CN101204794A - High temperature soldering CBN grinding wheel used metal combination dose layer material adding rare earths La - Google Patents
High temperature soldering CBN grinding wheel used metal combination dose layer material adding rare earths La Download PDFInfo
- Publication number
- CN101204794A CN101204794A CNA200710190937XA CN200710190937A CN101204794A CN 101204794 A CN101204794 A CN 101204794A CN A200710190937X A CNA200710190937X A CN A200710190937XA CN 200710190937 A CN200710190937 A CN 200710190937A CN 101204794 A CN101204794 A CN 101204794A
- Authority
- CN
- China
- Prior art keywords
- high temperature
- layer material
- lanthanum
- grinding wheel
- titanium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000463 material Substances 0.000 title claims abstract description 26
- 229910052751 metal Inorganic materials 0.000 title claims description 9
- 239000002184 metal Substances 0.000 title claims description 9
- 238000005476 soldering Methods 0.000 title claims description 9
- 239000010936 titanium Substances 0.000 claims abstract description 32
- 229910052746 lanthanum Inorganic materials 0.000 claims abstract description 20
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims abstract description 20
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000010949 copper Substances 0.000 claims abstract description 18
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 18
- 229910052761 rare earth metal Inorganic materials 0.000 claims abstract description 17
- 150000002910 rare earth metals Chemical class 0.000 claims abstract description 11
- 239000000126 substance Substances 0.000 claims abstract description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910052802 copper Inorganic materials 0.000 claims abstract description 4
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 18
- 229910052709 silver Inorganic materials 0.000 claims description 18
- 239000004332 silver Substances 0.000 claims description 18
- 229910045601 alloy Inorganic materials 0.000 claims description 4
- 239000000956 alloy Substances 0.000 claims description 4
- -1 copper rare earth Chemical class 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 2
- 230000008018 melting Effects 0.000 claims 1
- 238000002844 melting Methods 0.000 claims 1
- 238000005219 brazing Methods 0.000 abstract description 22
- 239000007769 metal material Substances 0.000 abstract description 2
- 241000412565 Argentina sphyraena Species 0.000 abstract 1
- AILDTIZEPVHXBF-UHFFFAOYSA-N Argentine Natural products C1C(C2)C3=CC=CC(=O)N3CC1CN2C(=O)N1CC(C=2N(C(=O)C=CC=2)C2)CC2C1 AILDTIZEPVHXBF-UHFFFAOYSA-N 0.000 abstract 1
- 229910000858 La alloy Inorganic materials 0.000 abstract 1
- 235000016594 Potentilla anserina Nutrition 0.000 abstract 1
- FQVNUZAZHHOJOH-UHFFFAOYSA-N copper lanthanum Chemical compound [Cu].[La] FQVNUZAZHHOJOH-UHFFFAOYSA-N 0.000 abstract 1
- 238000009736 wetting Methods 0.000 abstract 1
- 239000007767 bonding agent Substances 0.000 description 15
- 239000011159 matrix material Substances 0.000 description 14
- 230000007480 spreading Effects 0.000 description 12
- 238000003892 spreading Methods 0.000 description 12
- 229910000906 Bronze Inorganic materials 0.000 description 11
- 229910000831 Steel Inorganic materials 0.000 description 11
- 239000010974 bronze Substances 0.000 description 11
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 11
- 239000010959 steel Substances 0.000 description 11
- 229910001651 emery Inorganic materials 0.000 description 9
- 239000002245 particle Substances 0.000 description 7
- 229910001069 Ti alloy Inorganic materials 0.000 description 5
- 238000003723 Smelting Methods 0.000 description 3
- 239000003082 abrasive agent Substances 0.000 description 3
- 239000000428 dust Substances 0.000 description 3
- 238000005272 metallurgy Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 241001062472 Stokellia anisodon Species 0.000 description 2
- IUYOGGFTLHZHEG-UHFFFAOYSA-N copper titanium Chemical compound [Ti].[Cu] IUYOGGFTLHZHEG-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229910000765 intermetallic Inorganic materials 0.000 description 2
- 238000003754 machining Methods 0.000 description 2
- 229910052582 BN Inorganic materials 0.000 description 1
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 description 1
- AHGIVYNZKJCSBA-UHFFFAOYSA-N [Ti].[Ag].[Cu] Chemical compound [Ti].[Ag].[Cu] AHGIVYNZKJCSBA-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000011812 mixed powder Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 230000003746 surface roughness Effects 0.000 description 1
Images
Landscapes
- Polishing Bodies And Polishing Tools (AREA)
Abstract
A metallic bond layer material added with rare-earth La used for a high temperature brazing CBN grinding wheel belongs to the technical field of metallic material engineering and relates to the technical field of superhard tool high temperature brazing. The chemical components of the invention are matched according to the weight fractions of 20 to 30 percent of copper (Cu), 3 to 7 percent of titanium (Ti), 0.05 to 0.5 percent of lanthanum (La) and the other is argentine (Ag). The rare-earth lanthanum (La) is melt in the mode of a copper-lanthanum alloy. The bond of the invention has the advantages of few components, excellent wetting property, high intensity and excellent comprehensive performance. The invention can meet the requirements for the field of high temperature brazing superhard tool.
Description
Technical field
The invention belongs to the metal material engineering technical field, relate to high temperature brazing sintered carbide tools technical field, specially refer to a kind of high performance bond.
Background technology
Chemical metallurgy combination when high temperature brazing CBN emery wheel utilizes soldering between matrix-bond-abrasive particle has fundamentally been improved intensity has been controlled in the combination of abrasive material, abrasive material does not come off substantially in the process, satisfy the needs of high-efficiency and precision processing operation, helped the improvement of machined surface roughness; Simultaneously, high temperature brazing CBN emery wheel has shape hold facility preferably, can avoid drawbacks such as the uniformity interchangeability relatively poor, workpiece of the workpiece accuracy that multilayer instruments such as resinoid bond or vitrified bond need often repair, process is bad.The titanium alloy chemism is big, and thermal conductivity is low, belongs to typical difficult-to-machine material, is easy to stick in grinding process.Replace traditional emery wheel machining titanium alloy with the CBN emery wheel and obtained certain effect.When machining titanium alloy, to the demands for higher performance of high temperature brazing CBN emery wheel, not only to satisfy surface of the work integrality and dimension precision requirement, also require abrasive dust to be easy to come off from wheel face, do not stick, guarantee the long-time reliability service of emery wheel.Therefore the bond of high temperature brazing CBN emery wheel is had higher requirement, not only will have good wettability, guarantee firm being welded on the matrix of abrasive particle, require it to be difficult for sticking simultaneously with the titanium alloy abrasive dust to abrasive material and matrix.Metallic bond silver-bearing copper titanium commonly used has very big affinity owing to contain titanium with abrasive dust, but titanium is again bond and abrasive particle generation chemical reaction, the important element of realizing the chemical metallurgy combination, the content reduction can influence the intensity of controlling to abrasive particle, and then reduces wheel life.
Rare earth has very high chemism, be a kind of typically, very active metal, have and breed and go bad, strengthen, improve heat resistance and improve effect such as processing performance, obtained to use widely at metallurgy and material field.
Summary of the invention
The objective of the invention is to, a kind of high temperature soldering CBN grinding wheel used metal combination dose layer material that adds rare earth La is provided, it is by adding the combination property that rare-earth elements of lanthanum (La) improves bond in high temperature brazing CBN emery wheel metallic bond, simultaneously, improve the performance of high temperature brazing CBN emery wheel guaranteeing that abrasive particle controls the content that reduces titanium elements on the intensity based.
The high temperature soldering CBN grinding wheel used metal combination dose layer material of the interpolation rare earth La of the present invention's design is characterized in that: its chemical composition mark proportioning by weight is: 20%～30% copper (Cu), 2%～7% titanium (Ti), 0.05%～1.0% lanthanum (La), all the other are silver (Ag).
The preferred range of lanthanum of the present invention (La) is 0.1～0.5%.
Bonding agent layer material constituent element of the present invention is less, and wettability is good, because the adding of rare earth element, refinement intermetallic compound, make organizing of bond more even, improved the intensity of bond, high comprehensive performance can satisfy the requirement in sintered carbide tools high temperature brazing field.
Description of drawings
Fig. 1 is the alloy microscopic structure of silver-bearing copper titanium bonding agent layer material in the prior art, and the intermetallic compound length among the figure can reach 200 μ m.
Fig. 2 is the microscopic structure of Ag-Cu-Ti-0.25La (embodiment four) bonding agent layer material.
The specific embodiment
1) the commercially available silver of Shi Yonging, cathode copper, Titanium, copper lanthanum rare earth intermediate alloy, proportioning adopts conventional high frequency smelting furnace to smelt, pour into a mould on demand, and atomizing obtains required bond powder then; 2) according to actual needs, copper lanthanum rare earth intermediate alloy can be added in silver-copper-titanium alloy and smelt, pour into a mould, atomizing obtains required bond powder then; 3) smelting the mixed powder machine of preceding employing fully mixes raw material powder; 4) smelting temperature is incubated 4～5 hours between 850 ℃～1050 ℃.
Embodiment one:
20% bronze medal (Cu), 7% titanium (Ti), 0.05% lanthanum (La), all the other are silver (Ag).The solidus temperature of the bonding agent layer material that the mentioned component proportioning obtains, liquidus temperature, microhardness, the spreading area on high temperature brazing instrument steel matrix commonly used are as shown in table 1.
Embodiment two:
22% bronze medal (Cu), 5% titanium (Ti), 0.05% lanthanum (La), all the other are silver (Ag).The solidus temperature of the bonding agent layer material that the mentioned component proportioning obtains, liquidus temperature, microhardness, the spreading area on high temperature brazing instrument steel matrix commonly used are as shown in table 1.
Embodiment three:
25% bronze medal (Cu), 4.5% titanium (Ti), 0.1% lanthanum (La), all the other are silver (Ag).The solidus temperature of the bonding agent layer material that the mentioned component proportioning obtains, liquidus temperature, microhardness, the spreading area on high temperature brazing instrument steel matrix commonly used are as shown in table 1.
Embodiment four:
24% bronze medal (Cu), 4% titanium (Ti), 0.15% lanthanum (La), all the other are silver (Ag).The solidus temperature of the bonding agent layer material that the mentioned component proportioning obtains, liquidus temperature, microhardness, the spreading area on high temperature brazing instrument steel matrix commonly used are as shown in table 1.
Embodiment five:
26% bronze medal (Cu), 4% titanium (Ti), 0.25% lanthanum (La), all the other are silver (Ag).The solidus temperature of the bonding agent layer material that the mentioned component proportioning obtains, liquidus temperature, microhardness, the spreading area on high temperature brazing instrument steel matrix commonly used are as shown in table 1.
Embodiment six:
28% bronze medal (Cu), 4% titanium (Ti), 0.4% lanthanum (La), all the other are silver (Ag).The solidus temperature of the bonding agent layer material that the mentioned component proportioning obtains, liquidus temperature, microhardness, the spreading area on high temperature brazing instrument steel matrix commonly used are as shown in table 1.
Embodiment seven:
28% bronze medal (Cu), 3.5% titanium (Ti), 0.5% lanthanum (La), all the other are silver (Ag).The solidus temperature of the bonding agent layer material that the mentioned component proportioning obtains, liquidus temperature, microhardness, the spreading area on high temperature brazing instrument steel matrix commonly used are as shown in table 1.
Embodiment eight:
25% bronze medal (Cu), 3% titanium (Ti), 0.5% lanthanum (La), all the other are silver (Ag).The solidus temperature of the bonding agent layer material that the mentioned component proportioning obtains, liquidus temperature, microhardness, the spreading area on high temperature brazing instrument steel matrix commonly used are as shown in table 1.
Embodiment nine:
24% bronze medal (Cu), 4% titanium (Ti), 0.75% lanthanum (La), all the other are silver (Ag).The solidus temperature of the bonding agent layer material that the mentioned component proportioning obtains, liquidus temperature, microhardness, the spreading area on high temperature brazing instrument steel matrix commonly used are as shown in table 1.
Embodiment ten:
30% bronze medal (Cu), 3% titanium (Ti), 0.5% lanthanum (La), all the other are silver (Ag).The solidus temperature of the bonding agent layer material that the mentioned component proportioning obtains, liquidus temperature, microhardness, the spreading area on high temperature brazing instrument steel matrix commonly used are as shown in table 1.
Embodiment 11:
24% bronze medal (Cu), 4% titanium (Ti), 1% lanthanum (La), all the other are silver (Ag).The solidus temperature of the bonding agent layer material that the mentioned component proportioning obtains, liquidus temperature, microhardness, the spreading area on high temperature brazing instrument steel matrix commonly used are as shown in table 1.
The high temperature soldering CBN grinding wheel used metal combination dose layer material of interpolation rare earth La of the present invention has good wettability to doctor matrix and super-hard abrasive cubic boron nitride (CBN), simultaneously by simple and easy scratch test, the dropping situations of observation CBN abrasive particle, find any bonding agent layer material that contains Rare Earth Lanthanum in the foregoing description one to embodiment six, all show good hold abrasive particle.
The performance comparison of silver-bearing copper titanium bond in table 1 embodiments of the invention and the prior art
| The contrast project | Liquidus curve (℃) | Solidus (℃) | Hardness (HV) | Spreading area (cm 2) |
| The silver-bearing copper titanium | 792 | 774 | 80 | 9.75 |
| Embodiment 1 embodiment 2 embodiment 3 embodiment 4 embodiment 5 embodiment 6 embodiment 7 embodiment 8 embodiment 9 embodiment 10 embodiment 11 | 801 795 793 794 796 797 797 798 799 796 800 | 775 774 775 775 774 772 773 772 770 771 773 | 95 90 95 110 114 119 120 118 110 118 108 | 9.85 9.9 10.4 10.88 11 11.4 11.55 11.5 8.2 11.7 6.5 |
Claims (3)
1. high temperature soldering CBN grinding wheel used metal combination dose layer material that adds rare earth La, it is characterized in that its chemical composition by the mass fraction proportioning is: 20%～30% copper (Cu), 3%～7% titanium (Ti), 0.05%～1.0% lanthanum (La), all the other are silver (Ag).
2. the high temperature soldering CBN grinding wheel used metal combination dose layer material of interpolation rare earth La according to claim 1 is characterized in that: the mass fraction proportioning of described lanthanum (La) is 0.05～0.5%.
3. the high temperature soldering CBN grinding wheel used metal combination dose layer material of interpolation rare earth La according to claim 1 is characterized in that: described rare-earth elements of lanthanum (La) is the form melting with the copper rare earth alloy.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA200710190937XA CN101204794A (en) | 2007-12-03 | 2007-12-03 | High temperature soldering CBN grinding wheel used metal combination dose layer material adding rare earths La |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA200710190937XA CN101204794A (en) | 2007-12-03 | 2007-12-03 | High temperature soldering CBN grinding wheel used metal combination dose layer material adding rare earths La |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101204794A true CN101204794A (en) | 2008-06-25 |
Family
ID=39565384
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA200710190937XA Pending CN101204794A (en) | 2007-12-03 | 2007-12-03 | High temperature soldering CBN grinding wheel used metal combination dose layer material adding rare earths La |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101204794A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101353258A (en) * | 2008-08-07 | 2009-01-28 | 沈阳中科超硬磨具磨削研究所 | CBN grinding wheel of low temperature vitrified bond and preparation technique thereof |
| TWI426981B (en) * | 2010-11-23 | 2014-02-21 | Univ Nat Pingtung Sci & Tech | Wafer grinding plate and manufacture method thereof |
| CN103846820A (en) * | 2014-02-11 | 2014-06-11 | 当涂县南方红月磨具磨料有限公司 | High temperature resistant anti-bending brown corundum grinding wheel |
| CN106863158A (en) * | 2017-03-31 | 2017-06-20 | 苏州科技大学 | A kind of method of vacuum brazing cubic boron nitride abrasive wheel |
| CN106976023A (en) * | 2017-03-31 | 2017-07-25 | 苏州科技大学 | A kind of method of sensing heating high-entropy alloy Furnace Brazing of Diamond Grinding Wheel With Ni |
| CN111251199A (en) * | 2020-03-09 | 2020-06-09 | 西南交通大学 | Copper-based binder carborundum grinding wheel special for railway steel rail grinding and preparation method thereof |
| CN112192457A (en) * | 2020-09-08 | 2021-01-08 | 郑州磨料磨具磨削研究所有限公司 | Low-melting-point hard and brittle metal resin composite binding agent, grinding tool containing low-melting-point hard and brittle metal resin composite binding agent and preparation method of grinding tool |
| CN114055012A (en) * | 2021-11-05 | 2022-02-18 | 安徽工业大学 | Multi-element copper-based alloy brazing filler metal containing rare earth elements, preparation method and brazing method thereof |
-
2007
- 2007-12-03 CN CNA200710190937XA patent/CN101204794A/en active Pending
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101353258A (en) * | 2008-08-07 | 2009-01-28 | 沈阳中科超硬磨具磨削研究所 | CBN grinding wheel of low temperature vitrified bond and preparation technique thereof |
| CN101353258B (en) * | 2008-08-07 | 2013-04-24 | 沈阳中科超硬磨具磨削研究所 | CBN grinding wheel of low temperature vitrified bond and preparation technique thereof |
| TWI426981B (en) * | 2010-11-23 | 2014-02-21 | Univ Nat Pingtung Sci & Tech | Wafer grinding plate and manufacture method thereof |
| CN103846820A (en) * | 2014-02-11 | 2014-06-11 | 当涂县南方红月磨具磨料有限公司 | High temperature resistant anti-bending brown corundum grinding wheel |
| CN106863158A (en) * | 2017-03-31 | 2017-06-20 | 苏州科技大学 | A kind of method of vacuum brazing cubic boron nitride abrasive wheel |
| CN106976023A (en) * | 2017-03-31 | 2017-07-25 | 苏州科技大学 | A kind of method of sensing heating high-entropy alloy Furnace Brazing of Diamond Grinding Wheel With Ni |
| CN106976023B (en) * | 2017-03-31 | 2018-12-07 | 苏州科技大学 | A kind of method of induction heating high-entropy alloy Furnace Brazing of Diamond Grinding Wheel With Ni |
| CN111251199A (en) * | 2020-03-09 | 2020-06-09 | 西南交通大学 | Copper-based binder carborundum grinding wheel special for railway steel rail grinding and preparation method thereof |
| CN112192457A (en) * | 2020-09-08 | 2021-01-08 | 郑州磨料磨具磨削研究所有限公司 | Low-melting-point hard and brittle metal resin composite binding agent, grinding tool containing low-melting-point hard and brittle metal resin composite binding agent and preparation method of grinding tool |
| CN114055012A (en) * | 2021-11-05 | 2022-02-18 | 安徽工业大学 | Multi-element copper-based alloy brazing filler metal containing rare earth elements, preparation method and brazing method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101204794A (en) | High temperature soldering CBN grinding wheel used metal combination dose layer material adding rare earths La | |
| CN1255243C (en) | Reducing metals as brazing flux | |
| CN102059423B (en) | Method for manufacturing diamond tool with self-lubrication function | |
| CN104646852B (en) | Pricker applies cream and its application | |
| KR101867104B1 (en) | Sintered cubic boron nitride tool | |
| CN103231064B (en) | Manufacturing method for novel nickel base solder brazing monolayer diamond grinding wheel | |
| CN106976023B (en) | A kind of method of induction heating high-entropy alloy Furnace Brazing of Diamond Grinding Wheel With Ni | |
| CN105619272B (en) | A kind of production method of laser Furnace Brazing of Diamond Grinding Wheel With Ni | |
| CN105618883A (en) | Manufacturing method for vacuum-brazed monolayer cBN (cubic Boron Nitride) grinding wheel | |
| CN108748702B (en) | Diamond saw blade | |
| CN111390426B (en) | Composite brazing filler metal for superhard abrasive brazing, preparation method of composite brazing filler metal and brazing method | |
| CN106238962A (en) | A kind of active solder alloy | |
| CN102001053A (en) | Ceramic hollow sphere composite binder cubic boron nitride grinding wheel working layer and manufacturing method thereof | |
| CN110303269A (en) | For the Sn-Cu-Ti solder of low temperature brazing diamond and application | |
| CN108527176A (en) | A kind of production method of novel diamond tool | |
| CN110981497A (en) | High-thermal-conductivity and high-wear-resistance silicon nitride ceramic and preparation method and application thereof | |
| CN110512131B (en) | Integral metal ceramic alloy bar and preparation method and application thereof | |
| CN106031956A (en) | Welding process of cubic boron nitride soldering materials | |
| CN114182136B (en) | Copper-aluminum prealloy, preparation method and diamond tool | |
| CN109365879A (en) | A kind of military project plate armour Kevlar layer boring long-life ultra-thin sintering soldering hole drill | |
| CN102049583A (en) | Method for manufacturing composite welding blade | |
| JP2009102709A (en) | Cemented carbide with laminated structure, method for producing the same, and tool formed from the cemented carbide | |
| JPS61141672A (en) | Manufacture of cubic boron nitride base sintered body for cutting tool | |
| CN209255925U (en) | A kind of military project plate armour Kevlar layer boring long-life ultra-thin sintering soldering hole drill | |
| CN103231054B (en) | Sintering-brazing method of metal matrix diamond segments |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |