CN101306311A - 烧结烟气干法脱除方法及装置 - Google Patents
烧结烟气干法脱除方法及装置 Download PDFInfo
- Publication number
- CN101306311A CN101306311A CNA2008100705295A CN200810070529A CN101306311A CN 101306311 A CN101306311 A CN 101306311A CN A2008100705295 A CNA2008100705295 A CN A2008100705295A CN 200810070529 A CN200810070529 A CN 200810070529A CN 101306311 A CN101306311 A CN 101306311A
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- CN
- China
- Prior art keywords
- gas
- flue gas
- flue
- reaction zone
- ciculation fluidized
- Prior art date
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- 239000003546 flue gases Substances 0.000 title claims abstract description 62
- UGFAIRIUMAVXCW-UHFFFAOYSA-N carbon monoxide Chemical compound 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- 239000011593 sulfur Substances 0.000 description 1
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Abstract
本发明公开了这样一种烧结烟气干法脱除方法及装置。在高温烟气进入快速混合区(4)的入口烟道(1)加入吸收剂，脱除一部分有害气体；从快速混合区(4)出来的烟气经加速区(5)提速后进入循环流化反应区(7)，在循环流化反应区(7)前端喷水降温，并在循环流化反应区(7)继续进行脱除剩余的有害气体；被净化的烟气经反应塔出口烟道(8)进入气固分离器(9)，再经循环流化钭槽(12)进入快速混合区(4)，净化后的烟气经引风机(10)排入烟囱(11)；在引风机(10)的排风烟道上设置有清洁烟气再循环烟道(14)，清洁烟气再循环烟道(14)的另一端与反应塔入口烟道(1)连接。
Description
烧结烟气干法脱除方法及装置
所属技术领域
本发明涉及一种烧结烟气干法脱除方法，本发明还涉及用于该方法的 装置。
背景技术
中国专利（公告号CN2813075y)公开了这样一种烧结机机头烟气脱硫 装置，其结构特点：烟道，连接与烧结引风机的出口，用于引入被脱硫烟 气；脱硫剂给料装置，设置于烟道上；循环流化床反应器，其包括连接于 上述烟道的底部烟气入口段、上部直管段、以及位于底部烟气入口段和上 部直管段之间的文丘里管段；连接烟道，其入口连接、于循环流化床直管 段；机械式分离器，其连接于上述连接烟道的出口；袋式除尘器，其连接 于机械式分离器；流态化灰循环装置，其呈密闭结构，设置于袋式除尘器 底部，并连接于上述循环流化床反应器的文丘里管段；以及脱硫引风机， 其设置于袋式除尘器后。通过这种结构，可知其脱硫方法：当烟气通过时， 在烟道上设置的脱硫剂给料装置开始投料，烟气经入口段、上部直管端、 文丘里管进入循环流化床反应器脱硫，然后，再经布袋除尘器净化后排往 大气。但该技术只适合于满足脱硫要求，由于烧结烟气还存在有重金属、 二恶英、HCL和HF等多种有害气体，因此该技术和装置不易将这些有害气 脱除。另外，这种技术不能适应烟气量大范围变化的工况要求。
发明内容
本发明的目的在于提供一种能对烧结烟气中多种酸性气体、重金属、 二恶因等多组份进行脱除，并适合烧结机短时间内开停频繁的烧结烟气干 法脱除方法及装置。
为达到上述目的，本发明烧结烟气干法脱除方法，包括以下步骤：
1) 在高温烟气进入快速混合区时加入吸收剂，吸收剂在快速混合区与烟气预混合、预处理，脱除一部分S02、 S03、重金属、
二恶因、大部分的HCL、 HF气体；
2) 从快速混合区出来的烟气经加速区提速后进入循环流化反应 区，在循环流化反应区前端喷水降温，并在循环流化反应区继续 进行脱除剩余的S02、 S03、重金属、二恶因成分；
3) 被净化的烟气经反应塔出口烟道进入气固分离器，脱硫灰被 气固分离器捕集下来，经循环流化斜槽进入快速混合区，净化后 的烟气经引风机排入烟囱。
烟气在循环流化反应区的速度为4〜10m/s。 烟气在快速混合区的速度为12〜20m/s。 烟气在加速区的速度为33〜60m/s。
为保证反应塔内各反应区流速不变，可使净化后的烟气经无动力清洁 烟气再循环烟道返回反应塔入口烟道。
一种用于烧结烟气干法脱除的装置，由循环流化反应区、气固分离器、 循环流化斜槽、引风机和烟囱组成，循环流化反应区通过反应塔出口烟道 与气固分离器连接，气固分离器通过烟道和引风机与烟囱连接，在气固分 离器下方设置有循环流化斜槽，在循环流化反应区前端，设置有加速区， 在加速区前端设置有快速混合区，快速混合区与反应塔入口烟道连接；在 引风机的排风烟道上设置有清洁烟气再循环烟道，清洁烟气再循环烟道的 另 一端与反应塔入口烟道连接。
在循环流化反应区前端设置有独立的用于降温的水喷嘴。
由于采用双级反应，能充分脱除多种酸性气体、重金属、二恶英等组 分；又由于设置了清洁烟气再循环烟道，可以保证反应塔内各反应区，在 工矿烟气量变化时的流速保持相对稳定，从而保证整个系统稳定运行。
附图说明
下面结合附图和实施例对本发明作进一步的详细说明。图1为本发明的工艺流程示意图。
图2为为实现本发明的装置示意图。
图中：1、反应塔入口烟道，2、吸附剂仓，3、吸收剂仓，4、快速混 合区，5、加速区，6、水喷嘴，7、循环流化反应区，8、反应塔出口烟道， 9、气固分离器，10、引风机，11、烟囱，12、循环流化斜槽，13、气力输 送管，14、清洁烟气再循环烟道。
具体实施方式
图1所示烧结烟气干法脱除方法，包括以下步骤：
1 ) 在高温烟气进入快速混合区4时加入吸收剂，吸收剂在快速混合
区4与烟气预混合、预处理，脱除一部分S02、 S03、重金属、 二恶因、大部分的HCL、 HF气体；
2) 从快速混合区4出来的烟气经加速区5提速后进入循环流化反应 区7，在循环流化反应区7前端喷水降温，并在循环流化反应区 7继续进行脱除剩余的S02、 S03、重金属、二恶因成分；
3) 被净化的烟气经反应塔出口烟道8进入气固分离器9，脱硫灰被 气固分离器9捕集下来，经循环流化斜槽12进入快速混合区4， 净化后的烟气经引风机10排入烟囱11 。
烟气在循环流化反应区7的速度为4〜10m/s。 烟气在快速混合区4的速度为12〜20m/s。 烟气在加速区5的速度为33〜60m/s。
为保证反应塔内各反应区流速不变，可使净化后的烟气经无动力清洁 烟气再循环烟道14返回反应塔入口烟道1。
图2所示一种用于烧结烟气干法脱除的装置，由循环流化反应区7、气 固分离器9、循环流化斜槽12、引风机10和烟囱11组成，循环流化反应 区7通过反应塔出口烟道8与气固分离器9连接，气固分离器9通过烟道 和引风机10与烟囱11连接，在气固分离器9下方设置有循环流化斜槽12，在循环流化反应区7前端，设置有加速区5，在加速区5前端设置有快速混 合区4，快速混合区4与反应塔入口烟道1连接；在引风机10的排风烟道 上设置有清洁烟气再循环烟道14，清洁烟气再循环烟道14的另一端与反应 塔入口烟道1连接；在循环流化反应区7前端设置有独立的用于降温的水 喷嘴6。
当该装置处于工作状态时，烧结烟气经过反应塔入口烟道l、快速混合 区4、加速区5、循环流化反应区7进入气固分离器9，净化后的烟气经引 风机10排往烟囱11。吸附剂仓2里的吸附剂、吸收剂仓3里的吸收剂和循 环灰在加速区5下部加入，经过双级反应后，被气固分离器9除下来后， 又与循环灰回到快速混合区4。净化后的烟气可以经清洁烟气再循环烟道 14返回入口烟道1进行补风。
Claims (7)
1、一种烧结烟气干法脱除方法，其特征在于包括以下步骤： 1)在高温烟气进入快速混合区(4)时加入吸收剂，吸收剂在快速混合区(4)与烟气预混合、预处理，脱除一部分SO2、SO3、重金属、二恶因、大部分的HCL、HF气体； 2)从快速混合区(4)出来的烟气经加速区(5)提速后进入循环流化反应区(7)，在循环流化反应区(7)前端喷水降温，并在循环流化反应区(7)继续进行脱除剩余的SO2、SO3、重金属、二恶因成分； 3)被净化的烟气经反应塔出口烟道(8)进入气固分离器(9)，脱硫灰被气固分离器(9)捕集下来，经循环流化斜槽(12)进入快速混合区(4)，净化后的烟气经引风机(10)排入烟囱(11)。
2、 根据权利要求1所述的烧结烟气干法脱除方法，其特征在于:烟 气在循环流化反应区（7)的速度为4〜10m/s。
3、 根据权利要求1所述的烧结烟气干法脱除方法，其特征在于:烟 气在快速混合区（4)的速度为12〜20m/s。
4、 根据权利要求1所述的烧结烟气干法脱除方法，其特征在于:烟 气在加速区（5)的速度为33〜60m/s。
5、 根据权利要求1所述的烧结烟气干法脱除方法，其特征在于：为 保证反应塔内各反应区流速不变，可使净化后的烟气经无动力清 洁烟气再循环烟道（14)返回反应塔入口烟道（1)。
6、 一种用于烧结烟气干法脱除的装置，由循环流化反应区（7)、气 固分离器（9)、循环流化斜槽（12)、引风机（10)和烟囱（11) 组成，循环流化反应区（7)通过反应塔出口烟道（8)与气固分离器（9)连接，气固分离器（9)通过烟道和引风机（10)与烟 囱（11)连接，在气固分离器（9)下方设置有循环流化斜槽（12 )， 其特征在于:在循环流化反应区（7)前端，设置有加速区（5)， 在加速区（5)前端设置有快速混合区（4)，快速混合区（4)与 反应塔入口烟道（1)连接；在引风机（10)的排风烟道上设置 有清洁烟气再循环烟道（14)，清洁烟气再循环烟道（14)的另 一端与反应塔入口烟道（1)连接。 7、 根据权利要求6所述的用于烧结烟气干法脱除的装置，其特征在 于:在循环流化反应区（7)前端设置有独立的用于降温的水喷嘴 (6)。
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