CN101277674B - Stabilization of body-care and household products against degradation by UV radiation using merocyanine derivatives - Google Patents

Stabilization of body-care and household products against degradation by UV radiation using merocyanine derivatives Download PDF

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CN101277674B
CN101277674B CN 200680036374 CN200680036374A CN101277674B CN 101277674 B CN101277674 B CN 101277674B CN 200680036374 CN200680036374 CN 200680036374 CN 200680036374 A CN200680036374 A CN 200680036374A CN 101277674 B CN101277674 B CN 101277674B
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CN101277674A (en )
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芭芭拉·瓦格纳
奥利弗·赖克
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西巴特殊化学制品控股公司
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL AND VEGETABLE OILS, FATS, FATTY SUBSTANCES AND WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/162Organic compounds containing Si
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL AND VEGETABLE OILS, FATS, FATTY SUBSTANCES AND WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005Other compounding ingredients characterised by their effect
    • C11D3/0084Antioxidants; Free-radical scavengers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL AND VEGETABLE OILS, FATS, FATTY SUBSTANCES AND WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2093Esters; Carbonates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL AND VEGETABLE OILS, FATS, FATTY SUBSTANCES AND WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2096Heterocyclic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL AND VEGETABLE OILS, FATS, FATTY SUBSTANCES AND WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL AND VEGETABLE OILS, FATS, FATTY SUBSTANCES AND WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • C11D3/30Amines; Substituted amines ; Quaternized amines

Abstract

本发明描述了特定部花青衍生物用于保护身体护理产品和家用产品不受光解和氧化降解的用途。 The present invention describes the use of merocyanine derivatives for protecting specific body care products and household products from photolytic and oxidative degradation. 这些化合物具有优异的UV吸收剂性质。 These compounds have excellent UV absorbing properties.

Description

使用部花青衍生物使身体护理产品和家用产品稳定化防止UV辐射引起的降解 Merocyanine derivative for use body care products and household products stabilized against degradation caused by UV radiation

[0001] 本发明涉及所选择的光稳定剂用于保护身体护理产品和家用产品免受光解和氧化降解的用途。 [0001] The present invention relates to a light stabilizer for protecting a selected body care products and household products from photolytic and oxidative degradation use.

[0002] 近年来在化妆品制剂和家用产品中使用基于油和脂肪的天然物质的产品趋势增カロ,这也增加了脂肪和油的氧化降解的问题,导致产生酸败(rancidity)。 [0002] In recent years, the use in cosmetic formulations and household products based on natural substances product trends oils and fats increase ka ro, which also increases the problem of oxidation of fats and oils degradation, resulting in rancidity (rancidity). 乳液中几乎不会缺少天然油或不饱和脂肪酸。 The emulsion is hardly a lack of natural oils or unsaturated fatty acids. 氧化改变有时可能产生反应性代谢物,例如酮、醛、酸、环氧化物和脂过氧化物。 The reaction may occur by changing the oxidation metabolites, such as ketones, aldehydes, acids, epoxides, and lipid peroxides.

[0003] 结果,一方面在产品的气味方面有不期望的改变,另一方面可能得到改变皮肤耐受性(skin tolerance)的物质。 [0003] As a result, on the one hand undesired changes in odor of the product, on the other hand tolerance may be changed skin (skin tolerance) material. 自由基在皮肤上不受控制地形成,主要会促成多种病理调节(pathophysical modulation)(例如炎症、致癌作用(cancerogenesis)等)的引发和进展。 Uncontrolled free radical is formed on the skin, it will contribute to a variety of pathological main regulator (pathophysical modulation) (such as inflammation, carcinogenesis (cancerogenesis), etc.) initiation and progression.

[0004] 但是,氧化降解过程不仅仅发生在基于油和脂肪的天然物质的情况下。 [0004] However, oxidative degradation occurs not only in the case of oils and fats based on natural substances. 它们也发生于许多其它化妆品成分中,例如香料和芳香物质、维生素、着色剂等。 They also occur in a number of other cosmetic ingredients, such as fragrances and aromatic substances, vitamins, colorants and the like.

[0005] 为了防止氧化降解过程(光氧化、自动氧化),因而在化妆品和食品中使用所谓的抗氧化剂(AO)。 [0005] In order to prevent oxidative degradation processes (photo-oxidation, auto-oxidation), and thus a so-called antioxidant (AO) in cosmetics and foods. 这些抗氧化剂可分类成防止氧化的化合物(络合形成剂、还原剂等)和中断自由基链反应的化合物,例如2,6_ ニ叔丁基对甲酚(BHT)、丁基化羟基苯甲醚(BHA)、没食子酸酯如没食子酸丙酯(PG)或叔丁基氢醌(TBHQ)。 These antioxidants may be classified into a compound (a complexing agent, reducing agent) to prevent oxidation and free radical chain reaction of a compound of the interrupt, e.g. 2,6_ ni t-butyl-p-cresol (BHT), butyl hydroxyanisole ether (BHA), gallic acid esters such as propyl gallate (PG) or t-butyl hydroquinone (TBHQ). 但是,后ー类化合物常常不满足pH稳定性方面的要求以及光稳定性和温度稳定性方面的要求。 However, the compounds often does not meet the requirements ー claim temperature stability and light stability and stability in terms of pH.

[0006] 因而,这些容器中的活性物质由于自动氧化过程而不利地改变它们的性质。 [0006] Thus, the active substance in these containers due to the autoxidation processes detrimentally alter their properties. 这导致例如粘度的降低和颜色或气味的改变。 This reduction results in a change such as viscosity and color or odor.

[0007] 此外,近年来日益成长的产品趋势也导致用于化妆品制剂和家用产品的透明(玻璃、PET等)容器的使用増加。 [0007] Further, in recent years, the growing trend of the product also results in formulations for cosmetic and household products in a transparent (glass, PET, etc.) using the container plus zo. 虽然玻璃和普通塑料都在UV-B-范围内具有一定的固有吸收,但是在UV-A范围内的吸收是非常低的。 Although both glass and ordinary plastics have a certain inherent absorption in the UV-B- range, but absorbed in the UV-A range is very low.

[0008] 利用UV吸收对透明包装产品进行稳定化的各种技术得以广泛使用并且是公知的。 [0008] using the UV absorption of various technologies on transparent packaging product is stabilized widely used and are well known. 例如,与主要吸收UV-B的ニ苯甲酮类等其它吸收剂相比,宽谱带UV光稳定剂苯并三唑类由于它们具有非常好的UV-A和UV-B吸收性能,因而能提高产品的稳定性和保存期限。 For example, compared to other major absorbers of UV-B absorption ni benzophenones such broad band UV light stabilizer benzotriazoles due to their very good UV-A and UV-B absorbing properties, thus can improve the stability and shelf life of the product. 现今已知用于防止或延迟透明包装的产品光致褪色的最有效稳定剂例如是苯并三唑衍生物,以商标名Ciba TIN0GARD HS 或Ciba TIN0GARD TL 已知。 Products known today for preventing or delaying Transparent packaging photo fading most effective stabilizers are benzotriazole derivatives, for example, under the trade name Ciba TIN0GARD HS or Ciba TIN0GARD TL known.

[0009] 意想不到的是,已经发现基于部花青衍生物的特定光稳定剂具有杰出的UV吸收剂性质,并且因此适合用于产品保护。 [0009] Surprisingly, it has been found to have excellent properties based on the particular UV absorber light stabilizers merocyanine derivative, and is therefore suitable for product protection.

[0010] 因此,本发明涉及式(I)的部花青衍生物用于保护身体护理产品和家用产品免受光解和氧化降解的用途: [0010] Accordingly, the present invention relates to a merocyanine derivatives of formula (I) for the protection of body care products and household products from photolytic and oxidative degradation by:

[0011] [0011]

Figure CN101277674BD00061

[0012] L1 > L2或L3各自独立地为氣;轻基;C「C22烧基;C「C22烧氧基;C2-C22稀基;C2-C22炔基;c3-c12环烷基;c3-c12环烯基;c7-c2(l芳烷基^1-C2tl杂烷基;c3-c12环杂烷基(cycloheteroalkyl) ;C5_Cn 杂芳烧基;C6-C20芳基;C6-C2tl芳基-C2-C5亚烯基;C4_C9杂芳基;CN -(CH2)t-OR9 ;或COOR9 ; [0012] L1> L2 or L3 are each independently a gas; light-yl; C "burn C22-yl; C" burn C22 alkoxy; C2-C22 dilute group; C2-C22 alkynyl group; c3-c12 cycloalkyl; C3 -c12 cycloalkenyl; c7-c2 (l ^ 1-C2tl aralkyl heteroalkyl; c3-c12 cycloalkyl heteroalkyl (cycloheteroalkyl); C5_Cn burning heteroaryl group; C6-C20 aryl group; C6-C2tl aryl group -C2-C5 alkenylene; C4_C9 heteroaryl; CN - (CH2) t-OR9; or COOR9;

[0013] R4 是CN ;-COR7 -COOR7 -SO2R7 -CONR7R8 ; C1-C22 烷基;C2-C22 烯基;C2-C22 炔基;C3-C12环烷基;c3-c12环烯基;c7-c2(l芳烧基A-C2tl杂烷基;c3-c12环杂烷基;c5-cn杂芳烷基;C6-C20芳基;c「c12烷基羰基氨基-C6-C2tl芳基;c4-c9杂芳基; [0013] R4 is CN; -COR7 -COOR7 -SO2R7 -CONR7R8; C1-C22 alkyl; C2-C22 alkenyl; C2-C22 alkynyl; C3-C12 cycloalkyl; c3-c12 cycloalkenyl; C7- c2 (l burning aryl group A-C2tl heteroalkyl; c3-c12 cycloheteroalkyl; c5-cn heteroaralkyl; C6-C20 aryl group; C "c12 alkylcarbonylamino -C6-C2tl aryl group; C4 -c9 heteroaryl;

[0014] R5, R6, R7和R8各自独立地为氢;C「C22烷基、C2-C22烯基、C2-C22炔基;C3_C12环烷基;c3-c12 环烯基;c7-c2Q 芳烷基;cor9 ;-(CO)-COO-R9 ;C1-C20 杂烷基;c3-c12 环杂烷基;C5-Cn杂芳烧基;C6-C2(I 芳基!C1-C5 烧氧基-C6-C2tl 芳基;-(CH2)t-SO3H ;-(CH2)t-(CO) -OR9 ;-(CH2)t-0-C6-C10 芳基;-(CH2)vCOO-R9 ;C4-C9 杂芳基;-(CH2)U-SiR15R16R17 ;或基团-X-Sil ; [0014] R5, R6, R7 and R8 are each independently hydrogen; C "to C22 alkyl, C2-C22 alkenyl, C2-C22 alkynyl group; C3_C12 cycloalkyl; c3-c12 cycloalkenyl; c7-c2Q aryl alkyl; cor9 ;-( CO) -COO-R9; C1-C20 heteroalkyl; c3-c12 cycloheteroalkyl; C5-Cn heteroaryl group burn;! C6-C2 (I aryl-C1-C5 burning oxygen -C6-C2tl aryl group ;-( CH2) t-SO3H ;-( CH2) t- (CO) -OR9 ;-( CH2) t-0-C6-C10 aryl group ;-( CH2) vCOO-R9; C4-C9 heteroaryl ;-( CH2) U-SiR15R16R17; or a group -X-Sil;

[0015] R9 是氧;C「C22 烧基;C2_C22 稀基;C2_C22 块基;C3_C12 环烧基;C3_C12 环稀基;C7_C2Q 芳烷基;c「c2(l杂烷基;c3-c12环杂烷基;c5-cn杂芳烷基;c6-c2(l芳基;或C4-C9杂芳基;或 [0015] R9 is oxo; C "burn C22 group; C2_C22 dilute group; C2_C22 block group; C3_C12 burning cycloalkyl group; C3_C12 dilute cycloalkyl group; C7_C2Q aralkyl; C" c2 (l heteroalkyl; c3-c12 cycloheteroalkyl alkyl; c5-cn heteroaralkyl; c6-c2 (l aryl group; C4-C9 heteroaryl or aryl group; or

[0016] L1 和LpL1 和L3、L2 和LpL1 和R4、L2 和RpL1 和RpL2 和RpL3 和RpL3 和R5、R3 和R4> R1和R2> R7和R8> R5和R6可连接到一起形成1、2、3或4个碳环或N、O和/或S-杂环,其可进ー步与其它芳族环稠合,并且N-杂环中的每个N可是未取代的或被Rltl取代; [0016] L1 and LpL1 and L3, L2 and LpL1 and R4, L2 and RpL1 and RpL2 and RpL3 and RpL3 and R5, R3 and R4> R1 and R2> R7 and R8> R5 and R6 may be linked together to form 1,2 , 3 or 4 carbocyclic or N, O and / or S- heterocyclic ring, which ring may further be fused into ー with other aromatic, heterocyclic N- and N, but each unsubstituted or substituted Rltl ;

[0017] 并且每个烷基、烯基、炔基、环烷基或亚环烷基可是未取代的或被ー个或多个Rn取代; [0017] and each alkyl, alkenyl, alkynyl, cycloalkyl, alkylene or cycloalkyl may be unsubstituted or substituted with one or more Rn of ー;

[0018] 并且每个芳基、杂芳基、芳烷基、亚芳基、亚杂芳基或亚芳烷基可是未取代的或被ー个或多个R12取代; [0018] and each aryl, heteroaryl, arylalkyl, arylene, heteroarylene, or aralkylene may be unsubstituted or substituted ー one or more R12;

[0019] R10 是R13 ;C0R13 ;COOR13 ;或CONR13R14 ; [0019] R10 is R13; C0R13; COOR13; or CONR13R14;

[0020] R11 是齒素、OH ;NR15R16 ;O-R15 ;S-R15 ;O-CO-R15 ;C0_R15 ;氧代;硫羰基;CN ;COOR15 ;CONR15R16 ;SO2NR15R16 ;SO2R15 ;SO3R15 ;SiR15R16R17 ;0SiR15R16R17 ;P0R15R16 ;或基团-X-Sil ; [0020] R11 is a tooth element, OH; NR15R16; O-R15; S-R15; O-CO-R15; C0_R15; oxo; thiocarbonyl group; CN; SO2R15;; SO2NR15R16; SO3R15; SiR15R16R17; COOR15; CONR15R16 0SiR15R16R17; P0R15R16; or a group -X-Sil;

[0021 ] R12是C1-C12烷硫基、C3-C12环烷基硫基、C1-C12烯基硫基、C3-C12环烯基硫基、C1-C12烧氧基、C3-C12环烧氧基、C1-C12稀基氧基或C3-C12环稀基氧基,所述C1-C12烧硫基、C3-C12环烷基硫基、C1-C12烯基硫基、C3-C12环烯基硫基、C1-C12烷氧基、C3-C12环烷氧基、C1-C12烯基氧基或C3-C12环烯基氧基是未取代的或被一个或多个取代=R11 ;卤素;CN ;SH ;0H ;CH0 ;R18 ;OR18 ;SR18 ; C (R18) = CR19R20 ; O-CO-R19 ;NR18R19 ; CONR18R19 ; SO2NR18R19 ; SO2R18 ; COOR18 ; OCOOR18 ;NR18COR19 ;NR19COOR20 ;SiR15R16R17 ;0SiR15R16R17 ;P ( = 0) R19R20 ;或基团-X-Sil ; [0021] R12 is C1-C12 alkylthio, C3-C12 cycloalkyl group, C1-C12 alkenyl group, C3-C12 cycloalkenyl group, C1-C12 alkoxy burning, C3-C12 cycloalkyl burn alkoxy, C1-C12 group or dilute C3-C12 cycloalkyl group dilute group, a C1-C12 alkylthio burning, C3-C12 cycloalkyl group, C1-C12 alkenyl group, C3-C12 cycloalkyl alkenyl group, C1-C12 alkoxy, C3-C12 cycloalkoxy, C1-C12 alkenyl group or a C3-C12 cycloalkenyl group is unsubstituted or substituted by one or more substituents = R11; halogen; CN; SH; 0H; CH0; R18; OR18; SR18; C (R18) = CR19R20; O-CO-R19; NR18R19; CONR18R19; SO2NR18R19; SO2R18; COOR18; OCOOR18; NR18COR19; NR19COOR20; SiR15R16R17; 0SiR15R16R17; P (= 0) R19R20; or a group -X-Sil;

[0022] R13、R14、R15、R16、R17、R18、R19 和R2。 [0022] R13, R14, R15, R16, R17, R18, R19 and R2. 各自独立地为氢;(^-(:22烷基;C3_C12 环烷基;C2_C12烯基;C3-C12环烯基;C6-C14芳基;C4-C12杂芳基;c「c18芳烷基;或C5-C16杂芳烷基;或 Are each independently hydrogen; (^ - (: 22 alkyl; C3_C12 cycloalkyl; C2_C12 alkenyl; C3-C12 cycloalkenyl; C6-C14 aryl group; C4-C12 heteroaryl group; C "c18 aralkyl ; or C5-C16 heteroaryl group; or

[0023] R13和R14、R15和R16、R16和R17和/或R18和R19可连接到一起形成未取代的或C1-C4烷基取代的吡咯烷、哌啶、哌嗪或吗啉; [0023] R13 and R14, R15 and R16, R16 and R17 and / or R18 and R19 may be connected to form an unsubstituted or C1-C4 alkyl substituted with pyrrolidine, piperidine, piperazine or morpholine;

[0024] X是连接基团(linker);和 [0024] X is a linking group (Linker); and

[0025] Sil是硅烷部分,低聚硅氧烷部分或聚硅氧烷部分; [0025] Sil is a silane portion, oligosiloxane or polysiloxane moiety portion;

[0026] t是O至12的数; [0026] t is a number from O to 12;

[0027] u是I至12的数; [0027] u is a number from I to 12;

[0028] V是O至12的数; [0028] V is a number from O to 12;

[0029]如果 n = l,[0030] 则R1和R2各自独立地为氢;C「C22烧基;轻基-C1-C22烧基;C2_C22烯基;C2_C22块基;c3-c12环烷基;c3-c12环烯基;c7-c2(l芳烷基^1-C2tl杂烷基;c3-c12环杂烷基;c6-c2(l芳基; [0029] If n = l, [0030] then R1 and R2 are each independently hydrogen; C "burn C22 group; light burn-yl group -C1-C22; C2_C22 alkenyl group; C2_C22 block group; c3-c12 cycloalkyl ; c3-c12 cycloalkenyl; c7-c2 (l ^ 1-C2tl aralkyl heteroalkyl; c3-c12 cycloheteroalkyl; c6-c2 (l aryl group;

C5-C11杂芳烷基;C4-C9杂芳基;或式。 C5-C11 heteroaralkyl; C4-C9 heteroaryl; or formula.

Figure CN101277674BD00081

的基团; Group;

[0031] R21、R22、R23各自独立地为C1-C22烧基;或C1-C22烧氧基; [0031] R21, R22, R23 are each independently a C1-C22 group burning; burning or C1-C22 alkoxy;

[0032] A是连接至连接基团X的键; [0032] A is connected to the connecting group X is a bond;

[0033] R3 是CN ;NR5R6 -COR5 -COOR5 -SO2R5 ;-CONR5R6 ;C6-C20 芳基;或C4-C9 杂芳基; [0033] R3 is CN; NR5R6 -COR5 -COOR5 -SO2R5; -CONR5R6; C6-C20 aryl group; or C4-C9 heteroaryl;

[0034] P是O至100的数; [0034] P is a number from O to 100;

[0035] q是I至20的数; [0035] q is the number of I to 20;

[0036] s是O至4的数; [0036] s is a number from O to 4;

[0037]如果 n = 2, [0037] If n = 2,

[0038] 则R1和R2各自为选自C1-C5亚烷基的ニ价基团,其可被ー个或多个氧原子隔断;或 [0038] then R1 and R2 are each selected from C1-C5 divalent alkylene group of ni, which may be one or more oxygen atoms ー partition; or

[0039] R1和R2与所述氮原子一起形成六元杂环;并且同时R3如η = I时所定义;或 [0039] R1 and R2 together with the nitrogen atom form a six-membered heterocyclic ring; and R3 simultaneously are defined as η = I time; or

[0040] R3式-CO-V1-CrC12亚烷基-W1-*的ニ价基团,其中 [0040] R3 of formula -CO-V1-CrC12 alkylene group -W1- * ni is a divalent group, wherein

[0041] 星号表示连接至第二R3的键; [0041] The asterisk indicates the bond to the second R3;

[0042] V1 是-O-;或-NR7-;或直接键; [0042] V1 is -O-; or -NR7-; or a direct bond;

[0043] W1是连接至第二R3的连接基团,其中W1是直接键;或选自C1-C12亚烷基;或亚苯基;和 [0043] W1 is R3 is connected to the second connection group, wherein W1 is a direct bond; or a group selected from C1-C12 alkylene; or phenylene; and

[0044] 同时R1和R2如η = I时所定义; [0044] while R1 and R2 are as defined when η = I;

[0045]如果 η = 3, [0045] If η = 3,

[0046] 则R1, R2或R3之ー为三价基团; [0046] then R1, R2 or R3 is a trivalent group of ー group;

[0047]如果 η = 4, [0047] If η = 4,

Figure CN101277674BD00082

[0048] R1或R2是式-C1-C12亚烷基-W2—* (3) RvR2的基团,其中 [0048] R1 or R2 is a group of formula -C1-C12 alkylene -W2- * (3) RvR2 group, wherein

Figure CN101277674BD00083

[0049] 星号表示连接至第二、第三和第四R1ZiR2的键; [0049] The asterisk indicates that the connection to the second, third, and fourth R1ZiR2 bond;

[0050] W2 是*-0、; [0050] W2 is * -0 ,;

[0051] R3如η = I时所定义;或 [0051] R3 are as defined when η = I; or

Figure CN101277674BD00091

[0052] R3是式-CO-V1-C1-C12亚坑基-γ3—* <一(3) R3的基团,其中星号表示连接至第二 [0052] R3 is of formula -CO-V1-C1-C12 alkylene group pits -γ3- * <a group (3) R3, wherein the asterisk indicates that the connection to the second

Figure CN101277674BD00092

(2)、第三(3)和第四(4) R3的键;和 (2), third (3) and a fourth key (4) R3 is; and

[0053] W3 是 [0053] W3 is

Figure CN101277674BD00093

;或 ;or

[0054] R1 或R2 是式 [0054] R1 or R2 is of the formula

Figure CN101277674BD00094

的基团; Group;

[0055] 星号表示连接至第二、第三和第四R1A2的键; [0055] connected to the second asterisk indicates, third, and fourth R1A2 bond;

[0056] R24 是C「C22 烧基;或C1-C22 烧氧基。 [0056] R24 is C "burn C22 group; or C1-C22 alkoxy burn.

[0057] 术语“低聚硅氧烷”表示通式Si (R21) m[OSi (R22)]。 [0057] The term "oligosiloxane" represents the formula Si (R21) m [OSi (R22)]. 的基团;其中 Group; wherein

[0058] m 是0;1;或2, [0058] m is 0; 1; or 2,

[0059] ο 是3、2 或I;和 [0059] ο is 3,2 or I; and

[0060] m和ο之和是3;或 [0060] m is 3 and the sum ο; or

[0061] “低聚硅氧烷”是式(3a)、(3b)或(3c)的基团: [0061] "oligosiloxane" is of formula (3a), (3b) or (3c) of the group:

[0062] [0062]

^22 〒22 只21 ^21 ^21 ^ 22 ^ 21 ^ 21 〒22 only 21

r I Ί I , r |1Γ |1Γ I Ί r I Ί I, r | 1Γ | 1Γ I Ί

(3a) —O--Si—Α;或(3b) —Oi>)--—O-Si--—ο—G卜·^ ;或(3c) (3a) -O - Si-Α; or (3b) -Oi>) --- O-Si --- ο-G-Bu ^; or (3c)

R23 ^23 ^22 A R22 R23 ^ 23 ^ 22 A R22

* *

R I R I

r R21 (Ch2)s R2i r R21 (Ch2) s R2i

[0063] I r II「 Ii I 其中 [0063] I r II "Ii I in which

R?-r-Si—一O——Si---O——Si——O——Si-R59 R -r-Si- a O -? Si --- O - Si - O - Si-R59

22 ILI JpL I Jq 22 22 ILI JpL I Jq 22

rL rL rL R23[0064] A是连接至连接基团X的键; rL rL rL R23 [0064] A is connected to the connecting group X is a bond;

[0065] P是O至10的数; [0065] P is a number from O to 10;

[0066] q是I至10的数;和 [0066] q is a number from I to 10; and

[0067] V是O至I的数; [0067] V is the number of the O to I;

[0068] 在本申请的上下文中的术语“聚硅氧烷”是指通式(4a)或(4b)的基团: [0068] The term in the context of the present application "polysiloxane" refers to a radical of the formula (4a) or (4b) is:

Figure CN101277674BD00101

[0070] R21、R22和R23各自独立地为C1-C22烧基或C1-C22烧氧基; [0070] R21, R22 and R23 are each independently a C1-C22 group or a C1-C22 burn burn group;

[0071] A是连接至连接基团X的键; [0071] A is connected to the connecting group X is a bond;

[0072] s是4至250的数; [0072] s is a number of 4-250;

[0073] t是5至250的数;和 [0073] t is a number of 5-250; and

[0074] q是I至30的数; [0074] q is a number from I to 30;

[0075] 卤素是氯、溴、氟或碘,优选氟,更优选氟代烷基如三氟甲基、α,α,三氟こ基或全氟化烷基,如七氟丙基。 [0075] Halogen is chlorine, bromine, fluorine or iodine, preferably fluorine, and more preferably a fluoroalkyl group such as trifluoromethyl, α, α, trifluoro-ko or perfluorinated alkyl group, such as heptafluoropropyl.

[0076] 烧基、环烧基、烯基、烧叉基(alkylidene)或环烯基(cycloalkenyl)可为直链的或支化的,或者也为单环的或多环的。 [0076] The burn-yl, cycloalkyl burning, alkenyl, burning-yl (alkylidene) or cycloalkenyl (cycloalkenyl) may be linear or branched, or also monocyclic or polycyclic.

[0077] 烯基为例如直链C2-C12烯基或优选地,支化的C3-C12烯基。 [0077] alkenyl groups, for example, a straight chain C2-C12 alkenyl or preferably branched C3-C12 alkenyl group.

[0078] C1-C22烷基为例如甲基、こ基、正丙基、异丙基、正丁基、仲丁基、异丁基、叔丁基、正戊基、2-戊基、3-戊基、2,2_ ニ甲基丙基、正己基、正辛基、1,1,3,3-四甲基丁基、2-こ基己基、壬基、癸基、正十八烷基、二十烷基或十二烷基。 [0078] C1-C22 alkyl, for example methyl, ko group, n-propyl, isopropyl, n-butyl, sec-butyl, isobutyl, t-butyl, n-pentyl, 2-pentyl, 3 - pentyl, 2,2_ Ni-methylpropyl, n-hexyl, n-octyl, 1,1,3,3-tetramethylbutyl, 2-ko-ethylhexyl, nonyl, decyl, n-octadecyl base twenty or dodecyl.

[0079] C3-C12环烷基为例如环丙基、环丁基、环戊基、环己基、三甲基环己基、薄荷基(menthyl)、侦彳柏基(thujyl)、冰片基、I-金刚烷基或2-金刚烷基。 [0079] C3-C12 cycloalkyl group, for example, cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, trimethyl cyclohexyl, menthyl (menthyl), investigation left foot bogeys (thujyl), bornyl, the I - adamantyl or 2-adamantyl.

[0080] C2-C12烯基或C3-C12环烯基是指含有ー个或多个双键的不饱和烃基,例如こ烯基、稀丙基、丙稀~2~基、2_ 丁稀-I-基、3_ 丁稀-I-基、1,3- 丁ニ稀~2~基、2_环丁稀_1_基、2_戍稀-I-基、3_戍稀-2-基、2_甲基-I- 丁稀-3-基、2_甲基-3- 丁稀~2~基、 [0080] C2-C12 alkenyl or C3-C12 cycloalkenyl group refers to a unsaturated hydrocarbon ー or more double bonds, for example, an alkenyl group ko, dilute propyl, 2 ~ ~ propylene group, butoxy dilute 2_ - I- yl, but-3_ dilute -I- yl, 1,3-2 ~ yl ~ ni dilute, dilute _1_ 2_ cyclobutyloxy group, Shu dilute -I- group 2_, 3_ Shu dilute -2- group, 2_ -I- methyl-but-3-dilute, dilute ~ 2_ -3-methyl-2 - group,

3-甲基-2- 丁稀-I-基、1,4_戍ニ稀-3-基、2_环戍稀-I-基、2_环己稀-I-基、3-环己烯-I-基、2,4-环己ニ烯-I-基、I-对-薄荷烯-8-基、4 (10)-侧柏烯-10-基、2-降冰片稀_1_ 基、2,5-降冰片_■稀_1_ 基、7,7- _.甲基-2,4-降著_■稀_3~ 基(7,7-dimethyl-2, Dilute -I- methyl-2-butyl group, 3-1,4_ diluted ni Shu, Shu ring 2_ -I- group dilute, dilute 2_ -I- cyclohexyl group, 3-cyclohexyl -I- alkenyl group, 2,4-cyclohexene group -I- ni alkenyl, I- on - menthol-8-yl, 4 (10) - thujene 10-yl, 2-norbornyl dilute _1_ yl, 2,5-norbornadiene, dilute _1_ _ ■ yl, 7,7-_. ■ _ methyl-2,4-drop with dilute ~ _3-yl (7,7-dimethyl-2,

4-norcaradiene-3-yl)或选自己烯基、辛烯基、壬烯基、癸烯基或十二烯基的各种异构体。 4-norcaradiene-3-yl) or a group selected from hexene, the various isomers of octenyl, nonenyl, decenyl or dodecenyl group.

[0081] C7-C18芳烷基为例如苄基、2-苄基-2-丙基、β -苯基-こ基、9-芴基、α,α - ニ甲基节基、ω _苯基_ 丁基、ω -苯基-羊基、ω -苯基-十_■烧基或3-甲基-5- (I ',I ',3',3'-四甲基-丁基)-苄基。 [0081] C7-C18 aralkyl group such as benzyl, 2-benzyl-2-propyl, beta] - phenyl - ko-yl, 9-fluorenyl, α, α - methyl section Ni-yl, [omega] _ benzene _ butyl group, ω - phenyl - yl sheep, ω - phenyl - ■ _ ten burn-yl or 3-methyl -5- (I ', I', 3 ', 3'- tetramethyl - butyl ) - benzyl.

[0082] 所述C7-C18芳烷基部分可是未取代的或在芳烷基的在烷基部分以及芳基部分被取代,但是优选在芳基部分被取代。 [0082] The C7-C18 aralkyl moiety may be unsubstituted or substituted in the alkyl moiety in the aralkyl group and the aryl moiety, it is preferably substituted in the aryl moiety.

[0083] (C「C6)_烷叉基为例如亚甲基、1,1_亚こ基(ethyl-1-ene)或2,2_亚丙基(,propyl-2-ene)。 [0083] (C "C6) _ alkylidene group, for example, methylene, ethylene ko 1,1_ yl (ethyl-1-ene) or propylene 2,2_ (, propyl-2-ene).

[0084] C6-C14芳基为例如苯基、萘基、联苯基、2-芴基、菲基、蒽基或三联苯基。 [0084] C6-C14 aryl group, for example, phenyl, naphthyl, biphenylyl, 2-fluorenyl, phenanthryl, anthracenyl group, or a terphenyl group.

[0085] C4-C12杂芳基为例如具有4n+2个共轭Ji -电子的不饱和或芳族基团,例如2_噻吩基、2-呋喃基、2-吡啶基、2-噻唑基、2-〖恶唑基、2-咪唑基、异噻唑基、三唑基或者由噻吩环、呋喃环、吡啶环、噻唑环、囉唑环、咪唑环、异噻唑环、三唑环、吡啶环和苯环(它们是未取代的或被I至6个こ基、甲基、亚こ基和/或亚甲基取代)构成的任意其它环系,例如苯并三唑基。 [0085] C4-C12 heteroaryl group, for example, having 4n + 2 conjugated Ji - electronic unsaturated or aromatic groups, e.g. 2_ thienyl, 2-furyl, 2-pyridyl, 2-thiazolyl , 2 〖oxazolyl, 2-imidazolyl, isothiazolyl, triazolyl or a thiophene ring, a furan ring, a pyridine ring, a thiazole ring, La oxazole ring, an imidazole ring, isothiazole ring, a triazole ring, pyridine and benzene ring (which is unsubstituted or substituted by I to 6 ko, methyl, ko alkylene group and / or substituted methylene) any other ring system consisting of, for example, benzotriazole group.

[0086] C5-C16杂芳烷基为例如被C4-C8杂芳基基团取代的C1-C8烷基部分。 [0086] C5-C16 heteroaryl groups substituted with, for example, the C4-C8 heteroaryl group C1-C8 alkyl moiety.

[0087] 优选使用式⑴的化合物,其中 [0087] Preferred compounds of formula ⑴, wherein

[0088] L1. L2或L3各自独立地为氢;羟基A1-C5烷基,其可被ー个或多个氧原子隔断;COOR9 ;苯基,其可被卤素、C1-C5烷基、C1-C5烷氧基、三氟烷基、C2-C5烯基中的ー个或多个取代;C4-C9杂芳基;和 . [0088] L1 L2 or L3 are each independently hydrogen; hydroxy A1-C5 alkyl, which may be one or more oxygen atoms ー partition; COOR9; phenyl which may be substituted by halogen, C1-C5 alkyl, C1 -C5 alkoxy group, a trifluoromethyl group, or a plurality ー C2-C5 alkenyl group substituents; C4-C9 heteroaryl group;

[0089] R9如权利要求I中所定义;和 [0089] I R9 as defined in claim 1; and

[0090] η 是I ; [0090] η is I;

[0091] 并且更优选使用式(I)的化合物,其中 [0091] and the more preferable compound of formula (I), wherein

[0092] U、L2和L3各自独立地为氢、甲基、苯基;或-COOR9 ;其中 [0092] U, L2, and L3 are each independently hydrogen, methyl, phenyl; or -COOR9; wherein

[0093] R9 是C1-C5 烧基;和 [0093] R9 is C1-C5 burned group;

[0094] η 是I。 [0094] η is I.

[0095] 此外,使用式(I)的化合物,其中 [0095] Further, the compound of formula (I), wherein

[0096] L1和L2、或L1和L3、或L2和L3 —起形成选自义 [0096] L1 and L2, or L1 and L3, and L2 or L3 - Yi form selected from

Figure CN101277674BD00111
Figure CN101277674BD00112

价基团。 A divalent group.

[0097] 此外,优选使用式⑴的化合物,其中 [0097] Further, preferred compounds of formula ⑴, wherein

[0098] R1和R2各自独立地为C1-C12烷基;羟基-C1-C12烷基;苯基或苯基-C1-C5烷基,其 [0098] R1 and R2 are each independently C1-C12 alkyl; hydroxy -C1-C12 alkyl; phenyl or phenyl -C1-C5 alkyl, which

可被C1-C5烷基或SO3M中的一个或多个取代;或式 Which may be substituted with C1-C5 alkyl or SO3M one or more; or of formula

Figure CN101277674BD00113

的基团,其中 Group, wherein

^23 ^ 23

[0099] η 是I ; [0099] η is I;

[0100] 并且更优选式⑴的化合物,其中[0101 ] R1和R2各自独立地为C1-C4烷基; [0100] More preferred compounds of formula ⑴ and wherein [0101] R1 and R2 are each independently C1-C4 alkyl;

[0102] M是氢;或金属离子;和 [0102] M is hydrogen; or a metal ion; and

[0103] η 为I。 [0103] η is I.

[0104] 而且,优选使用式⑴的化合物,其中[0105] R1和R2—起形成选自; cQ:;和的ニ价基团。 [0104] Further, preferably used compounds of formula ⑴, wherein [0105] R1 and R2- together form selected; cQ :; ni and the divalent group.

Figure CN101277674BD00121

[0106] 此外,优选使用式(I)的化合物,其中 [0106] Further, preferably used compounds of formula (I), wherein

[0107] R3 和R4 各自独立地为CN ;C0R7 ;COOR7 ;CONR7R8 ;SO2R7 ;其中 [0107] R3 and R4 are each independently CN; C0R7; COOR7; CONR7R8; SO2R7; wherein

[0108] R7和R8各自独立地为C1-C22烷基;苯基;或基团-X-Sil ; [0108] R7 and R8 are each independently a C1-C22 alkyl; phenyl; or a group -X-Sil;

[0109] η是I;和 [0109] η is I; and

[0110] X和Sil如权利要求I中所定义; I as defined in [0110] X and Sil claim 1;

[0111] 并且更优选式⑴的化合物,其中 [0111] and more preferably a compound of formula ⑴, wherein

[0112] R3 和R4—起形成选 [0112] R3 and R4- together form selected from

Figure CN101277674BD00122

°)<^ ' ιΟ;和* l^s的ニ价碳环基团或ニ价杂 °) <^ 'ιΟ; and ni * l ^ s the divalent carbocyclic group or a divalent hetero ni

Figure CN101277674BD00123

环基团。 Cycloalkyl group.

[0113] 还优选使用式(I)的化合物,其中 Compound [0113] It is also preferable to use formula (I), wherein

[0114]も和し3形成选自 [0114] 3 mo shi formed and selected

Figure CN101277674BD00124

和OC* (り的 And OC * (ri of

ニ价基团。 Ni monovalent group.

[0115] 最优选使用式⑴的化合物,其中 [0115] The most preferred compound of formula ⑴, wherein

[0116] L1. L2或L3各自独立地为氢;羟基A1-C5烷基,其可被ー个或多个氧原子隔断;COOR9 ;苯基,其可被卤素、C1-C5烷基、C1-C5烷氧基、三氟烷基、C2-C5烯基中的ー个或多个取代;C4-C9杂芳基;或 . [0116] L1 L2 or L3 are each independently hydrogen; hydroxy A1-C5 alkyl, which may be one or more oxygen atoms ー partition; COOR9; phenyl which may be substituted by halogen, C1-C5 alkyl, C1 -C5 alkoxy group, a trifluoromethyl group, or a plurality ー C2-C5 alkenyl group substituents; C4-C9 heteroaryl; or

[0117] L1和L2,或L1和L3,或L2和L3 —起形成选自:DO; [0117] L1 and L2, or L1 and L3, and L2 or L3 - form a group selected from: DO;

〉,或丫^的_■价基团; >, Or Ah ^ _ ■ a monovalent group;

Figure CN101277674BD00125

[0118] R1和R2各自独立地为C1-C12烷基;羟基-C1-C12烷基;苯基或苯基-C1-C5烷基,其 [0118] R1 and R2 are each independently C1-C12 alkyl; hydroxy -C1-C12 alkyl; phenyl or phenyl -C1-C5 alkyl, which

Figure CN101277674BD00126

可被C1-C5烷基或SO3M中的一个或多个取代;或式—(CH2)r^i-R22的基团;或 It can be C1-C5 alkyl or one or more substitutions SO3M; or of formula - (CH2) r ^ i-R22 group; or

Figure CN101277674BD00127

[0119] R1和R2—起形成选自ぐ),( ),0广和、的ニ价基团; [0119] R1 and R2- together form selected gu), (), 0, and wide, the ni monovalent group;

Figure CN101277674BD00128

[0120] R3 和R4 各自独立地为CN ;C0R7 ;COOR7 ;CONR7R8 ;SO2R7 ;[0121] R7和R8各自独立地为C1-C22烷基;苯基;或基团-X-Sil ;或 [0120] R3 and R4 are each independently CN; C0R7; COOR7; CONR7R8; SO2R7; [0121] R7 and R8 are each independently a C1-C22 alkyl; phenyl; or a group -X-Sil; or

[0122] R3 和R4—起形成选自 [0122] R3 and R4- together form selected

Figure CN101277674BD00131

或ニ价杂环基团;或 Ni or divalent heterocyclic group; or

[0123] R2和L3形成选自 [0123] R2 and L3 are formed is selected from

Figure CN101277674BD00132

的二价基团;和 Divalent groups; and

[0124] R9、R21、R22、R23、X和Sil如权利要求I中所定义。 [0124] R9, R21, R22, R23, X and Sil are as defined in claim I.

[0125] 此外,优选式⑴的化合物,其中所述稳定剂对应于式(2a)、(2b)或(2c): [0125] Further, preferred compounds of formula ⑴, wherein said stabilizing agent corresponds to the formula (2a), (2b) or (2c):

[0126] [0126]

(2a) (2a)

Figure CN101277674BD00133

(2b) (2b)

Figure CN101277674BD00134

[0127] (2C) [0127] (2C)

Figure CN101277674BD00135

,其中R1、R2、R3、R4、L1、L2、L3、W1和W2 Wherein R1, R2, R3, R4, L1, L2, L3, W1 and W2

如式(1)中所定义。 As defined in formula (1).

[0128] 优选使用式(2a)的化合物,其中 [0128] Preferred compounds of formula (2a), wherein

[0129] R3是式-CO-V1-C1-C12亚烧基的基团,其中 [0129] R3 is of formula -CO-V1-C1-C12 alkylene group burned group, wherein

[0130] Vii-O;或-NH-; [0130] Vii-O; or -NH-;

[0131] W1是直接键A1-C4亚烷基;或亚苯基; [0131] W1 is a direct bond A1-C4 alkylene; or phenylene;

[0132] R1和R2各自独立地为C1-C12烷基; [0132] R1 and R2 are each independently C1-C12 alkyl;

[0133] L1, L2和L3各自独立地为氢;或C1-C5烷基;或 [0133] L1, L2 and L3 are each independently hydrogen; or C1-C5 alkyl; or

[0134] L3和R2 —起形成杂环; [0134] L3 and R2 - together form a heterocyclic ring;

[0135] R4 是CN ;C0R7 ; COOR7 ; CONR7R8 ; SO2R7 ;和 [0135] R4 is CN; C0R7; COOR7; CONR7R8; SO2R7; and

[0136] R7是C「C22烧基;或苯基。 [0136] R7 is C "burn C22 group; or a phenyl group.

[0137] 优选的式(2b)的化合物是下述的那些化合物,其中 [0137] Preferred compounds of formula (2b) are those compounds wherein

[0138] R1 是C1-C3 亚烧基; [0138] R1 is C1-C3 alkylene group burning;

[0139] L1, L2和L3各自独立地为氢;或C1-C5烷基;或[0140] L1和L3 —起形成杂环; [0139] L1, L2 and L3 are each independently hydrogen; or C1-C5 alkyl; or [0140] L1 and L3 - form a heterocyclo;

[0141] R2是氢;或C1-C5烷基; [0141] R2 is hydrogen; or C1-C5 alkyl;

[0142] W1是C1-C3亚烷基;或直接键; [0142] W1 is a C1-C3 alkylene; or a direct bond;

[0143] R3 和R4 各自独立地为CN ;C0R7 ;COOR7 ;CONR7R8 ;SO2R7 ;和 [0143] R3 and R4 are each independently CN; C0R7; COOR7; CONR7R8; SO2R7; and

[0144] R7和R8各自独立地为C1-C22烷基;或苯基。 [0144] R7 and R8 are each independently a C1-C22 alkyl; or phenyl.

[0145] 此外,优选使用(3a)或(3b)的化合物: [0145] Further, it is preferable to use (3a) or (3b) a compound of:

Figure CN101277674BD00141

中R1' R2、R3> R4> L1, L2、L3、W2和W3如权利要求I中所定义。 The R1 'R2, R3> R4> L1, L2, L3, W2 and W3 as claimed in claim I defined.

[0147] 更优选的式(3a)的化合物是下述的那些化合物,其中 Compound [0147] More preferred compounds of formula (3a) are those compounds wherein

[0148] L1, L2和L3各自独立地为氢;轻基A-C5烷基;或L1和L3 —起形成杂环; [0148] L1, L2 and L3 are each independently hydrogen; yl light A-C5 alkyl; or L1 and L3 - form a heterocyclo;

[0149] R1和R2各自独立地为氢;或C1-C12烷基; [0149] R1 and R2 are each independently hydrogen; or C1-C12 alkyl;

[0150] R3 是=^-CO-V1-C1-C12 亚烧基_林; [0150] R3 is = ^ - CO-V1-C1-C12 alkylene group _ burning forest;

[0151] 乂ェ是-。 [0151] qe S Factory is -. ;或-NH-;< ; Or -NH -; <

[0152] 胃2是式 [0152] Gastric 2 is of formula

Figure CN101277674BD00142

R3的四价基团 R3 is a tetravalent group

[0153] R4 是CN ;C0R7 ; COOR7 ; CONR7R8 ; SO2R7 ;和 [0153] R4 is CN; C0R7; COOR7; CONR7R8; SO2R7; and

[0154] R7和R8各自独立地为C1-C22烷基;或苯基。 [0154] R7 and R8 are each independently a C1-C22 alkyl; or phenyl.

[0155] 还优选使用聚合的化合物或低聚的化合物,其包括式(4) [0155] also use polymeric or oligomeric compound is preferably a compound comprising the formula (4)

Figure CN101277674BD00143

的结构 Structure

单元,其中 Unit, wherein

[0156] 至少ー个星号-标记的基团可连接至所述低聚的或聚合的基团;和LpLpLrR2和R4如式(I)中所定义。 [0156] at least ー asterisk - labeled groups may be attached to the oligomeric or polymeric group; and R4 and LpLpLrR2 formula (I) as defined above.

[0157] 式⑷的化合物是已知的,其实例披露于DE 3531383的第8_11页中。 [0157] The compound of formula ⑷ are known, examples of which are disclosed in pages 8_11 DE 3531383's.

[0158] 对本发明有用的部花青衍生物的实例列于下表: [0158] Examples of useful cyanine derivative unit of the present invention are listed in the following table:

[0159] [0159]

Figure CN101277674BD00151
Figure CN101277674BD00161
Figure CN101277674BD00171
Figure CN101277674BD00181

[0163] [0163]

Figure CN101277674BD00191
Figure CN101277674BD00201

[0165] [0165]

Figure CN101277674BD00211
Figure CN101277674BD00221

[0167] [0167]

Figure CN101277674BD00231
Figure CN101277674BD00241
Figure CN101277674BD00251
Figure CN101277674BD00261
Figure CN101277674BD00271
Figure CN101277674BD00281
Figure CN101277674BD00291
Figure CN101277674BD00301
Figure CN101277674BD00311
Figure CN101277674BD00321

[0177] 式(I)的化合物是已知的,例如可从W004/006878得知。 [0177] Compound of formula (I) are known, for example, known from W004 / 006878.

[0178] 但是对应于式(Γ)的化合物是新的,并且是本发明的另一方面目的: [0178] However, corresponding to formula (Gamma]) compounds are new and are another aspect of the present invention to:

Figure CN101277674BD00322

其中 among them

[0179] R3 是CN ;NR5R6 -COR5 -COOR5 -SO2R5 ;-CONR5R6 ;C6-C20 芳基;或C4-C9 杂芳基; [0179] R3 is CN; NR5R6 -COR5 -COOR5 -SO2R5; -CONR5R6; C6-C20 aryl group; or C4-C9 heteroaryl;

[0180] R4 是CN ;-COR7 -COOR7 -CONR7R8 ;C「C22 烷基;C2_C22 烯基;C2_C22 炔基;C3_C12 环烷基;c3-c12环烯基;c7-c2(l芳烷基A1-C2tl杂烷基;c3-c12环杂烷基;c5-cn杂芳烷基;c6-c2(l芳基A1-C12烷基羰基氨基-C6-C2tl芳基;c4-c9杂芳基; [0180] R4 is CN; -COR7 -COOR7 -CONR7R8; C "to C22 alkyl; C2_C22 alkenyl group; C2_C22 alkynyl group; C3_C12 cycloalkyl; c3-c12 cycloalkenyl; c7-c2 (l arylalkyl A1- C2tl heteroalkyl; c3-c12 cycloheteroalkyl; c5-cn heteroaralkyl; c6-c2 (l A1-C12 aryl group alkylcarbonylamino -C6-C2tl aryl group; c4-c9 heteroaryl;

[0181] R5、R6、R7和R8各自独立地为氢;C「C22烷基、C2-C22烯基、C2-C22炔基;C3_C12环烷基;c3-c12 环烯基;c7-c2Q 芳烷基;cor9 ;-(CO)-COO-R9 ;C1-C20 杂烷基;c3-c12 环杂烷基;C5-Cn杂芳烧基;C6-C2(I 芳基!C1-C5 烧氧基-C6-C2tl 芳基;-(CH2)t-SO3H ;-(CH2)t-(CO) -OR9 ;-(CH2)t-0-C6-C10 芳基;-(CH2)vCOO-R9 ;C4-C9 杂芳基;-(CH2)U-SiR15R16R17 ;或基团-X-Sil ; [0181] R5, R6, R7 and R8 are each independently hydrogen; C "to C22 alkyl, C2-C22 alkenyl, C2-C22 alkynyl group; C3_C12 cycloalkyl; c3-c12 cycloalkenyl; c7-c2Q aryl alkyl; cor9 ;-( CO) -COO-R9; C1-C20 heteroalkyl; c3-c12 cycloheteroalkyl; C5-Cn heteroaryl group burn;! C6-C2 (I aryl-C1-C5 burning oxygen -C6-C2tl aryl group ;-( CH2) t-SO3H ;-( CH2) t- (CO) -OR9 ;-( CH2) t-0-C6-C10 aryl group ;-( CH2) vCOO-R9; C4-C9 heteroaryl ;-( CH2) U-SiR15R16R17; or a group -X-Sil;

[0182] R9 是氢;C「C22 烷基;C2_C22 烯基;C2_C22 炔基;C3_C12 环烷基;C3_C12 环烯基;C7_CM芳烷基;c「c2(l杂烷基;c3-c12环杂烷基;c5-cn杂芳烷基;c6-c2(l芳基;或C4-C9杂芳基;或 [0182] R9 is hydrogen; C "to C22 alkyl; C2_C22 alkenyl group; C2_C22 alkynyl group; C3_C12 cycloalkyl; C3_C12 cycloalkenyl; C7_CM aralkyl; C" c2 (l heteroalkyl; c3-c12 cycloheteroalkyl alkyl; c5-cn heteroaralkyl; c6-c2 (l aryl group; C4-C9 heteroaryl or aryl group; or

[0183] L1和L3是H或可连接到一起形成1、2、3或4个碳环或N、O和/或S-杂环,其可进ー步与其它芳族环稠合,并且N-杂环中的每个N可是未取代的或被Rltl取代; [0183] L1 and L3 are H or may be connected to form a 2, 3 or 4 carbocyclic or N, O and / or S- heterocyclic ring, which may further into ー with other aromatic rings are fused, and N- heterocycle each may be unsubstituted or N-substituted Rltl;

[0184] 并且每个烷基、烯基、炔基、环烷基或亚环烷基可是未取代的或被ー个或多个R11取代; [0184] and each alkyl, alkenyl, alkynyl, cycloalkyl, alkylene or cycloalkyl may be unsubstituted or substituted ー one or more R11;

[0185] 并且每个芳基、杂芳基、芳烷基、亚芳基、亚杂芳基或亚芳烷基可是未取代的或被ー个或多个R12取代; [0185] and each aryl, heteroaryl, arylalkyl, arylene, heteroarylene, or aralkylene may be unsubstituted or substituted ー one or more R12;

[0186] R10 是R13 ;C0R13 ;COOR13 ;或CONR13R14 ; [0186] R10 is R13; C0R13; COOR13; or CONR13R14;

[0187] R11 是卤素、OH ;NR15R16 ;0_R15 ;S-R15 ;C0_R15 ;氧代;硫羰基;CN ;COOR15 ;CONR15R16 ;SO2NR15R16 ;SO2R15 ;SO3R15 ;SiR15R16R17 ;0SiR15R16R17 ;P0R15R16 ;或基团-X-Sil ; [0187] R11 is halogen, OH; NR15R16; 0_R15; S-R15; C0_R15; oxo; thiocarbonyl group; CN; SO2R15;; SO2NR15R16; SO3R15; SiR15R16R17; COOR15; CONR15R16 0SiR15R16R17; P0R15R16; or a group -X-Sil ;

[0188] R12是C1-C12烷硫基、C3-C12环烷基硫基、C1-C12烯基硫基、C3-C12环烯基硫基、C1-C12烧氧基、C3-C12环烧氧基、C1-C12稀基氧基或C3-C12环稀基氧基,所述C1-C12烧硫基、C3-C12环烧基硫基、C1-C12稀基硫基、C3-C12环稀基硫基、C1-C12烧氧基、C3-C12环烧氧基、C1-C12稀基氧基或C3-C12环烯基氧基是未取代的或被一个或多个基团取代=R11 ;卤素;CN ;SH ;0H ;CHO ;R18 ;0R18 ;SR18 ;C (R18) = CR19R20 ;O-CO-R19 ;NR18R19 ;CONR18R19 ;SO2NR18R19 ;SO2R18 ;COOR18,OCOOR18 ;NR18COR19 ;NR19COOR20 ;SiR15R16R17 ;0SiR15R16R17 ;P( = 0)R19R20 ;或基团-X-Sil ;[0189] R13、R14、R15、R16、R17、R18、R19 和R2。 [0188] R12 is C1-C12 alkylthio, C3-C12 cycloalkyl group, C1-C12 alkenyl group, C3-C12 cycloalkenyl group, C1-C12 alkoxy burning, C3-C12 cycloalkyl burn alkoxy, C1-C12 group or dilute C3-C12 cycloalkyl group dilute group, a C1-C12 alkylthio burn, burn C3-C12 cycloalkyl group group, C1-C12 alkylthio group lean, C3-C12 cycloalkyl dilute thio group, C1-C12 alkoxy burn, burn C3-C12 cycloalkyl group, a substituted C1-C12 group or dilute C3-C12 cycloalkenyl group is unsubstituted or substituted by one or more groups = R11; halogen; CN; SH; 0H; CHO; R18; 0R18; SR18; C (R18) = CR19R20; O-CO-R19; NR18R19; CONR18R19; SO2NR18R19; SO2R18; COOR18, OCOOR18; NR18COR19; NR19COOR20; SiR15R16R17; 0SiR15R16R17 ; P (= 0) R19R20; or a group -X-Sil; [0189] R13, R14, R15, R16, R17, R18, R19 and R2. 各自独立地为氢;。 Are each independently hydrogen;. 「。22烷基;C3_C12 环烷基;C2-C12烯基;C3-C12环烯基;C6-C14芳基;C4-C12杂芳基;c「c18芳烷基;或C5-C16杂芳烷基;或 ".22 alkyl; C3_C12 cycloalkyl; C2-C12 alkenyl; C3-C12 cycloalkenyl; C6-C14 aryl group; C4-C12 heteroaryl group; C" c18 aralkyl; or C5-C16 heteroaryl alkyl; or

[0190] R13和R14、R15和R16、R16和R17和/或R18和R19可连接至Ij一起形成未取代的或C「C4烷基取代的吡咯烷、哌啶、哌嗪或吗啉; [0190] R13 and R14, R15 and R16, R16 and R17 and / or R18 and R19 may be connected to form an unsubstituted or Ij C "C4 alkyl substituted with pyrrolidine, piperidine, piperazine or morpholine;

[0191] X是连接基团;和 [0191] X is a linking group; and

[0192] Sil是硅烷部分、低聚硅氧烷部分或聚硅氧烷部分; [0192] Sil is a silane portion, oligosiloxane or polysiloxane moiety portion;

[0193] t是O至12的数; [0193] t is a number from O to 12;

[0194] u是I至12的数; [0194] u is a number from I to 12;

[0195] V是O至12的数; [0195] V is a number from O to 12;

[0196]如果 n = l, [0196] If n = l,

[0197] 则R1和R2各自独立地为氢;C「C22烧基;轻基-C1-C22烧基;C2_C22烯基;C2_C22块基;c3-c12环烷基;c3-c12环烯基;c7-c2(l芳烷基^1-C2tl杂烷基;c3-c12环杂烷基;c6-c2(l芳基; [0197] R1 and R2 are each independently hydrogen; C "burn C22 group; light burn-yl group -C1-C22; C2_C22 alkenyl group; C2_C22 block group; c3-c12 cycloalkyl; c3-c12 cycloalkenyl; c7-c2 (l ^ 1-C2tl aralkyl heteroalkyl; c3-c12 cycloheteroalkyl; c6-c2 (l aryl group;

Figure CN101277674BD00331

C5-C11杂芳烧基A-C9杂芳基;或式Ii如—'丨并0ム如_4;的基团; Groups;; -; C5-C11 heteroaryl group burn A-C9 heteroaryl 'Shu and Rousseau 0 or Formula Ii such as _4

[0198] R21、R22、R23各自独立地为C1-C22烧基;或C1-C22烧氧基; [0198] R21, R22, R23 are each independently a C1-C22 group burning; burning or C1-C22 alkoxy;

[0199] P是O至100的数; [0199] P is a number from O to 100;

[0200] q是I至20的数; [0200] q is the number of I to 20;

[0201] s是O至4的数; [0201] s is a number from O to 4;

[0202] R3 是CN ;NR5R6 -COR5 -COOR5 -SO2R5 ;-CONR5R6 ;C6-C20 芳基;或C4-C9 杂芳基; [0202] R3 is CN; NR5R6 -COR5 -COOR5 -SO2R5; -CONR5R6; C6-C20 aryl group; or C4-C9 heteroaryl;

[0203]如果 n = 2, [0203] If n = 2,

[0204] 则R1和R2各自为选自C1-C5亚烷基的ニ价基团,其可被ー个或多个氧原子隔断;或 [0204] then R1 and R2 are each selected from C1-C5 divalent alkylene group of ni, which may be one or more oxygen atoms ー partition; or

[0205] R1和R2与所述氮原子一起形成六元杂环;并且同时R3如η = I时所定义;或 [0205] R1 and R2 together with the nitrogen atom form a six-membered heterocyclic ring; and R3 simultaneously are defined as η = I time; or

[0206] R3是式-CO-V1-CrC12亚烷基-W1-*的ニ价基团,其中 [0206] R3 is of formula -CO-V1-CrC12 alkylene group -W1- * ni is a divalent group, wherein

[0207] 星号表示连接至第二R3的键; [0207] asterisk indicates the bond to the second R3;

[0208] V1 是-O-;或-NR7-;或直接键; [0208] V1 is -O-; or -NR7-; or a direct bond;

[0209] W1是连接至第二R3的连接基团,其中W1是直接键;或选自C1-C12亚烷基;或亚苯基;和 [0209] W1 is R3 is connected to the second connection group, wherein W1 is a direct bond; or a group selected from C1-C12 alkylene; or phenylene; and

[0210] 同时R1和R2如η = I时所定义; [0210] while R1 and R2 are as defined when η = I;

[0211]如果 η = 3, [0211] If η = 3,

[0212] 则ル、R2或R3之ー为三价基团; [0212] is Hikaru, ー of R2 or R3 is a trivalent group;

[0213]如果 η = 4,[0214] 则R1或R2是式 [0213] If η = 4, [0214] then R1 or R2 is of the formula

Figure CN101277674BD00341

的基团,其中 Group, wherein

[0215] 星号表示连接至第二、第三和第四R1Z^R2的键; [0215] connected to the asterisk indicates second, third and fourth R1Z ^ R2 bond;

[0216] [0216]

Figure CN101277674BD00342

[0217] R3如n = I时所定义;或 [0217] R3 is defined as n = time I; or

[0218] R3是式 [0218] R3 is formula

Figure CN101277674BD00343

的基团,其中星号表示连接至第二 Group, where the asterisk indicates that the connection to the second

(2)、第三(3)和第四(4) R3的键;和 (2), third (3) and a fourth key (4) R3 is; and

[0219] W3 是 [0219] W3 is

Figure CN101277674BD00344

[0220]或 [0220] or

[0221] R1 或R2 是式 [0221] R1 or R2 is of the formula

Figure CN101277674BD00345

的基团; Group;

[0222] 星号表示连接至第二、第三和第四R1A2的键; [0222] connected to the asterisk indicates the second, third and fourth R1A2 bond;

[0223] R24 是C1-C22 烧基;或C1-C22 烧氧基; [0223] R24 is C1-C22 burn group; or C1-C22 alkoxy burning;

[0224] 其中基团H R3或R4中的至少之ー为硅有机化合物基团。 [0224] where the radicals H R3 or R4 is at least an organic compound of silicon ー group.

[0225] 式(I)的光稳定剂以及这些化合物与表1-3中所列的其它UV吸收剂、酚类抗氧化剂或非酹类抗氧化剂的混合物或与络合形成剂(complex former)的混合物,特别适合用于保护身体护理产品和家用产品不受光降解(photolytic degradation)。 [0225] The mixture of formula (I) and light stabilizer compounds and other UV absorbers Table 1-3 listed, phenolic antioxidant or antioxidants sprinkle or with a complexing agent (complex former) the mixture is particularly suitable for the protection of body care products and household products from light degradation (photolytic degradation).

[0226] 可与式(I)的化合物混合物使用的有机UV滤光材料的实例列于下表中: [0226] Examples of organic UV filter material with the use of a mixture of the compound of formula (I) are listed in the following table:

[0227] [0227]

Figure CN101277674BD00351
Figure CN101277674BD00361
Figure CN101277674BD00371
Figure CN101277674BD00381
Figure CN101277674BD00391
Figure CN101277674BD00401

[0233] [0233]

Figure CN101277674BD00411
Figure CN101277674BD00421

[0235] [0235]

Figure CN101277674BD00431
Figure CN101277674BD00441

[0237] 式(I)的化合物也可与例如在W000/25731中披露的酚类或内酯型抗氧化剂混合使用。 Compound [0237] Formula (I) may also be used, for example, disclosed in W000 / 25731 phenolic type antioxidants or lactone mixed.

[0238] 式(I)的化合物也可与如W003/103622中所披露的位阻胺光稳定剂(例如受阻硝酰羟胺和羟胺盐化合物)混合物使用。 Compound [0238] Formula (I) may also be with such W003 / 103622 disclosed in the hindered amine light stabilizers (e.g. hindered nitroxyl hydroxylamine and hydroxylamine salt compound) was used.

[0239] 个人护理用涂 [0239] Personal care Tu

[0240] 式(I)的部花青化合物可以作为単独的组分或者尤其是以与其它稳定剂的混合物的形式用于护肤剂、沐浴和淋浴添加剤、含有香料和芳香物质的制剂、护发产品、洁齿剂、除臭和止汗制品、美饰剂(decorative preparations)、光防护制剂和含活性成分的制品。 Portion cyanine compound [0240] Formula (I) may be alone or as a component of radiolabeling in particular in the form of a mixture with other stabilizers for skin care agents, bath and shower added Ji, preparations containing fragrances and fragrance, care hair products, dentifrices, deodorizing and antiperspirant product, decorative preparations (decorative preparations), light protection formulations and products containing the active ingredient.

[0241] 特别地,护肤剂是洁身油(body oil)、爽身水(body lotion)、洁身胶(bodygel)、护理霜(treatment cream)、护肤膏(skin protection ointment)、剃须制剂例如剃须泡沫或剃须胶、爽身粉(skin powders)例如婴儿爽身粉、保湿胶(moisturizing gel)、保湿喷剂(moisturizing spray)、清新护体喷剂(revitalizingbody sprays)、去皮肤角质胶(cellulite gels)和磨肤剂。 [0241] Specifically, the bidet skincare agent is an oil (body oil), body lotion (body lotion), bidet gum (bodygel), care cream (treatment cream), skin cream (skin protection ointment), shaving preparation e.g. shaving gel or shaving foam, powder (skin powders) such as baby powder, moisturizing gels (moisturizing gel), moisturizing sprays (moisturizing spray), fresh bodycare sprays (revitalizingbody sprays), to skin keratinocytes gel (cellulite gels) and grinding emollients.

[0242] 合适的沐浴和淋浴添加剂是淋浴凝胶、浴盐、泡沫浴剂和肥皂。 [0242] Suitable bath and shower additives are shower gels, bath salts, bubble baths and soaps.

[0243] 特别地,含有香料和芳香物质的制品是香水(scents)、香料、盥洗用香水和剃须液(须后制剂)。 [0243] In particular, products containing fragrances and fragrance perfume (Scents), perfumes, toilet waters and shaving lotions (aftershave preparations).

[0244] 合适的护发产品为例如人用和动物(尤其是犬)用的香波、毛发调理剂、用于定型和处理毛发的产品、烫发剂、美发喷剂和发腊、发用凝胶、发型固定剂(hair fixative)和染发剂或漂白剤。 [0244] Suitable hair-care products, for example, human and animals (in particular dogs) shampoo, a hair conditioner for treating hair and styling products, perming agents, hair sprays and hair wax, hair gel , hair fixatives (hair fixative) and hair dyeing or bleaching Ji.

[0245] 特别地,合适的洁齿剂是牙霜(tooth cream)、牙膏、漱ロ剂、口腔冲洗剂、防牙菌斑剂和假牙清洁剂。 [0245] In particular, suitable dentifrice a dental cream (tooth cream), toothpastes, rinses ro, oral rinses, anti-plaque agents, and cleaning agents for dentures.

[0246] 特别地,合适的美饰剂是唇膏、指甲油、眼影、睫毛膏、干和湿化妆品、胭脂、底粉、脱毛剂和晒黑液(suntan lotions)。 [0246] In particular, decorative preparations are suitable lipsticks, nail varnishes, eye shadows, mascaras, dry and moist make-up, rouge, powders, depilatory agents and suntan solution (suntan lotions).

[0247] 特别地,含有活性成分的合适化妆品制剂是激素制剂(hormonepreparations)、维生素制剂、植物提取物制剂(vegetable extract preparation)和抗菌制剂。 [0247] In particular, cosmetic formulations containing the active ingredient suitable to hormone preparations (hormonepreparations), vitamin preparations, vegetable extract preparations (vegetable extract preparation) and antibacterial agents.

[0248] 上述的身体护理产品可以是以下形式:霜膏(cream)、软膏、糊剂、泡沫体、凝胶、洗剂(lotion)、粉剂、美容品(make-ups)、喷剂(spray)、棒(sticks)或气溶胶。 [0248] The body care product may be in the form: cream (Cream), ointments, pastes, foams, gels, lotions (Lotion), powders, cosmetics (make-ups), sprays (Spray ), bar (sticks) or aerosols.

[0249] 它们优选含有式⑴的光稳定剂和,任选的其它UV吸收剂、位阻胺、络合剂和酚类或非酚类抗氧化剂。 [0249] They preferably contain the light stabilizers of formula ⑴ and, optionally, other UV absorbers, hindered amines, complexing agents and phenolic or non-phenolic antioxidant.

[0250] 因此,本发明也涉及包括至少ー种式(I)化合物的身体护理产品。 [0250] Accordingly, the present invention also relates to a body care product comprising at least ー compound of formula (I) are.

[0251] 式(I)化合物在身体护理产品和家用产品中存在的浓度为总制剂的约5至IOOOOppm,优选约10至约5000ppm,并且最优选约100至约lOOOppm。 Compound [0251] of formula (I) present in the body care products and household products in a concentration of from about 5 to total formulation IOOOOppm, preferably from about 10 to about 5000ppm, and most preferably from about 100 to about lOOOppm.

[0252] 本发明的化妆品组合物也可含有一种或多种下述的额外化合物。 The cosmetic composition [0252] The present invention may also contain one or more additional compounds described below.

[0253] 脂肪醇 [0253] fatty alcohols

[0254] 基于具有6-18、优选8-10个碳原子的脂肪醇的格尔伯特醇(Guerbetalcohol),其包括鲸蜡醇、硬脂醇、鲸蜡硬脂醇、油醇、辛基十二烷醇、C12-C15醇的苯甲酸酷、こ酰化羊毛脂醇等。 [0254] Guerbet alcohols based (Guerbetalcohol), which include cetyl alcohol, stearyl alcohol, cetyl stearyl alcohol, oleyl alcohol having 6 to 18, preferably fatty alcohols of 8-10 carbon atoms, octyl dodecanol, benzoate of C12-C15 alcohol cool, ko acylated lanolin alcohol.

[0255] 脂肪酸酯 [0255] fatty acid esters

[0256] 直链C6-C24脂肪酸与直链C3-C24醇的酷,支化的C6-C13羧酸与直链C6-C24脂肪醇的酷,直链C6-C24脂肪酸与支化醇尤其是2-こ基己醇的酷,羟基羧酸与直链或支化C6-C22脂肪醇的酯,特别是苹果酸ニ辛酷,直链和/或支化脂肪酸与多元醇(如丙ニ醇、ニ聚物ニ醇或三聚物三醇)和/或格尔伯特醇的酯,如己酸、辛酸、2-こ基己酸、癸酸、月桂酸、异十三烷酸、肉豆蘧酸、棕榈酸、棕榈油酸、硬脂酸、异硬脂酸、油酸、反油酸、洋芜荽子酸(petroselinic acid)、亚油酸、亚麻酸、桐酸、花生酸、二十碳_9_烯酸(gadoleicacid)、山箭酸和芥酸及其エ业级混合物(例如在天然脂肪和油的压カ脱除(pressure removal)中、在来自Roelen氧化合成的醛的还原中或在不饱和脂肪酸的ニ聚中得到),与醇如异丙醇、己醇、辛醇、2-こ基己醇、癸醇、月桂醇、异十三烷醇、肉豆蘧醇、鲸蜡醇、棕 [0256] C6-C24 straight chain fatty acids with cool linear C3-C24 alcohols, branched cool C6-C13 carboxylic acids with linear C6-C24 fatty alcohols, C6-C24 straight chain fatty acids with branched alcohols, especially cool 2- ko hexyl alcohol, hydroxycarboxylic acids with linear or branched fatty alcohol esters of C6-C22, especially dioctyl malate ni cool, linear and / or branched fatty acids with polyhydric alcohols (e.g. propan-Ni-ol , ni ni oligomers) and / or trimer triol esters of alcohols or Guerbet alcohols, such as caproic acid, caprylic acid, 2-ethylhexanoic acid group ko, capric acid, lauric acid, isotridecanoic acid, meat Qu beans acid, palmitic acid, palmitoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, parsley foreign sub acid (petroselinic acid), linoleic, linolenic, eleostearic, arachidic acid, ten carbon _9_ acid (gadoleicacid), and erucic acid, and Hill arrows industry grade mixtures Ester (e.g. natural fats and oils in the pressure removal of ka (pressure removal), the reduction in the oxidation of aldehydes from Roelen synthesized or in poly-unsaturated fatty acids obtained ni), with an alcohol such as isopropyl alcohol, hexanol, octanol, 2-hexyl group ko, decanol, lauryl alcohol, isotridecyl alcohol, myristoyl alcohol Qu, cetyl alcohol, brown 榈油醇(palmoleyl alcohol)、硬脂醇、异硬脂醇、油醇、反油醇(elaidyl alcohol)、洋芜荽子醇(petroselinyl alcohol)、亚油醇、亚麻醇、桐酉享(elaeostearyl alcohol)、花生醇、二十碳-9-烯醇(gadoleicacid)、山箭醇、瓢儿菜醇(erucyl alcohol)和巴惟醇(brassidylalcohol)及其エ业级混合物(例如在基于脂肪和油的エ业级甲基酯或来自Roelen氧化合成的醛的高压氢化中得到以及作为不饱和脂肪醇ニ聚中的单体馏分得到)的酷。 Palm oil alcohol (palmoleyl alcohol), stearyl alcohol, isostearyl alcohol, oleyl alcohol, elaidyl alcohol (elaidyl alcohol), parsley foreign sub-ol (petroselinyl alcohol), linoleyl alcohol, linolenyl alcohol, Tong unitary share (elaeostearyl alcohol ), peanut alcohol, gadoleic alcohol (gadoleicacid), mountain arrow alcohol, dish pans child alcohol (erucyl alcohol) and Pakistan but alcohol (brassidylalcohol) and Ester industry-grade mixtures thereof (for example, based on fats and oils ester industry grade and obtained as a methyl ester or unsaturated fatty alcohols cool ni polymerization of the monomer fraction obtained) in the high-pressure hydrogenation of aldehydes from Roelen oxide synthesis.

[0257] 上述酯油的实例是肉豆蘧酸异丙酷、棕榈酸异丙酯、硬脂酸异丙酯、异硬脂酸异丙酷、油酸异丙酯、硬脂酸正丁酷、月桂酸正己酷、油酸正癸酷、硬脂酸异辛酯、硬脂酸异壬酷、异壬酸异壬酯、棕榈酸2-こ基己酷、月桂酸2-己酷、硬脂酸2-己基癸酷、棕榈酸2-辛基十二烷基酯、油酸油基·酷、芥酸油基酷、油酸芥酯(erucyloleate)、芥酸芥酷、辛酸鲸蜡硬脂基酷、棕榈酸鲸蜡酯、硬脂酸鲸蜡酯、油酸鲸蜡酯、山嵛酸鲸蜡酯、こ酸鲸蜡酯、肉豆蘧酸肉豆蘧酯、山嵛酸肉豆蘧酯、油酸肉豆蘧酯、硬脂酸肉豆蘧酯、棕榈酸肉豆蘧酯、乳酸肉豆蘧酷、ニ辛酸丙ニ醇酯/ ニ癸酸丙ニ醇酯、庚酸硬脂酷、苹果酸ニ异硬脂酷、羟基硬脂酸辛酯 Examples [0257] The ester oils are isopropyl cool myristoyl Qu acid, isopropyl palmitate, isopropyl stearate, isopropyl isostearate cool, isopropyl oleate, n-butyl stearate, cool , n-hexyl laurate cool, cool n-decyl oleate, isooctyl stearate, isononyl stearate, cool, isononyl isononanoate, ethylhexyl palmitate, 2 ko cool, 2-hexyl laurate cool, hard 2-hexyl decyl palmitate cool, palmitate, 2-octyldodecyl oleate, oleyl · cool, cool oleyl erucamide, erucyl oleate (erucyloleate), mustard cool erucic, cetyl octanoate hard cool aliphatic group, cetyl palmitate, cetyl stearate, cetyl oleate, cetyl behenate, cetyl esters ko, myristoyl Qu Qu myristoyl acid esters, behenic acid nutmeg Qu oleate myristoyl Qu stearate myristoyl Qu palmitate myristoyl Qu lactate, myristoyl Qu cool, ni ni propyl octanoate ester / ni ni propyl decanoate esters, stearyl heptanoate cool, cool, isostearyl malate ni, hydroxy octyl stearate

坐寸ο Sit inch ο

[0258] 包括甘油酯和衍生物的天然或合成的甘油三酯类 [0258] and include natural or synthetic glyceride derivatives are triglycerides

[0259] 甘油ニ酯或甘油三酷,基于C6-C18脂肪酸与其他醇的反应而改性的(三(辛酸/癸酸)甘油酷,麦芽甘油酯等)。 [0259] Ni glycerol esters or triglycerides cool, C6-C18 fatty acids based on the reaction with other alcohols and modified (tri (caprylic acid / capric acid) glyceryl cool, wheat germ glycerides, etc.). 聚甘油(聚甘油(η)基)的脂肪酸酯类如癸酸聚甘油(4)酷,异硬脂酸聚甘油(2)酯等,或蓖麻油、氢化植物油、甜杏仁油、麦芽油(wheat germ oil)、芝麻油、氢化棉籽油、椰子油、鳄梨油、玉米油、氢化蓖麻油、牛油树脂(shea butter)、可可油、豆油、貂油(mink oil)、向日葵油、红花油、澳洲坚果油、橄榄油、氢化牛油、杏仁油、棒子油、琉璃苣油(borago oil)等。 Polyglycerin (polyglyceryl ([eta]) yl) fatty acid esters such as capric acid, polyglyceryl (4) cool, polyglyceryl isostearate (2) ester, or castor oil, hydrogenated vegetable oil, sweet almond oil, wheat germ oil ( wheat germ oil), sesame oil, hydrogenated cottonseed oil, coconut oil, avocado oil, corn oil, hydrogenated castor oil, shea butter (shea butter), cocoa butter, soybean oil, mink oil (mink oil), sunflower oil, safflower oil, macadamia nut oil, olive oil, hydrogenated tallow, apricot kernel oil, stick oil, borage oil (borago oil) and the like.

[0260]魈 [0260] elf

[0261] 包括长链酸和醇的酯以及具有似蜡性质的化合物,如巴西棕榈蜡、蜂蜡(白蜡或黄蜡)、羊毛脂蜡、小烛树蜡、地蜡、日本蜡、石蜡、微晶蜡、纯地蜡、鲸蜡硬脂基酯蜡(cetearyl esters wax)、合成蜂腊等。 [0261] comprising a long-chain acids and alcohols as well as compounds having wax-like properties, such as carnauba wax, beeswax (white wax, or yellow wax), lanolin wax, candelilla wax, ozokerite, japan wax, paraffin wax, microcrystalline wax, ceresin, cetearyl ester wax (cetearyl esters wax), synthetic beeswax and the like. 此外,亲水腊如鲸腊硬脂醇或偏甘油酷。 Further, hydrophilic wax such as cetearyl alcohol or partial glycerol cool.

[0262] 珠光赔(pearlescent wax) [0262] Pearlescent compensation (pearlescent wax)

[0263] 亚烷基ニ醇酷,尤其是ニ硬脂酸こニ醇酯;脂肪酸链烷醇酰胺,尤其是椰油脂肪酸ニこ醇酰胺;偏甘油酷,尤其是硬脂酸单甘油酯;多价的、不饱和的或羟基取代的羧酸与具有6-22个碳原子的脂肪醇的酷,尤其是酒石酸的长链酯;脂肪物质,例如脂肪醇、脂肪酮、脂肪醛、脂肪醚和脂肪碳酸酯,其总共具有至少24个碳原子,尤其是月桂酮和ニ硬脂基醚;脂肪酸,如硬脂酸、羟基硬脂酸或山嵛酸,具有12-22个碳原子的氧化烯与具有12-22个碳原子的脂肪醇和/或具有2-15个碳原子和2-10个羟基的多元醇的开环产物,及其混合物。 [0263] Ni alcohol alkylene cool, especially ko ni ni stearic acid esters; fatty acid alkanolamides, especially coco fatty acid alkanolamide ni ko; partial glycerol cool, especially stearic acid monoglyceride; multivalent, unsaturated, or hydroxy-substituted carboxylic acids with fatty alcohols having 6-22 cool carbon atoms, especially long-chain esters of tartaric acid; fatty substances, for example fatty alcohols, fatty ketones, fatty aldehydes, fatty ethers and fatty carbonates, which in total have at least 24 carbon atoms, especially laurone and Ni stearyl ether; fatty acids such as stearic acid, hydroxystearic acid or behenic acid, having 12 to 22 carbon atoms in the oxide alkenyl with fatty alcohols having 12 to 22 carbon atoms and / or ring-opened product of a polyol having 2 to 15 carbon atoms and 2 to 10 hydroxyl groups, and mixtures thereof.

[0264] 烃油 [0264] Hydrocarbon oils

[0265] 矿物油(轻质或重质),凡士林(黄凡士林或白凡士林),微晶蜡,链烷化合物和异构链烷化合物,氢化的异构链烷分子如聚癸烯和聚丁烯,氢化聚异丁烯,角鲨烷,异十六烷,异十二烷以及其他来自植物和动物界的其他化合物。 [0265] Mineral oil (light or heavy), petrolatum (white petrolatum or yellow petrolatum), microcrystalline wax, paraffinic and isoparaffinic compounds compounds, hydrogenated isoparaffinic molecules as polydecenes and polybutene alkenyl, hydrogenated polyisobutene, squalane, isohexadecane, isododecane and others from plant and animal compounds other sector.

[0266] 硅酮或硅氧烷类(有机取代的聚硅氧烷) [0266] silicones or siloxanes (organosubstituted polysiloxanes)

[0267] ニ甲聚硅氧烷,甲基苯基聚硅氧烷,环状硅酮,以及氨基-、脂肪酸_、醇_、聚醚_、环氧_、氟_、苷-和/或烷基改性的硅酮化合物,其在室温下可以呈液体或树脂形式。 [0267] A Ni polysiloxanes, methylphenyl polysiloxanes, cyclic silicones, and also amino- -, _ fatty acids, alcohols _, _ polyethers, epoxy _, _ fluorine, glycoside - and / or alkyl-modified silicone compounds, which may be in the form of liquid or resin at room temperature. 线性聚娃氧烧,ニ甲聚娃氧烧(Dow Corning 200 fluid, Rhodia Mirasil DM), ニ甲聚娃氧烧醇,环状娃酮流体,环五娃氧烧类(cyclopentasiloxanes)挥发物(Dow Corning 345 fluid),苯基三甲基聚娃氧烧(Dow Corning 556 fluid)。 Linear polyethylene oxide burn baby, baby ni A polyethylene oxide burn (Dow Corning 200 fluid, Rhodia Mirasil DM), ni A polyethylene oxide burn baby alcohols, cyclic ketones fluid baby, baby ring oxygen fired five classes (cyclopentasiloxanes) volatiles (Dow Corning 345 fluid), phenyltrimethicone baby oxide burn (Dow Corning 556 fluid). 同样合适的是ニ甲基娃油,其是具有平均链长200-300个ニ甲基硅氧烷单元的ニ甲聚硅氧烷与氢化硅酸盐的混合物。 Also suitable are methyl ni baby oil, which is having an average chain length ni methylsiloxane units 200-300 Ni A mixture of polysiloxane and hydrogenated silicates. Todd等人对合适的挥发性硅油的详细研究可以另外在Cosm. Toil. 91,27(1976)中找到。 Todd, who detailed study of suitable volatile silicone oil may additionally be found in Cosm. Toil. 91,27 (1976).

[0268] 氟化油或全氟化油 [0268] perfluorinated oils or fluorinated oils

[0269] 全氟己烷、ニ甲基环己烷、こ基环戊烷、聚全氟代甲基异丙基醚。 [0269] perfluorohexane, ni methylcyclohexane, cyclopentane ko, poly perfluoro isopropyl ether.

[0270] 乳化剂 [0270] Emulsifier

[0271] 可以将任何常用的乳化剂用于所述组合物中。 [0271] Any conventional emulsifier may be used in the composition. 乳化剂体系例如可以包含:羧酸及其盐:钠、钾和铵的碱性皂,钙或镁的金属皂,有机基皂如月桂酸、棕榈酸、硬脂酸和油酸等。 Emulsifier systems may comprise for example: carboxylic acids and their salts: sodium, potassium and ammonium alkaline soap, metallic soap of calcium or magnesium, an organic-based soaps such as lauric acid, palmitic acid, stearic acid and oleic acid. 烷基磷酸盐或磷酸酷,酸式磷酸盐,磷酸ニこ醇胺,鲸蜡基磷酸钾。 Alkyl phosphate or cool, acid phosphate, ni ko alcohol amines, potassium cetyl phosphate. こ氧基化羧酸或聚こニ醇酷,PEG-n丙烯酸酷。 Alkoxylated carboxylic or ko ko ni cool alcohol, PEG-n acrylate cool. 具有8-22个碳原子的直链脂肪醇,由2-30mol氧化こ烯和/或由0-5mol氧化丙烯与具有12-22个碳原子的脂肪酸和烷基中具有8_15个碳原子的烷基酚所支化。 Linear fatty alcohols having 8 to 22 carbon atoms, a 2-30mol ko alkylene oxide and / or propylene oxide alkyl having a 0-5mol with fatty acids and alkyl groups having 12-22 carbon atoms in the carbon atoms 8_15 the phenol branched. 脂肪醇聚ニ醇醚如月桂基聚氧こ烯(η)醚、鲸蜡硬脂基聚氧こ烯(η)醚、硬脂基聚氧こ烯(η)醚、油基聚氧こ烯(η)醚。 Ni fatty alcohol polyglycol ethers such as laureth-en-ko ([eta]) ether, stearyl polyoxyethylene cetyl ko-ene ([eta]) ether, stearyl polyoxyethylene ko-ene ([eta]) ether, polyoxyethylene oleyl alkenyl ko ([eta]) ether. 脂肪酸聚ニ醇醚如PEG-n硬脂酸酷、PEG-n油酸酷、PEG-n椰油酸酷。 Fatty acid polyglycol ethers such as PEG-n ni cool stearate, PEG-n oleate cool, cool PEG-n cocoate. 单酸甘油酯和多元醇酷。 Mono- and polyhydric alcohols cool. l-30mol氧化こ烯与多元醇的加成产物的C12-C22脂肪酸单酯和ニ酷。 ko l-30mol alkylene oxide addition products of polyhydric alcohols C12-C22 fatty acid mono- and Ni cool. 脂肪酸与聚甘油酯如单硬脂酸甘油酷,ニ异硬脂酸ニ异硬脂酰基聚甘油(3)酷,ニ异硬脂酸聚甘油(3)酷,ニ异硬脂酸三甘油酷,倍半异硬脂酸聚甘油(2)酷或聚甘油基ニ聚体化物(polyglyceryl dimerates)。 Fatty acid and polyglycerol ester such as monostearate glycerol cool, ni ni isostearyl isostearate, polyglyceryl (3) cool, ni polyglyceryl isostearate (3) cool, cool ni triglycerol isostearate , sesquiisostearate polyglyceryl (2), or polyglyceryl cool ni mer compound (polyglyceryl dimerates). 来自多个上述物质种类的化合物的混合物也是适合的。 A mixture of compounds from a plurality of types of the foregoing are also suitable. 脂肪酸聚ニ元醇酯如单硬脂酸ニ甘醇酯,脂肪酸与聚こニ醇酯,脂肪酸与鹿糖酯如鹿糖酯(sucro esters),甘油与鹿糖酯如鹿糖甘油酷。 Fatty acid esters such as polyethylene monoalcohol ni ni glycol monostearate, fatty acid and polyethylene ko ni alcohol esters, sugar esters of fatty acids such as deer and deer sugar esters (sucro esters), glycerol and sugar esters such as deer deer sugar glycerol cool. 山梨糖醇和脱水山梨糖醇,具有6-22个碳原子的饱和的或不饱和的脂肪酸和氧化こ烯加成产物的脱水山梨糖醇单酯和ニ酷。 Sorbitol and sorbitan alcohols having 6-22 carbon atoms, saturated or unsaturated fatty acids and addition products of alkylene oxide ko dehydrated sorbitan monoesters and Ni cool. 聚山梨酸酯-η系列,脱水山梨糖醇酯如倍半异硬脂酸脱水山梨糖醇酯,聚氧乙烯(6)醚脱水山梨糖醇异硬脂酸酷,聚氧こ烯醚(10)脱水山梨糖醇月桂酸酷,聚氧こ烯(17)醚脱水山梨糖醇ニ油酸酷。 Polysorbate -η series, sorbitan esters such as sesquiisostearate, sorbitan esters, polyoxyethylene (6) sorbitan ether alcohols cool isostearate, polyoxyethylene alkenyl ethers ko (10 ) sorbitan monolaurate cool alcohols, polyoxyethylene ko-ene (17) sorbitan ether alcohols ni oleic cool. 葡萄糖衍生物,C8-C22烷基单苷和低聚苷以及こ氧基化类似物,其中葡萄糖优选作为糖组分。 Glucose derivatives, C8-C22 alkyl mono- and oligoglycoside ko glycosides and ethoxylated analogues with glucose being preferred as the sugar component. 0/W乳化剂如甲基葡萄糖聚氧こ烯(20)醚倍半硬脂酸酯(methyl gluceth-20 sesquistearate),硬脂酸脱水山梨糖醇酷/鹿糖椰油酸酯,甲基葡萄糖倍半硬脂酸酷,鲸蜡硬脂醇/鲸蜡硬脂葡糖苷。 0 / W emulsifiers such as methyl glucose polyoxyethylene ko-ene (20) ether sesquistearate (methyl gluceth-20 sesquistearate), sorbitan stearate, sorbitan cool / Deer sugar cocoate, methyl glucose cool sesquistearate, cetearyl alcohol / cetearyl glucoside. W/0乳化剂如甲基葡萄糖ニ油酸酯/甲基葡萄糖异硬脂酸酷。 W / 0 emulsifiers such as methyl glucose dioleate Ni / methyl glucose isostearate cool. 硫酸酷(盐)和磺化衍生物,ニ烷基磺基琥珀酸酷,琥珀酸ニ辛酷,烧基月桂基磺酸酯,直链磺化链烧烃,磺化四聚丙烯磺酸酯(sulfonatedtetraproplynesulfonate),月桂基硫酸钠,月桂基硫酸铵和月桂基硫酸こ醇胺,月桂基醚硫酸盐,月桂基聚氧こ烯醚硫酸钠,磺基琥拍酸盐,こ酰基轻こ基磺酸盐(acetyl isothionate),链烧醇酰胺硫酸盐,牛磺酸盐(taurines),甲基牛磺酸盐,咪唑硫酸盐。 Cool sulfuric acid (salt) and sulfonated derivatives, alkyl sulfosuccinate cool ni, ni octyl succinic cool, burning yl lauryl sulfonate, linear sulfonated burning hydrocarbon chain, sulfonated tetrapropylene sulfonate (sulfonatedtetraproplynesulfonate), sodium lauryl sulfate, ammonium lauryl sulfate and sodium lauryl sulfate ko alcohol amines, lauryl ether sulfate, polyoxyethylene lauryl ether sulfate ko alkenyl, sulfo succinate salts shot, ko ko light-acyl sulfonamide salt (acetyl isothionate), burning chain alcohol sulphate amide, taurates (taurines), methyl taurate, imidazole sulfates. 胺衍生物,胺盐,こ氧基化胺,具有含杂环的链的氧化物胺,如烧基咪唑啉,卩比唳衍生物,异喹啉(isoquinoteines),鲸腊基吡啶鎗氯化物,鲸蜡基吡啶鎗溴化物,季铵化合物如鲸蜡基三甲基溴化铵(CTBA),硬脂基烧铵(stearyl alkonium)。 Amine derivatives, amine salts, ko alkoxylated amines, amine oxides having chain-containing heterocycle, such as burning imidazoline, Jie Li ratio derivatives, isoquinoline (isoquinoteines), cetyl pyridinium chloride gun , cetyl pyridinium bromide gun, quaternary ammonium compounds such as cetyl trimethyl ammonium bromide (the CTBA), stearyl ammonium burning (stearyl alkonium). 酰胺衍生物,链烧醇酰胺如酰胺DEA,こ氧基化酰胺如PEG_n酰胺,oxydiamides。 Amide derivatives, alcohols burning chain amides such as DEA, ethoxylated amides such as PEG_n ko amides, oxydiamides. 聚硅氧烷/聚烷基/聚醚共聚物及其衍生物,ニ甲聚硅氧烷,共聚醇,硅酮聚氧こ烯共聚物,娃酮ニ醇共聚物。 Polysiloxane / polyalkyl / polyether copolymers and derivatives thereof, polysiloxane A Ni, copolyols, silicone polyethylene oxide copolymer ko, baby ni ketone alcohol copolymer. 丙氧基化的或POE-η醚(Meroxapols), Polaxamers或聚(氧こ烯)m-嵌段-聚(氧丙烯)η-嵌段(氧こ烯)。 Propoxylated ethers or POE-η (Meroxapols), Polaxamers or poly (alkylene oxide ko) m- block - poly (oxypropylene) block eta-(alkylene oxide ko). 两性离子表面活性剤,其分子中带有至少ー个季铵基团和至少ー个羧酸根和/或磺酸根。 Zwitterionic surfactants Ji, having in its molecule at least one quaternary ammonium group ー and ー least one carboxylate and / or sulfonate. 特别适合的两性离子表面活性剂是甜菜碱,如N-烧基-N, N-ニ甲基铵甘氨酸盐,椰油烧基ニ甲基铵甘氨酸盐,N-酰基氨基丙基-N,N- ニ甲基铵甘氨酸盐,椰油酰氨基丙基ニ甲基铵甘氨酸盐和2-烷基-3-羧基甲基-3-羟基こ基咪唑啉,其各自在烷基或酰基中具有8-18个碳原子,以及椰油酰基氨基こ基羟基こ基羧基甲基甘氨酸盐,N-烷基甜菜碱,N-烷基氨基甜菜碱。 Particularly suitable zwitterionic surfactants are betaines, such as N- burning yl -N, N- dimethylammonium glycinates ni, ni coco methyl ammonium group burn glycinate, N- acylaminopropyl--N, N - Ni-ammonium glycinate, cocamidopropyl Ni-ammonium glycinate and 2-alkyl-3-carboxy-3-hydroxy imidazoline ko, each having 8 at the alkyl or acyl to 18 carbon atoms, and coco hydroxy ko ko acylamino group carboxymethyl glycinate, N- alkylbetaines, N- alkylamino betaines. 烷基咪唑啉,烷基肽(alkyl peptides),脂氨基酸(lipoamino acids),自乳化的喊以及在KF DePolo,A shorttextbookof cosmetology,第8章,表8-7,第250-251页中描述的化合物。 Alkyl imidazolines, alkyl peptides (alkyl peptides), aliphatic amino acids (lipoamino acids), and in self-emulsifying shouting KF DePolo, A shorttextbookof cosmetology, Chapter 8, Table 8-7, page 250-251 described compound.

[0272] 非离子乳化剂如聚氧こ烯(6)蜂蜡(和)硬脂酸聚氧こ烯(6)酷(和)异硬脂酸聚甘油(2)酯[Apifac],硬脂酸甘油酯(和)硬脂酸聚氧こ烯(100)酷。 [0272] nonionic emulsifiers such as polyoxyethylene ko-ene (6) beeswax (and) stearate, polyoxyethylene ko-ene (6) cool (and) polyglyceryl isostearate (2) ester [Apifac], stearate glycerides (and) alkenyl ko polyoxyethylene stearate (100) cool. [Arlacell65],聚氧こ烯(5)甘油醚硬脂酸酯[Arlatone 983 S],油酸脱水山梨糖醇酯(和)蓖麻醇酸聚甘油(3)酯[Arlacel 1689],硬脂酸脱水山梨糖醇酯和椰油酸鹿糖酯[Arlatone 2121],硬脂酸甘油酯和月桂基聚氧こ烯(23)醚[Cerasynth 945],鲸蜡硬脂醇和鲸蜡基聚氧こ烯(20)醚[cetomacrogol Wax],鲸腊硬脂醇和聚山梨醇酯60和聚氧こ烯-150和硬脂酸酯_20[polawax GP 200, polawax NF],鲸腊硬脂醇和鲸腊硬脂基聚葡糖苷[Emulgade PL1618],鲸腊硬脂醇和鲸腊硬脂基聚氧こ烯(20)醚[Emulgade 1000NI, Cosmowax],鲸腊硬脂醇和聚氧こ烯(40)蓖麻油[Emulgade F Special],鲸腊硬脂醇和聚氧こ烯(40)蓖麻油和鲸蜡硬脂基硫酸钠[Emulgade F],硬脂醇和硬脂基聚氧こ烯(7)醚和硬脂基聚氧こ烯(10)醚[Emulgator E 2155],鲸腊硬脂醇和硬脂基聚氧こ烯(7)醚和硬脂基聚氧こ烯(10)醚[Emulsifying wax USNF],硬脂酸甘油酯和硬脂酸聚氧こ烯(75)酯[Gelot6 [Arlacell65], polyoxyethylene ko-ene (5) glyceryl stearate [Arlatone 983 S], sorbitan oleate esters (and) polyglyceryl ricinoleate (3) ester [Arlacel 1689], stearyl acid sorbitan esters and sugar esters deer cocoate [Arlatone 2121], glyceryl stearate and laureth ko-ene (23) ether [Cerasynth 945], cetearyl alcohol and cetyl polyoxyethylene ko ene (20) ether [cetomacrogol wax], cetearyl alcohol and polysorbate 60 and polyoxyethylene stearates ko alkenyl -150 _20 [polawax GP 200, polawax NF], cetearyl alcohol, cetyl stearyl polyglucoside [Emulgade PL1618], cetearyl alcohol and cetearyl ko polyoxy alkylene group (20) ether [Emulgade 1000NI, Cosmowax], cetearyl alcohol and polyoxy alkylene ko (40) castor oil [Emulgade F Special], cetearyl alcohol and polyoxy alkylene ko (40) castor oil and cetearyl sulfate [Emulgade F], stearyl alcohol and stearyl polyoxyethylene ko-ene (7) stearyl ether and ko polyoxy alkylene group (10) ether [Emulgator E 2155], cetearyl alcohol and stearyl polyoxyethylene ko-ene (7) stearyl ether, and polyoxy alkylene ko (10) ether [Emulsifying wax USNF], hard fatty acid glycerides and polyoxyethylene stearate ko-ene (75) ester [Gelot6 4],丙ニ醇鲸腊基聚氧こ烯(3)醚こ酸酯[Hetester PCS],丙ニ醇异鲸腊基聚氧こ烯(3)醚こ酸酯[Hetester PHA],鲸蜡硬脂醇和鲸蜡基聚氧こ烯(12)醚和油基聚氧こ烯(12)醚[Lanbritol Wax N 21],硬脂酸聚氧こ烯(6)酯和硬脂酸聚氧こ烯(32)酯[Tefose 1500],硬脂酸聚氧こ烯(6)酯和鲸蜡基聚氧こ烯(20)醚和硬脂基聚氧こ烯(20)醚[Tefose2000],硬脂酸聚氧こ烯(6)酯和鲸蜡基聚氧こ烯(20)醚和硬脂酸甘油酯和硬脂基聚氧こ烯(20)醚[TefOSe2561],硬脂酸甘油酯和鲸蜡硬脂基聚氧こ烯(20)醚[Teginacid H,C,X]。 4], cetyl alcohol propan ni ko polyoxyalkylene alkenyl group (3) ko ether acetate [Hetester PCS], iso-propyl alcohol, cetyl ni polyoxyalkylene ko alkenyl group (3) ko ether acetate [Hetester PHA], cetearyl stearyl alcohol and cetyl polyoxyethylene ko-ene (12) oleyl ether and polyoxyethylene ko-ene (12) ether [Lanbritol wax N 21], polyoxyethylene stearate ko-ene (6) stearic acid esters and polyoxyethylene ko ene (32) ester [Tefose 1500], polyoxyethylene stearate ko-ene (6) ester and a polyoxyethylene cetyl ko-ene (20) stearyl ether, and polyoxy alkylene ko (20) ether [Tefose2000], hard polyoxyethylene fatty acid ko-ene (6) ester and a polyoxyethylene cetyl ko-ene (20) glyceryl ether and polyoxyethylene stearyl stearate, and ko-ene (20) ether [TefOSe2561], glyceryl stearate and cetearyl polyoxy alkylene ko (20) ether [Teginacid H, C, X].

[0273] 阴离子乳化剂如自乳化型硬脂酸聚氧こ烯(2)酷(PEG-2 stearate SE),自乳化型硬脂酸甘油酷(glyceryl stearate SE) [Monelgine, Cutina KD],丙ニ醇硬脂酸酷[TeginP],鲸腊硬脂醇和鲸腊硬脂基硫酸钠[Lanette N, Cutina LE7Crodacol GP],鲸腊硬脂醇和月桂基硫酸钠[Lanette W],三(羊毛脂醇聚氧こ烯(4)醚)磷酸盐和硬脂酸こニ醇酯和硬脂酸聚氧こ烯(2)酯[Sedefos 75],硬脂酸甘油酯和月桂基硫酸钠[Teginacid Special]。 [0273] Anionic emulsifiers such as polyoxyethylene stearate, self-emulsifying ko-ene (2) Cool (PEG-2 stearate SE), self-emulsifying glyceryl stearate cool (glyceryl stearate SE) [Monelgine, Cutina KD], prop stearic alcohol cool ni [TeginP], cetearyl alcohol, cetyl stearyl sulfate [Lanette N, Cutina LE7Crodacol GP], cetearyl alcohol and sodium lauryl sulfate [Lanette W], tris (lanolin alcohol polyoxy alkylene ko (4) ether) phosphates and phosphate esters ko ni stearate and polyoxyethylene stearate ko-ene (2) ester [Sedefos 75], glyceryl stearate and sodium lauryl sulfate [Teginacid Special] . 阳离子酸碱(cationic acid bases)如鲸腊硬脂醇和鲸腊基三甲基溴化铵。 Cationic acid bases (cationic acid bases), such as cetyl stearyl alcohol, cetyl trimethyl ammonium bromide.

[0274] 乳化剂的用量基于所述组合物的总重量可以例如是1-30重量%,特别是4-20重量%以及优选5-10重量%。 The amount of [0274] emulsifiers based on the total weight of the composition may be, for example, 1 to 30% by weight, in particular 4-20 wt% and preferably 5-10 wt%.

[0275] 当配制成0/W乳液时,上述乳化剂体系的优选用量可以占油相的5% -20%。 [0275] When formulated as 0 / W emulsions, the preferably amount of such emulsifier systems may constitute 5% to 20% oil phase.

[0276] IS富月旨齐[j (super-fattinR aRents) [0276] IS-rich month aimed Qi [j (super-fattinR aRents)

[0277] 适于用作超富脂剂的物质例如是羊毛脂和卵磷脂,以及聚こ氧基化或丙烯酸酯化羊毛脂和卵磷脂衍生物,多元醇脂肪酸酷,单酸甘油酯和脂肪酸链烷醇酰胺,后者同时充当泡沫稳定剂。 [0277] Substances suitable for use as super superfatting agents, for example, lanolin and lecithin, and poly ko group or acrylated lanolin and lecithin derivatives, polyol fatty cool, fatty acid monoglycerides and alkanolamides, the latter simultaneously acting as foam stabilizers. [0278] 表面活性剂 [0278] Surfactant

[0279] 适合的温和表面活性剤,也就是说特别好地为皮肤所接受的表面活性剤,其实例包括脂肪醇聚ニ醇醚硫酸盐、单甘油酷硫酸盐、单烷基和/或ニ烷基磺基琥珀酸盐、脂肪酸羟こ基磺酸盐、脂肪酸肌氨酸盐、脂肪酸牛磺酰胺、脂肪酸谷氨酸盐、α -烯烃磺酸盐、醚羧酸、烷基低聚葡糖苷、脂肪酸葡糖酰胺、烷基酰氨基甜菜碱和/或蛋白质脂肪酸缩合产物,后者优选基于小麦蛋白质。 [0279] Ji Suitable mild surfactants, that is to say surfactants especially well to the skin acceptable Ji, Ni and examples thereof include fatty alcohol polyglycol ether sulfates, monoglyceride sulfates cool, mono- and / or Ni alkyl sulfosuccinates, fatty ko hydroxyalkyl sulfonates, fatty acid sarcosinates, fatty acid taurocholic acid amide, fatty acid glutamates, α - olefin sulfonates, ether carboxylic acids, alkyl oligoglucosides , fatty acid glucamides, alkylamidobetaines and / or protein fatty acid condensation products, the latter preferably based on wheat proteins.

[0280]稠度调节剂/增稠剂和流变学改性剂 [0280] Consistency regulators / thickeners and rheology modifiers

[0281] ニ氧化硅,硅酸镁,硅酸铝,多糖或其衍生物如透明质酸、黄原胶、瓜尔胶、琼脂、藻酸盐、角叉菜胶(carraghenan)、胶凝糖(gellan)、果胶,或改性纤维素如轻基纤维素、轻丙基甲基纤维素。 [0281] Ni silicon oxide, magnesium silicate, aluminum silicates, polysaccharides or derivatives thereof such as hyaluronic acid, xanthan gum, guar gum, agar, alginates, carrageenan (carraghenan), gellan (gellan), pectin, cellulose or modified cellulose such as light, light methylcellulose. 此外聚丙烯酸酯或网状丙烯酸(reticulated acrylic acid)的均聚物和聚丙烯酰胺,卡波姆(carbomer) (carbopol types 980、981、1382、ETD2001、ETD2020、UltrezlO)或Salcare系列如Salcare SC80(硬脂基聚氧こ烯(10)醚烯丙基醚/丙烯酸酯共聚物),Salcare SC81 (丙烯酸酯共聚物),Salcare SC91和Salcare AST (丙烯酸钠共聚物/PPG-I十三烷基聚氧こ烯(6)醚),s印igel 305 (聚丙烯酰胺/月桂基聚氧こ烯(7)醚),Simulgel NS和Simulgel EG (丙烯酸轻基こ酷/丙烯酰基ニ甲基牛磺酸钠共聚物),Stabilen 30 (丙烯酸酯/异癸酸こ烯基酯交联聚合物),Pemulen TR-I (丙烯酸酯/丙烯酸C10-30烧基酯交联聚合物),Luvigel EM (丙烯酸钠共聚物),Aculyn 28 (丙烯酸酷/山嵛醇聚氧こ烯(25)醚甲基丙烯酸酯共聚物)等。 In addition polyacrylates or acrylate mesh (reticulated acrylic acid) homopolymer and polyacrylamides, carbomer (carbomer) (carbopol types 980,981,1382, ETD2001, ETD2020, UltrezlO) or Salcare range such as Salcare SC80 ( stearyl polyoxyethylene ko-ene (10) ether, allyl ether / acrylates copolymer), Salcare SC81 (acrylates copolymer), Salcare SC91 and Salcare AST (sodium acrylates copolymer / PPG-I trideceth oxygen ko-ene (6) ether), s plate igel 305 (polyacrylamide / laureth ko-ene (7) ether), Simulgel NS and Simulgel EG (acrylic light-yl cool ko / ni acryloyl taurate sodium acrylate copolymer), Stabilen 30 (acrylate / iso-capric acid ko-enyl acrylate crosspolymer), Pemulen TR-I (acrylates / C10-30 burn-yl acrylate crosspolymer), Luvigel EM (sodium acrylate copolymer), Aculyn 28 (acrylate cool / polyoxyethylene behenyl alcohol ko-ene (25) ether methacrylate copolymer).

[0282] 聚合物 [0282] Polymer

[0283] 适合的阳离子聚合物例如是阳离子纤维素衍生物,如可以名称PolymerJR 400从Amerchol得到的季铵化羟甲基纤维素,阳离子淀粉,ニ烯丙基铵盐和丙烯酰胺的共聚物,季铵化こ烯基吡咯烷酮/こ烯基咪唑聚合物,例如Luviquat ® (BASF),聚ニ醇和胺的缩合产 [0283] Suitable cationic polymers such as cationic cellulose derivatives, such as the name PolymerJR 400 can be obtained from Amerchol quaternary ammonium hydroxymethyl cellulose, cationic starch, copolymers of allyl Ni salts and acrylamides, ko quaternized vinylpyrrolidone / ko-vinylimidazole polymers, for example Luviquat ® (BASF), poly-condensation products of alcohols and amines ni

物,季铵化胶原多肽,如月桂基ニ甲基铵羟丙基水解胶原(Lamequat ® L/Grilnau),季铵化 Was quaternized collagen polypeptides, such as lauryl ni Hydroxypropyl Hydrolyzed Collagen (Lamequat ® L / Grilnau), quaternized

小麦多肽,聚こ烯亚胺,阳离子硅酮聚合物,如酰氨基甲基聚硅氧烷,己ニ酸和ニ甲基氨基轻基丙基ニ亚こ基三胺的共聚物(Cartaretin/Sandoz),丙烯酸与ニ甲基ニ烯丙基氯化铵的共聚物(Merquat 550/Chemviron),聚氨基聚酰胺,如在FR-A-2252840中描述的,及其交联水溶性聚合物,阳离子壳多糖衍生物,如季铵化的壳聚糖,其任选地作为微晶分布;ニ卤代烷如ニ溴丁烷与双ニ烷基胺的缩合产物,例如双ニ甲基氨基-1,3-丙烷,阳离子瓜尔胶,如来自Celanese 的Jaguar C-17> Jaguar C-16,季铵盐聚合物,如来自Miranol 的MirapolA-15,Mirapol AD-l.Mirapol AZ-I0至于阴离子、两性离子、两性和非离子聚合物,例如考虑こ酸こ烯酯/巴豆酸共聚物、こ烯基吡咯烷酮/丙烯酸こ烯酯共聚物、こ酸こ烯酯/马来酸丁酯/丙烯酸异冰片酯共聚物、甲基こ烯基醚/马来酸酐共聚物及其酷、未交联的聚丙烯酸和 Wheat polypeptide, polyethylene imine ko alkenyl, cationic silicone polymers, such as methyl polysiloxane amido, hexanoic acid and ni ni ni methylamino light propyl group ko alkylene triamine copolymers (Cartaretin / Sandoz ), copolymer (Merquat 550 / Chemviron) acrylic acid with methyl ni ni diallyl ammonium chloride, polyaminopolyamides, as described in FR-a-2252840, and their crosslinked water-soluble polymers, cationic chitin derivatives such as quaternized chitosan, optionally in microcrystalline distribution; haloalkoxy condensation products such as ni ni ni bromobutane with bis alkylamines, such as bis-methylamino-1,3 ni - propane, cationic guar gum, such as Jaguar from Celanese, C-17> Jaguar C-16, quaternary ammonium salt polymers, such as from the Miranol MirapolA-15, Mirapol AD-l.Mirapol AZ-I0 as anionic, zwitterionic , amphoteric and nonionic polymers, e.g. alkenyl consider ko ko acid ester / crotonic acid copolymers, vinyl pyrrolidone ko / ko alkenyl acrylate ester copolymers, esters of ethylenically ko ko acid / butyl maleate / isobornyl acrylate copolymer was ko methyl vinyl ether / maleic anhydride copolymers and cool, uncrosslinked polyacrylic acids and 多元醇交联的聚丙烯酸、丙烯酰氨基丙基.三甲基氯化铵/丙烯酸酯共聚物、辛基丙烯酰胺/甲基丙烯酸甲酷/甲基丙烯酸叔丁基氨基こ酷/甲基丙烯酸2-羟基丙酯共聚物、聚こ烯基吡咯烷酮、こ烯基吡咯烷酮/こ酸こ烯酯共聚物、こ烯基吡咯烷酮/甲基丙烯酸ニ甲基氨基こ酷/こ烯基己内酰胺三元共聚物以及任选衍生的纤维素醚和硅酮。 Polyol crosslinked polyacrylic acids, acrylamidopropyl. Trimethylammonium chloride / acrylate copolymers, octylacrylamide / methyl methacrylate cool / tert-butylaminoethyl methacrylate cool ko / methacrylic acid 2-hydroxypropyl methacrylate copolymers, poly vinyl pyrrolidone ko, ko vinylpyrrolidone / ko ko acid alkenyl ester copolymers, vinyl pyrrolidone ko / methacrylic acid ni methylamino cool ko / ko alkenyl caprolactam terpolymers and optionally derivatized cellulose ethers and silicones. 此外可以使用在EP 1093796(第3-8页,第17-68段)中所述的聚合物。 Also can be used in EP 1093796 (pages 3-8, paragraphs 17-68) of the polymer.

[0284]阳离子表面活性剂[0285] 鲸蜡基三甲基溴化铵(CTAB)、聚ニ甲基硅氧烷共聚醇、酰胺基甲硅烷(amidomethicones)、丙烯酰胺基丙基三甲基氯化铵/丙烯酰胺共聚物、瓜尔羟丙基三甲3¾ 氣化按、如International Cosmetic Ingredient Dictionary andHandoook,7thEdition 1997中所列的羟十六烷基羟こ基ニ甲基氯化铵季铵化合物,例如季铵_80 ;如International Cosmetic Ingredient Dictionary andHandbook, 7th Edition 1997 中所列的聚季铵化合物,例如聚季铵_5、聚季铵_6、聚季铵-7、聚季铵-10、聚季铵-II、聚季铵-17、聚季铵-18、聚季铵-24或聚季铵-27、聚季铵-28、聚季铵-32、聚季铵-37。 [0284] Cationic Surfactant [0285] Cetyl trimethylammonium bromide (of CTAB), poly ni dimethicone copolyol, silyl amide (amidomethicones), acrylamido-trimethylammonium chloride ammonium / acrylamide copolymers, guar hydroxypropyl trimethyl 3¾ by gasification, such as the International Cosmetic Ingredient Dictionary andHandoook, hydroxyalkyl cetyl hydroxyethyl ko 1997 listed in group ni 7thEdition chloride quaternary ammonium compound, for example, quaternary ammonium _80; the International Cosmetic Ingredient Dictionary andHandbook, polymeric quaternary ammonium compounds listed in the 7th Edition 1997, for example, polyquaternary ammonium _5, polyquaternium _6, polyquaternium-7, polyquaternium-10, polyquaternium -II, polyquaternium -17, polyquaternium-18, polyquaternium -24 or polyquaternium -27, polyquaternium -28, polyquaternium -32, polyquaternium -37.

[0286] 生物活性成分 [0286] Biological active ingredient

[0287] 生物活性成分应理解为例如指的是维生素E、维生素Eこ酸酷、维生素E棕榈酸酷、抗坏血酸、脱氧核糖核酸、视黄醇、没药醇(bisabolol)、尿囊素、植烷三醇、泛酰醇、AHA酸、氨基酸、神经酰胺、假神经酰胺、精油、植物提取物和维生素复合物。 [0287] biologically active ingredient to be understood as referring to, for example, vitamin E, vitamin E acid ko cool, cool vitamin E palmitate, ascorbic acid, deoxyribonucleic acid, retinol, bisabolol (Bisabolol), allantoin, plant alkyl triol, panthenol, the AHA acids, amino acids, ceramides, pseudoceramides, essential oils, plant extracts and vitamin complexes. [0288] 除臭活性成分 [0288] deodorant active ingredient

[0289] 除臭活性成分为例如止汗剂,如氯化铝水合物(參见J. Soc. Cosm.Chem. 24, 281 (1973))。 [0289] deodorising active ingredients, for example, antiperspirants, such as aluminum chlorohydrate (see J. Soc. Cosm.Chem. 24, 281 (1973)). 例如可以Hoechst AG的商标Locron ®购得的一种对应于式 For example, one available mark Locron ® of Hoechst AG may correspond to the formula

Al2 (OH) 5C1 X 2. 5H20的氯化铝水合物,其使用是特别优选的(參见J. Pharm. Pharmacol. 26,531 (1975))。 Al2 (OH) aluminum chloride hydrate 5C1 X 2. 5H20, using a particularly preferred (see J. Pharm. Pharmacol. 26,531 (1975)). 除了氯水合物(chlorohydrate)以外,也可以使用轻基こ酸招和招/错的酸式盐。 Apart chlorohydrate (chlorohydrate), may also be used a light-yl ko acid salts and acid strokes strokes / wrong. 酯酶抑制剂可以作为其他除臭活性成分加入。 Esterase inhibitors may be added as further deodorising active ingredients. 所述抑制剂优选是柠檬酸三烷基酷,如柠檬酸三甲酷、柠檬酸三丙酷、柠檬酸三异丙酯、柠檬酸三丁酯以及特别是柠檬酸三こ酯(Hydagen CAT,Henkel,其抑制酶活性以及因此减少气味形成。考虑作为酯酶抑制剂的其他物质是留醇硫酸盐(酷)或磷酸盐(酷),例如羊毛留醇、胆固醇、菜油留醇(campesterol)、豆甾醇(stigmasterol)和谷留醇(sitosterol)的硫酸盐或磷酸盐,ニ羧酸及其酯,例如戊ニ酸、戊ニ酸单こ酯、戊ニ酸ニこ酷、己ニ酸、己ニ酸单こ酷、己ニ酸ニこ酷、丙ニ酸和丙ニ酸ニこ酯以及羟基羧酸及其酷,例如柠檬酸、苹果酸、酒石酸或酒石酸ニこ酷。影响微生物菌群和杀死汗分解细菌或抑制其生长的抗菌活性成分同样可以存在于所述制剂中(尤其是在棒状制剂中)。其实例包括壳聚糖、苯氧基こ醇和葡萄糖酸洗必太(chlorhexidinegluconate) ο 5_ 氣_2_ (2,4_ The inhibitors are preferably trialkyl citrates is cool, such as citric acid trimethyl cool, cool tripropylene citrate, triisopropyl citrate, tributyl citrate and especially triethyl citrate ko ester (Hydagen CAT, Henkel , which inhibit enzyme activity and hence reduce odor formation. consideration as esterase inhibitors are other substances stay alcohol sulphates (cool) or phosphate (cool), for example, leaving the wool alcohol, cholesterol, alcohol, vegetable oil left (campesterol), beans sterols (stigmasterol) and valleys remain alcohol (sitosterol) sulfates or phosphates, carboxylic acids and esters ni, ni acids e.g. pentyl, pent-ni ko acid mono ester, pentyl ni ni ko cool acid, hexanoic acid, ni, ni hexyl acid monomethyl ko cool, hexanoic acid ni ni ko cool, propionic acid and propionic ni ni ni ko acid esters of hydroxycarboxylic acids and cool, such as citric acid, malic acid, tartaric acid or tartaric ni ko cool. Effect of microbial flora and kill death of sweat-decomposing bacteria or inhibiting the growth of antimicrobial active ingredient can also be present in the formulation will be too (chlorhexidinegluconate) ο (especially in stick preparations). examples include chitosan, phenoxyethanol and glucose ko acid 5_ gas _2_ (2,4_ ニ氣苯ノ氧是ノ-苯酌· (Triclosan, Irgasan, Ciba SpecialtyChemicals Inc.)也已经证实特别有效。 Ni is oxygen gas Techno Techno benzene - benzene discretion · (Triclosan, Irgasan, Ciba SpecialtyChemicals Inc.) has also proved especially effective.

[0290] 抗头皮屑剂 [0290] antidandruff agents

[0291] 至于抗头皮屑剂,例如可以使用苯咪丁酮(climbazole),羟甲辛吡酮(octopirox)和巯氧卩比唳锌(zinc pyrithione)。 [0291] As anti-dandruff agents, for example, may be used climbazole (Climbazole), octopirox (Octopirox) and the ratio of Li Jie zinc pyrithione (zinc pyrithione). 常规成膜剂例如包括壳聚糖、微晶壳聚糖、季铵化壳聚糖、聚こ烯基吡咯烷酮、こ烯基吡咯烷酮/こ酸こ烯酯共聚物、包含高比例丙烯酸的季铵化纤维素衍生物的聚合物、胶原、透明质酸及其盐以及类似化合物。 Customary film formers include, for example, chitosan, microcrystalline chitosan, quaternized chitosan, poly ko vinyl pyrrolidone, vinyl pyrrolidone ko / ko ko acid alkenyl ester copolymers, acrylic acid containing a high proportion of quaternary ammonium polymeric cellulose derivatives, collagen, hyaluronic acid and salts thereof and similar compounds.

[0292] 水溶助剂 [0292] Hydrotropes

[0293] 为了提高流动性质,也可以采用水溶助剂,例如こ氧基化或非こ氧基化碳原子数较少的一元醇、ニ元醇或多元醇或者其醚(如こ醇、异丙醇、1,2_ ニ丙烷ニ醇、丙ニ醇、甘油、こニ醇、こニ醇单こ基醚、こニ醇单丁基醚、丙ニ醇单甲基醚、丙ニ醇单こ基醚、丙ニ醇单丁基醚、ニ甘醇单甲基醚、ニ甘醇单こ基醚、ニ甘醇单丁基醚以及类似产品)。 [0293] In order to improve the flow properties, hydrotropes can be employed, for example, a small number of carbon atoms group or ko ko alkoxylated monohydric alcohols, monohydric or polyhydric alcohols Ni, or an ether (e.g. ko alcohol, iso propanol, propane 1,2_ ni ni alcohol, propyl alcohol, Ni, glycerol, alcohol ko ni, ni ko ko glycol mono ethers, glycol monobutyl ether ko ni, ni propan glycol monomethyl ether, propyl glycol monomethyl ko ni ether, propyl glycol monobutyl ether ni, ni glycol monomethyl ether, glycol monoethyl ko ether ni, ni glycol monobutyl ether and similar products). 为此目的的多元醇优选包括2-15个碳原子和至少2个羟基。 The purpose for this polyol preferably comprises 2-15 carbon atoms and at least 2 hydroxyl groups. 所述多元醇也可以含有其他官能团,尤其是氨基,和/或可以由氮改性。 The polyols may contain other functional groups, especially amino groups, and / or may be modified with nitrogen. 典型实例如下:甘油,亚烷基ニ醇,如こニ醇、ニ甘醇、丙ニ醇、丁ニ醇、己ニ醇以及具有100-1000道尔顿的平均分子量的聚こニ醇;具有I. 5-10的本征缩合度(intrinsic degree ofcondensation)的エ业级低聚甘油混合物,例如具有40-50重量%ニ甘油含量的エ业级ニ甘油混合物;羟甲基化合物,例如尤其是三羟甲基こ烷、三羟甲基丙烷、三羟甲基丁烷、季戊四醇和ニ季戊四醇;低级烷基-葡糖苷,尤其是在烷基部分中具有1-8个碳原子的那些,例如甲基和丁基葡糖苷;具有5-12个碳原子的糖醇,例如山梨糖醇或甘露糖醇;具有5-12个碳原子的糖,例如葡萄糖或蔗糖;氨基糖,如葡糖胺;ニ醇胺,如ニこ醇胺或2-氨基-1,3-丙ニ醇。 Typical examples are as follows: glycerol, alkylene ni alcohols, such as alcohols ko ni, ni glycol, propyl alcohol ni, ni butyl alcohol, hexyl alcohol, and poly ko ni ni alcohol having an average molecular weight of 100-1000 daltons; having I. intrinsic degree of condensation of 5-10 (intrinsic degree ofcondensation) the oligoglycerol mixture Ester industry level, for example 40-50 wt Ni glycerol content glycerol Ester industry grade mixtures% Ni; methylol compounds, such as in particular trimethylol ko alkoxy, trimethylol propane, trimethylol butane, pentaerythritol and dipentaerythritol ni; - lower alkyl glucosides, in particular having 1 to 8 carbon atoms in the alkyl portion of those, e.g. methyl and butyl glucoside; sugar alcohols having 5-12 carbon atoms, for example sorbitol or mannitol; sugars having 5 to 12 carbon atoms, for example glucose or sucrose; amino sugars such as glucosamine ; ni alcohol amines, alcohol amines such as Ni ko or 2-amino-1,3-propan-Ni-ol.

[0294] 防腐剂 [0294] Preservatives

[0295] 适合的防腐剂例如包括对羟基苯甲酸甲酷、对羟基苯甲酸こ酷、对羟基苯甲酸丙酷、对羟基苯甲酸丁酷,苯扎氯铵,2-溴-2-硝基丙烷-1,3-ニ醇,脱氢こ酸,ニ偶氮烧基脲(Diazolidinyl Urea), 2- ニ氯-节醇,DMDM乙内酰脲,甲醒溶液,甲基ニ溴戍ニ腈(Methyldibromoglutanitrile),苯氧基こ醇,轻甲基甘氨酸钠,咪唑烧基脲(Imidazolidinyl Urea),三氯生(Triclosan)以及列于以下參考文献中的其他物质类别: KF DePolo-A short textbook ofcosmetology,第7章,表7-2、7_3、7_4和7-5,第210-219页。 [0295] Suitable preservatives include, for example p-hydroxybenzoic acid A cool, cool ko paraben, propyl paraben cool, cool butyl paraben, benzalkonium chloride, 2-bromo-2-nitropropane propane-1,3-ni alcohol, dehydroacetic acid ko, Ni azo burning urea (Diazolidinyl urea), 2- chloro-ni - alcohol section, the DMDM ​​hydantoin, wake A solution of methyl-bromo-shu ni ni carbonitrile (Methyldibromoglutanitrile), phenoxy ko alcohol, sodium glycinate light, burn-yl-imidazol-urea (imidazolidinyl urea), triclosan (triclosan) and other substance classes listed in the following reference: KF DePolo-a short textbook ofcosmetology Chapter 7, table 7-2,7_3,7_4 and 7-5, pp. 210-219.

[0296] 抑菌剂 [0296] bacteriostats

[0297] 抑菌剂的典型实例是对革兰氏阳性细菌具有特定作用的防腐剤,如2,4,4' _三氣_2'_轻基ニ苯基酿,洗必太(1,6-ニ(4_氣苯基-ニ狐基)己烧)或TCC(3,4,4'_ ニ氣N-碳酰苯胺)。 [0297] Typical examples of antibacterial agents are antiseptic Ji having a specific action against gram-positive bacteria, such as 2,4,4 '_ three gas _2'_ light phenyl group ni brewing, chlorhexidine (1, 6- ni (4_ gas phenyl - Ni Fox-yl) hexyl fever) or TCC (3,4,4'_ Ni N- carbanilide gas). 多种芳族化合物和醚油也具有抗微生物性能。 More aromatic compounds and ether oils also have antimicrobial properties. 典型实例是丁香油、薄荷油和百里香油中的活性成分丁子香酚、薄荷醇和百里酚。 Typical examples are clove oil, mint oil and thyme oil active ingredients eugenol, menthol and thymol. 关注的天然除臭剂是存在于莱檬花油中的萜烯醇金合欢醇(3,7、11-三甲基-2,6,10-十二烷三烯-I-醇(3,7,ll-trimethyl-2,6,10-dodecatrien-l-ol))。 Natural deodorant concern is present in lime blossom oil terpene alcohol farnesol (3,7,11-trimethyl-2,6,10-triene dodecyl alcohol -I- (3, 7, ll-trimethyl-2,6,10-dodecatrien-l-ol)). 甘油单月桂酸酯也被证实为ー种抑菌剂。 Glycerol monolaurate also proved to be a bacteriostatic agent ー species. 所存在的其他抑菌剂的用量通常基于所述制剂的固体含量是O. 1-2重量%。 The amount of other antibacterial agent present is typically based on the solids content of the formulation is O. 1-2 wt%.

[0298] 芳香油 [0298] perfume oil

[0299] 天然和/或合成的芳族物质的混合物。 [0299] mixtures of natural and / or synthetic aromatic substances. 天然芳族物质例如是下列物质的提取物:花(百合(lilies)、熏衣草(lavender)、玫瑰(roses)、茉莉(jasmine)、橙花(neroli)、夷兰(ylang-ylang))、莖和叶(天竺葵(geranium)、绿叶刺蕊草(patchouli)、橙叶(petitgrain))、果实(茴芳:(aniseed)、胡荽(coriander)、藏茴香(caraway)、桧柏(juniper))、果实皮(香朽1 檬(bergamot)、梓檬(lemons)、橙子(oranges))、根(肉豆M (mace)、当归(angelica)、芳:菜(celery)、小豆蘧(cardamom)、木香(costus)、鳶尾根(iris)、菖蒲(calmus))、木材(松木(pinewood)、擅木(sandalwood)、愈创木(guaiacumwood)、杉木(cedarwood)、玫瑰木(rosewood))、草本和禾草(龙蒿(tarragon)、香茅(lemongrass)、鼠尾草(sage)、百里香(thyme))、针叶和细枝(云杉(spruce)、松树(pine)、欧洲赤松(Scots pine)、高山陆均松(mountain pine))、树脂和香脂(古篷香脂(galbanum)、榄香脂(elemi) Natural substances such as aromatic extracts of the following substances: flowers (lily (lilies), Lavender (lavender), rose (roses), jasmine (jasmine), orange flower (neroli), Yilan (ylang-ylang)) , stems and leaves (geranium (geranium), patchouli (patchouli), orange leaves (petitgrain)), fruit (fennel Fang: (aniseed), coriander (coriander), caraway (caraway), juniper (juniper )), fruit skin (bergamot mortal 1 lime (Bergamot), Zi lemon (Lemons), orange (oranges)), roots (nutmeg M (mace), Angelica (Angelica), aryl: vegetables (Celery), adzuki Qu ( cardamom), woody (costus), orris root (iris), Iris (calmus)), wood (pine (pinewood), trespassing wood (sandalwood), guaiac (guaiacumwood), fir (cedarwood), rosewood (rosewood )), herbs and grasses (tarragon (tarragon), citronella (lemongrass), sage (sage), thyme (thyme)), needles and twigs (spruce (spruce), pine (pine), Pinus sylvestris (Scots pine), alpine DACRYDIUM (mountain pine)), resins and balsams (ancient canopy balsam (galbanum), elemi (elemi) 安息香(benzoin)、没药树脂(myrrh)、乳香(olibanum)、合家欢(opopo-nax))。 Benzoin (benzoin), myrrh resin (myrrh), frankincense (olibanum), Family (opopo-nax)). 也可以考虑动物原料,如灵猫香和海狸香。 Animal raw materials can also be considered, such as civet and castoreum. 典型的合成芳族物质例如是酷、醚、醛、酮、醇或烃类产物。 Typical synthetic aromatic substances, for example, cool, ether, aldehyde, ketone, alcohol or hydrocarbon products. 酷类的芳族物质化合物例如是こ酸苄基酯、异丁酸苯氧基こ酷、こ酸对-叔丁基环己基酷、こ酸里哪酯、こ酸ニ甲基苄基甲酷、こ酸苯基こ酷、苯甲酸里哪酷、甲酸苄基酯、甘氨酸こ基甲基苯基酯、丙酸烯丙基环己基酷、丙酸苏合香酯(styrallylpropionate)和水杨酸苄基酷。 Aromatic substance compounds cool ko acid type, for example, benzyl acetate, phenoxyethyl isobutyrate cool ko, ko Acid - t-butylcyclohexyl cool, ko acid linalyl ester, ko acid A cool methylbenzyl ni, ko acid phenyl ko cool, cool linalyl benzoate, benzyl ester, ko-phenyl glycine ester, allyl cyclohexyl propionate, cool, styrallyl propionate (styrallylpropionate) and benzyl salicylate cool. 所述醚例如包括苄基乙基醚;所述醛例如包括具有8-18个烃原子的直链烧醛、柠檬醛、香茅醛、香茅基氧乙醛(citroneIIyIoxyacetaldehyde)、仙客来醛(cyclamen aldehyde)、轻基香茅醛(hydroxycitronellal)、玲兰醛(Iilial)和波旁醛(bourgeonal);所述酮例如包括紫罗兰酮、异甲基紫罗兰酮和甲基雪松酮(methylcedryl ketone);所述醇例如包括茴香脑(anethol)、香茅醇、丁子香酹、异丁子香酹、香叶醇、里哪醇、苯基乙基醇和萜品醇(terpinol);以及所述烃主要包括萜烯和香脂。 The ethers include, for example, benzyl ethyl ether; the aldehydes include, for example straight-chain aldehydes having 8-18 burning hydrocarbon atoms, citral, citronellal, citronellol yloxy acetaldehyde (citroneIIyIoxyacetaldehyde), cyclamen aldehyde (cyclamen aldehyde), citronellal light group (hydroxycitronellal), blue ling aldehyde (Iilial) and Bourbon aldehyde (bourgeonal,); the ketones include, for example ionone, iso-methyl ionone and methyl cedrylone (methylcedryl ketone) ; the alcohol includes, for example anethole (anethol), citronellol, eugenol, sprinkle, sprinkle isoeugenol, geraniol, linalool, phenylethyl alcohol and terpineol (terpinol); and said primary hydrocarbon They include the terpenes and balsams. 然而,优选使用共同产生有吸引人的香味的多种芳族物质的混合物。 Preferably, however, together produce an attractive scent with a mixture of various aromatic substances. 主要用作芳香组分的相对低挥发性的醚油也适于作为芳香油,如鼠尾草油、春黄菊油、丁香油、蜂花油、肉桂叶油、莱檬花油(lime blossom oil)、刺柏油、香根草油、乳香油、古篷香脂油、金莲花油和杂熏衣草油。 Mainly used as aroma components, oils of relatively low volatility ethers are also suitable as perfume oils such as sage oil, chamomile oil, clove oil, melissa oil, cinnamon leaf oil, lime blossom oil (lime blossom oil ), juniper, vetiver oil, frankincense oil, the ancient canopy balsam oil, nasturtium oil and lavandin oil. 优选使用单独或相互混合的香柠檬油、ニ氢月桂烯醇、玲兰醛、新玲兰醛(Iyral)、香茅醇、苯基乙基醇、己基肉桂醛、香叶醇、苄基丙酮、仙客来醛、里哪醇、甲氧基甲基环十二基醚(boisambrene) forte、龙诞呋喃(ambroxan)、卩引哚、ニ氢茉莉酮酸甲酷、sande I ice、朽1樣油、红橘油、橙油、乙醇酸烯丙基戍基酷、cyclovertal、杂熏衣草油、肉豆蘧酒洋苏叶油、突厥酮、波旁酒天竺葵油、水杨酸环己基酷、甲基柏木酮优级(vertofix coeur)、iso-E-Super、Fixolide NP、合成橡苔(evernyl)、甲基紫罗兰酮Y、苯基乙酸、乙酸香叶酯、乙酸节酯、玫瑰氧化物、romillat、irotyl 和floramat。 Preferably used singly or mixed with each other bergamot oil, ni hydrogen lauryl alcohol, aldehyde blue ling, blue ling new aldehyde (Iyral), citronellol, phenylethyl alcohol, hexyl cinnamaldehyde, geraniol, benzyl acetone , cyclamen aldehyde, linalool, cyclododecyl methoxymethyl ether (boisambrene) forte, Long birth furan (ambroxan), Jie indole, Ni hydrogen methyl jasmonate cool, sande I ice, rot 1 like oil, tangerine oil, orange oil, allyl pentyl glycolic cool, Cyclovertal, lavandin oil, nutmeg Qu wine sage oil, damascone, bourbon geranium oil, cyclohexyl salicylate cool, methyl cedrylone superior grade (vertofix coeur), iso-E-Super, Fixolide NP, synthesis of oakmoss (evernyl), methyl ionone Y, phenylacetic acid, geranyl acetate, acetic section acetate, rose oxide thereof, romillat, irotyl and floramat.

[0300] 其它助型 [0300] Other co-Type

[0301] 还可能的是,该化妆品制品含有作为助剂的消泡剂如硅氧烷,结构化剂(structurants)如马来酸,增溶剂如乙ニ醇、丙ニ醇、甘油或ニ甘醇,遮光剂如胶乳、苯乙烯/PVP或苯乙烯/丙烯酰胺共聚物,推进剂如丙烷/ 丁烷混合物、N20、ニ甲醚、C02、N2或空气,作为氧化染料前体的所谓偶联剂和显影剂组分,还原剂如硫代こ醇酸及其衍生物、硫代乳酸、半胱胺、硫代苹果酸或巯基乙烷磺酸,或氧化剂如过氧化氢、溴酸钾或溴酸钠。 [0301] It is also possible, the cosmetic article comprising as an adjuvant such as silicone antifoaming agents, structuring agents (structurants) such as maleic acid, solubilisers, such as ethyl alcohol, ni, ni propyl alcohol, glycerol or Ni Gan alcohol, opacifiers such as latex, styrene / PVP or styrene / acrylamide copolymers, propellants such as propane / butane mixtures, N20, Ni ether, C02, N2 or air, as oxidation dye precursor of the so-called coupling and the developer components, reducing agents such as thiosulfate ko alkyd and derivatives thereof, thiolactic acid, cysteamine, thiomalic acid or mercapto ethane sulfonic acid, or an oxidizing agent such as hydrogen peroxide, potassium bromate or a bromate sodium.

[0302] 合适的驱虫剂是例如N,N- ニ乙基-间-甲苯酰胺,1,2-戊ニ醇或驱虫剂3535 ;适合的自晒黑剂例如是ニ羟基丙酮和/或赤藓酮糖或ニ羟基丙酮和/或ニ羟基丙酮前体(如在TO 01/85124中描述的)和/或赤藓酮糖。 [0302] Suitable insect repellents are, for example N, N- ethyl-ni - inter - toluamide, 1,2-pentanediol or insect repellent 3535 ni alcohol; suitable self-tanning agents are, for example, Ni dihydroxyacetone and / or erythrulose and dihydroxyacetone or Ni / Ni or hydroxyacetone precursor (as described in tO 01/85124) and / or erythrulose.

[0303] 本发明的稳定剂体系特别适合用于稳定化身体护理产品,尤其是: [0303] The stabilizer system according to the present invention is particularly suitable for stabilizing body care products, in particular:

[0304]-护肤剂,如片剂形式或液体阜、无阜洗漆剂或洗漆糊剂形式(washingpaste)的皮肤洗涤和清洁制剂, [0304] - Skin agent, such as a tablet or liquid Fu, Fu washed skin without washing or paint removers paste form (washingpaste) and cleaning formulation,

[0305]-沐浴制剂,如液体(泡沫浴、乳、淋浴制剂)或固体沐浴制剂,如浴块和浴盐; [0305] - bathing preparations, such as liquid (foam baths, milks, shower preparations) or solid bath preparations such as bath salts and bath block;

[0306]-护肤剂,如护肤乳液(skin emulsion)、多重乳液或护肤油(skin oil);洁身油、爽身水、洁身胶;护肤骨; [0306] - skin protectants, such as skin care lotion (skin emulsion), multiple emulsion, or skin oil (skin oil); clean body oil, body lotion, gel bidet; Skin bone;

[0307]-化妆用个人护理制剂,如以日霜或粉霜(powder cream)、扑面粉(散粉或粉饼)、胭脂或乳膏化妆品形式的面部化妆品,眼部护理制剂,如眼影制剂、睫毛膏、眼线膏、眼霜或定眼乳膏(eye-fix cream);唇部护理制剂,如唇膏、亮唇膏(lip gloss)、润唇膏(lipcontour pencil)、唇线笔,指甲护理制剂,如指甲油、指甲油去除剂、指甲硬化剂或角质层去除剂; [0307] - cosmetic personal care preparations, such as in cream or powder cream (powder cream), face powder (loose or pressed powder), rouge or cream form cosmetic facial makeup, eye-care preparations, such as eye shadow preparations, mascara cream, eyeliner, eye creams or eye set (eye-fix cream); lip-care preparations, such as lipstick, lip balm light (lip gloss), lip balm (lipcontour pencil), lip liner, nail-care preparations, such as nail oil, nail polish remover, nail hardeners or cuticle removers;

[0308]--足部护理制剂,如足浴、足粉、足霜或足用香脂(footbalsam),特殊防臭剂和止汗剂或老苗去除制剂(callus-removing preparation); [0308] - foot-care preparations, such as a foot bath, foot powder, foot cream or full and balsam (footbalsam), special deodorants and antiperspirants or remove old seedlings formulation (callus-removing preparation);

[0309]-光防护制剂,如防晒乳、防晒露、防晒霜或防晒油,防晒剂(sunblock)或热带粉(tropical),预晒黑制剂或晒后制剂; [0309] - light-protective preparations, such as sun milks, sunscreen lotion, sunscreen or suntan oil, sunscreen (sunblock) or tropical powder (Tropical), pre-tanning preparations or after-sun preparations;

[0310]-皮肤晒黑制剂,如自晒黑霜; [0310] - skin-tanning preparations, such as self-tanning creams;

[0311]-去色素制剂(depigmenting preparation),如漂白皮肤用的制剂或皮肤光亮制剂; [0311] - depigmenting formulation (depigmenting preparation), such as a skin lightening formulations or formulations used to bleach skin;

[0312]-驱虫剂,如驱虫油、洗剂、喷剂或棒; [0312] - an insect repellent, insecticide, such as oils, lotions, sprays or sticks;

[0313]-除臭剂,如除臭喷剂、泵送喷剂、除臭凝胶、棒或走珠; [0313] - deodorants, such as deodorant sprays, pump sprays, deodorant gels, sticks or roll-on;

[0314]-止汗剂,如止汗剂棒、霜或走珠; [0314] - antiperspirants, such as antiperspirant sticks, creams or roll-on;

[0315]-用于清洁和护理被玷污皮肤的制剂,如合成洗涤剂(固体或液体),剥离或擦洗制剂或剥离掩模; [0316]-化学品形式的脱毛剂(脱毛),如脱毛粉,液体脱毛剂,霜或糊形式的脱毛剂,凝胶形式或气溶胶泡沫的脱毛剂; [0315] - defiled formulations for cleaning and care of the skin, such as synthetic detergents (solid or liquid), peeling or scrub preparations or peeling masks; [0316] - the form of the chemical depilatory (hair removal), depilating powders, liquid depilatory agents, depilatory cream or paste form, gel form or aerosol foams depilatory;

[0317]-剃须制剂,如剃须皂、发泡剃须乳膏、非发泡剃须乳膏、泡沫和凝胶、用于干剃须的须前制剂,须后水或须后洗剂; [0317] - shaving preparations such as shaving soap, foaming shaving creams, non-foaming shaving creams, foams and gels, pre-shave preparations for dry shaving, aftershaves or after washing to be agent;

[0318]-香料制剂,如含香料和芳香物质的制品(香水、科隆香水(eau deCologne)、化妆香水(eau de toilette)、香味香水(eau de parfum)、化妆香味(parfum de toilette)、香料),芳香油或香料乳膏; [0318] - perfume formulations, such as products containing fragrances and fragrance (perfume, cologne (eau deCologne), cosmetic fragrances (eau de toilette), scented perfume (eau de parfum), cosmetic fragrance (parfum de toilette), perfume ), perfume oils or perfume creams;

[0319]-化妆品毛发处理制剂,如香波和调理剂形式的毛发洗涤制剂,护发制剂,如预处理制剂、生发油(hair tonics)、造型乳膏(styling cream)、定型发胶(styling gels)、润发脂(pomade)、发用漂洗剂、处理包、深入型毛发处理剂,毛发结构化制剂,如用于烫发(热烫、温烫、冷烫)的烫发制剂,直发剂,液体毛发定型制剂,摩丝(hair foam),毛发喷雾,漂发剂,如过氧化氢溶液、光亮香波、漂白乳膏、漂白粉末、漂白糊剂或油,暂时、半永久或永久毛发着色剂,包含自氧化染料、或天然毛发着色剂如指甲花染料或甘菊的制剂; [0319] - Cosmetic hair treatment preparations, hair washing preparations in the form of shampoos and conditioners, hair care preparations such as pretreatment preparations, hair tonics (hair tonics), cream style (styling cream), styling gels (styling gels) , pomades (a pomade), hair rinses, treatment bag, depth-type hair treatment agent, hair structuring preparations such as permanent waving preparations for permanent wave (blanching, mild wave, cold wave), straight hair, liquid hair setting preparations, mousse (hair foam), a hair spray, hair bleaching agents, such as hydrogen peroxide solution, bright shampoos, bleaching creams, bleaching end, bleaching pastes or oils, temporary, semi-permanent or permanent hair colorants, comprising from oxidation dyes, or natural hair colorants, such as henna or camomile formulation;

[0320]-洁齿剂,尤其是牙霜、牙膏、漱口剂、口腔冲洗剂、防牙菌斑剂和假牙清洁剂; [0320] - dentifrice, particularly a dental creams, toothpastes, mouthwashes, mouth rinses, anti-plaque agents, and cleaning agents for dentures;

[0321]-美饰剂,尤其是唇膏、指甲油、眼影、睫毛膏、干和湿化妆品、胭脂、底粉、脱毛剂和晒黑液; [0321] - decorative preparations, in particular lipsticks, nail varnishes, eye shadows, mascaras, dry and moist make-up, rouge, powders, depilatory agents and suntan liquid;

[0322]-含有活性成分的化妆品制剂,尤其是激素制剂、维生素制剂、植物提取物制剂和抗菌制剂; [0322] - cosmetic formulations containing active ingredients, in particular hormone preparations, vitamin preparations, vegetable extract preparations and antibacterial preparations;

[0323] 特别地,合适的含有活性成分的化妆品制剂是激素制剂(hormonepreparations)、维生素制剂、植物提取物制剂(vegetable extract preparation)和抗菌制剂。 Cosmetic preparations [0323] In particular, containing the active ingredient suitable hormone preparations (hormonepreparations), vitamin preparations, vegetable extract preparations (vegetable extract preparation) and antibacterial agents.

[0324] 表现形式 [0324] manifestations

[0325] 所列举的最终组合物可以以许多种表现形式存在,例如: [0325] The final compositions listed may exist in a number of forms, for example:

[0326]-液体制剂形式,如W/0、0/W、0/W/0、W/0/W、或PIT乳液以及所有种类的微乳液, [0326] - in the form of liquid preparations, such as W / 0,0 / W, 0 / W / 0, W / 0 / W, or PIT emulsion and all kinds of microemulsions,

[0327]-凝胶形式, [0327] - a gel form,

[0328]-油、霜、乳或洗剂形式, [0328] - oil, cream, milk or lotion,

[0329]-棒的形式, [0329] - the form of rods,

[0330]-喷剂(使用推进剂气体的喷剂或泵送喷剂)或气溶胶形式, [0330] - spray (spray using propellant gas or pump spray) or an aerosol form,

[0331]-泡沫形式,或 [0331] - foam, or

[0332]-糊剂形式。 [0332] - paste.

[0333] 作为皮肤用化妆品制剂,特别重要的是光防护制剂,如防晒乳、防晒露、霜、洗剂油,防晒剂或热带粉,预晒黑制剂或晒后制剂,以及皮肤晒黑制剂,如自晒黑霜。 [0333] as a skin cosmetic preparation, is particularly important that the light-protective preparations, such as sun milks, sunscreen lotion, creams, lotions, oils, sunscreens powder or tropical, pre-tanning preparations or after-sun preparations, also skin-tanning preparations , such as self-tanning creams. 特别关注的是防晒保护霜、防晒保护露、防晒保护乳和喷剂形式的防晒保护制剂。 Of particular interest are sun protection creams, sun protection lotions, sun protection milk and sun protection preparations in the form of sprays.

[0334] 作为毛发用化妆品制剂,特别重要的是毛发处理用的上述制剂,尤其是香波形式的毛发洗涤制剂,毛发调理剂,毛发调理剂如预处理制剂、生发油、造型乳膏、定型发胶、润发脂、发用漂洗剂、处理包、深入型毛发处理剂(intensive hair treatments),直发剂(hair-straightening preparation),液体毛发定型制剂,摩丝(hair foam)和毛发喷剂。 [0334] As a hair cosmetic preparation, is particularly important with the above-described hair treatment formulations, especially hair-washing preparations in the form of shampoos, hair conditioners, hair conditioning agents such as pretreatment preparations, hair tonics, styling creams, styling gels , pomades, hair rinses, treatment bag, depth-type hair treatment agent (intensive hair treatments), straightening agent (hair-straightening preparation), liquid hair-setting preparations, mousse (hair foam), and hair sprays. 特别关注的是香波形式的毛发洗涤制剂。 Particular interest are hair-washing preparations in the form of a shampoo.

[0335] 香波例如具有下列组成: [0335] For example shampoo having the following composition:

[0336] O. 01-5重量%式(I)的化合物, [0336] O. 01-5 wt% Compound of formula (I), and

[0337] 12. O重量%月桂基聚氧乙烯(2)醚硫酸钠, [0337] 12. O wt% sodium lauryl polyoxyethylene (2) ether sulfate,

[0338] 4. O重量%椰油酰氨基丙基甜菜碱, [0338] 4. O wt% cocamidopropyl betaine,

[0339] 3. O重量%氯化钠, [0339] 3. O wt% sodium chloride,

[0340] 以及加至100%的水。 [0340] and to 100% water.

[0341] 例如,尤其可以使用以下的发用化妆品组合物: [0341] For example, the following may be used in particular hair cosmetic composition:

[0342] ax)自发乳化原料组合物(stock formulation),其包括本发明的式(I)的化合物、任选的其它稳定剂、PEG-6-C1Q氧代醇(PEG-6-C1Q oxoalcohol)和脱水山梨糖醇倍半油酸酯,向其中加入水和任何所需的季铵化合物,例如4%貂油酰氨基丙基二甲基-2-羟基乙基氯化铵(minkamidopropyIdimethyl-2-hydroxyethylammonium chloride)或季铵80 ; [0342] ax) spontaneously emulsifying stock composition (stock formulation), which comprises a formula (I) compounds of the present invention, optionally, other stabilizers, PEG-6-C1Q oxo alcohols (PEG-6-C1Q oxoalcohol) alcohol and sorbitan sesquioleate, to which water and any desired quaternary ammonium compound, for example 4% mink amidopropyl dimethyl-2-hydroxyethyl ammonium chloride (minkamidopropyIdimethyl-2- ) or quaternary ammonium hydroxyethylammonium chloride 80;

[0343] a2)自发乳化原料组合物,其包括本发明的式⑴的化合物、任选的其它稳定剂、柠檬酸三丁酯和PEG-20-脱水山梨糖醇单油酸酯,向其中加入水和任何所需的季铵化合物,例如4%貂油酰氨基丙基二甲基-2-羟基乙基氯化铵或季铵80 ; [0343] a2) spontaneously emulsifying stock composition comprising the present invention of formula ⑴ compound, optionally other stabilizers, tributyl citrate and PEG-20- sorbitan monooleate, to which was added water and any desired quaternary ammonium compound, for example 4% mink amidopropyl dimethyl-2-hydroxyethyl quaternary ammonium chloride or 80;

[0344] b) 1/4掺杂(quat-doped)溶液,其包括在丁基三甘醇(butyl triglycol)和朽1檬酸三丁酯中的本发明的式(I)的化合物;和任选的其它稳定剂; [0344] b) 1/4 doped (quat-doped) solution, which comprises a compound of formula 1 rot tributyl citric acid in the present invention (I) in triethylene glycol butyl (butyl triglycol); and optionally other stabilizers;

[0345] c)混合物或溶液,其包括本发明的式(I)的化合物和烷基吡咯烷酮;以及任选的其它稳定剂。 [0345] c) a mixture or solution, which comprises formula (I) and a compound of the present invention alkylpyrrolidones; and optionally other stabilizers.

[0346] 本发明的身体护理产品的实例列于下表中: [0346] Examples of body care products of the present invention are listed in the following table:

[0347] [0347]

Figure CN101277674BD00541

[0348]家用产品 [0348] household products

[0349] 本发明的稳定剂体系也用于家用清洁和处理剂中,例如用于洗衣用产品和织物软化剂、液体清洁和擦洗剂、玻璃洗涤剂、中性清洁剂(多用途清洁剂)、酸性家用清洁剂(沐浴)、浴室清洁剂、WC清洁剂、例如洗涤、漂洗和餐具洗涤剂、厨房和炉灶清洁剂、透明漂洗齐ϋ、洗碗机用洗涤剂、鞋油、上光蜡、地板洗涤剂和抛光剂、金属、玻璃和陶瓷清洁剂、织物护理剂、毯类清洁剂和地毯洗涤剂、去锈、去色和去污溃剂(去污溃盐)、家具和多用抛光剂以及皮革和乙烯基树脂修饰剂(皮革和乙烯基树脂喷剂)以及固体和液体空气清新剂。 [0349] The stabilizer system according to the present invention are also used in household cleaning and treatment agents, for example in laundry products and fabric softeners, liquid cleansing and scouring agents, glass detergents, neutral cleaners (all-purpose cleaners) , acid household cleaners (bath), bathroom cleaners, the WC cleaners, such as washing, rinsing and dishwashing detergent, kitchen and oven cleaners, clear rinsing Qi ϋ, dishwasher detergents, shoe polishes, polishing waxes, floor detergents and polishes, metal, glass and ceramic cleaners, textile care agents, rug cleaners and carpet shampoos, for removing rust, color removal and decontamination agent ulcer (ulcer detersive salt), furniture and multipurpose polishes and leather and vinyl resin modifiers (resins leather and vinyl sprays) and solid and liquid air fresheners.

[0350] 家用清洗剂是具有一种或多种以下组分的含水或醇(乙醇或异丙醇)的溶液: [0350] Household cleaning agents are aqueous or an alcohol having one or more of the following components (ethanol or isopropanol) was:

[0351]-阴离子、非离子、两性的和/或阳离子表面活性剂; [0351] - anionic, nonionic, amphoteric and / or cationic surfactant;

[0352]-皂,通过皂化动物和植物油脂而制备; [0352] - soaps, prepared by saponification of animal and vegetable fats and oils;

·[0353]-有机酸,如盐酸、磷酸或硫酸; * [0353] - organic acids, such as hydrochloric, sulfuric or phosphoric acid;

[0354]-对于碱性产品,无机碱(NaOH或Κ0Η)或有机碱; [0354] - for the basic product, an inorganic base (NaOH or Κ0Η) or an organic base;

[0355]-用于改善表面清洁的磨料; [0355] - for improving surface cleaning abrasive;

[0356]-用于保持和保护表面的蜡和/或有机硅; [0356] - for holding and protecting the surface of the wax and / or silicone;

[0357]-聚磷酸盐(酯); [0357] - polyphosphates (ester);

[0358]-除去次氯酸盐或卤素的物质; [0358] - removing substances hypochlorite or halogen;

[0359]-过氧化物,其包括漂白活性剂如TAED,例如过硼酸钠或H2O2 ; [0359] - peroxides comprising bleach activators such as TAED, for example sodium perborate or by H2O2;

[0360]-酶; [0360] - enzymes;

[0361]-洗漆剂中的脱色抑制剂(discoloration inhibitor)、去污化合物、灰度抑制剂(gray scale inhibitor)、泡沫抑制剂、突光增白剂; [0361] - removers in discoloration inhibitor (discoloration inhibitor), soil release compounds, gray scale inhibitors (gray scale inhibitor), suds suppressors, optical brighteners projection;

[0362]-基于蜡的清洗剂可包括选自汽油(benzine)、松节油和/或石蜡的溶剂和基于蜡的乳化剂; [0362] - cleaning agents based on wax may include those selected from gasoline (benzine), turpentine, and / or solvent-based paraffin wax and an emulsifier;

[0363]-填充剂如硅酸盐,聚磷酸盐,用于粉状清洗剂的沸石(Zeolithes); [0363] - fillers such as silicates, polyphosphates, the zeolite powder detergent (Zeolithes);

[0364]-颜料,色淀或可溶染料; [0364] - pigments, lakes or soluble dyes;

[0365]-香料;和 [0365] - spices; and

[0366]-光稳定剂、抗氧化剂和螯合剂。 [0366] - light stabilizers, antioxidants and chelating agents.

[0367] 有色的清洗剂和美饰用化妆品产品可包括以下染料: [0367] The cleaning agent a colored decorative beauty cosmetic item comprising the following dyes:

[0368]-无机颜料,例如氧化铁(氧化铁红、氧化铁黄、氧化铁黑等),群青(Ultramarines),氧化铬绿或碳黑; [0368] - inorganic pigments, for example iron oxide (red iron oxide, yellow iron oxide, black), ultramarine (the Ultramarines), chromium oxide green, or carbon black;

[0369]-天然或合成的有机颜料; [0369] - natural or synthetic organic pigments;

[0370]-可溶于溶剂中的分散染料,如HC型直接染发剂,如HC红No. 3,HC蓝No. 2以及列于1997 年第7 版的International Cosmetic IngredientDictionary and Handbook 中的所有其他染发剂或列于Color IndexInternational 或Society of Dyes and Colourists中的分散染料; [0370] - disperse dye may be dissolved in a solvent, such as HC type direct dyes, such as HC Red No. 3, HC Blue No. 2, 1997, and listed in the 7th edition of International Cosmetic IngredientDictionary and Handbook All other or dyes listed in the Color IndexInternational or Society of Dyes and Colourists disperse dye;

[0371]-彩色清漆(可溶性染料的不溶性盐,如阴离子染料的多种Ca盐、Ba盐或Al盐); [0371] - color varnishes (insoluble salts of soluble dyes, such as various anionic dyes Ca salt, Ba salt, or Al salt);

[0372]-可溶性阴离子或阳离子染料,如酸性染料(阴离子)、碱性染料(阳离子)、直接染料、活性染料或溶剂染料。 [0372] - soluble anionic or cationic dyes such as acid dyes (anionic), basic dyes (cationic), direct dyes, reactive dyes or solvent dyes.

[0373] 一般而言,对于家用制品和身体护理品的着色,在电磁辐射的可见光(波长约为400-700nm)中具有吸收作用的所有物质都是适宜的。 All substances [0373] Generally, for the coloration of household articles and body care products, having absorption in the visible electromagnetic radiation (wavelength approximately 400-700 nm) in it is suitable. 所述吸收通常由以下发色团所致:[0374] 偶氮-(一-、二-、二-或多-)均二苯乙烯-、类胡萝卜素-、二芳基甲烧-、二芳基甲烷_、咕吨_、吖啶_、喹啉、次甲基_(还有聚甲炔_)、噻唑-J引达胺_、靛酚_、吖嗪_、囉嗪_、噻嗪_、蒽醌_、靛青_、酞菁-以及其他合成的、天然的和/或无机发色团。 The absorbent is typically caused by the following chromophores: [0374] Azo - (a -, two -, di - or -) stilbene -, carotenoid -, diaryl burn -, di aryl _ methane, xanthene _, _ acridine, quinoline, methine _ (_ there polymethine), thiazole Indapamide -J _, _ indophenol, azine _, _ La triazine, thiophene _ piperazine, anthraquinone _, _ indigo, phthalocyanine - and other synthetic, natural and / or inorganic chromophores.

[0375] 本发明还涉及家庭护理和织物护理品如排水清洁剂、消毒液、室内装饰清洁剂、汽车护理用品(如清洁和/或抛光及保护油漆、轮胎、铬钢、乙烯基树脂、皮革、织物、橡胶、塑料和纤维)、脱脂剂、抛光剂(玻璃、木材、皮革、塑料、大理石、花岗岩和瓷砖等)、以及金属抛光剂和清洁剂。 [0375] The present invention further relates to home care and fabric care products such as drain cleaners, disinfectant, upholstery cleaners, automotive care products (e.g., cleaning and / or polishing and protective paint, tires, chrome steel, vinyl, leather , fabric, rubber, plastic and fabric), degreasers, polishes (glass, wood, leather, plastic, marble, granite, and tile, etc.), and metal polishes and cleaners. 抗氧化剂适于保护上述制品和干燥床单中的香料。 Antioxidants suitable for protecting said article and drying linen perfume. 本发明也涉及家用护理制品如蜡烛、凝胶蜡烛、空气清新剂和香精油(家用)。 The present invention also relates to home care products such as candles, gel candles, air fresheners and essential oils (home).

[0376] 家用清洁剂和处理剂的通常实例如下表所列: [0376] Examples in the following table typically household cleaning and treating agents listed:

[0377] [0377]

Figure CN101277674BD00561

[0378] 本发明的式(I)的稳定剂例如通过溶解而结合到油相或醇或水相中,需要时该过程在高温进行。 [0378] The stabilizers of the present invention of formula (I), for example, incorporated into the oil phase or alcoholic or water phase prepared by dissolving, if necessary for the process at high temperatures.

[0379] 本发明的身体护理产品和家用产品对存在于这些产品中的成分的颜色变化和化学降解具有高稳定性。 [0379] The body care products and household products according to the present invention is present in the composition of the products of these color changes and chemical degradation of high stability. 例如,发现本发明的包括染料的组合物具有优良的颜色稳定性。 For example, the dye found to include compositions of the present invention has excellent color stability.

[0380] 以下实施例说明本发明。 The present invention will be described [0380] The following Examples.

[0381] 在以下实施例中使用下表中列出的稳定剂: [0381] use of a stabilizer in the table below in the following examples:

[0382] [0382]

Figure CN101277674BD00571

[0383] [0383]

Figure CN101277674BD00581
Figure CN101277674BD00591

[0385] 与现有技术的稳定剂的效力比较 [0385] Compared with the effectiveness of the stabilizer of the prior art

[0386] 实施例I : [0386] Example I:

[0387] 制备以下有色基础香波制剂(basic shampoo formulation): [0387] The following base shampoo formulation colored (basic shampoo formulation) were prepared:

[0388]月桂基聚氧乙烯醚硫酸钠(Sodium Laureth Ether Sulfate) 10% [0388] polyoxyethylene lauryl ether sulfate (Sodium Laureth Ether Sulfate) 10%

[0389] 椰油酰胺基丙基甜菜碱 3% [0389] Cocamidopropyl betaine 3%

[0390] 柠檬酸 至pH 5 [0390] Citric acid to pH 5

[0391] FD&C Blue No. I O. 002% [0391] FD & C Blue No. I O. 002%

[0392] 稳定剂 适量(qa) [0392] Stabilizer suitable amount (QA)

[0393] 对于光稳定试验,制备该制剂的以下经稳定的和未经稳定的样品: [0393] For the light stability tests, the formulation prepared in the following stabilized and unstabilized samples of:

[0394] I.未经稳定的基础香波制剂 [0394] I. unstabilized base shampoo formulation

[0395] 2.基础香波制剂加0.05%的式(A0 07)的化合物 Compound [0395] 2. The base shampoo formulation with 0.05% of the formula (A0 07) of

[0396] 3.基础香波制剂加0.05%的式(101)的化合物 Compound [0396] 3. The base shampoo formulation with 0.05% of the formula (101)

[0397] 4.基础香波制剂加0.05%的式(102)的化合物 Compound [0397] 4. The base shampoo formulation with 0.05% of the formula (102)

[0398] 5.基础香波制剂加0.05%的式(103)的化合物 Compound [0398] The shampoo base formulation with 0.05% of the formula (103)

[0399] 6.基础香波制剂加0.05%的式(104)的化合物 Compound [0399] 6. The base shampoo formulation with 0.05% of the formula (104)

[0400] 7.基础香波制剂加0.05%的式(105)的化合物 Compound [0400] 7. A shampoo base formulation with 0.05% of the formula (105)

[0401] 将该制剂填充到30ml玻璃瓶中,并在ATLAS Suntest XLS+ XenonLamp(光强500W/m2,光谱调节至室内条件,样品室温度:32°C )中照射。 [0401] The formulation was filled into 30ml glass vials, and ATLAS Suntest XLS + XenonLamp (light intensity 500W / m2, spectrum adjusted to ambient conditions, the sample chamber temperature: 32 ° C) irradiation.

[0402] 结果如下表所列。 [0402] The results listed in the following table.

[0403] [0403]

[0404] [0404]

Figure CN101277674BD00592
Figure CN101277674BD00601

[0405] 与式(A0 07)的现有技术的UV吸收剂相比,包括本发明稳定剂的样品3_7显示出显著更好的光稳定性。 The prior art [0405] of the formula (A0 07) compared to the UV absorbers, the present invention comprises a stabilizer 3_7 samples show significantly better light stability.

[0406] 实施例2 : [0406] Example 2:

[0407] 制备以下有色基础香波制剂: [0407] The following colored basic shampoo formulation was prepared:

[0408] 月桂基聚氧乙烯醚硫酸钠 10% [0408] polyoxyethylene lauryl ether sulfate 10%

[0409] 椰油酰胺基丙基甜菜碱 3% [0409] Cocamidopropyl betaine 3%

[0410] 柠檬酸 至pH 5 [0410] Citric acid to pH 5

[0411] FD&C Blue No. I O. 002% [0411] FD & C Blue No. I O. 002%

[0412] 稳定剂 适量 [0412] Stabilizer suitable amount

[0413] 对于光稳定试验,制备该制剂的以下经稳定的和未经稳定的样品: [0413] For the light stability tests, the formulation prepared in the following stabilized and unstabilized samples of:

[0414] I.未经稳定的基础香波制剂 [0414] I. unstabilized base shampoo formulation

[0415] 2.基础香波制剂加O. 05%的式(A0 07)的化合物 Compound [0415] 2. The base shampoo formulation plus O. 05% of formula (A0 07) of

[0416] 3.基础香波制剂加O. 05%的式(A0 07)的化合物加O. 003%的化合物(A002) Compound plus O. [0416] 3. Add base shampoo formulation O. 05% of formula (A0 07) 003% of compound (A002)

[0417] 4.基础香波制剂加O. 05%的式(104)的化合物。 Compound [0417] 4. The base shampoo formulation plus O. 05% of formula (104).

[0418] 将该制剂填充到30ml玻璃瓶中,并在ATLAS Suntest XLS+ XenonLamp(光强500W/m2,光谱调节至室内条件,样品室温度:32°C )中照射。 [0418] The formulation was filled into 30ml glass vials, and ATLAS Suntest XLS + XenonLamp (light intensity 500W / m2, spectrum adjusted to ambient conditions, the sample chamber temperature: 32 ° C) irradiation.

[0419] 结果如下表所列。 [0419] The results listed in the following table.

[0420] [0420]

Figure CN101277674BD00602

[0421] 样品4包括本发明的稳定剂。 [0421] Sample 4 of the present invention comprises a stabilizer. 与式(A0 01)的现有技术UV吸收剂相比,样品4显示出显著更好的光稳定性,并且与样品3的高度有效稳定剂组合相比,甚至具有更好的光稳定性。 Compared to the formula (A0 01) of the prior art UV absorbers, 4 samples showed significantly better light stability, as compared stabilizer compositions are highly effective and Sample 3, having even better light stability.

[0422] 实施例3 : [0422] Example 3:

[0423] 对于抗氧化试验,制备该制剂的以下经稳定的和未经稳定的样品: [0423] For the oxidation test, the formulations prepared by the following non-stabilized and stabilized sample:

[0424] I.纯亚油酸 [0424] I. pure linoleic acid

[0425] 2.含有O. 05%式(104)化合物的亚油酸。 [0425] 2. O. compound containing 05% linoleic acid of formula (104).

[0426] 将样品置于RACIMAT中,并加热至80°C。 [0426] The samples were placed RACIMAT and heated to 80 ° C. 调节空气流为15L/min。 Adjusting the air flow of 15L / min. 将空气流鼓泡经过每个加热的样品,并且然后经过储水器。 The air flow was bubbled through each sample is heated, and then through the reservoir. 由此,空气流将由氧化过程所形成的挥发性所有有机化合物带入储水器中。 Thus, all the volatile organic compounds by the air flow into the formed oxidation process water reservoir. 在测量的过程中联机监测储水器的传导性(conductivity)。 In the course of the measurement line conductivity monitor of the reservoir (conductivity). 一旦氧化反应开始,挥发性有机化合物如甲酸就被运送至储水器中,这导致传导性的迅速(指数级)增加。 Once oxidation starts volatile organic compounds like formic acid was delivered to the reservoir, which results in conductivity rapidly (exponentially) increases. 直到氧化开始的时间称为“诱发时间”。 Time until oxidation starts is called the "induction time."

[0427] 结果列于下表。 [0427] The results are shown in the following table.

[0428] [0428]

Figure CN101277674BD00611

[0429] 与未经稳定的样品相比,包括本发明稳定剂的样品2显示出更好的氧化稳定性。 [0429] compared to the unstabilized samples of the present invention include stabilizers Sample 2 exhibited better oxidative stability.

[0430] 实施例4-15 :制备身体护理和家用制剂 Body care and household formulations was prepared: [0430] Example 4-15

[0431] [0431]

Figure CN101277674BD00612

[0432]制各: [0432] Each system:

[0433] 在室温分散组分(A)。 [0433] dispersing component (A) at room temperature.

[0434] 对(B)加热混合,直到该对羟基苯甲酸甲酯完全溶解,然后在温和搅拌下将(B)加到(A)中。 [0434] (B) of heating and mixing until the methylparaben was completely dissolved, with gentle stirring and then (B) was added in (A).

[0435] 混合(C)直到它完全溶解,然后在搅拌下将其缓慢加到㈧和⑶的混合物中。 [0435] mixing (C) until it is completely dissolved, then the mixture under stirring and slowly added to (viii) of ⑶.

[0436] 可通过加入少量的三乙醇胺(pH = 5. 6-5. 75)来增加该凝胶的透明度。 [0436] can be obtained by adding a small amount of triethanolamine (pH = 5. 6-5. 75) to increase the transparency of the gel.

[0437] [0437]

Figure CN101277674BD00621

[0438] 制备:混合表面活性剂和水直到得到均匀的溶液。 [0438] Preparation: mixing a surfactant and water until a homogeneous solution was obtained. 用柠檬酸将pH调节至6. 0-6. 5,并且以指定的顺序加入其它组分。 Adjusted with citric acid to pH 6. 0-6. 5, and in the order specified additional components. 搅拌该混合物,直到它完全溶解。 The mixture is stirred until it is completely dissolved.

[0439] [0439]

Figure CN101277674BD00622

[0440] 迦备:将组分以指定的顺序在50°C充分混合。 [0440] Gad Preparation: The components are thoroughly mixed in the order specified 50 ° C. 获得透明均匀的溶液。 Obtain a transparent homogeneous solution.

[0441] [0441]

Figure CN101277674BD00631

[0443] [0443]

Figure CN101277674BD00632
Figure CN101277674BD00641

[0444] [0444]

Figure CN101277674BD00642

[0445] [0445]

Figure CN101277674BD00651

[0447] [0447]

Figure CN101277674BD00661

[0448] 家用广品制剂的制备 Household products prepared wide formulation [0448]

[0449] [0449]

Figure CN101277674BD00662

[0450] ■:将组分以指定的顺序溶解,直到获得透明均匀的溶液。 [0450] ■: The ingredients in the order specified dissolution, until a clear homogeneous solution.

[0451] [0451]

Figure CN101277674BD00663

Claims (12)

1.式(I)的稳定剂用于保护身体护理产品和家用产品免受光解和氧化降解的用途: 1. Formula (I) as stabilizers for the protection of body care products and household products from photolytic and oxidative degradation by:
Figure CN101277674BC00021
,其中Lp L2或L3各自独立地为氢;轻基! Wherein Lp L2 or L3 are each independently hydrogen; light-yl! C1-C22烧基! C1-C22 burn-yl! C1-C22烧氧基;C7-C2(I芳烧基;C6_C2(I芳基;C4-C9杂芳基;或COOR9 ; R4 是CN ;-COR7 ;-COOR7 -SO2R7 ;-CONR7R8 ;C「C22 烷基;C7-C20 芳烷基;C「C20 杂烷基;C6-C20 芳基; R5> R6> R7 和R8 各自独立地为氢;C「C22 烷基;-(CH2) u-SiR15R16R17 ;或基团-X-Sil ; R9是氢;C1-C22烧基;或L1和l2、或L1和L3、或L2和L3—起形成选自 C1-C22 alkoxy burning; C7-C2 (I burn aryl group; C6_C2 (I aryl group; C4-C9 heteroaryl; or COOR9; R4 is CN; -COR7; -COOR7 -SO2R7; -CONR7R8; C "C22 alkyl; C7-C20 arylalkyl; C "heteroalkyl C20 alkyl; C6-C20 aryl group; R5> R6> R7 and R8 are each independently hydrogen; C" to C22 alkyl ;-( CH2) u-SiR15R16R17; or a group -X-Sil; R9 is hydrogen; C1-C22 burn group; or L1 and L2, or L1 and L3, and L2 or form selected from L3-
Figure CN101277674BC00022
Figure CN101277674BC00023
或* T的二价基团; R1和R2 —起形成选自 * T or a divalent group; Rl and R2 - together form selected
Figure CN101277674BC00024
的二价基团;或民和民一起形成选自 Or together form a group selected people and people; divalent radical
Figure CN101277674BC00025
Figure CN101277674BC00026
的二价碳环基团或二价杂环基团; 并且每个烧基、稀基、块基、环烧基或亚环烧基是未取代的或被一个或多个R11取代;并且每个芳基、杂芳基、芳烷基、亚芳基、亚杂芳基或亚芳烷基是未取代的或被一个或多个R12取代; R10 是R13 ; COR13 ; COOR13 ;或CONR13R14 ; R11 是卤素、OH ;NR15R16 ;O-R15 ;S-R15 ;O-CO-R15 ;CO-R15 ;氧代;硫羰基;CN ;COOR15 ;CONR15R16 ;SO2NR15R16 ;SO2R15 ;SO3R15 ;SiR15R16R17 ;0SiR15R16R17 ;P0R15R16 ;或基团-X-Sil ; R12是C1-C12烷硫基、C3-C12环烷基硫基、C1-C12烯基硫基、C3-C12环烯基硫基、C1-C12烷氧基、C3-C12环烧氧基、C1-C12稀基氧基或C3-C12环稀基氧基,所述C1-C12烧硫基、C3-C12环烷基硫基、C1-C12烯基硫基、C3-C12环烯基硫基、C1-C12烷氧基、C3-C12环烷氧基、C1-C12烯基氧基或C3-C12环烯基氧基是未取代的或被一个或多个下述基团取代=R11 ;卤素;CN ;SH ;0H ;CHO ;R Bivalent carbocyclic group or a divalent heterocyclic group; and each firing group, dilute group, the block group, a cycloalkyl group or a cycloalkylene burn burn group is unsubstituted or substituted with one or more R11; and each aryl group, a heteroaryl group, an aralkyl group, an arylene group, heteroarylene group, or aralkylene group is unsubstituted or substituted by one or more substituents R12; R10 is R13; COR13; COOR13; or CONR13R14; R11 is halogen, OH; NR15R16; O-R15; S-R15; O-CO-R15; CO-R15; oxo; thiocarbonyl group; CN; COOR15; CONR15R16; SO2NR15R16; SO2R15; SO3R15; SiR15R16R17; 0SiR15R16R17; P0R15R16; or a group -X-Sil; R12 is C1-C12 alkylthio, C3-C12 cycloalkyl group, C1-C12 alkenyl group, C3-C12 cycloalkenyl group, C1-C12 alkoxy, C3 burning -C12 cycloalkyl group, a C1-C12 group or a dilute group dilute C3-C12 cycloalkyl group, a C1-C12 alkylthio burning, C3-C12 cycloalkyl group, C1-C12 alkenyl group, C3-C12 cycloalkenyl group, C1-C12 alkoxy, C3-C12 cycloalkoxy, C1-C12 alkenyl group or a C3-C12 cycloalkenyl group is unsubstituted or substituted by one or more substituted following groups = R11; halogen; CN; SH; 0H; CHO; R 18 ;0R18 ;SR18 ;C (R18) = CR19R20 ;O-CO-R19 ;NR18R19 ;CONR18R19 ;SO2NR18R19 ;SO2R18 ;COOR18,OCOOR18 ;NR18COR19 ;NR19COOR20 ;SiR15R16R17 ;0SiR15R16R17 ;P( = 0)R19R20 ;或基团-X-Sil ;R13、R14、R15、R16、R17、R18、R19 和R20 各自独立地为氢;C1-C22 烷基;c3-c12 环烷基;C2-C12 烯基;C3-C12环烯基;C6-C14芳基;C4-C12杂芳基;C7-C18芳烷基;或C5-C16杂芳烷基;或R13和R14、R15和R16、R16和R17和/或R18和R19连接到一起形成未取代的或C1-C4烷基取代的吡咯烷、哌啶、哌嗪或吗啉; X是连接基团;和Sil是硅烷部分,低聚硅氧烷部分或聚硅氧烷部分; t是O至12的数; u是I至12的数; V是O至12的数; 如果η = 1, 则R1和R2各自独立地为C1-C12烷基;羟基-C1-C12烷基;苯基或苯基-C1-C5烷基,其任选被C1-C5烷基或SO3M中的一个或多个取代;或式 18; 0R18; SR18; C (R18) = CR19R20; O-CO-R19; NR18R19; CONR18R19; SO2NR18R19; SO2R18; COOR18, OCOOR18; NR18COR19; NR19COOR20; SiR15R16R17; 0SiR15R16R17; P (= 0) R19R20; or a group - X-Sil; R13, R14, R15, R16, R17, R18, R19 and R20 are each independently hydrogen; C1-C22 alkyl; c3-c12 cycloalkyl; C2-C12 alkenyl; C3-C12 cycloalkenyl group ; C6-C14 aryl group; C4-C12 heteroaryl group; C7-C18 aralkyl; or C5-C16 heteroaryl group; or R13 and R14, R15 and R16, R16 and R17 and / or R18 and R19 are connected to the together form an unsubstituted or C1-C4 alkyl-substituted pyrrolidine, piperidine, piperazine or morpholine; X is a linking group; and a silane portion Sil, oligosiloxane or polysiloxane moiety portion; t is a number from O to 12; and U is the number of I to 12; and V is a number from O to 12; If η = 1, then R1 and R2 are each independently C1-C12 alkyl; -C1-C12 alkyl hydroxy ; phenyl or phenyl -C1-C5 alkyl optionally substituted with C1-C5 alkyl or SO3M one or more; or of formula
Figure CN101277674BC00031
的基团; 或R1和R2 —起形成选自 Radicals; or R1 and R2 - together form selected
Figure CN101277674BC00032
的二价基团; R21、R22、R23各自独立地为C1-C22烧基;或C1-C22烧氧基; A是连接至连接基团X的键; R3 是CN ;NR5R6「C0R5 ;-C00R5 ;-SO2R5 ;-CONR5R6 ;C6-C20 芳基;或C4-C9 杂芳基; P是O至100的数; q是I ; s是O至4的数; 如果η = 2, 则R1和R2各自为选自C1-C5亚烷基的二价基团,其任选被一个或多个氧原子隔断;或R1和R2与所述氮原子一起形成六元杂环;并且同时R3如η = I时所定义;或R3是式-CO-V1-C1-C12亚烷基-W1-*的二价基团,其中星号表示连接至第二R3的键; V1是-O-;或-NR7-;或直接键; W1是连接至第二R3的连接基团,其中W1是直接键;或选自C1-C12亚烷基;或亚苯基;和同时R1和R2如η = I时所定义; 如果η = 3, 则Rp R2或R3之一为三价基团,其它如η = I时所定义; 如果η = 4,则R1或R2是式 A divalent group; R21, R22, R23 are each independently a C1-C22 group burning; burning or C1-C22 alkoxy; A is connected to the connecting group X bond; R3 is CN; NR5R6 'C0R5; -C00R5 ; -SO2R5; -CONR5R6; C6-C20 aryl group; C4-C9 heteroaryl, or aryl; P is a number from O to 100; Q is I; s is a number from O to 4; if η = 2, then R1 and R2 are each selected from C1-C5 divalent alkylene group, optionally substituted by one or more oxygen atoms partition; or R1 and R2 form a six-membered heterocyclic ring together with the nitrogen atom; and R3 simultaneously as η = when I as defined; or R3 is of formula -CO-V1-C1-C12 alkylene group -W1- * a divalent group, wherein the asterisk indicates the bond to the second R3; Vl is -O-; or - NR7-; or a direct bond; W1 is R3 is connected to the second connection group, wherein W1 is a direct bond; or a group selected from C1-C12 alkylene; or phenylene; and R1 and R2 are simultaneously such as when η = I as defined above; if defined as η = 3, then one of R2 or R3 Rp is a trivalent group, such as other η = I; if η = 4, then R1 or R2 is of the formula
Figure CN101277674BC00041
的基团,其中星号表示连接至第二、 第三和第四R1ZiR2的键; W2 是 Group, where the asterisk indicates that the connection to the second, third, and fourth R1ZiR2 bond; W2 of a
Figure CN101277674BC00042
R3如η = I时所定义;或R3是式 R3 are as defined when η = I; or R3 is of formula
Figure CN101277674BC00043
的基团,其中星号表不连接至第一(2)、 第三(3)和第四(4) R3的键;和 Group, wherein the asterisk is not connected to the first table (2), third (3) and a fourth key (4) R3 is; and
Figure CN101277674BC00044
或R1 或R2 是式 Or R1 or R2 is of the formula
Figure CN101277674BC00045
的基团; 星号表示连接至第二、第三和第四R1ZiR2的键; R24是C1-C22焼基;或C1-C22焼氧基。 Group; the asterisk indicates that the connection to the second, third, and fourth R1ZiR2 bond; R24 is C1-C22 ware group; or C1-C22 firing group.
2.权利要求I的用途,其中所述稳定剂对应于式(2a)、(2b)或(2c): 2. The use of claim I, wherein said stabilizing agent corresponds to the formula (2a), (2b) or (2c):
Figure CN101277674BC00051
其中R1' R2、R3> R4> L1, L2、L3J1和W2如权利要求I中所定义。 Wherein R1 'R2, R3> R4> L1, L2, L3J1 and W2 are as defined in claim I required.
3.权利要求I的用途,其中所述稳定剂对应于式(3a)或(3b): The use of claim I, wherein said stabilizing agent corresponds to the formula (3a) or (3b):
Figure CN101277674BC00052
H 1?3、1?4山、“ W2和W3如权利要求I中所定义。 H 1? 3,1? 4 Hill, "W2 and W3 are defined as claimed in claim I.
4.权利要求I至3中任一项的光稳定剂在用于皮肤及其附件的身体护理产品中的用途。 I 4. The use as claimed in claim any one of the light stabilizer 3 of body care products for the skin and its accessories.
5.权利要求4的用途,其中所述身体护理产品选自护肤剂、沐浴和淋浴添加剤、含有香料和芳香物质的制品、护发产品、洁齿剂、除臭和止汗制品、美饰剂、光防护制剂和含活性成分的制品。 4 The use of hair care products, dentifrices, deodorizing and antiperspirant article, embellishing claim, wherein said body care product is selected from skin care agents, bath and shower added Ji, products containing fragrances and fragrance, agents, light protection formulations and products containing the active ingredient.
6.权利要求4的用途,其中所述身体护理产品选自洁身油、爽身水、洁身胶、护理霜、护肤膏、剃须制剂和爽身粉。 The use of claim 4, wherein said body care product is selected from the bidet oils, body lotions, body gum clean, care cream, skin cream, shaving preparations and talcum powder.
7.权利要求4的用途,其中所述制品含有香料、盥洗用香水和剃须液。 The use of claim 4, wherein said article comprises perfume, toilet waters and shaving lotions.
8.权利要求4的用途,其中所述身体护理产品是护发产品,并且选自用于定型和处理毛发的产品。 The use of claim 4, wherein said body care products are hair care products, and selected for styling and treating hair products.
9.权利要求4的用途,其中所述身体护理产品是美饰剂,并且选自干和湿化妆品。 9. The use as claimed in claim 4, wherein said body care product is a decorative preparations, cosmetics and is selected from dry and wet.
10.权利要求4的用途,其中所述化妆品制品含有活性成分,并且选自激素制剂、维生素制剂、植物提取物制剂和抗菌制剂。 10. The use as claimed in claim 4, wherein the cosmetic preparations containing active ingredients, and are selected from hormone preparations, vitamin preparations, vegetable extract preparations and antibacterial preparations.
11.权利要求I至3中任一项的光稳定剂在家用清洁和处理剂中的用途。 3 to 11. I use a light stabilizer of any one of the household cleaning and treating agent as claimed in claim.
12.权利要求11的用途,其中所述家用清洁和处理剂选自洗涤剂;漂洗剂;鞋油;上光蜡;抛光剂;多用清洁剂;汽车香波和蜡;中性、酸性和碱性清洁剂;金属、玻璃和陶瓷清洁剂;织物护理剂;去锈、去色和去污溃剂;漂白剤;家具和多用抛光剂;表面防护制剂;成膜制剂;空气清新剂和蜡烛。 12. The use as claimed in claim 11, wherein said household cleaning and treating agents are selected from detergents; rinsing agent; shoe polish; polishing waxes; polishing agent; multi-purpose cleaners; car shampoos and waxes; neutral, acidic and alkaline cleaning agents; metal, glass and ceramic cleaners; fabric care agents; to rust, color and to collapse decontamination agent; bleaching Ji; furniture and multipurpose polishes; protective surface preparation; forming formulation; air fresheners and candles.
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