CN101297646A - Acaricides combination containing Spirodiclofen - Google Patents
Acaricides combination containing Spirodiclofen Download PDFInfo
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- CN101297646A CN101297646A CNA2008101502048A CN200810150204A CN101297646A CN 101297646 A CN101297646 A CN 101297646A CN A2008101502048 A CNA2008101502048 A CN A2008101502048A CN 200810150204 A CN200810150204 A CN 200810150204A CN 101297646 A CN101297646 A CN 101297646A
- Authority
- CN
- China
- Prior art keywords
- spiral shell
- mite
- mite ester
- alkynes
- shell mite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000642 acaricide Substances 0.000 title claims abstract description 16
- 230000000895 acaricidal Effects 0.000 title claims abstract description 12
- 239000005664 Spirodiclofen Substances 0.000 title abstract description 4
- DTDSAWVUFPGDMX-UHFFFAOYSA-N spirodiclofen Chemical compound CCC(C)(C)C(=O)OC1=C(C=2C(=CC(Cl)=CC=2)Cl)C(=O)OC11CCCCC1 DTDSAWVUFPGDMX-UHFFFAOYSA-N 0.000 title abstract description 4
- 241000488583 Panonychus ulmi Species 0.000 claims abstract description 14
- 229920000742 Cotton Polymers 0.000 claims abstract description 13
- 240000006962 Gossypium hirsutum Species 0.000 claims abstract description 13
- 240000007119 Malus pumila Species 0.000 claims abstract description 8
- 235000011430 Malus pumila Nutrition 0.000 claims abstract description 8
- 235000015103 Malus silvestris Nutrition 0.000 claims abstract description 8
- 150000002148 esters Chemical class 0.000 claims description 67
- 150000001345 alkine derivatives Chemical class 0.000 claims description 49
- 239000000203 mixture Substances 0.000 claims description 36
- 239000000839 emulsion Substances 0.000 claims description 21
- 239000000725 suspension Substances 0.000 claims description 15
- 239000004530 micro-emulsion Substances 0.000 claims description 13
- 239000003795 chemical substances by application Substances 0.000 claims description 9
- 241000238631 Hexapoda Species 0.000 claims description 3
- 241000675108 Citrus tangerina Species 0.000 claims 1
- 239000003814 drug Substances 0.000 abstract description 44
- 230000000694 effects Effects 0.000 abstract description 17
- ZYHMJXZULPZUED-UHFFFAOYSA-N Propargite Chemical compound C1=CC(C(C)(C)C)=CC=C1OC1C(OS(=O)OCC#C)CCCC1 ZYHMJXZULPZUED-UHFFFAOYSA-N 0.000 abstract description 13
- 230000002045 lasting Effects 0.000 abstract description 10
- 229940079593 drugs Drugs 0.000 abstract description 8
- 238000002360 preparation method Methods 0.000 abstract description 6
- 230000001276 controlling effect Effects 0.000 abstract description 4
- 230000002195 synergetic Effects 0.000 abstract description 3
- 239000000575 pesticide Substances 0.000 abstract description 2
- 239000004480 active ingredient Substances 0.000 abstract 4
- 239000002131 composite material Substances 0.000 abstract 3
- 239000000470 constituent Substances 0.000 abstract 2
- -1 alkyl phenol formaldehyde resin Chemical compound 0.000 description 40
- RTZKZFJDLAIYFH-UHFFFAOYSA-N diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 36
- 239000003921 oil Substances 0.000 description 26
- NBIIXXVUZAFLBC-UHFFFAOYSA-K [O-]P([O-])([O-])=O Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 23
- 239000010452 phosphate Substances 0.000 description 23
- 239000000375 suspending agent Substances 0.000 description 18
- 239000000047 product Substances 0.000 description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 15
- LRWZZZWJMFNZIK-UHFFFAOYSA-N 2-chloro-3-methyloxirane Chemical compound CC1OC1Cl LRWZZZWJMFNZIK-UHFFFAOYSA-N 0.000 description 14
- LYCAIKOWRPUZTN-UHFFFAOYSA-N glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 14
- CTQNGGLPUBDAKN-UHFFFAOYSA-N o-xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 14
- 239000002904 solvent Substances 0.000 description 13
- HXDOZKJGKXYMEW-UHFFFAOYSA-N 4-Ethylphenol Chemical compound CCC1=CC=C(O)C=C1 HXDOZKJGKXYMEW-UHFFFAOYSA-N 0.000 description 12
- WPYMKLBDIGXBTP-UHFFFAOYSA-N Benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 12
- 239000008367 deionised water Substances 0.000 description 12
- 239000002994 raw material Substances 0.000 description 12
- 238000005303 weighing Methods 0.000 description 12
- 238000009313 farming Methods 0.000 description 11
- 230000003449 preventive Effects 0.000 description 11
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 description 10
- WSFSSNUMVMOOMR-UHFFFAOYSA-N formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 10
- 229940051841 POLYOXYETHYLENE ETHER Drugs 0.000 description 8
- 241000488581 Panonychus citri Species 0.000 description 8
- WFDIJRYMOXRFFG-UHFFFAOYSA-N acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 8
- CSCPPACGZOOCGX-UHFFFAOYSA-N acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 8
- 239000003995 emulsifying agent Substances 0.000 description 8
- 238000009114 investigational therapy Methods 0.000 description 8
- 229920000056 polyoxyethylene ether Polymers 0.000 description 8
- YXFVVABEGXRONW-UHFFFAOYSA-N toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 8
- 229920001285 xanthan gum Polymers 0.000 description 8
- 239000003381 stabilizer Substances 0.000 description 7
- 239000005711 Benzoic acid Substances 0.000 description 6
- HVLLSGMXQDNUAL-UHFFFAOYSA-N Triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 description 6
- 235000010233 benzoic acid Nutrition 0.000 description 6
- LRHPLDYGYMQRHN-UHFFFAOYSA-N n-butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- HMFKFHLTUCJZJO-UHFFFAOYSA-N 2-{2-[3,4-bis(2-hydroxyethoxy)oxolan-2-yl]-2-(2-hydroxyethoxy)ethoxy}ethyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCCOCC(OCCO)C1OCC(OCCO)C1OCCO HMFKFHLTUCJZJO-UHFFFAOYSA-N 0.000 description 5
- 229920001214 Polysorbate 60 Polymers 0.000 description 5
- 241001454293 Tetranychus urticae Species 0.000 description 5
- 239000011780 sodium chloride Substances 0.000 description 5
- 241001672694 Citrus reticulata Species 0.000 description 4
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 4
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N iso-propanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
- 229920001568 phenolic resin Polymers 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 239000001587 sorbitan monostearate Substances 0.000 description 4
- 235000011076 sorbitan monostearate Nutrition 0.000 description 4
- 229940035048 sorbitan monostearate Drugs 0.000 description 4
- 239000000600 sorbitol Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- XSQUKJJJFZCRTK-UHFFFAOYSA-N urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 4
- DUIOKRXOKLLURE-UHFFFAOYSA-N 2-octylphenol Chemical compound CCCCCCCCC1=CC=CC=C1O DUIOKRXOKLLURE-UHFFFAOYSA-N 0.000 description 3
- 210000000481 Breast Anatomy 0.000 description 3
- JHIVVAPYMSGYDF-UHFFFAOYSA-N Cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 3
- 239000002518 antifoaming agent Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 230000002950 deficient Effects 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 238000004945 emulsification Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000008041 oiling agent Substances 0.000 description 3
- 230000000361 pesticidal Effects 0.000 description 3
- 229920001296 polysiloxane Polymers 0.000 description 3
- 230000002265 prevention Effects 0.000 description 3
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 3
- 239000004576 sand Substances 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- WXMKPNITSTVMEF-UHFFFAOYSA-M Sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 2
- 241001454295 Tetranychidae Species 0.000 description 2
- 241000344246 Tetranychus cinnabarinus Species 0.000 description 2
- HWKQNAWCHQMZHK-UHFFFAOYSA-N Trolnitrate Chemical compound [O-][N+](=O)OCCN(CCO[N+]([O-])=O)CCO[N+]([O-])=O HWKQNAWCHQMZHK-UHFFFAOYSA-N 0.000 description 2
- 240000006365 Vitis vinifera Species 0.000 description 2
- 235000014787 Vitis vinifera Nutrition 0.000 description 2
- 239000000440 bentonite Substances 0.000 description 2
- 229910000278 bentonite Inorganic materials 0.000 description 2
- HCWYXKWQOMTBKY-UHFFFAOYSA-N calcium;dodecyl benzenesulfonate Chemical compound [Ca].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 HCWYXKWQOMTBKY-UHFFFAOYSA-N 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 235000009754 grape Nutrition 0.000 description 2
- 235000012333 grape Nutrition 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- 239000000391 magnesium silicate Substances 0.000 description 2
- 229910052919 magnesium silicate Inorganic materials 0.000 description 2
- 230000003129 miticidal Effects 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 230000002335 preservative Effects 0.000 description 2
- 239000003755 preservative agent Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000004299 sodium benzoate Substances 0.000 description 2
- 235000010234 sodium benzoate Nutrition 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- DMAXMXPDVWTIRV-UHFFFAOYSA-N 2-(2-phenylethyl)phenol Chemical compound OC1=CC=CC=C1CCC1=CC=CC=C1 DMAXMXPDVWTIRV-UHFFFAOYSA-N 0.000 description 1
- 241000256844 Apis mellifera Species 0.000 description 1
- 241001643374 Brevipalpus Species 0.000 description 1
- 241000207199 Citrus Species 0.000 description 1
- 240000004259 Datura metel Species 0.000 description 1
- 241001221110 Eriophyidae Species 0.000 description 1
- 240000004282 Grewia occidentalis Species 0.000 description 1
- 229920001732 Lignosulfonate Polymers 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 206010067482 No adverse event Diseases 0.000 description 1
- 210000004681 Ovum Anatomy 0.000 description 1
- 206010034133 Pathogen resistance Diseases 0.000 description 1
- 235000000208 Solanum incanum Nutrition 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L Sulphite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- 241000916145 Tarsonemidae Species 0.000 description 1
- 241000488607 Tenuipalpidae Species 0.000 description 1
- 241000488533 Tetranychus viennensis Species 0.000 description 1
- 231100000605 Toxicity Class Toxicity 0.000 description 1
- 235000010724 Wisteria floribunda Nutrition 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 230000000240 adjuvant Effects 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- 235000020971 citrus fruits Nutrition 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 230000000875 corresponding Effects 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 230000037149 energy metabolism Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000000749 insecticidal Effects 0.000 description 1
- 230000004132 lipogenesis Effects 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- PSZYNBSKGUBXEH-UHFFFAOYSA-M naphthalene-1-sulfonate Chemical compound C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-M 0.000 description 1
- 238000003359 percent control normalization Methods 0.000 description 1
- 229920005646 polycarboxylate Polymers 0.000 description 1
- 230000002829 reduced Effects 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 230000001340 slower Effects 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Abstract
The invention discloses an acaricide composite containing spirodiclofen and application thereof, comprising (A) a first active ingredient: spirodiclofen and (B) a second active ingredients: propargite; the weight ratio of the first active ingredient and the second active ingredients is 0.01 to 10 : 1. The acaricide composite has reasonable constituent, good acarotoxic effect and low drug cost, and the activity and the acarotoxic effect are not simple sum of the activities of all the constituents but with the advantages of obvious synergistic effect, high quick action, long lasting effect, reducing the generation of resistance to drugs, little residual of preparation, no pollution to crops and good safety and meets the safety requirement of the pesticide preparation. The acaricide composite of the invention has controlling effect of 82.69 to 95.67 percent for red spider in citrous, apple trees and cotton.
Description
Technical field
The present invention relates to a kind of miticide composition and application thereof that contains spiral shell mite ester, particularly a kind of comprise contain spiral shell mite ester as first active component and alkynes mite spy as the miticide composition and the application thereof of second active component, belong to technical field of compounded pesticide.
Spiral shell mite ester (english common name spirodiclofen, chemical molecular formula C
21H
24Cl
2O
4) mechanism of action is for suppressing the lipogenesis in the evil mite body, harmful mite is finally killed in the energy metabolism activity of destruction acarid.The characteristics of control are to kill that mite broad spectrum activity, ovum children are held concurrently and killed, the lasting period is long, toxicity is low, safety is good and other miticides do not have cross resistance, and shortcoming is speed of action slow (drug effect peak be behind the medicine about 7 days), to becoming the mite effect undesirable.By China's pesticide toxicity grading criteria, spiral shell mite ester belongs to the low toxicity miticide.Be widely used in various mite class controls, as Panonychus citri, cotton spider mites, the Tetranychus cinnabarinus of Tetranychidae apple, citrus, Tarsonemidae (the many tarsonemids of side), Eriophyidae (thorn apple rust mite, grape rust mite), Tenuipalpidae (grape brevipalpus).But the spiral shell mite ester of selling on city's field boundary is a unitary agent at present, and this unitary agent in use exists easy generation resistance, the defective that the preventive effect cost rises day by day, speed of action is slow.
Alkynes mite spy has another name called the Aomei spy, propargite, english common name propargite, chemical molecular formula C
19H
26O
4S.Alkynes mite spy is the wide spectrum organosulfur acaricide, to becoming mite and if mite preventive effect height.Alkynes mite spy has selectivity, and is safer to honeybee and natural enemy, and quick-acting is good, and the lasting period is general, and toxicity is very low, little to people and animals and natural environment harm.But as a kind of miticide of long-term use, alkynes mite spy has produced resistance in various degree in long-term use, the defective that exists control efficiency to descend.
At present, the pesticidal preparations that with spiral shell mite ester is effective ingredient is based on 240 grams per liter spiral shell mite ester suspending agents, and in actual use, the lasting period is long, but quick-acting is relatively poor, to becoming the mite weak effect; The special quick-acting of alkynes mite is better, and to the one-tenth mite with as if mite preventive effect height, but lasting effect is general, and the unexpected discovery of inventor is mixed two active components to use and can improves its quick-acting, and the good lasting period is arranged again, slows down the generation of pest resistance.
Summary of the invention
One of purpose of the present invention is to provide a kind of miticidal effect good, and drug cost is low, the acaricide composition that contains spiral shell mite ester that is difficult for developing immunity to drugs.
Another object of the present invention is to provide the purposes of above-mentioned composition.
In order to overcome the defective of existing single component formulations, technical scheme of the present invention is to solve like this:
A kind of acaricide composition that contains spiral shell mite ester is characterized in that comprising:
A) the first active component spiral shell mite ester;
B) the second active component alkynes mite spy;
The weight ratio of first active component and second active component is 0.01～10: 1, be preferably 0.02～5: and 1, most preferably be 0.05～1: 1.
The preparation formulation that the present composition can be prepared according to the known method of those skilled in the art of the present technique can be missible oil, suspension emulsion, microemulsion or aqueous emulsion.
For missible oil, those skilled in the art are familiar with the use corresponding adjuvants and finish the present invention very much.Emulsifier such as calcium dodecyl benzene sulfonate (agricultural newborn 500#), Nongru-700 # (common name: alkyl phenol formaldehyde resin polyoxyethylene ether), the newborn 2201# of farming, Span-60# (common name sorbitan monostearate), Tween-60# (common name: anhydrous sorbitol monostearate polyoxyethylene groups ether), TX-10 (common name: octyl phenol polyoxy ethene (10) ether), the newborn 1601# of farming (common name: triphen ethyl-phenol polyoxyethylene polyoxypropylene block polymer), the newborn 600# of farming, the farming newborn 400# in one or more; In solvent such as dimethylbenzene, solvent naphtha (S-150, S-180, S-200), toluene, methyl alcohol, dimethyl formamide, cyclohexanone, acetone, the diesel oil one or more; In stabilizing agent such as triphenyl phosphite, epoxychloropropane, the aceticanhydride one or more.
To suspension emulsion, spendable auxiliary agent has: among dispersant such as polycarboxylate, lignosulfonates, alkylnaphthalene sulfonate, the TERSPERSE 2425 (U.S. Huntsman Corporation produces, the alkyl naphthalene sulfonic acid salt) one or more; Emulsifier such as Nongru-700 # (common name: alkyl phenol formaldehyde resin polyoxyethylene ether, farming breast 2201, this dish-60# (common name sorbitan monostearate), Tween-60 # (common name: anhydrous sorbitol monostearate polyoxyethylene groups ether), the newborn 1601# of farming (common name: triphen ethyl-phenol polyoxyethylene polyoxypropylene block polymer), among triphen ethyl phenol polyoxyethylene groups ether phosphate (agricultural newborn 600# phosphate) TERSPERSE4894 (the U.S. Huntsman Corporation product) TERSPERSE 2500 (U.S. Huntsman Corporation product) one or more; Among wetting agent such as alkylphenol-polyethenoxy base ether formaldehyde condensation products phosphate, alkylphenol-polyethenoxy base ether phosphate, phenethyl phenol polyethenoxy base ether phosphate, alkyl sulfate, alkylsulfonate, naphthalene sulfonate, the TERSPERSE 2500 (U.S. Huntsman Corporation product) one or more; Solvent: one or more in dimethylbenzene, toluene, the solvent naphtha (S-150, S-180, S-200); In thickener such as xanthans, polyvinyl alcohol, bentonite, the aluminium-magnesium silicate one or more; In preservative such as formaldehyde, benzoic acid, the Sodium Benzoate one or more; Defoamer such as organic silicon defoamer; In antifreezing agent such as ethylene glycol, propane diols, glycerine, urea, inorganic salts such as the sodium chloride one or more; In stabilizing agent such as triphenyl phosphite, epoxychloropropane, the aceticanhydride one or more; Water is deionized water.
To microemulsion, spendable auxiliary agent has: emulsifier such as calcium dodecyl benzene sulfonate (agricultural newborn 500#), Nongru-700 # (common name: alkyl phenol formaldehyde resin polyoxyethylene ether), agricultural newborn 2201#, Span-60# (common name sorbitan monostearate), Tween-60# (common name: anhydrous sorbitol monostearate polyoxyethylene groups ether), TX-10 (common name: octyl phenol polyoxy ethene (10) ether), farming breast 1601 (common name: triphen ethyl-phenol polyoxyethylene polyoxypropylene block polymer), among agricultural newborn 600#, the agricultural newborn 400# one or more; In assistant for emulsifying agent such as methyl alcohol, acetone, cyclohexanone, isopropyl alcohol, n-butanol, the ethanol one or more; Solvent such as dimethylbenzene, toluene, solvent naphtha (trade mark: S-150, S-180, S-200) one or more; In stabilizing agent such as triphenyl phosphite, epoxychloropropane, the aceticanhydride one or more; Water is deionized water.
To aqueous emulsion, spendable auxiliary agent has: emulsifier such as Nonyl pheno (EO=10) ether phosphate, triphen ethyl-phenol polyoxyethylene ether phosphate (agricultural newborn 600# phosphate), Nongru-700 # (common name: alkyl phenol formaldehyde resin polyoxyethylene ether), the newborn 2201# of farming, Span-60# (common name sorbitan monostearate), Tween-60# (common name: anhydrous sorbitol monostearate polyoxyethylene groups ether), TX-10 (common name: octyl phenol polyoxy ethene (10) ether), farming breast 1601 (common names: triphen ethyl-phenol polyoxyethylene polyoxypropylene block polymer), the newborn 600# of farming, the farming newborn 400# in one or more; Solvent such as dimethylbenzene, toluene, solvent naphtha (trade mark: S-150, S-180, S-200) one or more; In stabilizing agent such as triphenyl phosphite, epoxychloropropane, the aceticanhydride one or more; Antifreezing agent: in ethylene glycol, propane diols, glycerine, urea, inorganic salts such as the sodium chloride one or more; In thickener such as xanthans, polyvinyl alcohol, bentonite, the aluminium-magnesium silicate one or more; In preservative such as formaldehyde, benzoic acid, the Sodium Benzoate one or more, water is deionized water.
Component of the present invention is reasonable, and miticidal effect is good, and drug cost is low, and its active and insecticidal effect is not the simple superposition of each composition activity, but significant synergistic effect is arranged, and quick-acting height, lasting effect are long, slow down the generation of resistance, safety is good, meets the security requirement of pesticidal preparations.The present invention has 82.69%～95.67% control efficiency to oranges and tangerines, apple tree, cotton red spider insect.
Embodiment
Below in conjunction with embodiment content of the present invention is described further.
Example of formulations 1
Take by weighing 3% spiral shell mite ester, 30% alkynes mite spy, 4% agricultural newborn 500#, 2% Nongru-700 #, 4% agricultural newborn 1601#, 1% epoxychloropropane, dimethylbenzene adds to 100% weight portion.Above-mentioned raw materials makes the special missible oil of 33% spiral shell mite ester alkynes mite after mix, stirring and dissolving is complete.
Spiral shell mite ester and alkynes mite spy's part by weight can be 0.01～10 in the present embodiment: change between 1, both total weight items still are 33%, form new embodiment.
Example of formulations 2
Take by weighing 1% spiral shell mite ester, 70% alkynes mite spy, 4% agricultural newborn 500#, 2% agricultural newborn 400#, 3% Nongru-700 #, 3% triphenyl phosphite, solvent naphtha S-150 adds to 100% weight portion.Above-mentioned raw materials makes the special missible oil of 71% spiral shell mite ester alkynes mite after mix, stirring and dissolving is complete.
Spiral shell mite ester and alkynes mite spy's part by weight can be 0.01～10 in the present embodiment: change between 1, both total weight items still are 71%, form new embodiment.
Example of formulations 3
Take by weighing 30% spiral shell mite ester, 4% alkynes mite spy, 4% agricultural newborn 500#, 2% agricultural newborn 600#, 3% agricultural newborn 2201#, 3% triphenyl phosphite, solvent naphtha S-180 adds to 100% weight portion.Above-mentioned raw materials makes the special missible oil of 34% spiral shell mite ester alkynes mite after mix, stirring and dissolving is complete.
Spiral shell mite ester and alkynes mite spy's part by weight can be 0.01～10 in the present embodiment: change between 1, both total weight items still are 34%, form new embodiment.
Example of formulations 4
Take by weighing 2% spiral shell mite ester, 30% alkynes mite spy, 3%TERSPERSE 4894 (U.S. Huntsman Corporation product), 1.5%TERSPERSE 2500 (U.S. Huntsman Corporation product), 2%TERSPERSE 2425 (U.S. Huntsman Corporation product), 3% agricultural newborn 2201#, 3% triphen ethyl phenol polyoxyethylene groups ether phosphate (agricultural newborn 600# phosphate), 0.2% xanthans, 5% dimethylbenzene, 5% propane diols, 0.5% benzoic acid, 0.5% silicone defoaming agent (trade name: s-29 Nanjing "four news" (new ideas applied chemistry product company produces), 1% epoxychloropropane, deionized water add to 100% weight portion.Above-mentioned raw materials is pressed the suspension emulsion known method, alkynes mite spy and emulsifier, solvent, stabilizing agent are made missible oil, simultaneously spiral shell mite ester and other raw sand are ground into suspending agent, missible oil and suspending agent are mixed also high speed shear dispersion 30min, make 32% the special suspension emulsion of spiral shell mite ester alkynes mite.
Spiral shell mite ester and alkynes mite spy's part by weight can be 0.01～10 in the present embodiment: change between 1, both total weight items still are 32%, form new embodiment.
Example of formulations 5
Take by weighing 1% spiral shell mite ester, 40% alkynes mite spy, 3%TERSPERSE 4894 (U.S. Huntsman Corporation product), 1%TERSPERSE 2500 (U.S. Huntsman Corporation product), 1%TERSPERSE 2425 (U.S. Huntsman Corporation product), 4% agricultural newborn 2201#, 3% triphen ethyl phenol polyoxyethylene groups ether phosphate (agricultural newborn 600# phosphate), 0.2% xanthans, 5% dimethylbenzene, 5% ethylene glycol, 0.5% formaldehyde, 0.5% silicone defoaming agent (trade name: s-29 Nanjing "four news" (new ideas applied chemistry product company produces), 1% epoxychloropropane, deionized water add to 100% weight portion.Above-mentioned raw materials is pressed the suspension emulsion known method, alkynes mite spy and emulsifier, solvent, stabilizing agent are made missible oil, simultaneously spiral shell mite ester and other raw sand are ground into suspending agent, missible oil and suspending agent are mixed also high speed shear dispersion 30min, make 41% the special suspension emulsion of spiral shell mite ester alkynes mite.
Spiral shell mite ester and alkynes mite spy's part by weight can be 0.01～10 in the present embodiment: change between 1, both total weight items still are 41%, form new embodiment.
Example of formulations 6
Take by weighing 20% spiral shell mite ester, 5% alkynes mite spy, 3%TERSPERSE 4894 (U.S. Huntsman Corporation product), 1%TERSPERSE 2500 (U.S. Huntsman Corporation product), 1%TERSPERSE 2425 (U.S. Huntsman Corporation product), 2% agricultural newborn 2201#, 2% triphen ethyl phenol polyoxyethylene groups ether phosphate (agricultural newborn 600# phosphate), 0.2% xanthans, 5% dimethylbenzene, 5% ethylene glycol, 0.5% formaldehyde, 0.5% silicone defoaming agent (trade name: s-29 Nanjing "four news" (new ideas applied chemistry product company produces), 1% epoxychloropropane, deionized water add to 100% weight portion.Above-mentioned raw materials is pressed the suspension emulsion known method, alkynes mite spy and emulsifier, solvent, stabilizing agent are made missible oil, simultaneously spiral shell mite ester and other raw sand are ground into suspending agent, missible oil and suspending agent are mixed also high speed shear dispersion 30min, make 25% the special suspension emulsion of spiral shell mite ester alkynes mite.
Spiral shell mite ester and alkynes mite spy's part by weight can be 0.01～10 in the present embodiment: change between 1, both total weight items still are 25%, form new embodiment.
Example of formulations 7
Take by weighing 5% spiral shell mite ester, 10% alkynes mite spy, 6% agricultural newborn 500#, 6% agricultural newborn 400#, 5% agricultural newborn 1601#, 1% epoxychloropropane, 15% dimethylbenzene, 5% acetone, 4% isopropyl alcohol, deionized water adds to 100% weight portion.Above-mentioned raw materials makes 15% spiral shell mite ester propargite microemulsion after mix, stirring and dissolving is complete.
Spiral shell mite ester and alkynes mite spy's part by weight can be 0.01～10 in the present embodiment: change between 1, both total weight items still are 15%, form new embodiment.
Example of formulations 8
Take by weighing 5% spiral shell mite ester, 40% alkynes mite spy, 5% agricultural newborn 500#, 7% agricultural newborn 400#, 4% agricultural newborn 1601#, 1% epoxychloropropane, 5% dimethylbenzene, 10% cyclohexanone, 4% n-butanol, deionized water adds to 100% weight portion.Above-mentioned raw materials makes 45% spiral shell mite ester propargite microemulsion after mix, stirring and dissolving is complete.
Spiral shell mite ester and alkynes mite spy's part by weight can be 0.01～10 in the present embodiment: change between 1, both total weight items still are 45%, form new embodiment.
Example of formulations 9
Take by weighing 15% spiral shell mite ester, 15% alkynes mite spy, 5% agricultural newborn 500#, 5% agricultural newborn 400#, 7% agricultural newborn 1601#, 1% epoxychloropropane, 10% dimethylbenzene, 15% acetone, 5% n-butanol, deionized water adds to 100% weight portion.Above-mentioned raw materials makes 30% spiral shell mite ester propargite microemulsion after mix, stirring and dissolving is complete.
Spiral shell mite ester and alkynes mite spy's part by weight can be 0.01～10 in the present embodiment: change between 1, both total weight items still are 30%, form new embodiment.
Example of formulations 10
Take by weighing 4% spiral shell mite ester, 20% alkynes mite spy, 3% agricultural newborn 2201#, 2% Nonyl pheno (EO=10) ether phosphate, 2% triphen ethyl-phenol polyoxyethylene ether phosphate (agricultural newborn 600# phosphate), 2%Span-60#, 1% epoxychloropropane, 5% ethylene glycol, 10% dimethylbenzene, 0.3% xanthans, 0.5% benzoic acid, deionized water adds to 100% weight portion.Above-mentioned raw materials is through mixing, and high speed shear emulsification makes the special aqueous emulsion of 24% spiral shell mite ester alkynes mite.
Spiral shell mite ester and alkynes mite spy's part by weight can be 0.01～10 in the present embodiment: change between 1, both total weight items still are 24%, form new embodiment.
Example of formulations 11
Take by weighing 1.5% spiral shell mite ester, 30% alkynes mite spy, 3% agricultural newborn 2201#, 1.5% Nonyl pheno (EO=10) ether phosphate, 2.5% triphen ethyl-phenol polyoxyethylene ether phosphate (agricultural newborn 600# phosphate), 2%Span-60#, 1% epoxychloropropane, 5% ethylene glycol, 5% dimethylbenzene, 0.3% xanthans, 0.5% benzoic acid, deionized water adds to 100% weight portion.Above-mentioned raw materials is through mixing, and high speed shear emulsification makes the special aqueous emulsion of 31.5% spiral shell mite ester alkynes mite.
Spiral shell mite ester and alkynes mite spy's part by weight can be 0.01～10 in the present embodiment: change between 1, both total weight items still are 31.5%, form new embodiment.
Example of formulations 12
Take by weighing 10% spiral shell mite ester, 4% alkynes mite spy, 3%Tween60#, 2% Nonyl pheno (EO=10) ether phosphate, 2% triphen ethyl-phenol polyoxyethylene ether phosphate (agricultural newborn 600# phosphate), 3%Span-60#, 1% epoxychloropropane, 5% ethylene glycol, 20% dimethylbenzene, 0.3% xanthans, 0.5% benzoic acid, deionized water adds to 100% weight portion.Above-mentioned raw materials is through mixing, and high speed shear emulsification makes the special aqueous emulsion of 14% spiral shell mite ester alkynes mite.
Spiral shell mite ester and alkynes mite spy's part by weight can be 0.01～10 in the present embodiment: change between 1, both total weight items still are 14%, form new embodiment.
Biological Examples 1: control citrus red mite field trial
The inventor carried out the field control effectiveness test of the special missible oil control of 33% spiral shell mite ester alkynes mite citrus red mite on May 29th, 2007 in Yichang City, Hubei Province Xu Guang village, verified that this medicament is to the control efficiency of citrus red mite, effective dose and to the safety of mandarin tree.Trial crops is oranges and tangerines, controlling object citrus red mite (Panonychus citri Me Gregor).Test medicine and dosage are 1500 times, 2000 times, 2500 times of the special missible oil of 33% spiral shell mite ester alkynes mite, 3000 times of the special missible oil of 73% alkynes mite, and 4000 times of 240 grams per liter spiral shell mite ester suspending agents adopt conventional spray-on process.Investigation insect population radix before the dispenser, 1d, 3d, 10d, 15d, 30d investigate residual borer population alive respectively behind the medicine, and 2 strains are looked in every sub-district during investigation, every strain is looked into 5 leaves respectively by 4 orientation, the four corners of the world, every sub-district is looked into 40 leaves altogether, and record mite number alive carries out the control efficiency statistics.The preventive effect computational methods
In the formula: Pt
0Before-----treatment region medicine; Pt
1Behind-----treatment region medicine
CK
0Before the medicine of-----check plot; CK
1Behind the medicine of-----check plot
The special missible oil control of table 133% spiral shell mite ester alkynes mite citrus red mite result of the test
As shown in table 1, behind the medicine the 10th day the time each sub-district preventive effect carry out the biostatistics analysis, analysis result shows: handle differences and reach extremely outstanding level, district's group difference is not remarkable.Significance of difference comparative result shows: consistent with the significance of difference on 0.01 level on 0.05 level, the special missible oil of 33% spiral shell mite ester alkynes mite is respectively handled differences with other for 1500 times and is all reached utmost point significance level, 2000 times of the special missible oil of 33% spiral shell mite ester alkynes mite are not remarkable with 4000 times of processing of contrast medicament 240 grams per liter spiral shell mite ester suspending agents differences, and 3000 times of processing of 2500 times of processing of the special missible oil of 33% spiral shell mite ester alkynes mite and the special missible oil of contrast medicament 73% alkynes mite differences reaches utmost point significance level.
Field trial shows (seeing Table 1): the special missible oil of 33% spiral shell mite ester alkynes mite has than remarkable prevention effect citrus red mite, its 1500 times with 3000 times of the special missible oil of contrast medicament 73% alkynes mite, 4000 times of control efficiency of comparing of 240 grams per liter spiral shell mite ester suspending agents are better than contrasting medicament, its 2000 times equate with contrast medicament 240 grams per liter spiral shell mite ester suspending agents 4000 times of preventive effects, a little more than 3000 times of control efficiency of the special missible oil of 73% alkynes mite, after result of the test shows that spiral shell mite ester and alkynes mite spy are mixed, obviously improved control efficiency to two spotted spider mite, quick-acting and lasting period, greatly reduce dosage and drug cost simultaneously, to oranges and tangerines growth safety.
Biological Examples 2: control apple tree two spotted spider mite field trial
The inventor carried out the field control effectiveness test of the special suspension emulsion control of 32% spiral shell mite ester alkynes mite European red mite on July 26th, 2007 in Shi Tan town, Liquan County, Shaanxi Province, verified that this medicament is to the control efficiency of European red mite, effective dose and to the safety of apple tree.The trial crops apple, kind is Fuji's life in 11 years, controlling object: European red mite (Tetranychus viennensis Zacher), test medicine and dosage are 2000 times, 2500 times, 3000 times of the special suspension emulsions of 32% spiral shell mite ester alkynes mite, 4000 times of the special missible oil of 73% alkynes mite, 5000 times of 240 grams per liter spiral shell mite ester suspending agents.Adopt conventional spray-on process, before medicine, behind the medicine, carried out the control efficiency investigation in 1 day, 3 days, 7 days, 14 days, investigate altogether 5 times.During investigation every strain of every sub-district tree press thing, north and south, in 10 epiphyllous activity attitude mite numbers of each fixing investigation, and type of the dated blade of getting.Check blade with hand magnifier, record activity attitude mite quantity is carried out the control efficiency statistics.
Computational methods
In the formula: Pt
0Before-----treatment region medicine; Pt
1Behind-----treatment region medicine
CK
0Before the medicine of-----check plot; CK
1Behind the medicine of-----check plot
The special suspension emulsion control of table 232% spiral shell mite ester alkynes mite European red mite result of the test
To behind the medicine the 7th day the time each sub-district preventive effect carry out biostatistics analysis (seeing Table 2), analysis result shows: handle differences and reach extremely outstanding level, district's group difference is not remarkable.Significance of difference comparative result shows: consistent with the significance of difference on 0.01 level on 0.05 level, the special suspension emulsion of 32% spiral shell mite ester alkynes mite is respectively handled differences with other for 2000 times, 2500 times and is all reached utmost point significance level, and 3000 times of special suspension emulsions of 32% spiral shell mite ester alkynes mite and 4000 times of the special missible oil of contrast medicament 73% alkynes mite, that 5000 times 3 of 240 grams per liter spiral shell mite ester suspending agents are handled differences is all not remarkable.
Field trial shows (seeing Table 2): the special suspension emulsion of 32% spiral shell mite ester alkynes mite has than remarkable prevention effect European red mite, its 2000 times, 2500 times with 4000 times of the special missible oil of contrast medicament 73% alkynes mite, 5000 times of control efficiency of comparing of 240 grams per liter spiral shell mite ester suspending agents are better than contrasting medicament, its 3000 times with 4000 times of the special missible oil of 73% alkynes mite, 5000 times of control efficiency of 240 grams per liter spiral shell mite ester suspending agents are suitable substantially, after result of the test shows that spiral shell mite ester and alkynes mite spy are mixed, obviously improved control efficiency to two spotted spider mite, quick-acting and lasting period, greatly reduce dosage and drug cost simultaneously, to apple development safety.
Biological Examples 3: control cotton red spider field trial
The inventor reads the field control effectiveness test that the bridge township has carried out 15% spiral shell mite ester propargite microemulsion control cotton red spider on June 2nd, 2007 in Weinan City Dali County, Shaanxi Province, verify that the control efficiency of this medicament, effective dose reach the safety to cotton.Trial crops is a cotton, controlling object: cotton red spider (Tetranychuscinnabarinus (Biosduval)), test medicine and dosage: 2000 times, 2500 times, 3000 times of 15% spiral shell mite ester propargite microemulsions, 4000 times of the special missible oil of 73% alkynes mite, 5000 times of 240 grams per liter spiral shell mite ester suspending agents.Adopt conventional spray-on process to carry out, 5 samplings in every sub-district are fixed 2 strains investigation at every, and every strain fixedly upper blade has 5, the two spotted spider mite number on the investigation fixed blade; Preventive effect is calculated by 1d, 3d, the residual group of 7d investigation two spotted spider mite behind the medicine.
Computational methods
PT in the formula
0The equal group of the strain number of the worm alive before-chemicals treatment district medicine; PT
1The equal group of the strain number of the worm alive behind-chemicals treatment district medicine; CK
0The equal group of the strain number of the worm alive before-blank district medicine; CK
1The equal group of the strain number of the worm alive behind-blank district medicine;
Table 315% spiral shell mite ester propargite microemulsion control cotton red spider result of the test
As shown in table 3, to behind the medicine the 7th day the time each sub-district preventive effect carry out the biostatistics analysis, analysis result shows: handle differences and reach extremely outstanding level, district's group difference is not remarkable.Significance of difference comparative result shows: consistent with the significance of difference on 0.01 level on 0.05 level, 15% spiral shell mite ester propargite microemulsion is respectively handled differences with other for 2000 times and is reached utmost point significance level, its 2500 times are not all remarkable with 5000 times of processing of 240 grams per liter spiral shell mite ester suspending agents differences, and 3000 times of 15% spiral shell mite ester propargite microemulsions are not remarkable with 4000 times of processing of the special missible oil of contrast medicament 73% alkynes mite differences.Field trial shows: 15% spiral shell mite ester propargite microemulsion has remarkable prevention effect to cotton red spider, the preventive effect that 15% spiral shell mite ester propargite microemulsion is 2000 times all is better than the preventive effect with 4000 times of the special missible oil of contrast medicament 73% alkynes mite, 5000 times of 240 grams per liter spiral shell mite ester suspending agents, test shows: after spiral shell mite ester and alkynes mite spy are mixed, obviously improved quick-acting and control efficiency, greatly reduced dosage and drug cost cotton red spider.Handle all to cotton growth safety through each concentration of duration of test viewing test, have no adverse effects.
In sum, composition of the present invention is to adopt two kinds of active component compound schemes, and it is active and kill mite Effect is not the simple superposition of each composition activity, compares with existing unitary agent, except having the significant mite that kills Outside the effect, and significant synergistic effect is arranged, quick-acting height, lasting effect are long, slow down the generation of resistance, and be right Crop safety is good, and dosage reduces, and meets the security requirement of pesticidal preparations.
Claims (5)
1, a kind of acaricide composition that contains spiral shell mite ester is characterized in that comprising:
A) the first active component spiral shell mite ester;
B) the second active component alkynes mite spy;
The weight ratio of first active component and second active component is 0.01～10: 1.
2, a kind of acaricide composition that contains spiral shell mite ester according to claim 1, it is characterized in that: the weight ratio of first active component and second active component is 0.02～5: 1.
3, a kind of acaricide composition that contains spiral shell mite ester according to claim 2, it is characterized in that: the weight ratio of first active component and second active component is 0.05～1: 1.
4, according to one of any described a kind of acaricide composition that contains spiral shell mite ester of claim 1～3, it is characterized in that described composition is missible oil, suspension emulsion, microemulsion or aqueous emulsion agent.
5, the purposes of the described composition of claim 1 in control oranges and tangerines, apple tree, cotton red spider insect.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101690481A (en) * | 2009-07-07 | 2010-04-07 | 深圳诺普信农化股份有限公司 | Spirodiclofen multiple emulsion and preparation method thereof |
| CN102334478A (en) * | 2011-11-16 | 2012-02-01 | 南通联农农药制剂研究开发有限公司 | Suspoemulsion containing Envidor and preparation methods thereof |
| CN103238605A (en) * | 2012-02-11 | 2013-08-14 | 张秋芳 | Acaricide composition containing spirodiclofen |
-
2008
- 2008-06-30 CN CNA2008101502048A patent/CN101297646A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101690481A (en) * | 2009-07-07 | 2010-04-07 | 深圳诺普信农化股份有限公司 | Spirodiclofen multiple emulsion and preparation method thereof |
| CN101690481B (en) * | 2009-07-07 | 2013-09-11 | 深圳诺普信农化股份有限公司 | Spirodiclofen multiple emulsion and preparation method thereof |
| CN102334478A (en) * | 2011-11-16 | 2012-02-01 | 南通联农农药制剂研究开发有限公司 | Suspoemulsion containing Envidor and preparation methods thereof |
| CN103238605A (en) * | 2012-02-11 | 2013-08-14 | 张秋芳 | Acaricide composition containing spirodiclofen |
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