CN100519768C - Shaft furnace for production of ferrochromium and smelting method thereof - Google Patents
Shaft furnace for production of ferrochromium and smelting method thereof Download PDFInfo
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- CN100519768C CN100519768C CNB2006100236965A CN200610023696A CN100519768C CN 100519768 C CN100519768 C CN 100519768C CN B2006100236965 A CNB2006100236965 A CN B2006100236965A CN 200610023696 A CN200610023696 A CN 200610023696A CN 100519768 C CN100519768 C CN 100519768C
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Abstract
A ferrochrome smelting upright furnace and relative smelt method, comprises a main body with a smelting space formed by furnace frame and fireproof material, while the smelting space is divided into the upper, middle, and lower sections; the upper section is the furnace body of heating area; the middle section is the bosh whose one side has internal incline angle alpha; the lower section is the furnace cylinder; the large bell and the funnel are arranged at the top of furnace; the hot wind tube is at one side of the middle section; the wind entrance is at the lower edge of middle section; the cooling machine is in the frame; the slag outlet and iron outlet are at one side of lower cylinder; the ores and cokes are fed into the furnace via the large bell and funnel; the hot wind via the hot wind tube and the wind entrance are fed into the upright furnace via the lower part to burn the coke at the front of wind entrance; in the process of falling material, dropping melted material and lifting up the gas, the ores are heated and melted. The invention can utilize the heat energy from the reduction process to sinter the ferrochrome, while the iron water can be used to directly prepare stainless mother liquid.
Description
Technical field
The invention belongs to the ferroalloy smelting Processes and apparatus, relate to a kind of fusing-reduced form ferrochrome smelting device and smelting technology, be used for chromium-containing molten iron (mother liquor of stainless steel) smelting that stainless steel is used.
Background technology
Stainless production develops into electric arc furnace-AOD-two step method (duplex technology) from the single melting of electric arc furnace, refining and alloying.Developed " three-step approach " stainless steel new process of production the eighties, promptly first furnace (electric arc furnace or converter)-converter-vacuum refining furnace.Just furnace only plays fusing effect (mother liquor is provided), and vacuum refining furnace is mainly VOD or AOD, and RH OB, RH KTB are also arranged.The three-step approach proportion is near 20% at present.
From the angle of chromium, the source of mother liquor of stainless steel mainly contains following four kinds: (1) steel scrap; (2) solid high carbon ferro-chrome; (3) liquid high carbon ferro-chrome; (4) liquid mother liquor of stainless steel.
At present, most in the world stainless steel Production Flow Charts method of all adopting steel scrap (or molten iron) to add carbon ferrochrome is obtained mother liquor of stainless steel (being chromium-containing molten iron).Developing country's steel scrap shortage of resources, mother liquor of stainless steel adopt the electric arc furnace of solid high carbon ferro-chrome+common molten iron (or adding the part steel scrap again) to mix the method for converting mostly.This method need be used electric energy refuse solid high carbon ferro-chrome, and production cost increases.Because high carbon ferro-chrome is produced in ore-smelting furnace, there is the power consumption height in it, productivity is low reaches problems such as chrome ore requirement height, and chrome ore reductive dynamic conditions is poor, and the rate of recovery of its chromium only is 78%~93.7%.According to statistics, one ton of carbon ferrochrome of every smelting needs 1880~2250kg chromium lump ore, 410~520kg coke, 85~95kg silica and 75~85kg steel cuttings, power consumption 3100~3300kwh, chromium recovery ratio 92~95% approximately.
The fatal shortcoming of above-mentioned flow process is that energy consumption is big, cost is high, can not uses the fine ore resource, and the environmental pollution that produces is more serious.
Began in 1880 in the world to smelt the practice that contains chromium pig iron, but because prevailing condition is limit temperature of the furnace hearth deficiency particularly, furnace equipment well damage, and it is poor to contain the flowability of chromium pig iron and slag, can't produce normally with blast furnace.
Under this background, it is just extremely urgent to study a kind of cost new ferrochrome production equipment low, that can be extensive use of various resources.Fusing-reduction shaft furnace is expected to become one of Perfected process that overcomes the above problems.Its principle is that the rapid heating in the melting and reducing of blast furnace hearth and cupola furnace is combined, adopt oxygen-coal strengthening smelting technology to realize high temperature of combustion, hot consolidation ferrochrome agglomerate after the prereduction processing is sent into the shaft furnace metallurgy, for short flow process steel-making provides the ferrochrome mother liquor, thereby improve the competitive capacity of steel products.
The disclosed technology of Chinese patent CN218952Y " metallized pellet reduction shaft furnace " is to make reductive agent with water-gas, and acid pellet is made the reduction shaft furnace of raw material metal smelting pellet.The type of furnace is " wine jar " shape, and body of heater divides preheating section, reduction section, cooling section, and body of heater is provided with reducing gas import, cooling gas inlet and outlet, and body of heater adopts mechanical stepless speed change solid iron product discharge mechanism.This shaft furnace design is easy, and operation is also convenient, can obtain the solid metal iron product of higher metal rate.Analyze from technical matters, equipment, this shaft furnace is not suitable for smelting chromium-containing molten iron.
The disclosed technology of Chinese patent CN2273712Y " Shaft furnace for riducing iron " also is to make the special-purpose shaft furnace that reductive agent is produced sponge iron (solid product) with coal, mainly form by combustion chamber, reduction chamber and gas-circulating system, the reduction chamber is positioned at the body of heater center, reduce the outdoor combustion chamber that is arranged with, be positioned at the flue bottom and be provided with the resistance wall that falls in the combustion chamber, hinder wall and combustion chamber oneself and be provided with gas heater, well heater with enter the gas inlet pipe of reduction in the chamber and link to each other, the reduction chamber is exported gas and is entered well heater through purifying treatment and recycle.This shaft furnace can only be applied to produce solid-state sponge iron.
Summary of the invention
The purpose of this invention is to provide a kind of employing prereduction ferrochrome pellet and make melting raw materials-reduction ferrochrome smelting device, being used to produce the chromium heating molten steel (mother liquor of stainless steel) that contains that stainless steel uses smelts, replace traditional ore-smelting furnace ferrochrome smelting technology, reduce the dependence of ferrochrome production the smart lump ore resource of ferrochrome of a large amount of electric energy and costliness.
For achieving the above object the technical solution of the utility model
Ferrochrome smelting to the effect that of the present invention is with fusing-reduction shaft furnace and adopt prereduction ferrochrome pellet to make the method that contains the chromium heating molten steel that the raw material production stainless steel is used.
In order to overcome the deficiency that the hot stove in traditional ore deposit must use lump ore and electric energy, the technology that the present invention adopts is with rotary hearth furnace non-lump ore (fine ore or concentrate) to be carried out sending into the shaft furnace smelting again after agglomeration and the prereduction processing.Fusing-reduction shaft furnace is smelted to satisfy and is adopted prereduction pellet, oxide compound reduction and contain the qualified requirement of chromium heating molten steel product.
Ferrochrome smelting shaft furnace of the present invention, it comprises, the shaft furnace body, it forms one by furnace shell, refractory materials and smelts the space, is divided into the upper, middle and lower section; The stove epimere is the shaft of heating zone, and is similar with the cupola furnace, and its function is that furnace charge is heated rapidly to 1000~1300 ℃; Prereduction ore deposit or the mineral pieces therewith just heating in this zone that contains alloying element are not reduced, and therefore the reduction potential to furnace gas does not require; The stove stage casing is the bosh of fusing-reduction zone, and its sidewall has a leaning angle α; The stove hypomere is a cupola well, and its effect is that splendid attire molten iron and slag and the unreduced mineral of part continue reduction at this, and some chemical reactions such as desulfurization also carry out at this, finally generate qualified alloy heating molten steel or alloy mother liquor; Great bell and funnel are arranged at the top of shaft furnace body stove top shaft; Bustle pipe is arranged at stove stage casing one side; The air port is arranged at lower edge, stove stage casing; Refrigerating unit is arranged in the body furnace shell; Slag notch is opened in shaft furnace body stove hypomere cupola well one side, because the ferrochrome smelting quantity of slag is very big; Iron notch is opened in shaft furnace body stove hypomere cupola well one side.
Further, described shaft furnace body stove epimere shaft is an inverted cone-shaped structure.
The leaning angle α of described shaft furnace body stove stage casing bosh sidewall is less than 70 °.
Described refrigerating unit is a water-cooling structure.
Also be provided with the insulation layer of anti-the material in the described shaft furnace body furnace shell.
Ferrochrome smelting of the present invention is with the shaft furnace and the method for smelting ferrochrome, and it comprises,
A. crude fuel such as ore, coke is heated rapidly to 1000~1300 ℃ by great bell and the funnel ferrochrome smelting shaft furnace epimere of packing into by the coal gas that rises;
B. the temperature hot blast that reaches (1250~1350 ℃) more than 1250 ℃ blasts shaft furnace and light coke before the air port from the bottom; By the air port oxygen and coal dust are sent into stage casing in the stove, coal powder injection 300-400kg/t, air port oxygen coal spray gun can blow 5-20% oxygen, to guarantee that coal dust is quick, efficient burning; In this zone oxygen, coal dust and the temperature of coke burning generation up to 2300~2500 ℃, melt rapidly in the prereduction ore deposit, and most of mineral reduce at this, and first slag forms;
C. lower furnace is the cupola well of splendid attire molten iron and slag, and the unreduced mineral of part continue reduction at this, and some chemical reactions such as desulfurization also carry out at this, finally generate qualified molten iron or alloy mother liquor;
D. use the hot consolidation ferrochrome agglomerate after prereduction is handled, coke load is low, and the direct reduction ratio of ferrochrome is higher than 60%, and the coal gas generating capacity reaches 4000-6000m
3/ t, throat temperature is up to 500-700 ℃.
Crude fuel such as ore, coke is packed into by great bell and funnel in the stove, and the hot blast that temperature reaches more than 1250 ℃ blasts shaft furnace and light coke before the air port through bustle pipe and air port from the bottom; In the process that furnace charge descends, molten drop drips and coal gas rises, ore is heated, melts and reduces.As the shaft furnace matallurgical products, last slag is discharged from the cinder notch device, and following slag and alloy hot metal are discharged from iron mouth device, and shaft furnace coal gas is discharged from gas export control.Refrigerating unit, refractory materials and furnace shell can be guaranteed to form fixed and smelt the space, make smelting process be continued to carry out.
The invention has the advantages that, adding carbon ferrochrome technology with steel scrap (or molten iron) compares, under same crude fuel, energy medium price and same molten steel quality condition, the production cost that shaft furnace is smelted mother liquor of stainless steel per ton can reduce about 300 yuan, has saved the smart lump ore resource of a large amount of ferrochrome simultaneously; And use shaft furnace self produced gas and a small amount of coke (or coal dust) energy medium as rotary hearth furnace and shaft furnace, can significantly reduce the consumption of electric energy.Fusing-reduction shaft furnace can also provide cleaning coal gas, helps alleviating the contradiction of short flow process steel-making enterprise coal gas shortage.
Use prereduction pellet for adapting to ferrochrome smelting, the edge air-flow comparatively develops; Coke load is low, and the coal gas generating capacity is big, the throat temperature height; The cohesive zone height reduces, the practical situation that root position moves down, and type of furnace design increases throat diameter consciously, reduces furnace throat, shaft and height of the furnace hearth, suitably strengthens furnace bosh, furnace abdominal height.In addition, also take intensive draught interval, expansion shaft furnace cooling area, raising body of heater cooling intensity; Furnace bottom, cupola well select for use high-grade anti-material a series of measures such as to build by laying bricks or stones, adapt to the difference between pig iron blast furnace and the ferrochrome shaft furnace.
Table 1. is produced the blast furnace of molten iron and the difference of shaft furnace structure of the present invention and processing parameter
Structure position | The ferrochrome smelting shaft furnace | Produce the blast furnace of molten iron |
Hotblast stove | The air port blast temperature is 1250~1350 ℃ | The air port blast temperature is 1000~1250 ℃ |
The coal gas dust removal device | The dry method coal gas dust removal device that has the coal gas cooling apparatus | Be generally wet method coal gas dust removal device |
Coal powder injection/low-purity oxygen plant | Because wind-warm syndrome and air blast oxygen enrichment percentage height have the coal powder injection ability of 300-400kg/t, use air port oxygen coal spray gun, but oxygen enrichment 5-20%.To guarantee that coal dust is quick, efficient burning | Ton iron coal powder injection ability generally is lower than 230kg/t. and is generally the forward and backward oxygen enrichment of gas blower, and oxygen enrichment percentage is lower than 8%. |
Type of furnace design | Use the hot consolidation ferrochrome agglomerate after prereduction is handled, coke load is low, and the direct reduction ratio of ferrochrome is higher than 60%, and the coal gas generating capacity reaches | Use agglomerate oxide pellet smelt, coke load is low, directly reduction ratio is lower than 30%, the coal gas generating capacity is only |
4000-6000m 3/ t, throat temperature is up to 500-700 ℃, and the edge air-flow comparatively develops; The cohesive zone height is low; Throat diameter is big, furnace throat, shaft height are shorter, and it is higher that cupola well adds furnace abdominal height, and bosh angle is less than 68 degree, and stack angle is doline greater than 90 degree bodies of heater. | 1000-1500m 3/ t, only 200-300 ℃ of throat temperature, throat diameter is less, cohesive zone height height, shaft is higher; Furnace bosh, bosh are shorter, and bosh angle is greater than 80 degree, and stack angle is less than 82 degree, and body of heater is and spins the shape of hanging down. | |
The body of heater cooling system | Furnace bottom, cupola well select for use the high-grade anti-material of non-carbonaceous to build by laying bricks or stones, and establish thermal insulation layer, enlarge the shaft furnace cooling area, improve the body of heater cooling intensity | Body of heater cooling entirely, cupola well selects for use carbonaceous material to build and establish water cooling wall by laying bricks or stones |
The cupola well design | Cupola well is shorter, and the dead bed depth design of cupola well only reaches more than 1530 ℃ to keep the containing chromium heating molten steel for 0.3-0.5 rice | Cupola well is higher; Dead bed depth is designed to 20% of cupola well diameter |
Beneficial effect of the present invention
Utilize shaft furnace smelting reduction of the present invention directly to prepare mother liquor of stainless steel following advantage arranged:
(1) production cost reduces greatly;
(2) productivity height, suitable scale operation contains the needs of chromium heating molten steel;
(3) use of chromite raw material is flexible, uses after making the hot consolidation ferrochrome agglomerate of prereduction or sintering after especially available inexpensive ferrochrome fine ore is handled;
(4) chrome content in the mother liquor is lower than GB high carbon ferro-chrome, and the reduction of chromite is easier, and energy consumption is lower;
(5) the comprehensive recovery height of chromium;
(6) can save a large amount of electric power, reduce the stainless steel cost.
Description of drawings
Fig. 1 is the structural representation of ferrochrome smelting shaft furnace of the present invention;
Fig. 2 is the synoptic diagram of ferrochrome smelting shaft furnace smelting technology flow process of the present invention and support equipment thereof.
Embodiment
Referring to Fig. 1, ferrochrome smelting shaft furnace of the present invention, it comprises, shaft furnace body 1, it forms one by furnace shell, refractory materials and smelts the space, is divided into the upper, middle and lower section; Stove epimere 101 is the shaft of heating zone, and this shaft is an inverted cone-shaped structure, and furnace throat 104 diameters are big, and furnace throat, shaft height are shorter; Stove stage casing 102 is the bosh of fusing-reduction zone, and its sidewall has a leaning angle α, and this leaning angle α is less than 70 °; Stove hypomere 103 is a cupola well, and it is higher that cupola well adds furnace abdominal height; Great bell and funnel 2 are arranged at the top of shaft furnace body stove epimere 101 shafts; Bustle pipe 3 is arranged at stove stage casing 12 1 sides; Air port 4 is arranged at 102 lower edges, stove stage casing; Refrigerating unit 5 is arranged in shaft furnace body 1 furnace shell, and this refrigerating unit is a water-cooling structure; Slag notch 6 is opened in shaft furnace body 1 stove hypomere 103 cupola wells one side; Iron notch 7 is opened in shaft furnace body stove hypomere 103 cupola wells one side.
Crude fuels such as the hot consolidation ferrochrome agglomerate ore after prereduction is handled, coke (composition sees Table 2, table 3, table 4) are packed into by great bell and funnel 1 in the stove, and the hot blast that temperature reaches more than 1250 ℃ blasts shaft furnace and light coke before the air port through bustle pipe 3 and air port 4 from the bottom; In the process that furnace charge descends, molten drop drips and coal gas rises, above-mentioned ore is heated, melts and reduces, and wherein the main chemical reactions of chrome ore is as follows:
The carbothermic reduction of chromium sesquioxide: Cr
2O
3+ 3C=2Cr+3CO;
The reduction of picotite: MgOCr
2O
3+ 3C=2Cr+MgO+3CO;
The generation of chromium carbide: Cr
2O
3+ 13/3C=2/3Cr
2C
2+ 3CO;
The reduction of chromite: 3FeOCr
2O
3+ 3C=3Fe+Cr
2O
3+ 3CO.
As the shaft furnace matallurgical products, last slag is discharged from slag notch 6 cinder notch devices, and following slag and alloy hot metal are discharged from iron notch 7 iron mouth devices, and shaft furnace coal gas is discharged from gas export control 8.
Referring to Fig. 2, smelt and sieve, measure by ore deposit groove facility 11 with crude fuel; Send in the shaft furnace 14 in proper order in accordance with regulations by material loading facility 12; In the process that furnace charge descends, molten drop drips and coal gas rises, above-mentioned ore is heated, melts and reduces; And by hot-metal ladle and carriage 21 transportations.Wherein, coal powder blowing device 13 has the coal powder injection ability of 400 kilograms of ton iron, and uses oxygen coal spray gun, to guarantee that coal dust is quick, efficient burning; Dust removal installation 15, coal gas cooling device 16, cyclone dust collector 17 and bag-type dust collector 18 can be reduced to 15mg/Nm with final dust content of gas
3Below, not only protected atmospheric environment but also improved gas quality; Hotblast stove 19 adopts ball formula structure and waste-heat recovery device, uses self-produced shaft furnace coal gas (lower heating value 6000~8000KJ/Nm
3) blast temperature can be heated to 1250~1300 ℃; Air-blast device 20 is furnished with BBD dehumidification unit, can reduce to 10g/Nm to blast humidity
3Below.
Above-mentioned all facilities, device pass through role separately, provide the shaft furnace ordinary production required condition, make shaft furnace smelt 1530 ℃ of production processes that contain chromium heating molten steel (product composition sees Table 5) and are continued to carry out.
The chemical ingredients of table 2. prereduction hot consolidation ferrochrome pelletizing (ferrochrome smelting shaft furnace raw material), %
Heat | Temperature/℃ | TFe | TCr | | S | |
1 # | 1350 | 34.90 | 17.14 | 0.020 | 0.230 | |
2 # | 1350 | 31.53 | 15.49 | 0.020 | 0.170 | |
3 # | 1350 | 32.33 | 15.90 | 0.018 | 0.184 | |
4 # | 1350 | 30.62 | 15.13 | 0.017 | 0.172 | |
5 # | 1350 | 35.68 | 17.29 | 0.026 | 0.191 |
Working condition: 1350 ℃ of reduction of rotary hearth furnace 30min.
The composition (technical analysis) of table 3. ferrochrome smelting shaft furnace injection coal, %
Coal | H 2O | Ash | VM | C | P | S |
Become forever | 1.78 | 11.14 | 9.12 | 77.96 | 0.0063 | 0.205 |
Refreshing mansion | 6.77 | 6.18 | 30.15 | 56.90 | 0.0098 | 0.266 |
0.4 refreshing mansion+0.6 Yongcheng | 3.78 | 9.16 | 17.53 | 69.54 | 0.0089 | 0.258 |
The technical analysis of coke of table 4. ferrochrome smelting shaft furnace, %
H 2O | Ash | VM | C | P | S |
4.96 | 10.71 | 1.01 | 83.32 | 0.025 | 0.525 |
0 | 11.27 | 1.06 | 87.71 | 0.026 | 0.553 |
Table 5. contains the composition of chromium heating molten steel product
Heat | TFe (%) | TCr (%) | Si (%) | P (%) | S (%) | C (%) | Cr/(Cr+Fe) |
1 # | 64.4 | 26.5 | 0.2 | <0.03 | 0.1 | 7.4 | 29.15 |
2 # | 65.8 | 25.4 | 0.1 | <0.01 | 0.062 | 7.3 | 27.85 |
3 # | 61.0 | 26.5 | 1.1 | <0.02 | 0.12 | 7.9 | 30.29 |
4 # | 62.8 | 26.3 | 0.9 | <0.02 | 0.065 | 7.2 | 29.52 |
5 # | 68.0 | 23.8 | <0.1 | <0.01 | 0.21 | 7.1 | 25.93 |
Hot consolidation ferrochrome agglomerate after the present invention can adopt the prereduction of shaft furnace type smelting reduction to handle to Chinese large-sized stainless steel production base, obtain the chromium heating molten steel that contains directly prepare mother liquor of stainless steel, then the stainless steel new process of production flow process of becoming a useful person through converter high speed decarburization → VOD or AOD refining → continuous casting → tandem rolling set up significant.
Claims (4)
1. a ferrochrome smelting shaft furnace is characterized in that, it comprises,
The shaft furnace body, it forms one by furnace shell, refractory materials and smelts the space, is divided into the upper, middle and lower section; The stove epimere is the shaft of heating zone; The stove stage casing is the bosh of fusing-reduction zone, and its sidewall has a leaning angle α; The stove hypomere is a cupola well;
Great bell and funnel are arranged at the top of shaft furnace body stove top shaft;
Bustle pipe is arranged at stove stage casing one side;
The air port is arranged at lower edge, stove stage casing;
Refrigerating unit is arranged in the body furnace shell;
Slag notch is opened in shaft furnace body stove hypomere cupola well one side;
Iron notch is opened in shaft furnace body stove hypomere cupola well one side;
Described shaft furnace body stove epimere shaft is an inverted cone-shaped structure.
2. ferrochrome smelting shaft furnace as claimed in claim 1 is characterized in that, the leaning angle α of described shaft furnace body stove stage casing bosh sidewall is less than 70 °.
3. ferrochrome smelting shaft furnace as claimed in claim 1 is characterized in that, described refrigerating unit is a water-cooling structure.
4. ferrochrome smelting shaft furnace as claimed in claim 1 is characterized in that, also is provided with the insulation layer of anti-the material in the described shaft furnace body furnace shell.
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CN109321702A (en) * | 2018-11-23 | 2019-02-12 | 山西太钢不锈钢股份有限公司 | The production method of chromium-containing molten iron |
US11703280B2 (en) | 2019-03-08 | 2023-07-18 | Maerz Ofenbau Ag | Method and shaft furnace for burning carbon-containing material in a shaft furnace |
CN111397366A (en) * | 2020-05-06 | 2020-07-10 | 江苏必瑞驰科技有限公司 | Scrap steel melting furnace device with oxygen combustion gun as heat source |
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CN113791109B (en) * | 2021-09-17 | 2023-11-17 | 苏州大学 | Measuring device for soft melting and dripping performance of iron-containing raw material |
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