CN100444730C - 用酰胺化合物促进植物生长的方法 - Google Patents
用酰胺化合物促进植物生长的方法 Download PDFInfo
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- CN100444730C CN100444730C CNB2004800245821A CN200480024582A CN100444730C CN 100444730 C CN100444730 C CN 100444730C CN B2004800245821 A CNB2004800245821 A CN B2004800245821A CN 200480024582 A CN200480024582 A CN 200480024582A CN 100444730 C CN100444730 C CN 100444730C
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- plant
- methyl
- amide compound
- alkyl
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- -1 amide compounds Chemical class 0.000 title claims abstract description 121
- 238000000034 method Methods 0.000 title claims abstract description 31
- 230000008635 plant growth Effects 0.000 title abstract description 9
- 229910052736 halogen Inorganic materials 0.000 claims abstract description 17
- 150000002367 halogens Chemical class 0.000 claims abstract description 15
- 230000012010 growth Effects 0.000 claims abstract description 14
- 241000196324 Embryophyta Species 0.000 claims description 47
- 239000000203 mixture Substances 0.000 claims description 18
- 150000001875 compounds Chemical class 0.000 claims description 17
- 235000013399 edible fruits Nutrition 0.000 claims description 10
- 229930182692 Strobilurin Natural products 0.000 claims description 9
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 8
- 235000013311 vegetables Nutrition 0.000 claims description 7
- 241000894006 Bacteria Species 0.000 claims description 6
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- 229940118790 boscalid Drugs 0.000 claims description 6
- WYEMLYFITZORAB-UHFFFAOYSA-N boscalid Chemical compound C1=CC(Cl)=CC=C1C1=CC=CC=C1NC(=O)C1=CC=CN=C1Cl WYEMLYFITZORAB-UHFFFAOYSA-N 0.000 claims description 6
- HZRSNVGNWUDEFX-UHFFFAOYSA-N pyraclostrobin Chemical compound COC(=O)N(OC)C1=CC=CC=C1COC1=NN(C=2C=CC(Cl)=CC=2)C=C1 HZRSNVGNWUDEFX-UHFFFAOYSA-N 0.000 claims description 6
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- UFEODZBUAFNAEU-NLRVBDNBSA-N fluoxastrobin Chemical compound C=1C=CC=C(OC=2C(=C(OC=3C(=CC=CC=3)Cl)N=CN=2)F)C=1C(=N/OC)\C1=NOCCO1 UFEODZBUAFNAEU-NLRVBDNBSA-N 0.000 claims description 3
- ZOTBXTZVPHCKPN-HTXNQAPBSA-N kresoxim-methyl Chemical compound CO\N=C(\C(=O)OC)C1=CC=CC=C1COC1=CC=CC=C1C ZOTBXTZVPHCKPN-HTXNQAPBSA-N 0.000 claims description 3
- JHIPUJPTQJYEQK-ZLHHXESBSA-N orysastrobin Chemical compound CNC(=O)C(=N\OC)\C1=CC=CC=C1CO\N=C(/C)\C(=N\OC)\C(\C)=N\OC JHIPUJPTQJYEQK-ZLHHXESBSA-N 0.000 claims description 3
- 239000011708 vitamin B3 Substances 0.000 claims description 3
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- DFPAKSUCGFBDDF-UHFFFAOYSA-N Nicotinamide Chemical compound NC(=O)C1=CC=CN=C1 DFPAKSUCGFBDDF-UHFFFAOYSA-N 0.000 claims description 2
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- 125000000217 alkyl group Chemical group 0.000 abstract description 25
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract description 20
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- 125000001424 substituent group Chemical group 0.000 abstract description 4
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- 230000001737 promoting effect Effects 0.000 abstract 1
- 239000002585 base Substances 0.000 description 39
- 229910052801 chlorine Inorganic materials 0.000 description 18
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 17
- 239000000460 chlorine Substances 0.000 description 16
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- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 5
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Abstract
用于处理需要生长促进的植物的方法包括对所述植物、对它们从其生长的种子或者对它们生长的场所施加非植物毒性的有效的植物生长促进量的具有式A-CO-NR1R2的酰胺化合物,其中A为芳基或具有1-3个选自O、N和S的杂原子的芳族或非芳族5或6员杂环;其中芳基或杂环可以有或没有1、2或3个彼此独立地选自烷基、卤素、CHF2、CF3、烷氧基、卤代烷氧基、烷硫基、烷基亚磺酰基和烷基磺酰基的取代基;R1为氢原子;R2为可以有或没有1、2或3个彼此独立地选自烷基、链烯基、炔基、烷氧基、链烯氧基、炔氧基、环烷基、环烯基、环烷氧基、环烯氧基、苯基和卤素的取代基的苯基或环烷基,其中脂族和脂环族基团可以部分或全部地卤代和/或脂环族基团可以由1-3个烷基取代,并且其中苯基可以有1-5个卤原子和/或1-3个彼此独立地选自烷基、卤代烷基、烷氧基、卤代烷氧基、烷硫基和卤代烷硫基的取代基,并且其中酰胺苯基可以与或不与饱和5员环稠合,该饱和5员环可以用或不用一个或多个烷基取代和/或可以有选自O和S的杂原子。
Description
本发明涉及能够诱导正的生长调节响应的植物处理新方法。
本说明书中使用的术语“用于调节植物生长的方法”或者术语“生长调节方法”或者词语“生长调节”的使用或者使用词语“调节”的其它术语意指试图改进植物的一些特性、有别于农药作用的各种植物响应,农药作用的目的是破坏或阻碍植物或生命体的生长。因此,本发明实施中使用的化合物的用量对于要处理的植物是非植物毒性的。
更明确地,本发明涉及使用某些酰胺化合物,尤其是烟酰胺化合物以诱导生长调节响应。
EP-A 0545099描述了酰胺衍生物和它们抗葡萄孢属(Botrytis)的用途。没有公开关于植物生长的促进效果。
本发明的目的是为了得到更好的植物、更高的作物产量、更好的作物质量和更好的农业实践条件而提供一种植物生长的方法。
我们已经发现这个目的通过一种用于处理需要生长促进的植物的方法而实现,该方法包括对所述植物、对它们由其生长的种子或者对它们生长的场所施加非植物毒性的、有效的植物生长促进量的具有式I的酰胺化合物:
A-CO-NR1R2 I
其中A为芳基或具有1-3个选自O、N和S的杂原子的芳族或非芳族5或6员杂环;其中芳基或杂环可以有或没有1、2或3个彼此独立地选自烷基、卤素、CHF2、CF3、烷氧基、卤代烷氧基、烷硫基、烷基亚磺酰基和烷基磺酰基的取代基;
R1为氢原子;
R2为可以有或没有1、2或3个彼此独立地选自烷基、链烯基、炔基、烷氧基、链烯氧基、炔氧基、环烷基、环烯基、环烷氧基、环烯氧基、苯基和卤素的取代基的苯基或环烷基,其中脂族和脂环族基团可以部分或全部地卤代和/或脂环族基团可以由1-3个烷基取代,并且其中苯基可以有1-5个卤原子和/或1-3个彼此独立地选自烷基、卤代烷基、烷氧基、卤代烷氧基、烷硫基和卤代烷硫基的取代基,并且其中酰胺苯基可以与或不与饱和5员环稠合,该饱和5员环可以用或不用一个或多个烷基取代和/或可以有选自O和S的杂原子。
在本发明的上下文中,卤素是氟、氯、溴和碘,尤其是氟、氯和溴。
术语“烷基”包括直链和支化烷基。这些优选是直链或支化的C1-C12烷基,尤其是C1-C6烷基。烷基的例子有烷基,例如尤其是甲基、乙基、丙基、1-甲基乙基、丁基、1-甲基丙基、2-甲基丙基、1,1-二甲基乙基、正戊基、1-甲基丁基、2-甲基丁基、3-甲基丁基、1,2-二甲基丙基、1,1-二甲基丙基,2,2-二甲基丙基、1-乙基丙基、正己基、1-甲基戊基、2-甲基戊基、3-甲基戊基、4-甲基戊基、1,2-二甲基丁基、1,3-二甲基丁基、2,3-二甲基丁基,1,1-二甲基丁基,2,2-二甲基丁基、3,3-二甲基丁基、1,1,2-三甲基丙基,1,2,2-三甲基丙基,1-乙基丁基、2-乙基丁基、1-乙基-2-甲基丙基、正庚基、1-甲基己基、1-乙基戊基、2-乙基戊基、1-丙基丁基、辛基、癸基、十二烷基。
卤代烷基是部分或全部由一个或多个卤原子,尤其是氟和氯卤代的如上定义的烷基。优选存在1-3个卤原子,特别优选二氟甲基或三氟甲基。
对于烷基和卤代烷基的上述陈述相应地适用于烷氧基、卤代烷氧基、烷硫基、卤代烷硫基、烷基亚磺酰基和烷基磺酰基中的烷基和卤代烷基。
链烯基包括直链和支化的链烯基。这些优选是直链或支化的C3-C12链烯基,尤其是C3-C6链烯基。链烯基的例子有2-丙烯基、2-丁烯基、3-丁烯基、1-甲基-2-丙烯基、2-甲基-2-丙烯基、2-戊烯基、3-戊烯基、4-戊烯基、1-甲基-2-丁烯基、2-甲基-2-丁烯基、3-甲基-2-丁烯基、1-甲基-3-丁烯基、2-甲基-3-丁烯基、3-甲基-3-丁烯基、1,1-二甲基-2-丙烯基、1,2-二甲基-2-丙烯基、1-乙基-2-丙烯基、2-己烯基、3-己烯基、4-己烯基、5-己烯基、1-甲基-2-戊烯基、2-甲基-2-戊烯基、3-甲基-2-戊烯基、4-甲基-2-戊烯基、1-甲基-3-戊烯基、2-甲基-3-戊烯基、3-甲基-3-戊烯基、4-甲基-3-戊烯基、1-甲基-4-戊烯基、2-甲基-4-戊烯基、3-甲基-4-戊烯基、4-甲基-4-戊烯基、1,1-二甲基-2-丁烯基、1,1-二甲基-3-丁烯基、1,2-二甲基-2-丁烯基、1,2-二甲基-3-丁烯基、1,3-二甲基-2-丁烯基、1,3-二甲基-3-丁烯基、2,2-二甲基-3-丁烯基、2,3-二甲基-2-丁烯基、2,3-二甲基-3-丁烯基、1-乙基-2-丁烯基、1-乙基-3-丁烯基、2-乙基-2-丁烯基、2-乙基-3-丁烯基、1,1,2-三甲基-2-丙烯基、1-乙基-1-甲基-2-丙烯基和1-乙基-2-甲基-2-丙烯基,尤其是2-丙烯基、2-丁烯基、3-甲基-2-丁烯基和3-甲基-2-戊烯基。
链烯基可以部分或全部地由一个或多个卤原子,尤其是氟和氯卤代。链烯基优选有1-3个卤原子。
炔基包括直链和支化炔基。这些优选为直链和支化的C3-C12炔基,尤其是C3-C6炔基。炔基的例子有2-丙炔基、2-丁炔基、3-丁炔基、1-甲基-2-丙炔基、2-戊炔基、3-戊炔基、4-戊炔基、1-甲基-3-丁炔基、2-甲基-3-丁炔基、1-甲基-2-丁炔基、1,1-二甲基-2-丙炔基、1-乙基-2-丙炔基、2-己炔基、3-己炔基、4-己炔基、5-己炔基、1-甲基-2-戊炔基、1-甲基-3-戊炔基、1-甲基-4-戊炔基、2-甲基-3-戊炔基、2-甲基-4-戊炔基、3-甲基-4-戊炔基、4-甲基-2-戊炔基、1,2-二甲基-2-丁炔基、1,1-二甲基-3-丁炔基、1,2-二甲基-3-丁炔基、2,2-二甲基-3-丁炔基、1-乙基-2-丁炔基、1-乙基-3-丁炔基、2-乙基-3-丁炔基和1-乙基-1-甲基-2-丙炔基。
对于链烯基及其卤素取代基和对于炔基的上述陈述相应地适用于链烯氧基和炔氧基。
环烷基优选为C3-C6环烷基,例如环丙基、环丁基、环戊基或环己基。如果环烷基是取代的,它优选具有1-3个C1-C4烷基作为取代基。
环烯基优选为C4-C6环烯基,例如环丁烯基、环戊烯基或环己烯基。如果环烯基是取代的,它优选具有1-3个C1-C4烷基作为取代基。
环烷氧基优选为C5-C6环烷氧基,例如环戊氧基或环己氧基。如果环烷氧基是取代的,它优选具有1-3个C1-C4烷基作为取代基。
环烯氧基优选为C5-C6环烯氧基,例如环戊烯氧基或环己烯氧基。如果环烯氧基是取代的,它优选含有1-3个C1-C4烷基作为取代基。
芳基优选为苯基。
如果A为苯基,则它可以在任何位置有1个、2个或3个上述取代基。这些取代基优选彼此独立地选自烷基、二氟甲基、三氟甲基和卤素,尤其是氯、溴和碘。特别优选苯基在2位有取代基。
如果A为5员杂环,则它尤其为呋喃基、噻唑基、吡唑基、咪唑基、噁唑基、噻吩基、三唑基或噻二唑基或者其相应的二氢或四氢衍生物。优选噻唑基或吡唑基。
如果A为6员杂环,它尤其为吡啶基或者下式的基团:
其中基团X和Y中的一个为O、S或者NR12,其中R12是H或烷基,并且基团X和Y中的另一个是CH2、S、SO、SO2或NR9。虚线是指双键可以存在或不存在。
6员芳族杂环特别优选吡啶基,尤其是3-吡啶基或者下式的基团:
其中X为CH2、S、SO或SO2。
提到的杂环基可以有或没有1、2或3个上述取代基,其中这些取代基优选彼此独立地选自烷基、卤素、二氟甲基或三氟甲基。
A特别优选为下式的基团:
其中R3、R4、R6、R7、R8和R9彼此独立地为氢,烷基,尤其是甲基,卤素,尤其是氯,CHF2或CF3。
式I中的基团R1优选为氢原子。
式I中的基团R2优选为苯基。R2优选具有至少一个特别优选在2-位的取代基。取代基(或多个取代基)优选选自烷基、环烷基、环烯基、卤素或苯基。
基团R2的取代基可以再被取代。脂族或脂环族取代基可以部分或全部地卤代,尤其是氟代或氯代。它们优选具有1、2或3个氟或氯原子。如果基团R2的取代基是苯基,则该苯基可以优选由1-3个卤原子,尤其是氯原子取代,和/或由优选选自烷基和烷氧基的基团取代。特别优选苯基在对位用卤原子取代,即基团R2特别优选的取代基为对卤素取代的苯基。R2也可以与饱和5员环稠合,其中该环本身可以有1-3个烷基取代基。
此时,R2为例如茚满基、苯并二氢噻吩基和氧杂茚满基。优选尤其通过4位连到氮原子的茚满基和2-氧杂茚满基。
根据优选的实施方式,根据本发明的组合物包括式I化合物作为酰胺化合物,其中A定义如下:
苯基、吡啶基、二氢吡喃基、二氢氧硫杂环己二烯基、二氢氧硫杂环己二烯基氧化物、二氢氧硫杂环己二烯基二氧化物、呋喃基、噻唑基、吡唑基或噁唑基,其中这些基团可以有1、2或3个彼此独立地选自烷基、卤素、二氟甲基和三氟甲基的取代基。
根据进一步优选的实施方式,A为:
在2位可以由卤素、甲基、二氟甲基、三氟甲基、甲氧基、甲硫基、甲亚磺酰基或甲磺酰基取代或不取代的吡啶-3-基;在2-位可以由甲基、三氟甲基、氯、溴或碘取代或不取代的苯基;
2-甲基-5,6-二氢吡喃基;
2-甲基-5,6-二氢-1,4-氧硫杂环己二烯-3-基或者其4-氧化物或4,4-二氧化物;
2-甲基呋喃-3-基,其在4位和/或5位可以由甲基取代或不取代;
噻唑-5-基,其在2和/或4位可以由甲基、氯、二氟甲基或三氟甲基取代或不取代;
噻唑-4-基,其在2和/或5位可以由甲基、氯、二氟甲基或三氟甲基取代或不取代;
1-甲基吡唑-4-基,其在3和/或5位可以由甲基、氯、二氟甲基或三氟甲基取代或不取代;或者
噁唑-5-基,其在2和/或4位可以由甲基或氯取代或不取代。
根据进一步优选的实施方式,根据本发明的组合物包括作为酰胺化合物的式I化合物,其中R2为可以由1、2或3个上述取代基取代或不取代的苯基。
根据进一步优选的实施方式,根据本发明的组合物包括作为酰胺化合物的式I化合物,其中R2为在2位有下列取代基之一的苯基:
C3-C6烷基、C5-C6环烯基、C5-C6环烷氧基、环烯氧基,其中这些基团可以由1、2或3个C1-C4烷基取代,
由1-5个卤原子和/或1-3个彼此独立地选自C1-C4烷基、C1-C4卤代烷基、C1-C4烷氧基、C1-C4卤代烷氧基、C1-C4烷硫基和C1-C4卤代烷硫基的基团取代的苯基,
可以由1、2或3个C1-C4烷基取代或不取代的茚满基或氧杂茚满基。
根据进一步优选的实施方式,根据本发明的组合物包括作为酰胺化合物的式Ia化合物:
X为亚甲基、硫、亚磺酰基或磺酰基(SO2),
R3为甲基、二氟甲基、三氟甲基、氯、溴或碘,
R4为三氟甲基或氯,
R5为氢或甲基,
R6为甲基、二氟甲基、三氟甲基或氯,
R7为氢、甲基或氯,
R8为甲基、二氟甲基或三氟甲基,
R9为氢、甲基、二氟甲基、三氟甲基或氯,
R10为C1-C4烷基、C1-C4烷氧基、C1-C4烷硫基或卤素。
根据特别优选的实施方式,组合物包括作为酰胺化合物的式Ib化合物:
其中R4为卤素,
R11为卤素取代的苯基。
优选的尤其是下式的两种酰胺化合物,即如权利要求1所要求的杀真菌混合物,其包括作为酰胺化合物的下式化合物:
最优选的是2-氯-N-(4-氯联苯-2-基)烟酰胺,通用名称为啶酰菌胺(boscalid)。
EP-A-545 099和589 301中提到了有用的式I的酰胺化合物,将这些文献的全部内容在此引入作为参考。
式I的酰胺化合物的制备例如从EP-A-545 099或589 301中可知,或者可以通过类似的方法进行。
已经发现本发明的方法中所用的酰胺化合物取决于所用的浓度、采用的配方和所处理的植物种的类型而显示出各种各样的植物生长调节性能。
由于本发明的实施,各种各样的植物生长作出响应,包括如下:
a)更大的水果尺寸
b)更大的蔬菜尺寸
c)更高的水果糖浓度
d)更发达的根系
e)更高的作物坚固性
f)更长的可储存性
g)改进的外观
h)更好的水果光洁度
i)更早的水果成熟
j)植物高度增加
k)更大的叶片
l)更少的死基生叶
m)更绿的叶色
n)更早开花
o)增加的芽生长
p)增加的植物活力
q)更早萌芽
本说明书所用的术语“用于调节植物生长的方法”意指达到任何的上述16类响应以及植物、种子、水果、蔬菜的任何其它改性,不管水果或蔬菜是未收获的还是已收获的,只要最终结果是提高生长和质量或者有别于任何农药作用,植物、种子、水果或蔬菜的任何性能上的益处。本说明书中所用的术语“水果”应当理解为由植物产生的具有经济价值的任何物质。
与上述16类相关联的一些初步的细节应当是为了更好地理解本发明。
在专利申请EP-A-545099和EP-A-589301中有可能配方的描述。
化合物I的施用率为0.005-0.5kg/ha,优选0.01-0.2kg/ha,尤其为0.02-0.1kg/ha。
对于种子处理,混合物的施用率通常为0.001-250g/kg种子,优选0.01-100g/kg,尤其为0.01-50g/kg。
酰胺化合物I可以配制成例如即喷溶液、粉末和悬浮液的形式或者为高度浓缩的水性、油性或其它悬浮液、分散体、乳液、油分散体、糊剂、粉剂、用于撒播的材料或颗粒的形式,并通过喷雾、雾化、撒粉、撒播或浇灌来施用。使用形式取决于意欲的目的;无论如何,应当确保根据本发明的混合物尽可能精细和均匀地分布。
配方以已知的方法制备,例如通过用溶剂和/或载体展开活性成分,如果需要使用乳化剂和分散剂,如果水用作稀释剂,则也可以使用其它有机溶剂作为辅助溶剂。用于这种用途的适合助剂基本上是:溶剂如芳族化合物(例如二甲苯),氯代芳族化合物(例如氯苯),石蜡(例如矿物油馏分),醇(例如甲醇、丁醇),酮(例如环己酮),胺(例如乙醇胺、二甲基甲酰胺)和水;载体如磨碎的天然矿物(例如高岭土、粘土、滑石和白垩)和磨碎的合成矿物(例如细碎二氧化硅、硅酸盐);乳化剂如非离子和阴离子乳化剂(例如聚氧化乙烯脂肪醇醚、烷基磺酸盐和芳基磺酸盐)和分散剂如木素亚硫酸盐废液和甲基纤维素。
适合的表面活性剂为芳族磺酸如木素-、苯酚-、奈-和二丁基萘磺酸以及脂肪酸的碱金属盐、碱土金属盐和铵盐,烷基-和烷基芳基磺酸盐,烷基、十二烷基醚和脂肪醇硫酸盐,以及硫酸化的十六-、十七-和十八烷醇的盐,或者脂肪醇乙二醇醚的盐,磺化萘及其衍生物与甲醛的缩合物,萘或萘磺酸与酚和甲醛的缩合物,聚氧化乙烯辛基酚醚,乙氧基化的异辛基、辛基或壬基酚,烷基酚聚乙二醇醚,三丁基苯基聚乙二醇醚,烷基芳基聚醚醇,异十三烷醇,脂肪醇/环氧乙烷缩合物,乙氧基化蓖麻油,聚氧化乙烯烷基醚或聚氧化丙烯烷基醚,十二烷醇聚乙二醇醚乙酸酯、山梨糖醇酯,木素亚硫酸盐废液或甲基纤维素。
粉末、用于撒播的材料和粉剂可以通过将酰胺化合物与固体载体混合或共同研磨而制备。
颗粒(例如涂层颗粒、浸渍颗粒或均相颗粒)通常通过将活性成分或多种活性成分粘合到固体载体上来制备。
填料或固体载体例如为矿土,例如二氧化硅、硅胶、硅酸盐、滑石、高岭土、石灰石、石灰、白垩、红玄武土、黄土、粘土、白云石、硅藻土、硫酸钙、硫酸镁、氧化镁、磨碎的合成材料和肥料,例如硫酸铵、磷酸铵、硝酸铵、尿素和植物来源的产物如谷粉、树皮粉、木粉和坚果壳粉,纤维素粉或者其它固体载体。
配方通常包括0.1-95重量%,优选0.5-90重量%的化合物。使用的活性成分的纯度为90%-100%,优选95%-100%(根据NMR光谱或HPLC)。
包括活性成分的这种制剂的例子有:
I.90重量份活性成分和10重量份N-甲基吡咯烷酮的溶液;该溶液适于以微滴的形式使用;
II.20重量份活性成分、80重量份二甲苯、10重量份8-10mol环氧乙烷与1mol油酸N-单乙醇酰胺的加合物、5重量份十二烷基苯磺酸的钙盐、5重量份40mol环氧乙烷与1mol蓖麻油的加合物的混合物;分散体通过将溶液精细地分散在水中而获得;
III.20重量份活性成分、40重量份环己酮、30重量份异丁醇、20重量份40mol环氧乙烷与1mol蓖麻油的加合物的水分散体;
IV.20重量份活性成分、25重量份环己醇、65重量份沸点为210-280℃的矿物油馏分和10重量份40mol环氧乙烷与1mol蓖麻油的加合物的水分散体;
V.80重量份活性成分、3重量份二异丁基萘-1-磺酸的钠盐、10重量份来自亚硫酸盐废液的木素磺酸的钠盐和7重量份粉状硅胶在锤磨机中磨碎的混合物;喷雾混合物通过将混合物精细地分散在水中而得到;
VI.3重量份活性成分和97重量份细碎高岭土的均匀混合物;该粉剂包括3重量%活性成分;
VII.30重量份活性成分、92重量份粉状硅胶和8重量份已喷雾到该硅胶表面的石蜡油的均匀混合物;这种配方赋予活性成分良好的粘附性
VIII.40重量份活性成分、10重量份苯酚磺酸/脲/甲醛缩合物的钠盐、2重量份硅胶和48重量份水的稳定水分散体;该分散体可以进一步稀释;
IX.20重量份活性成分、2重量份十二烷基苯磺酸的钙盐、8重量份脂肪醇聚乙二醇醚、20重量份苯酚磺酸/脲/甲醛缩合物的钠盐和88重量份石蜡矿物油的稳定油分散体。
根据本发明的酰胺化合物也可以与其它活性化合物结合存在,例如与除草剂、杀虫剂、生长调节剂、杀真菌剂或与肥料结合。在很多情况下,作为生长促进剂形式使用的酰胺化合物I与其它活性化合物的混合物或包含它们的组合物产生更宽范围的活性。
根据本发明的酰胺化合物可以结合使用的下列杀真菌剂用来说明可能的结合,但不强加任何限制:
●硫、二硫代氨基甲酸盐和它们的衍生物,例如二甲基二硫代氨基甲酸铁(III)、二甲基二硫代氨基甲酸锌、亚乙基双二硫代氨基甲酸锌、亚乙基双二硫代氨基甲酸锰、乙二胺双二硫代氨基甲酸锰锌、二硫化四甲基秋兰姆、N,N-亚乙基双二硫代氨基甲酸锌的氨配合物、N,N′-亚丙基双二硫代氨基甲酸锌的氨配合物、N,N′-亚丙基双二硫代氨基甲酸锌、N,N′-亚丙基双(氨基硫羰基)二硫化物;
●硝基衍生物,例如二硝基-(1-甲基庚基)苯基丁烯酸酯、2-仲丁基-4,6-二硝基苯基-3,3-二甲基丙烯酸酯、2-仲丁基-4,6-二硝基苯基异丙基碳酸酯、5-硝基间苯二甲酸二异丙酯;
●杂环物质,例如2-十七烷基-2-咪唑啉乙酸酯、2,4-二氯-6-(邻氯苯胺基)-s-三嗪、O,O-二乙基邻苯二甲酰亚氨基硫代膦酸酯、5-氨基-1-[双(二甲氨基)氧膦基]-3-苯基-1,2,4-三唑、2,3-二氰基-1,4-二硫代蒽醌、2-硫代-1,3-二硫杂环戊二烯并[4,5-b]喹喔啉、1-(丁基氨基甲酰基)-2-苯并咪唑氨基甲酸甲酯、2-甲氧基羰基氨基苯并咪唑、2-(呋喃基-(2))苯并咪唑、2-(噻唑基-(4))苯并咪唑、N-(1,1,2,2-四氯乙硫基)四氢邻苯二甲酰亚胺、N-三氯甲硫基四氢邻苯二甲酰亚胺、N-三氯甲硫基邻苯二甲酰亚胺;
●N-二氯氟甲硫基-N′,N′-二甲基-N-苯基硫酸二酰胺、5-乙氧基-3-三氯甲基-1,2,3-噻二唑、2-氰硫基甲硫基苯并噻唑、1,4-二氯-2,5-二甲氧基苯、4-(2-氯苯基亚肼基)-3-甲基-5-异噁唑酮、吡啶2-硫代-1-氧化物、8-羟基喹啉或其铜盐、2,3-二氢-5-甲酰苯胺基-6-甲基-1,4-氧硫杂环己二烯、2,3-二氢-5-甲酰苯胺基-6-甲基-1,4-氧硫杂环己二烯4,4-二氧化物、2-甲基-5,6-二氢-4H-吡喃-3-甲酰苯胺、2-甲基呋喃-3-甲酰苯胺、2,5-二甲基呋喃-3-甲酰苯胺、2,4,5-三甲基呋喃-3-甲酰苯胺、N-环己基-2,5-二甲基呋喃-3-甲酰胺、N-环己基-N-甲氧基-2,5-二甲基呋喃-3-甲酰胺、2-甲基-N-苯甲酰苯胺、2-碘代-N-苯甲酰苯胺、N-甲酰基-N-吗啉2,2,2-三氯乙基缩醛、哌嗪-1,4-二基-双-1-(2,2,2-三氯乙基)甲酰胺、1-(3,4-二氯苯胺基)-1-甲酰氨基-2,2,2-三氯乙烷、2,6-二甲基-N-十三烷基吗啉或其盐、2,6-二甲基-N-环十二烷基吗啉或其盐、N-[3-(对叔丁基苯基)-2-甲基丙基]-顺-2,6-二甲基吗啉、N-[3-(对叔丁基苯基)-2-甲基丙基]哌啶、1-[2-(2,4-二氯苯基)-4-乙基-1,3-二氧戊环-2-基乙基]-1H-1,2,4-三唑、1-[2-(2,4-二氯苯基)-4-正丙基-1,3-二氧戊环-2-基乙基]-1H-1,2,4-三唑、N-(正丙基)-N-(2,4,6-三氯苯氧基乙基)-N′-咪唑基脲、1-(4-氯苯氧基)-3,3-二甲基-1-(1H-1,2,4-三唑-1-基)-2-丁酮、1-(4-氯苯氧基)-3,3-二甲基-1-(1H-1,2,4-三唑-1-基)-2-丁醇、(2RS,3RS)-1-[3-(2-氯苯基)-2-(4-氟苯基)环氧乙烷-2-基甲基]-1H-1,2,4-三唑、α-(2-氯苯基)-α-(4-氯苯基)-5-嘧啶甲醇、5-丁基-2-二甲氨基-4-羟基-6-甲基嘧啶、双(对氯苯基)-3-吡啶甲醇、1,2-双(3-乙氧羰基-2-硫脲基)苯、1,2-双-(3-甲氧羰基-2-硫脲基)苯;
●嗜球果伞素,例如E-甲氧基亚氨基-[α-(邻甲苯氧基)-邻甲苯基]乙酸甲酯、E-2-{2-[6-(2-氰基苯氧基)嘧啶-4-基氧基]-苯基}-3-甲氧基丙烯酸甲酯、甲基E-甲氧基亚氨基-[α-(2-苯氧基苯基)乙酰胺、甲基E-甲氧基亚氨基-[α-(2,5-二甲基苯氧基)-邻甲苯基]乙酰胺;
●苯胺基嘧啶,例如N-(4,6-二甲基嘧啶-2-基)苯胺、N-[4-甲基-6-(1-丙炔基)嘧啶-2-基]苯胺、N-(4-甲基-6-环丙基嘧啶-2-基)苯胺;
●苯基吡咯,例如4-(2,2-二氟-1,3-苯并二氧杂环戊烯-4-基)吡咯-3-甲腈;
●肉桂酰胺,例如3-(4-氯苯基)-3-(3,4-二甲氧基苯基)丙烯酰基吗啉;以及
●各种杀真菌剂,例如十二烷基胍乙酸酯、3-[3-(3,5-二甲基-2-氧环己基)-2-羟基乙基]戊二酰亚胺、六氯苯、N-(2,6-二甲基苯基)-N-(2-糠酰)-DL-丙氨酸甲酯、DL-N-(2,6-二甲基苯基)-N-(2′-甲氧基乙酰基)丙氨酸甲基酯、N-(2,6-二甲基苯基)-N-氯乙酰基-D,L-2-氨基丁内酯、DL-N-(2,6-二甲基苯基)-N-(苯基乙酰基)丙氨酸甲基酯、5-甲基-5-乙烯基-3-(3,5-二氯苯基)-2,4-二氧代-1,3-噁唑烷、3-(3,5-二氯苯基)-5-甲基-5-甲氧基甲基-1,3-噁唑烷-2,4-二酮、3-(3,5-二氯苯基)-1-异丙基氨基甲酰基乙内酰脲、N-(3,5-二氯苯基)-1,2-二甲基环丙烷-1,2-二甲酰亚胺、2-氰基-[N-(乙基氨基羰基)-2-甲氧基亚氨基]乙酰胺、1-[2-(2,4-二氯苯基)戊基]-1H-1,2,4-三唑、2,4-二氟-α-(1H-1,2,4-三唑基-1-甲基)二苯甲醇、N-(3-氯-2,6-二硝基-4-三氟甲基苯基)-5-三氟甲基-3-氯-2-氨基吡啶、1-((双-(4-氟苯基)甲基甲硅烷基)甲基)-1H-1,2,4-三唑。
作为可以由植物生长促进作用而改性的作物的例子,有蔬菜、坚果或水果。
本发明的另一方面是式I的酰胺化合物与嗜球果伞素的混合物在植物生长促进的方法中是适合的。
适用于这些混合物的嗜球果伞素例如有嘧菌酯(azoxystrobin)、醚菌胺(dimoxystrobin)、氟硫菌酯(fluoxastrobin)、醚菌酯(kresoxim-methyl)、苯氧菌胺(metominostrobin)、肟醚菌胺(orysastrobin)、啶氧菌酯(picoxystrobin)、唑菌胺酯(pyraclostrobin)或肟菌酯(trifloxystrobin)。
酰胺化合物I和嗜球果伞素优选以20∶1-1∶20,特别为10∶1-1∶10的重量比使用。
式I的酰胺化合物与嗜球果伞素可以一起或单独地同时施加,或者依次施加。
作为可以由植物生长调节作用而改性的作物的例子,有蔬菜、坚果或水果。
酰胺化合物的精确量将取决于被处理的特别植物种。这可以由本领域的技术人员用少许实验确定,并且取决于化合物的总用量以及被处理的特别的植物种,在植物响应上可能不同。当然,酰胺化合物的量应当对于被处理的植物是非植物毒性的。
虽然本发明的方法中所用的酰胺化合物的优选施用方法是直接施用于植物的叶和茎,但已经相信这类化合物可以施加到植物正生长的土壤,并且这类化合物将根部吸收到充足的程度以致根据本发明的教导产生植物响应。
下面的实施例说明根据本发明的植物生长调节的方法,但是不应理解为对本发明的限制。
实施例1:
将洋葱移植在7×30英尺的地中。移植7天后,用含有25.2%啶酰菌胺的BAS 516产品喷雾洋葱。喷雾剂还含有12.8%唑菌胺酯。BAS 516以每英亩0.45磅活性成分的施用率喷雾。在0.06%助剂的帮助下,将洋葱在第一次处理后每7天处理5次。在这个时间期间,给植物适当地浇水。最后处理14天后,测量作物产量。与未处理的地相比,每英亩作物产量增加4.2%。在该试验中,不存在真菌病害。
实施例2:
将芥花籽(canola seeds)播种在56平方英尺的地中。播种47天后,用含有70%啶酰菌胺的产品喷雾作物。该处理是在35%开花时进行。处理芥花使得剂量为每英亩0.26磅活性成分。在试验期间,给植物适当地浇水。在最后处理58天后或在播种植物105天后,测量作物产量。与未处理的地相比,每英亩作物产量增加21%。在该试验中,出现了有限的真菌病害。
实施例3:
重复实施例2,不同的是产品在50%开花时施用,这意味着播种50天后。得到了相同的结果,但是与未处理的地相比,产量增加为22%。
实施例4:
将树龄为8岁的葡萄树干在8×24英尺的地上处理。当出现6英寸的新藤时,用含有25.2%啶酰菌胺的BAS 516产品的悬浮乳液喷雾葡萄。喷雾剂还含有12.8%唑菌胺酯。BAS 516每14天以每英亩0.2磅活性成分的施用率喷雾。这些喷雾剂在第一次施用BAS 516后7天开始以14天的间隔用每英亩含有3磅活性成分的80%悬浮液交替处理。在用BAS 516第7次处理后,葡萄在藤上保持88天。在第一次处理182天后评价葡萄的大小和重量。观察从葡萄出现到收获的结果。有限的病害出现在该试验中。观察到11.8倍高的产量,具有下列植物生长调节效果:浆果更大、串的重量增加、植物更绿并且植物更高。
虽然已经描述了本发明的各个优选实施方式,但是本领域的技术人员应当理解不背离其精神可以作出各种改性、替代、省略和变化。因此,本发明的范围只由下列权利要求的范围(包括其等同物)来限定。
Claims (13)
2.根据权利要求1所述的方法,其包括作为酰胺化合物的下式的化合物:
3.根据权利要求1所述的方法,其中所述式(Ib)的酰胺化合物为2-氯-N-(4-氯联苯-2-基)烟酰胺。
4.根据权利要求1所述的方法,其中施加的式(Ib)的酰胺化合物的所述植物生长促进量足以提供选自以下的至少一种植物生长促进效果:
a)更大的水果尺寸
b)更大的蔬菜尺寸
c)更高的水果糖浓度
d)更发达的根系
e)更高的作物坚固性
f)更长的可储存性
g)改进的外观
h)更好的水果光洁度
i)更早的水果成熟
j)植物高度增加
k)更大的叶片
l)更少的死基生叶
m)更绿的叶色
n)更早开花
o)增加的芽生长
p)增加的植物活力
q)更早萌芽。
5.根据权利要求1所述的方法,其中将所述式(Ib)的酰胺化合物以颗粒形式以0.005-0.5kg/ha式(Ib)化合物的施用率施用于所述植物或者它们生长的场所。
6.根据权利要求5所述的方法,其中式(Ib)化合物的施用率为0.01-0.2kg/ha。
7.根据权利要求1所述的方法,其中所述植物选自禾谷类及蔬菜类植物和草皮。
8.根据权利要求1所述的方法,其中所述植物选自稻、玉米类及蔬菜类植物和草皮。
9.根据权利要求1所述的方法,其中使用式(Ib)的酰胺化合物与嗜球果伞素的混合物。
10.根据权利要求9所述的方法,其中所述嗜球果伞素选自嘧菌酯、醚菌胺、氟硫菌酯、醚菌酯、苯氧菌胺、肟醚菌胺、啶氧菌酯、唑菌胺酯或肟菌酯。
11.根据权利要求9所述的方法,其中使用啶酰菌胺与唑菌胺酯的混合物。
12.根据权利要求9所述的方法,其中所述酰胺化合物(Ib)与嗜球果伞素的重量比为20∶1-1∶20。
13.根据权利要求9所述的方法,其中所述酰胺化合物和嗜球果伞素一起或者单独地同时施加,或者依次施加。
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