CN101177646A - Method for deacidizing and regenerating waste used oil by using molecular distillation technology - Google Patents
Method for deacidizing and regenerating waste used oil by using molecular distillation technology Download PDFInfo
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- CN101177646A CN101177646A CNA200710031092XA CN200710031092A CN101177646A CN 101177646 A CN101177646 A CN 101177646A CN A200710031092X A CNA200710031092X A CN A200710031092XA CN 200710031092 A CN200710031092 A CN 200710031092A CN 101177646 A CN101177646 A CN 101177646A
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Abstract
The invention discloses a method for recovering and recycling waste machine oil by using a molecular distillation technique. Gasoline, diesel, machine oil or lubricants are distillated in sequence through three-class molecular distillation of the waste machine oil; the molecular distillation temperature of the first class is 50 to 90 DEG C, the pressure is minus 0.3MPa to minus 0.9MPa, and the gasoline is distillated; the molecular distillation temperature of the second class is 50 to 150 DEG C, the pressure is 200Pa to 10 Pa, and the diesel is distillated; the molecular distillation temperature of the third class is 100 to 300 DEG C, the pressure is 20Pa to 0.1 Pa, and the machine or the lubricants is distillated. Without chemical processes of acid washing, caustic washing, discoloring, precipitation and drying, etc., in the process of processing the waste machine oil, the process is simple, no sodium salt and decoloring agents are discharged after the neutralization of acid-bases without pollution, and the Gasoline, the diesel, the machine oil and the lubricants distillated with the molecular distillation method can achieve or exceed the original quality index.
Description
Technical field
The present invention relates on the oil grease separation regeneration field, particularly a kind of molecular distillation technique that utilizes separates gasoline, diesel oil, machine oil and lubricating oil in the reduction used oil of purifying.
Background technology
As shown in Figure 1, reclaiming the technology that the technology of waste used oil takes usually at present is: reclaim waste used oil → filtration → dehydration → acid, alkali cleaning → decolouring → filter residue → refiltered oil.There is following problem in this technical matters:
(1) because the source more complicated of waste used oil therefrom has gasoline, diesel oil, machine oil and lubricated wet goods, and the machine oil after the processing can not be separated gasoline, diesel oil, machine oil and lubricating oil respectively, the engine oil quality performance of recovery is uncontrollable.Handle gasoline, diesel oil, machine oil and lubricating oil that the back product can not be reduced to former quality, and be their mixture, only do decolouring and adjust potential of hydrogen, on quality, can not compare with former gasoline, diesel oil, machine oil and lubricating oil at all.
(2) treating processes is seriously polluted, and a large amount of waste sludge discharges is arranged, and causes environmental pollution.
(3) long consuming time, the power consumption of technical process.
Summary of the invention
The objective of the invention is to overcome the problem that prior art exists, a kind of method of utilizing molecular distillation technique reduction, regenerating waste used oil is provided, treating processes is pollution-free, waste used oil is reduced into gasoline, diesel oil, machine oil and the lubricating oil of former quality.
For achieving the above object, technical scheme of the present invention is:
A kind of method of utilizing molecular distillation technique reduction, regenerating waste used oil is carried out three grades of molecule distillations to waste used oil, distills out gasoline, diesel oil, machine oil or lubricating oil successively;
Described three grades of molecules distillation comprises: first step molecular distillation temperature is 50～90 ℃, pressure is-and 0.3Mpa～-0.9Mpa, isolate gasoline; Waste used oil material behind the separation gasoline enters second stage molecular distillation, and temperature is 50～150 ℃, and pressure is 200Pa～10Pa, isolates diesel oil; Material behind separation gasoline, the diesel oil enters third stage molecular distillation at last, and temperature is 100～300 ℃, and pressure is 20Pa～0.1Pa, isolates machine oil or lubricating oil.
For further realizing the object of the invention, described waste used oil carries out coarse filtration earlier and handles before carrying out three grades of molecule distillations, filters sand and mechanical particle.
Described waste used oil also comprises before carrying out the distillation of three grades of molecules waste used oil is outgased and processed by thin-film evaporator.The temperature of the described degassing and processed is preferably 30～70 ℃, and pressure is-0.3Mpa～-0.7Mpa.
Described first step molecular distillation temperature is preferably 70 ℃, and pressure is preferably-0.8Mpa.
Described second stage molecular distillation temperature is preferably 135 ℃, and pressure is preferably 25Pa.
With respect to prior art, the present invention has following advantage and beneficial effect:
The present invention is in handling the waste used oil process, not through chemical processes such as overpickling, alkali cleaning, decolouring, precipitation, dryings, flow process is simple, and there are not the sodium salt behind the acid-base neutralisation and the discharging of discoloring agent, do not pollute, the more important thing is, adopted molecular distillation to separate the gasoline, diesel oil, machine oil and the lubricating oil that distill and can meet or exceed its original quality index.
Description of drawings
Fig. 1 is the FB(flow block) that prior art reclaims waste used oil;
Fig. 2 is a FB(flow block) of the present invention;
Fig. 3 is device line figure of the present invention.
Embodiment
Shown in Fig. 2,3, the present invention is a kind of method of utilizing molecular distillation technique reduction, regenerating waste used oil, and it carries out molecular distillation to waste used oil, divides three grades and distills out gasoline, diesel oil, machine oil or lubricating oil successively.
In this method, waste used oil at first passes through coarse filtration, filter some sands and mechanical particle, waste used oil enters molecular distillation equipment subsequently, in this distillation plant, what the waste used oil sepn process first step distilled is gasoline, and what the second stage distilled is diesel oil, and what the third stage distilled is machine oil or lubricating oil.Molecular distillation apparatus can be adjusted according to the waste used oil of different sources, and the gasoline in the waste used oil of different ratios content, diesel oil, machine oil and lubricating oil are separated one by one.Concrete steps are as follows:
First, the waste used oil after coarse filtration is directly entered surge tank 1 place, be input to thin-film evaporator 2 by volume pump and outgas and dewater, 30～70 ℃ of temperature, pressure-0.3Mpa～-0.7Mpa;
Material after the degassing and the dehydration is input to first step molecular distillation post 3 through pump again, and temperature is controlled at 50～90 ℃, and pressure is-0.3Mpa～-0.9Mpa, isolate gasoline;
Material behind the separation gasoline is imported in the second stage molecular distillation post 4 again, and temperature is controlled at 50～150 ℃, and pressure is 200Pa～10Pa, and diesel oil is separated;
Material behind separation gasoline, the diesel oil is input in the third stage molecular distillation post 5 again, and temperature is controlled at 100～300 ℃, and pressure is 20Pa～0.1Pa, and machine oil or lubricating oil separation are come out;
Remaining at last impurity heavy oil is discharged.
Embodiment 1
Weighing, certain is retrieved and through the waste used oil 5000ml of coarse filtration, directly enters surge tank 1 place, is input to thin-film evaporator 2 by volume pump and outgases and dewater 50 ℃ of temperature, pressure-0.5Mpa.Subsequently, the material after the degassing is input in the first step molecular distillation post 3 through pump, gasoline is separated, and 70 ℃ of temperature, pressure-0.8Mpa, the gasoline weight of separating is 265ml.Afterwards, the material behind the separation gasoline is input in the second stage molecular distillation post 4 through pump again, diesel oil is separated, and 135 ℃ of temperature, pressure 25Pa, the diesel oil weight of separating is 380ml.At last, the material behind separation gasoline, the diesel oil passes through in the third stage molecular distillation post 5 again, and machine oil or lubricating oil separation are come out, and temperature is 210 ℃, and pressure is 0.5Pa, and the machine oil weight of separating is 4205ml.Total recovery rate 97%.
Certain is retrieved and through the waste used oil of coarse filtration, directly enters surge tank 1 place, is input to thin-film evaporator 2 by volume pump and outgases and dewater 30 ℃ of temperature, pressure-0.7Mpa.Subsequently, the material after the degassing is input in the first step molecular distillation post 3 through pump, gasoline is separated 90 ℃ of temperature, pressure-0.3Mpa.Afterwards, the material behind the separation gasoline is input in the second stage molecular distillation post 4 through pump again, diesel oil is separated 150 ℃ of temperature, pressure 200Pa.At last, the material behind separation gasoline, the diesel oil passes through in the third stage molecular distillation post 5 again, and machine oil or lubricating oil separation are come out, and temperature is 300 ℃, and pressure is 20Pa.
Certain is retrieved and through the waste used oil of coarse filtration, directly enters surge tank 1 place, is input to thin-film evaporator 2 by volume pump and outgases and dewater 70 ℃ of temperature, pressure-0.3Mpa.Subsequently, the material after the degassing is input in the first step molecular distillation post 3 through pump, gasoline is separated 50 ℃ of temperature, pressure-0.9Mpa.Afterwards, the material behind the separation gasoline is input in the second stage molecular distillation post 4 through pump again, diesel oil is separated 60 ℃ of temperature, pressure 10Pa.At last, the material behind separation gasoline, the diesel oil passes through in the third stage molecular distillation post 5 again, and machine oil or lubricating oil separation are come out, and temperature is 100 ℃, and pressure is 0.1Pa.
Claims (6)
1. a method of utilizing molecular distillation technique reduction, regenerating waste used oil is characterized in that: waste used oil is carried out three grades of molecule distillations, distill out gasoline, diesel oil, machine oil or lubricating oil successively;
Described three grades of molecules distillation comprises: first step molecular distillation temperature is 50～90 ℃, pressure is-and 0.3Mpa～-0.9Mpa, isolate gasoline; Waste used oil material behind the separation gasoline enters second stage molecular distillation, and temperature is 50～150 ℃, and pressure is 200Pa～10Pa, isolates diesel oil; Material behind separation gasoline, the diesel oil enters third stage molecular distillation at last, and temperature is 100～300 ℃, and pressure is 20Pa～0.1Pa, isolates machine oil or lubricating oil.
2. the method for utilizing molecular distillation technique reduction, regenerating waste used oil according to claim 1 is characterized in that: described waste used oil carries out coarse filtration earlier and handles before carrying out three grades of molecule distillations, filters sand and mechanical particle.
3. according to claim 1 or the 2 described methods of utilizing molecular distillation technique reduction, regenerating waste used oil, it is characterized in that: described waste used oil also comprises before carrying out three grades of molecules distillations waste used oil is outgased and processed by thin-film evaporator.
4. the method for utilizing molecular distillation technique reduction, regenerating waste used oil according to claim 3, it is characterized in that: the temperature of the described degassing and processed is 30～70 ℃, pressure is-0.3Mpa～-0.7Mpa.
5. according to claim 1 or the 2 described methods of utilizing molecular distillation technique reduction, regenerating waste used oil, it is characterized in that: described first step molecular distillation temperature is 70 ℃, and pressure is-0.8Mpa.
6. according to claim 1 or the 2 described methods of utilizing molecular distillation technique reduction, regenerating waste used oil, it is characterized in that: described second stage molecular distillation temperature is 135 ℃, and pressure is 25Pa.
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| Application Number | Priority Date | Filing Date | Title |
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| CNB200710031092XA CN100567470C (en) | 2007-10-26 | 2007-10-26 | Utilize the method for molecular distillation technique reduction, regenerating waste used oil |
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| CNB200710031092XA CN100567470C (en) | 2007-10-26 | 2007-10-26 | Utilize the method for molecular distillation technique reduction, regenerating waste used oil |
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| CN101177646A true CN101177646A (en) | 2008-05-14 |
| CN100567470C CN100567470C (en) | 2009-12-09 |
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101831348A (en) * | 2010-05-20 | 2010-09-15 | 佛山汉维机电科技有限公司 | Method for separating and recovering product oil from waste lubricating oil and device thereof |
| CN101906348A (en) * | 2010-08-18 | 2010-12-08 | 黄卫红 | Method for reducing waste engine oil into base oil |
| CN101928602A (en) * | 2010-08-30 | 2010-12-29 | 华南理工大学 | Method for separating paraffin from readymade oil |
| CN102597195A (en) * | 2009-11-09 | 2012-07-18 | 罗希特·乔希 | Method and apparatus for processing of spent lubricating oil |
| CN102719266A (en) * | 2012-07-03 | 2012-10-10 | 宁波博汇石油化工有限公司 | Heavy oil short-path distillation (molecular distillation) continuous production process |
| CN102977989A (en) * | 2012-07-25 | 2013-03-20 | 湖北爱国石化有限公司 | Waste lubricating oil recycling regeneration production process |
| CN106833736A (en) * | 2017-03-29 | 2017-06-13 | 山东铂铠环保科技有限公司 | A kind of method of waste oil regeneration base oil |
| CN107982950A (en) * | 2017-11-16 | 2018-05-04 | 广州市浩立生物科技有限公司 | A kind of useless transformer oil recovery method |
| CN108865401A (en) * | 2018-08-01 | 2018-11-23 | 中节能（连云港）清洁技术发展有限公司 | A kind of method of waste mineral oil recycled again |
| CN114768282A (en) * | 2022-04-24 | 2022-07-22 | 东营国安化工有限公司 | Pretreatment distillation device and method for continuous regeneration of waste lubricating oil |
-
2007
- 2007-10-26 CN CNB200710031092XA patent/CN100567470C/en not_active Expired - Fee Related
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102597195A (en) * | 2009-11-09 | 2012-07-18 | 罗希特·乔希 | Method and apparatus for processing of spent lubricating oil |
| CN101831348A (en) * | 2010-05-20 | 2010-09-15 | 佛山汉维机电科技有限公司 | Method for separating and recovering product oil from waste lubricating oil and device thereof |
| CN101831348B (en) * | 2010-05-20 | 2013-01-09 | 佛山汉维机电科技有限公司 | Method for separating and recovering product oil from waste lubricating oil and device thereof |
| CN101906348A (en) * | 2010-08-18 | 2010-12-08 | 黄卫红 | Method for reducing waste engine oil into base oil |
| CN101928602A (en) * | 2010-08-30 | 2010-12-29 | 华南理工大学 | Method for separating paraffin from readymade oil |
| CN101928602B (en) * | 2010-08-30 | 2013-03-20 | 华南理工大学 | Method for separating paraffin from readymade oil |
| CN102719266A (en) * | 2012-07-03 | 2012-10-10 | 宁波博汇石油化工有限公司 | Heavy oil short-path distillation (molecular distillation) continuous production process |
| CN102977989A (en) * | 2012-07-25 | 2013-03-20 | 湖北爱国石化有限公司 | Waste lubricating oil recycling regeneration production process |
| CN106833736A (en) * | 2017-03-29 | 2017-06-13 | 山东铂铠环保科技有限公司 | A kind of method of waste oil regeneration base oil |
| CN107982950A (en) * | 2017-11-16 | 2018-05-04 | 广州市浩立生物科技有限公司 | A kind of useless transformer oil recovery method |
| CN108865401A (en) * | 2018-08-01 | 2018-11-23 | 中节能（连云港）清洁技术发展有限公司 | A kind of method of waste mineral oil recycled again |
| CN114768282A (en) * | 2022-04-24 | 2022-07-22 | 东营国安化工有限公司 | Pretreatment distillation device and method for continuous regeneration of waste lubricating oil |
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| Publication number | Publication date |
|---|---|
| CN100567470C (en) | 2009-12-09 |
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Granted publication date: 20091209 Termination date: 20191026 |