CN101058232A - Method for manufacturing super slight type polarizing optical resin lens - Google Patents
Method for manufacturing super slight type polarizing optical resin lens Download PDFInfo
- Publication number
- CN101058232A CN101058232A CN 200710093819 CN200710093819A CN101058232A CN 101058232 A CN101058232 A CN 101058232A CN 200710093819 CN200710093819 CN 200710093819 CN 200710093819 A CN200710093819 A CN 200710093819A CN 101058232 A CN101058232 A CN 101058232A
- Authority
- CN
- China
- Prior art keywords
- optical resin
- mould
- resin lens
- type polarizing
- hours
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920005989 resin Polymers 0.000 title claims abstract description 40
- 239000011347 resin Substances 0.000 title claims abstract description 40
- 230000003287 optical effect Effects 0.000 title claims abstract description 30
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 16
- 238000000034 method Methods 0.000 title claims description 11
- 239000011521 glass Substances 0.000 claims abstract description 9
- 238000000465 moulding Methods 0.000 claims abstract description 8
- 238000005452 bending Methods 0.000 claims abstract description 7
- 239000003999 initiator Substances 0.000 claims abstract description 7
- 238000004140 cleaning Methods 0.000 claims abstract description 6
- 238000002360 preparation method Methods 0.000 claims abstract description 6
- 238000004381 surface treatment Methods 0.000 claims abstract description 5
- 239000000178 monomer Substances 0.000 claims description 12
- 238000006116 polymerization reaction Methods 0.000 claims description 10
- 239000000853 adhesive Substances 0.000 claims description 6
- 230000001070 adhesive effect Effects 0.000 claims description 6
- 230000009977 dual effect Effects 0.000 claims description 6
- 229920002635 polyurethane Polymers 0.000 claims description 5
- 239000004814 polyurethane Substances 0.000 claims description 5
- 238000003556 assay Methods 0.000 claims description 4
- 229920001971 elastomer Polymers 0.000 claims description 3
- 239000005304 optical glass Substances 0.000 claims description 3
- 238000004080 punching Methods 0.000 claims description 3
- 238000004026 adhesive bonding Methods 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims description 2
- 239000000806 elastomer Substances 0.000 claims description 2
- 238000010008 shearing Methods 0.000 claims description 2
- 229920002725 thermoplastic elastomer Polymers 0.000 claims description 2
- 239000000463 material Substances 0.000 abstract description 7
- 239000004033 plastic Substances 0.000 abstract description 4
- 229920003023 plastic Polymers 0.000 abstract description 4
- 238000005520 cutting process Methods 0.000 abstract description 3
- 238000007689 inspection Methods 0.000 abstract description 2
- 230000010287 polarization Effects 0.000 abstract 3
- 241001589086 Bellapiscis medius Species 0.000 abstract 1
- 239000010408 film Substances 0.000 abstract 1
- 238000009472 formulation Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000012788 optical film Substances 0.000 abstract 1
- 238000007711 solidification Methods 0.000 abstract 1
- 230000008023 solidification Effects 0.000 abstract 1
- 238000005516 engineering process Methods 0.000 description 4
- -1 polytetrafluoroethylene Polymers 0.000 description 4
- 238000003756 stirring Methods 0.000 description 3
- 238000010792 warming Methods 0.000 description 3
- 239000004836 Glue Stick Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 2
- 239000004810 polytetrafluoroethylene Substances 0.000 description 2
- 238000010105 thermoset forming Methods 0.000 description 2
- 241001270131 Agaricus moelleri Species 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 230000031700 light absorption Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- IUGYQRQAERSCNH-UHFFFAOYSA-N pivalic acid Chemical compound CC(C)(C)C(O)=O IUGYQRQAERSCNH-UHFFFAOYSA-N 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
Abstract
The invention relates to the manufacturing of super thin polarization optical resin glass that comprises the polarization optical film bending, mold preparation, plastic ring material selection, plastic ring preparation and optical resin individual selection and formulation, through surface treatment to match with the glass mold. It selects high deflection optical resin individual, inputting initiator twister evenly to pour into the mold, after thermal solidification and molding, through mold stripping, cutting, cleaning and inspection to make the qualified product. It has solved the combining issue of high deflection resin material and polarization film.
Description
Technical field
The present invention relates to a kind of manufacture method of optical resin polarized lenses, especially relate to a kind of manufacture method of super slight type polarizing optical resin lens.
Background technology
Development along with the eyeglass technology, resin lens is because its excellent physics, chemistry and optical property become people's new lover gradually, and the polarized resin eyeglass since the combination of light polarizing film and resin formed except that the excellent properties of resin lens, also possess particular optical performance: can barrier level the dazzle of vibration, but seldom to the vibration light absorption of other directions, realized taking into account of the two, shown distinctive advantage, the manufacture method of super slight type polarizing optical resin lens has very high technology content, belong to the new and high technology category, domestic and international at present research in this regard is very few.
Summary of the invention
Technical problem to be solved by this invention is: provide a kind of and make the polymerization of high refractive optics resin monomer good and combine the manufacture method of good super slight type polarizing optical resin lens with light polarizing film.
The present invention is achieved like this: it comprises the steps:
The manufacture method of super slight type polarizing optical resin lens comprises the steps:
1) glass optical mould and the preparation of moulding circle;
2) light polarizing film is standby after the assay was approved through press-bending, typing, surface treatment, shearing;
3) the inclined to one side film of the work of handling well and mould one are reinstated moulded circle matched moulds location;
4) mixed good optical resin monomer is injected the mould that gets togather, make qualified products through curing polymerization, the demoulding, side cut, cleaning, check successively;
It is characterized in that:
1) the described circle of moulding is the thermoplastic rubber elastomer, and moulds the band strong point in the loop-shaped;
2) the glass mold punching press is adopted in the press-bending of described light polarizing film, and its curvature is consistent with the optical glass mould that matched moulds is used;
3) surface treatment of described light polarizing film comprise cleaning, drying, destatic, gluing, selected adhesive is a polyurethane series adhesive;
4) described optical resin monomer is high refractive optics resin monomer.
Temperature control curve in the described polymerization process is as follows: 42 ℃ are incubated 8～10 hours, rise to 70～75 ℃ through 4～8 hours, rise to 95～100 ℃ in 1～3 hour, are incubated 1～3 hour then, reduce to 60～70 ℃ through 1 hour, totally 15～25 hours.
In solidifying polymerization process, adopt dual initiator to reduce polymerization rate.
The refractive index of described high refractive optics resin monomer is more than 1.60.
The present invention sets cure profile according to the initiation temperature of dual initiator, makes the good polymerization of high refractive optics resin monomer and can well combine with light polarizing film; The height selected for use refraction resin is because of refractive index higher (more than 1.60) and have good optical performance and mechanical performance, the polarized resin lens thickness of production with go out much to reach ultra-thin characteristic with low folding (about 1.50) the polarized resin eyeglass of Qu Guangdu than thin; The special circle of moulding has been determined the position of light polarizing film in resin lens with the adhesive of selecting for use, has further guaranteed the ultra-thin property of super slight type polarizing optical resin lens.
The specific embodiment
1, the mould and the preparation of moulding circle
According to production requirement, the band of selecting for use corresponding rubber particles to prepare required kind supports the polarisation of anchor point and moulds circle, removes foreign material such as the burr moulded on the circle, stain, send matched moulds; Will with mould clean up and send matched moulds.
2, the preparation of light polarizing film
Light polarizing film through film balance fixedly be placed on temperature be 45～50 ℃, humidity be in 90～95% the constant temperature and humidity stove softening after, carry out punching press with glass mold, and under pressurized state dryness finalization, the time is about 10 minutes; After the cooling, deliver to typing in 10～60 days between constant temperature and humidity.
Take required stereotyped light polarizing film clean, dry, destatic after, film inspection personnel detect color, camber and the membrane date of film again, select for use polyurethane series adhesive to be coated on uniformly on the light polarizing film after qualified, the curved film that then will handle well is put into cutter and is sheared matched moulds.
3, batching
Select for use the high index of refraction optical resin material as the base stock of producing this super slight type polarizing resin lens, in stirred tank, stir and be warming up to 50～60 ℃, be incubated 10 minutes, in cold bath, reduce to 20～30 ℃ again; Add high low temperature dual initiator and under this temperature, stirred 30～60 minutes, then-0.09～-to be poured after vacuumizing 10～20 minutes under the vacuum environment of 0.1MPa.
4, eyeglass production
Send the curved film of the polarisation handled well and the optical glass mould of getting ready and the circle matched moulds of moulding selected for use material feeding to use well according to the production demand.The material for preparing is watered in the mould that has got togather, and watering material filter employing aperture is the polytetrafluoroethylene (PTFE) filter membrane of 0.3 μ m.Mould thermosetting in configuring the computer control stove of temperature curve that cast is good, its temperature curve is: 42 ℃ are incubated 8～10 hours, rose to 70～75 ℃ through 4～8 hours, in 1～3 hour, rise to 95～100 ℃, be incubated 1～3 hour then, reduced to 60～70 ℃ through 1 hour, totally 15～25 hours, become after qualified products are made in the demoulding, side cut, cleaning, check.
Embodiment one:
It is softening in the constant temperature and humidity stove to take 10m grey light polarizing film, glass mold with 600 rates of curving, 80mm diameter strikes out 360 of the curved films of the 600 grey polarisations of bending, after dry typing in 20 days, through clean, dry, destatic processing, select the coating of polyurethane glue stick for use, cutting into the 74.6mm diameter, is that bands that the plastics of MILASTOR-6010N are made 600 curved 80mm diameters support anchor points and mould circle and 600 to bend 1.60 refractive indexes of 80mm diameters standby with asymptotic many focuses mould matched moulds with the Mitsui KCC trade mark.Selecting Japanese oil chemistry Co., Ltd. trade mark for use is that the 1.60 refractive index optical resin monomers of NK-16C stir in stirred tank and are warming up to 50～60 ℃, be incubated 10 minutes, in cold bath, reduce to 25～30 ℃ again, add new peroxide tert-butyl caprate, the peroxide-2-ethyl hexanoic acid tert-butyl dual initiator stirred under this temperature 30～60 minutes, then-0.09～-inject 360 moulds that get togather after vacuumizing 10～20 minutes under the vacuum environment of 0.1MPa, (42 ℃ are incubated 9 hours configuring temperature curve, rose to 70 ℃ through 6 hours, in 2 hours, rise to 100 ℃, be incubated 2 hours then, reduced to 70 ℃ through 1 hour) the computer control stove in behind the thermoset forming, through the demoulding, cut edge, clean, after the assay was approved, just having made refractive index is the asymptotic many focus half highly finished product eyeglasses of 1.60 ultrathin grey polarizing optical resins.
Embodiment two:
It is softening in the constant temperature and humidity stove to take the brown light polarizing film of 10m, glass mold with 800 rates of curving, 80mm diameter strikes out 360 of the curved films of the 800 brown polarisations of bending, after dry typing in 15 days, through clean, dry, destatic processing, select the coating of polyurethane glue stick for use, cutting into the 74.6mm diameter, is that bands that the plastics of THERMORUN LG are made 800 curved 80mm diameters support anchor points to mould 1.60 refractive indexes of circle and 800 curved 80mm diameters standby with flat-top pair optical mode tool matched moulds with the Mitsubishi KCC trade mark.Selecting the Wu Yu of the Amada Co., Ltd. trade mark for use is that the 1.60 refractive index optical resin monomers of K-136 stir in stirred tank and are warming up to 50～50 ℃, be incubated 10 minutes, in cold bath, reduce to 20～25 ℃ again, add new peroxide tert-butyl caprate, the special pentyl ester dual initiator of peroxidating pivalic acid stirred under this temperature 30～60 minutes, then-0.09～-inject 360 moulds that get togather after vacuumizing 10～20 minutes under the vacuum environment of 0.1MPa, (42 ℃ are incubated 8 hours configuring temperature curve, rose to 75 ℃ through 6 hours, in 3 hours, rise to 100 ℃, be incubated 2 hours then, reduced to 70 ℃ through 1 hour) the computer control stove in behind the thermoset forming, through the demoulding, cut edge, clean, after the assay was approved, just having made refractive index is the two light half highly finished product eyeglasses of 1.60 ultrathin brown polarizing optical resin flat-tops.
Claims (4)
1, the manufacture method of super slight type polarizing optical resin lens comprises the steps:
1) glass optical mould and the preparation of moulding circle;
2) light polarizing film is standby after the assay was approved through press-bending, typing, surface treatment, shearing;
3) the inclined to one side film of the work of handling well and mould one are reinstated moulded circle matched moulds location;
4) mixed good optical resin monomer is injected the mould that gets togather, make qualified products through curing polymerization, the demoulding, side cut, cleaning, check successively;
It is characterized in that:
1) the described circle of moulding is the thermoplastic rubber elastomer, and moulds the band strong point in the loop-shaped;
2) the glass mold punching press is adopted in the press-bending of described light polarizing film, and its curvature is consistent with the optical glass mould that matched moulds is used;
3) surface treatment of described light polarizing film comprise cleaning, drying, destatic, gluing, selected adhesive is a polyurethane series adhesive;
4) described optical resin monomer is high refractive optics resin monomer.
2, according to the manufacture method of the described super slight type polarizing optical resin lens of claim 1, it is characterized in that: the temperature control curve in the described polymerization process is as follows: 42 ℃ are incubated 8～10 hours, rose to 70～75 ℃ through 4～8 hours, in 1～3 hour, rise to 95～100 ℃, be incubated 1～3 hour then, reduced to 60～70 ℃ through 1 hour, totally 15～25 hours.
3, according to the manufacture method of claim 1 or 2 described super slight type polarizing optical resin lens, it is characterized in that: in solidifying polymerization process, adopt dual initiator to reduce polymerization rate.
4, according to the manufacture method of the described super slight type polarizing optical resin lens of claim 1, it is characterized in that: the refractive index of described high refractive optics resin monomer is more than 1.60.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200710093819 CN101058232A (en) | 2007-05-23 | 2007-05-23 | Method for manufacturing super slight type polarizing optical resin lens |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200710093819 CN101058232A (en) | 2007-05-23 | 2007-05-23 | Method for manufacturing super slight type polarizing optical resin lens |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101058232A true CN101058232A (en) | 2007-10-24 |
Family
ID=38864609
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200710093819 Pending CN101058232A (en) | 2007-05-23 | 2007-05-23 | Method for manufacturing super slight type polarizing optical resin lens |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101058232A (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102967949A (en) * | 2012-06-20 | 2013-03-13 | 毛林塘 | Ultra-thin polarized lens and its die |
| CN101868510B (en) * | 2007-12-28 | 2013-03-13 | 第一毛织株式会社 | Polarizing film comprising antistatic coating layer |
| CN103189190A (en) * | 2010-07-30 | 2013-07-03 | 库柏维景国际控股公司 | Ophthalmic lens molds, ophthalmic lenses molded therein, and related methods |
| CN104105997A (en) * | 2012-02-07 | 2014-10-15 | 豪雅光学制造菲律宾公司 | Polarized plastic lens for glasses and method for manufacturing polarized plastics lens for glasses |
| CN105204184A (en) * | 2015-10-12 | 2015-12-30 | 欧阳诚 | Manufacturing method of tempered glass resin polarized glasses |
| CN105404023A (en) * | 2014-09-12 | 2016-03-16 | 季叶俊 | Polarization light resin lens production process |
| CN107225782A (en) * | 2008-09-29 | 2017-10-03 | 庄臣及庄臣视力保护公司 | The method for forming energization Ophthalmoligic instrument |
| CN107346063A (en) * | 2017-07-31 | 2017-11-14 | 江苏淘镜有限公司 | A kind of processing technology of superhard polarized lenses |
| CN108749048A (en) * | 2018-06-05 | 2018-11-06 | 上海希尔康光学眼镜有限公司 | The production technology of polarizing resin lens |
-
2007
- 2007-05-23 CN CN 200710093819 patent/CN101058232A/en active Pending
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101868510B (en) * | 2007-12-28 | 2013-03-13 | 第一毛织株式会社 | Polarizing film comprising antistatic coating layer |
| CN107225782A (en) * | 2008-09-29 | 2017-10-03 | 庄臣及庄臣视力保护公司 | The method for forming energization Ophthalmoligic instrument |
| CN103189190A (en) * | 2010-07-30 | 2013-07-03 | 库柏维景国际控股公司 | Ophthalmic lens molds, ophthalmic lenses molded therein, and related methods |
| CN103189190B (en) * | 2010-07-30 | 2015-11-25 | 库柏维景国际控股公司 | Ophthalmic lens mold, wherein molded ophthalmic lens and correlation technique |
| CN104105997A (en) * | 2012-02-07 | 2014-10-15 | 豪雅光学制造菲律宾公司 | Polarized plastic lens for glasses and method for manufacturing polarized plastics lens for glasses |
| CN104105997B (en) * | 2012-02-07 | 2016-07-20 | Ehs透镜菲律宾股份有限公司 | The glasses manufacture method of polarization glass lens and glasses polarization glass lens |
| CN102967949A (en) * | 2012-06-20 | 2013-03-13 | 毛林塘 | Ultra-thin polarized lens and its die |
| CN105404023A (en) * | 2014-09-12 | 2016-03-16 | 季叶俊 | Polarization light resin lens production process |
| CN105204184A (en) * | 2015-10-12 | 2015-12-30 | 欧阳诚 | Manufacturing method of tempered glass resin polarized glasses |
| CN105204184B (en) * | 2015-10-12 | 2018-02-27 | 欧阳诚 | A kind of preparation method of safety glass resin polaroid glasses |
| CN107346063A (en) * | 2017-07-31 | 2017-11-14 | 江苏淘镜有限公司 | A kind of processing technology of superhard polarized lenses |
| CN108749048A (en) * | 2018-06-05 | 2018-11-06 | 上海希尔康光学眼镜有限公司 | The production technology of polarizing resin lens |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101058232A (en) | Method for manufacturing super slight type polarizing optical resin lens | |
| JP4840894B2 (en) | Polarizing molded body and method for producing the same | |
| CN102169241B (en) | 1 order type polaroid glasses | |
| US20100033675A1 (en) | Polarizing Lens and Method of Its Manufacture | |
| CN1143926A (en) | Method and apparatus for manufacturing composite lenses | |
| WO2006040954A1 (en) | Protective film for polarizing film and polarizing multilayer body | |
| JP2010037470A (en) | Optical material composition and optical element using the same | |
| EP2581782A1 (en) | Polarizing lens constituted of aromatic polycarbonate | |
| US20230305210A1 (en) | Optical Assembly | |
| CN112204440A (en) | Polarizing film, method for molding polarizing film, and method for producing polarizing lens | |
| CN101726764A (en) | Polarized lens and method for manufacturing same | |
| CN1715980A (en) | Aspherical lens and manufacture method thereof | |
| JP5065511B2 (en) | Polarizing molded body and method for producing the same | |
| US7790071B2 (en) | Ceramic hybrid lens and method for manufacturing the same | |
| CN1844958A (en) | Aspherical diffraction optical lens | |
| TWI704041B (en) | Method for manufacturing sunglasses lens and sunglasses lens | |
| JP2011001395A (en) | Composite optical element | |
| JP2009102539A (en) | Polymerizable resin composition and optical element using it | |
| CN103085297B (en) | The manufacture method of polarized lenses and the structure of the polarized lenses | |
| CN101067685A (en) | Method for producing photochromic optical resin lens by thin-film method | |
| CN1924641A (en) | Process for preparing composite photochromic optical resin lens | |
| CN2836046Y (en) | Composite structure of polarized lens | |
| CN201233450Y (en) | Photochromic polarization sunglass | |
| RU2005116316A (en) | METHOD FOR PRODUCING A HYBRID ASPHERIC LENS | |
| CN212515256U (en) | Progressive multifocal lens set |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |
Open date: 20071024 |