CN101191371A - Composite phenolic aldehyde building energy-saving heat-insulating board and its manufacturing method and application - Google Patents
Composite phenolic aldehyde building energy-saving heat-insulating board and its manufacturing method and application Download PDFInfo
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- CN101191371A CN101191371A CNA2007100099591A CN200710009959A CN101191371A CN 101191371 A CN101191371 A CN 101191371A CN A2007100099591 A CNA2007100099591 A CN A2007100099591A CN 200710009959 A CN200710009959 A CN 200710009959A CN 101191371 A CN101191371 A CN 101191371A
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Abstract
A composite phenolic aldehyde construction energy saving insulation plate and manufacturing method and application thereof relate to an insulation plate. The invention aims to provide the composite phenolic aldehyde construction energy saving insulation plate and the manufacturing method and application thereof with excellent insulation effect, convenient use and high construction efficiency. The invention comprises a phenolic aldehyde insulation layer, a bonding layer and an inorganic material composite board, wherein, the bonding layer is arranged between the phenolic aldehyde insulation layer and the inorganic material composite board; the thickness of the phenolic aldehyde insulation layer is 20-100mm, the thickness of the bonding layer is 0.1-1mm, and the thickness of the inorganic material composite board is 3-10mm. The inorganic material composite board is continuously produced for reserving; the inorganic material composite board is applied with bonding treatment agent; phenolic aldehyde resin which is prepared pro rata is frothed and solidified into shaping with the continuous production line of the composite board, and a target product can be received.
Description
Technical field
The present invention relates to a kind of warming plate, especially relate to a kind of composite phenolic aldehyde building energy-saving heat-insulating board and manufacture method thereof and application.
Background technology
Because building energy consumption is higher, energy waste seriously is a kind of very general problem, so building energy conservation is to alleviate energy scarcity contradiction, improve environmental protection condition, alleviate environment pollution, promote direct, a cheap system engineering of sustained economic development.Present employed building thermal insulation material, as foamed materials such as the high foaming of extruded sheet, polyphenyl plate, granular polystyrene, polyethylene, though in light weight, heat insulating effect still can, the following shortcoming of ubiquity: 1) inflammable, toxic smoke is greatly, heat resistance is poor; 2) water absorbing properties is poor, easily goes mouldy under the environment of humidity and causes the body of wall blackening; 3) when wall thermal insulating is constructed, poor, for example poor with the adhibit quality of the material of bonding gypsum class, cement mortar etc. with the cementitiousness of binding material, and need a large amount of bitch and crab-bolts to be fixed; 4) long construction period, construction sequence are numerous and diverse; 5) (reference: 1. the woods swallow becomes, the pre-test of rock wool External Thermal Insulation Technology for External, Chinese architecture insulation information, 2007,7:35 can't to carry out continuity one-shot forming production composite plate with inorganic material, metal, nonmetal and textile fabric class; 2. Yang Zong Kun, the big problem that should not ignore in current China building energy conservation, Chinese architecture insulation information, 2007,8:36; 3. Tian Junxian, Yang Tongxing, plate paste formula hard polyurethane foams insulation and decoration circuit board and external thermal insulation system research, Chinese architecture insulation information, 2007,10:32; 4. EPS polyphenyl board exterior wall outer thermal insulation workmanship common fault and solution, Chinese architecture insulation information, 2007,11:34; 5. Xu Shiyuan, the weak link and the counter-measure of external insulation system commonly used, Anhui building).
That phenol formaldehyde foam has is significantly fire-retardant, low toxicity, low temperature and high-temperature stability, because unique loose structure and a certain proportion of open-celled structure, make product have the waterproof and breathable function, body of wall can keep the aqueous vapor balance under various climatic environments, prevents phenomenons such as the mouldy blackening of body of wall ponding.Simultaneously this special material-structure of phenol formaldehyde foam make again it when heat preservation construction and the cementitiousness of binding material preferable, can with cement mortar and body of wall strong bond.But the phenol formaldehyde foam of being sold is applied in and has problems such as long construction period, construction sequence be numerous and diverse in the insulation on body of wall and roof equally in the market.
Summary of the invention
It is good to the purpose of this invention is to provide a kind of heat insulating effect, easy to use, the composite phenolic aldehyde building energy-saving heat-insulating board that efficiency of construction is high.But another object of the present invention provides the manufacture method of a kind of continuity one-shot forming production, composite phenolic aldehyde building energy-saving heat-insulating board that production efficiency is high.Another object of the present invention provides the using method of described composite phenolic aldehyde building energy-saving heat-insulating board.
Composite phenolic aldehyde building energy-saving heat-insulating board of the present invention is provided with phenol formaldehyde foam insulation layer, tack coat and inorganic material composite plate.Tack coat is located between phenol formaldehyde foam insulation layer and the inorganic material composite plate, and the thickness of phenol formaldehyde foam insulation layer is 20～100mm, and adhesive layer thickness is 0.1～1mm, and the thickness of inorganic material composite plate is 3～10mm.
Upper surface at the phenol formaldehyde foam insulation layer can be provided with the protection surface layer, and the thickness of protection surface layer is 0.01～0.1mm.
Upper surface at the phenol formaldehyde foam insulation layer can be provided with fish tail and waterproof layer, and fish tail and waterproof layer can adopt color steel etc. that the waterproofing materials of certain intensity is arranged, and its thickness depends on the needs.Between fish tail and waterproof layer and phenol formaldehyde foam insulation layer, can establish the reflect heat layer, the reflect heat layer visual to heat the reflection requirement and selection.
Tack coat is in order to strengthen the adhesion strength of phenol formaldehyde foam and inorganic material composite plate, the cementing agent that tack coat adopts can be selected architecture adhesion agents such as phenol aldehyde type polyurethane adhesive or polyurethane water-proof glue for use, and phenol aldehyde type polyurethane adhesive (sale of the applicant's existing procucts) is made by the rich benzylic ether resol of hydroxyl and polymethylene phenyl isocyanate and catalyst reaction.
The concrete matrix material that adopts based on heterogeneity of inorganic material composite plate, be equipped with the inorganic material composite plate that reinforcing material is composited, for example calcium silicate board, unorganic glass steel plate, gypsum plank, cement board, magnesite plate, glass magnesium plate etc., described calcium silicate board are to be SiO by main component
2The siliceous material of (as quartz powder, flyash, kieselguhr etc.), main component are the calcium silicate board that is composited after the calcareous material, reinforcing material, auxiliary agent of CaO (as lime, calcium carbide mud, cement etc.) etc. cooperates by a certain percentage.Described unorganic glass steel plate is the unorganic glass steel plate that is composited after being cooperated by a certain percentage by magnesia oxychloride cement, reinforcing material, auxiliary agent etc.Described gypsum plank is to be the main component material with the gypsum, the gypsum plank that paper muscle, fiber etc. are composited for reinforcing material.Described cement board is to be matrix material with cement, and the natural stone cotton fiber strengthens the cement board that is composited through advanced production moulding pressurization.Described magnesite plate is to be main component with the light calcined magnesia, the magnesite plate that glass etc. are composited for reinforcing material.Described glass magnesium plate (being commonly called as magnesium oxide plate) is with magnesia, magnesium chloride, and water ternary system are configured and add modifier and the magnesium gelatinous material of the stable performance of making, with the neutral and alkali glass fiber net is reinforcing material, is that filler is composited with the light material.
The manufacture method of composite phenolic aldehyde building energy-saving heat-insulating board of the present invention may further comprise the steps:
1) production inorganic material composite plate is standby continuously;
2) brushing binder-treatment agent on the inorganic material composite plate;
3) use the composite plate tinuous production with deployed in proportion phenolic resins foaming, curing molding, promptly get target product.
For strengthening combination property of the present invention, prolong life of product, in phenolic resins, add auxiliary agents such as surfactant, blowing agent, flexibilizer.Press mass ratio, phenolic resins: surfactant: blowing agent: flexibilizer=100: (1～5): (1～10): (1～15).Described surfactant is universal surfactants such as silicone oil, EL emulsifier, polysorbas20, Tween 80; Described blowing agent is the general blowing agents in market such as hydrocarbon blowing agents, 141b; Described flexibilizer is little strand auxiliary agents such as different molecular weight polyethylene glycol, polyvinyl alcohol.
When phenolic resins enters tinuous production foaming, curing molding; can on composite phenolic aldehyde building energy-saving heat-insulating board, protect surface layer by compound one deck; described protection surface layer can be metal, at least a in nonmetal etc.; the metal coating surface layer can be metal coating surface layers such as aluminium foil, aluminium-foil paper, aluminizer, and nonmetal protection surface layer can be nonmetal protection surface layers such as common paper, glass mat, grid cloth, glass grid composite felt (being glass mat and the grid a kind of product after compound).
The using method of composite phenolic aldehyde building energy-saving heat-insulating board of the present invention is as follows:
At first composite phenolic aldehyde building energy-saving heat-insulating board is cut into the male and female tongue and groove that can cooperatively interact according to required size; optionally the protection surface layer on composite phenolic aldehyde building energy-saving heat-insulating board top layer is removed then; paste assembly unit more from bottom to top on the body of wall or roof joist that scribble binding material (being commonly called as interfacial agents), form integral heat insulation metope or deck.
Described binding material can adopt adhesive mortars such as bonding adhesive or cement-bonded mortar.Described bonding adhesive adopts universal architecture adhesion agent or universal cement-bonded mortar.
Because composite phenolic aldehyde building energy-saving heat-insulating board of the present invention adopts phenol formaldehyde foam insulation layer, tack coat and inorganic material composite plate three layer construction, so heat insulating effect is good, and is easy to use, the efficiency of construction height.Owing to adopt production inorganic material composite plate at first continuously; brushing cementing agent on the inorganic material composite plate then; use the composite plate tinuous production with deployed in proportion phenolic resins foaming, the production technology of curing molding at last; therefore can adopt the batch production scale to produce continuously; saved cost of manufacture, improved production efficiency, the thermal and insulating performance of the composite insulation boards of producing is effective; easy to use, overall performance is good.The present invention simultaneously adopts equipment that composite insulation boards is cut into the male and female tongue and groove that can cooperatively interact by size; optionally the protection surface layer on top layer is removed at the construction field (site); composite insulation boards is pasted assembly unit from bottom to top on body of wall that scribbles binding material or roof joist; form integral heat insulation metope or deck; not only easy to use; the efficiency of construction height, and construction effect is good, but carry out other decorations constructions after the construction in the short time.
Description of drawings
Fig. 1 is the structural representation of the embodiment of the invention.
The specific embodiment
Referring to Fig. 1; composite phenolic aldehyde building energy-saving heat-insulating board of the present invention is provided with protection surface layer 1, phenol formaldehyde foam insulation layer 2, tack coat 3 and inorganic material composite plate 4; protection surface layer 1 is located at phenol formaldehyde foam insulation layer 2 upper surfaces, and tack coat 3 is located between phenol formaldehyde foam insulation layer 2 and the inorganic material composite plate 4.
The thickness of protection surface layer 1 is 0.01～0.1mm, looks the composite phenolic aldehyde building energy-saving heat-insulating board application system and selection; Adhesive layer thickness is 0.1～1mm; The thickness of phenol formaldehyde foam insulation layer 2 is 20～100mm, decides on customer demand; The thickness of inorganic material composite plate 4 is 3～10mm, is preferably 3mm for the thickness of exterior wall inorganic material composite plate 4; The thickness of interior wall inorganic material composite plate 4 is preferably 5～10mm; The thickness of roof inorganic material composite plate 4 is preferably 3～10mm.
During use, interfacial agents is adhesive mortars such as bonding adhesive or cement mortar, and thickness is not more than 20mm;
Following examples will the present invention is further illustrated in conjunction with the accompanying drawings.
Embodiment 1: the calcium silicate board that 3mm is thick is introduced into as the inorganic material composite plate in 80 ℃ the baking oven and carries out preheating; carry out brushing phenol aldehyde type polyurethane adhesive after the preheating; will be by a certain percentage behind the gluing (phenolic resins: surfactant: blowing agent: flexibilizer: cast thereon for the phenolic resins foaming combination material (guaranteeing that phenol formaldehyde foam thickness is 20mm) that curing compound=100: 1: 8: 5: 10) cooperates; and enter the composite insulation boards tinuous production with aluminium-foil paper and carry out foamed solidification and (annotate: must under calcium silicate board, fill up one deck plastic foil when entering the production line foamed solidification as the protection surface layer; prevent that combination material and foaming body from spilling), cut into the composite plate and the deburring packing of certain-length at last by specification requirement.This product is applied in the roof insulation, and the aluminium-foil paper of its upper surface also has reflection function, and most of sunshine is reflected back, and makes better heat preservation.
Surfactant is a silicone oil, and blowing agent is 141b, and flexibilizer is polyethylene glycol.Curing compound is selected 10% sulfuric acid for use.
Embodiment 2: the glass magnesium plate that 5mm is thick is introduced into as the inorganic material composite plate in 80 ℃ the baking oven and carries out preheating; carry out brushing phenol aldehyde type polyurethane adhesive after the preheating; will be by a certain percentage behind the gluing (phenolic resins: surfactant: blowing agent: flexibilizer: cast thereon for the phenolic resins foaming combination material (guaranteeing that phenol formaldehyde foam thickness is 40mm) that curing compound=100: 2: 1: 8: 10) cooperates; and enter the composite insulation boards tinuous production with aluminium-foil paper and carry out foamed solidification and (annotate: must under glass magnesium plate, fill up one deck plastic foil when entering the production line foamed solidification as the protection surface layer; prevent that combination material and foaming body from spilling), cut into the composite plate and the deburring packing of certain-length at last by specification requirement.This product is applied in the roof insulation, and the aluminium-foil paper of its upper surface also has reflection function, and most of sunshine is reflected back, and makes better heat preservation.
Surfactant is the EL emulsifier, and blowing agent is a hydrocarbon blowing agents, and flexibilizer is polyethylene glycol.Curing compound is selected 10% p-methyl benzenesulfonic acid for use.
Embodiment 3: the magnesite plate that 8mm is thick is introduced into as the inorganic material composite plate in 80 ℃ the baking oven and carries out preheating; carry out brushing phenol aldehyde type polyurethane adhesive after the preheating; will be by a certain percentage behind the gluing (phenolic resins: surfactant: blowing agent: flexibilizer: cast thereon for the phenolic resins foaming combination material (guaranteeing that phenol formaldehyde foam thickness is 60mm) that curing compound=100: 3: 6: 7: 12) cooperates; and enter the composite insulation boards tinuous production with aluminium-foil paper and carry out foamed solidification and (annotate: must under the magnesite plate, fill up one deck plastic foil when entering the production line foamed solidification as the protection surface layer; prevent that combination material and foaming body from spilling), cut into the composite plate and the deburring packing of certain-length at last by specification requirement.This product is applied in the roof insulation, and the aluminium-foil paper of its upper surface also has reflection function, and most of sunshine is reflected back, and makes better heat preservation.
Surfactant is a silicone oil, and blowing agent is 141b, and flexibilizer is polyvinyl alcohol.Curing compound is selected 13% phosphoric acid for use.
Embodiment 4: the unorganic glass steel plate that 6mm is thick is introduced into as the inorganic material composite plate in 80 ℃ the baking oven and carries out preheating; carry out brushing phenol aldehyde type polyurethane adhesive after the preheating; will be by a certain percentage behind the gluing (phenolic resins: surfactant: blowing agent: flexibilizer: cast thereon for the phenolic resins foaming combination material (guaranteeing that phenol formaldehyde foam thickness is 60mm) that curing compound=100: 5: 10: 10: 15) cooperates; and enter the composite insulation boards tinuous production with common paper and carry out foamed solidification and (annotate: must under the unorganic glass steel plate, fill up the last layer plastic foil when entering the production line foamed solidification as the protection surface layer; prevent that combination material and foaming body from spilling), cut into the composite plate and the deburring packing of certain-length at last by specification requirement.This product is mainly used in the gentle heat insulating inner wall of exterior wall insulating, only the common paper of upper layer need be torn off during construction and directly be attached on the foundation wall of having smeared adhesive mortar, easy construction, cementitiousness are strong, and the surface can carry out other processing according to requirement of engineering, as: tile fixing, coat etc.
Surfactant is polysorbas20 or Tween 80, and blowing agent is 141b, and flexibilizer is polyvinyl alcohol.Curing compound is selected 8% pyrovinic acid for use
Embodiment 5: the gypsum plank that 8mm is thick is introduced into as the inorganic material composite plate in 80 ℃ the baking oven and carries out preheating; carry out brushing phenol aldehyde type polyurethane adhesive after the preheating; will be by a certain percentage behind the gluing (phenolic resins: surfactant: blowing agent: flexibilizer: cast thereon for the phenolic resins foaming combination material (guaranteeing that phenol formaldehyde foam thickness is 80mm) that curing compound=100: 4: 6: 5: 8) cooperates; and enter the composite insulation boards tinuous production with common paper and carry out foamed solidification and (annotate: must under gypsum plank, fill up the last layer plastic foil when entering the production line foamed solidification as the protection surface layer; prevent that combination material and foaming body from spilling), cut into the composite plate and the deburring packing of certain-length at last by specification requirement.This product is mainly used in the gentle heat insulating inner wall of exterior wall insulating, only the common paper of upper layer need be torn off during construction and directly be attached on the foundation wall of having smeared adhesive mortar, easy construction, cementitiousness are strong, and the surface can carry out other processing according to requirement of engineering, as: tile fixing, coat etc.
Surfactant is tween polysorbas20 or Tween 80, and blowing agent is the hydrocarbon blowing agents pentamethylene, and flexibilizer is polyethylene glycol.Curing compound is selected phosphoric acid and pyrovinic acid (mass ratio 8: 2) for use
Embodiment 6: the cement board that 8mm is thick is introduced into as the inorganic material composite plate in 80 ℃ the baking oven and carries out preheating; carry out brushing phenol aldehyde type polyurethane adhesive after the preheating; will be by a certain percentage behind the gluing (phenolic resins: surfactant: blowing agent: flexibilizer: cast thereon for the phenolic resins foaming combination material (guaranteeing that phenol formaldehyde foam thickness is 100mm) that curing compound=100: 3: 9: 6: 4) cooperates; and enter the composite insulation boards tinuous production with common paper and carry out foamed solidification and (annotate: must under cement board, fill up the last layer plastic foil when entering the production line foamed solidification as the protection surface layer; prevent that combination material and foaming body from spilling), cut into the composite plate and the deburring packing of certain-length at last by specification requirement.This product is mainly used in the gentle heat insulating inner wall of exterior wall insulating, only the common paper of upper layer need be torn off during construction and directly be attached on the foundation wall of having smeared adhesive mortar, easy construction, cementitiousness are strong, and the surface can carry out other processing according to requirement of engineering, as: tile fixing, coat etc.
Surfactant is a silicone oil, and blowing agent is the hydrocarbon blowing agents pentamethylene, and flexibilizer is polyvinyl alcohol.Curing compound is selected phosphoric acid and p-methyl benzenesulfonic acid (mass ratio is 5: 3) for use
Claims (10)
1. composite phenolic aldehyde building energy-saving heat-insulating board is characterized in that being provided with phenol formaldehyde foam insulation layer, tack coat and inorganic material composite plate.Tack coat is located between phenol formaldehyde foam insulation layer and the inorganic material composite plate, and the thickness of phenol formaldehyde foam insulation layer is 20～100mm, and adhesive layer thickness is 0.1～1mm, and the thickness of inorganic material composite plate is 3～10mm.
2. composite phenolic aldehyde building energy-saving heat-insulating board as claimed in claim 1 is characterized in that being provided with the protection surface layer at the upper surface of phenol formaldehyde foam insulation layer, and the thickness of protection surface layer is 0.01～0.1mm.
3. composite phenolic aldehyde building energy-saving heat-insulating board as claimed in claim 1 is characterized in that being provided with fish tail and waterproof layer at the upper surface of phenol formaldehyde foam insulation layer, establishes the reflect heat layer between fish tail and waterproof layer and phenol formaldehyde foam insulation layer.
4. composite phenolic aldehyde building energy-saving heat-insulating board as claimed in claim 1 is characterized in that the inorganic material composite plate is calcium silicate board, unorganic glass steel plate, gypsum plank, cement board, magnesite plate or glass magnesium plate.
5. the manufacture method of composite phenolic aldehyde building energy-saving heat-insulating board as claimed in claim 1 is characterized in that may further comprise the steps:
1) production inorganic material composite plate is standby continuously;
2) brushing binder-treatment agent on the inorganic material composite plate;
3) use the composite plate tinuous production with deployed in proportion phenolic resins foaming, curing molding, promptly get target product.
6. the manufacture method of composite phenolic aldehyde building energy-saving heat-insulating board as claimed in claim 5, it is characterized in that in phenolic resins, adding surfactant, blowing agent, flexibilizer, press mass ratio, phenolic resins: surfactant: blowing agent: flexibilizer=100: 1～5: 1～10: 1～15.
7. the manufacture method of composite phenolic aldehyde building energy-saving heat-insulating board as claimed in claim 6 is characterized in that described surfactant is silicone oil, EL emulsifier, polysorbas20 or Tween 80.
8. the manufacture method of composite phenolic aldehyde building energy-saving heat-insulating board as claimed in claim 6 is characterized in that described blowing agent is hydrocarbon blowing agents or 141b; Described flexibilizer is the little strand auxiliary agent of different molecular weight polyethylene glycol or polyvinyl alcohol.
9. the manufacture method of composite phenolic aldehyde building energy-saving heat-insulating board as claimed in claim 5; it is characterized in that entering tinuous production foaming, curing molding simultaneously at phenolic resins; compound one deck protection surface layer on composite phenolic aldehyde building energy-saving heat-insulating board; the protection surface layer is metal, at least a in nonmetal; the metal coating surface layer is aluminium foil, aluminium-foil paper, aluminizer metal coating surface layer, and nonmetal protection surface layer is common paper, glass mat, grid cloth, the nonmetal protection surface layer of glass grid composite felt.
10. the using method of composite phenolic aldehyde building energy-saving heat-insulating board as claimed in claim 1; it is characterized in that: at first composite phenolic aldehyde building energy-saving heat-insulating board is cut into the male and female tongue and groove that can cooperatively interact according to required size; optionally the protection surface layer on composite phenolic aldehyde building energy-saving heat-insulating board top layer is removed then; paste assembly unit more from bottom to top on body of wall that scribbles binding material or roof joist; form integral heat insulation metope or deck; described binding material adopts bonding adhesive or cement-bonded mortar, and described bonding adhesive adopts universal architecture adhesion agent or universal cement-bonded mortar.
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| CN200710009959A CN101191371B (en) | 2007-12-07 | 2007-12-07 | Composite phenolic aldehyde building energy-saving heat-insulating board and its manufacturing method |
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| CN200710009959A CN101191371B (en) | 2007-12-07 | 2007-12-07 | Composite phenolic aldehyde building energy-saving heat-insulating board and its manufacturing method |
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| CN101191371B CN101191371B (en) | 2010-05-19 |
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| CN101871250A (en) * | 2010-06-25 | 2010-10-27 | 苏州浩海高分子材料研究所有限公司 | Fiber phenolic finished thermal-insulating decorative board |
| CN101871251A (en) * | 2010-06-29 | 2010-10-27 | 苏州浩海高分子材料研究所有限公司 | Ultra-light safe phenol-formaldehyde composite finished product heat-insulating decorative board |
| CN101943308A (en) * | 2009-07-06 | 2011-01-12 | 王广武 | Heat insulation board with fire protection layer |
| CN101988306A (en) * | 2010-09-16 | 2011-03-23 | 汪路 | Novel three-dimensional sandwich flame-retardant composite heat-retaining board |
| CN102003048A (en) * | 2010-09-16 | 2011-04-06 | 汪路 | Composite three-dimensional sandwich flame-retardant heat insulating decorative board |
| CN102877561A (en) * | 2012-10-23 | 2013-01-16 | 昌吉康蔓化工建材有限公司 | Fireproof phenolic foam plate for outer heat-insulation system of exterior wall and process for manufacturing fireproof phenolic foam plate |
| CN103485426A (en) * | 2012-06-12 | 2014-01-01 | 湖南省中政建材有限公司 | Composite type PF (Phenol Formaldehyde) building heat insulation board and manufacturing method thereof |
| CN105479842A (en) * | 2015-11-24 | 2016-04-13 | 安庆市大成防腐保温材料有限责任公司 | Composite silicate thermal insulation plate and production method thereof |
| CN106013479A (en) * | 2015-03-15 | 2016-10-12 | 黑龙江志鹏东辉外墙保温防火装饰材料有限公司 | Fireproof heat retaining panel with aluminum profile and injection molded antiflaming heat-conducting-heat-insulation component |
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| CN101943308A (en) * | 2009-07-06 | 2011-01-12 | 王广武 | Heat insulation board with fire protection layer |
| CN101871250A (en) * | 2010-06-25 | 2010-10-27 | 苏州浩海高分子材料研究所有限公司 | Fiber phenolic finished thermal-insulating decorative board |
| CN101871251A (en) * | 2010-06-29 | 2010-10-27 | 苏州浩海高分子材料研究所有限公司 | Ultra-light safe phenol-formaldehyde composite finished product heat-insulating decorative board |
| CN101988306A (en) * | 2010-09-16 | 2011-03-23 | 汪路 | Novel three-dimensional sandwich flame-retardant composite heat-retaining board |
| CN102003048A (en) * | 2010-09-16 | 2011-04-06 | 汪路 | Composite three-dimensional sandwich flame-retardant heat insulating decorative board |
| CN101988306B (en) * | 2010-09-16 | 2015-12-09 | 汪路 | A kind of Novel three-dimensional sandwich flame-retardant composite heat-retaining board |
| CN103485426B (en) * | 2012-06-12 | 2015-08-26 | 湖南省中政建材有限公司 | Composite phenolic aldehyde building heat preservation sheet material and manufacture method thereof |
| CN103485426A (en) * | 2012-06-12 | 2014-01-01 | 湖南省中政建材有限公司 | Composite type PF (Phenol Formaldehyde) building heat insulation board and manufacturing method thereof |
| CN102877561B (en) * | 2012-10-23 | 2015-03-18 | 昌吉康蔓化工建材有限公司 | Fireproof phenolic foam plate for outer heat-insulation system of exterior wall and process for manufacturing fireproof phenolic foam plate |
| CN102877561A (en) * | 2012-10-23 | 2013-01-16 | 昌吉康蔓化工建材有限公司 | Fireproof phenolic foam plate for outer heat-insulation system of exterior wall and process for manufacturing fireproof phenolic foam plate |
| CN106013479A (en) * | 2015-03-15 | 2016-10-12 | 黑龙江志鹏东辉外墙保温防火装饰材料有限公司 | Fireproof heat retaining panel with aluminum profile and injection molded antiflaming heat-conducting-heat-insulation component |
| CN106013479B (en) * | 2015-03-15 | 2019-12-06 | 哈尔滨鹏嵘科技发展有限公司 | Fireproof heat-insulation board with aluminum profile and injection-molded flame-retardant heat-conducting and heat-insulating component |
| CN105479842A (en) * | 2015-11-24 | 2016-04-13 | 安庆市大成防腐保温材料有限责任公司 | Composite silicate thermal insulation plate and production method thereof |
| CN106626544A (en) * | 2016-09-20 | 2017-05-10 | 江苏京沪重工有限公司 | Manufacturing process for non-developable skin decorative board |
| CN106626544B (en) * | 2016-09-20 | 2018-09-04 | 江苏京沪重工有限公司 | A kind of manufacturing process that can not open up leather upholstery plate |
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| CN111302758A (en) * | 2020-03-19 | 2020-06-19 | 江苏朗悦新材料科技有限公司 | Novel reinforced and toughened MGO substrate, preparation method and composite board with substrate |
| CN111302758B (en) * | 2020-03-19 | 2022-02-25 | 江苏朗悦新材料科技有限公司 | Novel reinforced and toughened MGO substrate, preparation method and composite board with substrate |
| CN113024223A (en) * | 2021-04-01 | 2021-06-25 | 漳州市贝丘工艺品有限公司 | Ultrathin flexible cement decorative plate and preparation method thereof |
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| CN101191371B (en) | 2010-05-19 |
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