CN100541190C - In-situ detection system for deep-sea high-temperature hydrothermal regions - Google Patents

In-situ detection system for deep-sea high-temperature hydrothermal regions Download PDF

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CN100541190C
CN100541190C CNB2007100707900A CN200710070790A CN100541190C CN 100541190 C CN100541190 C CN 100541190C CN B2007100707900 A CNB2007100707900 A CN B2007100707900A CN 200710070790 A CN200710070790 A CN 200710070790A CN 100541190 C CN100541190 C CN 100541190C
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hydrothermal
detection
water inlet
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CN101118227A (en
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陈鹰
谭春阳
杨灿军
顾临怡
吴怀超
金波
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Zhejiang University ZJU
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Abstract

本发明的深海高温热液区的原位探测系统，包括热液采样探测装置、供电装置、微电脑控制装置以及电极冲洗和标定装置。热液采样探测装置中的探测电极，在热液流过时可以探测热液的化学成分。微电脑控制装置的信号输出端与ICL线圈相连，可传输信号至深潜器。电极冲洗和标定装置可对热液采样探测装置内的探测电极进行标定。本发明依靠自身携带的电池供电，可在深海持续长时间自动运行。本发明具有高温热液探测、探测电极冲洗、探测电极标定三个工作状态，由微电脑控制装置实现状态的切换，具有对深海热液喷口的高温热液进行长期探测和探测电极的自维护标定功能，大大提高了探测电极的性能和化学量探测的准确性。可以为深海热液的科学研究提供详细准确的数据。

Figure 200710070790

The in-situ detection system of the deep-sea high-temperature hydrothermal area of the present invention includes a hydrothermal sampling detection device, a power supply device, a microcomputer control device, and an electrode flushing and calibration device. The detection electrode in the hydrothermal sampling detection device can detect the chemical composition of the hydrothermal fluid when the hydrothermal fluid flows through it. The signal output terminal of the microcomputer control device is connected with the ICL coil, which can transmit the signal to the deep submersible. The electrode flushing and calibration device can calibrate the detection electrodes in the hydrothermal sampling detection device. The invention is powered by the battery carried by itself, and can run automatically for a long time in the deep sea. The invention has three working states of high-temperature hydrothermal detection, detection electrode flushing, and detection electrode calibration, and the state switching is realized by a microcomputer control device, and has the functions of long-term detection of high-temperature hydrothermal fluid in deep-sea hydrothermal vents and self-maintenance calibration of detection electrodes , greatly improving the performance of the detection electrode and the accuracy of chemical quantity detection. It can provide detailed and accurate data for scientific research on deep sea hydrothermal fluids.

Figure 200710070790

Description

The in-situ detecting system of elevated temperature heat liquid zone, deep-sea
Technical field
The present invention relates to a kind of hypothermal original position long period detection system in deep-sea that is applicable to, be by its automatic operation of microcomputerized control specifically, have the system that high temperature (350-400 ℃) hydrothermal solution to the hydrothermal vent place is carried out long-term in-situ investigation and exploring electrode safeguarded calibrating function.
Background technology
Current in the ocean resources detection operations, international ocean circle has been carried out the research of deep-sea hydrothermal being carried out Detection Techniques.At the submarine hydrothermal solution spout, temperature reaches as high as 350～400 ℃, traditional detection, and the hydrothermal solution of ejection is a highly acid, strong reducing property, and dissolved the H of high concentration 2Toxic component such as S, heavy metal.1) traditional katathermal solution is surveyed the variation that the method for mostly using sampling analysis is observed the hydrothermal solution composition, but because the change of sample collecting, storage process environment of living in, its composition can change unavoidably, have and analyze the defective that data accurately and not have real-time, so the in-situ investigation technology is a modern deep-sea development of scientific research direction.2) traditional sniffer and exploring electrode is difficult to long-term stable operation under the high temperature, and exploring electrode can very fast inefficacy.Therefore development can be high temperature resistant and can to exploring electrode safeguard the hydrothermal solution sniffer be necessary.
Summary of the invention
The purpose of this invention is to provide the deep-sea katathermal solution original position long period detection system that can carry out long-term in-situ investigation to the katathermal solution at deep-sea hydrothermal vent place.
The in-situ detecting system of elevated temperature heat liquid zone, deep-sea of the present invention comprises following building block:
1) hydrothermal solution sampling sniffer: comprise L shaped housing, L shaped housing is the through through hole of relative two walls of section vertically, therein a through hole under an aperture is arranged, the outer device of housing has the filtering screen that covers above-mentioned through hole and aperture, in vertical section of housing, be provided with the piston type probe that the housing cavity volume is separated into epicoele and cavity of resorption, epicoele and cavity of resorption are connected through pipeline, be connected to first oil sac on this pipeline, the top of piston type probe is cylinder, the bottom is the cavity with end cap, a spring is arranged in the epicoele, one end of spring is connected with the cylinder top on probe top, the other end of spring links to each other with case top, the top cylinder of piston type probe is provided with radial direction through hole, device has exploring electrode and water inlet pipe in the lower cavity, the head of exploring electrode and the water delivering orifice of water inlet pipe reach respectively in the radial direction through hole of top cylinder, the water inlet of water inlet pipe is on the lower cavity wall of piston type probe, the end of L shaped housing horizontal segment is fixed with stepper motor, the rotating shaft of stepper motor links to each other with screw rod and is positioned on the axis of housing horizontal segment, screw rod is connected with tapped slide block, slide block is in the guide rail of fixing with housing, there is a pulley intersection at vertical section of housing and horizontal segment, be wound with wire rope on the pulley, one end of wire rope links to each other with slide block, the other end of wire rope links to each other with the end cap of probe bottom, and the end face of end cap offers several holes;
2) electric supply installation: comprise enclosed cell chamber enclosure and battery;
3) micro-computer controlling apparatus: comprise airtight control chamber shell, place the microcontroller of airtight control chamber, microcontroller links to each other with supplying cell, microcontroller and the deep-sea ICL coil that device carries out communication of diving is connected, and the stepper motor that microcontroller and hydrothermal solution are sampled in the sniffer links to each other with exploring electrode;
4) electrode washing and caliberating device: comprise closed container, place the flow control system of closed container, be connected to second oil sac on the closed container, titer leather bag and seawater water inlet pipe, flow control system links to each other with microcontroller, said flow control system comprises pump and two solenoid valves, the pump inlet divides two the tunnel, one the tunnel links to each other with the seawater water inlet pipe through first solenoid valve, another road second solenoid valve links to each other with the titer leather bag, the liquid outlet of pump is connected with flushing-liquid pipe, the water delivering orifice of flushing-liquid pipe is on the housing of hydrothermal solution sampling sniffer, and is corresponding with the water inlet of water inlet pipe.
Beneficial effect of the present invention is: can carry out long-term in-situ investigation near the katathermal solution the deep-sea hydrothermal vent, and can safeguard exploring electrode, prolong the life-span of exploring electrode, improved the performance of exploring electrode and the accuracy of long-term detection data greatly, detailed accurate data can be provided for the scientific research of deep-sea hydrothermal.
Description of drawings
Fig. 1 is the structural representation (diagram is in acquisition mode) of detection system of the present invention;
Fig. 2 is the synoptic diagram of detection system of the present invention when being in flushing and demarcating state;
Fig. 3 is the synoptic diagram of flow control system.
Embodiment
Further specify the present invention below in conjunction with accompanying drawing.
With reference to Fig. 1, the in-situ detecting system of elevated temperature heat liquid zone, deep-sea of the present invention comprises following building block:
1) hydrothermal solution sampling sniffer: comprise L shaped housing 1, L shaped housing is the through through hole 31 of relative two walls of section vertically, therein a through hole 31 under an aperture 7 is arranged, the outer device of housing has the filtering screen 6 that covers above-mentioned through hole 31 and aperture 7, utilize filtering screen can filter impurity in hydrothermal solution and the seawater, prevent that the hole is blocked.In vertical section of housing, be provided with the piston type probe 32 that the housing cavity volume is separated into epicoele 2 and cavity of resorption 27, epicoele 2 and cavity of resorption 27 are connected through pipeline 8, be connected to first oil sac 9 on this pipeline, in epicoele 2, cavity of resorption 27 and first oil sac 9, be filled with insulating oil, for example methyl-silicone oil mainly plays insulation and pressure balanced effect.The top of piston type probe 32 is cylinder, the bottom is the cavity 29 with end cap 28, and a spring 3 is arranged in the epicoele, and an end of spring is connected with the cylinder top on probe top, the other end of spring links to each other with case top, and the effect of spring mainly is that piston type probe 32 is resetted.The top cylinder of piston type probe is provided with radial direction through hole 5, device has exploring electrode 4 and water inlet pipe 30 in the lower cavity 29, the water delivering orifice of the head of exploring electrode 4 and water inlet pipe 30 reaches respectively in the radial direction through hole 5 of top cylinder, the water inlet of water inlet pipe 30 is on the lower cavity wall of piston type probe 32, the end of L shaped housing horizontal segment is fixed with stepper motor 26, the rotating shaft of stepper motor 26 links to each other with screw rod 25 and is positioned on the axis of housing horizontal segment, screw rod 25 is connected with tapped slide block 23, slide block 23 is in the guide rail of fixing with housing 24, there is a pulley 21 intersection at vertical section of housing and horizontal segment, be wound with wire rope 22 on the pulley 21, one end of wire rope links to each other with slide block 23, the other end of wire rope links to each other with the end cap 28 of probe bottom, and the end face of end cap 28 offers several holes, is used for communicating with cavity of resorption 27;
2) electric supply installation: comprise enclosed cell chamber enclosure 19 and battery 20;
3) micro-computer controlling apparatus: comprise airtight control chamber shell 18, place the microcontroller 17 of airtight control chamber, microcontroller 17 links to each other with supplying cell 20, microcontroller 17 and the deep-sea ICL coil 11 that device carries out communication of diving is connected, and the stepper motor 26 that microcontroller 17 and hydrothermal solution are sampled in the sniffer links to each other with exploring electrode 4;
4) electrode washing and caliberating device: comprise closed container 14, place the flow control system 13 of closed container 14, be connected to second oil sac 12 on the closed container, titer leather bag 16 and seawater water inlet pipe 15, flow control system 13 links to each other with microcontroller 17, said flow control system 13 comprises pump 13-2 and two solenoid valve 13-1,13-3, pump 13-2 inlet divides two the tunnel, one the tunnel links to each other with seawater water inlet pipe 15 through the first solenoid valve 13-1, another road second solenoid valve 13-3 links to each other with titer leather bag 16, the liquid outlet of pump 13-2 is connected with flushing-liquid pipe 10, the water delivering orifice of flushing-liquid pipe 10 is on the housing 1 of hydrothermal solution sampling sniffer, and is corresponding with the water inlet of water inlet pipe 30.
Be filled with insulating oil in the closed container 14 and second oil sac 12.The titer that is stored in the titer leather bag 16 is the liquid with certain chemical constitution for preparing on land, has been used for exploring electrode demarcation effect.
Connection between above-mentioned each parts all links to each other by underwater electrical connector.
The principle of work of in-situ detecting system that is applicable to elevated temperature heat liquid zone, deep-sea is as follows:
Total system work has three states, is respectively acquisition mode, flushing state, demarcation state.Elaborate below in conjunction with the principle of work of duty to system.
During acquisition mode, microcontroller 17 control step motors 26 drive screw rod 25 and rotate with certain speed, so drive slide block 23 shift positions, when wire rope 22 traction probes 32 change position to top cylinder through holes 5 connect with housing 1 through through hole 31 (as shown in Figure 1), stepper motor 26 just stops operating, owing to have self-locking performance between screw rod 25 and the slide block 23, probe 32 just can be still in position shown in Figure 1.This moment, the popped one's head in outer wall of lower cavity of water delivering orifice of flushing-liquid pipe 10 blocked, and the water inlet pipe 30 and the flushing-liquid pipe 10 of hydrothermal solution sampling sniffer are not communicated with.Because hydrothermal vent is constantly to the external eruption hydrothermal solution, hydrothermal solution enters top cylinder through hole 5 through filter mantle 6 and contacts with exploring electrode 4.Exploring electrode produces certain electric signal according to the difference of contained chemistry amount in the hydrothermal solution, and microcontroller 17 receives electric signal and just signal is further processed, such as computing, storage etc.Hydrothermal solution in this moment top cylinder through hole 5 mainly relies on hydrothermal solution to erupt to upgrade voluntarily.
Flushing and demarcation state: 26 rotations of microcontroller 17 control step motors, make probe 32 change position to top cylinder through hole 5 and leave the through through hole 31 of housing, and when aperture 7 on the housing links to each other, as shown in Figure 2, this moment, top cylinder through hole 5 and extraneous seawater were communicated with, the water delivering orifice alignment of the water inlet of water inlet pipe 30 and flushing-liquid pipe 10 is so water inlet pipe 30 and flushing-liquid pipe 10 are communicated with.
1) flushing process: microcontroller 17 sends instruction, pump 13-2 operation, and the first solenoid valve 13-1 opens, from extraneous extracting seawater.Seawater enters into probe top cylinder through hole 5 along washing fluid water inlet pipe 10 and water inlet pipe 30, discharge from aperture 7, flushing exploring electrode 4, fundamental purpose is some impurity that wash accumulation on the exploring electrode 4, thereby prevents that exploring electrode 4 from can not contact the detection effect that do not have with hydrothermal solution.Arrive when the time of setting, flow control system just cuts off the power supply and quits work.
2) demarcation state.Microcontroller 17 sends instruction, pump 13-2 operation, and the second solenoid valve 13-3 opens, from titer leather bag 16 draw standard liquid.Titer enters into probe top cylinder through hole 5 along washing fluid water inlet pipe 10 and water inlet pipe 30, discharge from aperture 7, exploring electrode 4 can be immersed in the titer in this process, thereby plays the demarcation effect, and the main effect of demarcation is to make exploring electrode 4 recover detection performance.Thereby prolongation mission life.
After total system was put into elevated temperature heat liquid zone, deep-sea by latent device, system just entered acquisition mode, and after detection after a while, exploring electrode is malfunctioning, and system just enters into flushing and the demarcation state is safeguarded exploring electrode.When flushing of exploring electrode process and demarcation, return to normal operating conditions, system enters into acquisition mode again.The continuous periodic duty of system like this guarantees that exploring electrode can long-term stable operation.

Claims (1)

1.深海高温热液区的原位探测系统，其特征在于包括以下组成部件：1. The in-situ detection system of the deep-sea high-temperature hydrothermal area is characterized in that it includes the following components: 1)热液采样探测装置：包括L形的壳体(1)，L形壳体竖直段的相对两壁对穿的通孔(31)，在其中一个通孔(31)的正下方有一小孔(7)，壳体外装置有罩住上述通孔(31)和小孔(7)的过滤网罩(6)，在壳体的竖直段内设有将壳体容腔分隔成上腔(2)和下腔(27)的活塞式探头(32)，上腔(2)和下腔(27)经管道(8)相连通，该管道上接有第一油囊(9)，活塞式探头(32)的上部为柱体，下部为具有端盖(28)的空腔(29)，上腔中有一根弹簧(3)，弹簧的一端与探头上部的柱体顶端连接，弹簧的另一端与壳体顶部相连，活塞式探头的上部柱体上设有径向通孔(5)，下部空腔(29)内装置有探测电极(4)和进水管(30)，探测电极(4)的头部和进水管(30)的出水口分别伸出到上部柱体的径向通孔(5)中，进水管(30)的进水口在活塞式探头(32)的下部空腔(29)壁上，L形壳体水平段的端部固定有步进电机(26)，步进电机(26)的转轴与螺杆(25)相连并位于壳体水平段的轴线上，螺杆(25)与带内螺纹的滑块(23)连接，滑块(23)处在与壳体固定的导轨(24)内，在壳体竖直段和水平段的相交处有一滑轮(21)，滑轮(21)上绕有钢丝绳(22)，钢丝绳的一端与滑块(23)相连，钢丝绳的另一端与探头下部的端盖(28)相连，端盖(28)的端面开设有数个孔；1) Hydrothermal sampling and detection device: comprising an L-shaped casing (1), through holes (31) pierced through opposite walls of the vertical section of the L-shaped casing, and a hole (31) directly below one of the through holes (31). Aperture (7), housing outer device has the screen cover (6) that covers above-mentioned through hole (31) and aperture (7), is provided with in the vertical section of housing and is divided into the upper housing chamber. The piston probe (32) of the chamber (2) and the lower chamber (27), the upper chamber (2) and the lower chamber (27) are connected through the pipeline (8), and the pipeline is connected with the first oil bag (9), The top of the piston probe (32) is a cylinder, the bottom is a cavity (29) with an end cover (28), a spring (3) is arranged in the upper cavity, one end of the spring is connected with the top of the cylinder on the probe top, and the spring The other end of the piston probe is connected to the top of the housing, and the upper cylinder of the piston probe is provided with a radial through hole (5), and a detection electrode (4) and a water inlet pipe (30) are installed in the lower cavity (29). The head of (4) and the water outlet of water inlet pipe (30) stretch out in the radial through hole (5) of upper cylinder body respectively, and the water inlet of water inlet pipe (30) is in the bottom space of piston type probe (32). On the cavity (29) wall, the end of the L-shaped housing horizontal section is fixed with a stepper motor (26), and the rotating shaft of the stepper motor (26) is connected with the screw rod (25) and is positioned on the axis of the housing horizontal section. (25) Connect with the slide block (23) with internal thread, the slide block (23) is in the guide rail (24) fixed with the casing, and there is a pulley (21) at the intersection of the vertical section and the horizontal section of the casing , a wire rope (22) is wound on the pulley (21), one end of the wire rope is connected to the slider (23), the other end of the wire rope is connected to the end cover (28) at the lower part of the probe, and several holes are provided on the end surface of the end cover (28) ; 2)供电装置：包括密闭电池腔外壳(19)和电池(20)；2) Power supply device: including a sealed battery chamber casing (19) and a battery (20); 3)微电脑控制装置：包括密闭控制腔外壳(18)，置于密闭控制腔中的微控制器(17)，微控制器(17)与供电电池(20)相连，微控制器(17)与深海潜器进行通讯的ICL线圈(11)连接，微控制器(17)与热液采样探测装置中的步进电机(26)和探测电极(4)相连；3) Microcomputer control device: comprising an airtight control chamber casing (18), a microcontroller (17) placed in the airtight control chamber, the microcontroller (17) is connected to the power supply battery (20), and the microcontroller (17) is connected to the power supply battery (20). The ICL coil (11) for communicating with the deep-sea submersible is connected, and the microcontroller (17) is connected with the stepper motor (26) and the detection electrode (4) in the hydrothermal sampling detection device; 4)电极冲洗和标定装置：包括密闭容器(14)，置于密闭容器(14)中的流控系统(13)，密闭容器上接有第二油囊(12)、标准液皮囊(16)及海水进水管(15)，流控系统(13)与微控制器(17)相连，所说的流控系统(13)包括泵(13-2)和两个电磁阀(13-1、13-3)，泵(13-2)进液口分二路，一路经第一电磁阀(13-1)与海水进水管(15)相连，另一路经第二电磁阀(13-3)与标准液皮囊(16)相连，泵(13-2)的出液口与冲洗液管道(10)连接，冲洗液管道(10)的出水口在热液采样探测装置的壳体(1)上，与进水管(30)的进水口相对应；4) Electrode flushing and calibration device: including an airtight container (14), a fluid control system (13) placed in the airtight container (14), the airtight container is connected with a second oil bag (12), a standard liquid bag (16) And seawater inlet pipe (15), flow control system (13) links to each other with microcontroller (17), and said flow control system (13) comprises pump (13-2) and two solenoid valves (13-1,13 -3), the liquid inlet of the pump (13-2) is divided into two roads, one road is connected with the sea water inlet pipe (15) through the first solenoid valve (13-1), and the other road is connected with the sea water inlet pipe (15) through the second solenoid valve (13-3) The standard liquid bladder (16) is connected, the liquid outlet of the pump (13-2) is connected with the flushing liquid pipeline (10), and the water outlet of the flushing liquid pipeline (10) is on the housing (1) of the hydrothermal sampling detection device. Corresponding to the water inlet of water inlet pipe (30); 上述各部件之间的连接均通过水密接插件相连。The connections between the above-mentioned components are all connected by watertight connectors.
CNB2007100707900A 2007-08-14 2007-08-14 In-situ detection system for deep-sea high-temperature hydrothermal regions Expired - Fee Related CN100541190C (en)

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CN109283179B (en) * 2018-11-19 2024-09-24 自然资源部第二海洋研究所 Self-contained in-situ detection device for seafloor hydrothermal plume
CN110646631B (en) * 2019-10-28 2025-03-07 南京晶捷生物科技有限公司 Calibration liquid, sample liquid conveying and heating device and POCT detection equipment
CN114878023A (en) * 2022-05-31 2022-08-09 浙江大学 Self-powered observation device based on submarine hydrothermal solution
CN118857856B (en) * 2024-09-12 2024-12-10 国家深海基地管理中心 Deep sea hydrothermal vent position surveying device and method based on submersible

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适用于深海热液环境的全固态电化学传感器的研究进展. 叶瑛等.自然科学进展，第14卷第2期. 2004 *

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