CN101238812A - Acetamiprid and pirimicarb pesticidal composition for controlling erisosma lanigerum hausmann and aphis citricola - Google Patents

Acetamiprid and pirimicarb pesticidal composition for controlling erisosma lanigerum hausmann and aphis citricola Download PDF

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Publication number
CN101238812A
CN101238812A CNA2008100493624A CN200810049362A CN101238812A CN 101238812 A CN101238812 A CN 101238812A CN A2008100493624 A CNA2008100493624 A CN A2008100493624A CN 200810049362 A CN200810049362 A CN 200810049362A CN 101238812 A CN101238812 A CN 101238812A
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China
Prior art keywords
acetamiprid
pirimicarb
aphox
yellow
aphid
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CNA2008100493624A
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CN100588320C (en
Inventor
张金勇
陈汉杰
郭小辉
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Zhengzhou Fruit Research Institute CAAS
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Zhengzhou Fruit Research Institute CAAS
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Abstract

The invention discloses an acetamiprid-pirimicarb pesticide compound monitoring Woolly apple aphid and yellow aphid, the effective ingredients of said pesticide compound are compound of acetamiprid and pirimicarb, the weight ratio between acetamiprid and pirimicarb is in the range of 1:20-1:2, the effective ingredient of pesticide compound is 5-30wt%, the compound of acetamiprid and pirimicarb which are effective ingredients can be made into creaming agent, micro-emulsion and other agents, for preventing the two kinds of aphid injuries Woolly apple aphid and yellow aphid at the same time, the effect of monitoring two kinds of aphid injuries at one time is significant, while it is safe for natural enemies of pest. So using the pesticide compound according to the invention is good for reducing the control cost and optimizing the pest integrated control system.

Description

Hold concurrently and control the Acetamiprid pirimicarb pesticidal composition of wooly aphis and yellow aphids
One, technical field:
The present invention relates to a kind of composition pesticide of prevention and control plant aphids, particularly relate to a kind of composition pesticide that contains Acetamiprid and Aphox that can control wooly aphis and two kinds of aphid evils of yellow aphids simultaneously.
Two, background technology:
The cultivated area of China's apple surpasses 2,000,000 hectares, and wooly aphis and yellow aphids are current important controlling objects.Wooly aphis is a kind of important plant quarantine object, spreads rapidly in each apple main producing region in recent years, and this worm breeds fast and secretion has the wax protection, and difficulty of prevention and cure is bigger, and is quite serious to apple tree harm.At present, the leading medicine of control woolly aphid is a chlopyrifos, and the shortcoming of this medicine is dangerous to pest natural enemy, and long-term the use destroyed seriously orchard ecology; The efficient medicament of control apple yellow aphid has Acetamiprid, but we find that in actual applications this medicament is relatively poor to the control efficiency of wooly aphis, and common dose kills and wounds also bigger to natural enemy.Because the emergence period basically identical of wooly aphis and yellow aphids, lack on the market to two kinds of insect a drugs can hold concurrently and control and to the safer medicament of natural enemy.Aphox is to be developed by Britain's ICI Imperial Chemical Industries nineteen sixty-five, and 1969 as special-purpose aphicide popularization.Good to the aphid quick-acting on the plants such as fruit tree, cereal, vegetables under recommended density, natural enemy of aphid such as ladybug, syrphus fly and aphid cocoon honeybee are had no adverse effects.Show through the test of our indoor biometrics, Aphox to the activity of wooly aphis apparently higher than apple yellow aphid.Aphox and Acetamiprid exist complementary when holding concurrently two kinds of aphids of control.Look into newly through data and to show, do not see the relevant report that has both to be mixed.For this reason, the medicine of a kind of double control wooly aphis of developmental research and two kinds of aphid evils of yellow aphids is very important.
Three, summary of the invention:
The objective of the invention is the action compensating that utilizes Aphox and Acetamiprid when prevention and control wooly aphis and two kinds of aphids of yellow aphids, to exist, respectively get the chief, overcome the problem that exists separately, by screening the rational proportion of synergy or summation action is arranged, provide a kind of a drug can effective prevention and control wooly aphis and the Acetamiprid pirimicarb pesticidal compositions of two kinds of insects of yellow aphids.
Technical scheme of the present invention:
The Acetamiprid pirimicarb pesticidal composition of a kind of double control wooly aphis and yellow aphids is provided, and wherein active ingredient is Acetamiprid and Aphox, the weight ratio scope between the two is generally 1: 20~and 1: 2, preferable range is 1: 10~1: 4.The percentage by weight that the two active ingredient accounts for composition pesticide is 5~30%.Utilize the prior dosage form process technology, above-mentioned composition pesticide can be mixed with missible oil or microemulsion formulation.The emulsifiable concentrate prescription is: described active ingredient 10~30%, organic solvent 45~70%, cosolvent 10~15% and emulsifier 10~15%; Micro-emulsion formulation is: described active ingredient 5~20%, and organic solvent 10~20%, cosolvent 10~15%, emulsifier 10~40%, all the other are water.Wherein said organic solvent is toluene or dimethylbenzene, and cosolvent is methyl alcohol or ethanol, and the emulsifier in the emulsifiable concentrate is OP, and the emulsifier in the microemulsion is the mixture of OP and neopelex.
The application of Acetamiprid pirimicarb pesticidal composition in prevention and control wooly aphis and yellow aphids of described double control wooly aphis and yellow aphids is equally applicable to the harmful prevention and control of various aphids that take place on the crops such as other fruit tree, vegetables, flowers and grain.
Positive beneficial effect of the present invention:
1, can effectively prevent and treat wooly aphis and two kinds of insects of yellow aphids with composition pesticide a drug of the present invention, the prevention and control effect is remarkable:
A, the experiment of the indoor virulence by a large amount of proportionings record: the composition pesticide that with Aphox and Acetamiprid is active ingredient reaches more than 230 the maximum co-toxicity coefficient of apple yellow aphid, and remarkable synergistic effect is arranged; About 100, the effect that is mixed symbolic animal of the birth year adds effect to the co-toxicity coefficient of wooly aphis.
The experimental data of b, table 1 and table 2 can illustrate the field effect of composition pesticide of the present invention to wooly aphis and two kinds of insects of yellow aphids:
Table 1 medicine is to the field control effect (spray-on process) of wooly aphis
Handle Radix before the medicine Behind the medicine 7 days Behind the medicine 14 days Behind the medicine 21 days
% goes down Preventive effect % % goes down Preventive effect % % goes down Preventive effect %
The blank CK of the anti-40mg/kg of the anti-48mg/kg pyridine of the anti-60mg/kg pyridine of pyridine 319 232 268 269 100.0 100.0 100.0 17.6 100.0 100.0 100.0 0.0 96.2 96.0 97.9 17.4 95.2 95.1 97.5 0.0 92.5 91.5 89.8 17.1 90.5 88.8 87.0 0.0
Table 2 medicine is to the field control effect (spray-on process) of apple yellow aphid
Handle Radix before the medicine Behind the medicine 2 days Behind the medicine 7 days Behind the medicine 14 days
% goes down Preventive effect % % goes down Preventive effect % % goes down Preventive effect %
The blank CK of the anti-25mg/kg of the anti-33.3mg/kg pyridine of the anti-50mg/kg pyridine of pyridine 1605 3086 2140 3880 97.4 92.8 90.0 -3.8 97.2 91.4 89.8 0 97.7 97.8 97.7 38.2 95.7 96.1 95.5 0 96.8 95.7 94.6 67.8 86.1 82.2 76.7 0
2, there is action compensating in two active ingredients of composition pesticide of the present invention when two kinds of aphids of prevention and control, respectively get the chief, rational proportion by screening synergy or summation action, overcome the shortcoming that exists separately, the pest natural enemy safety is improved, compare with the method for present control, not only help lowering the control cost, and more help sustainable Control of insect and the integrated control system of optimization insect.
3, not only the prevention and control effect to apple yellow aphid and woolly aphid is remarkable for composition pesticide of the present invention, and the various aphid evils that take place on the crops such as other fruit tree, vegetables, flowers and grain are also had good control efficiency.
Four, embodiment:
Following examples only in order to further specify the present invention, do not limit content of the present invention.
Embodiment one: the Acetamiprid Aphox missible oil of preparation active ingredient 10%
Each composition weight percentage: 1% Acetamiprid, 9% Aphox, 70% dimethylbenzene, 10% methyl alcohol and 10%OP.
Preparation method: earlier active ingredient Acetamiprid and the Aphox that takes by weighing fully dissolved with organic solvent and cosolvent, add other composition again after treating to dissolve fully and mix, get final product after fully stirring.
Embodiment two: the Acetamiprid Aphox missible oil of preparation active ingredient 15%
Each composition weight percentage: 2% Acetamiprid, 13% Aphox, 65% toluene, 10% ethanol and 10%OP.
The preparation method is with embodiment one.
Embodiment three: the Acetamiprid Aphox missible oil of preparation active ingredient 20%
Each composition weight percentage: 3% Acetamiprid, 17% Aphox, 60% dimethylbenzene, 10% methyl alcohol and 10%OP.
The preparation method is with embodiment one.
Embodiment four: the Acetamiprid Aphox missible oil of preparation active ingredient 21%
Each composition weight percentage: 1% Acetamiprid, 20% Aphox, 50% toluene, 14% ethanol and 15%OP.
The preparation method is with embodiment one.
Embodiment five: the Acetamiprid Aphox missible oil of preparation active ingredient 25%
Each composition weight percentage: 3% Acetamiprid, 22% Aphox, 50% toluene, 10% ethanol and 15%OP.
The preparation method is with embodiment one.
Embodiment six: the Acetamiprid Aphox missible oil of preparation active ingredient 30%
Each composition weight percentage: 3% Acetamiprid, 27% Aphox, 45% dimethylbenzene, 10% ethanol and 15%OP.
The preparation method is with embodiment one.
Embodiment seven: the Acetamiprid Aphox microemulsion of preparation active ingredient 5%
Each composition weight percentage: 1% Acetamiprid, 4% Aphox, 10% dimethylbenzene, 10% methyl alcohol, 10%OP, 5% neopelex, all the other are water.
Preparation method: earlier active ingredient Acetamiprid and the Aphox that takes by weighing fully dissolved with organic solvent and cosolvent, add other composition again after treating to dissolve fully and mix, can be made into after fully stirring, can convert the clear liquid that water is diluted to any concentration.
Embodiment eight: the Acetamiprid Aphox microemulsion of preparation active ingredient 6%
Each composition weight percentage: 2% Acetamiprid, 4% Aphox, 10% toluene, 10% ethanol, 12%OP, 8% neopelex, all the other are water.
The preparation method is with embodiment seven.
Embodiment nine: the Acetamiprid Aphox microemulsion of preparation active ingredient 10%
Each composition weight percentage: 1.25% Acetamiprid, 8.75% Aphox, 10% toluene, 10% ethanol, 20%OP, 8% neopelex, all the other are water.
The preparation method is with embodiment seven.
Embodiment ten: the Acetamiprid Aphox microemulsion of preparation active ingredient 15%
Each composition weight percentage: 2% Acetamiprid, 13% Aphox, 15% toluene, 10% ethanol, 25%OP, 10% neopelex, all the other are water.
The preparation method is with embodiment seven.
Embodiment 11: the Acetamiprid Aphox microemulsion of preparation active ingredient 20%
Each composition weight percentage: 2.5% Acetamiprid, 17.5% Aphox, 20% dimethylbenzene, 15% methyl alcohol, 30%OP, 10% neopelex, all the other are water.
The preparation method is with embodiment seven.

Claims (8)

1, the Acetamiprid pirimicarb pesticidal composition of a kind of double control wooly aphis and yellow aphids, it is characterized in that: the active ingredient of described composition pesticide is the mixture of Acetamiprid and Aphox, Acetamiprid and the Aphox weight ratio between the two is 1: 20~1: 2.
2, the Acetamiprid pirimicarb pesticidal composition of double control wooly aphis according to claim 1 and yellow aphids is characterized in that: Acetamiprid and the Aphox weight ratio between the two is 1: 10~1: 4 in the described active ingredient.
3, the Acetamiprid pirimicarb pesticidal composition of double control wooly aphis according to claim 1 and 2 and yellow aphids, it is characterized in that: the percentage by weight that described active ingredient accounts for composition pesticide is 5~30%.
4, the Acetamiprid pirimicarb pesticidal composition of double control wooly aphis according to claim 3 and yellow aphids, it is characterized in that: described composition pesticide is by described active ingredient 10~30%, organic solvent 45~70%, cosolvent 10~15% and emulsifier 10~15% are prepared into the emulsifiable concentrate preparation.
5, the Acetamiprid pirimicarb pesticidal composition of double control wooly aphis according to claim 4 and yellow aphids, it is characterized in that: described organic solvent is toluene or dimethylbenzene, and cosolvent is methyl alcohol or ethanol, and emulsifier is OP.
6, the Acetamiprid pirimicarb pesticidal composition of double control wooly aphis according to claim 3 and yellow aphids, it is characterized in that: described composition pesticide is by described active ingredient 5~20%, organic solvent 10~20%, cosolvent 10~15%, emulsifier 10~40%, all the other are prepared into microemulsion formulation for water.
7, the Acetamiprid pirimicarb pesticidal composition of double control wooly aphis according to claim 6 and yellow aphids, it is characterized in that: described organic solvent is toluene or dimethylbenzene, cosolvent is methyl alcohol or ethanol, and emulsifier is the mixture of OP and neopelex.
8, the Acetamiprid pirimicarb pesticidal composition of double control wooly aphis according to claim 1 and yellow aphids is characterized in that: the application of described composition pesticide on prevention and control wooly aphis and yellow aphids.
CN200810049362A 2008-03-14 2008-03-14 Acetamiprid and pirimicarb pesticidal composition for controlling erisosma lanigerum hausmann and aphis citricola Expired - Fee Related CN100588320C (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108849958B (en) * 2018-08-09 2021-04-30 兰博尔开封科技有限公司 Acetamiprid missible oil produced by green environment-friendly solvent and production method thereof
CN113197230A (en) * 2021-04-08 2021-08-03 山西省农业科学院植物保护研究所 Slow-release pesticide preparation for preventing woolly apple aphid and preparation method thereof

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1315132A (en) * 2000-03-28 2001-10-03 梁龙华 Composition of hexadecamacrolide-type antibiotic miticiding insecticide and pyridine-type insecticide
CN1299593A (en) * 2001-01-05 2001-06-20 深圳市诺普信农化有限公司 Abmectin-acetamiprid pesticide composition

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108849958B (en) * 2018-08-09 2021-04-30 兰博尔开封科技有限公司 Acetamiprid missible oil produced by green environment-friendly solvent and production method thereof
CN113197230A (en) * 2021-04-08 2021-08-03 山西省农业科学院植物保护研究所 Slow-release pesticide preparation for preventing woolly apple aphid and preparation method thereof

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