CN101108391A - Method for improving metallic element of plants enriched soil by improving temperature of soil - Google Patents
Method for improving metallic element of plants enriched soil by improving temperature of soil Download PDFInfo
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- CN101108391A CN101108391A CNA2007101309900A CN200710130990A CN101108391A CN 101108391 A CN101108391 A CN 101108391A CN A2007101309900 A CNA2007101309900 A CN A2007101309900A CN 200710130990 A CN200710130990 A CN 200710130990A CN 101108391 A CN101108391 A CN 101108391A
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Abstract
The invention relates to a method for improving the enriching of soil metal elements by plant through increasing the temperature of the soil, which belongs to the technical field for plant repairing for the environmental (soil) heavy metal pollution. When the quantity of the plants growing on a heavy-metal polluted soil reaches or approaches to the highest value, firstly, metal clelant solution is poured into the soil. After 12 to 48 hours, the temperature of the soil is risen to 40 to 60 degree and keeps for 1 to 3 hours. The plants are harvested in 2 to 14 days after the heat treatment. Comparing with the normal measures, the present method can increase the metal-element-enriching capability of the above-ground part of the plants by 5 to 40 times. The method of the invention can improve metal-element-enriching efficiency of the above-ground part of the plants, and improve the service efficiency of the clelant.
Description
(1) technical field:
The present invention relates to a kind ofly, belong to environment (soil) heavy metal pollution phytoremediation technology field by improving the method that the soil moisture improves metallic element in the plant extract environment (soil).
(2) technical background:
Phytoremediation (Phytoremediation) technology is to utilize a kind of new renovation technique of phytoremediation environmental contaminants the phase at the end of the eighties in last century.The phytoremediation technology of heavy-metal contaminated soil comprises types such as plant extract, plant curing, phytovolatilization and plant filtration.For most toxic heavy metal, the major technique that can take is a plant extract.The plant extract technology can be divided into two kinds of countermeasures: depend on the plant extract that is referred to as to continue of excess accumulator plant and depend on the plant extract that is referred to as chemical induction of utilizing chelating agent to promote common plant absorbing heavy metal-polluted soil.It is to come heavy metal in the activating soil by apply chelating agent in soil that inductivity is repaired extractive technique (Chelant-assisted phytoextraction), improve the biological effectiveness of heavy metal-polluted soil, thereby promote the plant absorbing heavy metal-polluted soil to reach the purpose of reparation.Present chelation evoked recovery technique has become a new direction of phytoremediation development, and has obtained remarkable progress.Ethylenediamine tetra-acetic acid (EDTA), EDDS (EDDS) etc. are the chelating agents that is applied to the inductivity plant extract at present, but the price comparison height.How improving chelation evoked repairing efficiency, improve the metallic element in the plants enriched soil (or culture matrix), reduce chelating agent and use cost, shorten the phytoremediation time, is to need the problem that solves in the chelation evoked recovery technique.
(3) summary of the invention
Technical problem the object of the present invention is to provide a kind of method that improves plants enriched soil metal elements, improves the efficient of plant shoot extraction heavy metal in the inductivity phytoremediation process, to improve the chelation evoked recovery technique of present plant.
A kind of method that improves plants enriched soil metal elements of technical scheme is characterized in that,
When growing into, plant gathers preceding 3 to 15 days in soil or culture matrix, in the soil in plant rhizosphere district or culture matrix, add the metal-chelator below one or more: ethylenediamine tetra-acetic acid (EDTA), EDDS (EDDS), diethyl pentetic acid (DTPA), ethyleneglycol bistetraacetic acid (EGTA), EDDA (EDDHA), the sodium of CDTA (CDTA) or aminotriacetic acid (NTA) or these chelating agents, potassium salt soln, solution concentration is 1-1000mmol/L, once water around root system of plant, the metal-chelating agent concentration that finally adds soil or culture matrix is 0.1-5mmol/kg.
Adding metal-chelator or its esters after 12 to 48 hours, make soil or culture matrix temperature be elevated to the 40-60 degree by a series of annealing devices, and kept 1-3 hour.These heat treatment measures comprise: hot-water line that bury in the lower berth, ground or the electrically heated rod that inserts by the face of land or by electrically heated metallic plate (net), the pipe laying vapor operation of spraying water, or the drip irrigation appliance of irrigation hot water etc.2-14 days results plant after heat treatment.
Beneficial effect the present invention can be used for the inductivity plant extract of heavy-metal contaminated soil.This method effect is obvious, has operability.Compare with conventional measure, use this method can make plant shoot divide the accumulation ability of metal element to improve 5-40 doubly.
Result of the test shows:
(1) in using the Cu contaminated soil of EDTA, along with the rising of the soil moisture (23-38 ℃), milpa top Cu content, accumulation and root system Cu content all are significantly increased.
(2) on copper polluted soil and heavy-metal composite pollution soil, all show, used chelating agent (EDDS or EDTA) afterwards, soil was handled 3 hours by high temperature (50 ℃ or 80 ℃), can significantly improve plant shoot and divide heavy metal concentration, the descending processing of its recruitment is followed successively by: and chelating agent uses after 2 days and heat-treats＞and heat treatment＞chelating agent of carrying out immediately after chelating agent is used uses the preceding heat treatment of carrying out in 2 days.
(3) adopt and to bury pvc pipe in the lower berth, ground, and feed the hot water (50 ℃) that circulates improving the soil moisture in pvc pipe, this method can improve the chelating agent inducing plant and extract the efficient about 5 times (mung beans) of soil Cu or 10-14 doubly (corn).
(4) the copper polluted agricultural land has carried out field test in the open air, and during near maximum biomass, (concentration of treatment is 1.0mmolkg to the solution of pouring EDTA or EDDS in soil at corn
-1Soil).Chelating agent added back 2 days, by adopting electrothermal tube soil was heated, or directly watered hot water treatment.Do not use chelating agent and handle and to compare with not heating, chelating agent is improving nearly 40 times of the auxiliary copper enriching quantity that can improve milpa top down of the soil moisture; With use chelating agent not heat treated compare, chelating agent is improving about 33 times of the auxiliary efficient that can improve corn enrichment Soil Copper down of the soil moisture.
These results show by improving the soil moisture can obviously increase the extraction efficiency of plant to heavy metal, reduces the amount of application of chelating agent, reduces the chelating agent use cost and reduces the potential danger of soluble heavy metal to the underground water migration thereby reach.This method provides a kind of new technology for restoration of soil polluted by heavy metal.
(4) description of drawings
Fig. 1 variable concentrations EDTA applies back 0 day (0d) or 2 days (2d), and 50 ℃ of heat treatment is to the influence of corn seedling aerial part Pb, Cu, Zn and Cd content
Fig. 2 EDTA with carry out the influence of different Temperature Treatment (25 ℃, 50 ℃, 80 ℃) after EDDS uses to mung bean seedlings aerial part heavy metal (Pb, Cu, Zn and Cd) content
Fig. 3: embodiment 1 and example 2 heat treatment modes
Fig. 4: by foggara mode of heating (embodiment 3)
Corn and mung bean seedlings (embodiment 3) that non-heating of Fig. 5: EDTA (left figure) and EDTA heating (right figure) are handled
Corn and mung bean seedlings (embodiment 3) that non-heating of Fig. 6 EDDS (left figure) and EDDS heating (right figure) are handled
(left side: EDDS handles not heating to the test effect of Fig. 7: embodiment 4 field heat treated; In: EDDS handles and uses electrical heating; Right: EDDS handles and heats with hot water)
(5) specific embodiment
The effect of heavy metal-polluted soil is extracted in 1.50 ℃ of heat treatments of embodiment to EDTA inducing maize seedling
Materials and methods:
For trying the topsoil that soil picks up from ground, Nanjing Wei Gang one vegetable garden 0-20cm,, cross the 4cm sieve through natural air drying.To the soil people for applying Pb (2000mg kg
-1Soil), Cu (200mg kg
-1), Zn (200mg kg
-1) and Cd (2mgkg
-1) wait four heavy metal species, respectively with Pb (NO
3)
2, CuSO
4, ZnSO
4And Cd (NO
3)
24H
2The form of O solution is added.Artificial composite heavy-metal contaminated soil was placed 1 year through alternation of wetting and drying balance repeatedly.The basic physical and chemical of soil sees Table 1.
The physicochemical property of table 1 heavy-metal composite pollution soil
| Physicochemical property | Artificial contamination's soil |
| Soil pH soil particle diameter＞0.05mm (%) soil particle diameter 0.05-0.001mm (%) soil particle diameter＜0.001mm (%) soil saturation water-holding capacity (%) cation exchange capacity (CEC) (cmol (+) kg -1) organic (gkg -1) heavy metal concentration (mg kg -1soil) Cu Pb Zn Cd | 6.50 34.2 49.5 16.3 38.3 17.10 32.94 205 1941 515 2.12 |
Take by weighing artificial composite heavy-metal contaminated soil and place disposal plastic cup (8.0cm diameter * 11.0cm height, 250 gram soil/cups), add water balance and place a week.
Corn (Zea mays L. cv.Nongda No.108) seed is seeded in the plastic cup behind sterilization, seed soaking 10h.Every glass is stayed three seedlings after emerging.Keeping soil moisture content with weight method is 60% of saturation moisture content.
After planting the 8th day, the EDTA that soil is carried out three kinds of concentration handled: 1.0,3.0, and 5.0mmolkg
-1Soil is (with 50ml variable concentrations Na
2The pouring of-EDTA solution), be made as control group to add 50ml water simultaneously.Handle back 0h or 48h respectively at EDTA, plastic cup is placed 50 ℃ of thermostat water bath 3h (keeping the interior water surface of water-bath to be positioned at plastic cup soil face below 1cm).3 repetitions are established in every processing.
Except that heat-treating, corn seedling is grown under natural lighting, temperature 21-32 ℃.Add water with weight method, keeping soil moisture content is 70% of saturation moisture content.
EDTA handled back 7 days, along clip milpa top, 0.5cm place, native face top, sample through clean, oven dry, pulverizing, after disappear with acid and to boil, use the atomic absorption spectrophotometer content of beary metal.
Result of the test:
Along with the increase of EDTA concentration of treatment, the content of corn seedling aerial part Pb, Cu, Zn and Cd also obviously increases (Fig. 1).Under same concentrations EDTA handles, the heat treatment phase that carries out immediately after using with EDTA is than (0d), EDTA uses and heat-treats the content that (2d) can more effectively increase corn seedling aerial part heavy metal after 2 days, and its recruitment probably is 3 times of (5.0mmolkg
-1EDTA) to 5 times (1.0 or 3.0mmolkg
-1EDTA).
Embodiment 2. heat treatments induce mung bean seedlings to extract the effect of heavy metal-polluted soil to EDTA, EDDS
Materials and methods:
For examination soil, test with plastic cup and soil loading amount with embodiment 1.
Dicotyledon mung bean [Vigna radiat (L.) R.Wilczek var.radiata cv.VC2768A] seed is sowed behind sterilization, seed soaking 4h.Every glass is stayed four of seedlings after emerging.
After planting 14 days (chelating agent was handled preceding 2 days, was designated as :-2d), the partly plastic cup places 25 ℃, 3h in the thermostat water bath of 50 ℃ or 80 ℃ three kinds of temperature (keeping the interior water surface of water-bath to be positioned at plastic cup soil face below 1cm).After planting 16 days (be designated as: 0d), 5.0mmol L
-1Na
3-EDDS or Na
2-EDTA solution 50ml waters in native face and (makes the chelating agent concentration of treatment be 1.0mmol kg
-1Soil).The plastic cup that does not carry out the chelating agent processing adds 50ml H
2O.After planting 18 days (chelating agent was handled back 2 days, was designated as :-2d), the plastic cup that part is carried out the chelating agent processing places 25 ℃, 3h in the thermostat water bath of 50 ℃ or 80 ℃ three kinds of temperature.4 repetitions are established in every processing.
Mung bean seedlings is grown under natural lighting, temperature 19-28 ℃.Keeping soil moisture content with weight method is 70% of saturation moisture content.
Chelating agent is handled after 7 days, from cotyledonary node clip aerial part sample.Sample post processing and content of beary metal assay method such as preceding.
Result of the test:
Compared under three kinds of Temperature Treatment (25 ℃, 50 ℃, or 80 ℃), two kinds of chelating agents (EDTA and EDDS) are to the influence of mung bean seedlings aerial part content of beary metal.
When soil does not add chelating agent, compare with 25 ℃ of processing, 50 ℃ or 80 ℃ handle 3 hours to mung bean seedlings on the ground content of beary metal slightly increase but general impacts little (Fig. 2).
When soil adds 1.0mmol kg
-1EDTA compares with 25 ℃ of processing, and heat treatment (50 ℃ or 80 ℃) has obviously increased the content of aerial part Pb, Cu, Zn and Cd.For EDDS, heat treatment (50 ℃ or 80 ℃) has then obviously increased the content of aerial part Cu, Zn and Cd, and is little to the content influence of Pb.Under all temperature conditions, EDDS more can improve aerial part Cu content effectively than EDTA, and EDTA more effectively improves the concentration (Fig. 2) of aerial part Pb and Cd than EDDS.
Embodiment 3. extracts the influence of heavy metal-polluted soil to corn and mung bean by the foggara heat treated
Materials and methods:
For soil on probation is the Cu contaminated soil, picks up from soup mountain, eastern suburb, Nanjing copper polluted agricultural land, and its physicochemical property sees Table 2.The Cu contaminated soil places in the plastic tub alms bowl (18.0cm diameter * 15.0cm height), every basin 2500g soil.In dress soil, around laying PVC (polyvinyl chloride) water pipe (internal diameter 18mm, 1.5m/ basin), except that water inlet and delivery port, its residual water pipe all is embedded in the soil along the bending of basin alms bowl inwall.After having buried water pipe, soil adds one week of water balance.
The physicochemical property of table 2 copper polluted soil
| Physicochemical property | Copper polluted soil |
| Soil pH soil particle diameter＞0.05mm (%) | 6.75 34.5 |
| Soil particle diameter 0.05-0.001mm (%) soil particle diameter＜0.001mm (%) soil saturation water-holding capacity (%) cation exchange capacity (CEC) (cmol (+) kg -1) organic (gkg -1) content of beary metal (mg kg -1soil) Cu Pb Zn Cd | 48.7 16.8 39.4 19.76 38.45 899 52.4 259 0.84 |
In each basin alms bowl with time kind corn and mung bean.The every kind of plant in back that emerges stays seedling 8-12.
After planting the 10th day, 250ml EDDS or EDTA solution watered in soil surface (with 10mmol L
-1Na
3-EDDS or Na
2The pouring of-EDTA solution, making the chelating agent concentration of treatment is 1.0mmol kg
-1Soil).Part basin alms bowl waters and organizes in contrast.Every processing repeats 4 times.
After planting the 12nd day, promptly chelating agent was handled back 2 days, and PVC water pipe internal circulation pump is gone into 50 ℃ of hot water and continued 4h (water pump is positioned in the 40L thermostat water bath).After planting the 13rd day, part basin alms bowl carried out 50 ℃ of circulating hot waters once more and handles 4h.
Except that heat-treating, seedling grows under natural lighting, temperature 12-26 ℃.After planting the 17th day (being that chelating agent was handled back 5 days) is because clip mung bean and corn seedling aerial part the leaf abscission phenomena of mortality appear, in the part mung bean seedlings.Sample sampling, post processing and content of beary metal assay method are as above.
Result of the test:
Soil adds 1.0mmol kg
-1EDDS does not compare with heat-treating, and heat treatment can improve corn and mung bean about 17 times and 5 times of Cu concentration on the ground respectively.Equally, EDTA is auxiliary down, and heat treatment can improve corn and mung bean about 20 times and 6 times (table 3) of Cu concentration on the ground respectively.
Down auxiliary at chelating agent, make the plant dry matter drop to the 50-80% that normal temperature is handled though improve soil temperature, owing to aerial part Cu concentration increases significantly, thereby the total Cu accumulation of aerial part also obviously increases.Compare with the processing of normal temperature chelating agent, the soil hyperthermic treatment can improve two plant shoots and divide total 4 to 14 times of Cu accumulations (table 3).
Compare with carry out a heat treated (50 ℃) by water pipe, twice heat treated (50 ℃+50 ℃) further do not increase the accumulation (table 3) of Cu.
Table 3 is by the influence of foggara heat treated to corn and mung bean seedlings aerial part Cu content and Cu accumulation
| Chelating agent | Heat treatment | Aerial part Cu content (mgkg -1 DW) | Aerial part Cu absorbs total amount (μ g plant -1) | ||
| Corn | Mung bean | Corn | Mung bean | ||
| Ck EDDS | 25℃ 50℃ 50℃+50℃ 25℃ 50℃ | 23.8±1.1 40.5±2.9 39.6±3.2 60.8±5.2 1060±243 | 7.8±1.3 17.2±4.5 19.3±5.2 331±70.0 1770±250 | 9.67±2.50 17.2±2.5 15.3±2.8 22.1±2.8 219±39 | 1.47±0.32 2.91±0.84 3.11±0.92 45.5±5.2 199±22 |
| EDTA | 50℃+50℃ 25℃ 50℃ 50℃+50℃ | 992±214 34.7±4.6 697±186 722±247 | 1630±281 274±33.2 1660±750 1230±418 | 187±59 13.4±3.5 180±91 167±73 | 182±41 38.4±5.6 191±81 125±42 |
The field heat run of embodiment 4. open-air copper polluted soils
Materials and methods:
Copper polluted agricultural land (the total copper content of soil 701mg kg in the open air
-1Soil) maize planting, during near maximum biomass, (concentration of treatment is 1.0mmol kg to the solution of pouring EDTA or EDDS in soil at corn
-1Soil).Chelating agent added back 2 days, with two kinds of methods soil was carried out heat treated: A and directly watered hot water; The soil surface of B around milpa inserts the electrical heating metal tube, switches on 2 hours, and the soil moisture is maintained about 50 degree.Heat treated is got milpa top sample after 5 days, measure the copper content and the gross absorption on milpa top.
Result of the test:
By table 4 as seen, do not using under the chelating agent condition, compared with the control, the pouring hot water treatment does not have positive effect, handles by electrical heating and can improve milpa top copper gross accumulation amount.Use 1.0mmol k
G-1The EDDS or the EDTA of soil, not obvious to the gross accumulation amount increase of milpa top copper compared with the control, but under heating condition, can obviously increase the service efficiency of chelating agent.Can improve the about 4-6 of efficient times of chelating agent by pouring hot water, and handle the about 24-40 of efficient times that to improve chelating agent by electrical heating.
Table 4 is by electrical heating or water the influence of hot water treatment to copper in the open-air copper polluted soil of milpa top enrichment
| Handle | Milpa top copper concentration (mgkg -1 DW) | Individual plant milpa top accumulation copper amount (mg/ strain) | |
| Chelating agent | Heat treatment mode | ||
| H 2O EDDS EDTA | Do not heat and water the hot water electric treatment and do not heat and water the hot water electric treatment and do not heat and water the hot water electric treatment | 13.5±2.2 13.3±2.9 20.1±1.6 16.3±1.7 93.8±39.2 570.0±159.3 13.7±1.3 55.1±34.2 347.8±80.9 | 0.95±0.15 0.82±0.20 1.37±0.22 1.14±0.13 6.42±3.23 37.30±8.32 0.99±0.15 3.96±2.84 22.92±3.52 |
Claims (5)
1. one kind by improving the method that soil temperature improves plants enriched soil metal elements, it is characterized in that:
When growing into, plant gathers preceding 3 to 15 days in soil or culture matrix, the solution that in the soil in plant rhizosphere district or culture matrix, adds metal-chelator or metal-chelator salt, after 12 to 48 hours, make soil or culture matrix temperature be elevated to the 40-60 degree by heat treatment, and kept 2-14 days results plant after the heat treatment 1-3 hour.
2. the method for the plants enriched soil metal elements of raising according to claim 1, it is characterized in that, the heat treatment measure comprises: the hot-water line that bury in the lower berth, ground, the electrically heated rod that inserts by the face of land, by electrically heated metallic plate or net, the pipe laying vapor operation of spraying water, or irrigate the drip irrigation appliance of hot water.
3. the method for the plants enriched soil metal elements of raising according to claim 1 and 2, it is characterized in that described metal-chelator is ethylenediamine tetra-acetic acid, EDDS, diethyl pentetic acid, ethyleneglycol bistetraacetic acid, EDDA, CDTA or amino (nitrilo) triacetic acid; The metal-chelator saline solution refers to chelating agent sodium, potassium salt soln, and the adding concentration of its metal-chelator is 0.1-5mmol/kg soil or culture matrix.
4. the method for the plants enriched soil metal elements of raising according to claim 1 and 2 is characterized in that, described plant is meant common crops, vegetables and wild plant, metal patience plant or metal super enriching plant.
5. the method for the plants enriched soil metal elements of raising according to claim 3 is characterized in that, described plant is meant common crops, vegetables and wild plant, metal patience plant or metal super enriching plant.
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|---|---|---|---|
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|---|---|---|---|
| CNB2007101309900A CN100569402C (en) | 2007-09-06 | 2007-09-06 | A kind of by improving the method that soil temperature improves plants enriched soil metal elements |
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| Publication Number | Publication Date |
|---|---|
| CN101108391A true CN101108391A (en) | 2008-01-23 |
| CN100569402C CN100569402C (en) | 2009-12-16 |
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|---|---|---|---|
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102962247A (en) * | 2012-11-26 | 2013-03-13 | 中国科学院南京土壤研究所 | Physico-chemical restoration method of copper-cadmium composite contaminated soil |
| CN105860988A (en) * | 2016-06-06 | 2016-08-17 | 佛山市聚成生化技术研发有限公司 | Method for preparing degradable soil improvement chelating agent and prepared degradable soil improvement chelating agent |
| CN106085444A (en) * | 2016-06-06 | 2016-11-09 | 佛山市聚成生化技术研发有限公司 | The preparation method of a kind of soil improvement chelating agen reducing Lead In Soil content and prepared soil improvement chelating agen |
| CN109201727A (en) * | 2018-09-03 | 2019-01-15 | 杭州鸿明市政工程有限公司 | A kind of leached soil solutions, application method and equipment |
| CN111545194A (en) * | 2020-06-03 | 2020-08-18 | 中国科学院南京土壤研究所 | Carbon-based manganese composite material and preparation method and application thereof |
| CN112574751A (en) * | 2019-09-29 | 2021-03-30 | 中国石油化工股份有限公司 | Ferric-iron-containing heavy metal leaching composition, application thereof and method for repairing heavy metal soil |
-
2007
- 2007-09-06 CN CNB2007101309900A patent/CN100569402C/en not_active Expired - Fee Related
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102962247A (en) * | 2012-11-26 | 2013-03-13 | 中国科学院南京土壤研究所 | Physico-chemical restoration method of copper-cadmium composite contaminated soil |
| CN102962247B (en) * | 2012-11-26 | 2014-11-05 | 中国科学院南京土壤研究所 | Physico-chemical restoration method of copper-cadmium composite contaminated soil |
| CN105860988A (en) * | 2016-06-06 | 2016-08-17 | 佛山市聚成生化技术研发有限公司 | Method for preparing degradable soil improvement chelating agent and prepared degradable soil improvement chelating agent |
| CN106085444A (en) * | 2016-06-06 | 2016-11-09 | 佛山市聚成生化技术研发有限公司 | The preparation method of a kind of soil improvement chelating agen reducing Lead In Soil content and prepared soil improvement chelating agen |
| CN109201727A (en) * | 2018-09-03 | 2019-01-15 | 杭州鸿明市政工程有限公司 | A kind of leached soil solutions, application method and equipment |
| CN112574751A (en) * | 2019-09-29 | 2021-03-30 | 中国石油化工股份有限公司 | Ferric-iron-containing heavy metal leaching composition, application thereof and method for repairing heavy metal soil |
| CN111545194A (en) * | 2020-06-03 | 2020-08-18 | 中国科学院南京土壤研究所 | Carbon-based manganese composite material and preparation method and application thereof |
| CN111545194B (en) * | 2020-06-03 | 2021-04-27 | 中国科学院南京土壤研究所 | Carbon-based manganese composite material and preparation method and application thereof |
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|---|---|
| CN100569402C (en) | 2009-12-16 |
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