CN101090637B - Improved pan coating process - Google Patents

Improved pan coating process Download PDF

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CN101090637B
CN101090637B CN 200580034826 CN200580034826A CN101090637B CN 101090637 B CN101090637 B CN 101090637B CN 200580034826 CN200580034826 CN 200580034826 CN 200580034826 A CN200580034826 A CN 200580034826A CN 101090637 B CN101090637 B CN 101090637B
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coating
polyol
method according
weight
layer
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CN 200580034826
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Chinese (zh)
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CN101090637A (en
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克努特·M·拉普
约尔格·科瓦尔奇克
贝恩德·哈斯林格
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曼海姆/奥克森富特希德楚格股份公司
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Priority to DE102004050516.0 priority
Priority to DE102004050516A priority patent/DE102004050516A1/en
Priority to US60/619,177 priority
Priority to US11/075,930 priority
Priority to US11/075,930 priority patent/US20060204614A1/en
Application filed by 曼海姆/奥克森富特希德楚格股份公司 filed Critical 曼海姆/奥克森富特希德楚格股份公司
Priority to PCT/EP2005/010982 priority patent/WO2006040144A1/en
Publication of CN101090637A publication Critical patent/CN101090637A/en
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Abstract

The present invention relates to pan-coated products produced by a process comprising the following steps: (a) applying a solution or suspension of one or more polyols to a core, (b) dusting with one or more polyols in powder form and (c) carrying out drying at 20 DEG C-80 DEG C. The amount of polyol in powder form is from 30% to 75% by weight, based on the total solids content of the polyol in the coating.

Description

改进的表面包被方法 Improved surface coating method

技术领域 FIELD

[0001] 本发明涉及改进的表面包被方法(pan coating process)和用该方法生产的包被 [0001] The present invention relates to an improved method of surface coating (pan coating process) and a process for producing the packets are

女口 Female mouth

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背景技术 Background technique

[0002] 在表面包被(pan coating)技术、或挂糖衣(panning)技术中存在多种工艺,比如硬包被(hard coating)(加或不加粉末)、软包被(soft coating)(通常加入大量粉末)、溶液包被(solution coating)(加或不加粉末)以及悬浮液包被(suspensioncoating)(加或不加粉末)。 [0002] In the surface coating (pan coating) techniques, or panning (panning) in the presence of a variety of process technologies, such as hard coating (hard coating) (with or without powder), soft coating (soft coating) ( typically added bulk powder), coated solution (solution coating) (with or without a powder), and suspension coating (suspensioncoating) (with or without powder).

[0003] 挂糖衣工艺是极其冗长的操作,通常按下列顺序进行:a)加入包被介质,b)分布(distribution), c)可选地加入粉末,和d)干燥。 [0003] panning processes are extremely lengthy operations, usually performed in the following order: a) is added coating medium, b) distribution (distribution), c) optionally added to the powder, and d) drying. 这些操作步骤频繁地重复(80次-120 次),这样才在需要包被的材料上逐渐形成包被层。 These operating steps are repeated frequently (80 times -120 times), so as to gradually form a coating layer on the coated material needs. 在这一操作过程中,在所用的量,分布时间,单个阶段的循环数,单个阶段的干燥时间均有变化。 During this operation, the amounts used, the distribution time, number of cycles in a single stage, single stage both the change drying time.

[0004] 熟练工人所要一直关心的是在短时间内生产出好的产品。 [0004] skilled workers have to be concerned about is to produce a good product in a short time. 尽管这样,到目前为止, 还没有成功获得该过程的明显加速。 Despite this, to date, it has not been successful to achieve significant speed up the process.

[0005] 因为必须进行水分的重复蒸发,同时必须防止需要包被的材料相互粘连和/或粘到器具上,所以不可能在所述的材料上随意喷洒大量的溶液或悬浮液。 [0005] Since the evaporation of water must be repeated, while preventing the need to be coated or bonded material adherent to each other and to the / appliance, it can not be arbitrarily large number of spraying on a solution or suspension of the material. 结果是,表面包被操作持续时间是冗长的、不经济的。 As a result, the surface coating operation duration lengthy, uneconomical.

[0006] 试图避免这些缺点的工艺是Lycoat工艺(欧洲专利EP0625311B1),该工艺使用多元醇麦芽糖醇(maltitol)。 [0006] An attempt to avoid the disadvantages of these processes are Lycoat process (European Patent No. EP0625311B1), the process using maltitol polyol (maltitol).

[0007]在一份公司文章(成分世界(The World of Ingredients),1999 年10 月,第59 页)中,对该创新方法与标准方法进行了对比。 [0007] In a company's articles (components in the world (The World of Ingredients), October 1999, p. 59), the innovative method and the standard method were compared. 所述文章描述到节约了一段时间:从3小时30分钟节约到2小时30分钟。 The article describes the saving period: saving from 3 hours 30 minutes to 2 hours and 30 minutes. 该比较是用5kg核心(center)在Dumoulin TVV 600表面涂层机中进行的。 This comparison is performed in Dumoulin TVV 600 coater with 5kg surface core (center).

[0008]用 7. 5kg 核心在Driacoater DRC500/600Vario 中重复Lycoat 工艺,所需要的包被时间为3小时19分钟。 [0008] In the process repeated Lycoat Driacoater DRC500 / 600Vario with the core 7. 5kg, the required coating time was 3 hours 19 minutes.

[0009] PCT专利W000/38532描述了粉末状异麦芽酮糖醇(isomalt)的加入,粉末的量是(实施例A :0. 23kgX 15 = 3. 45kg)或在实施例3的情况下是糖浆(syrup) 7 :8. Ikg ;这分别是异麦芽酮糖醇总量的7. 8%或17. 3%。 [0009] PCT Patent No. W000 / 38532 describes a powdered sugar alcohol is isomalt (Isomalt) is added, the amount of the powder (Example A:. 0 23kgX 15 = 3. 45kg) or, in the case of Example 3 syrup (syrup) 7: 8 Ikg; this is 7.8% or 17.3% of the total amount of sugar alcohol is isomalt, respectively.

[0010] 上述两种技术的缺点是,由这两种方法生产的包被产品的表面是粗糙的,并且着色的表面包被的糖果是不均一的(patchy),以及/或不可能实现包被时间的充分减少。 [0010] The disadvantage of the two techniques is that produced by both methods is surface-coated product is rough, and the surface coating is colored candy is heterogeneous (patchy), and / or impossible to achieve packet substantially reduce the time.

[0011] PCT专利W000/38532描述了从3小时33分钟降至2小时27分钟的最长节约时间,即节约了1小时6分钟或31%。 [0011] PCT Patent No. W000 / 38532 describes 2 hours to 27 minutes from 3 hours 33 minutes to save the maximum time, i.e., saving 1 hours and 6 minutes or 31%. 这只和实际的挂糖衣操作有关。 And only the actual panning operation related.

[0012] PCT专利W000/38532中所描述的方法的一个明显缺点是使用了两种不同的糖浆。 An obvious disadvantage of the process of PCT Patent W000 / 38532 as described in [0012] the use of two different syrups. 在新建工厂的情况下,这意味着更高的投资成本和更复杂的、更易出现故障的产品生产过程。 In the case of new plants, which means higher investment costs and more complex, the failure of the production process occurs more easily. [0013] 因此,在经济与技术基础上,急需要在尽可能短的时间内、以最低的成本和最少的不便生产具有高度贮藏稳定性并且其包被层不会从空气中吸收水分的光滑的、松脆的(crunchy)、易着色的包被产品。 [0013] Accordingly, the economic and technical basis, urgent need in the shortest possible time, at minimum cost and minimum inconvenience and producing a high degree of storage stability which coating layer does not absorb moisture from the air smooth and crispy (crunchy), packets are likely to be colored product.

发明内容 SUMMARY

[0014] 本发明尤其提供了一种用于生产包含内核(core)(例如无糖(sugar-free)内核) 和不吸湿的(non-hygroscopic)(优选无糖的)包被层(coating)的表面包被产品(特别是无糖产品)的方法,该包被层由至少一涂层(layer),优选两个涂层或更多涂层组成, 或包括至少一涂层,优选两个涂层或更多涂层,其中制备包括一种含有一种或多种多元醇(polyol)的溶液或悬浮液的包被介质(coating medium),并在第一步骤a)中将所述包被介质涂布(尤其是部分涂布)于内核上,然后在第二步骤b)中,将干粉状的一种或多种多元醇涂布于所包被的内核(尤其是糖衣糖果(dragee))上,即将相对大量的粉状的一种或多种多元醇撒在所包被的内核上,接着在第三步骤c)中以20°C -80°C进行干燥,在一特别优选的实施例中,涂布包被介质,随后用粉状的一种或多种多元醇涂布(尤其是分撒) [0014] In particular, the present invention provides a method for (non-hygroscopic) (preferably sugar free) coating layer (coating,) comprising an inner core production (Core) (e.g. sugar-free (sugar-free) cores) and non-hygroscopic the method of coating the surface of the products (especially sugar-free products), the packet is composed of at least one coating layer (layer), preferably two or more coating a coating composition or a coating comprising at least one, preferably two coating or more coatings, wherein the preparation comprises one containing one or more polyols (polyol) a solution or suspension of the coating medium (coating medium), and the packet in a first step a) medium was applied (especially partially coated) on a core, then in a second step b), the dry powder of one or more polyols is applied to the packet core (especially sugar-coated candies ( on Dragee)), a relatively large amount of powder is about one or more polyols sprinkled on the package of the core, followed by drying in a third step c) to 20 ° C -80 ° C, in a particularly in a preferred embodiment, the coated coating medium, followed by one or more powdered polyol is applied (in particular dusting) ,然后在20°C -80°C,优选25°C -50°C干燥的工艺顺序可以进行不止一次,特别地进行5次-50 次,特别地进行10次-50次,优选进行20次-40次。 , Then at 20 ° C -80 ° C, preferably 25 ° C -50 ° C the drying process sequence may be performed more than once, in particular for 5 to 50 times, in particular for 10 to 50 times, preferably 20 times -40 times. 如本发明所述,制备一种包括一种含有一种或多种多元醇的溶液或悬浮液的包被介质,并涂布于内核,分撒上大量的粉状的一种或多种多元醇,并对所获得的涂层进行干燥,该工艺顺序可以重复,具体地重复10次-50 次,优选重复20次-40次。 According to the invention, comprising preparing one kind of one or more polyols comprising a solution or suspension of packets by the medium, and applied to the core, a large number of sub-powdered sprinkle one or more polyols alcohol, and the obtained coating layer was dried, the process sequence can be repeated, particularly repeated 10 to 50 times, preferably from 20 to 40 times repeated. 本发明尤其提供了一种上述工艺,其中每次用于分撒在涂层的粉状的一种或多种多元醇的量占包被层,也就是所有涂层中所有多元醇的固体总量的比例具体为25% (重量)-75% (重量),优选30% (重量)-60% (重量),尤其是50% (重量)-60% (重量)。 In particular, the present invention provides said process, wherein the amount for each package dusting powder in the coating one or more polyols are layers, i.e. the total of all solids in the coating of all polyols proportion of the amount of 25% (wt) -75% (by weight), preferably 30% (wt) -60% (by weight), especially from 50% (wt) -60% (by weight). 在一个尤其优选的实施例中,每次用于分撒在涂层的粉状的一种或多种多元醇的量占包被层,也就是所有的涂层中所有多元醇的固体总量的比例是从30% (重量)、35% (重量)、40% (重量)、45% (重量)、50% (重量)、55% (重量)、60% (重量)、65% (重量)或70% (重量)到75% (重量),具体为35% (重量)-75% (重量), 更优选40% (重量)-75% (重量),最优选45% (重量)-75% (重量),具体为50% (重量)-75% (重量)。 In a particularly preferred embodiment, the powder used for dusting or coating a packet amount is more polyols layer, i.e. all of the total solids in the coating of all polyols the proportion of from 30% (by weight), 35% (by weight), 40% (by weight), 45% (by weight), 50% (by weight), 55% (by weight), 60% (by weight), 65% (wt. ) or 70% (by weight) to 75% (wt), particularly 35% (wt) -75% (by weight), more preferably 40% (wt) -75% (wt), most preferably 45% (by weight) - 75% (wt), particularly 50% (wt) -75% (by weight).

[0015] 在一个更进一步特别优选的实施例中,每次用于分撒在涂层的粉状的一种或多种多元醇的量占包被层,即在所有涂层中所有多元醇的固体总量的比例是从30% (重量)、特别地从40% (重量)到45% (重量)、50% (重量)、55% (重量)、60% (重量)或70% (重量),最优选40% (重量)-55% (重量)。 Amount bag [0015] In a still further particularly preferred embodiment, the coating is used for dusting powder in one or more polyols are layers, i.e., all of all polyols in the coating the proportion of the total amount of solids is from 30% (by weight), especially from 40% (by weight) to 45% (by weight), 50% (by weight), 55% (by weight), 60% (wt.) or 70% ( by weight), most preferably 40% (wt) -55% (by weight).

[0016] 在一个特别优选的实施例中,上面所提到的步骤a),b)和C)相互连续进行,具体地按确定顺序。 [0016] In a particularly preferred embodiment, the above-mentioned step a), b) and C) to each other continuously, in particular a predetermined order. 在本发明的一个更进一步优选实施例中,步骤a),b)和c)同时进行。 Embodiment, step a), b) and c) In a still further preferred embodiment of the present invention simultaneously. 在本发明的一个更进一步的优选实施例中,步骤a)和b)同时进行,然后进行步骤C)。 Embodiment, steps a) and b) are performed simultaneously, followed by step C) In a still further preferred embodiment of the present invention. 在本发明的一个更进一步的优选实施例中,步骤a)和c)同时进行。 Embodiment, steps a) and c) In a still further embodiment of the present invention is preferably performed simultaneously. 在本发明的另一个优选实施例中,步骤a)和c)同时进行,然后进行步骤b)。 In another preferred embodiment of the present invention, steps a) and c) are performed simultaneously, followed by step b). 也可以先进行步骤a),然后同时进行步骤b)和C)。 May be performed before steps a), and simultaneously in step b) and C). 当然,也可以先进行步骤a) —次或更多次,然后进行一次步骤b),再进行一次或更多次步骤a),等等。 Of course, also be performed before step a) - once or more times, and then once steps b), then one or more times steps a), and the like.

[0017] 在一个特别优选的实施例中,表面包被产品的内核是口香糖(chewing gum)内核或核心(center)或枕状物(pillow)。 [0017] In a particularly preferred embodiment, the surface of the coated product is a chewing gum core (chewing gum) core or core (Center) or pillows (pillow). 然而,应当理解,也可以选择将坚果(nut)、硬的或软的焦糖(caramels)、硬的或软的小点心(snack articles)、其它糖果(confectionery), 药片、压缩物(compact)或诸如动物饲料、含杀虫剂的物体、含杀草剂的物体、催化剂、衣物洗涤剂等等适于进行表面包被的其他产品作为内核。 However, it should be appreciated that the nut may be selected (NUT), hard or soft caramel (caramels), hard or soft snack (snack articles), other confectionery (Confectionery), tablet, compressed matter (Compact) or as animal feed, pesticide-containing body, herbicide-containing objects, catalyst, laundry detergent, etc. coated surface adapted to other products as a kernel. 这些内核在一特别优选的实施例中可以由无糖组分组成,或含有无糖组分,比如糖醇(sugar alcohols),像异麦芽酮糖醇(isomalt),麦芽糖醇(maltitol),木糖醇(xylitol),赤藻糖醇(erythritol),甘露醇(mannitol),山梨醇(sorbitol),异麦芽酮糖醇GS (isomalt GS),或含有这些化合物的任意一种。 The cores may be composed of a sugar-free constituents in a particularly preferred embodiment, containing or sugarless components, such as sugar alcohols (sugar alcohols), alcohols like isomalt (Isomalt), maltitol (maltitol), wood sugar alcohols (xylitol), erythritol (erythritol), mannitol (mannitol), sorbitol (sorbitol), alcohols isomalt GS (isomalt GS), or contain any of these compounds.

[0018] 一个特别优选的实施例提供了用于分撒的粉状的一种或两种或更多种多元醇的量(每种情况下基于涂布于内核即所有涂层中的所有多元醇总量的固体含量)是25% (重量)-75% (重量),优选30% (重量)-60% (重量),具体为50% (重量)-60% (重量),优选从30% (重量)、35% (重量)、40% (重量)、45% (重量)、50% (重量)、55% (重量)、60% (重量)、65% (重量)或70% (重量)到75% (重量),具体为35% (重量)-75% (重量),具体为40% (重量)、优选45% (重量)或50% (重量)到75% (重量)。 [0018] A particularly preferred embodiment provides one or two or more of the amount of powdered polyol used for dusting is (in each case based on all of the coating applied to the core i.e. all polyol the total solids content of alcohol) 25% (wt) -75% (by weight), preferably 30% (wt) -60% (wt), particularly 50% (wt) -60% (wt.), preferably from 30 % (by weight), 35% (by weight), 40% (by weight), 45% (by weight), 50% (by weight), 55% (by weight), 60% (by weight), 65% (wt.) or 70% ( by weight) to 75% (wt), particularly 35% (wt) -75% (wt), particularly 40% (by weight), preferably 45% (by weight) or 50% (by weight) to 75% (by weight). 在一个更进一步特别优选的实施例中,每次用于撒在涂层上的粉状的一种或多种多元醇的量(基于包被层、即所有涂层中的所有多元醇的固体总量)是从30% (重量),具体从40% (重量)到45% (重量)、50% (重量)、55% (重量)、60% (重量)或70% (重量),最优选40% (重量)-55% (重量)。 In a still further particularly preferred embodiments, the amount or more polyols in powder sprinkled on a coating layer for each (based on the coating layer, i.e., all of the coatings all solid polyol total) is from 30% (wt), particularly from 40% (by weight) to 45% (by weight), 50% (by weight), 55% (by weight), 60% (wt.) or 70% (by weight), most preferably 40% (wt) -55% (by weight).

[0019] 本发明的方法包括在温度提高条件下(优选25°C _90°C,比如优选40°C _80°C,优选45°C -55°C )制备一种表面包被介质,即一种溶液或悬浮液,比如,一种溶解的多元醇和适当情况下一种未溶解的多元醇(也指作为悬浮组分)的混合物,并在需要包被的内核上涂布或分布阶段后,用充分更大量的多元醇精细粉末分撒在包被的内核上。 [0019] The method of the present invention comprises (preferably 25 ° C _90 ° C, such as preferably 40 ° C _80 ° C, preferably 45 ° C -55 ° C) to prepare a surface coating medium at a temperature increase conditions, i.e., a kinds of solutions or suspensions, for example, the appropriate one dissolved polyols and polyol (also referred to as the suspended component) of a mixture of undissolved, and require coating or package distribution stages after the kernel, with a greater amount of polyol sufficient fine powder dusting on the coated cores. 而且,烘干空气的温度高于标准方法的烘干空气的温度。 Further, the temperature of the drying air is higher than the temperature of the drying air standard methods. 粉末的数量和加入的频率以惯常的方式适用于对应的多元醇。 The amount and frequency of addition of the powder in the usual manner applies to the corresponding polyols.

[0020] 令人惊讶的是,在这种工艺中,伴随着极其快速的涂层形成,获得了坚硬的、光滑的、容易着色的、松脆的产品。 [0020] Surprisingly, in this process, along with the extremely rapid formation of the coating, to obtain a hard, smooth, readily colored, crunchy product. 因此本发明提供了一类“软包被工艺”形成的坚硬包被产品, 即包被的产品拥有一坚硬松脆的包被层。 The present invention thus provides a class of "soft coating process" hard pack is formed product, i.e. the coated product has a crunchy hard coating layer. 因此,本发明的产品是在现有技术上的进一步改进,因为他们具有出色的贮藏寿命,即改进的贮藏稳定性。 Thus, the product of the present invention is a further improvement over the prior art because of their excellent shelf life, i.e. improved storage stability.

[0021] 同样令人惊奇的是,尽管根据本发明优选对烘干空气温度加以提高,即200C -80°C,优选25°C -50°C,对于口香糖(软化温度约30°C )而言,温度敏感的核心仍然保持空间的稳定性。 [0021] It is also surprising that, despite the improvement of the drying air temperature is to be preferred according to the invention, i.e., 200C -80 ° C, preferably 25 ° C -50 ° C, for chewing gums (softening temperature about 30 ° C) and words, temperature sensitive core remains stable space.

[0022] 在本发明的一个特别优选的实施例中,在包被工艺的最后,提高烘干空气的温度, 较佳地,持续一段短时间。 [0022] In a particularly preferred embodiment of the present invention, in the final coating, raising the temperature of the drying air, preferably for a short time process.

[0023] 所加的粉末状多元醇占包被层的所有多元醇的固体总量的百分比优选大于50%, 是PCT专利W000/38532 (实施例3)的比例的3倍,几乎是该专利的实施例A的7倍,成为一个格外经济的步骤。 Percent [0023] added powdered polyhydric alcohol accounts of all polyols in the total solid coating layer is preferably greater than 50%, it is 3 times bigger PCT Patent W000 / 38532 (Example 3), almost the patent Example a 7-fold, to be a particularly economical step.

[0024] 本发明的方法所节约的时间达到53% (与PCT专利W000/38532的实施例3相比),与实施例A相比甚至达到68% :换句话说,在这之前能进行一次包被操作的那些情况下,在相同的单位时间内现在能进行两或三次包被操作。 [0024] The method of the present invention, the time saved 53% (compared to the Example in PCT Patent W000 / 38532. 3), even as compared to Example A 68%: in other words, before this can be a in those cases where the package is operated in the same unit of time can now be coated with two or three operations. [0025] 这对于现有技术来说是一个特别显著的优点。 [0025] This is a particularly significant advantage over the prior art.

[0026] 方法的详细描述 Detailed Description [0026] Method

[0027] 在一优选实施例中,需要包被的核心被放在一表面涂层机(pan coater)中,在适当情况下,首先通过摇动和停止空气抽气免于粘附灰尘。 [0027] In a preferred embodiment, the core needs to be coated on the surface of a coater (pan coater), in the appropriate case, first by shaking and adhesion of dust from the exhaust air is stopped.

[0028] 包被介质,也就是包被溶液或悬浮液的制备通过下列步骤完成:在升高的温度下完全溶解多元醇,加入其他可选择的组分,比如阿拉伯树胶(gum arabic)、用于调整包被介质粘性和/或表面张力的化合物、着色剂、香料、活性物质、制药物质、强力甜料、保健品、牙齿矿化剂等等。 [0028] the coating medium, i.e. coating solution or suspension prepared by the following steps is completed: polyol was completely dissolved at elevated temperature, addition of other optional ingredients, such as gum acacia (gum arabic), with to adjust the viscosity and the coating medium / surface tension compound, colorants, fragrances, active substances, pharmaceutical substances, strong sweeteners, health care products, tooth mineralizing agent, or the like. 而且,在适当情况下,加入作为悬浮组分的那部分多元醇。 Also, where appropriate, that portion of the polyol is added as a suspension component.

[0029] 在本发明的一个优选实施例中,包被介质的固体含量为30% -90%,具体为50% -70%,优选55% -60%。 [0029] In a preferred embodiment of the present invention, the solids content of the coating medium is from 30% to 90%, particularly 50% -70%, preferably 55% -60%.

[0030] 在提高的温度(比如25°C -90°C,具体为40°C -80°C,优选45°C -55°C )下搅拌该包被溶液或悬浮液。 [0030] The stirring at an elevated temperature (such as 25 ° C -90 ° C, particularly of 40 ° C -80 ° C, preferably 45 ° C -55 ° C) of the coating solution or suspension. 在本发明的一个特别优选的实施例中,具体地通过喷洒方式(比如以喷洒流或喷洒柱并/或优选地分步喷洒)将包被介质涂布到摇动的内核或核心。 In a particularly preferred embodiment of the present invention, in particular by spraying manner (such as in a spray stream or spray columns and / or fractional preferably spraying) the applied coating medium to the core or core shaking.

[0031] 在本发明的一个特别优选的实施例中,涂布阶段后,尤其是喷洒涂布阶段后,用作分撒粉末的多元醇均勻分散在摇动的核心上,在操作中,使用量可能增加,达到上面提到的所有的量,比如整个挂糖衣操作中所用的和涂布的多元醇的25% (重量)-75% (重量), 具体为30% (重量)-60% (重量),最优选50% (重量)-60% (重量),具体从30% (重量)、35% (重量)、40% (重量)、45% (重量)、50% (重量)、55% (重量)、60% (重量)、 65% (重量)或70% (重量)到75% (重量),具体为35% (重量(重量)。在本发明的一个更进一步特别优选的实施例中,每次用于分撒在涂层的粉状的一种或更多种多元醇的量(占在包被层,也就是指在所有的层中的所有多元醇的固体总量的比例)是从30% (重量),具体为40% (重量)到45% (重量)、50% (重量)、55% (重量)、60% (重量)或70% (重量 [0031] In a particularly preferred embodiment of the present invention, after the coating stage, especially after the spray coating step is used as dusting powder is uniformly dispersed in the polyol shaking core, in operation, the amount of may be increased to achieve all the above-mentioned amount, for example 25% of the entire linked polyol used in sugar coating operations and coating (wt) -75% (wt), specifically 30% (wt) -60% ( by weight), most preferably 50% (wt) -60% (wt), particularly from 30% (by weight), 35% (by weight), 40% (by weight), 45% (by weight), 50% (by weight), 55 % (by weight), 60% (by weight), 65% (wt.) or 70% (by weight) to 75% (wt), specifically (by weight (wt) of 35%. in a still further particularly preferred embodiment of the present invention embodiment, each of one or more powdered weight polyol dusting in the coating (coating layer accounted for, i.e. the total amount of all polyols of the solid in all of the layers ratio) is from 30% (wt), specifically (by weight) 40% to 45% (by weight), 50% (by weight), 55% (by weight), 60% (wt.) or 70% (wt. ),最优选40% (重量)-55% (重量)。 ), And most preferably 40% (wt) -55% (by weight).

[0032] 这个量远大于现有技术中所描述的量。 [0032] This amount is much larger than the amount of the prior art described. 在本方法操作过程中作为分撒粉末加入的粉末的组成成分,可以与多元醇一起使用防结块组分(an anticaking compound)、流动增强齐Ll (a now—ability enhancer)或自由流动齐[J (a free-flow agent)。 As dusting powder to the powder composition, may be used during the operation of the present process, together with a polyol anticaking compound (an anticaking compound), flow enhancement Qi Ll (a now-ability enhancer) or free flowing homogeneous [ J (a free-flow agent).

[0033] 因为包被介质的温度在本发明的一个特别优选的实施例中被增加到40°C以上,具体为50°C以上,优选55°C以上,并在本发明的一个更进一步的特别优选的实施例中烘干空气的温度同样达到该水平,所以对要进行包被的材料,每单位时间使用大量固体是可能的, 同时,作为粉末的加入的一个结果是大量的固体快速涂布于核心。 [0033] Since the temperature of the package medium is increased to a particularly preferred embodiment of the present invention, the above 40 ° C, particularly less than 50 ° C, more preferably 55 ° C, and a still further of the present invention the temperature of the drying air in the particularly preferred embodiment of the same embodiment of this level is reached, so the material to be coated, a large amount of solid per unit of time is possible, while, as a result of the added amount of solids powder is coated quickly distributed in the core.

[0034] 有利的是,在一个优选的实施例中,在本方法操作过程中,液体包被介质所涂布的量和/或粉末所分撒的量连续增加。 [0034] Advantageously, in one preferred embodiment, during the operation of the present process, the amount of applied liquid coating medium and / or increasing the amount of powder is spread in a continuous points.

[0035] 在本发明的一个优选实施例中,所用的多元醇,尤其是不吸湿的多元醇,可以是糖醇(sugar alcohol)或糖替代物(sugar substitute),具体地,它可以是二糖醇(disaccharide alcohols),最优选不吸湿的二糖醇。 [0035] In this embodiment, the polyol used in a preferred embodiment of the present invention, in particular, non-hygroscopic polyol may be a sugar alcohols (sugar alcohol) or sugar substitutes (sugar substitute), in particular, it may be two sugar alcohols (disaccharide alcohols), most preferably a non-hygroscopic disaccharide alcohol.

[0036] 使用的不吸湿的多元醇可以是,比如,l,6-GPS(6-0_a-D-吡喃葡糖-D-山梨醇,6-0-a -D-glucopyranosyl-D-sorbitol),1,l-GPM(l-0-a -D-批喃葡糖_D_ 甘露醇,1-0- a -D-glucopyranosyl-D-mannitol),异麦芽酮糖醇(isomalt),异麦芽酮糖醇ST(isomalt ST),异麦芽酮糖醇GS (isomalt GS),异麦芽酮糖醇LM(isomalt LM),赤藻糖醇(erythritol),甘露醇(marmitol),麦芽糖醇(maltitol)或者它们的混合物。 [0036] The non-hygroscopic polyol used can be, for example, l, 6-GPS (6-0_a-D- -D- glucopyranosyl-sorbitol, 6-0-a -D-glucopyranosyl-D-sorbitol ), 1, l-GPM (l-0-a -D- glucopyranosyl _D_ batch mannitol, 1-0- a -D-glucopyranosyl-D-mannitol), isomalt alcohol (isomalt), iso isomalt ST (isomalt ST), alcohols isomalt GS (isomalt GS), alcohols isomalt LM (isomalt LM), erythritol (erythritol), mannitol (marmitol), maltitol (maltitol ) or mixtures thereof. 而且,1, I-GPS (1-0- α -D-吡喃葡糖-D-山梨醇,1_0_ α -D-glucopyranosyl-D-sorbitol)或木糖醇(xylitol)也可以在本发明中被用作多元醇。 Further, 1, I-GPS (1-0- α -D- glucopyranosyl -D-sorbitol, 1_0_ α -D-glucopyranosyl-D-sorbitol) or xylitol (xylitol) of the present invention may also be in the It was used as the polyol. 在本发明的上下文中,一种吸湿的糖醇是比如山梨醇,其在本发明的一优选实施例中,没有用在包被介质中和以干粉形式使用,优选地不存在于产品的包被层中,优选地,其存在量少于包被层中所用的多元醇的总的固体量的5.0% (重量),具体地,存在量少于包被层中所用的多元醇的总的固体量的1.0% (重量)。 In the context of the present invention, a hygroscopic sugar alcohol is for example sorbitol, which in a preferred embodiment of the present invention is not used in the coating medium and used in dry powder form, preferably not present in the product package the layer is, preferably, it is present an amount less than the total package is 5.0% (wt.) of total solids of the layer used in the polyol, in particular, the presence of the polyol is less in coating layers used in the the solid amount of 1.0% (by weight).

[0037] 因此,在本发明的一优选实施例中,所用的多元醇是异麦芽酮糖醇,即基本等摩尔的1,6-GPS 和1,I-GPM 的混合物,优选由43 % -57 % 的1,6-GPS 和57 % -43 % 的1,I-GPM 组成。 [0037] Thus, in a preferred embodiment of the present invention, the polyol used is isomalt alcohol, i.e., substantially equimolar 1,6-GPS and 1, I-GPM is a mixture, preferably from 43% - 57% 1,6-GPS and 57% to 43% of 1, I-GPM components. 在本发明的一更进一步的优选实施例中,多元醇可以是1,6-GPS和1,I-GPM与其它多元醇比如1,I-GPS的混合物。 In a further preferred embodiment of the present invention, the polyhydric alcohol may be, I-GPM with other polyols such as 1, and a mixture of 1,6-GPS in 1 I-GPS. 在欧洲专利EP0625578B1中有关于这样的混合物的描述。 On such mixtures are described in European patent EP0625578B1 in.

[0038] 在本发明的一更进一步的更加优选的实施例中,使用了包括1,6_GPS和1,I-GPM 的富含1,6-GPS的混合物,具体地,这些混合物由大于57%至99%的1,6-GPS和小于47% 至的1,I-GPM组成。 [0038] In a further even more preferred embodiment of the present invention was used comprising a mixture enriched with 1,6-GPS and 1,6_GPS 1 I-GPM, in particular, the mixture consisted of greater than 57% to 99% 1,6-GPS and 47% to less than a 1, I-GPM components. 因此,一个例子是包括75% (重量)-80% (重量)的1,6_GPS和25% (重量)-20% (重量)的1,I-GPM的一种混合物异麦芽酮糖醇GS。 Thus, one example is a 75% (wt) -80% (by weight) and 25% of 1,6_GPS (wt) -20% (wt.) Of 1, a mixture of I-GPM is isomalt alcohol GS. 在本发明的一更进一步的优选的实施例中,使用了富含1,I-GPM的混合物,优选由大于57%至99%的1,I-GPM 和小于47%至的1,6-GPS组成。 In a further preferred embodiment of the present invention, using an enriched mixture of I-GPM, preferably a 1 is greater than 57-99%, the I-GPM and 1,6 to less than 47% GPS components. 在德国专利DE19532396C2中有关于这样的混合物的描述(除非特别指明,本说明书中的所有的百分数是重量百分数)。 Such mixtures are described on (unless otherwise specified in this specification all percentages are weight percentages) in the German Patent DE19532396C2.

[0039] 在本发明的一特别优选的实施例中,在包被介质中使用的或在表面包被过程中作为粉末使用的(例如存在于包被层中的)唯一多元醇(例如糖醇),是选自1,1_GPM,1, 6-GPS,异麦芽酮糖醇,异麦芽酮糖醇ST,异麦芽酮糖醇GS,异麦芽酮糖醇LM,麦芽糖醇,木糖醇的一种多元醇或它们的混合物。 [0039] In a particularly preferred embodiment of the invention embodiment, used in the coating medium or a surface coating process as (the layer, for example, present in the packet) the only polyol powder used (such as sugar alcohols ), is selected 1,1_GPM, 1, 6-GPS, isomalt alcohols, alcohol isomalt ST, isomalt alcohol GS, iso- isomalt LM, maltitol, xylitol polyols or mixtures thereof. 这样,本发明预见到没有其他的多元醇(例如糖醇)使用在包被介质中和以粉末的方式使用(例如存在于产品的包被层中)。 Thus, the present invention contemplates no other polyol (e.g. sugar alcohols) and the medium is used in a way to use a powder (e.g., packets are present in the product layer) in the package. 在一特别优选的实施例中,选自1,6-6?3,1,1-6?11,1,1-6?3,异麦芽酮糖醇,异麦芽酮糖醇31\异麦芽酮糖醇GS,异麦芽酮糖醇LM,木糖醇和麦芽糖醇的多元醇,例如糖醇,不但是使用在包被中和以粉末形式(例如在包被层中)使用的唯一的多元醇,而且也是使用在包被介质中和以粉末形式使用的(例如在包被层中)唯一的甜味剂(sweetening agent),例如是除提供甜味外也为产品或包被层提供主要部分的唯一的甜味剂。 In a particularly preferred embodiment, the selected 1,6-6? 3,1,1-6? 11,1,1-6? 3, isomalt alcohols, isomalt alcohol 31 \ isomalt ketoses alcohols GS, iso polyols isomalt LM, xylitol and maltitol, a sugar alcohol, e.g., not only in the coating and the only polyols in powder form (e.g. in the coating layer) used , but also used in the coating medium and to provide the main part (e.g., packet layer) only sweetener (sweetening agent), for example, other layers also provide sweetness in powder form using the outer product or package the only sweetener. 在一更进一步的优选实施例中,在包被过程中使用的粉末状多元醇是粉末中使用的唯一物质,也就是粉末只由所用的多元醇组成。 In a further preferred embodiment, powdered polyhydric alcohol used in the coating process is the only substance used in the powder, i.e. the powder solely by the composition of the polyol used.

[0040] 尽管优选无糖产品,但是在包被层中除了多元醇外或者作为一种“多元醇”替代物,也可使用糖(sugar),比如异麦芽酮糖(isomaltulose)。 [0040] Although sugarless products is preferred, but in addition to or instead of one kind of polyhydric alcohol "polyol" was also possible to use a sugar (Sugar) in the coating layer, such as isomaltulose (isomaltulose). 这样,在本发明中,术语“多元醇”也包括异麦芽酮糖。 Thus, in the present invention, the term "polyol" also comprises isomaltulose. 在另一优选的实施例中,术语“多元醇”包括除所有的糖比如异麦芽酮糖以外的糖醇。 In another preferred embodiment, the term "polyol" includes all of the sugar alcohol other than sugars such as isomaltulose is.

[0041] 可是,在一特别优选的实施例中,本发明预见到表面包被方法和由该方法得到的包被层不含吸湿物质,例如不含山梨醇(sorbitol)。 [0041] However, in a particularly preferred embodiment, the present invention contemplates a method and a surface coating obtained by the method of coating layer does not contain absorbent material, for example free of sorbitol (sorbitol). 在一更进一步的特别优选的实施例中,本方法和由此得到的包被层是不含吸湿的无糖材料,比如山梨醇,不含甘露醇或氢化的淀粉水解产物或它们的混合物。 In a further particularly preferred embodiment, the method and the coating layer thus obtained is free of hygroscopic sugarless material, such as sorbitol, mannitol or hydrogenated starch free hydrolyzate or a mixture thereof. 因此,在本发明的一优选的实施例中,包被层不含山梨醇,不含氢化的淀粉水解产物或它们的混合物,也不含粘连剂(bindingagent)和分散剂(dispersing agent),具体地说,不含任何吸湿材料。 Thus, in a preferred embodiment of the present invention embodiment, the coating layer does not contain sorbitol, hydrogenated starch hydrolysates contain, or mixtures thereof, also free of blocking agent (bindingagent) and a dispersant (dispersing agent), particularly say, does not contain any absorbent material.

[0042] 在一更进一步的优选的实施例中,本发明的方法和包被层,优选地,整个产品不含糖(sugar),比如蔗糖(sucrose),因此,可定义为“无糖(sugarless) ”产品,且不含吸湿物质。 [0042] In a further preferred embodiment, the methods and packages of the present invention is layer, preferably, the product sugar (Sugar), such as sucrose (sucrose), therefore, defined as "sugar-free ( sugarless) "product and does not contain hygroscopic substance.

[0043] 根据本发明的一实施例,在包被介质中使用的多元醇可以与以粉末使用的多元醇一样。 [0043] According to an embodiment of the present invention, polyhydric alcohol used in the coating medium may be as a powder with the polyol used. 在另一优选的实施例中,在包被介质中使用的多元醇可以与以粉末使用的一种或多种多元醇不同。 In another preferred embodiment, the polyol used in the coating medium may be different from the one or more polyols used in powder.

[0044] 以粉末状加入的多元醇的优选颗粒大小分布从90% <50 μ m到90% <100 μ m的范围内较方便的选择,也就是比如90% <50 μ m, 90% <60 μ m, 90% <70 μ m, 90% <80 μ m, 90% <90ymo [0044] Preferably the particle size of powder form is added to the polyol distribution from 90% <50 μ m to 90% in the range of <100 μ m is more convenient selection, i.e. for example 90% <50 μ m, 90% < 60 μ m, 90% <70 μ m, 90% <80 μ m, 90% <90ymo

[0045] 在一优选实施例中,粉末可以由异麦芽酮糖醇ST-PA,也就是颗粒大小90%小于50 μ m的异麦芽酮糖醇ST或异麦芽酮糖醇GS-PF (颗粒大小:90%小于100 μ m)或GS-PA, 也即是颗粒大小90%小于50 μ m的异麦芽酮糖醇GS组成。 [0045] In a preferred embodiment, the powder may be composed of isomalt alcohol ST-PA, i.e. a particle size of 90% less than isomalt alcohol ST 50 μ m or isomalt alcohol GS-PF (particle size: 90% less than 100 μ m) or GS-PA, i.e. a particle size of 90% less than 50 μ m of isomalt GS alcohol composition.

[0046] 在本发明的一优选实施例中,本发明所用的粉末也进一步包括添加剂,比如香料, 颜料,活性制药物质,牙齿矿化剂,保健品,强力甜料,自由流动剂,流动增强剂,比如二氧化硅(SiO2),磷酸三钙和/或一种防结块组分。 [0046] In a preferred embodiment of the invention, the used in the present invention, the powder further comprises an additive, such as flavors, colors, active pharmaceutical substance, tooth mineralizing agent, health care products, strong sweeteners, free-flow agents, flow enhancement agent, such as silica (SiO2), tricalcium phosphate and / or an anti-caking component.

[0047] 在本发明的一更进一步的优选实施例中,本发明预见到由具体组成物形成的第一批涂层涂布在内核上,然后由不同组成物形成的第二批涂层涂在第一批涂层上。 [0047] embodiment, the present invention contemplates a second batch of the coating to the first coating layer formed by coating on the core specific composition, and formed from different compositions applied to a further preferred embodiment of the present invention. on the first coating. 例如,相对于第一批涂层,第二批涂层可以含有颜料和/或香料和/或制药物质和/或保健品等等。 For example, with respect to the first coating, the second coating layer may contain a batch of a pigment and / or perfumes and / or pharmaceutical substances and / or health care products and the like. 在本发明的一优选实施例中,当然也可能是超过两批由不同组成物形成的涂层涂布在内核上,比如3,4,5,6或更多不同组成的涂层。 In a preferred embodiment of the present invention, of course, it may be more than two batches of different layer coating formed on the core compositions, such as 3,4, 5,6 or more different coating compositions.

[0048] 在本发明的一更进一步的优选实施例中,用于第二种类型的涂层的多元醇或糖是从异麦芽酮糖,赤藻糖醇和木糖醇中选择的。 [0048] In a further preferred embodiment of the present invention, a second type of polyol or sugar coating from isomalt, erythritol and xylitol selected.

[0049] 作为大量粉末加入的一个结果,节约了表面包被时间,涂布次数也大大降低,使得少于30次涂布获得光滑的涂层成为可能。 [0049] As a result of a large amount of powder added, saving the surface of the coating time, coating times are greatly reduced, so that the coating is less than 30 times to obtain a smooth coating becomes possible.

[0050] 令人惊奇的是,形成的包被层是光滑的、坚硬的并松脆的。 [0050] Surprisingly, the packet layer is formed is smooth, hard and crunchy.

[0051] 对于包被层可比比例而言,与欧洲专利EP0625311B1的方法相比,节约的时间大约是50%,与PCT专利W000/38532的方法相比,大约是35 %。 [0051] than the ratio for the coating layer, compared with the method of European Patent No. EP0625311B1, time saving is about 50%, compared with the method described in PCT patent W000 / 38532, and is about 35%. 这意味着在生产工厂,它可以增加30% -50%的产出,这在批量生产操作情况下导致显著的成本节约。 This means that in the production plant, which can be increased by 30% -50% of the output, which results in significant cost savings in the production operating conditions.

[0052] 创造性地改良的优选以干燥形式加入精细粉末(与它在悬浮液中的加入不同)的一个结果是精细的晶体结构得到了保留。 [0052] One result of the improved creatively fine powder is preferably added in dry form (which was added to the suspension with different) fine crystalline structure is preserved. 已知异麦芽酮糖醇由1,1_GPM和1,6-GPS组成。 Isomalt alcohols known from the 1,6-GPS and 1,1_GPM composition. 这两种物质的固体在水溶液中表现不同:换句话说,这两种不同的晶体表现出显著不同的溶解和结晶行为。 Solid two substances behave differently in aqueous solutions: in other words, the two different crystals show markedly different dissolution and crystallization behavior.

[0053] 这意味着依据时间和温度,微粒固体的颗粒大小和组成在液体表面包被介质中是不同的。 [0053] This means that based on the time and temperature, the particle size of the particulate solid and the liquid surface coating composition of the medium is different.

[0054] 作为在容器和生产线上的长时间滞留的结果,比如作为浓缩或稀释过程的结果, 不能排除部分晶体会长大和/或部分晶体会溶解。 [0054] As a result of the long retention vessel and the production line, for example as a result of concentration or dilution processes, it can not be excluded part of the crystal will grow and / or partially dissolve the crystal. 在本发明的方法中,这样的风险得到了降低,因为整个表面包被操作快得多。 In the method of the present invention, this risk has been reduced, because the whole surface of the coating operation faster.

[0055] 与现有技术不同,它也不必使用两种不同的包被介质。 [0055] Unlike the prior art, it is not necessary to use two different media packets. 在本发明的方法中,使用一种液体包被介质,换句话说,一种溶液或悬浮液,和一种合适颗粒大小分布的粉末已完全足够。 In the method of the present invention, using a liquid coating medium, in other words a solution or suspension, and a powder of suitable particle size distribution is perfectly adequate. [0056] 在软糖衣包被情况下,也是这样的,即大量粉末状糖或糖醇和一种流体投料交替涂布需要包被的核心。 [0056] In the case where the soft dragee coating, is such that a large number of powdered sugar or sugar alcohol are alternately applied to a fluid feed needs to be in packet core. 可是,与本发明的方法不同,在软包被中既不使用温度调节也不使用烘干空气,以致-10%的湿气仍然存在最终的产品中。 However, different methods of the invention, are neither used nor drying air temperature was adjusted in a soft package, so that the 10% moisture still present in the final product. 这也是必要地,因为软包被的最终产品被认为咬起来是柔软的。 It is also necessary, because the soft-coated final product is considered to be a soft bite them. 而且,在软包被情况下,涂布了大约只有3-10层糖衣涂层。 Further, in the case of soft coating, only about 3-10 coated with a sugar coating layer coating.

[0057] 因此,新方法不同于硬包被和软包被。 [0057] Accordingly, a new method is different from the hard coating and soft bag. 然而,本发明的方法的具体条件(粉末的一致性,粉末的量,流体阶段和烘干空气的温度)导致表面包被产品显示出令人惊奇的坚硬的,松脆的和光滑的表面。 However, the specific conditions of the process according to the invention (identity of powder, amount of powder, the fluid phase and the drying air temperature) causes the surface coated products show a hard, crunchy, and smooth surface surprising.

[0058] 本发明的方法的时间优势不仅仅限于实际的挂糖衣操作(水分蒸发减少),也延及包被介质的制备。 [0058] The time advantage of the process of the present invention is not limited only to the actual panning operation (reduced evaporation of water), also extends to the preparation of the media pack. 因为需要溶解的多元醇较少,这里也实现了时间和成本的节约。 Because it requires less soluble polyols, also realized here, time and cost savings. 与PCT 专利W000/38532的描述相反,PCT专利W000/38532写到:“有时,干投料可以用于硬包被中,但是在整个过程中,通常干投料的量有限制,且用于其中的几次涂布。”,在表面包被过程中,本发明的分撒采用大量的粉末来实现,并用于很多情况。 Instead, the patent PCT W000 / 38532 and described in PCT Patent writes W000 / 38532 are: "Sometimes, the dry feed may be used in the hard coating, but throughout the process, typically the amount of dry feed is limited, and for which applied several times. ", a surface coating process, dusting the present invention employs a large amount of powder is achieved, and used in many cases. 高浓缩的溶液,大量用于涂布,和快速结晶被认为是在硬包被中产生问题(粘,粗糙,不均勻的表面)的原因(来源: Technologie der Herstellung von Hart—,Weich—und. Schokodragees,Frank Perchtold, ZDS Solingen/D in Einfiihrung HerstelltechnologieDragees,ZDS,0ctober9_13,2000)。 Highly concentrated solutions, for coating large, and rapid crystallization are considered causes (the source of the problem is generated (sticky, rough, uneven surface) in the hard pack: Technologie der Herstellung von Hart-, Weich-und. Schokodragees, Frank Perchtold, ZDS Solingen / D in Einfiihrung HerstelltechnologieDragees, ZDS, 0ctober9_13,2000).

[0059] 建议的补救措施包括下述方法: [0059] proposed remedies include the following methods:

[0060] 加热或稀释溶液 [0060] or a diluted solution heated

[0061] 干燥更加缓慢 [0061] drying more slowly

[0062] 稀释涂布溶液 [0062] The coating solution was diluted

[0063] 降低核心温度 [0063] reduce the core temperature

[0064] 减少粘性 [0064] The reduced viscosity

[0065] 减少每次涂布的溶液量; [0065] reduce the amount of each coating solution;

[0066] 延长两次涂布间的干燥时间; [0066] extend the drying time between the two coating;

[0067] 在本发明的方法中,几乎对于每一点都做了相反的事: [0067] In the method of the present invention, for almost every point to the contrary things:

[0068] 在同样温度溶液不稀释 [0068] undiluted solution at the same temperature

[0069] 干燥比通常快 [0069] The drying is usually faster than

[0070] 涂布介质是且保持高度浓缩的 [0070] The coating medium is and remains highly concentrated

[0071] 烘干空气的温度和核心的温度在过程中实际上增加 [0071] The drying air temperature and the core temperature is actually increased in the process

[0072] 不改变粘性 [0072] does not change the viscosity

[0073] 每次涂布的量增加 [0073] The amount of each coating increased

[0074] 以及每次干燥时间和标准程序相比短得多。 [0074] as well as each and drying time is much shorter compared to the standard procedures.

[0075] 很容易明白,本发明的方法操作时在很大程度上与现有技术相反。 [0075] readily apparent, the method of the present invention, when the operation of the prior art largely opposite.

[0076] 因此,更令人惊奇的是,产品清楚地表现出硬包被产品的特性。 [0076] Thus, more surprisingly, the clear demonstration of the product to be hard pack product characteristics.

[0077] 根据本发明,另一优点是有可能在大量粉末的帮助下对成形/模压较差的核心或硬糖(hard boiled candies)或其他不平坦的成形复合物进行包被以形成光滑的和平坦的产品。 [0077] A further advantage of the present invention, it is possible to form / mold core or hard candy poor (hard boiled candies) or other non-planar molded composite in bulk powder be coated to help form a smooth and flat products. 能使表面或边缘有瑕疵的部分变光滑,形成平滑的表面区域。 Make defective surface or edge portion becomes smooth, to form a smooth surface region. 这为包被产品提供了更快、更简单的生产条件。 This provides a faster, easier production conditions for coated products. 根据本发明,甚至由于制造导致的粗糙的物体也能被包被形成光滑的,美观的产品。 According to the invention, even as a result of manufacturing rough objects can also be coated with a smooth, beautiful products.

[0078] 由于在涂层构造阶段大量粉末的使用,烘干空气的温度可选的很高,因为粉末将 [0078] Since a large amount of powder used, the temperature of the drying air at high optional coating stage configuration, as powder

10防止核心过热。 10 to prevent the overheating of the core.

[0079] 在本发明的一特别优选实施例中,在包被过程中的烘干可由共向流(Co currentstream)完成,共向流也叫顺流(direct flow),指的是烘干空气和喷洒流通过糖果床(dragee bed)或表面涂层机时的方向相同,或在本发明的另一优选实施例中,由反流(counter flow)完成,反流也叫反向流(counter current stream),即烘干空气和喷洒流通过糖果床或表面涂层机时的方向相反。 [0079] In a particularly preferred embodiment of the present invention, the drying in the coating process may be to co (Co currentstream) stream is completed, also called co-current flow to total (direct flow), refers to the dry air Confectionery and spraying stream through the bed (dragee bed) or the same surface coating machine direction, or, in another preferred embodiment of the present invention, accomplished by reflux (counter flow), also called regurgitation reverse flow (counter current stream), i.e. opposite to the drying air and spray flow direction through the bed or surface candy coater.

[0080] 在本发明的一特别优选实施例中,后一种的方法,即烘干空气对喷洒流的反流,在干投料添加过程,也就是步骤b)的涂层构建过程当中进行。 [0080] In a particularly preferred embodiment of the present invention, the latter method, i.e., the spray drying air flow of reflux, add the dry feeding process, i.e. in step b) is carried out among a coating build process. 因此,在本发明的一特别优选实施例中,步骤a),b)和c)可以同时进行。 Thus, in a particularly preferred embodiment of the present invention, step a), b) and c) may be performed simultaneously. 烘干空气的反流减小了粉末的损失。 Reflux the drying air reduces the loss of powder.

[0081] 在本发明的另一优选实施例中,前一种提到的方法,也就是烘干空气对喷洒流的顺流,在光滑阶段进行,也就是,步骤c)与步骤a)同时进行。 [0081] A method of the kind mentioned before, i.e. downstream of the spray drying air stream, in a preferred embodiment the smooth phase In another embodiment of the present invention, i.e., step c) and step a) simultaneously get on.

[0082] 在本发明的另一实施例中,通过在表面涂层机或包被桶中使用一个或多个折流板(baffle)使得步骤b)中糖果和粉末的混合得到更大改进。 [0082] In another embodiment of the present invention, by using one or more baffles coater or coating the surface of the tub (baffle) such that the step b) mixing the powder and confectionery greater improvement.

[0083] 在本发明的一更进一步的优选实施例中,步骤a)中包被介质的涂布和步骤b)中粉末的应用同时进行。 [0083] In embodiments, the coating medium in step a coating application step b) is performed while the powder) in a further preferred embodiment of the present invention.

[0084] 为减少包被介质和粉末涂布到内核的持续时间,这些涂布可以通过同时加入两者,或更优选地,通过流体包被介质的涂布开始后进行时间上滞后的粉末的应用来实现。 [0084] To reduce the coating to the core and the powder coating medium duration, which can be applied both by the addition of, or more preferably, a time lag after the start of coating fluid through the coating medium powder applications to achieve. 在本发明的一优选实施例中,步骤a)中包被介质的涂布,即具体而言喷洒流,应该在步骤b), 也就是粉末加入前击中内核,尤其是移动的糖果床,从而使得潮湿的核心能获得粉末颗粒。 In a preferred embodiment of the present invention, step a) is applied in the coating medium, i.e., specifically spray jet should be at steps b), i.e. hitting the powder before addition of the core, in particular candy moving bed, so that the core can be obtained wet powder particles.

[0085] 本发明的另一设计是使用一种低浓缩的液体包被介质,该液体包被介质可以作为单一或平滑糖浆从包被过程开始使用或在步骤a)和b)中构建涂层阶段后与大量粉末使用。 [0085] Another design of the present invention is the use of a low concentrated liquid coating medium, the liquid coating medium may be smooth or as a single coating syrup from the start or during use to build a coating steps a) and b) later stage using bulk powder.

[0086] 本发明也涉及一种根据本发明的上述方法的任意一种方法获得的产品,尤其涉及包被产品,尤其是无糖包被产品或具有无糖包被层的包被产品,比如糖果、坚果、硬或软的焦糖、硬或软的小点心、药片、压缩物和口香糖。 [0086] The present invention also relates to a process for obtaining the product according to any of the methods described above of the present invention is particularly directed to coated products, in particular sugarless coated product having a package or sugarless coating layer is the product, such as candy, nuts, hard or soft caramels, hard or soft snack, tablets, chewing gum and compressed matter.

[0087] 进一步的优选实施方式是从属的权利要求的主题。 [0087] Further preferred embodiments are the subject matter claimed in the dependent claims.

附图说明 BRIEF DESCRIPTION

[0088] 图1是本发明的包被流程示意图。 [0088] FIG. 1 is a packet is a schematic flow diagram of the present invention. 具体实施方式 Detailed ways

[0089] 本发明参考实施例和图进一步详细说明。 [0089] the present invention with reference to the embodiment and described in more detail.

[0090] 在本发明的描述,权利要求和例子中,使用了下面的术语,缩写和计算方案: [0090] In the description of the present invention, the claims and examples, the use of the following terms, abbreviations and calculating schemes:

[0091] 包被溶液或悬浮液的总的流体量:TFA(Iotal Fluid Amount of a coating solution orsuspension) [0091] The total coated amount of fluid solutions or suspensions: TFA (Iotal Fluid Amount of a coating solution orsuspension)

[0092] TFA 的干物质含量:DSTFA(2ry substance content of the TFA) Dry matter content of [0092] TFA is: DSTFA (2ry substance content of the TFA)

[0093]总的粉末加入:TPA (Iotal Powder Addition) [0093] The total powder added: TPA (Iotal Powder Addition)

[0094] (总)的核心重量:(T) Cff (Total 1 Center Weight) [0094] (total) Core Weight: (T) Cff (Total 1 Center Weight)

[0095](总)的糖果最后重量:⑴ DEW (dotal) Sragee End Weight)[0096] (总)的涂层的重量:(T)Lff (dotal)Layer Weight【(T)DEff-(T)Cff] [0095] (total) weight of the final candy: ⑴ DEW (dotal) Sragee End Weight) [0096] (total weight) of the coating: (T) Lff (dotal) Layer Weight [(T) DEff- (T) Cff]

[0097] 涂层部分百分数:PLP percentage Layer Portion) [0097] Part percent coating: PLP percentage Layer Portion)

[0098] 包被材料(流体和粉末)(总)的损失:(T) L ((Iotal)Loss of the coating material(fluid and as powder)) [0098] coating (fluid and powder) (total) material loss: (T) L ((Iotal) Loss of the coating material (fluid and as powder))

[0099] 糖果涂层的粉末部分(=在包被层中多元醇的所有固体中的粉末状多元醇的量):PPDL (Powder Portion in the Dragee Layer (= amount of polyol in powder form based ontotal solids content of the polyol in the coating)) (= Amount of all solids in the coating layer polyol powdered polyol) [0099] Candy coated powder fraction: PPDL (Powder Portion in the Dragee Layer (= amount of polyol in powder form based ontotal solids content of the polyol in the coating))

[0100] 糖果涂层中粉末部分百分数(=粉末状多元醇占包被层中多元醇的所有固体量白勺百分数):PPPDL (Percentage Powder Portion in the Dragee Layer ( = percentage amountof polyol in powder form based on total solids content of the polyol in the coating)) [0100] the percentage powder portion (= polyol powdered solids account for all package is white spoon percentage layers polyol) Confectionery coatings: PPPDL (Percentage Powder Portion in the Dragee Layer (= percentage amountof polyol in powder form based on total solids content of the polyol in the coating))

[0101] 图中: [0101] FIG:

[0102] TFA指在所有阶段加入/喷洒的包被溶液或悬浮液的总量。 [0102] TFA means the total amount of added / sprayed coating solution or suspension in all phases.

[0103] DSTFA指不带水分的TFA。 [0103] DSTFA means the TFA without the water.

[0104] TPA指加到(湿润)核心的总的粉末量: [0104] TPA means added (wet weight) of the total amount of powder core:

[0105] TCff是需要包被的核心的质量(核心的数量乘以一个核心的质量),CW是一个核心的平均质量。 [0105] TCff packet needs to be a core mass (mass multiplied by a number of cores of the core), CW is the average mass of a core.

[0106] TDEW指完成的糖果的质量(核心的总质量加上糖果涂层的总质量);DEW是一个糖果的平均质量。 [0106] Quality TDEW means to carry out candy (core plus the total mass of the total mass of a confectionery coating); DEW is the average mass of a confectionery.

[0107] TLff是所有糖果的重量减去所有核心的重量的差值;LW是一个糖果的平均重量减去一个核心的平均重量。 [0107] TLff all weight minus the weight of the confectionery all cores; LW is an average weight of the confectionery core minus the average weight a.

[0108] PLP是总涂层重量(X100)和总的糖果最后重量的比。 [0108] PLP is the total coating weight (XlOO) ratio and total weight of the final candy. 它也可以如下计算: It can also be calculated as follows:

[0109] PLP = χ 片XLWXIOO/x 片XDEW,涂层百分数(percentage layer portion)通过最终产品的重量减去核心重量再除以最终产品的重量,该值乘以100来计算。 [0109] PLP = χ sheet XLWXIOO / x pieces XDEW, the coating percentage (percentage layer portion) by subtracting the weight of the core weight of the final product divided by the weight of the final product, the value is multiplied by 100 to calculate. 或通过完成的带有同样核心数量的糖果的不太小数量的X值进行估算。 Or estimated by a small number of completed core with the same number of X values ​​less candy.

[0110] TL是(DSTFA+TPA)减去TLW的差值,总损失可以归咎于磨损(在烘干空气中)和内部装置部件的包被。 [0110] TL is (DSTFA + TPA) minus the TLW total loss can be attributed to abrasion (in the drying air) and the package member is inside of the apparatus.

[0111] PPDL由下面的公式1计算: [0111] PPDL calculated by the following formula 1:

[0112] PPDL【kg】=(TPAXTLW)/(TPA+DSTFA-TL)【kg】 [0112] PPDL [kg] = (TPAXTLW) / (TPA + DSTFA-TL) [kg]

[0113] 用语言描述,PPDL [kg]=(总粉末加入X总的层的重量)/(总的粉末加入+总流体的干物质量-总的损失) [0113] description language, PPDL [kg] = (Total weight of the total powder added layer X) / (total dry weight of the total powder added fluid + - loss of the total)

[0114] 涂层中粉末部分百分数是(公式2): [0114] the percentage powder portion in the coating is (Equation 2):

[0115] PPPDL【%】=PPDL/TLWX 100 =在糖果涂层的粉末部分/总的涂层的重量X 100 【%】 [0115] PPPDL [%] = PPDL / TLWX 100 = in the confectionery coating portion of the powder / coating weight of the total X 100 [%]

[0116] 计算方案(例子) [0116] Calculation scheme (Examples)

[0117] 在包被过程中,60. 00公斤的核心(TCW)被包被到重为90. 00公斤的最终的产品(TDEff)上,导致30. 00公斤的总的涂层的重量(TLW)。 [0117] In the coating process, 60.00 kg of the core (a TCW) were coated to a weight of 90.00 kg of final product (TDEff) on, resulting in a total weight of 30.00 kg coating ( TLW). 糖果的33. 3% (PLP)由包被材料组成。 33.3% of the candy (PLP) by a coating material composition.

[0118] 作为流体加入,即包被介质,用了58. 70kg (TFA),含有66 %的DS (干物质),也就是38. 75kg干物质(DSTFA)。 [0118] As fluid is added, i.e. coating medium, with 58. 70kg (TFA), containing 66% DS (dry), i.e. 38. 75kg of dry matter (DSTFA). 作为粉末加入,总共消耗了8. IOkg(TPA)。 Added as a powder, it consumed a total 8. IOkg (TPA). 因此,在包被过程中加入的总量是46. 85kg干物质。 Thus, the total amount of coating added was 46. 85kg dry process. 糖果层的粉末部分是(8. 10/46. 85)*3000 = 5. 19kg(PPDL), 糖果层的粉末部分百分数是(PPDL/TLW) X 100,所以是5. 19/30. 00*100 = 17. 3% (PPPDL)。 Portion of the candy layer is a powder (8. 10/46. 85) * 3000 = 5. 19kg (PPDL), the candy powder layer is partially percentage (PPDL / TLW) X 100, so that 5 19/30 00 * 100 = 17. 3% (PPPDL).

[0119] 本实施例中,不出现在包被产品的加入物质的总损失(TL)是46. 85-30. 00 = 16.85kg。 [0119] In this embodiment, the packet is not present in the total loss of the product added substance (TL) is 46. 85-30. 00 = 16.85kg.

[0120] 如果没有考虑到加入的包被介质和粉末的必然的损失(比如,由于部分留在表面包被机器中),总的粉末加入8. IOkg(TPA)和总的涂层的重量30. OOkg(TLff)的比如下,结果8. 10/30. 00 = 27. 0% (PPPDL)会造成糖果层中粉末部分高得多的假象,必然的损失会被认为是仅是加入的流体。 [0120] If not taken into account the weight of the medium and the inevitable loss of added powder package (for example, left on the surface due to partial coating machine), the total powder added 8. IOkg (TPA) and the total coating 30 artifacts. OOkg (TLff) is as follows, the result 8. 10/30. 00 = 27. 0% (PPPDL) will result in much higher confectionery powder layer portion, the inevitable losses would be considered merely added to the fluid .

[0121] 在更少或没有损失的情况下,两PPPDL值将给出(TPA*100) /TLff ( = TPA+DSTFA), 因为在上面的公式1中,TLW等于TPA+DSTFA。 [0121] In the case of less or no loss, two values ​​would give PPPDL (TPA * 100) / TLff (= TPA + DSTFA), as in the above formula 1, TLW is equal to TPA + DSTFA. 在本例子中,限度是8. 10/54. 95 = 14.7%, 这是粉末部分在总包被材料的比例。 In the present example, the limit is 8. 10/54. 95 = 14.7%, which is the proportion of material powder portion in the total package.

[0122] 下列实施例阐述本发明,而不限制本发明的范围。 [0122] The following examples illustrate the present invention without limiting the scope of the present invention.

[0123] 实施例1 [0123] Example 1

[0124] 4. 365kg的异麦芽酮糖醇GS (75 % (重量)的1,6-GPS和25 % (重量)的1,1-GPM) 在65°C溶解于2. 9L水中,温度稍低时加入2. 215kg的异麦芽酮糖醇ST-PF(50%的1,6-GPS 和50%的1,1_GPM,颗粒大小:90% <100 μ m)。 [0124] isomalt GS 4. 365kg of alcohol (75% (by weight) of 1,6-GPS and 25% (by weight) of 1,1-GPM) at 65 ° C 2. 9L dissolved in water, the temperature 2. 215kg slightly upon addition of the sugar alcohol is isomalt ST-PF (50% of 1,6-GPS and 50% 1,1_GPM, particle size: 90% <100 μ m). 另外,在液体中再加0. 41g阿拉伯树胶(gum arabic)(以一种浓度为50%的溶液形式)和50g 二氧化钛(Ti02)。 Further, in the liquid plus 0. 41g gum acacia (gum arabic) (in a 50% concentration in solution) and 50g of titanium oxide (Ti02). 将该表面包被悬浮液喷洒到口香糖(chewing gum)核心(枕头状,pillow-shaped)上。 The surface coating suspension is sprayed into the chewing gum (chewing gum) core (pillow-shaped, pillow-shaped) on. 在分布期间,总共2. 18kg 的异麦芽酮糖醇ST-PA(50%的1,6-GPS和50%的1,1_GPM,颗粒大小:90% <50 μ m)被不均一地分撒在摇动的、潮湿的核心,随后,25°C-50°C的烘干空气通过糖果床。 During the distribution, a total of isomalt alcohol 2. 18kg of ST-PA (50% of 1,6-GPS and 50% 1,1_GPM, particle size: 90% <50 μ m) are not uniformly dusting shaking, moist core, and then, the drying air 25 ° C-50 ° C through the bed candy. 下表总结了各阶段及所用的数量(以流体形式和以粉末形式)。 The following table summarizes the various stages and the number (in fluid form and in powder form) to be used.

[0125] [0125]

Figure CN101090637BD00131

[0126] 总的表面包被时间(不包括抛光)是69分钟,包被部分达到糖果重量的33%。 [0126] The overall surface of the coating time (without polishing) is 69 minutes, coated portions of 33% by weight of the candy. 产品是松脆的,有一个光滑的表面。 Products are crunchy and have a smooth surface.

[0127] 实施例2 [0127] Example 2

[0128] Driacoater DRC500/600Vario,核心重量7. 5kg。 [0128] Driacoater DRC500 / 600Vario, by weight of the core 7. 5kg.

[0129] [0129]

Figure CN101090637BD00132
Figure CN101090637BD00141

[0130]共计:1.01kg [0130] Total: 1.01kg

[0131] 共计:2.00kg的TS (来自包被介质)和2. 18kg粉末共投料26次。 [0131] Total: 2.00kg of TS (from coating medium) and 2. 18kg total powder feed 26. 多元醇的52% 采用粉末的形式。 52% of the polyol in the form of a powder.

[0132] 实施例3 (比较) Example 3 (Comparative) [0132] Embodiment

[0133] Lycoat ^^ (The world of ingredients, 1999) [0133] Lycoat ^^ (The world of ingredients, 1999)

[0134] [0134]

Figure CN101090637BD00142

[0135]总数: 2191 100 1859 465 [0135] Total: 21911001859465

[0136] 在Lycoat方法中,多元醇总数的20. 0%采用粉末投料。 [0136] In Lycoat method, 20.0% of the total polyhydric alcohol by powder feeding.

[0137] 实施例4 (比较)[0138] 在本例中,分析了PCT专利W000/38532的实施例3 (核心重量60kg [0137] Example 4 (Comparative) [0138] In the present embodiment, the analysis of Example PCT Patent W000 / 38532 3 (core weight 60kg

[0139] [0139]

Figure CN101090637BD00151

[0140] 总计:36次涂布了38. 75kg的DS (38. 75kg的数量来自PCT专利W000/38532第16 页的实施例3的表1),进行了8. Ikg的干投料,也就是说,多元醇的17. 3% (PPPDL)是以干投料的形式使用。 [0140] Total: 36 coated with DS 38. 75kg (number of 38. 75kg embodiment from PCT patent W000 / 38532 in Table 1 on page 3 of 16) was used 8. Ikg dry feed, i.e. He said polyhydric alcohol is 17.3% (PPPDL) is used in the form of dry feed.

[0141] 实施例5 [0141] Example 5

[0142] 包被由麦芽糖醇(maltitol)制备的硬糖[0143] 在Driacoater中包被了7. Okg由麦芽糖醇(maltitol)制备的硬糖。 [0142] Hard Candy [0143] coating prepared from maltitol (maltitol) were coated in a Driacoater 7. Okg hard candy prepared from maltitol (maltitol) a. 一种55°C、 65° Bx的异麦芽酮糖醇GS溶液(75% (重量)的1,6_GPS和25% (重量)的1,I-GPM)) 用作流体包被介质。 One kind of 55 ° C, isomalt GS solution of alcohol of 65 ° Bx (1,6_GPS 75% (by weight) and 25% (by weight) of 1, I-GPM)) is used as a fluid coating medium. 在溶液总的3028g中,即使用了1968g干物质,和总的2340g的异麦芽酮糖醇ST-PF (50% (重量)的1,6-GPS和50% (重量)的1,1-GPM,颗粒大小<100 μ m)。 3028g of the total solution, i.e. the use of 1968g of dry matter, and a total of 2340g of ST-PF (50% (by weight) of 50% 1,6-GPS and isomalt alcohol (by weight) of 1,1- GPM, particle size <100 μ m). 单一粉末加入是:1 X 300g (阶段1),6 X 150g (阶段2),3 X 180g (阶段3)和3 X 200g (阶段4)。 Single powder was added: 1 X 300g (phase 1), 6 X 150g (Phase 2), 3 X 180g (Stage 3) and 3 X 200g (Phase 4). 包被时间是72分钟。 Coating time is 72 minutes.

[0144] 计算获得的本方法的粉末部分百分数是54.3%。 Percentage powder portion of the process [0144] 54.3% was obtained by calculation. 最终的产品具有光滑的平整的表面。 The final product has a smooth flat surface. 涂层在包被的最终产品的比例是38%。 The proportion of coating coated end product was 38%.

[0145] 实施例6 [0145] Example 6

[0146] 一种下述配方的异麦芽酮糖醇GS (75% (重量)的1,6_GPS和25% (重量)的1, 1-GPM)溶液在Vario500/600涂层机中在60°C用于包被7. 5kg的垫子状(cushion-shaped) 的核心。 [0146] A sugar alcohol is isomalt GS following formulation (75% (wt) and 25% of 1,6_GPS (by weight) of 1, 1-GPM) solution at 60 ° in Vario500 / 600 coater C for mat-shaped core coating (cushion-shaped) of the 7. 5kg.

[0147] [0147]

55.00% 异麦芽酮糖醇GS 55.00% isomalt GS alcohol

4.10% 阿拉伯树月交溶液(Gum arabic-solution, 50%浓度(ds)) 4.10% gum arabic solution month post (Gum arabic-solution, 50% concentration (DS))

0.05% AK糖(AcesulfamK) 0.05% AK sugar (AcesulfamK)

0.05% 阿斯巴特(Aspartame) 0.05% aspartame (of Aspartame)

1.00% 二氧化4太(TiO2) 39.80% 水_ 1.00% 4 too dioxide (TiO2) 39.80% water _

100.00% 100.00%

[0148] 25g 薄荷油香料(peppermint flavour) [0148] 25g peppermint perfume (peppermint flavour)

[0149] 2930g 异麦芽酮糖醇GS-PA (作为干投料) [0149] 2930g alcohol isomalt GS-PA (as dry feed)

[0150] 整个包被过程是69分钟,涂层百分数(PLP)是36.3%。 [0150] overall coating time was 69 minutes, the coating percentage (PLP) was 36.3%. 用26个循环构建涂层。 Layer was build in 26 cycles.

[0151] 所用的固体异麦芽酮糖醇和液体异麦芽酮糖醇的比例是2930g/1471g= 1.99。 [0151] ratio of the solid isomalt alcohol liquid used isomalt alcohol is 2930g / 1471g = 1.99. 在包被材料中固体异麦芽酮糖醇的量(PPPDL)是2930g/4400g = 66. 6%。 Amount (PPPDL) in the coating material in the solid isomalt alcohol is 2930g / 4400g = 66. 6%. 糖果有一个光滑平整和松脆的表面。 The dragees have a smooth even and crunchy surface.

[0152] 实施例7: [0152] Example 7:

[0153] 一种下述配方的异麦芽酮糖醇GS (75% (重量)的1,6_GPS和25% (重量)的1, 1-GPM)溶液在Vario500/600涂层机中在60°C用于包被7. 5kg的垫子状(cushion-shaped) 的核心。 [0153] A sugar alcohol is isomalt GS following formulation (75% (wt) and 25% of 1,6_GPS (by weight) of 1, 1-GPM) solution at 60 ° in Vario500 / 600 coater C for mat-shaped core coating (cushion-shaped) of the 7. 5kg.

[0154]55.00% 异麦芽酮糖醇GS 4.10% 阿拉伯树胶溶液(50%浓度(ds)) 0.05% AK 糖0.05% 阿斯巴特 [0154] 55.00% alcohol isomalt GS 4.10% gum arabic solution (50% strength (ds)) 0.05% AK sugar, aspartame 0.05%

0.06% 深色苹果绿(Apple Green Shade colour) 0.06% dark apple (Apple Green Shade colour)

40.74% _ 40.74 percent _

100.00% 100.00%

[0155] 2180g含可选的0. 二氧化硅(SiO2)的异麦芽酮糖醇ST-PA (作为干投料) [0155] 2180g isomalt ST-PA-containing alcohol 0.5 optional silica (SiO2) (as a dry feed)

[0156] 整个包被过程是64分钟,涂层百分数(PLP)是29.0%。 [0156] overall coating time was 64 minutes, the coating percentage (PLP) was 29.0%. 用25个循环构建涂层。 The layer was build in 25 cycles.

[0157] 所用的固体异麦芽酮糖醇和液体异麦芽酮糖醇的比例是2180g/1262g= 1.73。 [0157] ratio of the solid isomalt alcohol liquid used isomalt alcohol is 2180g / 1262g = 1.73. 在包被材料中固体异麦芽酮糖醇的量(PPPDL)是2180g/3442g = 63. 3%。 Amount (PPPDL) in the coating material in the solid isomalt alcohol is 2180g / 3442g = 63. 3%. 糖果有一个光滑平整和松脆的表面。 The dragees have a smooth even and crunchy surface.

[0158] 实施例8 [0158] Example 8

[0159] 一种下述配方的异麦芽酮糖醇GS (75% (重量)的1,6_GPS和25% (重量)的1, 1-GPM)溶液在Vario500/600涂层机中在60°C用于包被7. 5kg的垫子状(cushion-shaped) 的核心。 [0159] A sugar alcohol is isomalt GS following formulation (75% (wt) and 25% of 1,6_GPS (by weight) of 1, 1-GPM) solution at 60 ° in Vario500 / 600 coater C for mat-shaped core coating (cushion-shaped) of the 7. 5kg.

[0160] [0160]

55.00% 异麦芽酮糖醇GS 55.00% isomalt GS alcohol

4.10% 阿拉伯树胶溶液(50%浓度(ds)) 0.05% AK 糖 4.10% gum arabic solution (50% strength (ds)) 0.05% AK sugar

0.05% 阿斯巴特 0.05% aspartame

0.06% 诱惑红(AlluraRed) 0.06% Allura Red (AlluraRed)

0.50% 二氧化钛 0.50% titanium dioxide

40.24% 7K_ 40.24% 7K_

100.00% 100.00%

[0161] 2580g含可选的0. 二氧化硅(SiO2)的异麦芽酮糖醇ST-PA (作为干投料) [0161] 2580g isomalt ST-PA-containing alcohol 0.5 optional silica (SiO2) (as a dry feed)

[0162] 整个包被过程是65分钟,涂层百分数(PLP)是36.0%。 [0162] overall coating time was 65 minutes, the coating percentage (PLP) was 36.0%. 用23个循环构建涂层。 Layer was build in 23 cycles.

[0163] 所用的固体异麦芽酮糖醇和液体异麦芽酮糖醇的比例是2580g/1326. 7g = 1. 94。 [0163] ratio of the solid isomalt alcohol liquid used isomalt alcohol is 2580g / 1326. 7g = 1. 94. 在包被材料中固体异麦芽酮糖醇的量(PPPDL)是2580g/3906. 6g = 66. 0%。 Amount (PPPDL) in the coating material in the solid isomalt alcohol is 2580g / 3906. 6g = 66. 0%. 糖果有一个光滑平整和松脆的表面。 The dragees have a smooth even and crunchy surface.

[0164] 实施例9 [0164] Example 9

[0165] 一种下述配方的异麦芽酮糖醇GS (75% (重量)的1,6_GPS和25% (重量)的1, 1-GPM)溶液在Vario500/600涂层机中在60°C用于包被7. 5kg的垫子状(cushion-shaped) 的核心。 [0165] A sugar alcohol is isomalt GS following formulation (75% (wt) and 25% of 1,6_GPS (by weight) of 1, 1-GPM) solution at 60 ° in Vario500 / 600 coater C for mat-shaped core coating (cushion-shaped) of the 7. 5kg.

[0166]55.00% 异麦芽酮糖醇GS 4.10% 阿拉伯树胶溶液(50%浓度(ds)) 0.05% AK 糖 [0166] 55.00% alcohol isomalt GS 4.10% gum arabic solution (50% strength (ds)) 0.05% AK sugar

0.05% 阿斯巴特(Aspartame) 0.01% Vegex color yellow 0.50% 二氧化饮 0.05% aspartame (Aspartame) 0.01% Vegex color yellow 0.50% drink dioxide

40.29% 水_ 40.29% water _

100.00% 100.00%

[0167] 2250g含可选的0. 二氧化硅(SiO2)的异麦芽酮糖醇ST-PA (作为干投料) [0167] 2250g isomalt ST-PA-containing alcohol 0.5 optional silica (SiO2) (as a dry feed)

[0168] 整个包被过程是53分钟,层百分数(PLP)是30. 1%。 [0168] overall coating time was 53 minutes, the percentage layer (PLP) was 30.1%. 用21个循环构建层。 Construction layer was 21 cycles.

[0169] 所用的固体异麦芽酮糖醇和液体异麦芽酮糖醇的比例是2250g/1179. 3g = 1. 91。 [0169] ratio of the solid isomalt alcohol liquid used isomalt alcohol is 2250g / 1179. 3g = 1. 91. 在包被材料中固体异麦芽酮糖醇的量(PPPDL)是2250g/3429. 3g = 65. 6%。 Amount (PPPDL) in the coating material in the solid isomalt alcohol is 2250g / 3429. 3g = 65. 6%. 糖果有一个光滑平整和松脆的表面。 The dragees have a smooth even and crunchy surface.

[0170] 实施例10 [0170] Example 10

[0171] 一种下述配方的异麦芽酮糖醇GS (75% (重量)的1,6_GPS和25% (重量)的1, 1-GPM)溶液在Vario500/600涂层机中在60°C用于包被7. 5kg的垫子状(cushion-shaped) 的核心。 [0171] A sugar alcohol is isomalt GS following formulation (75% (wt) and 25% of 1,6_GPS (by weight) of 1, 1-GPM) solution at 60 ° in Vario500 / 600 coater C for mat-shaped core coating (cushion-shaped) of the 7. 5kg.

[0172] [0172]

55.00% 异麦芽酮糖醇GS 55.00% isomalt GS alcohol

4.10% 阿拉伯树股溶液(50%浓度(ds)) 4.10% solution of gum arabic shares (50% concentration (ds))

0.05% AK 糖 0.05% AK sugar

0.05% 阿斯巴特 0.05% aspartame

0.02% 天然绿(natural green color) 0.02% natural green (natural green color)

0.50% 二氧化钛 0.50% titanium dioxide

40.28% _ 40.28 percent _

100.00% 100.00%

[0173] 2250g含可选的0. 二氧化硅(SiO2)的异麦芽酮糖醇ST-PA (作为干投料) [0173] 2250g isomalt ST-PA-containing alcohol 0.5 optional silica (SiO2) (as a dry feed)

[0174] 整个包被过程是50分钟,层百分数(PLP)是30. 0%。 [0174] overall coating time was 50 minutes, the percentage layer (PLP) was 30.0%. 用21个循环构建层。 Construction layer was 21 cycles.

[0175] 所用的固体异麦芽酮糖醇和液体异麦芽酮糖醇的比例是2250g/1178. 2g = 1. 91。 [0175] As used solid ratio of sugar alcohol isobutyl ketone liquid isomalt alcohol malt 2250g / 1178. 2g = 1. 91. 在包被材料中固体异麦芽酮糖醇的量(PPPDL)是2250g/3429. 3g = 65. 6%。 Amount (PPPDL) in the coating material in the solid isomalt alcohol is 2250g / 3429. 3g = 65. 6%. 糖果有一个光滑平整和松脆的表面。 The dragees have a smooth even and crunchy surface.

[0176] 实施例11 [0176] Example 11

[0177] 在一个带有4个管口的Driacoaterl600/1,25中,用核心为316kg和流体及粉末状异麦芽酮糖醇进行了3次试验。 [0177] In Driacoaterl600 / 1,25 4 with a spout in the fluid and with the core and 316kg powdered isomalt alcohol test was conducted three times. 对于构建33. 2%,31. 和28. 7%的糖果层,需要的包被时间是110分钟,108分钟和93分钟。 For building 33.2%, 31, and 28.7% of the candy layer, coating time it is required 110 minutes, 108 minutes and 93 minutes. 使用的粉末量分别是52. 3%,46. 0%和47. 9%0 The amount of powder used was 52.3%, 46.0% and 47.9% respectively 0

[0178] 实施例12[0179]配方: [0178] Example 12 [0179] Formulation:

[0180] [0180]

5500g 异麦芽酮糖醇GS 3980g 水 5500g alcohol isomalt GS 3980g water

4IOg 阿拉伯树胶溶液(50% ) 5g 阿斯巴特 4IOg gum arabic solution (50%) 5g Aspartame

5g AK 糖 5g AK sugar

12g 姜黄色素(Curcumin) 12g Curcumin (Curcumin)

4g_Eurolake Brilliant Blue 4g_Eurolake Brilliant Blue

10016g 流体包被介质 10016g fluid coating medium

1680g 粉末状的异麦芽酮糖醇GS-PA 1680g of powdered sugar alcohol is isomalt GS-PA

[0181] 阶段加入流体(ml) 粉末(g) 流体TS(g) 烘干空气(°C) [0181] Add phase fluid (ml) Powder (g) the TS fluid (g) drying air (° C)

[0182] 1 1 114 100 62.7 30 [0182] 11114100 62.7 30

[0183] 1 2 114 100 62.7 30 [0183] 12114100 62.7 30

[0184] 1 3 114 100 62.7 30 [0184] 13114100 62.7 30

[0185] 1 4 114 100 62.7 30 [0185] 14114100 62.7 30

[0186] 2 5 120 100 66 40 [0186] 251201006640

[0187] 2 6 120 100 66 40 [0187] 261201006640

[0188] 2 7 120 100 66 40 [0188] 271201006640

[0189] 2 8 120 100 66 40 [0189] 281201006640

[0190] 2 9 120 100 66 40 [0190] 291201006640

[0191] 2 10 120 100 66 40 [0191] 2101201006640

[0192] 2 11 120 100 66 40 [0192] 2111201006640

[0193] 3 13 132 76 72.6 50 [0193] 31313276 72.6 50

[0194] 3 14 132 76 72.6 50 [0194] 31413276 72.6 50

[0195] 3 15 132 76 72.6 50 [0195] 31513276 72.6 50

[0196] 3 16 132 76 72.6 50 [0196] 31613276 72.6 50

[0197] 3 17 132 76 72. 6 50 [0197] 31713276 72.6 50

[0198] 3 18 132 76 72.6 50 [0198] 31813276 72.6 50

[0199] 3 19 132 72.6 50 [0199] 50 319 132 72.6

[0200] 4 20 120 66 30 [0200] 4201206630

[0201] 4 21 120 66 30 [0201] 4211206630

[0202] 4 22 120 66 30 [0202] 4221206630

[0203] 4 23 120 66 30 [0203] 4231206630

[0204] 5 24 104 57. 2 30 [0204] 30 524 104 57.2

[0205] 5 25 104 57. 2 30 [0205] 30 525 104 57.2

[0206] 5 26 104 57. 2 30[0207] 6 27 84 46. 2 30 [0206] 526 104 57.2 30 [0207] 62 784 46.2 30

[0208] 7 28 0 0 50 [0208] 7,280,050

[0209] 8 29 0 0 25 [0209] 8,290,025

[0210] 9 30 60 33 25 [0210] 930603325

[0211] 总计3276ml 1680g 1801.8g [0211] Total 3276ml 1680g 1801.8g

[0212] 总的干物质 3481. 8g [0212] 3481. 8g total dry matter

[0213] 粉末百分数 48.3% [0213] Powder percentage 48.3%

[0214] 在Driacoater Vario 500/600中用异麦芽酮糖醇包被了7. 5kg的垫子状的口香糖核心。 [0214] In Driacoater Vario 500/600 with isomalt alcohol coated chewing gum cushion-shaped core of 7. 5kg. 包被溶液温度是60°C。 Coating the solution temperature was 60 ° C.

[0215] 应当注意到,在上面的配方(10016g)中提到的成分的数量不对应实际上作为包被材料的流体的量(3276ml),因为进行这样的实验,必须考虑到大量的浪费(在容器、管子等中的不可避免的损失)。 [0215] It should be noted that the number of recipe (10016g) in the above-mentioned ingredients does not actually correspond to the amount of fluid as the coating material (3276ml), because for such experiments, a lot of waste must be considered ( inevitable losses in containers, pipes and the like). 与此相反,在配方(1680g)中粉末的量完全对应实际使用的粉末的量(1680g),因为粉末称重后直接加到包被床,没有任何损失。 On the contrary, in the recipe (1680 g) in an amount corresponding to the amount of powder actually used entirely powder (1680 g), because the powder is added directly to the coating bed weighing without any loss.

[0216] 表中的包被方案除了表示烘干空气的温度和包被循环的数目之外,还表示在不同的包被阶段应用的物质的量(流体包被材料(ml),流体包被材料中的干物质(g),粉末添加剂(g))。 [0216] The packet table is in addition to that the program than the drying air temperature and the number of packages to be recycled, the amount of said substance (fluid coating material (ml), fluidic packets are applied at different stages of the packet is the dry material (g), the additive powder (g)). 在包被层中的粉末百分数比例是48.3%。 Percent ratio of layer-coated powder is 48.3%. 涂层的百分数,从平均重量差异计算, 是29.2%。 Percent of the coating, calculated from the average weight difference, was 29.2%. 包被时间(不包括打蜡抛光)是86分钟。 Coating time (without wax polishing) is 86 minutes. 一个特殊的特征是在包被程序的最后、打蜡抛光之前的短暂加热。 A special feature is the last, briefly heated before polishing wax package program.

[0217] 实施例13 [0217] Example 13

[0218] 用下列配方在Driacoater Vario500/600中包被7. Okg预涂阿拉伯树胶的、巧克 [0218] with the following formulation in a Driacoater package Vario500 / 600 is precoated 7. Okg gum arabic, chocolate

力包被的榛实。 Force coated hazelnuts.

[0219] [0219]

6500g 65.6% 异麦芽酮糖醇GS 2980g 30.1% 水410g 4.1% 阿拉伯树胶溶液(50%) IOg 0.1% 阿斯巴特/AK糖(1: 1)的混合物 Mixture (1: 1) to 6500g 65.6% isomalt GS 2980g 30.1% alcohol 410g 4.1% aqueous gum arabic solution (50%) IOg 0.1% aspartame / AK sugar

IOg 0.1% 酒石黄(Tartrazine) IOg 0.1% tartrazine (Tartrazine)

100% 100%

[0220] IlOOg 异麦芽酮糖醇GS-PA(作为粉末/干投料) [0220] IlOOg alcohol isomalt GS-PA (as powder / dry feed)

[0221] 溶液保持在55°C,在最初的11次加入过程中加入粉末添加剂,每次IOOg粉末的 [0221] The solution was maintained at 55 ° C, was added powdered additive added during the first 11, each powder IOOg

Mo Mo

[0222] 包被时间是157分钟,在糖果层中的粉末添加剂是32. 1%。 [0222] coating time was 157 minutes, the additive powder in the candy layer is 32.1%. 由于温度敏感核心(巧克力),烘干空气为20°C。 Since the temperature-sensitive core (chocolate) the drying air is 20 ° C. 涂层的量为最终产品的29. 1%。 The amount of coating was 29.1 percent of the final product.

[0223] 100件(减去最轻的5片)未包被的、传统包被的和本实施例的包被件根据其重量的一致性进行了比较。 [0223] 100 (minus the lightest 5) is not coated, the package and the conventional coated member of the present embodiment is compared according to the weight consistency. 未包被的核心(巧克力包被的榛实)的平均重量是2562g,标准偏差0. 318g( = 11. 相对标准偏差)。 Uncoated core (chocolate-coated hazelnuts) has an average weight of 2562g, a standard deviation of 0. 318g (= 11. The relative standard deviation).

[0224] 用传统的异麦芽酮糖醇包被的产品的平均重量是3497g,标准偏差0.400g(= 11. 4%相对标准偏差)。 [0224] by a conventional isomalt average weight alcohol coated product is 3497g, a standard deviation of 0.400g (= 11. 4% relative standard deviation). [0225] 根据本发明的方法获得的糖果的平均重量是3665g,标准偏差0. 396g( = 10. 8% 相对标准偏差)。 [0225] The average weight was 3665g confectionery obtained by the method of the present invention, the standard deviation of 0. 396g (= 10. 8% relative standard deviation).

[0226] 这清楚表明本发明的方法的光滑和平均效果。 [0226] This clearly shows that the average and smooth the effect of the method of the present invention.

Claims (26)

1. 一种生产表面包被产品的方法,其特征在于,所述表面包被产品包括内核和不吸湿的包被层,其中所述包被层包括至少一个涂层,通过制备包被介质,所述包被介质为一种含有一种或多种多元醇的溶液或悬浮液,和下述方法将所述包被层涂覆在内核上,在步骤a) 中在所述内核上涂布所述包被介质以涂布上一个所述涂层,然后在步骤b)中分撒上一种或多种粉末状的所述多元醇,随后在步骤c)中在20°C -80°C干燥,粉末状的所述多元醇的量占包被层中总的多元醇的固体的量为30% (重量)-75% (重量),或选择交替重复步骤a),b)和c) 2次以上,其中所述多元醇是木糖醇,赤藻糖醇,甘露醇,1,1-GPM,1,6-GPS, 1, 1-GPS,或它们的混合物,其中用于分撒的以粉末形式加入的所述多元醇的颗粒大小分布为90%< 50μπι。 1. A surface coating method for production, wherein the surface of the coated product comprising an absorbent core and not the coating layer, wherein the coating comprises at least one coating layer is prepared by the media pack, the coating medium containing one or as a solution or suspension, and a method more polyols of the coating on the core, the core layer is coated on said coating in step a) the coating is applied on a medium of the coating layer, and one or more powdered sprinkle the polyhydric alcohol in step b) the equatorial then, in step c) at 20 ° C -80 ° C dried, powdered packet amount of the polyol is the layer of the total amount of the solid polyol is 30% (wt) -75% (by weight), or select alternately repeating steps a), b) and c ) two or more times, wherein the polyol is xylitol, erythritol, mannitol, 1,1-GPM, 1,6-GPS, 1, 1-GPS, or mixtures thereof, wherein for points the spread is added as a powder of particle size distribution of the polyol 90% <50μπι.
2.如权利要求1所述的方法,其特征在于,所述包被层是无糖的包被层。 2. The method according to claim 1, wherein said coating layer is a sugarless coating layer.
3.如权利要求1所述的方法,其特征在于,所述包被层包括两个以上所述涂层。 The method according to claim 1, wherein said coating layer comprises two or more of the coating.
4.如权利要求1所述的方法,其特征在于,粉末状的所述多元醇的量占包被层中总的多元醇的固体的量为40% (重量)-75% (重量)。 4. The method according to claim 1, wherein the amount of packet powdered polyol is the total amount of the solid layer of polyol (by weight) to 75% (by weight) of 40%.
5.如权利要求4所述的方法,其特征在于,粉末状的所述多元醇的量占包被层中总的多元醇的固体的量为50% (重量)-60% (重量)。 5. The method according to claim 4, wherein the amount of packet powdered polyol is the total amount of the layer of solid polyol (wt) -60% (by weight) of 50%.
6.如权利要求1所述的方法,其特征在于,可以选择交替重复步骤a),b)和c)5次-50次。 6. The method according to claim 1, characterized in that it is possible to select alternately repeating steps a), b) and c) 5 to 50 times.
7.如权利要求6所述的方法,其特征在于,可以选择交替重复步骤a),b)和c)20次-40次。 7. The method according to claim 6, characterized in that it is possible to select alternately repeating steps a), b) and c) 20 times -40 times.
8.如权利要求1所述的方法,其特征在于,其中所述包被介质的固体含量范围为30% -90%。 8. The method according to claim 1, wherein, wherein the solids content of the coating medium in the range of 30% -90%.
9.如权利要求8所述的方法,其特征在于,所述包被介质的固体含量范围为50% -70%。 9. The method according to claim 8, wherein the solids content of the coating medium in the range of 50% -70%.
10.如权利要求1所述的方法,其特征在于,其中以溶解形式或以悬浮液组分存在的所述多元醇和/或用于分撒的所述多元醇选自二糖醇。 10. The method according to claim 1, characterized in that, in dissolved form or in which the suspension components present in the polyol and / or used for dusting the polyol is selected from disaccharide alcohols.
11.如权利要求1所述的方法,其特征在于,其中所述多元醇是异麦芽酮糖醇,富含1, 6-GPS的1,I-GPM和1,6-GPS的混合物,或者是富含1,I-GPM的1,I-GPM和1,6-GPS的混合物。 11. The method according to claim 1, characterized in that wherein the polyol is isomalt alcohol, and the mixture I-GPM and 1,6-GPS in 1 1 of 6-GPS enriched, or is a mixture of I-GPM and 1,6-GPS in 1 I-GPM enriched 1.
12.如权利要求1所述的方法,其特征在于,其中在涂布所述包被层过程中,所述包被介质的温度是为25°C -90°C。 12. The method according to claim 1, wherein, wherein said coating layer coating process, the temperature of the medium the packet is 25 ° C -90 ° C.
13.如权利要求12所述的方法,其特征在于,所述包被介质的温度是为45°C -55°C。 13. The method of claim 12, wherein the packet is the medium temperature is 45 ° C -55 ° C.
14.如权利要求1所述的方法,其特征在于,其中在包被层中使用阿拉伯树胶,香料,颜料,活性物质,强力甜料,和/或保健品。 14. The method according to claim 1, characterized in that, wherein gum arabic, flavors, colors, active substances, strong sweeteners, and / or health products in the coating layer.
15.如权利要求14所述的方法,其特征在于,所述活性物质是活性制药物质。 15. The method according to claim 14, wherein said active substance is an active pharmaceutical substance.
16.如权利要求1所述的方法,其特征在于,其中涂布上第一批涂层后,再涂上第二批组分不同的涂层。 16. The method according to claim 1, wherein the first group of coatings which after coating, then coated with different batches of the second component of the coating.
17.如权利要求16所述的方法,其特征在于,所述的组分不同的涂层是含有颜料的涂层。 17. The method according to claim 16, characterized in that the different components of the coating layer is a coating containing a pigment.
18.如权利要求1所述的方法,其特征在于,其中所述粉末状的多元醇中含有防结块组分。 18. The method according to claim 1, wherein, wherein the powdered polyol containing anticaking compound.
19.如权利要求1所述的方法,其特征在于,其中所述包被介质含有一种调节所述包被介质的粘性和/或表面张力的化合物。 19. The method according to claim 1, wherein, wherein the coating comprises a compound of adjusting the viscosity of the coating medium and / or surface tension of the medium.
20.如权利要求18所述的方法,其特征在于,所述防结块组分是二氧化硅。 20. The method according to claim 18, wherein the anticaking component is silica.
21.如权利要求1所获得的产品。 21. The product obtained as claimed in claim 1.
22.如权利要求21所述的产品,其特征在于,所述产品选自糖果,坚果,坚硬的和柔软的焦糖,坚硬的和柔软的小点心,药片。 22. The product according to claim 21, wherein said product is selected from candy, nuts, hard and soft caramels, hard and soft snack tablet.
23.如权利要求22所述的产品,其特征在于,所述糖果是口香糖。 23. The product according to claim 22, wherein the confectionery is a chewing gum.
24.如权利要求21所述的产品,其特征在于,所述产品包括动物饲料、种子,含杀虫剂的物体、含杀草剂的物体、催化剂、衣物洗涤剂。 24. The product according to claim 21, characterized in that said product comprises an animal feed, seed, pesticide-containing body, herbicide-containing body, a catalyst, laundry detergent.
25.如权利要求21所述的产品,其特征在于,其包被层包括防结块组分,和/或一种调节所述包被介质的粘性和/或表面张力的化合物。 25. The product according to claim 21, characterized in that it comprises an anticaking coating layer component, and / or a compound for regulating the viscosity of the coating medium and / or surface tension.
26.如权利要求25所述的产品,其特征在于,所述防结块组分是二氧化硅。 26. The product according to claim 25, wherein the anticaking component is silica.
CN 200580034826 2004-10-15 2005-10-13 Improved pan coating process CN101090637B (en)

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DE102004050516A DE102004050516A1 (en) 2004-10-15 2004-10-15 Production of pan-coated products e.g. confectionaries or nuts involves applying solution or suspension of polyol to core; dusting polyol in powder form; and drying
US60/619,177 2004-10-15
US11/075,930 2005-03-09
US11/075,930 US20060204614A1 (en) 2005-03-09 2005-03-09 Pan coating process
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ITMI20080889A1 (en) * 2008-05-15 2009-11-16 Perfetti Van Melle Spa A process for producing chewing gum provided with one covering layer and chewing gum obtainable by this process
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