CN101298193B - Making method of spicy bottom - Google Patents
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- CN101298193B CN101298193B CN2008101260547A CN200810126054A CN101298193B CN 101298193 B CN101298193 B CN 101298193B CN 2008101260547 A CN2008101260547 A CN 2008101260547A CN 200810126054 A CN200810126054 A CN 200810126054A CN 101298193 B CN101298193 B CN 101298193B
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Abstract
The invention provides a fabrication method of an undersole with fragrance, which relates to the fabrication of the undersole and comprises the steps as follows: (1) preparing the raw material of the undersole with spice added; (2) injecting the raw material of the undersole with the spice added into a die to fabricate the undersole; the spice is 867 Bubble gums or Bubble gum squeed number 1 liquid. The fabrication method of the undersole with the fragrance directly adds the spice in the preparation process of the raw material of the undersole, obtains the undersole with the fragrance withoutincreasing additional production procedures, leads the fragrance to be slowly and continuously emitted, reduces the usage dosage of the spice, reduces production cost, and ensures that the added spice is not easy to be recognised and counterfeited at the same time.
Description
Technical field
The present invention relates to the making at the big end, the preparation method at a kind of specifically big end with fragrance.
Background technology
One deck fragrant paint is normally smeared at the big basal surface of making in the big end of existing band fragrance, has not only increased independent production process one, and the fragrance retention time is short, volatilization easily.
Summary of the invention
The objective of the invention is to overcome above-mentioned weak point, the preparation method at a kind of big end with fragrance is provided, in the preparation process of raw material of the big end, directly add spices, under the situation that does not increase extra production process, obtain the big end, make fragrance slowly to continue to distribute with fragrance; And reduced the use amount of spices, and reduced production cost, guaranteed that simultaneously the spices that adds is difficult for being identified and copying.
For reaching above purpose, the technical scheme that the present invention takes is:
The preparation method at a kind of big end with fragrance is characterized in that: raw material of the big end is a rubber,
Concrete steps are:
The raw material of the big end of spices is added in preparation:
1. by weight in close stone roller machine, adding natural mark glue 8～10%, butadiene rubber 28～32%, butylbenzene 16～20%, white carbon black 22～26%, diethylene glycol (DEG) solid DEG1.3～1.7%, diethylene glycol (DEG) liquid PEG liquid 0.8～1.2%, nanometer calcium 8～10%, Cornstarch 4～6%, anti-wear agent 0.4～0.6%, antifoggant 0.4～0.6%, activating agent 0.4～0.6%, the close stone roller time is 8～15 minutes, and temperature is 70～100 ℃; The model of said natural mark glue is 3L, the model of said butadiene rubber is BR900, the model of said butylbenzene is 1502, the model of said white carbon black is X-1065, the model of said nanometer calcium is CCR, and the model of said Cornstarch is EVA, and the model of said anti-wear agent is SP, the model of said antifoggant is 1900, and the model of said activating agent is ST;
2. in close stone roller machine, add sulphur promoter 0.4～0.6% by weight, anti-xanthochromia promoter 0.4～0.6%, spices 4～6%, toner, the close stone roller time is 8～15 minutes, temperature is 50～80 ℃; The model of said sulphur promoter is NS, and the model of said anti-xanthochromia promoter is platform Xiang 1# or platform Xiang 2#;
3. carry out vulcanizing treatment, the mixture after obtaining vulcanizing after the mixture in the close stone roller machine being poured out;
4. the mixture after will vulcanizing according to the raw material consumption at each big end cuts into the rubber raw materials sheet, obtains adding the raw material of the big end of spices;
The material injecting mould of the big end that adds spices is made the big end: with adding the raw material of the big end of spices, promptly cut into the rubber raw materials sheet, directly inject mould and make the big end, mold temperature is 150～160 ℃, and the time is 2～5 minutes;
Said spices is Bubble gum 867 particles or No. 1 liquid of Bubble gum squeed.
The manufacture method at the big end of band fragrance of the present invention directly adds spices in the preparation process of raw material of the big end, obtain the big end with fragrance under the situation that does not increase extra production process, makes fragrance slowly to continue to distribute; And reduced the use amount of spices, and reduced production cost, guaranteed that simultaneously the spices that adds is difficult for being identified and copying.
Description of drawings
The present invention has following accompanying drawing:
The preparation method flow chart at the big end of Fig. 1 band fragrance
The specific embodiment
Below in conjunction with accompanying drawing the present invention is described in further detail.
Fig. 1 as shown in Figure 1, the steps include: for the preparation method flow chart at the big end of band fragrance
1. the raw material of the big end of spices is added in preparation, 2. the material injecting mould of the big end that adds spices is made the big end, and said spices is Bubble gum 867 particles or No. 1 liquid of Bubble gum squeed.Owing in the preparation process of raw material of the big end, directly add spices, under the situation that does not increase extra production process, obtain the big end with fragrance, make fragrance slowly to continue to distribute; And reduced the use amount of spices, and reduced production cost, guaranteed that simultaneously the spices that adds is difficult for being identified and copying.
On the basis of technique scheme, raw material of the said big end is thermoplastic rubber TR or thermoplastic rubber TPR, and the concrete steps that the raw material of the big end of spices is added in said preparation are:
1. by weight add TPE plastic cement 45～47% in mixer, PS is U.S. 16～17% very, CCR nanometer calcium 8～10%, and white cigarette 2.5～3.5%, White Mineral Oil 17～19% stirred 10～15 minutes; The model of said TPE plastic cement is 475# or 675#, and the model of said white cigarette is 3061 or S1065, and the model of said White Mineral Oil is 405#, 4006# or 4010#;
2. in mixer, add ultraviolet absorber 0.25～0.35% by weight, antioxidant 0.25～0.35%, Cornstarch 2～3%, brightening agent 0.01～0.02% stirred 2～4 minutes; The model of said ultraviolet absorber is UV-9 or UV-24, and the model of said antioxidant is GW-540 or AM-101, and the model of said Cornstarch is BA01-01 or BA-01, and the model of said brightening agent is DA-3 or 128#;
3. by weight in mixer, adding anti-wear agent 2.5～3.5%, stirred 1～2 minute; Said anti-wear agent model is NM or NM-06;
4. steep 0.2～0.4% by weight in mixer, adding white hair, zinc powder 0.6～0.8%, yellow foaming 0.2～0.4% was stirred 2～4 minutes; The model of said white hair bubble is HX-1 or CA-06, and the model of said zinc powder is CF-1 or ZNO, and the model of said yellow foaming is KF-01 or AC;
5. the compound in the mixer after 1～2 minute, was dewatered 1～2 minute the raw material of the big end after obtaining dewatering with the water cooler cooling through dewaterer;
6. the raw material of the big end after will dewatering adds mixer, by weight add spices 3～4% in mixer, adds toner according to color demand of the big end, stirs 10～15 minutes;
7. close mixer, under the normal temperature laboratory state, allow mixed material cool off, obtain adding the raw material of the big end of spices;
Temperature was 40～50 ℃ when 1. step began, and heated gradually in the mixed process, and temperature is 80～95 ℃ when 7. step finishes;
Said material injecting mould of the big end with interpolation spices is made the concrete steps at the big end and is: the raw material of the big end that adds spices is added extruder, injector at normal temperatures successively, injector is made the big end with the material injecting mould of the big end that adds spices, the injection temperature of injector is 130～180 ℃, and be 2～5 minutes inject time.
In the technique scheme, step 1. in, the consumption of TPE plastic cement can be 45%, 45.5%, 46%, 46.5% or 47%; The strange beautiful consumption of PS can be 16%, 16.2%, 16.4%, 16.6%, 16.8% or 17%; The consumption of CCR nanometer calcium can be 8%, 8.5%, 9%, 9.5% or 10%; The consumption of white cigarette can be 2.5%, 2.6%, 2.7%, 2.8%, 2.9%, 3.0%, 3.1%, 3.2%, 3.3%, 3.4% or 3.5%; The consumption of White Mineral Oil can be 17%, 17.2%, 17.4%, 17.6%, 17.8%, 18%, 18.2%, 18.4%, 18.6%, 18.8% or 19%; Mixing time is 10 minutes, 11 minutes, 12 minutes, 13 minutes, 14 minutes or 15 minutes.Step 2. in, the consumption of ultraviolet absorber can be 0.25%, 0.26%, 0.27%, 0.28%, 0.29%, 0.3%, 0.31%, 0.32%, 0.33%, 0.34% or 0.35%; The consumption of antioxidant can be 0.25%, 0.26%, 0.27%, 0.28%, 0.29%, 0.3%, 0.31%, 0.32%, 0.33%, 0.34% or 0.35%; The consumption of Cornstarch can be 2%, 2.2%, 2.4%, 2.6%, 2.8% or 3%; The consumption of brightening agent can be 0.01%, 0.012%, 0.014%, 0.016%, 0.018% or 0.02%; Mixing time is 2 minutes, 2.5 minutes, 3 minutes, 3.5 minutes or 4 minutes.Step 3. in, the consumption of anti-wear agent can be 2.5%, 2.6%, 2.7%, 2.8%, 2.9%, 3.0%, 3.1%, 3.2%, 3.3%, 3.4% or 3.5%; Mixing time is 1 minute, 1.5 minutes or 2 minutes.Step 4. in, the consumption of white hair bubble can be 0.2%, 0.25%, 0.3%, 0.35% or 0.4%; The consumption of zinc powder can be 0.6%, 0.65%, 0.7%, 0.75% or 0.8%; The consumption of yellow foaming can be 0.2%, 0.25%, 0.3%, 0.35% or 0.4%; Mixing time is 2 minutes, 2.5 minutes, 3 minutes, 3.5 minutes or 4 minutes.Step 5. in, be 1 minute, 1.5 minutes or 2 minutes with the compound in the mixer with water cooler cool time; The dewaterer dewatering time is 1 minute, 1.5 minutes or 2 minutes.Step 6. in, the consumption of spices can be 3%, 3.2%, 3.4%, 3.6%, 3.8% or 4%; The color and the concrete consumption that add toner can adopt existing techniques in realizing, because it is irrelevant to add the technology and the toner of spices.Mixing time is 10 minutes, 11 minutes, 12 minutes, 13 minutes, 14 minutes or 15 minutes.Temperature was 40～50 ℃ when 1. step began, for example: can be 40 ℃, 41 ℃, 42 ℃, 43 ℃, 44 ℃, 45 ℃, 46 ℃, 47 ℃, 48 ℃, 49 ℃ or 50 ℃; Temperature is 80～95 ℃ when 7. step finishes, for example: can be 80 ℃, 81 ℃, 82 ℃, 83 ℃, 84 ℃, 85 ℃, 86 ℃, 87 ℃, 88 ℃, 89 ℃, 90 ℃, 91 ℃, 92 ℃, 93 ℃, 94 ℃ or 95 ℃; Heat gradually in the mixed process and can adopt existing techniques in realizing, for example: the stirring machine of selecting the temperature in the adjustable mixer.When with injector the material injecting mould of the big end that adds spices being made the big end, the injection temperature of injector is 130 ℃, 135 ℃, 140 ℃, 145 ℃, 150 ℃, 155 ℃, 160 ℃, 165 ℃, 170 ℃, 175 ℃ or 180 ℃; Be 2 minutes, 2.5 minutes, 3 minutes, 3.5 minutes, 4 minutes, 4.5 minutes or 5 minutes inject time.GW-540, AM-101 belong to light stabilizer, and light stabilizer is the activity of oxygen composition in the stable air, so light stabilizer is also referred to as antioxidant.
On the basis of technique scheme, raw material of the said big end is a rubber, and the concrete steps that the raw material of the big end of spices is added in said preparation are:
1. by weight in close stone roller machine, adding natural mark glue 8～10%, butadiene rubber 28～32%, butylbenzene 16～20%, white carbon black 22～26%, diethylene glycol (DEG) solid DEG1.3～1.7%, diethylene glycol (DEG) liquid PEG liquid 0.8～1.2%, nanometer calcium 8～10%, Cornstarch 4～6%, anti-wear agent 0.4～0.6%, antifoggant 0.4～0.6%, activating agent 0.4～0.6%, the close stone roller time is 8～15 minutes, and temperature is 70～100 ℃; The model of said natural mark glue is 3L, the model of said butadiene rubber is BR900, the model of said butylbenzene is 1502, the model of said white carbon black is X-1065, the model of said nanometer calcium is CCR, and the model of said Cornstarch is EVA, and the model of said anti-wear agent is SP, the model of said antifoggant is 1900, and the model of said activating agent is ST;
2. in close stone roller machine, add sulphur promoter 0.4～0.6% by weight, anti-xanthochromia promoter 0.4～0.6%, spices 4～6%, toner, the close stone roller time is 8～15 minutes, temperature is 50～80 ℃; The model of said sulphur promoter is NS or TS, and the model of said anti-xanthochromia promoter is platform Xiang 1# or platform Xiang 2#;
3. carry out vulcanizing treatment, the mixture after obtaining vulcanizing after the mixture in the close stone roller machine being poured out;
4. the mixture after will vulcanizing according to the raw material consumption at each big end cuts into the rubber raw materials sheet, obtains adding the raw material of the big end of spices;
Said material injecting mould of the big end with interpolation spices is made the concrete steps at the big end and is:
With adding the raw material of the big end of spices, promptly cut into the rubber raw materials sheet, directly to inject mould and make the big end, mold temperature is 150～160 ℃, the time is 2～5 minutes.
In the technique scheme, step 1. in, the consumption of natural mark glue can be 8%, 8.5%, 9%, 9.5% or 10%; The consumption of butadiene rubber can be 28%, 29%, 30%, 31% or 32%; The consumption of butylbenzene can be 16%, 17%, 18%, 19% or 20%; The consumption of white carbon black can be 22%, 23%, 24%, 25% or 26%; The consumption of diethylene glycol (DEG) solid DEG can be 1.3%, 1.4%, 1.5%, 1.6% or 1.7%; The consumption of diethylene glycol (DEG) liquid PEG liquid can be 0.8%, 0.9%, 1.0%, 1.1% or 1.2%; The consumption of nanometer calcium can be 8%, 8.5%, 9%, 9.5% or 10%; The consumption of Cornstarch can be 4%, 4.2%, 4.4%, 4.6%, 4.8%, 5%, 5.2%, 5.4%, 5.6%, 5.8% or 6%; The consumption of anti-wear agent can be 0.4%, 0.42%, 0.44%, 0.46%, 0.48%, 0.5%, 0.52%, 0.54%, 0.56%, 0.58% or 0.6%; The consumption of antifoggant can be 0.4%, 0.42%, 0.44%, 0.46%, 0.48%, 0.5%, 0.52%, 0.54%, 0.56%, 0.58% or 0.6%; The consumption of activating agent can be 0.4%, 0.42%, 0.44%, 0.46%, 0.48%, 0.5%, 0.52%, 0.54%, 0.56%, 0.58% or 0.6%; The close stone roller time is 8 minutes, 9 minutes, 10 minutes, 11 minutes, 12 minutes, 13 minutes, 14 minutes or 15 minutes; The temperature of close stone roller machine is 70 ℃, 75 ℃, 80 ℃, 85 ℃, 90 ℃, 95 ℃ or 100 ℃.Step 2. in, the consumption of sulphur promoter can be 0.4%, 0.42%, 0.44%, 0.46%, 0.48%, 0.5%, 0.52%, 0.54%, 0.56%, 0.58% or 0.6%; The consumption of anti-xanthochromia promoter can be 0.4%, 0.42%, 0.44%, 0.46%, 0.48%, 0.5%, 0.52%, 0.54%, 0.56%, 0.58% or 0.6%; The consumption of spices can be 4%, 4.2%, 4.4%, 4.6%, 4.8%, 5%, 5.2%, 5.4%, 5.6%, 5.8% or 6%; The color and the concrete consumption that add toner can adopt existing techniques in realizing, because it is irrelevant to add the technology and the toner of spices; The close stone roller time is 8 minutes, 9 minutes, 10 minutes, 11 minutes, 12 minutes, 13 minutes, 14 minutes or 15 minutes; The temperature of close stone roller machine is 50 ℃, 55 ℃, 60 ℃, 65 ℃, 70 ℃, 75 ℃ or 80 ℃.The step 3. concrete grammar and the technological parameter of said vulcanizing treatment can adopt existing techniques in realizing, and above-mentioned is sulfidation with mixture close stone roller in close stone roller machine; Mixture after the 4. said raw material consumption according to each big end of step will vulcanize cuts into the rubber raw materials sheet and can adopt existing techniques in realizing, for example: finished weight of the needed big end is 200 grams, promptly mixture is cut into 200 bulks that restrain and adds the finished product of the big end that promptly obtains 200 grammes per square metres in the mould.The rubber raw materials sheet of well cutting is the raw material of the big end of required interpolation spices.When the material injecting mould of the big end that adds spices being made the big end, mold temperature is 150 ℃, 152 ℃, 154 ℃, 156 ℃, 158 ℃ or 160 ℃; Making required time of the big end is 2 minutes, 3 minutes, 4 minutes or 5 minutes.
On the basis of technique scheme, raw material of the said big end is expansion PVC, and the concrete steps that the raw material of the big end of spices is added in said preparation are:
1. in mixer, add resin 45～50% by weight, dibutylester 18～20%, dibutyl ester 16～20%, nanometer calcium 8～10%, heat stabilizer 4～5% stirs, and the time is 8～10 minutes, and temperature is 120～180 ℃; The model of said resin is a polyvinyl chloride, and the model of said dibutylester is DEP, and the model of said dibutyl ester is DOP, and the model of said nanometer calcium is CCR, and the model of said heat stabilizer is 301 compound stabilizers;
2. in mixer, add toner by weight, spices 3～4%, mixing time is 10～15 minutes, temperature is 50～80 ℃;
3. the mixture in the mixer is added extruder, by extruder mixture is made the raw material of the big end of granular interpolation spices under the normal temperature, extrusion time is 2～5 minutes;
Said material injecting mould of the big end with interpolation spices is made the concrete steps at the big end and is: the raw material of the big end that adds spices is added extruder, injector at normal temperatures successively, injector is made the big end with the material injecting mould of the big end that adds spices, the injection temperature of injector is 150～190 ℃, and be 2～4 minutes inject time.
In the technique scheme, step 1. in, the consumption of resin can be 45%, 46%, 47%, 48%, 49% or 50%; The consumption of dibutylester can be 18%, 18.2%, 18.4%, 18.6%, 18.8%, 19%, 19.2%, 19.4%, 19.6%, 19.8% or 20%; The consumption of dibutyl ester can be 16%, 17%, 18%, 19% or 20%; The consumption of nanometer calcium can be 8%, 8.5%, 9%, 9.5% or 10%; The consumption of heat stabilizer can be 4%, 4.2%, 4.4%, 4.6%, 4.8% or 5%; Mixing time is 8 minutes, 8.5 minutes, 9 minutes, 9.5 minutes or 10 minutes; The mixer temperature is 120 ℃, 125 ℃, 130 ℃, 135 ℃, 140 ℃, 145 ℃, 150 ℃, 155 ℃, 160 ℃, 165 ℃, 170 ℃, 175 ℃ or 180 ℃.Step 2. in, the color and the concrete consumption that add toner can adopt existing techniques in realizing, have nothing to do with toner because add the technology of spices.The consumption of spices can be 3%, 3.2%, 3.4%, 3.6%, 3.8% or 4%; Mixing time is 10 minutes, 11 minutes, 12 minutes, 13 minutes, 14 minutes or 15 minutes; The mixer temperature is 50 ℃, 55 ℃, 60 ℃, 65 ℃, 70 ℃, 75 ℃ or 80 ℃.Step 3. in, the extrusion time of extruder is 2 minutes, 3 minutes, 4 minutes or 5 minutes.When with injector the material injecting mould of the big end that adds spices being made the big end, the injection temperature of injector is 150 ℃, 155 ℃, 160 ℃, 165 ℃, 170 ℃, 175 ℃, 180 ℃, 185 ℃ or 190 ℃; Be 2 minutes, 2.5 minutes, 3 minutes, 3.5 minutes or 4 minutes inject time.
Claims (1)
1. preparation method with the big end of fragrance is characterized in that: raw material of the big end is a rubber, and concrete steps are:
The raw material of the big end of spices is added in preparation:
1. by weight in close stone roller machine, adding natural mark glue 8～10%, butadiene rubber 28～32%, butylbenzene 16～20%, white carbon black 22～26%, diethylene glycol (DEG) solid DEG1.3～1.7%, diethylene glycol (DEG) liquid PEG liquid 0.8～1.2%, nanometer calcium 8～10%, Cornstarch 4～6%, anti-wear agent 0.4～0.6%, antifoggant 0.4～0.6%, activating agent 0.4～0.6%, the close stone roller time is 8～15 minutes, and temperature is 70～100 ℃; The model of said natural mark glue is 3L, the model of said butadiene rubber is BR900, the model of said butylbenzene is 1502, the model of said white carbon black is X-1065, the model of said nanometer calcium is CCR, and the model of said Cornstarch is EVA, and the model of said anti-wear agent is SP, the model of said antifoggant is 1900, and the model of said activating agent is ST;
2. in close stone roller machine, add sulphur promoter 0.4～0.6% by weight, anti-xanthochromia promoter 0.4～0.6%, spices 4～6%, toner, the close stone roller time is 8～15 minutes, temperature is 50～80 ℃; The model of said sulphur promoter is NS, and the model of said anti-xanthochromia promoter is platform Xiang 1# or platform Xiang 2#;
3. carry out vulcanizing treatment, the mixture after obtaining vulcanizing after the mixture in the close stone roller machine being poured out;
4. the mixture after will vulcanizing according to the raw material consumption at each big end cuts into the rubber raw materials sheet, obtains adding the raw material of the big end of spices;
The material injecting mould of the big end that adds spices is made the big end: with adding the raw material of the big end of spices, promptly cut into the rubber raw materials sheet, directly inject mould and make the big end, mold temperature is 150～160 ℃, and the time is 2～5 minutes;
Said spices is Bubble gum 867 particles or No. 1 liquid of Bubble gum squeed.
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| Application Number | Priority Date | Filing Date | Title |
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| CN2008101260547A CN101298193B (en) | 2008-07-02 | 2008-07-02 | Making method of spicy bottom |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2008101260547A CN101298193B (en) | 2008-07-02 | 2008-07-02 | Making method of spicy bottom |
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| CN101298193B true CN101298193B (en) | 2011-02-16 |
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