CN100551974C - Completely degradable water retaining mulching of fruit residue humic acid and production method thereof - Google Patents
Completely degradable water retaining mulching of fruit residue humic acid and production method thereof Download PDFInfo
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- CN100551974C CN100551974C CNB2006101186291A CN200610118629A CN100551974C CN 100551974 C CN100551974 C CN 100551974C CN B2006101186291 A CNB2006101186291 A CN B2006101186291A CN 200610118629 A CN200610118629 A CN 200610118629A CN 100551974 C CN100551974 C CN 100551974C
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Abstract
The invention discloses a kind of completely degradable water retaining mulching of fruit residue humic acid and production method thereof, this technology is produced high reactivity BHA with solid-state fermentation technology earlier, utilizes the starch based industrial residue of biological pesticide enterprise to produce the completely degradable water retaining mulch film again.Its process comprises: the pulverizing of (1) BHA raw material, the solid state fermentation under fungi (Trichoderma, black aspergillus), yeast composite bacteria effects such as (open and flat aspergillus, aspergillus sydowiis); (2) pre-treatment of starch based industrial residue is with film-forming properties processing and the packing and storing of high reactivity BHA.The BHA-high reactivity completely degradable water retaining mulch film purposes of this explained hereafter is wide, and cost is low, has both helped the apple place of production or has added the conservation of natural environment in building site; More help the soil moisture conservation volume increase of China western severe cold water-deficient area farm crop.
Description
Technical field
The present invention relates to a kind of completely degradable water retaining mulch film and production method thereof.
Technical background
At apple product, pin and a large amount of apple peel of processing area meeting generation, these apple peels mainly are made up of Pericarpium Mali pumilae, apple seed and stalk, leaf and the fruit of rotting, and will have a strong impact on physical environment as not dealing carefully with.Recent studies show that, contains the high polyphenolic substance of added value in the Pericarpium Mali pumilae, has multiple pharmacological effect such as anticancer, anti-oxidant, arteriosclerosis.Apple residue is except being used for feed (needing the strict pesticide residue that detect) on a small quantity at present, and major part is directly used in the production of fertilizer.
The pomace humic acid organic fertilizer of bibliographical information is produced, generally similar to weathered coal humic acid, stalk humic acids (as: Chinese patent CN 1182797A, CN1232831A).Do not note character, screening and microorganisms bacterial classification according to raw material and product characteristic component.Therefore, except using conventional humic acids content not ≮ 50%, or contain inorganic fertilizer elements such as N, P, K, or contain trace elements such as Cu, Fe, Zn and represent outside its high reactivity, be difficult to characterize pomace humic acids (abbreviation BHA with the content of plant growth hormoness such as indolic acid, dormin, high reactivity down together) and diversity (agricultural chemicals of holding concurrently) are unfavorable for production and the application of high added value BHA.
Membrane covering is a kind ofly to improve the cultivation technique of crop growth environment with manual method, and this method can prevent soil water evaporation, suppresses weed growth, improves crop to light, temperature, water, fertile and land utilization ratio etc. comprehensively.The present kind of China is few.
For avoiding " white pollution ", the applying starch base, comprise that it is a kind of trend that Wholly-degradable materials such as poly(lactic acid) are made the environmental type material.But because such material cost height, toughness is relatively poor, and is existing except as the hospital surgical material, outside a small amount of packaging material for food, generally is not used for mulch film production.Chinese patent CN1459471 discloses a kind of liquid-state mulch film with stalk-humic-acid kind material preparation, can improve field temperature 1-4 ℃, finally can turn fertilizer, not contaminated soil into.But it also slightly is worse than plastic films such as PE, PS on use propertieies such as insulation moisture-resistant.
Summary of the invention
The purpose of this invention is to provide a kind of completely degradable water retaining mulching of fruit residue humic acid and production method thereof, to overcome the above-mentioned defective that prior art exists.
The production method of BHA-high reactivity completely degradable water retaining mulch film of the present invention comprises the steps:
(1) will extract apple peel behind the polyphenolic substance, and add the water of 2~10 times of weight and N, P, K nutritious cpds, sterilization is inoculated in fungal spore or yeast in the above-mentioned mixture then, cultivates 24-56 hour for 15~40 ℃, obtains liquid spawn;
The method that apple peel extracts polyphenolic substance is published in " Xibei Univ. of Agricultural ﹠ Forest Science ﹠ Technology's journal; 33 (8) 2005:131-134 " at Li Zhixi, Li Yuanrui etc., Guo Juan etc. have similar play-by-play in " foodstuffs industry science and technology 2006 (2): 178-180 " document.
Said nutritious cpds is the material that contains N, P and K, preferably sulfuric acid ammonium, dipotassium hydrogen phosphate, Repone K, starch, comes from nitrogen compound in the apple amino acid, the auxiliary material kitchen excess and contains phosphorus component or plant ash, and absolute composition addition is 10~20mg/L;
Said fungi is Trichoderma (Trichoderma viride) or black aspergillus (Aspergillus, nigervan tienghem), yeast is preferably (Aspergllus oryzae Ass.3944), above-mentioned fungi or yeast are provided by Chinese microbial preservation center, or the commercialization bacterial classification that adopts GuanShengYuan, Shanghai group company to produce;
According to the present invention, can with spore inoculating after extracting polyphenolic substance apple peel and the mixture of plant stem-leaf, plant stem-leaf is selected from more than one in fragrant plant thatch, reed cauline leaf, folder branch peach leaf or the two look Stem or leaf of Shrub Lespedeza;
(2) plant stem-leaf after will pulverizing and extract polyphenolic substance after apple peel, the liquid spawn that obtains with the step (1) of 0.01-0.1 times of weight mixes, under anaerobic, in 20~30 ℃, fermented 6~10 days, acquisition contains the high reactivity BHA of components such as indolylacetic acid, dormin, and then with tonality material mixed milling, obtaining viscosity is the mulch film work in-process of 1~100,000 centipoise;
Said plant stem-leaf is selected from more than one in fragrant plant thatch, reed cauline leaf, folder branch peach leaf or the two look Stem or leaf of Shrub Lespedeza;
The parts by weight of the apple peel behind leaf and the extraction polyphenolic substance are:
2~4 parts of leaf, 1~3 part of the apple peel behind the extraction polyphenolic substance;
Said tonality material is the industrial residue that contains starchy material, preferred A Wei mycin fermentation residue or gibberellin fermented waste residue;
The parts by weight of tonality material are 5~65 parts, and high reactivity BHA is 10~75 parts;
(3) work in-process that step (2) is obtained mix with membrane-forming agent, spray the place that covers in needs, can form the completely degradable water retaining mulching of fruit residue humic acid of 0.12-0.38mm naturally;
It is a kind of in 0.2-10mg/L polyvinyl alcohol, chitose or the xylo-oligosaccharide that said membrane-forming agent is selected from concentration;
The adding weight of membrane-forming agent is said half-finished 0.001~0.009 times.
By the BHA-high reactivity completely degradable water retaining mulch film that production method of the present invention obtains, can prevent and treat effectively that cucumber downy mildew, Ipomoea batatas black spot, cotton are withered, the anthrax of verticillium, capsicum, tobacco etc.; And can effectively promote seed germination, fruit maturation, improve effects such as plant stress-resistance; And production cost is low, and the insulation volume increase can preserve soil moisture.Below describe enforcement of the present invention in detail by specific embodiment, purpose is to help the reader to understand the essence of an invention content better, but not as to the qualification of the scope of the present invention.
Description of drawings
Fig. 1 is the high reactivity BHA capillary electrochromatography that contains the IAA.ABA component
Embodiment
Embodiment 1
With the apple peel behind the 100 gram extraction polyphenolic substances, after adding water, 0.003 ammonium sulfate that restrains, 0.002 dipotassium hydrogen phosphate that restrains, 0.001 Repone K that restrains and the 0.005 starch nutrition compound that restrains of 2 times of weight, and behind 3 minutes uv irradiating, inoculation 3.1 * 10
5The Trichoderma of cfu/ml and 1.2 * 10
5The mixture of the black aspergillus spore of cfu/ml, in 30 ℃ 48 hours, prepare liquid spawn;
With the reed cauline leaf that 65 grams are pulverized, 35 grams extract the liquid spawn that the apple peel compound behind the polyphenolic substance is put into 0.02 times of weight, under anaerobic, in 25 ℃, solid state fermentation; Made the high reactivity BHA that contains components such as IAA through 7 days;
38 gram high reactivity BHA and 62 gram starch based industrial residues etc. are mixing, and making viscosity is 80,000 centipoise mulch film work in-process, and said industrial residue is gibberellin fermented waste residue, the product that can adopt biological pesticide company to produce;
(3) be that 5.5mg/L polyvinyl alcohol membrane-forming agent mixes with mixing product 98 grams of high reactivity BHA with 2 gram concentration, spray the place that covers in needs, forming thickness is the completely degradable water retaining mulching of fruit residue humic acid of 0.12mm.
Adopt the identical method of embodiment 1, wherein:
With the apple peel behind the 33 gram extraction polyphenolic substances, adding part by weight is 1: 3 plant fragrant plant thatch after the pulverizing, adds the water of 10 times of weight, inoculation yeast bacterium spore, under anaerobic, in 20 ℃ of solid state fermentations; Made the high reactivity BHA that contains components such as ABA through 10 days.
(3) be that 0.2-10mg/L polyvinyl alcohol membrane-forming agent, 0.3 gram Palmiticacid thickening material, 0.1 restrain the Whitfield's ointment antioxidant and mix with high reactivity BHA with 5 gram concentration, be adjusted at 40 ℃ stable down, viscosity is that the work in-process of 50,000 centipoises spray the place that covers in needs, and forming thickness is the completely degradable water retaining mulching of fruit residue humic acid of 0.12mm;
Embodiment 3
With extracting secondary apple residue behind the polyphenol,,, made the high reactivity BHA (seeing accompanying drawing 1) of components such as containing IAA, ABA through 6 days in 30 ℃ of following solid state fermentations by the liquid spawn expansion bacterium cultivating method of enforcement 1 with after the broken leaf of wild reed mixes; Make the mulch film work in-process by implementing 2 again.
The said work in-process of 200 grams are added 3 gram concentration in the scene be the PVA anion surfactant of 10mg/L, sprays in the field; After the film forming, measure the membrane covering bed thickness 0.15mm on pedosphere surface; After 3 months, can be degraded to humic acid fertilizer entirely.
Claims (9)
1. the production method of a completely degradable water retaining mulching of fruit residue humic acid is characterized in that, comprises the steps:
(1) will extract apple peel behind the polyphenolic substance, and add water and N, P and K nutritious cpds, sterilization is inoculated in fungal spore or yeast in the above-mentioned mixture then, cultivates 24-56 hour for 15~40 ℃, obtains liquid spawn;
Said fungi is Trichoderma or black aspergillus;
(2) plant stem-leaf after will pulverizing and extract polyphenolic substance after apple peel, the liquid spawn that obtains with the step (1) of 0.01-0.1 times of weight mixes, under anaerobic, in 20~30 ℃, fermented 6~10 days, obtain high reactivity BHA, then with tonality material mixed milling, obtaining viscosity is the mulch film work in-process of 1~100,000 centipoise;
(3) work in-process that step (2) is obtained mix with membrane-forming agent, spray the place that covers in needs, form the completely degradable water retaining mulching of fruit residue humic acid of 0.12-0.38mm naturally.
2. method according to claim 1 is characterized in that, the apple peel with behind the extraction polyphenolic substance adds the water of 2~10 times of weight.
3. method according to claim 1 is characterized in that, the absolute composition addition of said nutritious cpds is 10~20mg/L.
4. method according to claim 1 is characterized in that, in the step (2), said plant stem-leaf is selected from more than one in fragrant plant thatch, reed cauline leaf, folder branch peach leaf and the two look Stem or leaf of Shrub Lespedeza;
The parts by weight of the apple peel behind leaf and the extraction polyphenolic substance are:
35~50 parts of leaf, 20~50 parts of the apple peels behind the extraction polyphenolic substance.
5. method according to claim 1 is characterized in that, said tonality material is the industrial residue that contains starchy material, and the parts by weight of tonality material are 20~60 parts, and high reactivity BHA is 30~55 parts.
6. method according to claim 1 is characterized in that, it is a kind of in 0.2-10mg/L polyvinyl alcohol chitose or the xylo-oligosaccharide that said membrane-forming agent is selected from concentration;
The adding weight of membrane-forming agent is said half-finished 0.001~0.009 times.
7. according to each described method of claim 1~6, it is characterized in that, with spore inoculating after extracting polyphenolic substance apple peel and the mixture of plant stem-leaf.
8. method according to claim 7 is characterized in that, plant stem-leaf is selected from more than one in fragrant plant thatch, reed cauline leaf, folder branch peach leaf and the two look Stem or leaf of Shrub Lespedeza.
9. according to the completely degradable water retaining mulching of fruit residue humic acid of each described method preparation of claim 1~8.
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Families Citing this family (5)
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CN101792672B (en) * | 2010-03-02 | 2012-05-23 | 昆明春叶塑料制成品有限公司 | Method for producing liquid mulching film for tobacco by using tobacco waste humic acid |
CN104446895B (en) * | 2014-11-10 | 2017-08-01 | 张常书 | Trichoderma as biological humic acid and its product |
CN105778550B (en) * | 2016-03-07 | 2018-05-25 | 周霞萍 | Matrix membrane, humic acid-containing composition, preparation method and application of humic acid-containing composition, and prepared product |
CN110249877B (en) * | 2019-07-25 | 2021-09-14 | 南宁新科健生物技术有限公司 | Grass-control ecological mulching film for organic planting and preparation and use methods thereof |
CN110452046A (en) * | 2019-08-21 | 2019-11-15 | 上海臻衍生物科技有限公司 | It is a kind of can degradable multi-functional environment-protection mulch and its production method |
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