CN101100854A - Environment-friendly type soil solidifying agent - Google Patents

Environment-friendly type soil solidifying agent Download PDF

Info

Publication number
CN101100854A
CN101100854A CNA2007100123815A CN200710012381A CN101100854A CN 101100854 A CN101100854 A CN 101100854A CN A2007100123815 A CNA2007100123815 A CN A2007100123815A CN 200710012381 A CN200710012381 A CN 200710012381A CN 101100854 A CN101100854 A CN 101100854A
Authority
CN
China
Prior art keywords
calcium
soil
sodium
tons
aluminum sulfate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CNA2007100123815A
Other languages
Chinese (zh)
Inventor
杨毅男
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CNA2007100123815A priority Critical patent/CN101100854A/en
Publication of CN101100854A publication Critical patent/CN101100854A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/24Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing alkyl, ammonium or metal silicates; containing silica sols
    • C04B28/26Silicates of the alkali metals
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00017Aspects relating to the protection of the environment
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00732Uses not provided for elsewhere in C04B2111/00 for soil stabilisation
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/0075Uses not provided for elsewhere in C04B2111/00 for road construction
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/2038Resistance against physical degradation
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

Abstract

This is a compound material of contents as: one or two from fly ash, aluminum sulfate, calcium sulfate, sodium sulfate, sodium carbonate, potassium carbonate, aluminum oxide; one or two from granulated blast furnace slag, calcium carbonate, potassium hydroxide, calcium oxide, sodium silicate, silica oxide; one or two from aluminum potassium sulfate, Portland cement, carbide slag, lime, alunite, gesso; one or two surface active agent from triethanolamine, calcium lignosulphonate and sodium lignosluphonate.

Description

A kind of environment protection type soil solidifying agent
A kind of environment protection type soil solidifying agent, the curing soil effect is remarkable, and the scope of application is extensive, and the preparation method is simple and direct, compliance with environmental protection requirements.
One, technical field
Belong to city's construction work category of having stable political situation, be the fine chemical technology field.
Two, background technology
1, to inventing the understanding of " a kind of environment protection type soil solidifying agent "
When soil-solidified-agent and after containing the mixing with soil of certain moisture, a series of physical-chemical reactions promptly take place.At first, the acicular crystals of the crystallization water are rich in a large amount of formation in soil, intert to form the intensity skeleton between the soil particle hole.Secondly, the silicates hydrate makes curing system further closely knit among being filled in the intensity skeleton.At last, soil-solidified-agent and part soil particle carry out chemical reaction under the effect of exciting agent, make compacted soil have irreversible favorable durability.
The curing mechanism of soil-solidified-agent should be summarised as physical mechanics process, chemical process and three processes of physical and chemical process.The physical mechanics process is that soil-solidified-agent is when curing soil, soil is through construction technology processes such as pulverizing, screen, mix and stir and roll, and the elementary cell of the soil body is pressed close to each other under the effect of external force and agreed with mutually, thereby reduces the porosity of the soil body, increase compactness, reduce seepage of water.This process is reversible, and the intensity of the soil body can change along with the change of external condition.The physical mechanics process is that the soil-solidified-agent of any kind is necessary when curing soil, because the density of curing soil and the soil-solidified-agent uniformity in the soil body, the formation of intensity is had important function.In fact, the physical mechanics process is to solidify a kind of the simplest of the soil body and fundamental method.And chemical process is meant soil-solidified-agent in the process of curing soil, the reaction of chemical reaction that itself component takes place and some component generation in soil and the soil-solidified-agent etc.The former comprises the hydrolysis of mineral-type soil solidification agent material itself and the carbonation reaction of hydration reaction and Carbon Dioxide in Air, the polymerization of organic firming agent for soil and polycondensation reaction etc.Component in latter's soil-solidified-agent and the pozzolanic reaction between the soil particle, the complex reaction between organic polymer and soil particle surface etc.Physical and chemical process mainly is meant the adsorption process of each component in soil particle and the soil-solidified-agent, comprises physical absorption, chemisorbed and physical and chemical adsorption.Physical absorption is meant that under the effect of molecular force the elementary cell of the soil body is adsorbed on its surface with some component in the soil-solidified-agent, and its surface free energy is minimized.Chemisorbed is meant generation chemical reaction between adsorbent and the adsorbed material and generates new insoluble substance, and form chemical bond between adsorbent and adsorbed material.Physical and chemical adsorption is meant that ion-exchange absorption has taken place for some ion in the soil-solidified-agent and the ion on soil body elementary cell surface.In the physics chemical action process of the soil-solidified-agent and the soil body, the mineral-type soil-solidified-agent mainly is a physical and chemical adsorption.After the dissolving of the calcium salt in the mineral-type soil-solidified-agent and magnesium salts, the sodium ion generation exchange reaction that calcium ion and magnesium ion and soil body elementary cell are adsorbed can increase the agglomeration of soil particle.Organic firming agent for soil mainly is physical absorption and chemisorbed process, such as some group of macromolecular material and the physical absorption between the soil particle, the chemisorbed between macromolecular material and the soil particle etc.More than three kinds of processes different because of the composition of soil-solidified-agent, but these three kinds of processes are not isolated mutually, but connect each other and mutually promote.In these three kinds of processes, have only chemical process and physical and chemical process that the engineering properties such as mechanical property, anti-permeability performance, endurance quality of the soil body are improved, the physical mechanics process then is to guarantee that chemical process and physical and chemical process better play a role.
2, the selected primary raw material of a kind of environment protection type soil solidifying agent
A kind of environment protection type soil solidifying agent, it is by flyash, aluminum sulfate: Al 2(SO 4) 3, calcium sulfate: CaSO 4, sodium sulphate: Na 2SO 4, sodium carbonate: Na 2CO 2, potash: K 2CO 3, calcium carbonate: CaCO 3In a kind of or two kinds with granulated blast-furnace slag, alundum (Al: Al 2O 3, potassium hydroxide: KOH, calcium oxide: CaO, silicate of soda: Na 2O nSiO 2, silica: SiO 2In a kind of or two kinds and Potassium aluminum sulfate dodecahydrate: KAl (SO 4) 212H 2A kind of in a kind of in O or Portland clinker or carbide slag or lime or alunite or the gypsum or two kinds and surfactant triethanolamine or calcium lignosulfonate or the sodium lignin sulfonate or two kinds, form multiple best complex prescription by attribute separately, through optimizing composite refining forming.
3, the scope of application of the present invention extensively and the curing soil effect remarkable
A kind of environment protection type soil solidifying agent is the solid granular of 0.0045mm-0.5mm, and it has the attribute of curing soil.It mainly is applicable to anti-seepage of channels processing and the production of solidified earth prefabricated section; Watch out for bank slope and reinforce; Subgrade strengthening and road surface sclerosis and Soft Ground.
Three, summary of the invention
1, the purpose of invention " a kind of environment protection type soil solidifying agent "
For solving at present in construction work and municipal infrastructure construction, employed soil-solidified-agent generally is strong basicity.Because the nature influence of various factors, such as rainwash etc.This alkaline soil-solidified-agent can make the salinization of soil of periphery, and polluted surface water and underground water, has a strong impact on ecological environment.And solving its function singleness in use, anti-permeability performance and intensity are low, Gu native effect and durability are relatively poor.The invention provides a kind of environment protection type soil solidifying agent.
2, the technical solution adopted for the present invention to solve the technical problems
A kind of environment protection type soil solidifying agent of the present invention, it is by flyash, aluminum sulfate: Al 2(SO 4) 3, calcium sulfate: CaSO 4, sodium sulphate: Na 2SO 4, sodium carbonate: Na 2CO 2, potash: K 2CO 3, alundum (Al: Al 2O 3In a kind of or two kinds with granulated blast-furnace slag, calcium carbonate: CaCO 3, potassium hydroxide: KOH, calcium oxide: CaO, silicate of soda: Na 2O nSiO 2, silica: SiO 2In a kind of or two kinds and Potassium aluminum sulfate dodecahydrate: KAl (SO 4) 212H 2A kind of or two kinds of compositions in a kind of in O or Portland clinker or carbide slag or lime or alunite or the gypsum or two kinds and surfactant triethanolamine or calcium lignosulfonate or the sodium lignin sulfonate, the parts by weight of component of each component is in its technical formula:
Aluminum sulfate: Al 2(SO 4) 31~20 calcium sulfate: CaSO 40.1~10
Sodium sulphate: Na 2SO 40.1~10 sodium carbonate: Na 2CO 20.1~10
Potash: K 2CO 30.1~10 calcium carbonate: CaCO 31~50
Alundum (Al: Al 2O 30.1~10 potassium hydroxide: KOH 0.1~10
Calcium oxide: CaO 0.1~10 silicate of soda: Na 2O nSiO 20.1~10
Silica: SiO 20.1~10 clinkers: 1~85
Granulated blast-furnace slag: 1~80 flyash: 1~50
Carbide slag or lime: 1~50 Potassium aluminum sulfate dodecahydrate: KAl (SO 4) 212H 2O 0.1~10
Alunite or gypsum: 1~30 triethanolamine: 0.01~0.5
Calcium lignosulfonate: 0.01~0.5 sodium lignin sulfonate: 0.01~0.5
A kind of environment protection type soil solidifying agent of the present invention is the solid granular of 0.0045mm-0.5mm, and the technology proportioning of soil and soil-solidified-agent is a component 100: 6~15 by weight during use, is suitable for extensive mechanized construction operation.
3., the beneficial effect compared with background technology of a kind of environment protection type soil solidifying agent
A kind of environment protection type soil solidifying agent of the present invention, good environmental protection.It utilizes natural soil to be cured, and gathers materials on the spot, and reduces construction costs.Good seepage-proof property, cured layer can bear certain pressure, has certain durability, through the water logging bubble argillization does not take place.It has utilized a large amount of trade wastes, has promptly saved raw material, reduces the sandstone consumption, has solved a large amount of trade waste discharging and problem of environmental pollution again, and the protection of ecological environment is had positive role.Its consumption is few, and environment protecting is good, and its main raw material(s) is inorganic matter, and is nontoxic, harmless, pollution-free, all is safe to animal and plant, multinomial function such as have deodorant to taste, sterilizing simultaneously, purify water.It is with low cost, and raw material supply is sufficient and be easy to buying, and production technology is simple and easy to do.It mainly is applicable to anti-seepage of channels processing and the production of solidified earth prefabricated section; Watch out for bank slope and reinforce; Subgrade strengthening and roadbed or road surface sclerosis and Soft Ground are suitable for extensive mechanized construction operation.
Four, the specific embodiment
When environment protection type soil solidifying agent is the solid granular of 0.0045mm-0.5mm:
At first, according to the best of breed prescription of environment protection type soil solidifying agent, required various industrial chemicals are tested.Through check, after being defined as meeting quality specifications, each material is seated in carries out crushing and screening in the mill; Then, each material after pulverizing is seated in carries out grinding in the ball mill, make it reach the quality specifications of 0.0045mm-0.5mm solid granular; Secondly, it is placed to fully to stir in the mixer again and makes it even; Once more, the environment protection type soil solidifying agent sample of gathering finished product carries out test verification; At last, the finished product pack, the storage that are up to the standards after tested is standby, guard against damp during storage.
Embodiment one:
Produce 100 tons of environment protection type soil solidifying agents, the parts by weight of component of each component is in its technical formula:
Sodium sulphate: 1 clinker: 15
Granulated blast-furnace slag: 68 flyash: 10
Carbide slag: 5 calcium lignosulfonates: 0.5
Potassium aluminum sulfate dodecahydrate: 0.5
With ball mill Portland clinker and granulated blast-furnace slag and flyash are worn into the superfine powder of 0.045mm, after the carbide slag drying, with the sieve of 2mm.68 tons of granulated blast-furnace slags are mixed stirring with 10 tons of flyash with 5 tons of carbide slags with 15 tons of Portland clinkers; make it even; then add 1 ton of anhydrous sodium sulfate and each calcium lignosulfonate of 0.5 ton and Potassium aluminum sulfate dodecahydrate and mix stirring once more; make it even, promptly make 100 tons of environment protection type soil solidifying agents.
Embodiment two:
Produce 100 tons of environment protection type soil solidifying agents, the parts by weight of component of each component is in its technical formula:
Calcium sulfate: 1 granulated blast-furnace slag: 76
Flyash: 10 lime: 10
Alunite: 2 silica:: 0.5
Sodium lignin sulfonate: 0.5
With ball mill granulated blast-furnace slag and flyash and alunite are worn into the superfine powder of 0.045mm, with the sieve of lime with 2mm.76 tons of granulated blast-furnace slags are mixed stirring with 10 tons of flyash with 10 tons of lime; make it even; then add 1 ton of dead plaster and each sodium lignin sulfonate of 0.5 ton and silica and mix stirring once more, make it even, promptly make 100 tons of environment protection type soil solidifying agents.
Embodiment three:
Produce 100 tons of environment protection type soil solidifying agents, the parts by weight of component of each component is in its technical formula:
Aluminum sulfate: 1 calcium carbonate: 3
Granulated blast-furnace slag: 65 flyash: 15
Lime: 15.5 sodium lignin sulfonates: 0.5
With ball mill granulated blast-furnace slag and flyash are worn into the superfine powder of 0.045mm, with the sieve of lime with 2mm.65 tons of granulated blast-furnace slags are mixed stirring with 15 tons of flyash with 15.5 tons of lime; make it even; then add the sodium lignin sulfonate of 1 ton of aluminum sulfate and 3 tons of calcium carbonate and 0.5 ton and mix once more and stir, make it even, promptly make 100 tons of environment protection type soil solidifying agents.
Embodiment four:
Produce 100 tons of environment protection type soil solidifying agents, the parts by weight of component of each component is in its technical formula:
Calcium carbonate: 10 calcium sulfate: 1
Granulated blast-furnace slag: 55 flyash: 20
Carbide slag: 13 Potassium aluminum sulfate dodecahydrates: 0.5
Sodium lignin sulfonate: 0.5
With ball mill granulated blast-furnace slag and flyash are worn into the superfine powder of 0.0045mm, after the carbide slag drying, with the sieve of 2mm.55 tons of granulated blast-furnace slags are mixed stirring with 20 tons of flyash with 13 tons of carbide slags; make it even; after then adding 10 tons of calcium carbonate and 1 ton of dead plaster; add each sodium lignin sulfonate of 0.5 ton and 0.5 ton of Potassium aluminum sulfate dodecahydrate again and mix stirring once more; make it even, promptly make 100 tons of environment protection type soil solidifying agents.
Embodiment five:
Produce 100 tons of environment protection type soil solidifying agents, the parts by weight of component of each component is in its technical formula:
Granulated blast-furnace slag: 50 flyash: 35
Calcium oxide: 6 silica: 5
Potassium aluminum sulfate dodecahydrate: 0.5 alundum (Al: 3
Calcium lignosulfonate: 0.3 sodium lignin sulfonate: 0.2
Granulated blast-furnace slag and flyash are worn into the superfine powder of 0.045mm with ball mill; with granulated blast-furnace slag: 50 tons with flyash: 35 tons with calcium oxide: 6 tons with silica: 5 tons with Potassium aluminum sulfate dodecahydrate: 0.5 ton with alundum (Al: 3 tons are mixed stirring; make it even; then add each 0.5 ton sodium lignin sulfonate and calcium lignosulfonate and mix stirring once more; make it even, promptly make 100 tons of environment protection type soil solidifying agents.
Embodiment six:
Produce 100 tons of environment protection type soil solidifying agents, the parts by weight of component of each component is in its technical formula:
Sodium sulphate: 1 clinker: 15
Granulated blast-furnace slag: 68 flyash: 10
Lime: 5 calcium lignosulfonates: 0.5
Potassium aluminum sulfate dodecahydrate: 0.5
With ball mill Portland clinker and granulated blast-furnace slag and flyash are worn into the superfine powder of 0.045mm, after the lime drying, with the sieve of 2mm.68 tons of granulated blast-furnace slags are mixed stirring with 10 tons of flyash with 5 tons of lime with 15 tons of Portland clinkers; make it even; then add 1 ton of anhydrous sodium sulfate and each calcium lignosulfonate of 0.5 ton and Potassium aluminum sulfate dodecahydrate and mix stirring once more; make it even, promptly make 100 tons of environment protection type soil solidifying agents.

Claims (2)

1, a kind of environment protection type soil solidifying agent is characterized in that: it is by flyash, aluminum sulfate: Al 2(SO 4) 3, calcium sulfate: CaSO 4, sodium sulphate: Na 2SO 4, sodium carbonate: Na 2CO 2, potash: K 2CO 3, alundum (Al: Al 2O 3In a kind of or two kinds with granulated blast-furnace slag, calcium carbonate: CaCO 3, potassium hydroxide: KOH, calcium oxide: CaO, silicate of soda: Na 2O nSiO 2, silica: SiO 2In a kind of or two kinds and Potassium aluminum sulfate dodecahydrate: KAl (SO 4) 212H 2A kind of or two kinds of compositions in a kind of in O or Portland clinker or carbide slag or lime or alunite or the gypsum or two kinds and surfactant triethanolamine or calcium lignosulfonate or the sodium lignin sulfonate, the parts by weight of component of each component is in its technical formula:
Aluminum sulfate: Al 2(SO 4) 31~20 calcium sulfate: CaSO 40.1~10
Sodium sulphate: Na 2SO 40.1~10 sodium carbonate: Na 2CO 20.1~10
Potash: K 2CO 30.1~10 calcium carbonate: CaCO 31~50
Alundum (Al: Al 2O 30.1~10 potassium hydroxide: KOH 0.1~10
Calcium oxide: CaO 0.1~10 silicate of soda: Na 2O nSiO 20.1~10
Silica: SiO 20.1~10 clinkers: 1~85
Granulated blast-furnace slag: 1~80 flyash: 1~50
Carbide slag or lime: 1~50 Potassium aluminum sulfate dodecahydrate: KAl (SO 4) 212H 2O 0.1~10
Alunite or gypsum: 1~30 triethanolamine: 0.01~0.5
Calcium lignosulfonate: 0.01~0.5 sodium lignin sulfonate: 0.01~0.5.
2, a kind of environment protection type soil solidifying agent according to claim 1; it is characterized in that: it is for the solid granular of 0.0045mm-0.5mm; the technology proportioning of soil and soil-solidified-agent is a component 100: 6~15 by weight during use, is suitable for extensive mechanized construction operation.
CNA2007100123815A 2007-08-06 2007-08-06 Environment-friendly type soil solidifying agent Pending CN101100854A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CNA2007100123815A CN101100854A (en) 2007-08-06 2007-08-06 Environment-friendly type soil solidifying agent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CNA2007100123815A CN101100854A (en) 2007-08-06 2007-08-06 Environment-friendly type soil solidifying agent

Publications (1)

Publication Number Publication Date
CN101100854A true CN101100854A (en) 2008-01-09

Family

ID=39035290

Family Applications (1)

Application Number Title Priority Date Filing Date
CNA2007100123815A Pending CN101100854A (en) 2007-08-06 2007-08-06 Environment-friendly type soil solidifying agent

Country Status (1)

Country Link
CN (1) CN101100854A (en)

Cited By (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102173633A (en) * 2011-03-04 2011-09-07 攀枝花九鼎建材有限责任公司 Activator for improving reactivity of fly ash in cement
CN102344813A (en) * 2011-07-18 2012-02-08 徐辰楚 Curing agent for curing marine poor subsoil
CN102604642A (en) * 2012-02-14 2012-07-25 张宇 Soil stabilizer
CN102628246A (en) * 2012-03-19 2012-08-08 尚路 Road construction method adopting compound ion soil stabilizer and carbide slag
CN103013526A (en) * 2012-12-14 2013-04-03 华北水利水电学院 Soil solidifier and soil solidification method
CN103159391A (en) * 2011-12-08 2013-06-19 宇星科技发展(深圳)有限公司 Sludge dewatering solidification treatment method
CN103933696A (en) * 2014-03-19 2014-07-23 上海鼓华生态科技有限公司 Curing agent for curing and stabilization of poisonous and harmful solid waste
CN104045293A (en) * 2014-06-17 2014-09-17 东南大学 Soil curing agent based on desulfurized fly ash activity and preparation method and application thereof
CN104513034A (en) * 2013-09-27 2015-04-15 斯蒂芬·施泰因克勒 Binder material useful for forming concrete type material
CN105219396A (en) * 2015-09-18 2016-01-06 广西路佳道桥勘察设计有限公司 A kind of soil-solidified-agent and preparation method thereof
CN105924124A (en) * 2016-05-09 2016-09-07 佳木斯大学 Soil stabilizer for reinforcing roadbed base
CN106118674A (en) * 2016-06-27 2016-11-16 郭迎庆 A kind of preparation method of freeze proof anti-cracking type soil-solidified-agent
CN106284294A (en) * 2016-08-08 2017-01-04 上海强劲地基工程股份有限公司 A kind of weak soil strengthens curing
CN106495600A (en) * 2015-09-08 2017-03-15 江苏鼎泰工程材料有限公司 Hydraulic engineering soft fascine mattress river bottom protection shore protection, shield beach sand soil solidifying agent
CN106542794A (en) * 2016-11-10 2017-03-29 嘉善弘欣化工厂(普通合伙) A kind of construction material firming agent and its preparation technology
CN106929029A (en) * 2017-03-08 2017-07-07 原生泰科技发展(北京)有限公司 A kind of new loam wall special-purpose soil curing agent and preparation method thereof
CN106987251A (en) * 2017-02-10 2017-07-28 内蒙古君子津环境科技有限公司 The preparation method of contracting agent is rolled into a ball in a kind of inorganic moisturizing of fixing the sand
CN107384418A (en) * 2017-07-18 2017-11-24 成都新柯力化工科技有限公司 A kind of soil fixing restoration of the ecosystem agent and preparation method
CN107503256A (en) * 2017-07-12 2017-12-22 河海大学 A kind of sandy soil improves filling roadbed construction method
CN107761496A (en) * 2017-10-13 2018-03-06 北京市政建设集团有限责任公司 A kind of curing agent of the thick extra large mud widening subgrade of Powder Piles Reinforcement and preparation method thereof
CN108203269A (en) * 2017-12-30 2018-06-26 晋中市鸿亮物资再生利用有限公司 A kind of residue stabilization agent containing industrial waste carbide slag
CN110451769A (en) * 2019-08-21 2019-11-15 北京本农科技发展有限公司 A kind of method of curing agent and preparation method thereof, slurry curing
CN110591727A (en) * 2019-10-28 2019-12-20 长安大学 Loose soil curing agent and preparation method thereof
CN111778033A (en) * 2020-06-28 2020-10-16 鞍钢绿色资源科技有限公司 Curing agent for curing soil and application method
US11168028B2 (en) * 2018-11-03 2021-11-09 Cemalt LLC Additives for geopolymer cements
FR3112546A1 (en) * 2020-07-20 2022-01-21 Vinci Construction Process for the manufacture of a concrete formulated with activated slag

Cited By (37)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102173633B (en) * 2011-03-04 2012-11-21 攀枝花九鼎建材有限责任公司 Activator for improving reactivity of fly ash in cement
CN102173633A (en) * 2011-03-04 2011-09-07 攀枝花九鼎建材有限责任公司 Activator for improving reactivity of fly ash in cement
CN102344813B (en) * 2011-07-18 2014-04-02 徐辰楚 Curing agent for curing marine poor subsoil
CN102344813A (en) * 2011-07-18 2012-02-08 徐辰楚 Curing agent for curing marine poor subsoil
CN103159391A (en) * 2011-12-08 2013-06-19 宇星科技发展(深圳)有限公司 Sludge dewatering solidification treatment method
CN102604642A (en) * 2012-02-14 2012-07-25 张宇 Soil stabilizer
CN102628246A (en) * 2012-03-19 2012-08-08 尚路 Road construction method adopting compound ion soil stabilizer and carbide slag
CN103013526B (en) * 2012-12-14 2014-11-26 华北水利水电学院 Soil solidifier and soil solidification method
CN103013526A (en) * 2012-12-14 2013-04-03 华北水利水电学院 Soil solidifier and soil solidification method
US9856174B2 (en) * 2013-09-27 2018-01-02 Stephan STEINKELLER Binder based on activated ground granulated blast furnace slag useful for forming a concrete type material
CN104513034A (en) * 2013-09-27 2015-04-15 斯蒂芬·施泰因克勒 Binder material useful for forming concrete type material
US20160214899A1 (en) * 2013-09-27 2016-07-28 Stephan STEINKELLER A binder based on activated ground granulated blast furnace slag useful for forming a concrete type material
CN104513034B (en) * 2013-09-27 2018-01-16 斯蒂芬·施泰因克勒 For forming the adhesive material of concrete-type material
CN103933696A (en) * 2014-03-19 2014-07-23 上海鼓华生态科技有限公司 Curing agent for curing and stabilization of poisonous and harmful solid waste
CN104045293A (en) * 2014-06-17 2014-09-17 东南大学 Soil curing agent based on desulfurized fly ash activity and preparation method and application thereof
CN106495600A (en) * 2015-09-08 2017-03-15 江苏鼎泰工程材料有限公司 Hydraulic engineering soft fascine mattress river bottom protection shore protection, shield beach sand soil solidifying agent
CN105219396A (en) * 2015-09-18 2016-01-06 广西路佳道桥勘察设计有限公司 A kind of soil-solidified-agent and preparation method thereof
CN105924124A (en) * 2016-05-09 2016-09-07 佳木斯大学 Soil stabilizer for reinforcing roadbed base
CN106118674A (en) * 2016-06-27 2016-11-16 郭迎庆 A kind of preparation method of freeze proof anti-cracking type soil-solidified-agent
CN106284294A (en) * 2016-08-08 2017-01-04 上海强劲地基工程股份有限公司 A kind of weak soil strengthens curing
CN106542794A (en) * 2016-11-10 2017-03-29 嘉善弘欣化工厂(普通合伙) A kind of construction material firming agent and its preparation technology
CN106987251A (en) * 2017-02-10 2017-07-28 内蒙古君子津环境科技有限公司 The preparation method of contracting agent is rolled into a ball in a kind of inorganic moisturizing of fixing the sand
CN106929029A (en) * 2017-03-08 2017-07-07 原生泰科技发展(北京)有限公司 A kind of new loam wall special-purpose soil curing agent and preparation method thereof
CN106929029B (en) * 2017-03-08 2019-11-08 原生泰科技发展(北京)有限公司 A kind of novel loam wall special-purpose soil curing agent and preparation method thereof
CN107503256A (en) * 2017-07-12 2017-12-22 河海大学 A kind of sandy soil improves filling roadbed construction method
CN107384418B (en) * 2017-07-18 2020-02-14 北京埃克兰德生态环保技术有限公司 Soil fixation ecological restoration agent and preparation method thereof
CN107384418A (en) * 2017-07-18 2017-11-24 成都新柯力化工科技有限公司 A kind of soil fixing restoration of the ecosystem agent and preparation method
CN107761496A (en) * 2017-10-13 2018-03-06 北京市政建设集团有限责任公司 A kind of curing agent of the thick extra large mud widening subgrade of Powder Piles Reinforcement and preparation method thereof
CN108203269A (en) * 2017-12-30 2018-06-26 晋中市鸿亮物资再生利用有限公司 A kind of residue stabilization agent containing industrial waste carbide slag
JP2022506806A (en) * 2018-11-03 2022-01-17 セモルト エルエルシー Additives for geopolymer cement
US11168028B2 (en) * 2018-11-03 2021-11-09 Cemalt LLC Additives for geopolymer cements
JP7122468B2 (en) 2018-11-03 2022-08-19 セモルト エルエルシー Additives for Geopolymer Cement
CN110451769A (en) * 2019-08-21 2019-11-15 北京本农科技发展有限公司 A kind of method of curing agent and preparation method thereof, slurry curing
CN110591727A (en) * 2019-10-28 2019-12-20 长安大学 Loose soil curing agent and preparation method thereof
CN111778033A (en) * 2020-06-28 2020-10-16 鞍钢绿色资源科技有限公司 Curing agent for curing soil and application method
FR3112546A1 (en) * 2020-07-20 2022-01-21 Vinci Construction Process for the manufacture of a concrete formulated with activated slag
WO2022018037A1 (en) * 2020-07-20 2022-01-27 Vinci Construction Method for manufacturing a concrete formulated on the basis of activated slag

Similar Documents

Publication Publication Date Title
CN101100854A (en) Environment-friendly type soil solidifying agent
Huang et al. Use of slaked lime and Portland cement to improve the resistance of MSWI bottom ash-GBFS geopolymer concrete against carbonation
CN101250041A (en) Environment-friendly type soil curing agent
Guo et al. Development and characterization of a new multi-strength level binder system using soda residue-carbide slag as composite activator
US6334895B1 (en) System for producing manufactured materials from coal combustion ash
ES2593335T3 (en) Universal hydraulic binder based on fly ash type F
CN104876500B (en) A kind of self-compaction powder concrete and preparation method and application for ocean engineering
CN102167558B (en) Excitant for exciting activity of industrial waste residues of phosphorite ore as well as preparation method and application thereof
CN101381194A (en) Environment-friendly type sludge firming agent
An et al. Strength development and microstructure of recycled gypsum-soda residue-GGBS based geopolymer
CN108218264B (en) Single-component alkali-activated cementing material taking lime-sodium carbonate as activator
Vasugi et al. Identification of design parameters influencing manufacture and properties of cold-bonded pond ash aggregate
CN108467249A (en) A kind of soil-solidified-agent and its application method using ardealite and Desulphurization preparation
CN108675751A (en) A kind of environment-friendly type mud composite curing agent
CN102060428A (en) Silt curing agent and preparation method thereof
AU2019324581B2 (en) High strength Class C fly ash cementitious compositions with controllable setting
CN110167901A (en) Geopolymer compositions and the mortar and concrete for using it
CN107761496A (en) A kind of curing agent of the thick extra large mud widening subgrade of Powder Piles Reinforcement and preparation method thereof
Feng et al. Synthesis and characterization of cemented paste backfill: Reuse of multiple solid wastes
KR20180027888A (en) Soft ground surface mixing and soil pavement process
CN101130955A (en) Environment-friendly soil solidifying agent
CAI et al. Physical and mechanical performance of quicklime-activated GGBS stabilized Hong Kong marine sediment at high water content
KR100940811B1 (en) The ground stabilization for which foundation improved material and this were used
CN101475810A (en) Environment-friendly soil curing agent
Zhang et al. Preparation and properties of alkali and sulfate coactivated ternary cementitious matrix and its application in high-strength cold bonded lightweight aggregates

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C02 Deemed withdrawal of patent application after publication (patent law 2001)
WD01 Invention patent application deemed withdrawn after publication