CN100548111C - The artificial flower stationary support - Google Patents

The artificial flower stationary support Download PDF

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Publication number
CN100548111C
CN100548111C CNB2005100603071A CN200510060307A CN100548111C CN 100548111 C CN100548111 C CN 100548111C CN B2005100603071 A CNB2005100603071 A CN B2005100603071A CN 200510060307 A CN200510060307 A CN 200510060307A CN 100548111 C CN100548111 C CN 100548111C
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China
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agent
pore
parts
catalyzer
blowing agent
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Expired - Fee Related
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CNB2005100603071A
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Chinese (zh)
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CN1754423A (en
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姜旭军
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Individual
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Abstract

The present invention relates to a kind of artificial flower stationary support.It is by 100 parts of PPGs, foam stabiliser 2-3 part, catalyzer 2-3 part, blowing agent 25-30 part, pore-creating agent 2-10 part, isocyanates 130-140 part is prepared from, after particularly adding pore-creating agent and opaque inserts, make that its goods elasticity significantly descends, intensity obviously increases, it is big to have a perforate degree, the characteristics that hole wall is frangible can be widely used in the Artificial flowers and plants of fixing and support insertion etc.

Description

The artificial flower stationary support
Technical field
The invention belongs to the polyurethane synthetic material technical field, specifically a kind of is the foams artificial flower stationary support of matrix with the PPG.
Background technology
That polyurethane foamed material has is soft, the branch of hard, semi-rigid is the main kind of polyurethane synthetic material, because it makes the polytropy of prescription and the adaptability of product properties, has determined that it is extremely extensive in the application of national economy every field.Just present, flexible polyurethane foams is mainly used in: furniture, bed accessory, automobile, aviation, packing, textile composite foam liner, carpet lining, exercise, toy, household supplies, medical and health, structural insulated, military affairs and national defence tip etc., rigid polyurethane foam is mainly used in: refrigerating equipment, reefer truck and tank car, petrochemical pipe and basin adiabatic heat-insulation cold insulation, building, aviation, shipbuilding, packing, electrical equipment, space technology, military affairs etc., the semi-hard polyurethane foams are mainly used in shockproof cushioning parts and automobile, the interior trim of aircraft.In addition also constantly enlarging range of application at aspects such as disposal of waste gas, water and industrial residue, crop genetics, protecting energy, low temperature liquid are defeated in recent years.As the past always by being used for fixing of occupying of phenolic foams with support plant or sign the holder market of inserting thing, because the preparation of phenolic foams is to use fluon type pore former and joy Malin as reactant, may produce serious environmental problems and cost is higher is substituted by the semi-hard polyurethane foams basically to atmosphere.But existing polyurethane foam is still possessed higher elasticity and toughness, so that fixedly fastness is relatively poor and insert difficultly, particularly resembles when inserting dried flower, becomes very thin after its rhizome dehydrates and lack rigidity just to insert and be not easy very much.
Summary of the invention
The object of the present invention is to provide the artificial flower stationary support of the frangible easy insertion of a kind of hole wall.
The technical scheme that realizes the object of the invention is such: it is that the employing PPG is that matrix adds foam stabiliser, catalyzer, blowing agent, be prepared from isocyanate reaction behind the pore-creating agent, the stabilizing agent that is used to prepare this foam artificial flower stationary support can be a silicone oil, tween, catalyzer can be a cyclohexylamine, triethanolamine, stannous octoate etc., blowing agent can be a pentane, 141B, water etc., and pore-creating agent then can be to have added aluminium hydroxide, aluminium oxide, opaque inserts such as white carbon, as: add the opaque inserts as common pore-creating agent polybutene, atoleine adds the opaque inserts.
And each component shared weight portion can be 100 parts of PPGs, foam stabiliser 2-3 part, catalyzer 2-3 part, blowing agent 25-30 part, pore-creating agent 2-10 part isocyanates 130-140 part in the above-mentioned prescription.
Also having the weight ratio of two kinds of compositions of pore-creating agent also can be 1: 5-10.
A kind of artificial flower stationary support of the present invention, adopting PPG is the prescription that matrix and isocyanate reaction foam with halogenated hydrocarbons, especially after adding pore-creating agent and filler, make that its goods elasticity significantly descends, intensity obviously increases, it is big to have the perforate degree, the characteristics that hole wall is frangible, make fixing and when supporting dried flower fastness big and insert very easy.
Particularly, technical scheme of the present invention is as follows.
A kind of artificial flower stationary support, it is to add foam stabiliser with the matrix PPG, catalyzer, blowing agent is prepared from isocyanate reaction behind the pore-creating agent, and described stabilizing agent is silicone oil or tween, catalyzer is cyclohexylamine, triethanolamine or stannous octoate, blowing agent is pentane, 141B or water, and pore-creating agent is polybutene and white carbon
Wherein, the shared weight portion of each component is: 100 parts of PPGs, and foam stabiliser 2-3 part, catalyzer 2-3 part, blowing agent 25-30 part, isocyanates 130-140 part, polybutene in the pore-creating agent and white carbon respectively are 5 parts.
A kind of artificial flower stationary support, it is to add foam stabiliser with the matrix PPG, catalyzer, blowing agent is prepared from isocyanate reaction behind the pore-creating agent, and described stabilizing agent is silicone oil or tween, catalyzer is cyclohexylamine, triethanolamine or stannous octoate, blowing agent is pentane, 141B or water, and pore-creating agent is atoleine and aluminium oxide
Wherein, the shared weight portion of each component is: 100 parts of PPGs, and foam stabiliser 2-3 part, catalyzer 2-3 part, blowing agent 25-30 part, isocyanates 130-140 part, atoleine in the pore-creating agent and aluminium oxide respectively are 4 parts.
A kind of artificial flower stationary support, it is to add foam stabiliser with the matrix PPG, catalyzer, blowing agent is prepared from isocyanate reaction behind the pore-creating agent, and described stabilizing agent is silicone oil or tween, catalyzer is cyclohexylamine, triethanolamine or stannous octoate, blowing agent is pentane, 141B or water, and pore-creating agent is polybutene and aluminium hydroxide
Wherein, the shared weight portion of each component is: 100 parts of PPGs, and foam stabiliser 2-3 part, catalyzer 2-3 part, blowing agent 25-30 part, isocyanates 130-140 part, the polybutene in the pore-creating agent is that 4 parts, aluminium hydroxide are 6 parts.
A kind of artificial flower stationary support, it is to add foam stabiliser with the matrix PPG, catalyzer, blowing agent is prepared from isocyanate reaction behind the pore-creating agent, and described stabilizing agent is silicone oil or tween, catalyzer is cyclohexylamine, triethanolamine or stannous octoate, blowing agent is pentane, 141B or water, and pore-creating agent is atoleine and aluminium hydroxide
Wherein, the shared weight portion of each component is: 100 parts of PPGs, and foam stabiliser 2-3 part, catalyzer 2-3 part, blowing agent 25-30 part, isocyanates 130-140 part, the atoleine in the pore-creating agent is that 2 parts, aluminium hydroxide are 4 parts.
Embodiment
The present invention is further illustrated below in conjunction with embodiment, and following each embodiment only is used to illustrate technical scheme of the present invention, but to not restriction of the present invention.
Embodiment one
100 parts of PPGs, 3 parts of foam stabiliser silicone oil, 2 parts of catalyst cyclohexane, 30 parts of blowing agent pentanes, each 5 parts of pore-creating agent polybutene and white carbons, 1 part in fire retardant aluminium hydroxide, 138 parts of post-foamings that are mixed of isocyanates.
Embodiment two
100 parts of PPGs, 2 parts of foam stabiliser tweens, 2 parts of catalyzer triethanolamines, 28 parts of blowing agent pentanes, each 4 parts in pore-creating agent atoleine and aluminium oxide, 134 parts of post-foamings that are mixed of isocyanates.
Embodiment three
100 parts of PPGs, 2.5 parts of foam stabiliser silicone oil, 2.5 parts in the inferior tin of octoate catalyst, 25 parts in blowing agent water, 6 parts in 4 parts of pore-creating agent polybutene and aluminium hydroxide, 132 parts of post-foamings that are mixed of isocyanates.
Embodiment four
100 parts of PPGs, 2.5 parts of foam stabiliser tweens, 2.5 parts of catalyst cyclohexane, 25 parts of blowing agent 141B, 4 parts in 2 parts of pore-creating agent atoleines and aluminium hydroxide, 132 parts of post-foamings that are mixed of isocyanates.

Claims (4)

1, a kind of artificial flower stationary support, it is to add foam stabiliser with the matrix PPG, catalyzer, blowing agent is prepared from isocyanate reaction behind the pore-creating agent, and it is characterized in that: described stabilizing agent is silicone oil or tween, catalyzer is cyclohexylamine, triethanolamine or stannous octoate, blowing agent is pentane, 141B or water, and pore-creating agent is polybutene and white carbon
Wherein, the shared weight portion of each component is: 100 parts of PPGs, and foam stabiliser 2-3 part, catalyzer 2-3 part, blowing agent 25-30 part, isocyanates 130-140 part, polybutene in the pore-creating agent and white carbon respectively are 5 parts.
2, a kind of artificial flower stationary support, it is to add foam stabiliser with the matrix PPG, catalyzer, blowing agent is prepared from isocyanate reaction behind the pore-creating agent, and it is characterized in that: described stabilizing agent is silicone oil or tween, catalyzer is cyclohexylamine, triethanolamine or stannous octoate, blowing agent is pentane, 141B or water, and pore-creating agent is atoleine and aluminium oxide
Wherein, the shared weight portion of each component is: 100 parts of PPGs, and foam stabiliser 2-3 part, catalyzer 2-3 part, blowing agent 25-30 part, isocyanates 130-140 part, atoleine in the pore-creating agent and aluminium oxide respectively are 4 parts.
3, a kind of artificial flower stationary support, it is to add foam stabiliser with the matrix PPG, catalyzer, blowing agent is prepared from isocyanate reaction behind the pore-creating agent, and it is characterized in that: described stabilizing agent is silicone oil or tween, catalyzer is cyclohexylamine, triethanolamine or stannous octoate, blowing agent is pentane, 141B or water, and pore-creating agent is polybutene and aluminium hydroxide
Wherein, the shared weight portion of each component is: 100 parts of PPGs, and foam stabiliser 2-3 part, catalyzer 2-3 part, blowing agent 25-30 part, isocyanates 130-140 part, the polybutene in the pore-creating agent is that 4 parts, aluminium hydroxide are 6 parts.
4, a kind of artificial flower stationary support, it is to add foam stabiliser with the matrix PPG, catalyzer, blowing agent is prepared from isocyanate reaction behind the pore-creating agent, and it is characterized in that: described stabilizing agent is silicone oil or tween, catalyzer is cyclohexylamine, triethanolamine or stannous octoate, blowing agent is pentane, 141B or water, and pore-creating agent is atoleine and aluminium hydroxide
Wherein, the shared weight portion of each component is: 100 parts of PPGs, and foam stabiliser 2-3 part, catalyzer 2-3 part, blowing agent 25-30 part, isocyanates 130-140 part, the atoleine in the pore-creating agent is that 2 parts, aluminium hydroxide are 4 parts.
CNB2005100603071A 2005-08-03 2005-08-03 The artificial flower stationary support Expired - Fee Related CN100548111C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CNB2005100603071A CN100548111C (en) 2005-08-03 2005-08-03 The artificial flower stationary support

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Application Number Priority Date Filing Date Title
CNB2005100603071A CN100548111C (en) 2005-08-03 2005-08-03 The artificial flower stationary support

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CN100548111C true CN100548111C (en) 2009-10-14

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Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105461453A (en) * 2015-12-28 2016-04-06 常熟市金玉花卉泡沫有限公司 Special flower arrangement mud for osmanthus
CN105461452A (en) * 2015-12-28 2016-04-06 常熟市金玉花卉泡沫有限公司 Special flower arrangement mud for southern magnolia

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4431455A (en) * 1981-02-04 1984-02-14 Imperial Chemical Industries Plc Wax dispersions and their use in the manufacture of sheets or moulded bodies
US4929646A (en) * 1988-04-26 1990-05-29 The Dow Chemical Company Polyurethane foam prepared using high functionality cell openers
CN1189172A (en) * 1996-04-19 1998-07-29 福梅克斯公司 Breathable open cell urethane polymers
CN1239485A (en) * 1996-12-02 1999-12-22 拜尔公司 Method for discontinuous prodn. of flexible, open-cell polyurethane foams
CN1254730A (en) * 1998-11-17 2000-05-31 气体产品与化学公司 Weak Bronsted acid derivative for improving size stability of soft polyurethane foam body
CN1269373A (en) * 1999-03-29 2000-10-11 气体产品与化学公司 Water-contained wax dispenser used as pore-creating agent in preparation of polyurethane flexible foams

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4431455A (en) * 1981-02-04 1984-02-14 Imperial Chemical Industries Plc Wax dispersions and their use in the manufacture of sheets or moulded bodies
US4929646A (en) * 1988-04-26 1990-05-29 The Dow Chemical Company Polyurethane foam prepared using high functionality cell openers
CN1189172A (en) * 1996-04-19 1998-07-29 福梅克斯公司 Breathable open cell urethane polymers
CN1239485A (en) * 1996-12-02 1999-12-22 拜尔公司 Method for discontinuous prodn. of flexible, open-cell polyurethane foams
CN1254730A (en) * 1998-11-17 2000-05-31 气体产品与化学公司 Weak Bronsted acid derivative for improving size stability of soft polyurethane foam body
CN1269373A (en) * 1999-03-29 2000-10-11 气体产品与化学公司 Water-contained wax dispenser used as pore-creating agent in preparation of polyurethane flexible foams

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