CN1008745B - 生产热海绵铁的方法 - Google Patents
生产热海绵铁的方法Info
- Publication number
- CN1008745B CN1008745B CN87102213A CN87102213A CN1008745B CN 1008745 B CN1008745 B CN 1008745B CN 87102213 A CN87102213 A CN 87102213A CN 87102213 A CN87102213 A CN 87102213A CN 1008745 B CN1008745 B CN 1008745B
- Authority
- CN
- China
- Prior art keywords
- flow
- gas
- air
- reduction
- sponge iron
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title claims abstract description 126
- 229910052742 iron Inorganic materials 0.000 title claims abstract description 63
- 238000000034 method Methods 0.000 title claims abstract description 26
- 239000007789 gas Substances 0.000 claims abstract description 98
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 88
- 230000009467 reduction Effects 0.000 claims abstract description 52
- 238000005255 carburizing Methods 0.000 claims abstract description 27
- 239000003345 natural gas Substances 0.000 claims abstract description 15
- 230000002829 reductive effect Effects 0.000 claims abstract description 7
- 230000000153 supplemental effect Effects 0.000 claims abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
- 239000004215 Carbon black (E152) Substances 0.000 claims description 12
- 235000009508 confectionery Nutrition 0.000 claims description 12
- 229930195733 hydrocarbon Natural products 0.000 claims description 12
- 150000002430 hydrocarbons Chemical class 0.000 claims description 12
- 238000006243 chemical reaction Methods 0.000 claims description 9
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 8
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 8
- 239000001257 hydrogen Substances 0.000 claims description 8
- 229910052739 hydrogen Inorganic materials 0.000 claims description 8
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 6
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 5
- 235000011089 carbon dioxide Nutrition 0.000 claims 3
- 238000000629 steam reforming Methods 0.000 claims 1
- 238000001816 cooling Methods 0.000 description 13
- 239000000203 mixture Substances 0.000 description 12
- 239000000047 product Substances 0.000 description 12
- 238000004519 manufacturing process Methods 0.000 description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- 229910052799 carbon Inorganic materials 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 6
- 230000003134 recirculating effect Effects 0.000 description 5
- 238000003723 Smelting Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 229910000831 Steel Inorganic materials 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- -1 being methane) Chemical compound 0.000 description 2
- 238000000280 densification Methods 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 238000001465 metallisation Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000007670 refining Methods 0.000 description 2
- 230000004044 response Effects 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000013589 supplement Substances 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 229910001567 cementite Inorganic materials 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 239000000112 cooling gas Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 238000012432 intermediate storage Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000012495 reaction gas Substances 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 210000000952 spleen Anatomy 0.000 description 1
- 238000009687 sponge iron process Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B13/00—Making spongy iron or liquid steel, by direct processes
- C21B13/02—Making spongy iron or liquid steel, by direct processes in shaft furnaces
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B2100/00—Handling of exhaust gases produced during the manufacture of iron or steel
- C21B2100/20—Increasing the gas reduction potential of recycled exhaust gases
- C21B2100/26—Increasing the gas reduction potential of recycled exhaust gases by adding additional fuel in recirculation pipes
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B2100/00—Handling of exhaust gases produced during the manufacture of iron or steel
- C21B2100/20—Increasing the gas reduction potential of recycled exhaust gases
- C21B2100/28—Increasing the gas reduction potential of recycled exhaust gases by separation
- C21B2100/282—Increasing the gas reduction potential of recycled exhaust gases by separation of carbon dioxide
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B2100/00—Handling of exhaust gases produced during the manufacture of iron or steel
- C21B2100/60—Process control or energy utilisation in the manufacture of iron or steel
- C21B2100/64—Controlling the physical properties of the gas, e.g. pressure or temperature
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/10—Reduction of greenhouse gas [GHG] emissions
- Y02P10/122—Reduction of greenhouse gas [GHG] emissions by capturing or storing CO2
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/10—Reduction of greenhouse gas [GHG] emissions
- Y02P10/134—Reduction of greenhouse gas [GHG] emissions by avoiding CO2, e.g. using hydrogen
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/10—Reduction of greenhouse gas [GHG] emissions
- Y02P10/143—Reduction of greenhouse gas [GHG] emissions of methane [CH4]
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacture Of Iron (AREA)
- Manufacture And Refinement Of Metals (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/898,940 US4834792A (en) | 1986-08-21 | 1986-08-21 | Method for producing hot sponge iron by introducing hydrocarbon for carburizing into reduction zone |
| US898,940 | 1986-08-21 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN87102213A CN87102213A (zh) | 1988-03-16 |
| CN1008745B true CN1008745B (zh) | 1990-07-11 |
Family
ID=25410263
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN87102213A Expired CN1008745B (zh) | 1986-08-21 | 1987-03-20 | 生产热海绵铁的方法 |
Country Status (9)
Families Citing this family (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB9200423D0 (en) * | 1992-01-09 | 1992-02-26 | Cavanagh Patrick E | Direct steelmaking process |
| JPH0673384A (ja) * | 1992-05-07 | 1994-03-15 | Hylsa Sa | 有機物質をガス化するための方法および装置 |
| US5656044A (en) * | 1992-05-07 | 1997-08-12 | Hylsa S.A. De C.V. | Method and apparatus for gasification of organic materials |
| US5851246A (en) * | 1992-05-07 | 1998-12-22 | Hylsa, S.A. De C.V. | Apparatus for gasifying organic materials |
| US5387274A (en) * | 1993-11-15 | 1995-02-07 | C.V.G. Siderurgica Del Orinoco, C.A. | Process for the production of iron carbide |
| US5824134A (en) * | 1997-01-29 | 1998-10-20 | Powers; Jim | Direct reduction of iron ore utilizing organic hazardous materials |
| GB2342360B (en) * | 1998-08-03 | 2002-10-09 | Hatch Ass Ltd | Shaft furnace for direct reduction of iron bearing pellets or lump iron ore |
| IT1302811B1 (it) | 1998-12-11 | 2000-09-29 | Danieli & C Ohg Sp | Procedimento e relativo apparato per la riduzione direttadi ossidi di ferro |
| KR101235252B1 (ko) * | 2005-12-26 | 2013-02-20 | 주식회사 포스코 | 탄화수소 함유가스 취입에 의한 용철제조방법 및 이를이용한 용철제조장치 |
| EA022922B1 (ru) * | 2009-04-20 | 2016-03-31 | Мидрэкс Текнолоджиз, Инк. | Способ для секвестирования двуокиси углерода из топлива на основе колошникового газа |
| US8771638B2 (en) | 2009-04-20 | 2014-07-08 | Midrex Technologies, Inc. | Method and apparatus for sequestering carbon dioxide from a spent gas |
| KR101710560B1 (ko) | 2009-07-31 | 2017-02-27 | 에이치와이엘 테크놀로지즈, 에스.에이. 데 씨.브이. | 제한된 co2 방출로 직접 환원 철을 제조하기 위한 방법 |
| EP2744922B1 (en) | 2011-08-20 | 2020-07-01 | HYL Technologies, S.A. de C.V. | Process for producing direct reduced iron (dri) utilizing gases derived from coal |
| ITUD20120130A1 (it) * | 2012-07-18 | 2014-01-19 | Danieli Off Mecc | Apparato e metodo per la rimozione dello zolfo da un flusso di gas naturale da alimentare al reformer di un processo di riduzione diretta |
| ES2689779T3 (es) | 2012-09-14 | 2018-11-15 | Voestalpine Stahl Gmbh | Procedimiento para producir acero con energía renovable |
| US10065857B2 (en) | 2013-03-12 | 2018-09-04 | Midrex Technologies, Inc. | Systems and methods for generating carbon dioxide for use as a reforming oxidant in making syngas or reformed gas |
| CN104451017B (zh) * | 2014-11-28 | 2016-03-16 | 中冶赛迪工程技术股份有限公司 | 一种钒钛磁铁矿竖炉直接还原铁的渗碳工艺 |
| CN108474048B (zh) * | 2015-12-28 | 2021-02-23 | 伊尔技术有限公司 | 通过使用合成气来生产高碳dri的方法和系统 |
| CN108016854A (zh) * | 2017-12-01 | 2018-05-11 | 中冶焦耐(大连)工程技术有限公司 | 还原铁及残炭混合物料输送方法 |
| SE546651C2 (en) * | 2020-05-04 | 2025-01-07 | Hybrit Development Ab | Process for the production of carburized sponge iron |
| DE102020116425A1 (de) | 2020-06-22 | 2021-12-23 | Salzgitter Flachstahl Gmbh | Verfahren zur Herstellung von Rohstahl mit niedrigem N-Gehalt |
| SE545311C2 (en) * | 2020-11-25 | 2023-06-27 | Hybrit Development Ab | Process for the production of carburized sponge iron |
| DE102021122350A1 (de) * | 2021-08-30 | 2023-03-02 | Thyssenkrupp Steel Europe Ag | Verfahren zur Herstellung einer Eisenschmelze |
| CN115652012B (zh) * | 2022-09-08 | 2024-05-07 | 中冶赛迪工程技术股份有限公司 | 一种氢基竖炉产海绵铁的渗碳冷却与煤气利用方法、系统及其应用 |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3749386A (en) * | 1971-07-01 | 1973-07-31 | Midland Ross Corp | Method and means for reducing iron oxides in a gaseous reduction process |
| US4046557A (en) * | 1975-09-08 | 1977-09-06 | Midrex Corporation | Method for producing metallic iron particles |
| US4054444A (en) * | 1975-09-22 | 1977-10-18 | Midrex Corporation | Method for controlling the carbon content of directly reduced iron |
| US4002422A (en) * | 1975-09-22 | 1977-01-11 | Midrex Corporation | Packed bed heat exchanger |
| JPS5847449B2 (ja) * | 1978-04-10 | 1983-10-22 | 株式会社神戸製鋼所 | 直接製鉄法 |
| GB2064590B (en) * | 1979-09-13 | 1984-07-25 | Kobe Steel Ltd | Gas reduction of iron oxide |
| US4270739A (en) * | 1979-10-22 | 1981-06-02 | Midrex Corporation | Apparatus for direct reduction of iron using high sulfur gas |
| GB2084610B (en) * | 1980-09-29 | 1983-10-12 | Woods Jack L | Anodic oxidation of aluminium and aluminum alloys |
| US4584016A (en) * | 1982-03-23 | 1986-04-22 | Hylsa, S.A. | Method for controlling metallization and carburization in the reduction of metal ores to sponge iron |
| US4439233A (en) * | 1983-05-09 | 1984-03-27 | Midrex Corporation | Direct reduction of iron |
| US4556417A (en) * | 1983-05-17 | 1985-12-03 | Hylsa, S.A. | Process for the direct reduction of iron ores |
| AT382166B (de) * | 1985-05-13 | 1987-01-26 | Voest Alpine Ag | Verfahren zur direktreduktion von teilchenf¯rmigem eisenoxidhaeltigem material |
| US4702766A (en) * | 1986-03-21 | 1987-10-27 | Midrex International, B.V. Rotterdam, Zurich Branch | Method of increasing carbon content of direct reduced iron and apparatus |
| US4752329A (en) * | 1986-03-21 | 1988-06-21 | Midrex International B.V. Rotterdam, Zurich Branch | Apparatus and method for increasing carbon content of hot directly reduced iron |
-
1986
- 1986-08-21 US US06/898,940 patent/US4834792A/en not_active Expired - Lifetime
-
1987
- 1987-03-20 CN CN87102213A patent/CN1008745B/zh not_active Expired
- 1987-07-29 MY MYPI87001171A patent/MY101772A/en unknown
- 1987-08-03 IN IN555/MAS/87A patent/IN169940B/en unknown
- 1987-08-11 DE DE8787111607T patent/DE3777515D1/de not_active Expired - Lifetime
- 1987-08-11 EP EP87111607A patent/EP0262353B1/en not_active Expired - Lifetime
- 1987-08-18 BR BR8704259A patent/BR8704259A/pt not_active IP Right Cessation
- 1987-08-20 MX MX7825A patent/MX164807B/es unknown
- 1987-08-21 JP JP62208066A patent/JPS63114913A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| BR8704259A (pt) | 1988-04-12 |
| DE3777515D1 (de) | 1992-04-23 |
| IN169940B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1992-01-11 |
| CN87102213A (zh) | 1988-03-16 |
| EP0262353B1 (en) | 1992-03-18 |
| EP0262353A1 (en) | 1988-04-06 |
| JPH0159328B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1989-12-15 |
| MY101772A (en) | 1992-01-17 |
| JPS63114913A (ja) | 1988-05-19 |
| MX164807B (es) | 1992-09-25 |
| US4834792A (en) | 1989-05-30 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| C13 | Decision | ||
| GR02 | Examined patent application | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |