CN101275746A - New Waste Incineration Flue Gas Purification System and Purification Process - Google Patents

New Waste Incineration Flue Gas Purification System and Purification Process Download PDF

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CN101275746A
CN101275746A CNA2007103039681A CN200710303968A CN101275746A CN 101275746 A CN101275746 A CN 101275746A CN A2007103039681 A CNA2007103039681 A CN A2007103039681A CN 200710303968 A CN200710303968 A CN 200710303968A CN 101275746 A CN101275746 A CN 101275746A
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flue gas
gas
fluidized bed
outlet
particles
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董长青
杨勇平
张俊姣
何磊
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North China Electric Power University
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Abstract

The invention belongs to the waste gas handling technical field, particularly a novel waste burning gas cleaning system and the cleaning technology, wherein the system includes a dump dry type gas washing tower, a circulating fluid bed, a bag dust collector and a fan, and the cleaning technology is: the gas enters the dump dry type gas washing tower through the gas entry, which removes the sour gas in the gas; the cleaned gas enters the circulating fluid bed through the tower gas outlet, which removes the water and the residue sour gas, and enters the bag dust collector through the gas outlet of the circulating fluid bed; the bag dust collector filters the fine dust particles, the neutralizer particles, the deacidification reaction product particles and the active carbon particles in the gas, the cleaned gas is discharged into the air through the fan and the chimney. The system and the technology of the invention can greatly advance the cleaning capacity to the gas with wide accommodation limit and regulating range, low cost.

Description

新型废弃物焚烧烟气净化系统及净化工艺 New Waste Incineration Flue Gas Purification System and Purification Process

技术领域 technical field

本发明属于废气处理技术领域,特别涉及一种新型废弃物焚烧烟气净化系统及净化工艺。The invention belongs to the technical field of waste gas treatment, and in particular relates to a novel waste incineration flue gas purification system and purification process.

背景技术 Background technique

目前对含有较多可燃成份的废弃物通常采用焚烧的方式进行减量化和无害化处理,采用常规焚烧系统往往产生新的污染物,如酸性气体(SO2、NO等)、二恶英等。这些污染物会破坏大气环境,还会对人体造成危害,因此焚烧后的烟气必须得到净化。国家专利“工业危险废弃物焚烧处理系统”(专利号:02235414.X)采用的烟气净化系统由水洗气塔和布袋除尘器组成,国家专利“工业区危险废弃物集中焚烧综合处理系统”(专利号:200420050509.9)采用的烟气净化系统由喷淋塔、袋除尘器和二次袋除尘器组成,这些烟气净化系统虽然可以较有效地去除酸性气体等污染物,但烟气中的水分无法有效去除,这样会造成布袋除尘器内部腐蚀,使用寿命缩短。再者,因为焚烧的废弃物品种繁多,所生成的污染物产量波动较大,因此只用洗气塔无法保证污染物的彻底去除。在管道或洗气塔中喷入活性炭或消石灰,虽然可以进一步吸附污染物,减少它们的排放,但由于不能充分接触,活性炭或消石灰对污染物的吸附效果不佳。并且,由于对污染物量的不可估量,当污染物量较少时会造成活性炭或消石灰的浪费。本发明针对以上废弃物焚烧烟气净化系统所出现的问题,旨在提高焚烧烟气的净化处理能力,降低处理成本,而提供一种新型废弃物焚烧烟气净化系统。At present, wastes containing more combustible components are usually reduced and harmlessly treated by incineration. Conventional incineration systems often produce new pollutants, such as acid gases (SO 2 , NO, etc.), dioxins, etc. wait. These pollutants will damage the atmospheric environment and cause harm to the human body, so the flue gas after incineration must be purified. The flue gas purification system used in the national patent "incineration treatment system for hazardous waste in industrial areas" (patent number: 02235414.X) is composed of a water scrubber tower and a bag filter. Patent No.: 200420050509.9) The flue gas purification system used is composed of a spray tower, a bag filter and a secondary bag filter. Although these flue gas purification systems can effectively remove pollutants such as acid gases, the moisture in the flue gas It cannot be effectively removed, which will cause internal corrosion of the bag filter and shorten the service life. Furthermore, because there are many types of wastes incinerated, the output of pollutants generated fluctuates greatly, so only using scrubbers cannot guarantee the complete removal of pollutants. Spraying activated carbon or hydrated lime into pipelines or scrubbers can further adsorb pollutants and reduce their emissions, but due to insufficient contact, activated carbon or hydrated lime has poor adsorption effects on pollutants. Moreover, due to the immeasurable amount of pollutants, when the amount of pollutants is small, it will cause waste of activated carbon or slaked lime. The present invention aims at improving the purification and treatment capacity of the waste incineration flue gas and reducing the treatment cost in order to provide a novel waste incineration flue gas purification system for the above problems in the waste incineration flue gas purification system.

发明内容 Contents of the invention

本发明为了现有技术中存在的问题,特别涉及一种新型废弃物焚烧烟气净化系统及净化工艺。The present invention solves the problems existing in the prior art, and in particular relates to a novel waste incineration flue gas purification system and purification process.

本发明的技术方案如下:Technical scheme of the present invention is as follows:

一种新型废弃物焚烧烟气净化系统,该系统由半干式洗气塔1、循环流化床4、布袋除尘器7和风机10组成;A new waste incineration flue gas purification system, the system consists of a semi-dry scrubber 1, a circulating fluidized bed 4, a bag filter 7 and a fan 10;

所述半干式洗气塔1顶部设有烟气进口2,内部装有雾化器;The top of the semi-dry scrubber 1 is provided with a flue gas inlet 2, and an atomizer is installed inside;

所述循环流化床4的底部设有流化床进气口5,与洗气塔出气口3相通;循环流化床4的底部设有排料机构。The bottom of the circulating fluidized bed 4 is provided with a fluidized bed inlet 5, which communicates with the gas outlet 3 of the scrubber; the bottom of the circulating fluidized bed 4 is provided with a discharge mechanism.

所述布袋除尘器7的除尘器进气口8与流化床出气口6相连,除尘器出气口9连接风机10,风机10与烟囱11连接。The dust collector inlet 8 of the bag filter 7 is connected to the fluidized bed outlet 6 , the dust collector outlet 9 is connected to a fan 10 , and the fan 10 is connected to a chimney 11 .

一种新型废弃物焚烧烟气净化工艺,对烟气的净化包括如下步骤:A new waste incineration flue gas purification process, the flue gas purification includes the following steps:

步骤一、烟气通过烟气进口2进入半干式洗气塔1,消石灰浆液或水通过半干式洗气塔1中的高效雾化器从塔顶或塔底喷入,形成同向流或逆行流的方式与烟气充分作用,去除烟气中的酸性气体;烟气经洗气塔出气口3的温度为200℃以下,以防止二恶英生成。Step 1. The flue gas enters the semi-dry scrubber 1 through the flue gas inlet 2, and the slaked lime slurry or water is sprayed from the top or bottom of the semi-dry scrubber 1 through the high-efficiency atomizer to form a codirectional flow Or the way of countercurrent flow fully interacts with the flue gas to remove the acid gas in the flue gas; the temperature of the flue gas passing through the gas scrubber outlet 3 is below 200°C to prevent the formation of dioxins.

步骤二、净化后的烟气经洗气塔出气口3进入循环流化床4,去除烟气中的水份及残余酸性气体,并经流化床出气口6进入布袋除尘器7;其中循环流化床4中的床料为CaCO3或CaO粉末和活性炭粉末的混合物,其中CaCO3或CaO粉末与活性炭粉末的摩尔比在1000∶1~10∶1之间。烟气经流化床出气口6的温度为120~180℃。Step 2, the purified flue gas enters the circulating fluidized bed 4 through the gas outlet 3 of the scrubber, removes the moisture and residual acid gas in the flue gas, and enters the bag filter 7 through the gas outlet 6 of the fluidized bed; The bed material in the fluidized bed 4 is a mixture of CaCO 3 or CaO powder and activated carbon powder, wherein the molar ratio of CaCO 3 or CaO powder to activated carbon powder is between 1000:1 and 10:1. The temperature of the flue gas passing through the gas outlet 6 of the fluidized bed is 120-180°C.

步骤三、布袋除尘器7过滤烟气中的细灰尘颗粒、中和剂颗粒、脱酸反应产物颗粒和活性炭颗粒后,烟气由除尘器出气口9排出;烟气经除尘器出气口9的温度为80~120℃。Step 3: After the bag filter 7 filters the fine dust particles, neutralizer particles, deacidification reaction product particles and activated carbon particles in the flue gas, the flue gas is discharged from the air outlet 9 of the dust collector; The temperature is 80-120°C.

步骤四、净化后的烟气经风机10烟囱11排入大气中。Step 4, the purified flue gas is discharged into the atmosphere through the chimney 11 of the fan 10 .

当废弃物焚烧处理量较小时,半干式洗气塔可只喷水降温,循环流化床和布袋除尘器可承担烟气净化任务;当废弃物焚烧处理量较大时,三者联合使用。When the amount of waste incineration is small, the semi-dry scrubber can only spray water to cool down, and the circulating fluidized bed and bag filter can undertake the task of flue gas purification; when the amount of waste incineration is large, the three can be used in combination .

本发明的有益效果,半干式洗气塔、循环流化床联合使用可以大大提高系统对烟气的净化能力,适应范围广,调节范围大,降低运行成本;循环流化床、布袋除尘器的联合使用可以实现两次除尘,保证烟气的彻底净化。并且采用本发明系统及工艺净化后的烟气,符合国标《危险废物焚烧污染控制标准》GB18484-2001和《生活垃圾焚烧污染控制标准》GB18485-2001所规定的排放标准。The beneficial effect of the present invention is that the combined use of the semi-dry gas scrubber and the circulating fluidized bed can greatly improve the system’s ability to purify the flue gas, and has a wide range of adaptation, a large adjustment range, and reduced operating costs; the circulating fluidized bed and the bag filter The combined use can achieve two dust removals to ensure the thorough purification of the flue gas. And the flue gas purified by the system and process of the present invention complies with the emission standards stipulated in the national standard "Pollution Control Standards for Hazardous Waste Incineration" GB18484-2001 and "Standards for Pollution Control of Domestic Garbage Incineration" GB18485-2001.

附图说明 Description of drawings

图1为本发明的系统示意图Fig. 1 is a schematic diagram of the system of the present invention

其中1为半干式洗气塔,2为烟气进口,3为洗气塔出气口,4为循环流化床,5为流化床进气口,6为流化床出气口,7为布袋除尘器,8为除尘器进气口,9为除尘器出气口,10为风机,11为烟囱。Among them, 1 is a semi-dry scrubber, 2 is the flue gas inlet, 3 is the outlet of the scrubber, 4 is the circulating fluidized bed, 5 is the inlet of the fluidized bed, 6 is the outlet of the fluidized bed, and 7 is the For the bag filter, 8 is the air inlet of the dust collector, 9 is the air outlet of the dust collector, 10 is the fan, and 11 is the chimney.

图2为本发明的工艺流程图Fig. 2 is a process flow diagram of the present invention

具体实施方式 Detailed ways

下面结合附图和具体实施方式对本发明作进一步详细说明。The present invention will be described in further detail below in conjunction with the accompanying drawings and specific embodiments.

参照图1,该系统主要由半干式洗气塔1、循环流化床4、布袋除尘器7和风机10组成。Referring to Figure 1, the system is mainly composed of a semi-dry scrubber 1, a circulating fluidized bed 4, a bag filter 7 and a fan 10.

参照图1、图2,烟气从半干式洗气塔1顶部的烟气进口2进入,消石灰浆液从塔底向上或从塔顶向下喷入半干式洗气塔1中,同时被内部的高效雾化器雾化,使之与高温烟气充分接触并产生中和作用,去除烟气中的酸性气体,使烟气快速降温。烟气温度可降至200℃以下,防止二恶英再生成。Referring to Figure 1 and Figure 2, the flue gas enters from the flue gas inlet 2 at the top of the semi-dry scrubber 1, and the slaked lime slurry is sprayed into the semi-dry scrubber 1 from the bottom of the tower upwards or downwards from the top of the tower, and is simultaneously The internal high-efficiency atomizer atomizes, makes it fully contact with the high-temperature flue gas and produces a neutralizing effect, removes the acid gas in the flue gas, and rapidly cools the flue gas. The flue gas temperature can be lowered below 200°C to prevent the regeneration of dioxins.

烟气从半干式洗气塔1出来之后进入循环流化床4,其底部设有进气口5,与半干式洗气塔1的出气口3相通,循环流化床4的底部设有排料机构,床料为CaCO3或CaO粉末和活性炭粉末的混合物。当半干式洗气塔1喷消石灰浆液时,CaCO3或CaO粉末与活性炭粉末的摩尔比在1000∶1~10∶1之间;当焚烧处理的是废电池、废水银温度计等重金属含量较高的废弃物时,床料中活性炭的含量提高,与CaCO3或CaO粉末的摩尔比可控制在100∶1~10∶1左右。当半干式洗气塔1只喷水降温时,CaCO3或CaO粉末与活性炭粉末的摩尔比在1000∶1~10∶1之间。循环流化床4起到调节湿度和去除残余酸性气体等污染物的作用,使烟气得到第二步净化,并且对布袋除尘器7起到保护作用:由于废弃物种类复杂,生成的污染物产量不恒定,烟气从半干式洗气塔出来之后带有水分和酸性气体,会影响布袋除尘器7的工作状况和使用寿命,循环流化床4的床料可以吸收水分,从而减少甚至去除烟气中的水分,调节了烟气的湿度,同时循环流化床4的碱性床料CaCO3或CaO粉末对半干式洗气塔1中未除尽的酸性气体进行再次去除,从而改善了布袋除尘器7的工作状况和延长了使用寿命;床料中掺入活性炭粉末还能对二恶英类物质和重金属进行吸附;循环流化床7可以依靠自己本身特有的优点,使床料与烟气充分接触,床料对污染物的吸附效果可以得到改善,同时,床料可以循环利用,提高其利用性,避免了CaCO3或CaO、活性炭的浪费。The flue gas enters the circulating fluidized bed 4 after coming out of the semi-dry scrubber 1, and the bottom is provided with an air inlet 5, which communicates with the gas outlet 3 of the semi-dry scrubber 1, and the bottom of the circulating fluidized bed 4 is provided with There is a discharge mechanism, and the bed material is a mixture of CaCO 3 or CaO powder and activated carbon powder. When the semi-dry scrubber 1 sprays slaked lime slurry, the molar ratio of CaCO or CaO powder to activated carbon powder is between 1000:1 and 10:1; When the waste is high, the content of activated carbon in the bed material is increased, and the molar ratio to CaCO 3 or CaO powder can be controlled at about 100:1 to 10:1. When the semi-dry scrubber only sprays water to cool down, the molar ratio of CaCO 3 or CaO powder to activated carbon powder is between 1000:1 and 10:1. The circulating fluidized bed 4 plays the role of adjusting humidity and removing pollutants such as residual acid gas, so that the flue gas can be purified in the second step, and it also protects the bag filter 7: due to the complex types of waste, the generated pollutants The output is not constant, and the flue gas contains moisture and acid gas after coming out of the semi-dry scrubber, which will affect the working condition and service life of the bag filter 7. The bed material of the circulating fluidized bed 4 can absorb moisture, thereby reducing or even The moisture in the flue gas is removed, and the humidity of the flue gas is adjusted. At the same time, the alkaline bed material CaCO or CaO powder in the circulating fluidized bed 4 removes the unremoved acid gas in the semi-dry scrubber 1 again, thereby The working condition of the bag filter 7 is improved and the service life is extended; the bed material mixed with activated carbon powder can also adsorb dioxins and heavy metals; the circulating fluidized bed 7 can rely on its own unique advantages to make the bed The material is in full contact with the flue gas, and the adsorption effect of the bed material on pollutants can be improved. At the same time, the bed material can be recycled to improve its utilization and avoid the waste of CaCO 3 or CaO and activated carbon.

烟气从循环流化床4出来之后进入布袋除尘器7。循环流化床出气口6连接布袋除尘器进气口8。布袋除尘器作为净化系统的最后一道工序,通过过滤将烟气中细灰尘粒、中和剂及脱酸反应产物颗粒和活性炭颗粒等捕集后排出。烟气由布袋除尘器出口9排出,实现烟气第三步净化。最后净化后的烟气经风机10和烟囱11排到大气中。The flue gas enters the bag filter 7 after coming out of the circulating fluidized bed 4 . The air outlet 6 of the circulating fluidized bed is connected to the air inlet 8 of the bag filter. As the last process of the purification system, the bag filter collects fine dust particles, neutralizers, deacidification reaction product particles and activated carbon particles in the flue gas through filtration and then discharges them. The flue gas is discharged from the outlet 9 of the bag filter to realize the third step of flue gas purification. Finally, the purified flue gas is discharged into the atmosphere through the fan 10 and the chimney 11.

本发明的的净化系统及净化工艺,可以大大提高系统对烟气的净化能力,适应范围广,调节范围大,降低运行成本。The purification system and purification process of the present invention can greatly improve the system's ability to purify flue gas, have a wide range of adaptation, a large adjustment range, and reduce operating costs.

Claims (4)

1、一种新型废弃物焚烧烟气净化系统,其特征在于:1. A new waste incineration flue gas purification system, characterized in that: 该系统由半干式洗气塔(1)、循环流化床(4)、布袋除尘器(7)和风机(10)组成;The system consists of a semi-dry scrubber (1), a circulating fluidized bed (4), a bag filter (7) and a fan (10); 所述半干式洗气塔(1)顶部设有烟气进口(2),内部装有雾化器;The top of the semi-dry gas scrubber (1) is provided with a flue gas inlet (2), and an atomizer is installed inside; 所述循环流化床(4)的底部设有流化床进气口(5),与洗气塔出气口(3)相通;The bottom of the circulating fluidized bed (4) is provided with a fluidized bed inlet (5), which communicates with the gas scrubber outlet (3); 所述布袋除尘器(7)的除尘器进气口(8)与流化床出气口(6)相连,除尘器出气口(9)连接风机(10),风机(10)与烟囱(11)相连。The dust collector inlet (8) of the bag filter (7) is connected to the fluidized bed outlet (6), and the dust collector outlet (9) is connected to the fan (10), and the fan (10) is connected to the chimney (11) connected. 2、一种新型废弃物焚烧烟气净化工艺,其特征在于包括如下步骤:2. A new waste incineration flue gas purification process, characterized in that it comprises the following steps: 步骤一、烟气通过烟气进口(2)进入半干式洗气塔(1),消石灰浆液或水通过半干式洗气塔(1)中的高效雾化器从塔顶或塔底喷入,形成同向流或逆行流的方式与烟气充分作用,去除烟气中的酸性气体;Step 1. The flue gas enters the semi-dry scrubber (1) through the flue gas inlet (2), and the slaked lime slurry or water is sprayed from the top or bottom of the semi-dry scrubber (1) through the high-efficiency atomizer Inlet, the way of forming cocurrent or countercurrent flow fully interacts with the flue gas to remove the acid gas in the flue gas; 步骤二、净化后的烟气经洗气塔出气口(3)进入循环流化床(4),去除烟气中的水分及残余酸性气体,并经流化床出气口(6)进入布袋除尘器(7);Step 2. The purified flue gas enters the circulating fluidized bed (4) through the gas scrubber outlet (3), removes the moisture and residual acid gas in the flue gas, and enters the bag dust removal through the fluidized bed gas outlet (6) device (7); 步骤三、布袋除尘器(7)过滤掉烟气中的细灰尘颗粒、中和剂颗粒、脱酸反应产物颗粒和活性炭颗粒后,烟气由除尘器出气口(9)排出;Step 3: After the bag filter (7) filters out the fine dust particles, neutralizer particles, deacidification reaction product particles and activated carbon particles in the flue gas, the flue gas is discharged from the dust collector outlet (9); 步骤四、净化后的烟气经风机(10)和烟囱(11)排入大气中。Step 4, the purified flue gas is discharged into the atmosphere through the blower fan (10) and the chimney (11). 3、根据权利要求2所述的一种新型废弃物焚烧烟气净化工艺,其特征在于:所述步骤二中循环流化床的床料为CaCO3或CaO粉末与活性炭粉末的混合物,其中CaCO3或CaO粉末与活性炭粉末的摩尔比在1000∶1~10∶1之间。3. A new waste incineration flue gas purification process according to claim 2, characterized in that: the bed material of the circulating fluidized bed in the second step is CaCO 3 or a mixture of CaO powder and activated carbon powder, wherein CaCO 3 or the molar ratio of CaO powder to activated carbon powder is between 1000:1 and 10:1. 4、根据权利要求2所述的一种新型废弃物焚烧烟气净化工艺,其特征在于:烟气经洗气塔出气口(3)的温度为200℃以下,经流化床出气口(6)的温度为120~180℃,经除尘器出气口(9)的温度为80~120℃。4. A new waste incineration flue gas purification process according to claim 2, characterized in that: the temperature of the flue gas passing through the gas scrubber outlet (3) is below 200°C, and passing through the fluidized bed gas outlet (6 ) is 120 to 180°C, and the temperature at the air outlet (9) of the dust collector is 80 to 120°C.
CNA2007103039681A 2007-12-24 2007-12-24 New Waste Incineration Flue Gas Purification System and Purification Process Pending CN101275746A (en)

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Cited By (7)

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CN102233230A (en) * 2011-07-18 2011-11-09 创冠环保(中国)有限公司 Waste burning smoke purification process and purification system
CN102814117A (en) * 2012-09-14 2012-12-12 重庆理工大学 Garbage leaching liquor biochemical treatment effluent method for garbage incinerator tail gas treatment
CN102949919A (en) * 2012-10-30 2013-03-06 湘潭闯创环保科技有限公司 Tail gas purification treatment agent
CN103282098A (en) * 2010-09-10 2013-09-04 禾鼎过滤技术股份有限公司 Filtration equipment and filtration method
CN103432887A (en) * 2013-08-30 2013-12-11 大连绿亿环保科技有限公司 Waste incineration flue gas purifying system and process
CN104406183A (en) * 2014-11-19 2015-03-11 四川四通欧美环境工程有限公司 Dry spray absorption system for waste incineration flue gas
CN112121619A (en) * 2020-08-27 2020-12-25 广州维港环保科技有限公司 Flue gas water purification and recovery device and process thereof

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103282098A (en) * 2010-09-10 2013-09-04 禾鼎过滤技术股份有限公司 Filtration equipment and filtration method
CN103282098B (en) * 2010-09-10 2015-08-19 禾鼎过滤技术有限公司 Filtration equipment and filtration method
CN102233230A (en) * 2011-07-18 2011-11-09 创冠环保(中国)有限公司 Waste burning smoke purification process and purification system
CN102814117A (en) * 2012-09-14 2012-12-12 重庆理工大学 Garbage leaching liquor biochemical treatment effluent method for garbage incinerator tail gas treatment
CN102814117B (en) * 2012-09-14 2015-04-22 重庆理工大学 Method for garbage leaching liquor biochemical treatment effluent to be used in garbage incinerator tail gas treatment
CN102949919A (en) * 2012-10-30 2013-03-06 湘潭闯创环保科技有限公司 Tail gas purification treatment agent
CN103432887A (en) * 2013-08-30 2013-12-11 大连绿亿环保科技有限公司 Waste incineration flue gas purifying system and process
CN104406183A (en) * 2014-11-19 2015-03-11 四川四通欧美环境工程有限公司 Dry spray absorption system for waste incineration flue gas
CN104406183B (en) * 2014-11-19 2017-01-11 四川四通欧美环境工程有限公司 Dry spray absorption system for waste incineration flue gas
CN112121619A (en) * 2020-08-27 2020-12-25 广州维港环保科技有限公司 Flue gas water purification and recovery device and process thereof

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