CN100494606C - A kind of building template with oriented strand board as base material and its manufacturing method - Google Patents
A kind of building template with oriented strand board as base material and its manufacturing method Download PDFInfo
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Abstract
Description
技术领域 technical field
本发明涉及一种以定向结构刨花板为基材的建筑模板,本发明还涉及该建筑模板的制造方法。The invention relates to a building template with an oriented structure particle board as a base material, and also relates to a manufacturing method of the building template.
背景技术 Background technique
目前,建筑模板的需求量呈现逐日上升的趋势。过去,我国普遍采用多层胶合板、竹材胶合板乃至实木或钢材制造建筑模板。采用实木和多层胶合板制造模板,每年耗费了大量的大径级原木资源;采用竹材胶合板和钢材制造模板,成本昂贵,难以普及,而且资源消耗严重。At present, the demand for building templates is showing an increasing trend day by day. In the past, multi-layer plywood, bamboo plywood and even solid wood or steel were commonly used to make building templates in my country. The use of solid wood and multi-layer plywood to make formwork consumes a large amount of large-diameter log resources every year; the use of bamboo plywood and steel to make formwork is expensive, difficult to popularize, and consumes serious resources.
定向结构刨花板是一种新型结构用材。20世纪90年代,由南京林业大学承担国家“八五”科技攻关实现国产化成套工艺与设备,在全国推广建厂,并申报了发明专利(专利号为95111192.2、名称为“定向结构刨花板制作方法”)。定向结构刨花板以小径级木材(包括枝桠材)为原料,以耐水性合成树脂为胶粘剂,经过系列工序制造而成,具备优良的综合性能:(1)物理性能:抗湿变、抗翘曲,防腐蚀、防虫蛀,隔热、隔声;(2)力学性能:结构紧密,强重比高,各向异性;(3)环境性能:甲醛释放量低;(4)加工性能:易锯、易钉、易钻、易刨、易砂,可油漆,可贴面。因此,定向结构刨花板一直作为结构用材,广泛应用于建筑场合。分析建筑模板的应用实际,其性能要求主要包括:(1)较高的平面抗弯曲性能;(2)较强的表面耐水性;(3)较高的表面防粘性;(4)容易进行锯、钉加工。由于定向结构刨花板的构成单元为窄长刨花,长达100-150mm,宽至50-75mm,厚至0.8-1.0mm,导致定向结构刨花板表面比较粗糙,不宜直接用作混凝土固化用的模板。虽然对普通人造板进行贴面早已有之,但以定向结构刨花板为基材、通过复合贴面材料改善其性能的技术应用于建筑模板领域,则未见报道。Oriented strand board is a new type of structural material. In the 1990s, Nanjing Forestry University undertook the national "Eighth Five-Year Plan" scientific and technological research to realize the localization of complete sets of technology and equipment, promoted the construction of factories across the country, and applied for a patent for invention (patent number 95111192.2, named "Oriented Structure Particleboard Manufacturing Method "). Oriented strand board is made of small-diameter wood (including branch wood) and water-resistant synthetic resin as adhesive. It is manufactured through a series of processes and has excellent comprehensive properties: (1) Physical properties: moisture resistance, warping resistance, Anti-corrosion, anti-moth, heat insulation, sound insulation; (2) mechanical properties: compact structure, high strength-to-weight ratio, anisotropy; (3) environmental performance: low formaldehyde emission; (4) processing performance: easy sawing, Easy to nail, drill, plan, sand, paint and veneer. Therefore, oriented strand board has been used as a structural material and is widely used in construction occasions. Analyzing the actual application of building formwork, its performance requirements mainly include: (1) high plane bending resistance; (2) strong surface water resistance; (3) high surface anti-adhesion; (4) easy to saw , Nail processing. Since the constituent units of OSB are narrow and long shavings, which are 100-150mm long, 50-75mm wide, and 0.8-1.0mm thick, the surface of OSB is relatively rough, so it is not suitable for direct use as a formwork for concrete curing. Although the veneering of ordinary wood-based panels has long been known, there is no report on the application of the technology of using oriented strand board as the base material and improving its performance through composite veneer materials in the field of building formwork.
发明内容 Contents of the invention
本发明的目的在于提供一种利用定向结构刨花板替代多层胶合板作为基材,采用复合贴面材料制造的耐水、防粘、高强度的复合建筑模板。The object of the present invention is to provide a water-resistant, anti-adhesive, high-strength composite building formwork made of oriented strand board instead of multi-layer plywood as the base material and composite veneer material.
本发明的另一个目的是提供上述建筑模板的制造方法。Another object of the present invention is to provide a method for manufacturing the above-mentioned building formwork.
本发明的目的是通过下列技术措施实现的:The purpose of the present invention is achieved through the following technical measures:
一种以定向结构刨花板为基材的建筑模板,该建筑模板以定向结构刨花板为基板,基板表面贴有单板。根据需要,可以只贴单板,实践表明效果尚可;但如果需要进一步提高耐水性和对水泥的耐粘性,也可以在单板表面再贴浸渍纸。The utility model relates to a building formwork with an oriented strand board as a base material. The building formwork uses an oriented strand board as a base plate, and a veneer is pasted on the surface of the base plate. According to the needs, only the veneer can be pasted, and the practice shows that the effect is acceptable; but if it is necessary to further improve the water resistance and the resistance to cement adhesion, the impregnated paper can also be pasted on the surface of the veneer.
所述的建筑模板,其中定向结构刨花板指采用长条形刨花,使用酚醛树脂、脲醛树脂、三聚氰胺甲醛树脂、异氰酸酯或上述合成树脂的改性树脂为胶粘剂,热压而成的结构型板材。长条形刨花通常可以选用长50-150mm,宽10-75mm,厚0.1~1.0mm。The building formwork described above, wherein the oriented strand board refers to a structural board made of strip-shaped shavings and hot-pressed using phenolic resin, urea-formaldehyde resin, melamine-formaldehyde resin, isocyanate or a modified resin of the above-mentioned synthetic resins as an adhesive. Long shavings can usually be selected to be 50-150mm long, 10-75mm wide, and 0.1-1.0mm thick.
所述的建筑模板,其中单板为木材薄片,厚度为0.2~3.0mm,优选厚度0.8~2.0mm,可采用旋切、锯切或刨切方法形成,树种涵盖天然林和人工林,幅面尺寸根据定向结构刨花板的幅面尺寸确定,可采用拼接的方法生产所需幅面尺寸的单板。The building formwork described above, wherein the veneer is a thin sheet of wood with a thickness of 0.2-3.0mm, preferably 0.8-2.0mm, which can be formed by rotary cutting, sawing or planing, and the tree species cover natural forests and artificial forests, and the format size According to the format size of OSB, splicing method can be used to produce the veneer with required format size.
所述的建筑模板,其中单板纹理方向与定向结构刨花板的表层铺装方向垂直或平行,单板层数控制在1-2层,且当单板层数为2层时相邻单板层之间保持方向交叉。The building formwork described above, wherein the grain direction of the veneer is perpendicular to or parallel to the pavement direction of the surface layer of the oriented strand board, the number of veneer layers is controlled at 1-2 layers, and when the number of veneer layers is 2 layers, the adjacent veneer layers maintain direction intersections.
定向结构刨花板模仿胶合板,一般呈3层结构,上下两层刨花的铺装方向与板的长度方向平行,中间层刨花的铺装方向垂直,这样板才不容易发生变形。由于定向结构刨花板采用的刨花为长条形刨花,因此,所谓表层铺装方向即与表层结构中长条形刨花长边相平行的方向。另外,由于单板也是有纹理方向(即:细胞排列方向或树的生长方向)的,在贴面的时候,就存在单板纹理方向与定向结构板表层铺装方向一致或垂直的问题,采用相邻层之间方向交叉可增强板的抗弯性能。Oriented strand board imitates plywood, and generally has a 3-layer structure. The paving direction of the upper and lower layers of shavings is parallel to the length direction of the board, and the paving direction of the middle layer of shavings is vertical, so that the board is not easy to deform. Since the shavings used in oriented strand board are strip-shaped shavings, the so-called surface paving direction is the direction parallel to the long side of the long strip-shaped shavings in the surface structure. In addition, since the veneer also has a texture direction (that is, the cell arrangement direction or the tree growth direction), when veneering, there is a problem that the veneer texture direction is consistent with or perpendicular to the surface pavement direction of the oriented structural board. The direction crossing between adjacent layers can enhance the flexural performance of the plate.
所述的建筑模板,单板覆贴定向结构刨花板所用胶粘剂为热固性树脂。常用的热固性树脂为酚醛树脂、脲醛树脂或三聚氰胺甲醛树脂。这些树脂都是耐水性合成树脂胶粘剂。In the construction formwork described above, the adhesive used for covering the veneer with the oriented strand board is a thermosetting resin. Commonly used thermosetting resins are phenolic resins, urea-formaldehyde resins or melamine-formaldehyde resins. These resins are water-resistant synthetic resin adhesives.
所述的建筑模板,其中浸渍纸采用合成树脂浸渍、刷涂或辊涂的方法或这些方法相互结合的方式处理饰面板原纸,再干燥定型而成。饰面板原纸要求定量在70g/m2以上效果较好。所用的合成树脂包括酚醛树脂、脲醛树脂、三聚氰胺甲醛树脂、邻苯二甲酸二丙烯酯树脂等热固性树脂,以及这些树脂的改性树脂。浸渍纸采用的合成树脂用量为饰面板原纸绝干质量的10~200%。The building formwork described above, wherein the impregnated paper is formed by treating the veneer base paper by synthetic resin impregnation, brush coating or roller coating or a combination of these methods, and then drying and shaping. The base paper of the veneer panel requires a basis weight of 70g/ m2 or more, and the effect is better. The synthetic resins used include thermosetting resins such as phenolic resins, urea-formaldehyde resins, melamine-formaldehyde resins, dipropylene phthalate resins, and modified resins of these resins. The amount of synthetic resin used in the impregnated paper is 10-200% of the absolute dry mass of the veneer base paper.
所述的建筑模板的制造方法,当只在定向结构刨花板表面贴单板时包括下列步骤:The manufacturing method of the described building formwork comprises the following steps when only veneer is pasted on the surface of the oriented strand board:
(1)对定向结构刨花板进行表面定厚砂光处理;(1) Carry out surface thickness sanding treatment to oriented strand board;
(2)采用耐水性合成树脂胶粘剂,覆贴合适厚度的木材单板;(2) Water-resistant synthetic resin adhesive is used to cover wood veneers of appropriate thickness;
(3)热压形成所需建筑模板。(3) Hot pressing to form the required building formwork.
所述的建筑模板的制造方法,当在定向结构刨花板表面贴单板和浸渍纸时包括下列步骤:The manufacturing method of the described building formwork comprises the following steps when pasting veneer and impregnated paper on the surface of the oriented strand board:
(1)对定向结构刨花板进行表面定厚砂光处理;(1) Carry out surface thickness sanding treatment to oriented strand board;
(2)采用耐水性合成树脂胶粘剂,覆贴合适厚度的木材单板;(2) Water-resistant synthetic resin adhesive is used to cover wood veneers of appropriate thickness;
(3)对单板表面进行精砂或不精砂;(3) Fine sand or non-fine sand on the surface of the veneer;
(4)在单板表面贴合成树脂浸渍纸;(4) Paste synthetic resin impregnated paper on the surface of the veneer;
(5)热压形成所需建筑模板。(5) Hot pressing to form the required building formwork.
选用的定向结构刨花板和单板的厚度可根据建筑模板的厚度要求进行调节,对单板表面精砂的程度可根据建筑场合对模板表面光洁度的要求调节,浸渍纸的合成树脂用量可根据建筑场合对模板耐水性的要求调节,常用范围为原纸绝干质量的10~200%。The thickness of the selected OSB and veneer can be adjusted according to the thickness requirements of the construction formwork, the degree of fine sand on the surface of the veneer can be adjusted according to the requirements of the construction site for the surface finish of the formwork, and the amount of synthetic resin impregnated paper can be adjusted according to the construction site Adjust the water resistance requirements of the template, and the commonly used range is 10-200% of the absolute dry mass of the base paper.
所述的耐水性合成树脂胶粘剂为酚醛树脂、脲醛树脂或三聚氰胺甲醛树脂。The water-resistant synthetic resin adhesive is phenolic resin, urea-formaldehyde resin or melamine-formaldehyde resin.
建筑模板的幅面根据需要可调,一般为1220mm×2440mm;厚度也可根据需要调整,建筑模板的成品厚度一般分为12mm,15mm,18mm,21mm四种标准。由于贴单板和浸渍纸,所以需要将定向刨花板基材的厚度作相应调整。例如,制造15mm厚的模板,双面贴1.7mm的单板,如果直接用15mm厚度的定向刨花板,制造的模板厚度肯定超过15mm,因此,必须通过定厚砂光,将定向刨花板的厚度降低,同时在热压时控制单板的压缩率,使最终模板的厚度能接近于15mm。The width of the building formwork can be adjusted according to the needs, generally 1220mm×2440mm; the thickness can also be adjusted according to the needs. The finished thickness of the building formwork is generally divided into four standards: 12mm, 15mm, 18mm, and 21mm. Due to veneer and impregnated paper, the thickness of OSB substrate needs to be adjusted accordingly. For example, to manufacture a template with a thickness of 15mm and stick a veneer of 1.7mm on both sides, if the oriented strand board with a thickness of 15mm is directly used, the thickness of the manufactured template must exceed 15mm. At the same time, the compression rate of the veneer is controlled during hot pressing, so that the thickness of the final template can be close to 15mm.
本发明的有益效果:Beneficial effects of the present invention:
在定向刨花板表面进行覆贴加工,既可利用定向结构刨花板自身优良的物理力学性能,也充分发挥了贴面材料(单板、浸渍纸)在抗弯曲、防混凝土粘附等方面的增强优势(详见实施例效果数据),同时解决了小径材的利用并节约了大量的大径级木材,实现了“小材大用、劣材优用”。该建筑模板的制造方法简单易行,便于工业化生产。Lamination processing on the surface of oriented strand board can not only take advantage of the excellent physical and mechanical properties of oriented strand board itself, but also give full play to the enhanced advantages of veneer materials (veneer, impregnated paper) in terms of bending resistance and concrete adhesion resistance ( See the embodiment effect data for details), solve the utilization of small-diameter timber and save a large amount of large-diameter grade timber simultaneously, have realized " small timber big use, inferior timber optimal use ". The manufacturing method of the building formwork is simple and easy to implement, and is convenient for industrialized production.
具体实施方式 Detailed ways
以下通过实施例对本发明作进一步的阐述,但不限制本发明。The present invention will be further described below by way of examples, but the present invention is not limited.
一般性说明:General Notes:
实施例中采用的合成树脂胶粘剂可以从市场上购买得到,具体型号的树脂性能可参见生产厂商的产品说明书。The synthetic resin adhesive used in the examples can be purchased from the market, and the performance of the specific type of resin can be found in the manufacturer's product specification.
浸渍纸的制备方法为采用合成树脂浸渍、刷涂或辊涂的方法或这些方法相互结合的方式处理饰面板原纸,再干燥定型形成。饰面板原纸要求定量在70g/m2以上,合成树脂用量为饰面板原纸绝干质量的10~200%。The impregnated paper is prepared by treating the veneer base paper by synthetic resin impregnation, brush coating or roller coating or a combination of these methods, and then drying and shaping. The base paper of the veneer is required to be more than 70g/ m2 , and the amount of synthetic resin is 10-200% of the absolute dry mass of the base paper of the veneer.
实施例中所制成的模板性能测试的方法均根据GB/T 17657-1999“人造板及饰面人造板理化性能试验方法”进行测试。The methods for testing the performance of the templates made in the examples are all tested according to GB/T 17657-1999 "Testing methods for physical and chemical properties of wood-based panels and facing wood-based panels".
实施例1:杨木厚单板贴面,不贴浸渍纸Example 1: Poplar thick veneer veneer without impregnated paper
采用11mm厚,密度为0.65g/cm3的定向结构刨花板为基板,将基板定厚砂光为10.5mm,采用固含量为37.5%的酚醛树脂胶粘剂,施胶量为110g/m2,双面贴1.7mm厚度的杨木单板,单板纹理方向与定向刨花板表层铺装方向平行,采用热压方法覆贴。热压条件为:热压温度:125℃:热压压力:0.9MPa;热压时间:3min。制成的模板厚度为12.4mm(达到±0.5mm的公差要求),吸水厚度膨胀率从原定向刨花板的22%降低到10.75%,抗弯强度高达37.5MPa,弹性模量达到6286.32MPa。Oriented strand board with a thickness of 11mm and a density of 0.65g/cm 3 is used as the substrate, and the thickness of the substrate is sanded to 10.5mm, and a phenolic resin adhesive with a solid content of 37.5% is used, and the sizing amount is 110g/m 2 , double-sided Paste poplar veneer with a thickness of 1.7mm, the grain direction of the veneer is parallel to the pavement direction of the surface layer of oriented strand board, and it is pasted by hot pressing method. The hot-pressing conditions are: hot-pressing temperature: 125° C.; hot-pressing pressure: 0.9 MPa; hot-pressing time: 3 min. The thickness of the template made is 12.4mm (reaching the tolerance requirement of ±0.5mm), the water absorption thickness expansion rate is reduced from 22% of the original oriented strand board to 10.75%, the bending strength is as high as 37.5MPa, and the elastic modulus is 6286.32MPa.
实施例2:杨木厚单板贴面,贴酚醛树脂浸渍纸Example 2: Poplar thick veneer veneer, pasted with phenolic resin impregnated paper
采用11mm厚,密度为0.65g/cm3的定向结构刨花板为基板,将基板定厚砂光为10.5mm,采用固含量为37.5%的酚醛树脂胶粘剂,施胶量为110g/m2,双面贴1.7mm厚度的杨木单板,单板纹理方向与定向刨花板表层铺装方向平行,再双面贴酚醛树脂浸渍纸(浸渍纸的制备方法为采用酚醛树脂浸渍与辊涂相互结合的方式处理饰面板原纸,再干燥定型形成。饰面板原纸定量在80g/m2,酚醛树脂用量为饰面板原纸绝干质量的100%),采用热压方法覆贴。热压条件为:热压温度:135℃;热压压力:1.1MPa;热压时间:5min。制成的模板厚度为12.49mm(达到±0.5mm的公差要求),吸水厚度膨胀率从原定向刨花板的22%降低到8.76%,抗弯强度高达54.11MPa,弹性模量达到6551.51MPa。Oriented strand board with a thickness of 11mm and a density of 0.65g/cm 3 is used as the substrate, and the thickness of the substrate is sanded to 10.5mm, and a phenolic resin adhesive with a solid content of 37.5% is used, and the glue amount is 110g/m 2 , double-sided Paste poplar veneer with a thickness of 1.7mm, the grain direction of the veneer is parallel to the pavement direction of the surface layer of oriented strand board, and then paste phenolic resin impregnated paper on both sides (the preparation method of impregnated paper is the combination of phenolic resin impregnated and roller coating. The base paper for the veneer is formed by drying and shaping. The basis weight of the base paper for the veneer is 80g/m 2 , and the amount of phenolic resin is 100% of the dry mass of the base paper for the veneer). The hot-pressing conditions are: hot-pressing temperature: 135° C.; hot-pressing pressure: 1.1 MPa; hot-pressing time: 5 min. The thickness of the template made is 12.49mm (tolerance requirement of ±0.5mm), the water absorption thickness expansion rate is reduced from 22% of the original oriented strand board to 8.76%, the bending strength is as high as 54.11MPa, and the elastic modulus is 6551.51MPa.
实施例3:杨木薄单板贴面,贴酚醛树脂改性树脂浸渍纸Example 3: poplar veneer veneer, paste phenolic resin modified resin impregnated paper
采用12mm厚,密度为0.65g/cm3的定向结构刨花板为基板,将基板定厚砂光为11.0mm,采用固含量为37.5%的酚醛树脂胶粘剂,施胶量为60g/m2,双面贴0.8mm厚度的杨木单板,单板纹理方向与定向刨花板表层铺装方向平行,再双面贴酚醛树脂改性树脂浸渍纸(浸渍纸的制备:酚醛树脂采用脲醛树脂改性(脲醛树脂与酚醛树脂比例为7:3),浸渍和辊涂饰面板原纸,再干燥定型形成。饰面板原纸定量在85g/m2,改性树脂用量为饰面板原纸绝干质量的150%),采用热压方法覆贴。热压条件为:热压温度:130℃;热压压力:1.1MPa;热压时间:3min。制成的模板厚度为11.67mm(达到±0.5mm的公差要求),吸水厚度膨胀率从原定向刨花板的22%降低到11.48%,抗弯强度高达28.94MPa,弹性模量达到3723.36MPa。Oriented strand board with a thickness of 12mm and a density of 0.65g/cm 3 is used as the substrate, and the thickness of the substrate is sanded to 11.0mm, and a phenolic resin adhesive with a solid content of 37.5% is used, and the sizing amount is 60g/m 2 , double-sided Paste poplar veneer with a thickness of 0.8mm, the grain direction of the veneer is parallel to the pavement direction of the surface layer of oriented strand board, and then paste phenolic resin modified resin impregnated paper on both sides (preparation of impregnated paper: phenolic resin is modified with urea-formaldehyde resin (urea-formaldehyde resin The ratio of the base paper to the phenolic resin is 7:3), impregnating and rolling the base paper of the decorative panel, and then drying and shaping. Pressure method overlay. The hot-pressing conditions are: hot-pressing temperature: 130° C.; hot-pressing pressure: 1.1 MPa; hot-pressing time: 3 min. The thickness of the template made is 11.67mm (tolerance requirement of ±0.5mm), the water absorption thickness expansion rate is reduced from 22% of the original oriented strand board to 11.48%, the bending strength is as high as 28.94MPa, and the elastic modulus is 3723.36MPa.
实施例4:马尾松薄单板贴面,贴酚醛树脂浸渍纸Example 4: Masson pine thin veneer veneer, pasted with phenolic resin impregnated paper
采用12mm厚,密度为0.65g/cm3的定向结构刨花板为基板,将基板定厚砂光为10.5mm,采用固含量为37.5%的酚醛树脂胶粘剂,施胶量为80g/m2,双面贴0.8mm厚度的马尾松单板,单板纹理方向与定向刨花板表层铺装方向垂直,再双面贴酚醛树脂浸渍纸(浸渍纸的制备方法为采用酚醛树脂浸渍的方式处理饰面板原纸,再干燥定型形成。饰面板原纸定量在80g/m2,酚醛树脂用量为饰面板原纸绝干质量的50%),采用热压方法覆贴。热压条件为:热压温度:125℃;热压压力:1.0MPa;热压时间:4min。制成的模板厚度为12.08mm(达到±0.5mm的公差要求),吸水厚度膨胀率从原定向刨花板的22%降低到11.14%,抗弯强度高达31.16MPa,弹性模量达到3867.80MPa。Oriented strand board with a thickness of 12mm and a density of 0.65g/cm3 is used as the substrate, and the thickness of the substrate is sanded to 10.5mm, and a phenolic resin adhesive with a solid content of 37.5% is used, and the glue amount is 80g/m 2 . Masson pine veneer with a thickness of 0.8mm, the grain direction of the veneer is perpendicular to the pavement direction of the surface layer of the oriented strand board, and then pasted with phenolic resin impregnated paper on both sides (the impregnated paper is prepared by treating the veneer base paper with phenolic resin impregnation, and then drying Shaping and forming. The weight of the base paper for the veneer is 80g/m 2 , and the amount of phenolic resin is 50% of the absolute dry mass of the base paper for the veneer), and it is pasted by hot pressing. The hot-pressing conditions are: hot-pressing temperature: 125° C.; hot-pressing pressure: 1.0 MPa; hot-pressing time: 4 min. The thickness of the template made is 12.08mm (tolerance requirement of ±0.5mm), the water absorption thickness expansion rate is reduced from 22% of the original oriented strand board to 11.14%, the bending strength is as high as 31.16MPa, and the elastic modulus is 3867.80MPa.
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| CN102501275B (en) * | 2011-11-03 | 2013-12-25 | 福建农林大学 | Impregnated paper composite fir core board and production method thereof |
| CN103452307A (en) * | 2013-08-21 | 2013-12-18 | 薛保东 | Novel building template and preparation process thereof |
| CN107322728A (en) * | 2017-07-12 | 2017-11-07 | 明光市新丰新型材料有限公司 | A kind of light granules partition plate and preparation method thereof |
| CN107471337A (en) * | 2017-08-14 | 2017-12-15 | 柳州市林道科技有限公司 | A kind of preparation technology of multifunctional artificial sheet material |
| CN108943201A (en) * | 2018-07-26 | 2018-12-07 | 广西丰林木业集团股份有限公司 | A kind of superpower particieboard of veneer facing and its manufacturing process |
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| CN1122745A (en) * | 1995-09-14 | 1996-05-22 | 南京林业大学 | Method for mfg. oriented structure shaving board |
| CN2568755Y (en) * | 2002-09-12 | 2003-08-27 | 中国林业科学研究院木材工业研究所 | Composite cement formwork |
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| JPH0617535A (en) | 1992-07-02 | 1994-01-25 | Kana Flex Corp Kk | Working method for board material building using the same |
| CN1122745A (en) * | 1995-09-14 | 1996-05-22 | 南京林业大学 | Method for mfg. oriented structure shaving board |
| CN1464156A (en) * | 2002-06-03 | 2003-12-31 | 廊坊思创新技术有限公司 | Shuttering made of novel composite material and process for making the same |
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