CN101187256A - Ceramic plate for building and incombustible decorative panel - Google Patents

Ceramic plate for building and incombustible decorative panel Download PDF

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Publication number
CN101187256A
CN101187256A CNA2007101875195A CN200710187519A CN101187256A CN 101187256 A CN101187256 A CN 101187256A CN A2007101875195 A CNA2007101875195 A CN A2007101875195A CN 200710187519 A CN200710187519 A CN 200710187519A CN 101187256 A CN101187256 A CN 101187256A
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China
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porcelain plate
magnesium
layer
decoration panel
mentioned
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CNA2007101875195A
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Chinese (zh)
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CN101187256B (en
Inventor
姜吉镐
金光敏
孙范玖
榆在民
李容圭
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Lg化学株式会社
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Priority to KR1020060115929 priority
Priority to KR10-2006-0115929 priority
Application filed by Lg化学株式会社 filed Critical Lg化学株式会社
Publication of CN101187256A publication Critical patent/CN101187256A/en
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Publication of CN101187256B publication Critical patent/CN101187256B/en

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Abstract

The invention relates a vitrolite for architecture and a flame resistant decorative panel. The vitrolite includes: an inorganic substance based on magnesium and the sandwich layer of light debris; surface layer formed on the one side or two side of the sandwich layer. The decorative panel includes: a base plate; wood grain decorative wood pasted on the base plate by a flame resistant adhesive layer; a transparent UV curing resin layer. The vitrolite of the invention keeps and improves the advantages of the thermal insulation, sound insulation and water resistance of existing plates based on magnesium and has good dimension stability, excellent lightweight effect and Scene cutting. Otherwise, the decorative panel of the invention is beautiful and can release anion which has the same state as nature so as to provide a suitable environment.

Description

Porcelain plate for building and incombustible decorative panel

Technical field

The present invention relates to porcelain plate for building (Ceramic board) and incombustible decorative panel (Incombustible ornament wood panel), relate in particular to a kind ofly, and use the noninflammability bond layer on substrates such as above-mentioned porcelain plate, to paste the decoration panel that graining wood forms than prior art light weight and have excellent on-site cutting and non-flame properties porcelain plate for building more.

Background technology

The porcelain plates such as gypsum plank that are used in built-in plate for building are kept structure making tabular gypsum two sides adhesive paper usually, thereby guarantee shear strength.This sheet material is widely used in interior material for building because of having excellent thermal insulation and noninflammability.To run into its binding site of water lax and cause the structure breakage but this gypsum plank has one, or its intensity is low can't use shortcoming such as nail.

In order to improve the problems referred to above, Korea S's publication discloses a kind of calcareous raw material such as limestone that adds for 2004-99709 number in siliceous raw materials such as quartz powder or kieselguhr, and with the coagulating agent based on magnesium stir make it carry out chemical bond after, be formed for improving the glass layer of shear strength and the structural lumber made at its front-back.In addition, Korea S's publication discloses the constructional materials forming method that a kind of use is made of magnesium oxide powder and vegetalitas or mineral powder for 2003-2960 number.Though above-mentioned prior art has been improved water resistance or intensity to a certain extent, the excessive construction of sheet material weight is inconvenient, and on-site cutting is relatively poor.

Japan Patent discloses and discloses that a kind of will to comprise magnesian hydrability oxidation inorganic matter be main composition for 2001-279860 number, stir after adding tackifier, to carrying out thermoforming rapidly, keep the light noninflammable sheet material of the swelling state that contains bubble after the cooling at the cooperation raw material that contains the pasty state that expansion forms under the state of a large amount of bubbles.But, in the above-mentioned technology, be difficult to bubble is dispersed in the entire product, and its intensity is also not ideal enough.

Though water resistance compared by existing porcelain plates such as above-mentioned structural lumber based on magnesium and gypsum plank or intensity has improved, weight is big and on-site cutting is relatively poor, and size changing rate is bigger.

In addition, interior of building is finally handled by wall coverings such as wallpaper or wallboard materials usually, and this wall covering generally uses to paste on above-mentioned gypsum plank thinly slices the graining wood that forms with log.But, the wall covering of this existing use graining wood, it is big and application property and on-site cutting are poor to have weight, and heat resistance is not ideal enough, shortcomings such as the fragility that seems when running into fire very.

Summary of the invention

The present invention is intended to solve above-mentioned the problems of the prior art, and its purpose is to provide a kind of lightweight and has excellent intensity, on-site cutting and non-flame properties porcelain plate.Another object of the present invention is to provide a kind of decoration panel that comprises the noninflammability bond layer.

Porcelain plate among the present invention is characterized in that comprising, and contains inanimate matter and the sandwich layer of lightweight fragment and the surface course that is formed on the one or both sides of above-mentioned sandwich layer based on magnesium.

Following the present invention's porcelain plate is elaborated.

The inanimate matter based on magnesium in the sandwich layer of the porcelain plate that is contained in the present invention is not limited especially, preferably use magnesia, magnesium chloride or said mixture, more preferably use the mixture of magnesia or magnesia and magnesium chloride.Said mixture preferably mixes the magnesium chloride of 50 to 150 weight portions with respect to the magnesia of 100 weight portions, but is not limited thereto.

The sandwich layer of the present invention's porcelain plate,, not only can prevent intensity reduction intensity but also can have light-weighted effect by adding the lightweight fragment of appropriate amount based on also comprising lightweight fragment (Chip) the inanimate matter of magnesium except above-mentioned.Though the content to above-mentioned lightweight fragment is not particularly limited, to 60vol%, preferably comprise 1 to 10 weight % with the whole relatively sandwich layer of weight ratio with volume ratio preferred 20.When the content of above-mentioned lightweight fragment is lower than 20vol% or 1 weight %, can not get required lightweight effect, and when surpassing 60vol% or 10 weight %, might when mix, shape deform or can not get desirable strength.

In the present invention, above-mentioned lightweight fragment preferably uses through the silane coupler surface-treated, can improve adhesion between the glass fiber-reinforced inanimate matter layer of inanimate matter in itself and the sandwich layer or sandwich layer outside by carrying out surfacing.Above-mentioned silane coupler can use this area normally used, preferably uses for example amine silane coupler or acrylic compounds silane coupler.

As above-mentioned amine silane coupler, preferred gamma-aminopropyl-triethoxy-silane, γ-(2-amino-ethyl)-aminopropyl trimethoxysilane, γ-(2-amino-ethyl)-aminopropyl methyl dimethoxysilane or the γ-anilino-propyl trimethoxy silicane etc. of using, and as the acrylic compounds silane coupler, preferred use gamma-methyl allyl acyloxypropyl trimethoxysilane, gamma-methyl allyl acyloxypropyl dimethoxy silane, but be not limited thereto.

Surface treatment method with above-mentioned silane coupler can use this area usual way, rubbing method or dipping (dip) coating etc. of for example spraying, but be not limited thereto.

Shape to above-mentioned lightweight fragment is not particularly limited, and can have rectangle or unformed different shape.The size of above-mentioned lightweight fragment as long as its thickness less than sandwich layer also is not particularly limited, but is considered preferred 0.1 to 3mm scope from porcelain plate intensity angle.As above-mentioned size is during less than 0.1mm, might can not get the lightweight effect, and when surpassing 3mm, made timber intensity might reduce.

Above-mentioned lightweight fragment all can use so long as usually used in this field, is preferably the more than one foaming fragment of selecting from polystyrene, polypropylene, polyethylene and aerogel particle.Above-mentioned foaming fragment is not particularly limited, but preferably has 15 to 70 times frothing percentage, and preferably have 0.015 to 0.05g/cm 3Density.Surpass 70 times or density less than 0.015g/cm as above-mentioned frothing percentage 3The time, the timber intensity of being finished might descend, in addition, and when above-mentioned frothing percentage surpasses 0.05g/cm less than 15 times or density 3The time, might can not get enough lightweight effects.

Within the scope that does not influence required effect, can suitably add by wood powder, expanded perlite, blowing agent and solidify selected more than one additive among the group that conditioning agent constitutes the sandwich layer of the present invention's porcelain plate.

In the present invention's the porcelain plate, its surface course is preferably through glass fiber-reinforced inanimate matter layer.Above-mentioned can be by glass fiber material being immersed in the inanimate matter based on magnesium through glass fiber-reinforced inanimate matter layer, or will and make based on the inanimate matter coating above-mentioned material of magnesium.

So long as normally used in this area, all can be used as above-mentioned glass fabric and use, preferably use fabric, adhesive-bonded fabric or its combination of glass fiber.Above-mentioned glass fiber preferably has every square metre 20 to 200g quality (20-200g/m 2).When the quality of glass fiber surpasses every square metre of 200g, might cause the lightweight effect insufficient.

The inanimate matter based on magnesium through glass fiber-reinforced inanimate matter layer that is used in the present invention is not particularly limited, preferably uses magnesia, magnesium chloride or its mixture, more preferably the mixture of magnesia or itself and magnesium chloride.In addition, from improving the angle of intensity, can add selected more than one additive among the group who constitutes by wood powder, expanded perlite, blowing agent and curing conditioning agent to inanimate matter based on magnesium.

Porcelain plate thickness to the present invention does not limit, and can suitably select according to institute's suitable application area, is preferably 3 to 15mm scope.In addition, can increase the tissue layer that constitutes by fabric at the one or both sides of the present invention's porcelain plate, by increase that the above-mentioned fabrics layer can improve and other built-in material between binding ability or intensity, also can improve decorative effect.

Below, with reference to Fig. 1 the structure of the present invention's porcelain plate is elaborated.The present invention's porcelain plate comprises and containing based on the inanimate matter of magnesium and the sandwich layer 120 of lightweight fragment 121, and the one or both sides of above-mentioned sandwich layer 120 are formed with surface course 110,130.Porcelain plate for building with the present invention of said structure can use the normally used method in this area to make, and its manufacture method is lifted one for example down.Fig. 2 is an embodiment of the manufacturing process of the present invention's porcelain plate for building.

To add water based on the inorganic powder of magnesium and lightweight fragment or independent inorganic powder and stir, make sandwich layer raw material 203 and surface course raw material 202 based on magnesium.The then above-mentioned surface course raw material 202 of coating on plate-shaped frame 301, laminated glass cloth 201 and use backer roll 311 pressurizations and form surface course thereon.Afterwards, stacked or coating sandwich layer raw material 203 and use backer roll 312 pressurizations and form sandwich layer on surface course, stack gradually again or coated glass cloth 204, surface course raw material 202 after, with backer roll 313 pressurizations, thereby make porcelain plate of the present invention.

In the manufacture method of the present invention's porcelain plate, before above-mentioned surface course forms operation and/or after, also can increase the stacked operation of tissue layer, also can be used as the glass fiber-reinforced inorganic plate that above-mentioned surface course uses in advance on glass fabric dipping or coating to form based on the inanimate matter of magnesium.Can use series-operation or a kind of in the operation (batch process) in batch in the manufacturing process of the present invention's porcelain plate.

The manufacturing process of the porcelain plate of the invention described above also can increase the curing in water operation, preventing causing be full of cracks because of excessive maintenance, and discharges the harmful components of sneaking in the manufacture process.

In addition, the present invention relates to a kind of decoration panel, it is characterized in that comprising: substrate; Be bonded in graining wood on the above-mentioned plate by the noninflammability bond layer; And be formed on transparent, UV curing resin layer on the above-mentioned graining wood.

Following with reference to Fig. 3, the present invention's decoration panel is elaborated.

Substrate 400 for the present invention's decoration panel is not particularly limited so long as have non-flame properties inanimate matter sheet material, for example can use porcelain plates such as magnesium plate, concrete plate and gypsum plank, wherein preferably uses the present invention's porcelain plate.Use the present invention's porcelain plate can further improve the noninflammability of decoration panel.

The bond layer 401 of the present invention's decoration panel is a non-automatic incombustible material, can reach by making bonding agent contain fire retardant.This area is normally used all to can be used for above-mentioned bonding agent, preferably uses polyurethanes, acrylic compounds or epoxies bonding agent.The fire retardant that is included in the bonding agent also is not particularly limited, preferred use among the group who constitutes by aluminium hydroxide, magnesium hydroxide, aluminium alloys and silica selected more than one.

Content to above-mentioned fire retardant is not particularly limited, and with respect to the bonding agent of 100 weight portions, preferably uses in the scope of 20 to 50 weight portions.When above-mentioned flame retardant amount is lower than 20 weight portions, noninflammability might be reduced, and when surpassing 50 weight portions, bonding force might be reduced.

Can use the wooden thin plate of the normally used band natural wood grain in this area to the graining wood layer 402 of the decoration panel that is used for the present invention, this thin plate can be made by log is thinly sliced.In addition, though, be preferably 0.2 to 0.5mm to the thickness indefinite of above-mentioned graining wood layer.

In the present invention's decoration panel, transparent, UV cured layer 403 can use the normally used material in this area.The common noninflammability of material that constitutes above-mentioned cured layer 403 is relatively poor, so preferably reduce its thickness as far as possible, for example is below the 0.3mm, but is not limited thereto.Lower thickness limit to above-mentioned cured layer 403 is not particularly limited, and is preferably more than the 0.01mm.

Bond layer 401 in the present invention's decoration panel, curing resin layer 403 or bond layer 401 and curing resin layer 403 also can add the anion h substance, with the anion of release with the identical level of natural forest.

Above-mentioned anion h substance is not particularly limited,, preferably uses selected more than one materials among the group who constitutes by tourmaline, Kweiyang stone and rare-earth like mine as long as have negative ion releasing function.Content to above-mentioned anion h substance is not particularly limited, with respect to the bond layer of 100 weight portions, curing resin layer or above-mentioned both, preferably add 10 to 30 weight portions.

The present invention's decoration panel can be made by the normally used method in this area, and its manufacture method is exemplified below.

Promptly, elder generation's prepared substrate, graining wood, noninflammability bonding agent and ultraviolet curable resin composition, after using noninflammability bonding agent adhesive base plate and graining wood, coating ultraviolet curable resin composition and make its curing and make on bonding above-mentioned graining wood.

As mentioned above, the present invention's porcelain plate keeps or has improved outstanding thermal insulation, sound insulation and the dimensional stability of existing sheet material based on magnesium, also has outstanding lightweight effect, and the cutting when cutting with cutter at the scene is also very outstanding.In addition, the present invention's decoration panel has kept the surface characteristic of natural line wood, has outstanding decorative effect, and noninflammability is outstanding, also can have the anion burst size identical with native state.

Description of drawings

Fig. 1 is an embodiment schematic diagram of the present invention's porcelain plate for building;

Fig. 2 is an embodiment schematic diagram of the manufacturing process of the present invention's porcelain plate for building;

Fig. 3 is the sectional view of the present invention's incombustible decorative panel.

The specific embodiment

Below, the present invention is described in detail for embodiment by the present invention and comparative example, but scope of the present invention is not limited to described embodiment.

Embodiment 1

Surface course forms the manufacturing with raw material

The magnesia of 10Kg, the magnesium chloride of 10Kg and the water of 4Kg are evenly mixed, produce the inanimate matter mixture based on magnesium that surface course forms usefulness, the 10Kg magnesia at this moment and the volume of mixture of 10Kg magnesium chloride are 18L.

Sandwich layer forms the manufacturing with raw material

The density of adding 250g in the above-mentioned surface course of 6Kg forms with raw material is 0.03g/cm 3, diameter is 0.01 to 3mm unformed expanded polystyrene (EPS) fragment (expanded particle), evenly mixed sandwich layer forms use raw material, at this moment the volume of the expanded polystyrene (EPS) fragment of 250g is 4.5L.

The manufacturing of porcelain plate

On plastic bottom board, with the raw material of the coating of 3mm thickness, stacked above-mentioned surface course formation usefulness, stacked thereon 50g/m 2The glass fiber adhesive-bonded fabric, use the backer roll pressurization and form surface course.Then, behind the raw material with the coating of 8mm thickness, stacked sandwich layer formation usefulness on the above-mentioned surface course, use the backer roll pressurization and form sandwich layer.Stacked 50g/m on above-mentioned sandwich layer 2The glass fiber adhesive-bonded fabric, form the raw material of usefulness with 1mm thickness coating, laminate surface layer thereon after, use backer roll to form the even curface layer, thereby make the porcelain plate that thickness is 9mm.

At 0 ℃, the above-mentioned porcelain plate of maintenance after 24 hours, 50 ℃ of dryings three days, maintenance three days in atmosphere again.The above-mentioned porcelain plate that makes is cut into the size of 450cm * 450cm, has measured its physical characteristic.

Embodiment 2

Form with in the raw material at the prepared surface course of the embodiment 1 of 6Kg, add 50g expanded perlite, 250g use amine silane to carry out the surface-treated expanded polypropylene and density is 0.02g/cm 3, diameter is 0.01 to 3mm unformed expanded polystyrene (EPS) fragment, make the raw material that sandwich layer forms usefulness through evenly mixing, and appended in glass fiber adhesive-bonded fabric inboard glass fabric stacked in order to improve intensity, in addition, the method identical with the foregoing description 1 makes porcelain plate.

Embodiment 3

The manufacturing of adhesive composite

Main composition at 1Kg is in the bonding agent of water soluble polyurethane resin, adds the aluminium hydroxide of 300g as fire retardant, uses vacuum mixer evenly to mix and makes the adhesive composite of 1.2Kg.

The manufacturing of decoration panel

Use scraping strip coating machine to be 1.0g/m as 4mm, every square metre of quality at commercially available thickness 2The magnesium plate on the coating above-mentioned bonding agent after, with thickness is the graining wood use cold-press method stickup of 0.2mm, in the above, use rolling method to be coated with the ultraviolet curable resin composition of main composition, make decoration panel through curing as polyurethane resin with the thickness of 0.2mm.

Embodiment 4

Except on adhesive composite, to add as the anion h substance outside the tourmaline of 200g, the method identical with the foregoing description 3 makes decoration panel.

Embodiment 5

Except the porcelain plate that uses embodiment 1 replaces the magnesium plate, made decoration panel with the method identical with the foregoing description 3.

Embodiment 6

Except the porcelain plate with embodiment 2 replaces the magnesium plate, made decoration panel with the method identical with the foregoing description 3.

Embodiment 7

Except the porcelain plate that uses embodiment 1 replaces the magnesium plate, made decoration panel with the method identical with the foregoing description 4.

Embodiment 8

Except the porcelain plate that uses embodiment 2 replaces the magnesium plate, made decoration panel with the method identical with the foregoing description 4.

Comparative example 1

Except the thickness with the ultraviolet curing layer is made as the 0.5mm, made decoration panel with the method identical with the foregoing description 3.

Comparative example 2

Except in bonding agent, not using the fire retardant, made decoration panel with the method identical with the foregoing description 3.

To the foregoing description 1 to 8 of being obtained, comparative example 1,2 and the commercially available magnesium oxide plate and the physical characteristic of gypsum plank, make with the following method and measure.

1. to the holding power of screw

According to the method for testing of KS F 2214 defineds, the holding power for screw of embodiment 1,2 and commercially available sheet material is measured.

2. bending strength

According to the method for testing of KS F 2263 defineds, the bending strength of embodiment 1,2 and commercially available sheet material is measured.

3. density

According to the method for testing of KS F 2518 defineds, embodiment 1,2 and commercially available panel density are measured.

4. dimensional stability

According to the method for KS M 3802 defineds, the dimensional stability of embodiment 1,2 and commercially available sheet material is measured.

5. noninflammability

According to the method for testing of KS F 2271 defineds, the noninflammability of embodiment 1 to 8, comparative example 1,2 and commercially available sheet material is measured.

6. ocular estimate

According to following standard the outward appearance of the sheet material of embodiment 3 to 8, comparative example 1,2 is estimated.

Zero: can observe with the naked eye the clearly apparent natural wood grain of sheet material.

*: because of reasons such as surface coatings, the natural wood grain of sheet material outward appearance seems unnatural during perusal.

7. the test of anion burst size

Use the anion sensing equipment, the anion burst size of embodiment 3 to 8 and comparative example 1,2 is carried out surface measurements.

Each physical characteristic of said determination is shown in table 1 and table 2.

[table 1]

Embodiment 1 Embodiment 2 The magnesium plate Gypsum plank Thickness (mm) ????9 ????9 ????9 ????9.5 Holding power (Kgf/cm) to screw ????38 ????39 ????39 ????6 Density (g/m 3) ????0.78 ????0.80 ????1.15 ????0.9 Bending strength (Kgf/mm 2) ????0.9 ????1.6 ????1.2 ????0.57 Bending strength (Kgf/mm after the immersion 2) ????0.7 ????1.5 ????0.9 ????0.08 Dimensional stability (%) ????0.25 ????0.25 ????0.55 ????- Noninflammability ????1 ????1 ????1 ????2 On-site cutting Good Good Bad Good Surface texture Good Good Bad ????-

[table 2]

Noninflammability Ocular estimate The anion burst size is (individual/cm 3) Embodiment 3 Do not fire 2 grades ????○ ????5 Embodiment 4 Do not fire 2 grades ????○ ????1,000 Comparative example 1 Do not fire 3 grades ????○ ????4 Comparative example 2 Do not fire below 3 grades ????○ ????4

Can find out that from above-mentioned table 1 the present invention's porcelain plate is under the prerequisite of intensity and water resistance keeping or improving the advantage that has the magnesium plate now, can bring into play the lightweight effect more than 30%.Be specially, when the present invention's porcelain plate and gypsum plank were compared, it obviously was better than the latter to the holding power of screw and the bending strength before and after the immersion.When comparing with the magnesium plate, about 32.174% (embodiment 1) in light weight and 30.435% (embodiment 2), and noninflammability, bending strength and the physical characteristics such as holding power of screw are equated or be better than the latter, and have excellent on-site cutting and surperficial texture.

In addition, embodiment 3 and 4 decoration panel have more excellent noninflammability than the comparative example 1 that does not add fire retardant.Can find out that when using the porcelain plate of embodiment 1 and 2 on embodiment 3 and 4, noninflammability further improves, the negative ion amount that embodiment 4 is discharged is comparative example 1 and 2 250 times.

Claims (22)

1. porcelain plate is characterized in that comprising:
Contain based on the inanimate matter of magnesium and the sandwich layer of lightweight fragment;
Be formed on the surface course on the one or both sides of above-mentioned sandwich layer.
2. porcelain plate according to claim 1 is characterized in that described inanimate matter based on magnesium is magnesia, magnesium chloride or their mixture.
3. porcelain plate according to claim 1 is characterized in that described lightweight fragment contains 20 to 60vol% with respect to sandwich layer.
4. porcelain plate according to claim 1 is characterized in that, by silane coupler described lightweight fragment is carried out surfacing.
5. porcelain plate according to claim 1 is characterized in that, the size of described lightweight fragment is 0.1 to 3mm.
6. porcelain plate according to claim 1 is characterized in that, more than one the foaming fragment of described lightweight fragment for selecting from polystyrene, polypropylene, polyethylene and aerogel particle.
7. as porcelain plate as described in the claim 6, it is characterized in that described foaming fragment has 15 to 70 times frothing percentage and 0.015 to 0.05g/cm 3Density.
8. porcelain plate according to claim 1 is characterized in that described surface course is through glass fiber-reinforced inanimate matter layer.
9. as porcelain plate as described in the claim 8, it is characterized in that, described through glass fiber-reinforced inanimate matter layer by impregnated in inanimate matter at glass fabric based on magnesium, or coating forms based on the inanimate matter of magnesium on above-mentioned glass fabric.
10. as porcelain plate as described in the claim 9, it is characterized in that of fabric, adhesive-bonded fabric or their combination of described glass fabric for making by glass fiber.
11., it is characterized in that every square metre of quality of described glass fabric is 20 to 200g/m as porcelain plate as described in the claim 9 2
12., it is characterized in that described inanimate matter based on magnesium is magnesia, magnesium chloride or its mixture as porcelain plate as described in the claim 9.
13. a decoration panel is characterized in that, comprising:
Substrate;
Stick on graining wood on the aforesaid substrate by the noninflammability bond layer;
Be formed on the transparent, UV curing resin layer on the above-mentioned graining wood.
14., it is characterized in that described substrate is each described porcelain plate in the claim 1 to 12 as decoration panel as described in the claim 13.
15., it is characterized in that described bond layer forms by contain fire retardant in polyurethanes, acrylic compounds or epoxies bonding agent as decoration panel as described in the claim 13.
16., it is characterized in that described fire retardant is selected more than one materials from the group that aluminium hydroxide, magnesium hydroxide, aluminium alloys and silica constitute as decoration panel as described in the claim 15.
17., it is characterized in that described fire retardant contains 20 to 50 weight portions with respect to the bonding agent of 100 weight portions as decoration panel as described in the claim 15.
18., it is characterized in that described graining wood is the plank of band natural wood grain as decoration panel as described in the claim 13.
19., it is characterized in that the thickness of described curing resin layer is below the 0.3mm as decoration panel as described in the claim 13.
20. as decoration panel as described in the claim 13, it is characterized in that, in bond layer, curing resin layer or bond layer and curing resin layer, add the anion h substance.
21., it is characterized in that described anion h substance is more than one materials in tourmaline, Kweiyang stone and the rare-earth like mine as decoration panel as described in the claim 20.
22. as decoration panel as described in the claim 20, it is characterized in that, add the described anion h substance of 10 to 30 weight portions.
CN2007101875195A 2006-11-22 2007-11-21 Ceramic plate for building CN101187256B (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
KR1020060115929A KR101056699B1 (en) 2006-11-22 2006-11-22 Lightweight ceramic board for construction
KR1020060115929 2006-11-22
KR10-2006-0115929 2006-11-22

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