acid, with first mixture and second group of mixed second mixture that obtains of material.
In second mixture, add additive and obtain the 3rd mixture.
Described weak acid adopts a kind of or combination in the following material: boric acid, oxalic acid.
Described weak acid shared weight ratio in first mixture is＞0, to 10%.
Described additive adopts a kind of in the following material or above a kind of combination: flyash, coal gangue, metallurgical slag, building waste.
Technique effect of the present invention is as follows:
The present invention relates to a kind of inorganic adhesive and technology of preparing thereof.Described tackiness agent comprises one or more oxide compounds or oxyhydroxide and one or more phosphoric acid or phosphoric acid salt.Described method comprises following key step: according to the adherend property sort and pulverize where necessary and/or pre-treatment such as ball milling; Selected and prepare corresponding tackiness agent according to the adherend characteristic; With prepared adhesive and adherend thorough mixing; The gained mixture is mixed with an amount of water and stir and make slurry and the gained slurry is injected the mold cured moulding.The present invention has very strong bonding, ability to cure to nearly all known material.Wherein, described binder materials compound has comprised basic oxide or oxyhydroxide, or the mixture of multiple basic oxide, oxyhydroxide.And described binder materials compound has comprised phosphoric acid or phosphoric acid salt, or the mixture of multiple phosphoric acid salt and phosphoric acid.And, basic oxide in tackiness agent or the encapsulants or oxyhydroxide, or mixture and the phosphoric acid or the phosphoric acid salt of multiple basic oxide, oxyhydroxide, or the weight ratio of the mixture of multiple phosphoric acid salt and phosphoric acid is 1: 0.2 to 1: 9.5.And described tackiness agent can be used for the bonding of nearly all known materials and solidifies.And described tackiness agent and adherend cause chemical curing reaction by adding a certain amount of water. and water shared weight ratio in final product is 5%-40%.And,, can prepare the final product of respective color by adding the building pigment of different colours.And,, can improve the mechanical property of final product by adding different types of fiber.And described oxide compound and oxyhydroxide include but not limited to: the oxide compound of first, second, third and fourth main group metal or oxyhydroxide, the oxide compound of fourth, fifth, six cycle transition metals or oxyhydroxide.And described acid or corresponding acid ion or corresponding salt comprise phosphoric acid and the corresponding phosphate anion or the phosphoric acid salt of known all kinds. described phosphoric acid salt or vitriol include but not limited to sodium, the various phosphoric acid salt of potassium.And described a small amount of additive includes but not limited to: boric acid, oxalic acid etc.And the oxide compound of described first, second, third and fourth main group metal can be Li
2O, MgO, Al
2O
3, GaO, SiO
2Deng; Described oxyhydroxide can be Mg (OH)
2, Ca (OH)
2, Ca (OH)
2, NaOH, KOH etc.; The oxide compound of described fourth, fifth, six cycle transition metals can be TiO
2, Fe
2O
3, ZrO, WO
3Deng; Described oxyhydroxide can be Mn (OH)
2, Zr (OH)
2Deng.And described phosphoric acid salt can be potassium primary phosphate/sodium, dipotassium hydrogen phosphate/sodium etc.Compare existing invention, the present invention has greatly enlarged the suitable ratio range of starting compound, closes application cost the end of present technique and products thereof and makes the present invention have great economy value.
Novel inorganic binding agent described in the invention can be used for bonding nearly all known material.And its zero release, chilling process, need not extraneous provide additional energy and high features such as adhesion efficiency, will be in energy-saving and emission-reduction, improve and play a significant role aspect resource utilization, emissions processes and the renewable resources.For example, the present invention will be for providing high-quality and efficient spreadability scheme to all harmless waste recycle or to the processing of all bazardous wastes.
Embodiment
The present invention relates to a kind of inorganic adhesive and technology of preparing thereof.Described tackiness agent comprises one or more oxide compounds or oxyhydroxide and one or more phosphoric acid or phosphoric acid salt.Described method comprises following key step: according to the adherend property sort and pulverize where necessary and/or pre-treatment such as ball milling; Selected and prepare corresponding tackiness agent according to the adherend characteristic; With prepared adhesive and adherend thorough mixing; The gained mixture is mixed with an amount of water and stir and make slurry and the gained slurry is injected the mold cured moulding.The present invention has very strong bonding, ability to cure to nearly all known material.Wherein, described binder materials compound has comprised basic oxide or oxyhydroxide, or the mixture of multiple basic oxide, oxyhydroxide.And described binder materials compound has comprised phosphoric acid or phosphoric acid salt, or the mixture of multiple phosphoric acid salt and phosphoric acid.And, basic oxide in tackiness agent or the encapsulants or oxyhydroxide, or mixture and the phosphoric acid or the phosphoric acid salt of multiple basic oxide, oxyhydroxide, or the weight ratio of the mixture of multiple phosphoric acid salt and phosphoric acid is 1: 0.2 to 1: 9.5.And described tackiness agent can be used for the bonding of nearly all known materials and solidifies.And described tackiness agent and adherend cause chemical curing reaction by adding a certain amount of water. and water shared weight ratio in final product is 5%-40%.And,, can prepare the final product of respective color by adding the building pigment of different colours.And,, can improve the mechanical property of final product by adding different types of fiber.And described oxide compound and oxyhydroxide include but not limited to: the oxide compound of first, second, third and fourth main group metal or oxyhydroxide, the oxide compound of fourth, fifth, six cycle transition metals or oxyhydroxide.And described acid or corresponding acid ion or corresponding salt comprise phosphoric acid and the corresponding phosphate anion or the phosphoric acid salt of known all kinds. described phosphoric acid salt or vitriol include but not limited to sodium, the various phosphoric acid salt of potassium.And described a small amount of additive includes but not limited to: boric acid, oxalic acid etc.And the oxide compound of described first, second, third and fourth main group metal can be Li
2O, MgO, Al
2O
3, GaO, SiO
2Deng; Described oxyhydroxide can be Mg (OH)
2, Ca (OH)
2, Ca (OH)
2, NaOH, KOH etc.; The oxide compound of described fourth, fifth, six cycle transition metals can be TiO
2, Fe
2O
3, ZrO, WO
3Deng; Described oxyhydroxide can be Mn (OH)
2, Zr (OH)
2Deng.And described phosphoric acid salt can be potassium primary phosphate/sodium, dipotassium hydrogen phosphate/sodium etc.Thus, the concrete preparation method of described product may further comprise the steps:
1). to the oxide compound of described first, second, third and fourth main group metal (can but to be not limited to be Li
2O, MgO, Al
2O
3, GaO, SiO
2Deng) or oxyhydroxide (can but to be not limited to be Mg (OH)
2, Ca (OH)
2, Ca (OH)
2, NaOH, KOH etc.); Or the oxide compound of described fourth, fifth, six cycle transition metals (can but to be not limited to be TiO
2, Fe
2O
3, ZrO, WO
3Deng) or oxyhydroxide (can but to be not limited to be Mn (OH)
2, Zr (OH)
2Deng) carry out pre-treatment and make it to become Powdered. when needing, can it be heat-treated, promptly heat to remove the small molecules dirt settling.
2). to through 1) powder material of gained adds a certain amount of boric acid or oxalic acid, with the speed of regulation and control curing reaction.The boric acid or the oxalic acid that add are being 0%-10% with being added into weight ratio shared in the formed mixture of powder material.First mixture to gained carries out uniform mixing.
3). to through 2) add phosphoric acid or phosphoric acid salt in first mixture of gained. or the mixture of multiple phosphoric acid salt and phosphoric acid. first mixture and phosphoric acid or phosphoric acid salt, or the weight ratio of the mixture of multiple phosphoric acid salt and phosphoric acid is 1: 0.2 to 1: 9.5.
4). to through 3) second mixture of gained carries out uniform mixing.
5). to through 4) adding waste in second mixture of gained through giving processing. waste shared weight ratio in final product is 15% to 95%.
6). to through 5) the 3rd mixture of gained carries out uniform mixing.
7). to through 6) add a certain amount of water and uniform mixing in the 3rd mixture of gained, form slurry.Water shared weight ratio in final product is 5%-40%.If aforesaid step 3) has been used phosphoric acid, then institute's water content is accrued in the acid goes in total water-content.
8). will be through 7) curing molding in the slurry injected plastic mould of gained.
The pre-treatment of the described waste of step 5) is meant large-sized solid waste pulverized and grinds and the liquid towards waste carries out water-content and measures. the water content of liquid waste should count in total water-content.
Eventually the above, technological process of the present invention can be sketched and be: according to the adherend property sort and pulverize where necessary and/or pre-treatment such as ball milling; Selected and prepare corresponding tackiness agent according to the adherend characteristic; With prepared adhesive and adherend thorough mixing; The gained mixture is mixed with an amount of water and stir and make slurry and the gained slurry is injected the mold cured moulding.
Feature of the present invention: the room temperature process need not additional energy; Form fast hard, to close accurate ceramic product; End properties and moulding process are adjustable; In most cases, small expansion is arranged during the products solidifying moulding, thereby can form good sealing prod, fabulous to close property.
Unique excellent performance that present technique/product had can be widely used in it: 1. utilize harmless waste to produce building products (as fragment of brick, tile, ceramic tile, fireproof brickwork division board or the like); High pressure resistance structured material; The super fire lagging that can spray; Drilling water mud and sealing material; Seal coating; 2. bazardous waste is carried out secure package; The nothing of radioactive pollutant is revealed encapsulation process; The safety of harmful mixture and radio active material (liquid or solid-state) is sealed up for safekeeping.
Embodiment one: flyash is bonding
Make adherend with flyash, with MgO and KH
2PO
4Mix as tackiness agent by aforementioned proportioning, follow the proportioning of aforementioned adherend/tackiness agent and prepare hard, closely knit product by preceding method.Product is deposited several months outward appearance and performance no change in air.In water, soak outward appearance and also no change of performance several weeks.
Embodiment two: the steelworks waste residue is bonding
Make adherend with the steelworks waste residue, with MgO and KH
2PO
4Mix as tackiness agent by aforementioned proportioning, follow the proportioning of aforementioned adherend/tackiness agent and prepare hard, closely knit product by preceding method.Product is deposited several months outward appearance and performance no change in air.In water, soak outward appearance and also no change of performance several weeks.
Embodiment three: brickbat and gravel-concrete are bonding
Make adherend with brickbat and gravel-concrete, with MgO and KH
2PO
4Mix as tackiness agent by aforementioned proportioning, follow the proportioning of aforementioned adherend/tackiness agent and prepare hard, closely knit product by preceding method.Product is deposited several months outward appearance and performance no change in air.In water, soak outward appearance and also no change of performance several weeks.
The preparation method of inorganic adhesive comprises following key step:
A) miscellany and a spot of weak acid of pulverous one or more oxide compounds or oxyhydroxide is fully mixed.Described weak acid includes but not limited to boric acid or oxalic acid.Described weak acid shared weight ratio in miscellany is 0%-10%.
B) in first miscellany of a) gained, add one or more phosphoric acid or phosphoric acid salt by a certain percentage.
C) with b) second miscellany of gained is evenly mixed.
D) toward c) add one or more additives by a certain percentage in second miscellany of gained.Additive can be any solid matter beyond plastics or the rubber.Additive includes but not limited to flyash, coal gangue, metallurgical slag, building waste etc.
E) with b) the 3rd miscellany of gained is evenly mixed.
The starting material interpolation order of described each key step is variable.
Described tackiness agent can be used for bonding nearly all known material.Solidification process causes by adding a certain amount of water. and water shared weight ratio in final product is 3%-60%.
Tackiness agent and solidification process by adding the building pigment of different colours, can be prepared the final product of respective color.
Tackiness agent and solidification process by adding different types of fiber, can improve the mechanical property of final product.
Should be pointed out that the above embodiment can make those skilled in the art more fully understand the present invention, but do not limit the present invention in any way.
Claims (23)
1. inorganic adhesive, it is characterized in that: comprise first group of material and second group of material, first group of material comprises one or more oxide compound or oxyhydroxide; Second group of material comprises one or more phosphorated acid or phosphorated salt.
2. inorganic adhesive according to claim 1 is characterized in that: described oxide compound is basic oxide.
3. inorganic adhesive according to claim 1 is characterized in that: described phosphorated acid comprises phosphoric acid, high phosphoric acid or Hypophosporous Acid, 50.
4. inorganic adhesive according to claim 1 is characterized in that: described phosphorated salt comprises phosphoric acid salt, high phosphate or hypophosphite.
5. inorganic adhesive according to claim 1 is characterized in that: the weight ratio of described first group of material and second group of material is 1: (0.2～9.5).
6. inorganic adhesive according to claim 1 is characterized in that: the weight ratio of described first group of material and second group of material is 1: (0.5～3.5).
7. inorganic adhesive according to claim 1 is characterized in that: the weight ratio of described first group of material and second group of material is 1: (0.75～1.5).
8. inorganic adhesive according to claim 1 is characterized in that: described oxide compound is meant the oxide compound that belongs to first, second, third and fourth cycle main group metal in the periodic table of elements, and the oxide compound of fourth, fifth, six cycle transition metals.
9. inorganic adhesive according to claim 1 is characterized in that: described oxyhydroxide is meant in the periodic table of elements it is the oxyhydroxide of first, second, third and fourth cycle main group metal, and the oxyhydroxide of fourth, fifth, six cycle transition metals.
10. as the application of the described inorganic adhesive of one of claim 1-9 in material is bonding.
11. the application of inorganic adhesive according to claim 10 in material is bonding, it is characterized in that: described application comprises curing schedule, and described curing schedule is meant that described tackiness agent and bonded material cause chemical curing reaction by adding a certain amount of water.
12. the application of inorganic adhesive according to claim 11 in material is bonding is characterized in that: described a certain amount of water accounts for 3～60% of gross weight.
13. the application of inorganic adhesive according to claim 11 in material is bonding is characterized in that: described a certain amount of water accounts for 5～40% of gross weight.
14. the application of inorganic adhesive according to claim 11 in material is bonding is characterized in that: described application is included in and adds building pigment in the tackiness agent, perhaps adds building pigment in curing schedule.
15. the application of inorganic adhesive according to claim 11 in material is bonding is characterized in that: described application is included in and adds fiber in the tackiness agent, perhaps adds fiber in curing schedule.
16. the preparation method of inorganic adhesive is characterized in that: comprise following two groups of material's proportion are mixed that first group of material comprises one or more oxide compound or oxyhydroxide; Second group of material comprises one or more phosphorated acid or phosphorated salt.
17. the preparation method of inorganic adhesive according to claim 16 is characterized in that: described first group of material is prepared into powder.
18. the preparation method of inorganic adhesive according to claim 16 is characterized in that: described first group of material is prepared into powder by pulverizing and/or ball milling pretreatment.
19. the preparation method according to claim 17 or 18 described inorganic adhesives is characterized in that: with pulverous first group of material and mixed first mixture that obtains of weak acid, with first mixture and second group of mixed second mixture that obtains of material.
20. the preparation method of inorganic adhesive according to claim 19 is characterized in that: in second mixture, add additive and obtain the 3rd mixture.
21. the preparation method of inorganic adhesive according to claim 19 is characterized in that: described weak acid adopts a kind of or combination in the following material: boric acid, oxalic acid.
22. the preparation method of inorganic adhesive according to claim 19 is characterized in that: described weak acid shared weight ratio in first mixture is＞0, to 10%.
23. the preparation method of inorganic adhesive according to claim 20 is characterized in that: described additive adopts a kind of in the following material or above a kind of combination: flyash, coal gangue, metallurgical slag, building waste.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2008101166668A CN101319126A (en) | 2008-07-15 | 2008-07-15 | Inorganic adhesive agent, preparation and application thereof |
| PCT/CN2008/072041 WO2010006488A1 (en) | 2008-07-15 | 2008-08-19 | An inorganic binder, the preparation and the use thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2008101166668A CN101319126A (en) | 2008-07-15 | 2008-07-15 | Inorganic adhesive agent, preparation and application thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101319126A true CN101319126A (en) | 2008-12-10 |
Family
ID=40179405
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2008101166668A Pending CN101319126A (en) | 2008-07-15 | 2008-07-15 | Inorganic adhesive agent, preparation and application thereof |
Country Status (2)
| Country | Link |
|---|---|
| CN (1) | CN101319126A (en) |
| WO (1) | WO2010006488A1 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010015129A1 (en) * | 2008-08-04 | 2010-02-11 | 北京赛力格科技发展有限公司 | Curing agent, polymeric compound and method therrof |
| CN103011711A (en) * | 2012-12-24 | 2013-04-03 | 胡中波 | Binder for inorganic solid waste and method |
| CN107428615A (en) * | 2014-12-23 | 2017-12-01 | 圣戈班韦伯公司 | Acid/base binding agent comprising the cement based on phosphate compounds |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH09241583A (en) * | 1996-03-07 | 1997-09-16 | Mitsubishi Electric Corp | Inorganic binder composition and production thereof |
| JP2002155244A (en) * | 2000-11-20 | 2002-05-28 | Asahi Fiber Glass Co Ltd | Method for producing curing inorganic composition |
| CN1186292C (en) * | 2002-04-15 | 2005-01-26 | 吴伟文 | Catalytic cougulator for converting solid waste into building material, and use thereof |
| CN100420649C (en) * | 2005-09-30 | 2008-09-24 | 北京赛力格科技发展有限公司 | Inorganic phosphor-contained polymer and its production |
| CN101062847A (en) * | 2006-04-28 | 2007-10-31 | 李智 | Additive felting material for structure product reproduction by steady waste material assimilation |
| CN100453190C (en) * | 2007-05-30 | 2009-01-21 | 北京赛力格科技发展有限公司 | Waste polymerizing treatment method |
| CN101328031A (en) * | 2008-08-04 | 2008-12-24 | 北京赛力格科技发展有限公司 | Curing agent, polymer and method |
-
2008
- 2008-07-15 CN CNA2008101166668A patent/CN101319126A/en active Pending
- 2008-08-19 WO PCT/CN2008/072041 patent/WO2010006488A1/en active Application Filing
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010015129A1 (en) * | 2008-08-04 | 2010-02-11 | 北京赛力格科技发展有限公司 | Curing agent, polymeric compound and method therrof |
| CN103011711A (en) * | 2012-12-24 | 2013-04-03 | 胡中波 | Binder for inorganic solid waste and method |
| CN107428615A (en) * | 2014-12-23 | 2017-12-01 | 圣戈班韦伯公司 | Acid/base binding agent comprising the cement based on phosphate compounds |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2010006488A1 (en) | 2010-01-21 |
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