CN101182174B - Modified vitreous hollow micro-beads heat-insulating fireproof mortar - Google Patents

Modified vitreous hollow micro-beads heat-insulating fireproof mortar Download PDF

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Publication number
CN101182174B
CN101182174B CN2007100537793A CN200710053779A CN101182174B CN 101182174 B CN101182174 B CN 101182174B CN 2007100537793 A CN2007100537793 A CN 2007100537793A CN 200710053779 A CN200710053779 A CN 200710053779A CN 101182174 B CN101182174 B CN 101182174B
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CN
China
Prior art keywords
portions
performance
mortar
product
heat
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN2007100537793A
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Chinese (zh)
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CN101182174A (en
Inventor
邬性仁
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WUHAN BIHU ENERGY SAVING NEW MATERIAL CO Ltd
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WUHAN BIHU ENERGY SAVING NEW MATERIAL CO Ltd
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Priority to CN2007100537793A priority Critical patent/CN101182174B/en
Publication of CN101182174A publication Critical patent/CN101182174A/en
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Publication of CN101182174B publication Critical patent/CN101182174B/en
Expired - Fee Related legal-status Critical Current
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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/0004Compounds chosen for the nature of their cations
    • C04B2103/0017Refractory metal compounds
    • C04B2103/0019Ti
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/28Fire resistance, i.e. materials resistant to accidental fires or high temperatures

Abstract

The invention relates to a modified vitrified hollow micro-pearl insulation fireproof mortar, which consists of the mixed components with the following weight portions of 450-500 portions of ordinary Portland cement, 450-500 portions of vitrified micro-pearl, 13.5-15.5 portions of emulsion powder, 3.5-4.0 portions of polypropylene staple, 3.5-3.8 portions of hydroxypropyl methylcellulose, 3.5-4.0portions of water-soluble titanate coupling agent and 10 portions of calcium formate. The product of the invention overcomes the phenomenon of expanded perlite of large water absorption, easy pulverization, large volume shrinkage in slurry stirring, laser easy made low strength, hollow bulge, split, etc. At the same time, the product of the invention makes up for the defects of polystyrene particle organic materials of inflammable performance, poor fireproof performance, generated harmful gas at high temperature, low anti-aging and weatherability performances, large anti-elasticity in the construction, bitten easiness by insects, etc. the product of the invention has the advantages of good insulation performance, good cohesiveness and bleeding resistance, perfect anti-aging performance, high performance-price ratio, twenty five years of weatherability, A grade of fireproof combustion resistance, bulge-free, split-free, high compressive strength, etc.

Description

Modified vitreous hollow beads heat-insulating fireproof mortar
Technical field
The present invention relates to a kind of heat-insulating fireproof mortar, particularly a kind of modified vitreous hollow beads heat-insulating fireproof mortar.
Background technology
Application number 200510115103.3 is introduced a kind of glass micro bead heat insulating fire proof grout, and with the aglite of glass bead as dry-mixed mortar, premixing forms single-component inorganic dry powder thermal insulation mortar in dry powder additive, and site operation adds water and stirs and can use; Described glass bead shared volume ratio in mortar is 50%~95%; The accumulation unit weight of described glass bead is 60~100 kilograms/cubic metre; The granularity of described glass bead is that scope is 0.5~1.5mm; The thermal conductivity of described glass bead is 0.032~0.045w/m.k; The refractoriness of described glass bead is 1000~1200 ℃; The kervit microbead insulated sand slurry of this invention has insulation, heat insulation, fire prevention and workability; but during this patent application; that adopt is industry standard JG158-2004; carry out technical feature requirement among the GB/T20473-2006 " building heat-insulating mortar " by national standard; former industry standard technical feature is lower than existing national standard; again the ultimate compression strength index because of regulation among the GB/T20473-2006 " building heat-insulating mortar " quite low 〉=0.4MPa; in actual use; the prescription ultimate compression strength of this application is low, careless slightlyly just quality accident may occur.Must adjust prescription, strengthen its ultimate compression strength.
Application number 200510134947.2 is introduced a kind of thermal insulation mortar, especially a kind of with glass bead as ultralight matter aggregate, the Superlight vitrification micropearl morttar that is composited by gelling material, redispersable latex powder, Mierocrystalline cellulose, fiber, starch ethers etc.Because of it is super light heat-insulation mortar, Yin Wendu or temperature and drying shrinkage produce wall body slit jointly easily, and the influence of thermal stresses also can make it produce wall body slit.
Summary of the invention
The present invention is in order to overcome defective and the problem that above-mentioned prior art exists; a kind of modified vitreous hollow beads heat-insulating fireproof mortar is provided; in the thermal insulation mortar that common glass bead, cement, rubber powder and auxiliary components are formed; add coupling agent again; make the mechanical property of thermal insulation mortar that improvement be arranged greatly, prepared ultimate compression strength and reached the above heat-insulating fireproof mortar of 1000KPa.
Technical scheme of the present invention is:
A kind of modified vitreous hollow beads heat-insulating fireproof mortar is mixed by following component, each component by weight,
Ordinary portland cement 450-500 part, glass bead 450-500 part, latex powder 13.5-15.5 part, polypropene staple 3.5-4.0 part, Vltra tears 3.5-3.8 part, water-soluble titanate coupling agent 3.5-4.0 part, 10 parts of calcium formiates.
Thinking with reference to the glass reinforced plastic modification, we also add the coupling agent of some amount in thermal insulation mortar, after test of many times, selected the kind and the add-on of coupling agent, make the mechanical property of thermal insulation mortar that improvement be arranged greatly, especially ultimate compression strength can be brought up to more than the 1MPa.
Modified vitreous hollow beads heat-insulating fireproof mortar preparation method takes multistage pre-mixing dry-mixed mortar technology, controls multiple material mixture ratio exactly, guarantees material quality compound and that all mix.
Modified vitreous hollow beads heat-insulating fireproof mortar preparation method; by above-mentioned prescription; at first ordinary portland cement, polypropene staple are dropped into stirrer; after the fly cutter operation; dropping into latex powder, Vltra tears, water-soluble titanate coupling agent, calcium formiate again mixes; drop into glass bead then and mix stirring 2-3 minute, throw in feed bin, put in storage by the metering pack by transfer roller.
Glass bead is the pearl glassiness mineral substance that the extraordinary high-temperature technology of a kind of process produces; it is a kind of high temperature resistant slight adiabatic inorganic materials; its unit weight is light, thermal conductivity is little, have fire prevention, insulation, premium properties such as heat insulation, and the thermal conductivity of its material self is 0.03W/ (mk).The glass bead Chemical Composition is as shown in table 1, and the glass bead physicals is as shown in table 2.
Table 1 glass bead Chemical Composition
SiO 2 TiO 2 Ai 2O 3 Fe 2O 3 FeO MnO
72.00 0.09 12.31 0.54 0.80 0.06
MgO CaO K 2O Na 2O P 2O 5 Loss on ignition
0.14 1.00 4.67 3.29 0.04 4.94
Table 2 glass bead physicals
The performance title Unit Material index
Granularity Mm 0.1-2.0
Unit weight kg/m 3 80-100
Thermal conductivity W/(M·K) 0.032-0.045
Its floatability ≥98
Surface vitreous rate ≥95
Water-intake rate (vacuum filtration method mensuration) 20-50
The volume of the tube pressure 1MPa pressure rate of reporting lost property to the authorities 38-46
Refractoriness 1280-1360
Use temperature Below 1000 ℃
Product of the present invention is main aggregate with glass bead; and and corresponding inorganic materials be polymerized " modified vitreous hollow beads heat-insulating fireproof mortar; substitute traditional common perlite and the granular polystyrene light skeletal as the thermal-insulating type dry-mixed mortar on-the-spotly added the water stirring by 1: 1 and can use.Product of the present invention can directly be put on the dried shape body of wall, remedied with common perlite and polyphenyl and made many deficiencies in the light skeletal tradition thermal insulation mortar, it is big to have overcome the pearlstone water-absorbent, easily efflorescence, volumetric shrinkage is big in slurry stirs, and easily causes phenomenons such as the low and hollowing cracking of product later strength.Remedied again simultaneously that a polyphenyl material organic materials is inflammable, fire resistance is poor, high temperature produces obnoxious flavour, anti-aging and weathering resistance is low, and bounce-back property is big and be subject to the worm ant and bite and defective such as sting in the construction.Product of the present invention has that excellent heat insulation performance, cohesiveness and bleeding resistance are good, ageing resistance is good, cost performance is high, weathering resistance 25 years, fire prevention flame retardancy A level, not hollowing, do not ftracture, characteristics such as intensity height, application property are good, not bitten by the worm ant stings, non-volatility obnoxious flavour.The performance of the modified vitreous hollow beads heat-insulating fireproof mortar of the present invention is as shown in table 3.
The performance of the modified vitreous hollow beads heat-insulating fireproof mortar of table 3 the present invention
Sequence number The performance title Unit Product performance
1 Dry density kg/m 3 301-400
2 Slurry density kg/m 3 ≤800
3 Thermal conductivity W/(M·K) ≤0.070-0.085
4 Shearing resistance KPa ≥50
5 Hot-pressing strength KPa ≥0.40
6 The alkalescence shrinking percentage ≤0.30
7 Coefficient of softening ≥0.50
8 Ultimate compression strength KPa ≥1000
Product adaptation of the present invention is incubated plastering engineering inside and outside the enclosure walls such as Steel Concrete, gas concrete, building block, vitrified brick and no-firing brick of multilayer and Highrise buildings, and fireproof heat insulating engineering such as vault, garage, stair, corridor, fire passage, also be applicable to the insulation improvement project of all kinds of old buildings.
Embodiment
Table 4. is example 1~8 raw materials used and consumption unit: Kg of the present invention
Example 1 Example 2 Example 3 Example 4 Example 5 Example 6 Example 7 Example 8
Ordinary portland cement 450 500 480 460 470 490 500 450
Glass bead 500 450 470 490 480 460 500 450
Latex powder 13.5 15、5 14.0 15.0 14.5 13.8 14.8 15.2
Polypropene staple 4.0 3.5 3.8 3.6 3.7 3.9 3.5 4.0
Vltra tears 3.5 4.0 3.7 3.8 3.9 3.6 4.0 3.8
Example 1 Example 2 Example 3 Example 4 Example 5 Example 6 Example 7 Example 8
Water-soluble titanate coupling agent 3.5 4.0 3.5 3.6 3.5 3.7 3.7 4.0
Calcium formiate 10 10 10 10 10 10 10 10
Used water-soluble titanate coupling agent is that the model of buying from Nanjing longitude and latitude chemical industry company limited is JW-311W in the embodiment of the invention.
Modified vitreous hollow beads heat-insulating fireproof mortar preparation method; get each component by the described amount of table 4; at first ordinary portland cement, polypropene staple are dropped into stirrer; after the fly cutter operation; dropping into latex powder, Vltra tears, water-soluble titanate coupling agent, calcium formiate again mixes; drop into glass bead then and mix stirring 2-3 minute, throw in feed bin, put in storage by the metering pack by transfer roller.

Claims (1)

1. a modified vitreous hollow beads heat-insulating fireproof mortar is mixed by following component, each component by weight,
Ordinary portland cement 450-500 part, glass bead 450-500 part, latex powder 13.5-15.5 part, polypropene staple 3.5-4.0 part, Vltra tears 3.5-3.8 part, water-soluble titanate coupling agent 3.5-4.0 part, 10 parts of calcium formiates.
CN2007100537793A 2007-11-07 2007-11-07 Modified vitreous hollow micro-beads heat-insulating fireproof mortar Expired - Fee Related CN101182174B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2007100537793A CN101182174B (en) 2007-11-07 2007-11-07 Modified vitreous hollow micro-beads heat-insulating fireproof mortar

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
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CN101182174A CN101182174A (en) 2008-05-21
CN101182174B true CN101182174B (en) 2010-06-23

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Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101725208B (en) * 2009-11-27 2011-05-25 河南大学 Heat-preservation and heat-insulation crack-resisting brick made from modified vitrified micro beads
CN101781109B (en) * 2010-02-05 2012-04-25 江苏荣能集团有限公司 Light-weight dry-mixed masonry mortar
CN101805163A (en) * 2010-03-29 2010-08-18 河南省龙裕建筑节能有限公司 Non-ignitable thermal insulation material for quickly solidifying fireproof insulation board
CN102050602A (en) * 2010-08-25 2011-05-11 潍坊绿城低碳建筑科技有限公司 Anti-cracking protective mortar for fabricated machine-made light-weight interlaid energy-saving outer wall board
CN102249614B (en) * 2011-05-23 2013-01-02 上海曹杨建筑粘合剂厂 Light thermal insulation soundproof damping floor mortar
CN103102119B (en) * 2011-11-10 2015-08-26 比亚迪股份有限公司 A kind of stiffening agent and preparation method thereof
CN104909674A (en) * 2015-06-16 2015-09-16 合肥吉科新材料有限公司 Acid-alkali-resistant glazed hollow bead thermal-insulation mortar and production method thereof
CN105130284A (en) * 2015-07-03 2015-12-09 枞阳县天筑新型建筑材料有限公司 Thermal-insulation mortar with high waste utilization comprehensive performance and preparation method thereof
CN106348665A (en) * 2016-08-23 2017-01-25 柳州市国正机电物资有限责任公司 Fireproof mortar and method for preparing same
CN106565176A (en) * 2016-11-14 2017-04-19 绍兴职业技术学院 Silane coupling agent low-carbon environmental-friendly regenerable special mortar
CN109422526A (en) * 2017-08-23 2019-03-05 滁州市南谯生辉新型建材有限公司 A kind of sintered hollow block and its preparation process of high temperature resistant high tenacity
CN111848211A (en) * 2019-04-29 2020-10-30 贵州建工安顺建筑工程有限公司 Inorganic hollow vitrified micro bubble thermal insulation mortar and preparation method thereof

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Publication number Priority date Publication date Assignee Title
CN1721369A (en) * 2004-07-05 2006-01-18 张虎 Process for producing high performance concrete product with superfine hollow microsphere additive
CN1752043A (en) * 2004-09-20 2006-03-29 杨小平 Anti cracking antipercelation grout powder

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1721369A (en) * 2004-07-05 2006-01-18 张虎 Process for producing high performance concrete product with superfine hollow microsphere additive
CN1752043A (en) * 2004-09-20 2006-03-29 杨小平 Anti cracking antipercelation grout powder

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