CN101194754A - Solvent for perfuming cigarette capable of improving perfume addition efficiency and uses thereof - Google Patents

Solvent for perfuming cigarette capable of improving perfume addition efficiency and uses thereof Download PDF

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Publication number
CN101194754A
CN101194754A CNA2007103000234A CN200710300023A CN101194754A CN 101194754 A CN101194754 A CN 101194754A CN A2007103000234 A CNA2007103000234 A CN A2007103000234A CN 200710300023 A CN200710300023 A CN 200710300023A CN 101194754 A CN101194754 A CN 101194754A
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China
Prior art keywords
cigarette
solvent
flavor
perfuming
flavoring
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CNA2007103000234A
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Chinese (zh)
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CN101194754B (en
Inventor
宋瑜冰
宗永立
李鹏
屈展
孙世豪
杨春强
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Zhengzhou Tobacco Research Institute of CNTC
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Zhengzhou Tobacco Research Institute of CNTC
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Abstract

The invention relates to a cigarette flavoring solvent capable of improving the flavor addition efficiency and the application thereof, and the invention is characterized in that: the solvent comprises by volume percentage: glycerin 5-50 %, methyl glycol 5-50 %, glycerin triacetate 10-80 % and alcohol 10-80 %, the solvent is used as the cigarette flavoring solvent and is prepared into the flavoring solution which is charged into the tobacco of the cigarette to improve the cigarette flavoring addition effect. The invention has the advantages that the solvent can effectively improve the transferring rate of the additive flavor into the cigarette mainstream smoke and particle phase, thereby improving the flavor addition efficiency with no abnormal smell and no changing of the cigarette flavor style; through even mixing of the solvent with flavoring agents, a flavor solution is prepared with good effect in the flavor addition of the cigarette, meanwhile, the invention has simple process, low cost and can be used as a common solvent for the flavor agents addition of cigarettes.

Description

A kind of solvent for perfuming cigarette and application thereof that can improve perfume addition efficiency
Technical field
The invention belongs to the tobacco field, concretely, relating to a kind of solvent for perfuming cigarette and application thereof that can improve perfume addition efficiency, mainly is recently to improve perfume addition efficiency by use during spice solution this solvent to improve the percentage that spices enters in the main flume granule phase substance in preparation.
Technical background
The essence spice for cigarette technology is one of important core technology of tobacco business, determining the reasonable volume of perfume monomer and adding efficient is a very important part in the essence spice for cigarette technology, put forth effort to promote the style and features of cigarette flavoring efficient, raising cigarette flavor matter perfume quantity, reinforcement cigarette, most important to improving the cigarette product quality.
The tobacco enterprise perfuming adopts usually and in the pipe tobacco process spice solution is sprayed on the pipe tobacco at present, makes cigarette product through the series of process flow process then, the interpolation efficient of this process spices is estimated obviously extensive relatively.The laboratory generally adopts the method that quantitative spice solution is injected into cigarette shreds to carry out perfuming, and this method even injection, quantitatively precisely is fit to spices is carried out quantitative analysis and perfuming efficiency rating.
The rate of transform of spices in the cigarette mainstream flue gas granule phase substance is the direct reflection of its perfuming efficient, and the main flume grain phase transfer rate of spices is high more, and corresponding perfuming efficient is also high more.Therefore, improving spices is the key that improves the perfuming effect to the rate of transform, the lost of minimizing spices of main flume grain phase.Literature survey is found the solvent kind deficiency of preparation spice solution at present, and the tobacco flavoring of having reported mostly is ethanol with solvent, former research (Houseman T H.Beitr.Tabakforsch Int.1973, (7): 142-147; BinghamM A, Craig J J D, Mckeivor R.Chem.Res.Conf.1979.33; LynmD.Tob.Chem.Res.Conf., 1987,41 (29): 32; Song Yubing, Zong Yongli etc. Chinese tobacco journal 2005, (03): 21.) show, when using ethanol as perfume solvent, the spices that boiling point is lower can not enter the main flume grain mutually in, the percentage that the higher spices of boiling point enters main flume grain phase is also lower, so cause the interpolation efficient of spices low, the amount of flavorants of waste is bigger.
Summary of the invention
The present invention just is being based on above-mentioned tobacco business hot issue, solvent kind deficiency, use at the preparation spice solution lack the science data support, cause spice solution to add cigarette and aspirate the laggard problem that spices percentage lower, perfume addition efficiency lower of main flow flue gas grain in mutually of going into, a kind of solvent for perfuming cigarette that can improve perfume addition efficiency is provided.The present invention is that the spices with required interpolation evenly mixes with this solvent, is mixed with spice solution, adds in the cigarette shreds, reaches the purpose that improves the spices additive effect.
The objective of the invention is to realize by following technical measures: the solvent for perfuming cigarette that can improve perfume addition efficiency of the present invention comprises the raw material composition of following percent by volume: glycerine 5-50%, propane diols 5-50%, glyceryl triacetate 10-80%, ethanol 10-80%.
With the solvent of solvent of the present invention as tobacco aromatics using, be mixed with spice solution and add in the cigarette shreds, can reach the purpose that improves the spices additive effect.
Perfuming mode of the present invention, method of testing are as follows: 1. earlier cigarette is propped up and be placed on temperature (18-26) ℃ equably, under the environmental condition of relative humidity (50-70) % balance 48-72 hour, select quality (800-1000) mg, resistance to suction (110-130) mmH 2The cigarette of O props up to testing cigarette and props up.2. then the perfume material of required interpolation is mixed with the potpourri solution that each monomer mass concentration is 0.1-1.5% with solvent, be injected in the pipe tobacco of reference cigarette with automatic injection perfuming instrument, injection volume is 5-20 μ L, during the injection, the injection room rotary speed is: 1-5rps, injection speed are 1-5mm/s.3. after injection finished, the perfuming cigarette placed temperature (18-26) ℃ with cigarette case sealing, under the environmental condition of relative humidity (50-70) %, places 1-6 week.4. press YC/T29-1996 standard suction perfuming cigarette with JJZ-20 linear pattern automatic smoking machine, collect the cigarette mainstream flue gas granule phase substance with filter disc.Gleanings is carried out carrying out quantitative analysis after the pre-treatment, measure the rate of transform of spices in the main flume granule phase substance.
The invention has the beneficial effects as follows: use this solvent can effectively improve the rate of transform of outer perfuming in the cigarette mainstream flue gas granule phase substance, because propane diols, glycerine, the viscosity of glyceryl triacetate, density and boiling point are all than the ethanol height, can strengthen solvent when making solvent holding of spices stayed and transmittability mixing with ethanol, when making solvent with ethanol, the percentage that makes the lower spices of boiling point enter main flume grain phase compares obvious raising, the higher spices of boiling point enters the percentage specific energy of main flume grain in mutually and remains on higher level, thereby improves the whole perfuming efficient of spice solution.And can not bring peculiar smell, can not change the fragrance style of cigarette, utilize made solvent of the present invention and spices to mix, being mixed with spice solution has good effect in perfuming cigarette.Technology simultaneously of the present invention is made simple, and cost is low, and the usual vehicle that can be used as the outer perfuming of cigarette uses.
Description of drawings
Accompanying drawing is used for the process chart of perfuming cigarette with the perfuming solvent for cigarette of the present invention.
The specific embodiment
The present invention is described further below in conjunction with embodiment, but does not limit the present invention.
Embodiment 1
At first cigarette is propped up and be placed on temperature (22 ± 2) ℃ equably, balance is 48 hours under the environmental condition of relative humidity (60 ± 5) %, selects quality (920 ± 10) mg, resistance to suction (115 ± 5) mmH 2The cigarette of O props up to testing cigarette and props up.
Accurately measure glycerine 1.0ml then and pour in the 20ml beaker, add propane diols 1.5ml, glyceryl triacetate 1.5ml and the ethanol 6.0ml of accurately measuring in beaker, the back that stirs is standby.
With methyl isovalerate, ethyl isovalerate, propyl isovalerate, butyl iso valerate, iso-amyl iso-valeriate, n-hexyl isovalerate, ethyl butyrate, ethyl hexanoate, cognac oil, ethyl caprilate, ethyl pelargonate, ethyl caprate; Butyl acetate, isoamyl acetate, hexyl acetate, heptyl acetate, octyl acetate, nonyl acetate, decyl acetate; The potpourri mother liquor about 4% is standby respectively to be mixed with mass concentration.
Really take by weighing spices mother liquor 0.5g, be mixed with two kinds of spice solutions with 5.0ml ethanol and made solvent respectively, potpourri solution is injected the pipe tobacco that perfuming instrument (Switzerland Burghart company) injects the sample cigarette automatically with the CIJECTOR type, injection volume is 15 μ L, during the injection, the injection room rotary speed is: 2.0rps, injection speed are 1.0mm/s.After injection finished, the perfuming cigarette placed temperature (22 ± 2) ℃ with cigarette case sealing, under the environmental condition of relative humidity (60 ± 5) %, places for 1 week.Press YC/T29-1996 standard suction cigarette with JJZ-20 linear pattern automatic smoking machine then, collect the cigarette mainstream flue gas granule phase substance with filter disc.Quantitative analysis will be carried out after the gleanings pre-treatment, measure the rate of transform of spices in the main flume granule phase substance, find with the made solvent of the present invention and 19 kinds of ester perfumes make spice solution to perfuming cigarette after, main flow grain phase transfer rate has on average improved 11.21% when making solvent than ethanol, has improved perfuming efficient.
Embodiment 2
At first earlier cigarette is propped up and be placed on temperature (22 ± 2) ℃ equably, balance is 48 hours under the environmental condition of relative humidity (60 ± 5) %, selects quality (910 ± 20) mg, resistance to suction (115 ± 5) mmH 2The cigarette of O props up to testing cigarette and props up.
Accurately measure glycerine 3.5ml then and pour in the 20ml beaker, add propane diols 0.5ml, glyceryl triacetate 4.0ml and the ethanol 2.0ml of accurately measuring in beaker, the back that stirs is standby.
With amylalcohol, anti--the 2-hexen-1-ol, hexanol, enanthol, octanol, nonyl alcohol, decyl alcohol are mixed with mass concentration the potpourri mother liquor about 5% are standby respectively.
Accurately take by weighing spices mother liquor 0.5g, be mixed with two kinds of spice solutions with 2.0ml ethanol and made solvent respectively, potpourri solution is injected the pipe tobacco that perfuming instrument (Switzerland Burghart company) injects the sample cigarette automatically with the CIJECTOR type, injection volume is 5 μ L, during the injection, the injection room rotary speed is: 3.0rps, injection speed are 4.0mm/s.After injection finished, the perfuming cigarette placed temperature (22 ± 2) ℃ with cigarette case sealing, under the environmental condition of relative humidity (60 ± 5) %, places for 2 weeks.Press YC/T29-1996 standard suction cigarette with JJZ-20 linear pattern automatic smoking machine then, collect the cigarette mainstream flue gas granule phase substance with filter disc.Quantitative analysis will be carried out after the gleanings pre-treatment, measure the rate of transform of spices in the main flume granule phase substance, find with the made solvent of the present invention and 8 kinds of alcohols spices make spice solution to perfuming cigarette after, main flow grain phase transfer rate has on average improved 10.06% when making solvent than ethanol, has improved perfuming efficient.
Embodiment 3
At first cigarette is propped up and be placed on temperature (22 ± 2) ℃ equably, balance is 48 hours under the environmental condition of relative humidity (60 ± 5) %, selects quality (920 ± 20) mg, resistance to suction (115 ± 5) mmH 2The cigarette of O props up to testing cigarette and props up.
Accurately measure glycerine 0.5ml then and pour in the 20ml beaker, add propane diols 3.5ml, glyceryl triacetate 5.0ml and the ethanol 1.0ml of accurately measuring in beaker, the back that stirs is standby.
With cyclopentanone, enanthaldehyde, octanal, aldehyde C-9, capraldehyde, 2-heptanone, methyln-hexyl ketone, methyl n-heptyl ketone, 2-decanone, 2-undecyl ketone, 2,4-dimethyl acetophenone, acetylacetone,2,4-pentanedione, 6-methyl-5-hepten-2-one, phenylacetaldehyde, acetophenone, isophorone, oxidation isophorone, geranyl acetone and alpha, beta-lonone are mixed with mass concentration the potpourri mother liquor about 4% are standby respectively.
Accurately take by weighing spices mother liquor 0.5g, be mixed with two kinds of spice solutions with 2.5ml ethanol and made solvent respectively, potpourri solution is injected the pipe tobacco that perfuming instrument (Switzerland Burghart company) injects the sample cigarette automatically with the CIJECTOR type, injection volume is 5 μ L, during the injection, the injection room rotary speed is: 1.0rps, injection speed are 2.0mm/s.After injection finished, the perfuming cigarette placed temperature (22 ± 2) ℃ with cigarette case sealing, under the environmental condition of relative humidity (60 ± 5) %, places for 3 weeks.Press YC/T29-1996 standard suction cigarette with JJZ-20 linear pattern automatic smoking machine then, collect the cigarette mainstream flue gas granule phase substance with filter disc.Quantitative analysis will be carried out after the gleanings pre-treatment, measure the rate of transform of spices in the main flume granule phase substance, find with the made solvent of the present invention and 19 kinds of aldoketones spices make spice solution to perfuming cigarette after, main flow grain phase transfer rate has on average improved 7.80% when making solvent than ethanol, has improved perfuming efficient.
Other it should be noted that: the present invention can carry out countless versions combination in the claim scope, and the respective change of what and component of each component content of solvent for example all can reach the purpose of raising perfume addition efficiency of the present invention.

Claims (2)

1. solvent for perfuming cigarette that can improve perfume addition efficiency is characterized in that: it comprises that the raw material of following percent by volume forms: glycerine 5-50%, propane diols 5-50%, glyceryl triacetate 10-80%, ethanol 10-80%.
2. the application of a solvent for perfuming cigarette as claimed in claim 1 is characterized in that: this solvent is mixed with spice solution and adds in the cigarette shreds as the solvent of tobacco aromatics using, can reach the purpose that improves perfume addition efficiency.
CN2007103000234A 2007-12-21 2007-12-21 Solvent for perfuming cigarette capable of improving perfume addition efficiency and uses thereof Active CN101194754B (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103141940A (en) * 2013-02-27 2013-06-12 湖北中烟工业有限责任公司 Entrapment agent for selectively lowering crotonaldehyde content in cigarette smoke and filter stick
CN104432500A (en) * 2014-12-25 2015-03-25 中国烟草总公司郑州烟草研究院 Composite filter stick capable of improving sensory quality of low-tar cigarette
CN104522883A (en) * 2014-12-25 2015-04-22 中国烟草总公司郑州烟草研究院 Improved cigarette with a low tar/nicotine ratio
CN104939298A (en) * 2015-05-21 2015-09-30 湖南中烟工业有限责任公司 Atomizing agent for electronic cigarette and electronic cigarette liquid
CN106590931A (en) * 2016-12-14 2017-04-26 江西中烟工业有限责任公司 Preparation method of cigarette protein-polysaccharide composite emulsion carrier system and application of carrier system in cigarettes

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4715390A (en) * 1985-11-19 1987-12-29 Philip Morris Incorporated Matrix entrapment of flavorings for smoking articles
CN1114546A (en) * 1994-10-12 1996-01-10 王国恩 Molecular sieve natural moistening agent for cigarette and preparing process thereof
GB9712815D0 (en) * 1997-06-19 1997-08-20 British American Tobacco Co Smoking article and smoking material therefor
US8887737B2 (en) * 2005-07-29 2014-11-18 Philip Morris Usa Inc. Extraction and storage of tobacco constituents

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103141940A (en) * 2013-02-27 2013-06-12 湖北中烟工业有限责任公司 Entrapment agent for selectively lowering crotonaldehyde content in cigarette smoke and filter stick
CN103141940B (en) * 2013-02-27 2014-08-27 湖北中烟工业有限责任公司 Entrapment agent for selectively lowering crotonaldehyde content in cigarette smoke and filter stick
CN104432500A (en) * 2014-12-25 2015-03-25 中国烟草总公司郑州烟草研究院 Composite filter stick capable of improving sensory quality of low-tar cigarette
CN104522883A (en) * 2014-12-25 2015-04-22 中国烟草总公司郑州烟草研究院 Improved cigarette with a low tar/nicotine ratio
CN104939298A (en) * 2015-05-21 2015-09-30 湖南中烟工业有限责任公司 Atomizing agent for electronic cigarette and electronic cigarette liquid
CN106590931A (en) * 2016-12-14 2017-04-26 江西中烟工业有限责任公司 Preparation method of cigarette protein-polysaccharide composite emulsion carrier system and application of carrier system in cigarettes

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