CN101245183A - Thermoplastic elastic body for jetting and adhibiting with ABS at low-temperature - Google Patents
Thermoplastic elastic body for jetting and adhibiting with ABS at low-temperature Download PDFInfo
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- CN101245183A CN101245183A CNA2008100661329A CN200810066132A CN101245183A CN 101245183 A CN101245183 A CN 101245183A CN A2008100661329 A CNA2008100661329 A CN A2008100661329A CN 200810066132 A CN200810066132 A CN 200810066132A CN 101245183 A CN101245183 A CN 101245183A
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Abstract
The invention relates to a thermoplastic elastomer used for projecting and clinging with ABS at low temperature, and components of the raw material are: thermoplastic polyurethane: 20 to 35 portions; compatilizer: 6 to 7 portions; SEBS resin: 20 to 25 portions; mineral oil: 22 to 29 portions; mineral filling: 10 to 20 portions and antioxidant: 0.1 to 1 portion, and 0.1 to 1 portion of processing aid can be added selectively. The thermoplastic elastomer used for projecting and clinging with ABS at temperature is low in hardness, good in surface effect at the injection temperature of 135 DEG C, good in the property of projecting and clinging with the ABS resin at low temperature.
Description
[technical field]
The present invention relates to polymeric material field, relate in particular to a kind of being used for to penetrate sticking thermoplastic elastomer with ABS low temperature.
[background technology]
Shock-resistant, high rigidity that ABS resin has, oil resistant, low temperature resistant, excellent properties such as dimensional stability good, molding shrinkage is little are a kind of purposes thermoplasticss extremely widely.But by the product that ABS resin is made, its surface is often harder and smooth, lacks texture and feel in some product application.So, often coating one deck flexible glue on ABS finished product top layer to strengthen its texture and feel, industry adopts the mode of penetrating sticking one deck thermoplastic elastomer on ABS finished product surface to realize usually.It is on the various injecting products of base material that the thermoplastic elastomer of penetrating sticking ABS is widely used in ABS, makes the ABS finished product have good texture and feel, increases user's comfortableness, makes product that better outward appearance be arranged, and has improved the class of product.
(the ABS resin heat-drawn wire of general grade is below 105 ℃, and Vicat softening point is 160 ℃ but the heat-drawn wire of ABS resin is lower; The heat resisting temperature of heat-resisting level ABS resin is 110～120 ℃, the heat resisting temperature of super heat-resisting level ABS resin is 125～130 ℃), generally penetrate sticking ABS temperature of articles (very sophisticated) more than 180 degree, but for some hollow pieces, the perhaps goods of shape more complicated, high temperature is easy to produce distortion, therefore need a kind of low temperature to penetrate the material of sticking ABS, generally be not higher than 150 ℃, and the existing injection temperature of penetrating sticking thermoplastic elastomer with ABS can not meet the demands generally all more than 180 ℃.
[summary of the invention]
Goal of the invention of the present invention is the above-mentioned defective at thermoplastic elastomer in the prior art, provides a kind of being used for to penetrate sticking thermoplastic elastomer with ABS, to reach the purpose of the injection temperature that reduces thermoplastic elastomer.
To achieve the above object of the invention, the present invention proposes following technical scheme: a kind of being used for penetrated sticking thermoplastic elastomer with ABS low temperature, comprises the following materials based on weight component:
Thermoplastic polyurethane 20-35 part
Compatilizer 6-7 part
SEBS resin 20-25 part
Mineral oil 22-29 part
Mineral filler 10-20 part
Oxidation inhibitor 0.1-1 part.
Provided by the invention being used for penetrated sticking thermoplastic elastomer with ABS low temperature, also comprises the processing aid of 0.1-1 part in the described component.
Provided by the invention being used for penetrated sticking thermoplastic elastomer with ABS low temperature, and described thermoplastic polyurethane (TPU) is the soft thermoplastic polyurethane, and S60AW, S70AW or S80A (German BASF trade names) are specifically arranged.
Provided by the invention being used for penetrated sticking thermoplastic elastomer with ABS low temperature, described compatilizer is to be selected from least a among SEBS-co-TPU (hydrogenation thermoplastic styrene butadiene rubber-thermoplastic polyurethane copolymer), the SEBS-g-MAH (hydrogenation thermoplastic styrene butadiene rubber-maleic anhydride grafts), concrete as TU-5265 (SEBS-co-TPU, Japan Kuraray trade names), 1901 (SEBS-g-MAH, U.S. Kraton company trade names).
Provided by the invention being used for penetrated sticking thermoplastic elastomer with ABS low temperature, and described SEBS resin is to be selected from least a among SEBS1651, SEBS1654, the SEBS8006 (more than be Kuraray company of U.S. Kraton company/Japanese trade names).
Provided by the invention being used for penetrated sticking thermoplastic elastomer with ABS low temperature, described mineral oil is that flash-point is higher than 200 ℃ saturated straight chain alkane oil or naphthenic oil, specifically as the 500N saturated straight chain alkane oil of the two dragons of Korea S or KN4006, the KN4010 naphthenic hydrocarbon wet goods of Kelamayi refinery.
Provided by the invention being used for penetrated sticking thermoplastic elastomer with ABS low temperature, described oxidation inhibitor is to be selected from antioxidant 1076 (β (3,5-di-t-butyl-4 hydroxy phenyl) propionic acid octadecyl alcohol ester), (β (3 for antioxidant 1010,5-di-t-butyl-4 hydroxy phenyl) at least a in the oxidation inhibitor 168 (three (2, the 4-DI-tert-butylphenol compounds) phosphorous acid ester) propionic acid pentaerythritol ester).
Provided by the invention being used for penetrated sticking thermoplastic elastomer with ABS low temperature, and described mineral filler is to be selected from least a in lime carbonate, talcum powder, terra alba, asbestos powder, potter's clay, barium sulfate, mica powder, the kaolin.
Provided by the invention being used for penetrated sticking thermoplastic elastomer with ABS low temperature, and described processing aid is to be selected from least a in lipid acid, fatty acid amide, the silicone, and be concrete as stearic acid, favourable triumphant agate 1753 (erucicamide) etc.
As can be seen from the above technical solutions, provided by the invention being used for penetrated sticking thermoplastic elastomer with ABS low temperature, is to be base material with TPU, cooperates compatilizer, SEBS resin, mineral oil, auxiliary agent etc. to form through the Couble screw rod high-temp high shear mixing.This thermoplastic elastomer hardness is low, and under 135 ℃ of injection temperatures, penetrate and be stained with the surface of good effect with ABS, and good adhesion; Solved because the resistance to elevated temperatures of ABS material is poor, and limited it in a difficult problem of penetrating the application that sticks into the V-neck V territory.
[embodiment]
1. proportioning raw materials
In the above-mentioned raw materials, compatilizer TU-5265,1901 can be replaced by other SEBS-co-TPU, SEBS-g-MAH of the same type;
Mineral oil 500N, KN4006 can be replaced by other flash-point is higher than 200 ℃ saturated straight chain alkane oil or naphthenic oil;
Auxiliary agent 1753 can be replaced by other suitable lipid acid, fatty acid amide, silicone;
Antioxidant 1076 can be other similar antioxidant 1010s, 168 replacements;
Mineral filler is one or more the mixture in lime carbonate, talcum powder, terra alba, asbestos powder, potter's clay, barium sulfate, mica powder, the kaolin.
2. injection moulding processing
Get feed composition by above-mentioned each proportioning respectively, SEBS and mineral oil thorough mixing is even, blot oil back adding compatilizer, TPU, auxiliary agent, oxidation inhibitor, mineral filler etc. and in mixer, mix.Mixed material is sent in the twin screw extruder, set the processing temperature of suitable twin screw extruder, starting material through the twin screw high speed shear, mixing, extrude, tie rod, cooling, granulation promptly get a kind of being used for of the present invention and penetrate sticking thermoplastic elastomer with ABS low temperature
3. performance test
The thermoplastic elastomer that makes by above-mentioned each prescription is carried out performance test, result such as following table:
Remarks: the test condition of melting index is: 190 ℃ of temperature, pressure 5KG
The above embodiment has only expressed several embodiment of the present invention, and it describes comparatively concrete and detailed, but can not therefore be interpreted as the restriction to claim of the present invention.Should be pointed out that for the person of ordinary skill of the art without departing from the inventive concept of the premise, can also make some distortion and improvement, these all belong to protection scope of the present invention.Therefore, the protection domain of patent of the present invention should be as the criterion with claims.
Claims (9)
1. one kind is used for penetrating sticking thermoplastic elastomer with ABS low temperature, comprises the following materials based on weight component:
Thermoplastic polyurethane 20-35 part
Compatilizer 6-7 part
SEBS resin 20-25 part
Mineral oil 22-29 part
Mineral filler 10-20 part
Oxidation inhibitor 0.1-1 part.
2. according to claim 1 being used for penetrated sticking thermoplastic elastomer with ABS low temperature, it is characterized in that, also comprises the processing aid of 0.1-1 part in the described component.
3. according to claim 1 and 2 being used for penetrated sticking thermoplastic elastomer with ABS low temperature, it is characterized in that, described thermoplastic polyurethane is to be selected from S60AW, S70AW or S80A.
4. according to claim 1 and 2 being used for penetrated sticking thermoplastic elastomer with ABS low temperature, it is characterized in that, described compatilizer is to be selected from least a among TPU-co-SEBS, the SEBS-g-MAH.
5. according to claim 1 and 2 being used for penetrated sticking thermoplastic elastomer with ABS low temperature, it is characterized in that, described SEBS resin is to be selected from least a among SEBS1651, SEBS1654, the SEBS8006.
6. according to claim 1 and 2 being used for penetrated sticking thermoplastic elastomer with ABS low temperature, it is characterized in that, described mineral oil is that flash-point is higher than 200 ℃ saturated straight chain alkane oil or naphthenic oil.
7. according to claim 1 and 2 being used for penetrated sticking thermoplastic elastomer with ABS low temperature, it is characterized in that, described oxidation inhibitor is to be selected from least a in antioxidant 1076, antioxidant 1010, the oxidation inhibitor 168.
8. according to claim 1 and 2 being used for penetrated sticking thermoplastic elastomer with ABS low temperature, it is characterized in that described mineral filler is to be selected from least a in lime carbonate, talcum powder, terra alba, asbestos powder, potter's clay, barium sulfate, mica powder, the kaolin.
9. according to claim 2 being used for penetrated sticking thermoplastic elastomer with ABS low temperature, it is characterized in that, described processing aid is to be selected from least a in lipid acid, fatty acid amide, the silicone.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2008100661329A CN101245183B (en) | 2008-03-21 | 2008-03-21 | Thermoplastic elastic body for jetting and adhibiting with ABS at low-temperature |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2008100661329A CN101245183B (en) | 2008-03-21 | 2008-03-21 | Thermoplastic elastic body for jetting and adhibiting with ABS at low-temperature |
Publications (2)
| Publication Number | Publication Date |
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| CN101245183A true CN101245183A (en) | 2008-08-20 |
| CN101245183B CN101245183B (en) | 2011-06-22 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN2008100661329A Expired - Fee Related CN101245183B (en) | 2008-03-21 | 2008-03-21 | Thermoplastic elastic body for jetting and adhibiting with ABS at low-temperature |
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Cited By (18)
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| CN101845196A (en) * | 2010-05-07 | 2010-09-29 | 浙江俊尔新材料有限公司 | Thermoplastic elastomer for ABS jetting adhesion |
| CN101983990A (en) * | 2010-03-29 | 2011-03-09 | 金发科技股份有限公司 | Thermoplastic elastomer and preparation method thereof |
| CN102140240A (en) * | 2010-12-31 | 2011-08-03 | 东莞市迅创实业有限公司 | Thermoplastic elastomer for injection adhering with acrylonitrile-butadiene and styrene terpolymer |
| CN102199343A (en) * | 2011-01-27 | 2011-09-28 | 上海锦湖日丽塑料有限公司 | Dumb thermoplastic polyurethane elastomer composition and preparation method thereof |
| CN101712788B (en) * | 2008-10-07 | 2012-04-11 | 东莞市卡帝德塑化科技有限公司 | Formula of master batch for toughening polystyrene |
| CN102516747A (en) * | 2011-12-09 | 2012-06-27 | 上海锦湖日丽塑料有限公司 | Thermoplastic elastomer composition of encapsulation PETG (poly(ethylene terephthalate) glycol) and preparation method thereof |
| CN102924900A (en) * | 2012-07-24 | 2013-02-13 | 深圳市沃特新材料股份有限公司 | Thermoplastic elastomer, and preparation method and application thereof |
| CN106366671A (en) * | 2016-08-31 | 2017-02-01 | 南京京锦元科技实业有限公司 | TPE encapsulating material for electric tool PC shell |
| JP6074075B1 (en) * | 2016-01-28 | 2017-02-01 | 蘇州天裕塑膠有限公司 | TPE composite membrane material and its use in the manufacture of wound core tubes |
| CN106751372A (en) * | 2016-12-30 | 2017-05-31 | 慈溪市山今高分子塑料有限公司 | A kind of TPE material and its preparation technology for encapsulated ABS |
| CN106867231A (en) * | 2017-01-23 | 2017-06-20 | 美瑞新材料股份有限公司 | The technique that a kind of In Situ Compatibilization prepares TPU alloy materials |
| CN106928692A (en) * | 2017-03-22 | 2017-07-07 | 宁波市恩睿塑胶有限公司 | A kind of TPE encapsulated formula and production technology |
| CN107227027A (en) * | 2017-07-20 | 2017-10-03 | 广东创弘材料科技有限公司 | Thermoplastic composite elastomer and preparation method thereof, purposes |
| CN107383851A (en) * | 2017-08-29 | 2017-11-24 | 江阴市洸洋塑业有限公司 | A kind of elastomer ABS claddings material and preparation method thereof |
| CN108003544A (en) * | 2016-11-01 | 2018-05-08 | 上海鼎事新材料科技有限公司 | A kind of TPU/TPE composite modification materials |
| CN110845855A (en) * | 2019-11-27 | 2020-02-28 | 新钻塑料科技（上海）有限公司 | Thermoplastic elastomer material for secondary injection bonding with polyketone material and preparation method thereof |
| CN113621229A (en) * | 2021-08-25 | 2021-11-09 | 东莞市长锦成电器有限公司 | Plastic for driving wheel of sweeping robot, driving wheel and sweeping robot |
| CN114958270A (en) * | 2022-05-24 | 2022-08-30 | 广东汇齐新材料有限公司 | Ultralow-hardness low-temperature activated thermoplastic polyurethane hot-melt adhesive film and preparation method thereof |
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2008
- 2008-03-21 CN CN2008100661329A patent/CN101245183B/en not_active Expired - Fee Related
Cited By (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101712788B (en) * | 2008-10-07 | 2012-04-11 | 东莞市卡帝德塑化科技有限公司 | Formula of master batch for toughening polystyrene |
| CN101983990A (en) * | 2010-03-29 | 2011-03-09 | 金发科技股份有限公司 | Thermoplastic elastomer and preparation method thereof |
| CN101983990B (en) * | 2010-03-29 | 2012-07-18 | 金发科技股份有限公司 | Thermoplastic elastomer and preparation method thereof |
| CN101845196A (en) * | 2010-05-07 | 2010-09-29 | 浙江俊尔新材料有限公司 | Thermoplastic elastomer for ABS jetting adhesion |
| CN102140240A (en) * | 2010-12-31 | 2011-08-03 | 东莞市迅创实业有限公司 | Thermoplastic elastomer for injection adhering with acrylonitrile-butadiene and styrene terpolymer |
| CN102140240B (en) * | 2010-12-31 | 2012-08-22 | 东莞市迅创实业有限公司 | Thermoplastic elastomer for injection adhering with acrylonitrile-butadiene and styrene terpolymer |
| CN102199343A (en) * | 2011-01-27 | 2011-09-28 | 上海锦湖日丽塑料有限公司 | Dumb thermoplastic polyurethane elastomer composition and preparation method thereof |
| CN102199343B (en) * | 2011-01-27 | 2013-06-12 | 上海锦湖日丽塑料有限公司 | Dumb thermoplastic polyurethane elastomer composition and preparation method thereof |
| CN102516747A (en) * | 2011-12-09 | 2012-06-27 | 上海锦湖日丽塑料有限公司 | Thermoplastic elastomer composition of encapsulation PETG (poly(ethylene terephthalate) glycol) and preparation method thereof |
| CN102924900A (en) * | 2012-07-24 | 2013-02-13 | 深圳市沃特新材料股份有限公司 | Thermoplastic elastomer, and preparation method and application thereof |
| JP6074075B1 (en) * | 2016-01-28 | 2017-02-01 | 蘇州天裕塑膠有限公司 | TPE composite membrane material and its use in the manufacture of wound core tubes |
| CN106366671A (en) * | 2016-08-31 | 2017-02-01 | 南京京锦元科技实业有限公司 | TPE encapsulating material for electric tool PC shell |
| CN108003544A (en) * | 2016-11-01 | 2018-05-08 | 上海鼎事新材料科技有限公司 | A kind of TPU/TPE composite modification materials |
| CN106751372A (en) * | 2016-12-30 | 2017-05-31 | 慈溪市山今高分子塑料有限公司 | A kind of TPE material and its preparation technology for encapsulated ABS |
| CN106867231A (en) * | 2017-01-23 | 2017-06-20 | 美瑞新材料股份有限公司 | The technique that a kind of In Situ Compatibilization prepares TPU alloy materials |
| CN106928692A (en) * | 2017-03-22 | 2017-07-07 | 宁波市恩睿塑胶有限公司 | A kind of TPE encapsulated formula and production technology |
| CN107227027A (en) * | 2017-07-20 | 2017-10-03 | 广东创弘材料科技有限公司 | Thermoplastic composite elastomer and preparation method thereof, purposes |
| CN107227027B (en) * | 2017-07-20 | 2020-05-19 | 广东创弘材料科技有限公司 | Thermoplastic composite elastomer and preparation method and application thereof |
| CN107383851A (en) * | 2017-08-29 | 2017-11-24 | 江阴市洸洋塑业有限公司 | A kind of elastomer ABS claddings material and preparation method thereof |
| CN110845855A (en) * | 2019-11-27 | 2020-02-28 | 新钻塑料科技（上海）有限公司 | Thermoplastic elastomer material for secondary injection bonding with polyketone material and preparation method thereof |
| CN113621229A (en) * | 2021-08-25 | 2021-11-09 | 东莞市长锦成电器有限公司 | Plastic for driving wheel of sweeping robot, driving wheel and sweeping robot |
| CN114958270A (en) * | 2022-05-24 | 2022-08-30 | 广东汇齐新材料有限公司 | Ultralow-hardness low-temperature activated thermoplastic polyurethane hot-melt adhesive film and preparation method thereof |
| WO2023226133A1 (en) * | 2022-05-24 | 2023-11-30 | 广东汇齐新材料有限公司 | Ultralow-hardness low-temperature activated thermoplastic polyurethane hot melt adhesive film and preparation method therefor |
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| CN101245183B (en) | 2011-06-22 |
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Owner name: DONGGUAN GUOFENG ZHIJIA PLASTIC RAW MATERIALS CO., Free format text: FORMER OWNER: SHENZHEN SUNGALLON RUBBER + PLASTIC INDUSTRY CO., LTD. Effective date: 20120427 |
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Effective date of registration: 20120427 Address after: 523623 Guangdong Province, Dongguan City Zhangmutou Zhangyang Sentosa Industrial Zone, plastic industry science and Technology Park building D No. 5 Patentee after: Dongguan Guofeng Zhijia plastic material Co. Ltd. Address before: Shenzhen City, Guangdong province Guanlan street 518040 sightseeing road rich industrial zone Guifeng No. 1 Patentee before: Shenzhen Sungallon Rubber & Plastic Industry Co., Ltd. |
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