Fire retardant cotton nonwoven fabrics and manufacture method thereof
Technical field
The present invention relates to a kind of retardant cotton, especially a kind of fire retardant cotton nonwoven fabrics.The present invention also provides the manufacture method of this fire retardant cotton nonwoven fabrics.
Background technology
The fire that the fibre burning causes has become one of great disaster of modern society, the result that the death by accident that is caused by fire is investigated shows, the fire that is caused by upholstery and textiles holds pride of place, discover that simultaneously the pernicious gas that discharges during flammable textile combustion substantially exceeds the anti-flammability textiles to the extent of injury of human body.Adopt fire resistance fibre and goods thereof with the substantive requirements of form of law and mandatory provisions in succession both at home and abroad at present, as explicitly calling in " fire service law " passed through recently at public places such as theater employing fire-retardant product, the mandatory employing fire-retardant product of decorative textile product that Ministry of Communications's requirement is used on railway and passenger vehicle, national security production general bureau and Safety of Coal Mine Production Surveillance Authority begin mandatory requirement downhole operations personnel and wear flame retardant textiles.Therefore, for preventing fire, produce fire resistance fibre and more and more be subject to people's attention.
Fire resistance fibre of the prior art generally has several classes, and wherein a class is a natural fabric, and natural fabric can only rely on post-processing approach to reach fire-retardant requirement, and also having a class is synthetic fiber, and it can make fire resistance fibre by add ways such as fire retardant in spinning solution.It is specialty fibers that one class is arranged again, for example carbon fiber etc.
The weak point of existing fire resistance fibre mainly is, flame retardant effect is bad, and the product fusing point is low, easily catches fire, and part is poisonous, and range of application is narrow, cost height, the very big cost expense of civilian military existence.Have, existing fire resistance fibre should not be made clothes because fusing point is not high again.In specialty fibers; Glass fibre can only be used as the flame retardant rubber coated base fabric, and carbon fiber and tower teflon price are too high.Therefore, the exploitation present situation of fire resistance fibre also is difficult to reach instructions for use.
Just realized at present the fire-retardant polyester fibre that industrialization is produced, its application is wider, though such flame-retardant textile can stop spreading of flame effectively, but, the phenomenon of fusion drippage at high temperature takes place in easily, and the fusion dropping makes the people scald easily, even the combustible material of the low ignition point that ignites, cause more conflagration, the user of service is caused potential injury.These defectives make its application be subjected to certain restriction, particularly use at aspects such as clothes to be not suitable for.Therefore development of new fire resistance fibre and textiles make it not only have the fire resistance while but also prevent that fusion from having become a urgent subject.
Summary of the invention
The objective of the invention is to improve the deficiencies in the prior art, a kind of nonwoven retardant cotton with flame-retardant and anti-dripping performance is provided.
Another object of the present invention is to provide the manufacture method of above-mentioned nonwoven retardant cotton.
The object of the present invention is achieved like this:
Fire retardant cotton nonwoven fabrics provided by the invention comprises that peace spins fire resistance fibre (Anti-fcell) and wash/polyester/polyester composite hot-melt short fiber, and wherein, pacifying the percentage by weight that spins fire resistance fibre is 70%~90%, and all the other are for washing/polyester/polyester composite hot-melt short fiber; Above-mentioned two kinds of fiber composite and/or IPN are combined into nonwoven fabric.
The preparation method of fire retardant cotton nonwoven fabrics provided by the invention is:
A. peace is spun fire resistance fibre (Anti-fcell) and washed/two kinds of raw materials of polyester/polyester composite hot-melt short fiber mixed according to the rules;
B. mixed raw material is carried out shredding by opener;
C. the mixture after the shredding is carried out the fiber combing;
D. carry out lapping with the fiber after the combing;
E. the lapping fiber is carried out processing and forming, make nonwoven fabric with a thickness;
F. the nonwoven fabric of making is cut edge, be rolled into and be finished product.
In the E step, the method for described processing and forming can be:
A. needle point method:
By end curtain is that convoying curtain is sent constantly into the fibre web of lapping in the needing machine, carries out acupuncture for the fiber of lapping, fiber is intertwined under the effect of pricker and form the nonwoven fabric of a thickness, then, again by scalding the moulding of roller hot pressure.
In acupuncture course, when fibre web feeding acupuncture, when many pieces of thorns are needled into fibre web, thorn hook on the pricker will drive the fiber of fibre web surface and subsurface, by the in-plane of fibre web movement in vertical direction to fibre web, make fiber produce displacement up and down, and the fiber that produces displacement up and down just produces certain extruding to fibre web, make in the fibre web fiber draw close and be compressed.After pricker reaches certain degree of depth, the pricker bottom out, because thorn hook cause forward, the fiber that produces displacement breaks away from the thorn hook and stays in the fibre web with plumbness almost, hammered into fibre web just as many fibre bundles " pin ", thereby the compression that fibre web is produced can not recover, if on every square centimeter fibre web through tens of or up to a hundred time repeated localised puncture, just a considerable amount of fibre bundles have been thrust fibre web, frictional force in the fibre web between fiber and the fiber strengthens, fibre web intensity raises, increase in density, and fibre web has formed has certain brute force, density, the needle punched non-woven fabrics of performances such as elasticity.
Acupuncture is divided into facing down into the following acupuncture of pin and go into two kinds of the last acupunctures of pin from bottom to top from fibre web.Needle point method provided by the invention successively descends acupuncture and two acupuncture courses of last acupuncture for fibre web, like this, and can be so that the nonwoven fabric intensity of making, density and flexible combination property be superior.
In order to make acupuncture course carry out smoothly, before normal acupuncture, carry out a pre-needling process earlier, promptly the bestock of pre-pricking machine is less, and pin is bigger deeply, and its main purpose is that the fibre web that cohesive force is little between high loft and fibre web is carried out acupuncture.
The acupuncture of using this form is to have higher and bulking intensity because of the fibre web of sending into needing machine through the lapping machine, just produces certain brute force by the cohesive force between fiber and the fiber, but powerful very poor, needs sting in advance through pre-pricking machine earlier.
After the pre-needling, carry out main acupuncture, main acupuncture can be: by following needing machine fibre web is descended acupuncture earlier, then, acupuncture on fibre web being carried out by main needing machine.
Adopt this elder generation pre-, the needle-punching method of the main thorn in back can make the nonwoven fabric cloth cover more even, smooth, and is powerful, density is bigger, thereby makes fire retardant nonwoven fabric obtain better flame retardant effect.
The degree of depth of acupuncture can not surpass the fibre web thickness of lapping, otherwise fibre fluff can appear in two surfaces of nonwoven fabric, makes the cloth cover out-of-flatness, even the phenomenon of broken needle can occur.The degree of depth of acupuncture can not be too shallow, otherwise pricker can not penetrate web layer, thereby cause the brute force of nonwoven fabric to descend, even the phenomenon of nonwoven fabric layering occurs; Needle-punching method provided by the invention, the degree of depth of its pre-needling is suitable with regard to thickness with the shop of fibre web, dark (depth of needling) 7~10mm of pre-needling eedle, dark (depth of needling) 5~7mm of following acupuncture eedle, dark (depth of needling) 3~4mm of main acupuncture eedle.But the degree of depth sum of the degree of depth of following acupuncture and last acupuncture greater than the shop of fibre web with regard to thickness.Like this, the degree of depth of acupuncture all less than the thickness of fibre web, the problem that fibre fluff appears in nonwoven surface can not occur up and down, but makes fibre web the problem of layering, superior performances such as brute force not occur.
In the hot pressure forming process, the temperature of scalding roller is generally 180 ℃~200 ℃, and preferred 185 ℃~195 ℃, optimum temperature is 190 ℃.Hot pressure pressure is 0.2MPa~0.4MPa, preferred 0.3MPa, and optimum pressure is 0.3MPa.The hot pressure time is 6S~10S, preferred 7S~9S, and Best Times is 8S.
Scald the temperature of roller and will not have the effect of dough made with boiling water when low, and it is too high to scald the temperature of roller, can make again that the physical property of fiber changes in the nonwoven fabric, make becoming of nonwoven fabric stiff, influence the aesthetic of nonwoven fabric.
The pressure that scalds roller hour will not have the effect of extruding, and it is excessive to scald the pressure of roller, then makes the thickness attenuation of nonwoven fabric, and hardness increases, and influences the feel of nonwoven fabric.
The hot pressure time will not have the effect of dough made with boiling water more in short-term, and the hot pressure overlong time also can make the fiber physical property of nonwoven fabric change, even can be along with the further increase of hot pressure time, the color of nonwoven fabric also can change, and finally influences the flame retardant effect of nonwoven fabric.
After needle point method processing and forming operation, can also be provided with a hot blast and cross furnaceman's preface, it promptly is to utilize hot blast as medium and carrier that hot blast is crossed stove, and nonwoven fabric is carried out drying or baking, transpiring moisture carries out HEAT SETTING, thereby obtains dry and comfortable product.
In the method provided by the invention, after acupuncture, make nonwoven acupuncture cotton, and then hot blast crosses stove, carry out a dark step processed.Make the existing uniform and stable characteristics of product, do not lose elasticity again, its fracture strength and tensile strength all have outstanding performance.For example, when not crossing stove through hot blast, fracture strength<10N, tensile strength<10N; After the process hot blast was crossed stove, the fracture strength of nonwoven fabric was>50N tensile strength>50N.We can say, because selling point has been given in the improvement on processing technology.
B. hot blast method:
At first, the fiber of lapping is sent into baking oven,, then,, exert pressure, again by air-cooler blowing cooling forming with the cooling of cold water roller with the fiber taking-up baking oven of moulding through baking molding.
In hot blast method moulding process, baking temperature is 160 ℃~200 ℃; 170 ℃~190 ℃ of preferred temperature, optimum temperature is 180 ℃, stoving time can be 8min~15Min, preferred 9min~14min, Best Times is 12min.
During the cooling of cold water roller was exerted pressure, the temperature of cold water roller was 10 ℃~20 ℃, and preferred 13 ℃~18 ℃, optimum temperature is 18 ℃.Optimum pressure is 0.1MPa.
Air-cooler blowing cooling is to carry out after the cooling of cold water roller is exerted pressure, 10 ℃~18 ℃ of cold wind temperature, and preferred 12 ℃~16 ℃, best cold wind temperature is 14 ℃.
Described washing/polyester/polyester composite hot-melt short fiber is a low-melting fiber.
It is main prescription that fire retardant cotton nonwoven fabrics provided by the invention adopts peace to spin fire resistance fibre.Peace is spun fire resistance fibre (Anti-fcell
) be functional fibre with anti-flame fusion-resisting effect, this inflammable, fusion drippage and inflammable problem of viscose with regard to having solved terylene.Add therein and wash/polyester/polyester composite hot-melt short fiber, can increase its bonding coefficient, make fiber evenly to be bonded together better.Utilize the processing process of original creation again, carry out Compound Machining, as by acupuncture or hot blast forming method, make fire retardant cotton nonwoven fabrics obtain advantages of higher tensile strength, fracture strength, and don't lose elasticity and certain bulkiness.
Fire retardant cotton nonwoven fabrics provided by the invention is because fiber and textiles is fire-retardant and anti-fusion effective, improve the application performance and the security performance of chemical fibre greatly, improve the added value of fiber and textiles, can be widely used in fields (as army's training, fighting uniform and fire-entry suit etc.) such as civilian, industry and military affairs, main feature is as follows:
1. this product safety is nontoxic, has high flame retardant; Anti-flame fusion-resisting cellulose viscose and fabric limited oxygen index LOI>30%, carbonization degree is more than 80%; Fabric from putting out less than 7S, prolongs the combustion time less than 5S from fire, and char length is less than 10 centimetres;
2. inorganic constituents content can be up to 20~40% in the fiber, and flame-retardant composition is uniformly dispersed, the stoste good spinnability.
3. the physical and mechanical properties of fiber and common viscose fiber are similar, the moisture absorption good easy dyeing of breathing freely, and fabric has good hand feeling, snugness of fit and drapability.
4. fiber when burning, only produce a small amount of flue gas, not fusion, do not discharge poison gas, have from going out effect, and can keep original form after the carbonization;
5. wash resistant and chemical treatment has nonvolatil fire retardation;
But 6. product natural biology degraded, compliance with environmental protection requirements.
Therefore, fire retardant cotton nonwoven fabrics provided by the invention can be applicable to following aspect:
1. clothes are with nonwoven fabric (as: clothes, gloves lining cloth, shopping bag, garment bag etc.);
2. family expenses are decorated, household nonwoven fabric (as: carpet and base cloth, wall covering material, furniture decoration, bedding and curtain, valance etc.);
3. industrial nonwoven fabric (as: protective clothing, laboratory clothes, aircraft seat artificial leather lining cloth, the indoor carpet of automobile, roof, door decorations, retaining wall material etc.);
4. filtering material nonwoven fabric;
5. packaging nonwoven fabric.
Description of drawings
The invention will be further described below in conjunction with accompanying drawing.
Fig. 1 is a kind of technological process of production figure of fire retardant cotton nonwoven fabrics provided by the invention;
Fig. 2 is the another kind of technological process of production figure of fire retardant cotton nonwoven fabrics provided by the invention.
The specific embodiment
Further specify concrete feature of the present invention and technological means below in conjunction with accompanying drawing, and further specify good effect of the present invention by the specific embodiment.
Retardant cotton fire retardant cotton nonwoven fabrics provided by the invention comprises that peace spins fire resistance fibre (Anti-fcell) and wash/polyester/polyester composite hot-melt short fiber, and wherein, pacifying the percentage by weight that spins fire resistance fibre is 70%~90%, and all the other are for washing/polyester/polyester composite hot-melt short fiber; Above-mentioned two kinds of fiber composite and/or IPN are combined into nonwoven fabric.
Concrete, the percentage by weight that can provide peace to spin fire resistance fibre is 75% ± 5%, wash/polyester/polyester composite hot-melt short fiber is 25% ± 5% proportioning.
The concrete preparation method of this fire retardant cotton nonwoven fabrics is:
A. peace is spun fire resistance fibre (Anti-fcell) and washed/two kinds of raw materials of polyester/polyester composite hot-melt short fiber mixed according to the rules;
B. mixed raw material is carried out shredding by opener;
Be introduced into pre-opener and carry out shredding, send into the whirlwind hopper through airduct then, enter main opener by the whirlwind hopper again and carry out the secondary shredding.The effect of opener: mainly be the fiber of loosening,, make the fiber of being entangled with of bulk send and form fritter or pencil by tearing, simultaneously in the process of loosening with mix, the removal of impurities effect.
C. the mixture after the shredding is carried out the fiber combing;
To send into the collection hopper through the raw material after the shredding, and be sent to carding machine through feeding curtain and carry out combing.
D. carry out lapping with the fiber after the combing;
Fiber after the combing soon is fed into lapping machine, lapping.
E. the lapping fiber is carried out processing and forming, make nonwoven fabric with a thickness;
F. the nonwoven fabric of making is cut edge to be rolled into and be finished product.
In the E step, the method for described processing and forming can be a needle point method, that is:
Fiber for lapping carries out acupuncture, and fiber is intertwined under the effect of pricker and form the nonwoven fabric of a thickness, then, again by scalding the moulding of roller hot pressure, shown in figure l.
In acupuncture course, through convoying curtain is that end curtain and pre-needling machine and following thorn machine, main needing machine carry out acupuncture, fiber is intertwined under the effect of pricker and form certain thickness, make the nonwoven fabric of required certain brute force and intensity, carry out the hot pressure moulding, the rolling of cutting edge at last through scalding roller then.
Dark (depth of needling) 7~10mm of pre-needling eedle, dark (depth of needling) 5~7mm of following acupuncture eedle, dark (depth of needling) 3~4mm of main acupuncture eedle.Pin frequency: sting 15~25HZ in advance, following thorn 25~35HZ, main thorn 30~45HZ.
Pin is frequently less, and the brute force of nonwoven fabric will descend, and pin is frequently excessive, the brute force of nonwoven fabric can increase, but is not that pin is the bigger the better frequently, when pin is crossed given value range frequently, owing to do not match with the feed speed of fibre web, the needing machine broken needle will occur, in addition, with the situation of feed speed coupling under, if pin is frequently too fast, the thickness of nonwoven fabric is reduced, make the cloth cover of nonwoven fabric significantly pin hole occur, influence the attractive in appearance of nonwoven fabric, cause the flame retardant effect instability of nonwoven.Compare with normal conditions, the pin in this technology is frequently bigger.
In described hot pressure forming process, the temperature of two boiling hot rollers is 185 ℃~195 ℃ up and down.Hot pressure pressure is 0.3MPa, and the hot pressure time is 7S~9S.
After described needle point method processing and forming operation, can also be provided with a hot blast and cross furnaceman's preface, send in the hot-blast stove through the nonwoven fabric after the acupuncture moulding, carry out drying and HEAT SETTING.
Above-mentioned peace spins fire resistance fibre (Anti-fcell) and wash/and the ratio of polyester/polyester composite hot-melt short fiber can also be, and peace is spun fire resistance fibre 90 ± 5%, and all the other are for washing/polyester/polyester composite hot-melt short fiber.
Through acupuncture course, dark at the pre-needling eedle, depth of needling is 7-8mm, and following acupuncture eedle is dark, depth of needling 5~6mm, and main acupuncture eedle is dark, and depth of needling is 3~4mm.Pin frequency: sting 20HZ in advance, following thorn 30HZ, main thorn 38HZ.
In described hot pressure forming process, the temperature of scalding roller is 190 ℃.Hot pressure pressure is 0.3MPa, and the hot pressure time is 8S.
List the match condition of each technological parameter among several embodiment in the following table:
Needling process parameter: see Table 1
Table 1:
Example 1 |
Example 2 |
Example 3 |
Example 4 |
Peace is spun fire resistance fibre ratio 90% |
Peace is spun fire resistance fibre ratio 78% |
Peace is spun fire resistance fibre ratio 86% |
Peace is spun fire resistance fibre ratio 75% |
Pre-needling degree of depth 9mm, pin is 20HZ frequently |
Pre-needling degree of depth 8mm, pin is 25HZ frequently |
Pre-needling degree of depth 10mm, pin is 23HZ frequently |
Pre-needling degree of depth 7mm, pin is 16HZ frequently |
Following depth of needling 5mm, pin is 30HZ frequently |
Following depth of needling 4mm, pin is 35HZ frequently |
Following depth of needling 6mm, pin is 32HZ frequently |
Following depth of needling 4mm, pin is 27HZ frequently |
Main depth of needling 3.5mm, pin is 38HZ frequently |
Main depth of needling 4mm.Pin is 45HZ frequently |
Main depth of needling 4mm.Pin is 40HZ frequently |
Main depth of needling 3mm.Pin is 32HZ frequently |
185 ℃ of the temperature of boiling hot roller |
190 ℃ of the temperature of boiling hot roller |
195 ℃ of the temperature of boiling hot roller |
195 ℃ of the temperature of boiling hot roller |
Hot pressure pressure 0.30.3MPa |
Hot pressure pressure 0.3MPa |
Hot pressure pressure 0.3MPa |
Hot pressure pressure 0.3MPa |
Hot pressure time 7S |
Hot pressure time 8S |
Hot pressure time 9S |
Hot pressure time 7S |
In the E step, the method of described processing and forming can also be the hot blast method, make fire-retardant hot blast cotton: promptly: as shown in Figure 2, retardant cotton is after mixing by the good fiber of certain ratio proportioning, enter pre-opener by feeding procedure and equipment and carry out shredding, shredding is after airduct enters cotton feeder (cotton feeder with the collection hopper together), enter main opener through airduct then and carry out the secondary shredding, pass through No. 1 after the shredding, No. 2 cotton feeder enters No. 1, No. 2 carding machine carries out the fiber combing, the fiber that combing is good carries out No. 1 then, No. 2 the lapping machine carries out lapping, enter baking oven after completing stratum reticulare, the fiber of completing net is through molded behind the baking oven, and cool off with cold water roller and air-cooler and exert pressure this moment, make it moulding, be processed into certain thickness nonwoven fabric,, make finished product in the side cut rolling.
At first, the fiber of lapping is sent into baking oven,, then,, exert pressure, again by air-cooler blowing cooling forming with the cooling of cold water roller with the fiber taking-up baking oven of moulding through baking molding.
In hot blast method moulding process, baking temperature is 160 ℃~200 ℃; Stoving time can be 8min~15min.
During the cooling of cold water roller was exerted pressure, the temperature of cold water roller was 10 ℃~20 ℃, and optimum pressure is 0.1MPa.
Air-cooler blowing cooling is to carry out 10 ℃~18 ℃ of cold wind temperature after the cooling of cold water roller is exerted pressure.
Described washing/polyester/polyester composite hot-melt short fiber can be the low-melting fiber of Korea S Saehan company sale.It is to be that Shandong sea otter company sells that peace is spun fire resistance fibre.
Now give an example, the raw material of use is: the percentage by weight that peace is spun fire resistance fibre is 80% ± 5%, wash/polyester/polyester composite hot-melt short fiber is 20% ± 5% proportioning.Processing technology is:
A. peace is spun fire resistance fibre (Anti-fcell) and washed/two kinds of raw materials of polyester/polyester composite hot-melt short fiber mixed according to the rules;
B. mixed raw material is carried out shredding by opener;
Be introduced into pre-opener and carry out shredding, enter main opener through airduct then and carry out the secondary shredding.The effect of opener: mainly be the fiber of loosening,, make the fiber of being entangled with of bulk send and form fritter or pencil by tearing, simultaneously in the process of loosening with mix, the removal of impurities effect.
C. the mixture after the shredding is carried out the fiber combing;
To send into the collection hopper through the raw material after the shredding, and be sent to carding machine through feeding curtain and carry out combing.
D. carry out lapping with the fiber after the combing;
Fiber after the combing soon is fed into lapping machine, lapping.
Soon it sends baking oven to after completing stratum reticulare, and the fiber of completing net is through baking oven, and baking temperature is 180 ℃ of temperature, and stoving time is 12min, promptly plastic, then, with the product taking-up baking oven of moulding, with cold water roll-in system, during the cooling of cold water roller was exerted pressure, the temperature of cold water roller was 18 ℃.Afterwards, product is being carried out air-cooled, the temperature of blowing the cold wind on product is 14 ℃, makes it moulding, is processed into certain thickness nonwoven fabric, and last, the side cut rolling is made finished product.
List the match condition of each technological parameter among the embodiment of several hot blast methods in the following table 2:
Table 2: hot blast method technological parameter
Example 5 |
Example 6 |
Example 7 |
Example 8 |
Peace is spun fire resistance fibre ratio 90% |
Peace is spun fire resistance fibre ratio 70% |
Peace is spun fire resistance fibre ratio 80% |
Peace is spun fire resistance fibre ratio 85% |
190 ℃ of baking temperatures |
160 ℃ of baking temperatures |
180 ℃ of baking temperatures |
170 ℃ of baking temperatures |
Stoving time 15min |
Stoving time 8min |
Stoving time 10min |
Stoving time 14min |
10 ℃ of the temperature of cold water roller |
20 ℃ of the temperature of cold water roller |
15 ℃ of the temperature of cold water roller |
18 ℃ of the temperature of cold water roller |
Cold water roller rolling pressure 0.1MPa |
Cold water roller rolling pressure 0.1MPa |
Cold water roller rolling pressure 0.1MPa |
Cold water roller rolling pressure 0.1MPa |
10 ℃ of air-cooler blowing temperature |
18 ℃ of air-cooler blowing temperature |
12 ℃ of air-cooler blowing temperature |
15 ℃ of air-cooler blowing temperature |
In the various embodiments described above, wherein used washing/polyester/polyester composite hot-melt short fiber can be commercially available washing now/polyester/polyester composite hot-melt short fiber, and 4080 fibers more specifically, can be that 4D*65mm washs/polyester/polyester composite hot-melt short fiber.