CN101007710A - Method for manufacturing glass substrate for display and glass substrate - Google Patents

Method for manufacturing glass substrate for display and glass substrate Download PDF

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Publication number
CN101007710A
CN101007710A CNA2006100798695A CN200610079869A CN101007710A CN 101007710 A CN101007710 A CN 101007710A CN A2006100798695 A CNA2006100798695 A CN A2006100798695A CN 200610079869 A CN200610079869 A CN 200610079869A CN 101007710 A CN101007710 A CN 101007710A
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China
Prior art keywords
glass substrate
coating agent
defective
recessed
recessed defective
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CNA2006100798695A
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Chinese (zh)
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CN101007710B (en
Inventor
西山智弘
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SAISAN STAINLESS CHEMICAL CO Ltd
Nishiyama Stainless Chemical Co Ltd
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SAISAN STAINLESS CHEMICAL CO Ltd
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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C15/00Surface treatment of glass, not in the form of fibres or filaments, by etching
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2218/00Methods for coating glass
    • C03C2218/30Aspects of methods for coating glass not covered above
    • C03C2218/32After-treatment
    • C03C2218/328Partly or completely removing a coating
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/133302Rigid substrates, e.g. inorganic substrates

Abstract

The invention relates to a method for manufacturing glass basal plates of flat panel display, including following steps: chemical polishing glass basal plates (ST2) of flat panel display by a aqueous solution containing hydrofluoric acid; checking the chemical polished glass basal plates to discover whether exist incurvated defect having maximum diameter between 50 to 200 mum, detecting the glass basal plates (ST3) having this kind of incurvated defect; coating a first coating agent on the incurvated defect (ST11) of the faulted glass basal plates; coating a second coating agent on the incurvated defect coated the first coating agent until the second coating agent overflow from the incurvated defect (ST12); curing the second coating agent (ST14); only removing cured the second coating agent extruded on surface of the glass basal plates (ST16) to flatten surface thereof. The manufacturing method allows produce high quality glass basal plates of flat panel display with high efficiency.

Description

Be used to make the method and the glass substrate of the glass substrate that indicating meter uses
Technical field
The present invention relates to a kind of method that is used to make glass basal plates of flat panel display, in particular for make the method for high quality glass substrate with high qualification rate.
Background technology
The use of term " flat-panel monitor " (below be abbreviated as FPD) is with respect to the indicating meter with curved surface display panel, for example the cathode ray tube (CRT) indicating meter.The principal character of flat-panel monitor comprises the thin degree of depth, little floor space (footprint) and flat display board.This flat-panel monitor is particularly useful as and is liquid-crystal display, plasma display, OLED display etc.In these flat-panel monitors, liquid-crystal display not only is widely used for televisor especially, and is widely used as especially and is indicating meter portable phone or computer equipment.
Fig. 2 is the cross-sectional view of the typical display panel PN of liquid-crystal display.As shown in Figure 2, display panel has a kind of structure, and liquid crystal LC places between a pair of first and second glass substrates 1 and 2 laminated together in this structure.
On the internal surface of first glass substrate 1, the color filter 4, the supercoat 5 that is used to cover black matrix 3 and color filter 4, transparency electrode 6A and the oriented film 7A that were opened in 3 minutes by black matrix (Black Matrix) pile up in this order.On the internal surface of second glass substrate, be provided with thin film transistor 8 and transparency electrode 6B, also be provided with oriented film 7B thereon.
Usually, this have as shown in Figure 2 that the display panel PN of structure makes as follows.First glass substrate 1 and second glass substrate 2 are laminated together in such a way, make a plurality of partitions be arranged between oriented film 7A respect to one another and the 7B, are the space of about 3 to 6 μ m so that thickness to be provided to liquid crystal.Then, liquid crystal LC is expelled in the space between glass substrate 1 and 2 by vacuum take-off.At last, on the corresponding outside surface that is attached to glass substrate 1 and 2 of light polarizing film 10A and 10B.
Nearest situation is, each glass substrate 1 and 2 thickness drop to lowest limit.Particularly have the first and second glass substrate GL1 of a plurality of display panels zone PN-PN and GL2 laminated together obtaining laminated glass substrate GL, and the neighboring of laminated glass substrate GL closely seal.Then laminated glass substrate GL is immersed in the bag aqueous hydrofluoric acid containing solution, to reduce the thickness (see figure 3) of laminated glass substrate GL by chemical rightenning.By using chemical polishing not only may make a plurality of display panel PN simultaneously but also may boost productivity, because the polishing velocity of chemical rightenning is than the speed height of mechanical polishing.Also the thickness of laminated glass substrate GL may be reduced to its lowest limit in addition, this may satisfy the thickness that reduces display panel PN and the requirement of weight.
After finishing chemical rightenning, laminated glass substrate GL cuts into the display panel PN that is separated from each other.Each display panel PN is through the process of injection liquid crystal and the process of subsides light polarizing film then.It should be noted that the display panel that yet existence does not have light polarizing film.
As mentioned above, by making laminated glass substrate GL, may effectively the thickness of laminated glass substrate GL be decreased to its lowest limit through chemical rightenning.But this method has caused some arguements that need further investigate.
For example when glass substrate by chemical rightenning when reducing its thickness, being present in the extremely small defective in the glass substrate or the part of change potentially obviously becomes a defective (hereinafter referred to as " etching defect ") because of chemical rightenning becomes.This etching defect can be eliminated by continuing the chemical rightenning glass substrate.But when glass substrate can not continue chemical rightenning when allow eliminating the degree of etching defect, etching defect keeps as a visible defects.More specifically, from the orthographic plan that the front of the residual body of glass substrate is seen, measure, have the etching defect that maximum diameter is approximately 50 to 2000 μ m.This etching defect is the defective that is recessed into, and it is level and smooth relatively and has basically circular or avette shape because of it has been subjected to etching.
In addition, even glass substrate does not have recessed defective after finishing chemical rightenning, so also might be because for example other recessed defectives (hereinafter referred to as " non-etching defect ") of crackle appear in the cuttings of carrying out after chemical rightenning etc.This non-etching defect is rough and does not have circular shape because of it is not subjected to etching.Therefore, the internal surface of non-etching defect has sharp irregularity.
This recessed defective that is formed on the glass baseplate surface detects in the quality test step.In this step, if there is the glass substrate of recessed defective to be removed, productivity obviously worsens so, means the display panel of removing costliness because remove the glass substrate of recessed defective.If but there is the glass substrate of recessed defective to use as usual, be presented at the quality deteriorated of the image on the screen so.Especially, deterioration of image is fatal shortcoming for the portable phone of closely observing or the display panel of PC.Most of obvious defects that become after finishing chemical rightenning all were potential before chemical rightenning.Therefore can not just handle the problem of latent defect effectively by before chemical rightenning, only carrying out quality test, and be too high expectation by adopting the recessed defective of some method reparation that imperfect glass substrate is transformed into unblemished glass substrate.
Some approach can be used for repairing recessed defective.A kind of approach is to make imperfect glass substrate through mechanical polishing.But problem is a polished glass substrate at a high speed because the thickness of glass substrate be reduced to its lowest limit and a plurality of partition be arranged on glass substrate laminated together between, therefore significantly worsen productivity.In fact usually further a surface of mechanical polishing glass substrate needs about 60 minutes with the thickness that reduces by 30 μ m.Even glass substrate is with so low speed polishing in addition, about 20% glass substrate breaks during polishing.Therefore, it is not too high imperfect glass substrate to be transformed into the ratio of unblemished glass substrate.
Another approach is to fill out appropriate filler (tackiness agent) to recessed defective.Under the situation of non-etching defect, it is relatively easy allowing filler be attached to securely on the glass substrate.But under the situation of the etching defect that has wide opening because of chemical rightenning, if filler is normally used filler, the adhesion between filler and glass substrate is very poor so.For example under the situation that is necessary light polarizing film and glass substrate separated and light polarizing film is attached to again on the glass substrate, worry that the filler of filling out in etching defect is easy to peel off from glass substrate, because etching defect has wide opening.Also worry in addition complete operation for example grinding during peel off filler from glass substrate.This is because be necessary to make the smooth surface of filling out the filler in recessed defective to arrive and the consistent degree of glass baseplate surface that centers on this recessed defective.
Above-mentioned these problems are not inherent in liquid-crystal display, are general character with other flat-panel monitors still.
Summary of the invention
Therefore the purpose of this invention is to provide a kind of method and a kind of high-quality glass substrate that is used for making the high-quality glass substrate that flat-panel monitor uses with high productivity.In order to solve above-mentioned purpose, the present invention relates to a kind of method that is used to make glass basal plates of flat panel display, this method may further comprise the steps: the glass substrate that is used for flat-panel monitor with a kind of chemistry of aqueous solution polishing that comprises hydrofluoric acid; Check is by the glass substrate of chemical rightenning, to find whether have the recessed defective that maximum diameter is 50 to 2000 μ m, to detect the imperfect glass substrate of this recessed defective; A kind of first coating agent is applied on the described recessed defective that the shortcoming glass substrate arranged; A kind of second coating agent is applied on the recessed defective that has applied described first coating agent, makes second coating agent overflow recessed defective; Second coating agent hardens; Make the surfacing of glass substrate by only removing second coating agent of hardened that protrudes in glass baseplate surface.
In the present invention, when second coating agent has hardened, it is used from the effect of the filler of filling recessed defective.Therefore, the amount that need be applied to first coating agent of recessed defective is restricted to a minimum, to such an extent as to but second coating agent is applied in the recessed defective and overflows recessed defective.Especially, second coating agent is applied in the recessed defective with enough amounts, even so that also protrude in the surface of glass substrate when shrinking because of sclerosis in second coating agent.It should be noted that and select first and second coating agents to make that their specific refractory power and transmissivity is substantially the same in the specific refractory power and the transmissivity of glass substrate when they harden.
In smooth treatment step, hardened second coating agent that protrudes in glass baseplate surface is removed with smooth glass substrate.Therefore, be applied to the perfect surface that can there be the mirror surface type that is similar to glass baseplate surface second coating agent that is recessed into defective.Consequently, imperfect laminated glass substrate transfer becomes unblemished laminated glass substrate.In addition, smooth processing preferably by with artificiallies such as perching knives the unnecessary portions of second coating agent being struck off from glass substrate, is perhaps only cut second coating agent by the electricity consumption scraper.It should be noted that a kind of method in back obtain smooth more outstanding than preceding a kind of method aspect perfect surperficial.
Under the situation of using perching knife, the whole edge of perching knife is pressed against on the glass substrate with the angle about 25 to 35 ° with respect to glass substrate, so that about load of 0.7 to 1.0kg is applied on the glass substrate, and push away forward then to strike off the unnecessary portions of second coating agent from glass substrate.On the other hand, make under the situation of electrical appliance, this electrical equipment is pressed against on the glass substrate with the angle with respect to 30 to 40 ° of glass substrates, so that 0.2kg or cutting loading still less are applied on the glass substrate, and promotes not cause only to cut second coating agent infringement to glass substrate then.
If too big in the recessed defective that produces on glass baseplate surface during the chemical rightenning, effect so of the present invention reduces by half.Therefore, the maximum diameter of recessed defective preferably is controlled at 2000 μ m or littler.Especially, the control of the maximum diameter of recessed defective can be carried out effectively by a kind of method (a) and/or a kind of method (b), in method (a), before chemical rightenning, remove the potential defective during in preset thickness by the mechanical polishing glass substrate, in method (b), the chemical rightenning amount of glass substrate is restricted.On the other hand, maximum diameter can keep motionless less than the recessed defective of 50 μ m, because it sees harmful effect from angle of practice.In the present invention, the recessed defective of need considering not only comprises the etching defect that comes from the tiny flaw that had been present in the glass substrate and has enlarged by chemical rightenning before chemical rightenning, and comprises the non-etching defect that produces by the operation of carrying out after chemical rightenning.
In addition in the present invention, can carry out chemical rightenning by using two kinds of polishing solutions different on composition.In this case, for example, glass substrate polishes with 1 μ m/sec or higher speed with first polishing solution, polishes with the low rate of 0.5 to 20 μ m/min with second polishing solution then.By doing like this, may suppress maximum diameter to the 100 μ m of the recessed defective (etching defect) that produces by chemical rightenning or bigger effectively, but less than 300 μ m (preferred 100 μ m or bigger, but less than 200 μ m).
First polishing solution is a kind of hydrofluoric acid and vitriolic aqueous solution of comprising.The concentration of the hydrofluoric acid in first polishing solution is preferably 10 to 30wt%, and more preferably 15 to 28wt%, also more preferably 17 to 25wt%.Vitriolic concentration in first polishing solution is preferably 20 to 50wt%, and more preferably 30 to 45wt%, also more preferably 35 to 42wt%.The time that glass baseplate surface is contacted with first polishing solution is preferably one minute or still less.As mentioned above, be 1 μ m/sec or bigger with the polishing speed of first polishing solution, but be preferably 3 to 10 μ m/sec, more preferably 5 to 8 μ m/sec.
On the other hand, second polishing solution is the aqueous solution of a kind of 10wt% of comprising or hydrofluoric acid still less.Second polishing solution preferably also comprises one or both or more kinds of mineral acid and tensio-active agent except hydrofluoric acid.Representative examples of mineral pigments comprises hydrochloric acid, nitric acid, sulfuric acid and phosphoric acid.The example of this tensio-active agent comprises the tensio-active agent of tensio-active agent, the phenolic group of ester group, (amine-based) tensio-active agent of amino (amide-based) tensio-active agent, the tensio-active agent of ether, non-ionic tensio-active agent and amido.As mentioned above, be 0.5 to 20 μ m/min with the polishing speed of second polishing solution, but preferred 0.5 to 10 μ m/min.
First coating agent is not limited especially, but preferred a kind of adhering priming paint that is used to improve between the glass substrate and second coating agent.The opening of etching defect has enlarged by chemical rightenning and the filler that therefore is used to fill this recessed defective may peel off from glass substrate.Therefore, priming paint is effective especially as first coating agent.A kind of silane couplent (silanecoupling agent) that comprises is preferred the use as the priming paint of the silylation of main component.
A kind of hardenable resin is used as second coating agent.In order to prevent the scalloping on the display screen, methacrylic resin or acrylic resin with specific refractory power identical with transmissivity with the specific refractory power of glass substrate basically after its sclerosis and transmissivity are preferred the uses.This hardenable resin can for example be the thermosetting type or photohardenable type, but the photohardenable type of preferred use.Especially, preferably use a kind of UV cured tackiness agent.In UV cured tackiness agent, the anaerobic sclerosis type that requirement lacks air is preferred especially the use, but also can use only by the UV cured type of ultraviolet energy hardened.
As mentioned above, according to the present invention, may produce the high quality glass substrate that is used for flat-panel monitor with high productivity.In addition, when repairing glass substrate, or not the mechanical polishing glass substrate, therefore reduced the time and the expense of repairing.In addition, this restorative procedure can not cause the damage of glass substrate, therefore realizes 100% zero defect rate basically.
Description of drawings
Figure 1A is used to make the schema of the method for liquid-crystal display;
Figure 1B repairs the detail flowchart of the step of glass substrate;
The cross-sectional view of the display panel of Fig. 2 liquid-crystal display;
The synoptic diagram of Fig. 3 laminated glass substrate;
Fig. 4 A and 4B are used to explain the legend of the step of smooth glass substrate;
Fig. 5 repairs the schema of step of the change of glass substrate.
Embodiment
Describe the present invention in detail below by the reference preferred embodiment.Figure 1A is the schema that a demonstration is used to make the method for liquid-crystal display, and Figure 1B is the detail flowchart of the step of a reparation glass substrate.
The display panel PN of Huo Deing has identical as shown in Figure 2 structure at last.But in the step ST1 of laminated glass substrate shown in Figure 1, a plurality of half-finished display panel PN...PN for example are arranged to a matrix (see figure 3) on the laminated glass substrate GL of 730mm * 920mm a size.
Especially in this state, each display panel PN is a work in-process display panel, it does not have to place the liquid crystal LC between glass substrate GL1 and the glass substrate GL2 in step ST6, and does not have to be attached to respectively in step ST7 light polarizing film 10A and 10B on glass substrate GL1 and the GL2.At glass substrate GL1 with GL2 is laminated together and after obtaining a laminated glass substrate GL, the periphery of laminated glass substrate GL seals with an acid proof sealing agent.
Then, laminated glass substrate GL is immersed in the bag aqueous hydrofluoric acid containing solution with the outside surface (ST2) of chemical rightenning glass substrate GL1 and GL2.The whole thickness of laminated glass substrate GL is approximately 0.6mm, 0.8mm or 1.0mm.About 50 to the 300 μ m of the polished reduction thickness of each glass substrate GL1 and GL2 (the whole thickness of laminated glass substrate GL reduces by 100 to 600 μ m).At this moment, above-mentioned first and second polishing solutions preferably use by this requirement.
In the step of chemical rightenning, must reduce the thickness of each glass substrate GL1 and GL2, keep the smooth of these glass substrates simultaneously.Therefore, preferred bubble constantly forms to produce polishing solution in the bottom in polishing pond and upwards flows.In addition also preferably, polishing solution constantly overflows the polishing pond to get rid of reaction product by filtering.Perhaps, polishing solution upgraded wholly or in part in the appropriate time.
Carried out chemical rightenning in the above described manner but both made, because the chemical rightenning of glass substrate, the latent defect that was present in originally in glass substrate GL1 and the GL2 is tending towards enlarging.Therefore the degree of depth that depends on this latent defect, latent defect may become and become obviously that maximum diameter is arranged is the recessed defective of 50 to 2000 μ m after finishing chemical rightenning.
This recessed defective has a circle or an oval in shape basically in orthographic plan, and they are separated from each other or are connected with each other.In either case, carry out chemical rightenning by adopting above-mentioned this preferable methods, the maximum diameter of recessed defective is less than 2000 μ m.The maximum diameter that it should be noted that recessed defective is measured the orthographic plan of seeing from the front of glass substrate, and when recessed defective was connected with each other, the maximum diameter of recessed defective was meant the wherein maximum diameter of the supposition of each recessed defective.
After finishing the step ST2 of chemical rightenning, laminated glass substrate GL (see figure 3) stands cutting and separation steps ST3 then.In cutting and separation steps, the half-finished display panel PN-PN that is arranged to matrix form is separated from each other by cutting.Link to each other preferably therewith, before chemical rightenning, line mechanically is arranged on the laminated glass substrate GL along the separation line between the display panel (being represented by the dotted line among Fig. 3).By such work, make to be separated from each other display panel by cutting and to become easy.In this case, by chemical rightenning in step ST2, compare with other parts, the part that mechanically has been provided with line is etched darker, therefore forms groove.Therefore, in cutting and separation steps ST3,, make each display panel PN cut down from laminated glass substrate GL along described groove by only mechanically applying appropriate load to laminated glass substrate GL.In addition, the cutting surface of each display panel PN is slick, because etching has been stood on the cutting surface.
After finishing cutting and separation steps ST3, the step ST4 that stands quality tests of display panel then.In this step, except that typical quality test, also check each half-finished display panel PN to find that whether having maximum diameter is the recessed defective of 50 to 2000 μ m.If the display panel of this recessed defective is arranged, this display panel stands to repair the step ST5 of glass substrate so.
Shown in Figure 1B, in the step of repairing glass substrate, at first use for example surperficial ST10 of ethanol cleaning glass substrate.Then, contaminate a kind of priming paint to cotton swab, this priming paint is first coating agent, and cotton swab pushes and brush wiping facing to recessed defective, this priming paint is applied to this recessed defective ST11.It should be noted that the time of pushing cotton swab facing to recessed defective is about 30 seconds, this can not damage workability.
Then, a kind of anaerobic UV cured resin as second coating agent is applied to recessed defective ST12.Especially, with small suction pipe etc. a kind of anaerobic UV cured resin being applied to recessed defective makes and overflows recessed defective.It should be noted that UV cured resin capacity is applied to recessed defective, even after UV cured resin shrinks owing to sclerosis, also can be outstanding from the surface of glass substrate.
As mentioned above, because anaerobic ultraviolet hardening resin uses in the present embodiment, after completing steps ST12, shield mask is laminated to is used for degasification on second coating agent.At this moment, shield mask is laminated on second coating agent in the mode that bubble can not be trapped in second coating agent.As a kind of shield mask that is used, a kind of ultraviolet polypropylene (PP) film that sees through is preferred the use.
After finishing above-mentioned preparation, use the ultraviolet ray of launching to shine the second coating agent ST14 via shield mask from hand-held UV cured unit.It should be noted that the amount of uviolizing and the size and the degree of depth that the recessed defective that will be repaired is depended in the variation of time, but by about 3 to 4 minutes second coating agents that can harden of uviolizing with 200 to 450mJ intensity.Therefore, do not consuming second coating agent that to harden glossily in the so many time.
, shield mask from second coating agent removed (ST15), and carry out smooth step ST16 then thereafter.Because hardened second coating agent is outstanding from the surface of glass substrate, so in this step, use perching knife 20 or electricity to cut off cutter 30 smooth glass substrates.
Under the situation of using perching knife 20, the whole edge of perching knife 20 is pressed against on the glass substrate GL with the angle about 25 to 35 ° with respect to glass substrate GL, so that 0.7 to 1.0kg load is applied on the glass substrate GL, and push away forward then to strike off projection 40 (seeing Fig. 4 A).On the other hand, under the situation that makes electricity consumption scraper 30, scraper is pressed against on the glass substrate GL with the angle with respect to GL30 to 40 ° of glass substrate, so that 0.2kg or cutting loading still less are applied on the glass substrate GL, and spurs then with only excision projection 40 (seeing Fig. 4 B).
Finish smooth after, with the surface (ST17) of cleaning such as ethanol, to finish the step of repairing glass substrate around the glass substrate GL of restoring area.Thereafter, liquid crystal LC is expelled in the display panel PN of reparation (ST16), and then light polarizing film 10A and 10B correspondingly is attached to front surface and the rear surface of display panel PN.By light polarizing film being attached on the display panel PN, it is possible fully covering the zone of having repaired.Even needing for some reason light polarizing film from the display panel under the isolating situation, needn't worry that also second coating agent can peel off from glass substrate, because first coating agent and second coating agent are layered in the recessed defective, therefore improved the adhesivity between the glass substrate and second coating agent.
The above-mentioned schedule of operation of describing in detail with reference to figure 1 only is illustrative, and does not mean that the qualification invention scope.For example, under the situation of unnecessary creation anaerobism condition, step ST13 and ST15 omit naturally.
In addition, second coating agent needn't once be applied to recessed defective.For example, be that second coating agent preferably is applied to so recessed defective more than twice ground under the situation of 200 to 300 μ m or bigger relatively large recessed defective at maximum diameter.
Fig. 5 shows the schema that applies the schedule of operation of second coating agent more than twice ground.Especially, after first coating agent was applied to recessed defective, second coating agent is applied to recessed defective so that recessed defective is filled up (ST20) with second coating agent basically.In case of necessity, cover second coating agent with shield mask.Then, with uviolizing second coating agent.In this case, the amount of uviolizing and time are set so that second coating agent hardens into gel state.With shield mask cover the situation of second coating agent under, remove shield mask thereafter.In addition, under second coating agent is present in situation around the recessed defective, strike off with perching knife etc.
Then, to such an extent as to further being applied to recessed defective, second coating agent overflows recessed defective (ST22).In case of necessity, cover second coating agent with shield mask.Use uviolizing second coating agent then.In this case, the amount of uviolizing and time are set so that finally be applied to second coating agent of recessed defective and fully harden.As a result, be applied to further sclerosis the in second coating agent of recessed defective for the first time so that the adhesivity between second coating agent and glass substrate further improves.Thereafter, shown in Figure 1B, carry out smooth.
As above-mentioned, be applied under the situation of recessed defective more than twice ground in second coating agent, and under the situation of carrying out step ST5 according to schema shown in Figure 1B, to compare, the adhesivity between second coating agent and glass substrate further improves.Therefore, even be not attached in light polarizing film under the situation on surface of glass substrate, recessed defective is fully covered.

Claims (9)

1. method that is used to make glass basal plates of flat panel display, this method may further comprise the steps:
With a kind of chemistry of aqueous solution polishing glass basal plates of flat panel display that comprises hydrofluoric acid;
Check is by the glass substrate of chemical rightenning, to find whether have the recessed defective that maximum diameter is 50 to 2000 μ m, to detect the imperfect glass substrate of this recessed defective;
A kind of first coating agent is applied on the described recessed defective that the shortcoming glass substrate arranged;
A kind of second coating agent is applied on the recessed defective that has applied described first coating agent, makes second coating agent overflow recessed defective;
Second coating agent hardens;
Make the surfacing of glass substrate by only removing second coating agent that protrudes in glass baseplate surface.
2. by the manufacture method of claim 1, also comprise light polarizing film is attached to step on the glass substrate that passes through planarization step.
3. press the manufacture method of claim 1 or 2, it is characterized in that: described glass substrate is a laminated glass substrate, a matrix is arranged in a plurality of display panels zone therein, and cutting lamination glass substrate carried out before the step of check glass substrate with the step that the display panel zone is separated from each other.
4. by each manufacture method of claim 1 to 3, it is characterized in that: only second coating agent is mechanically ground off in the step of smooth glass substrate.
5. by each manufacture method of claim 1 to 4, it is characterized in that: first coating agent is that a kind of adhering priming paint and second coating agent that is used to improve between the glass substrate and second coating agent is a kind of photohardenable tackiness agent.
6. by each manufacture method of claim 1 to 5, it is characterized in that: when second coating agent harden in cure step with a kind of covering material covering of light-permeable.
7. by each manufacture method of claim 1 to 6, it is characterized in that: the step that applies second coating agent further comprises the steps:
A kind of second coating agent is applied on the recessed defective that has applied described first coating agent in advance, makes second coating agent not overflow recessed defective;
Second coating agent is applied on the female defective before hardening fully being applied to second coating agent on the recessed defective in advance at last, makes second coating agent overflow this recessed defective.
8. the glass substrate by making by each method of claim 1 to 7.
9. with the flat-panel monitor of making by the glass substrate of claim 8.
CN2006100798695A 2006-01-25 2006-05-15 Method for manufacturing glass substrate for display and glass substrate Expired - Fee Related CN101007710B (en)

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JP2006-015968 2006-01-25
JP2006015968 2006-01-25
JP2006015968A JP2007197236A (en) 2006-01-25 2006-01-25 Method for manufacturing glass substrate for display and glass substrate

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CN101007710A true CN101007710A (en) 2007-08-01
CN101007710B CN101007710B (en) 2012-05-23

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KR (1) KR100983856B1 (en)
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