CN101222952A - Mask - Google Patents

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Publication number
CN101222952A
CN101222952A CNA200680026239XA CN200680026239A CN101222952A CN 101222952 A CN101222952 A CN 101222952A CN A200680026239X A CNA200680026239X A CN A200680026239XA CN 200680026239 A CN200680026239 A CN 200680026239A CN 101222952 A CN101222952 A CN 101222952A
Authority
CN
China
Prior art keywords
main part
mouth mask
face
woven fabrics
nonwoven
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CNA200680026239XA
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Chinese (zh)
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CN101222952B (en
Inventor
藤田雅也
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Daio Paper Corp
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Daio Paper Corp
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Filing date
Publication date
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Publication of CN101222952A publication Critical patent/CN101222952A/en
Application granted granted Critical
Publication of CN101222952B publication Critical patent/CN101222952B/en
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Classifications

    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62BDEVICES, APPARATUS OR METHODS FOR LIFE-SAVING
    • A62B18/00Breathing masks or helmets, e.g. affording protection against chemical agents or for use at high altitudes or incorporating a pump or compressor for reducing the inhalation effort
    • A62B18/02Masks
    • A62B18/025Halfmasks
    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62BDEVICES, APPARATUS OR METHODS FOR LIFE-SAVING
    • A62B18/00Breathing masks or helmets, e.g. affording protection against chemical agents or for use at high altitudes or incorporating a pump or compressor for reducing the inhalation effort
    • A62B18/02Masks
    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41DOUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D13/00Professional, industrial or sporting protective garments, e.g. surgeons' gowns or garments protecting against blows or punches
    • A41D13/05Professional, industrial or sporting protective garments, e.g. surgeons' gowns or garments protecting against blows or punches protecting only a particular body part
    • A41D13/11Protective face masks, e.g. for surgical use, or for use in foul atmospheres
    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41DOUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D13/00Professional, industrial or sporting protective garments, e.g. surgeons' gowns or garments protecting against blows or punches
    • A41D13/05Professional, industrial or sporting protective garments, e.g. surgeons' gowns or garments protecting against blows or punches protecting only a particular body part
    • A41D13/11Protective face masks, e.g. for surgical use, or for use in foul atmospheres
    • A41D13/1107Protective face masks, e.g. for surgical use, or for use in foul atmospheres characterised by their shape
    • A41D13/113Protective face masks, e.g. for surgical use, or for use in foul atmospheres characterised by their shape with a vertical fold or weld
    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62BDEVICES, APPARATUS OR METHODS FOR LIFE-SAVING
    • A62B23/00Filters for breathing-protection purposes
    • A62B23/02Filters for breathing-protection purposes for respirators
    • A62B23/025Filters for breathing-protection purposes for respirators the filter having substantially the shape of a mask

Abstract

To provide a less napped mask. This mask is so formed that all or a part of the surface of the body part of the mask which is brought into contact with the face of a user is soaked with a smoothing agent. The body part covers the objective portion of the face of the user having the nose and the mouth of the user.

Description

Mouth mask
Technical field
The present invention relates to cover the mouth mask of nose and mouth, particularly relate to being used to prevent to be the disposable breathing mask that enters or prevent that the saliva spittle from dispersing towards periphery etc. of the anaphylactogen etc. of representative with pollen.
Background technology
In recent years, the demand to the disposable breathing mask that is used to tackle pollinosis, preventing cold etc. increases to some extent.The mouth mask that has various materials such as using cotton, paper, nonwoven in the mouth mask, wherein, owing to can make at an easy rate and also excellent, and be convenient to disposable use, so particularly used the mouth mask of nonwoven to obtain popularizing widely to the removing property excellence of dust and pollen and gas permeability.
Patent documentation 1: TOHKEMY 2004-313293 communique
Patent documentation 2: Japanese Utility Model is registered No. 2533937
But for the disposable breathing mask of existing use nonwoven, the friction of skin and mouth mask causes the contact-making surface of mouth mask and skin to fluff gradually during owing to use, sometimes because of this fluffing can produce sense of discomfort, or injury skin.
Particularly the frequency of utilization of disposable breathing mask high winter to the early spring because temperature is low and dry, this fluffing trends towards strengthening to the stimulation of skin, therefore needs to improve this situation.
Summary of the invention
Therefore, major subjects of the present invention is, improves the flatness between mouth mask and skin, and the stimulation to skin of preventing to rub prevents to follow the fluffing of friction and the stimulation to skin that causes, improves the sense of wearing when wearing for a long time.
The present invention who solves above-mentioned problem is as described below.
The described invention in<the 1 aspect 〉
A kind of mouth mask, this mouth mask has: the main part that covers the object position of the face that comprises nose and mouth; With the left and right sides of being located at this main part, be used to fix the holding division on ear, described mouth mask is characterised in that the layer of the formation of described main part and the face of facial contact is a nonwoven, and all or part of of main part and face facial contact contains smooth agent.
(action effect)
Because all or part of of main part and face facial contact contains smooth agent, so little to the stimulation of skin.
The described invention in<the 2 aspect 〉
As the described mouth mask in the 1st aspect, wherein, be coated with smooth agent at the circumference with face facial contact main part.
(action effect)
In the main part of mouth mask, particularly constitute structure with the skin driving fit in order to prevent pollen, dust etc. from entering, so this peripheral part especially easily and skin friction with the peripheral part of the face of facial contact.Thereby,, can reduce stimulation effectively to skin by at this peripheral part coating smooth agent.
The described invention in<the 3 aspect 〉
As the described mouth mask in the 1st or 2 aspects, wherein, on main part and face facial contact, be coated with the smooth agent of 1~15gsm.
(action effect)
The coating amount of smooth agent is preferably 1~15gsm.If less than 1gsm, then be difficult to bring into play the effect of smooth agent, if surpass 15gsm, then be clamminess easily.
The described invention in<the 4 aspect 〉
As the described mouth mask of the either side in the 1st~3 aspect, wherein, described nonwoven is a hydrophily.
(action effect)
When nonwoven was hydrophily, the compatibility excellence of itself and smooth agent, and the confining force of smooth agent is also excellent was difficult for dryly in addition, further reduces the stimulation to skin.
The described invention in<the 5 aspect 〉
As the described mouth mask of the either side in the 1st~4 aspect, wherein, main part has two-layer above layer structure, and all or part of of the layer of the face of formation and facial contact formed by melt spraying non-woven fabrics.
(action effect)
If main part forms sandwich construction, then can with the layer of facial contact as melt spraying non-woven fabrics reducing stimulation to skin, and use the other materials of the control of dust excellence of dust at other layer.In addition, the inventor finds, compares with other nonwoven such as spun-bonded non-woven fabrics, and melt spraying non-woven fabrics fluffs less and little to the stimulation of skin with skin friction the time.The present invention is based on this discovery.
The described invention in<the 6 aspect 〉
As the described mouth mask of the either side in the 1st~5 aspect, wherein, the peripheral part with face facial contact main part is formed by melt spraying non-woven fabrics.
(action effect)
As mentioned above, the circumference with face facial contact main part is easy to and skin friction, therefore fluffing easily.Thereby, especially can the further stimulation that reduces skin at the mouth mask of the present invention of this part configuration melt spraying non-woven fabrics.
As mentioned above, can play above-mentioned action effect according to the present invention, satisfy these will make phozy, skin do not had the mouth mask that stimulates.
Description of drawings
Fig. 1 is the stereogram of the expression first shape example.
Fig. 2 is the stereogram of the expression second shape example.
Fig. 3 is the stereogram of expression the 4th shape example.
Fig. 4 is the profile along the IV-IV line of Fig. 3.
Fig. 5 is the side view of expression the 4th shape example.
Fig. 6 is the stereogram of expression the 5th shape example.
Fig. 7 is the front elevation that is illustrated in the main part of the mode of the part configuration melt spraying non-woven fabrics of the face of facial contact.
Fig. 8 is the front elevation that is illustrated in the main part of other modes of the part configuration melt spraying non-woven fabrics of the face of facial contact.
Symbol description
1 mouth mask; 2 main parts; 20 main parts and face facial contact; 3 holding divisions; 4 bonding parts; 5 openings; 6 gauffers; The A circumference; Near the part B center line; The C center line.
The specific embodiment
Below, with reference to accompanying drawing embodiments of the present invention are elaborated.
(the first shape example)
Fig. 1 shows the mouth mask 1 of bag type.This mouth mask 1 has: the main part 2 that covers the corners of the mouth and nasal cavity; With the holding division 3 that is used for this main part 2 is fixed on health.Main part 2 is made of the left part 2L and the right side part 2R that are symmetry about the width Central Line, and these two part 2L, 2R are made by smooth material, and are joined together in the edge portion 4 of width center side.And this bonding part 4 has formed the bending that pars intermedia swells more laterally than both sides up and down.
On the other hand, holding division 3 is the flat member with ring-type of the opening 5 that is used to hang on the ear, and it engages with left and right sides edge 2e, the 2e of main part 2.
Under the overlapping non-working condition of left part 2L and right side part 2R, main part 2 and holding division 3 are smooth.Relative therewith, under the user mode of launching between left part 2L and the right side part 2R (shown position), main part 2 is a cup-shaped.Under this state, put on mouth mask so that it when covering wearer's the corners of the mouth and nasal cavity, can leave ground, space and covering around the corners of the mouth and nasal cavity.
(the second shape example)
In the first shape example, main part 2 and holding division 3 are formed as the parts that separate, and both are bonded together, but also can as shown in Figure 2 main part 2 and holding division 3 be formed as single parts.
(the 3rd shape example)
And, though not shown, in the mode of bag type, do not need to form along the vertical direction closing line, for example also can broad ways form closing line.
(the 4th shape example)
Fig. 3 and Fig. 4 show the mouth mask 11 of flat type, and this mouth mask 11 has: the main part 2 that covers the corners of the mouth and nasal cavity; With the holding division 3 that is used for this main part 2 is fixed on health.Main part 2 has a plurality of gauffers 6 along width (be converted into zigzag and form fold), and the hangers rubber rope as holding division 3 is installed in the form of a ring in its both sides.The quantity of gauffer is preferably 2~3.
In this example, in the width pars intermedia tractive top and bottom of main part 11 so that they when leaving, gauffer 6 is deformed into cup-shaped on the whole so that the mode that the central portion of main part 11 swells is laterally launched.Thereby, as shown in Figure 5, when under this state, wearing mouth mask, can around the corners of the mouth and nasal cavity, leave ground, space and covering with the corners of the mouth that covers the wearer and nasal cavity.
As the shape of main part 2, except rectangle as shown in the figure, can also use suitable shapes such as ellipse, rhombus.
(the 5th shape example)
The 5th shape is a mode of having omitted gauffer with respect to the 4th shape example with gauffer 6 for example as shown in Figure 6.Also can adopt this simple mode.
(the 6th shape example)
The holding division 3 of Fig. 1~mode shown in Figure 4 is that endless member is hung over type on the ear, but also can adopt utilize strip-shaped parts to connect the both sides of main part and with this strip-shaped parts around hanging over the type (omitting diagram) that head or neck fix.Such holding division is for example shown in Japanese kokai publication hei 9-313631 communique.
(structure and material of main part)
Main part 2 can be single layer structure, but is preferably formed the structure that constitutes for by a plurality of layers.For example, can form double-decker as shown in Figure 2 with outer 2A and internal layer 2B, also can be and as shown in Figure 6 as Fig. 4, form have outer 2A, internal layer 2B and between the three-decker of the intermediate layer 2C between them.Especially, can utilize outer 2A (also can be internal layer) as shown in Figure 2, main part 2 and holding division 3 are formed as single parts, stacked internal layer 2B forms double-decker with main part 2 thus on the inner surface of the part that is equivalent to this main part.
Forming under the situation of multilayer, preferred one deck at least, for example the internal layer 2B in the double-decker shown in Figure 2 or the intermediate layer 2C in the three-decker shown in Fig. 4, Fig. 6 have the functional layer that function, aromatic function, virus/anaphylactogen deactivation function, antibacterial functions, the shape of filtering dust etc. keep function etc.
For this functional layer, preferred dismounting is contained in the mode on the main part 2 freely.For example, as shown in Figure 6, under the situation of intermediate layer 2C as functional layer with three-decker, the ora terminalis (perhaps also can be the opening of being located on outer 2A or the internal layer 2B) by main part 2 freely picks and places functional layer 2C, dismounting functional layer freely thus.And, also can adopt this layer structure that constitutes by a plurality of layers at holding division.
Herein, no matter main part is individual layer or sandwich construction, the invention is characterized in, the layer of the face of the formation of main part and facial contact is a nonwoven at least, and, all or part of smooth agent that contains of main part and face facial contact.That is to say, the invention is characterized in, constitute with the nonwoven layer of the face of facial contact, with the face of facial contact all or part of on infiltration or coating smooth agent, thereby make it contain smooth agent.In addition, what make easily is the nonwoven fabric construct of individual layer and the mode that applies smooth agent on entire contact surface, but also can be only to make the mode that is easy to contain with the part of skin friction smooth agent.
Herein, as the part that is easy to skin friction, can enumerate: among Fig. 7 with square main part be shown in the example like that, require the part with the adaptation of skin in order to prevent entering of dust, pollen etc., i.e. the circumference A of the face that contacts with skin 20 of main part; And among Fig. 8 equally with square main part be shown in the example like that, be easy to the part that contacts with nose, promptly in the face that contacts with skin 20 of main part, near the part B center line that extends longitudinally at the left and right directions center.Therefore, can be near the mode of B coating smooth agent etc. this circumference A or center line only.Certainly, also can be the mode of coating smooth agent on these two parts A, B.In addition, circumference A is meant, is roughly 1~5cm apart from the distance L 1 of main part Zhou Duanyuan E, the scope about 2~3cm preferably, B is meant near the center line, apart from the distance L 2 of center line C towards about (holding division direction) be roughly 1~3cm, the preferably scope about 1.5~2cm.In addition, though not shown among the figure, under the situation of the main part that adopts three-dimensional shape illustrated in figures 1 and 2, only equally also can form near the mode of the coating smooth agent circumference of main part and center line.
As smooth agent, can use the known smooth agent that in health tissue papers such as face tissue etc., uses herein.Specifically can enumerate, containing wax, MPC polymer, glycerine, diglycerol, mean molecule quantity is polyethylene glycol, D-sorbite, the propane diols, 1 of 200 above less thaies 1000, the smooth agent of more than one in 3-butanediol, glycinebetaine, 2-pyrrolidone-5-carboxylic acid, pyrrolidone carboxylic acid salt, maltitol, the sodium lactate etc.Preferred wax, MPC polymer, glycerine.
Be manufactured on the mouth mask that contains the mode of smooth agent on described of main part, as long as in advance to being cut to nonwoven base (Woven cloth is not anti-) coating or the infiltration smooth agent before the main part size.For example can adopt known method such as spray pattern, roller transfer method the nonwoven base to be carried out coating of smooth agent etc.If adopt online (inline) coating can suitably apply at necessary position, and needn't correspondingly shear spacing (cut pitch) as when the nonwoven base applies the mode of smooth agent.
Like this, under the situation of coating smooth agent etc., the nonwoven as constituting with the layer of facial contact preferably uses hydrophilic nonwoven.So not only can improve the compatibility with smooth agent, make the confining force excellence of smooth agent, it is dry that it is difficult for, and further reduces the stimulation to skin.As hydrophilic non-woven, can enumerate the nonwoven, the nonwoven that has adopted staple fibre that have adopted through the fiber of hydrophilicity-imparting treatment, adopt cotton nonwoven etc., or slurry hybrid nonwoven cloth etc.
The coating amount of smooth agent is 1~15gsm, is preferably 3~8gsm, is preferably 4~6gsm especially.If coating amount less than 1gsm, then a little less than the moistening effect, if surpass 15gsm, then becomes and is clamminess, sense of discomfort is arranged on the contrary.
Herein, on the other hand owing to can further reduce stimulation to skin, so the face of the formation of preferred main part and facial contact layer partly or entirely make by melt spraying non-woven fabrics.In addition, what make easily is single layer structure and whole modes of being made by melt spraying non-woven fabrics of layer, but also can be only to make the mode that the part with skin friction is made of melt spraying non-woven fabrics that is easy to.Herein, what is called is easy to the part with skin friction, is the circumference A and the part B that is easy to contact with nose of aforesaid mask main body portion.
The manufacturing of melt spraying non-woven fabrics can be adopted existing known method, for example, raw polymers such as crystallinity propylene class can be melt extruded, utilize the gas of high temperature and high speed, the mode that will be flowed with superfine fibre by the fiber that the melt-blow spinneret spinning obtains melts blows spinning, on capturing devices such as wire netting or band, form superfine fleece, make through bonding process.There is no particular limitation to form the fiber diameter of fiber of this melt spraying non-woven fabrics, is generally about 1~30 μ m, is preferably about 2~10 μ m.
The weight per unit area that constitutes the nonwoven of main part is generally 15~70g/m 2, be preferably 20~60g/m 2If less than 15g/m 2, then be difficult to guarantee necessary strength, if surpass 70g/m 2, sense of touch variation and not preferred then.
On the other hand, main part is being formed under the double-deck situation, formation can be a melt spraying non-woven fabrics nonwoven in addition with the layer layer in addition of the face of facial contact.Therefore, for example can be with utilizing spun-bond process shape spun-bonded non-woven fabrics into the net (S) layer and utilizing meltblown shape melt-blown nonwoven layer of cloth into the net (M) stacked more than 2 layers and the non-woven fabric laminate that obtains uses as the material of mask main body portion.Like this, the part that just can make with the face of facial contact is the main part of the stepped construction of melt spraying non-woven fabrics.
Promptly, when obtaining duplexer, if adopt as inferior method just can be easily will be made melt spraying non-woven fabrics with the part of the face of facial contact: for example, directly will utilize fiber accumulations that meltblown forms after the part (can certainly be whole) of spun-bonded non-woven fabrics goes up and forms melt spraying non-woven fabrics, make the method for spun-bonded non-woven fabrics and melt spraying non-woven fabrics heat fusion; After making spun-bonded non-woven fabrics and melt spraying non-woven fabrics overlapping, make the method for two kinds of nonwoven fusions by the heating pressurization; The method of utilizing bonding agents such as hot-melt adhesive, solvent based bonding agent that spun-bonded non-woven fabrics and melt spraying non-woven fabrics are bonded together.
Herein, the method that directly forms melt spraying non-woven fabrics on spun-bonded non-woven fabrics can be undertaken by following meltblown, that is, and and to the fused mass of part or all spraying thermoplastic resin on the surface of spun-bonded non-woven fabrics, so that fiber accumulations.At this moment, for spun-bonded non-woven fabrics, the face of opposition side that is coated with the face of fused mass one side is a negative pressure, spraying utilizes the fiber of meltblown formation and makes its accumulation, make spun-bonded non-woven fabrics and melt spraying non-woven fabrics integrated simultaneously, thereby obtain having the flexibility non-woven fabric laminate of spun-bonded non-woven fabrics layer and melt-blown nonwoven layer of cloth.Under the integrated inadequate situation of two kinds of nonwoven, can utilize heating pressurization embossing roller to wait and make it integrated fully.
As merging the method that spun-bonded non-woven fabrics and melt spraying non-woven fabrics are merged by heat, have the hot method that merges of the entire contact surface that makes spun-bonded non-woven fabrics and melt spraying non-woven fabrics and making spun-bonded non-woven fabrics and the method for the part heat fusion of the contact-making surface of melt spraying non-woven fabrics.
(material of holding division)
As the material of holding division 3, also can from the same material of main part 2 select, but preferably select to be rich in retractility and elasticity and the material little to the stimulation of skin.
For example, under the situation of the mouth mask 1 of bag type, except pasting nonwoven and implement the lamination nonwoven that processes of raising retractilities such as acupuncture processing as required or in both sides in the table of elastic extension film by the net that is made of the composite fibre with hot crimp property being heat-treated the flexible nonwoven fabrics that obtains, can also be suitable for using following nonwoven, that is, by a pair of nonwoven being sticked together and between nonwoven, accompanying flexible nonwoven fabrics that elastic telescopic parts such as rubber covered wire form etc.
And, for example be under the situation of flat type mouth mask 11, except can from the situation identical materials of the mouth mask 1 of bag type select, can also use for example flat rubber strip (flat go system), rubber ring (ball go system) etc.
In addition, can also will be used for holding division 3 to these materials and the material in the item of main part 2, narrated by the stacked grade material that obtains that combines.
Certainly, so long as in the scope that does not influence the retractility that is used to fix, can adopt with melt spraying non-woven fabrics and form mode holding division and face facial contact, also can apply smooth agent.
(size of main part)
The size of main part 2 can suitably be set and there is no particular limitation, for example, mouth mask is under the situation of bag type, can make the size of long 90~150mm, wide 60~110mm, and, mouth mask is (having under the situation of gauffer 6 for not launching the state of gauffer 6) under the situation of flat type, can make the size of long 80~110mm, wide 80~180mm.
(other)
Can utilize known joint method such as heat-sealing or hot melt adhesion, ultrasonic wave coating etc. to carry out parts joint or layer joint each other each other.
Utilizability on the industry
The present invention is except the anaphylactogen that can be applied to tackle pollinosis etc. or the infection that prevents from catching a cold etc. Cover for purpose outside the mouth mask of nose or mouth, can also be applied to widely purposes.

Claims (6)

1. mouth mask, this mouth mask has: the main part that covers the object position of the face that comprises nose and mouth; With the left and right sides of being located at this main part, be used to fix the holding division on ear, it is characterized in that,
The layer of the formation of described main part and the face of facial contact is a nonwoven, and all or part of of main part and face facial contact contains smooth agent.
2. mouth mask as claimed in claim 1, wherein,
Be coated with smooth agent at the circumference with face facial contact main part.
3. mouth mask as claimed in claim 1 or 2, wherein,
On main part and face facial contact, be coated with the smooth agent of 1~15gsm.
4. as each the described mouth mask in the claim 1~3, wherein,
Described nonwoven is a hydrophily.
5. as each the described mouth mask in the claim 1~4, wherein,
Main part has two-layer above layer structure, and all or part of of the layer of the face of formation and facial contact formed by melt spraying non-woven fabrics.
6. as each the described mouth mask in the claim 1~5, wherein,
Peripheral part with face facial contact main part is formed by melt spraying non-woven fabrics.
CN200680026239XA 2005-07-20 2006-07-20 Mask Active CN101222952B (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2005210441A JP4594180B2 (en) 2005-07-20 2005-07-20 mask
JP210441/2005 2005-07-20
PCT/JP2006/314351 WO2007010967A1 (en) 2005-07-20 2006-07-20 Mask

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Publication Number Publication Date
CN101222952A true CN101222952A (en) 2008-07-16
CN101222952B CN101222952B (en) 2011-10-05

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JP (1) JP4594180B2 (en)
KR (1) KR101283518B1 (en)
CN (1) CN101222952B (en)
WO (1) WO2007010967A1 (en)

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CN103734939A (en) * 2014-01-27 2014-04-23 山东爱地高分子材料有限公司 High-heat-conducting durable mask
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US10808338B1 (en) * 2020-04-10 2020-10-20 Finotex U.S.A. Corp. Woven personal respirator mask and methods of making same
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CN102781523A (en) * 2010-03-03 2012-11-14 3M创新有限公司 Dispensable face mask and method of making the same
CN102781523B (en) * 2010-03-03 2015-09-09 3M创新有限公司 Disposable face guard and preparation method thereof
CN103533990A (en) * 2011-04-08 2014-01-22 尤妮佳股份有限公司 Mask
CN103533990B (en) * 2011-04-08 2016-09-07 尤妮佳股份有限公司 Mouth mask
CN103734939A (en) * 2014-01-27 2014-04-23 山东爱地高分子材料有限公司 High-heat-conducting durable mask
CN110602959A (en) * 2017-07-28 2019-12-20 尤妮佳股份有限公司 Gauze mask

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CN101222952B (en) 2011-10-05
KR20080038166A (en) 2008-05-02
KR101283518B1 (en) 2013-07-15
JP4594180B2 (en) 2010-12-08
WO2007010967A1 (en) 2007-01-25
JP2007021025A (en) 2007-02-01

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