CN100384971C - Composition - Google Patents
Composition Download PDFInfo
- Publication number
- CN100384971C CN100384971C CNB2003801013719A CN200380101371A CN100384971C CN 100384971 C CN100384971 C CN 100384971C CN B2003801013719 A CNB2003801013719 A CN B2003801013719A CN 200380101371 A CN200380101371 A CN 200380101371A CN 100384971 C CN100384971 C CN 100384971C
- Authority
- CN
- China
- Prior art keywords
- acid
- composition
- weight
- agent
- oxidation resistant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2/00—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
- A61L2/16—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using chemical substances
- A61L2/18—Liquid substances or solutions comprising solids or dissolved gases
- A61L2/186—Peroxide solutions
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/14—Disinfection, sterilisation or deodorisation of air using sprayed or atomised substances including air-liquid contact processes
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/722—Oxidation by peroxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/04—Water-soluble compounds
- C11D7/06—Hydroxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/265—Carboxylic acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/32—Organic compounds containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/42—Nature of the water, waste water, sewage or sludge to be treated from bathing facilities, e.g. swimming pools
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2303/00—Specific treatment goals
- C02F2303/04—Disinfection
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/30—Wastewater or sewage treatment systems using renewable energies
- Y02W10/37—Wastewater or sewage treatment systems using renewable energies using solar energy
Abstract
The invention relates to a composition, comprising: 0.1 to 40 wt. % of at least one oxidation-stable, at least mono-unsaturated, substituted or unsubstituted organic acid, 0.1 to 40 wt. % of at least one oxidation-stable, saturated, substituted or unsubstituted organic acid, up to 30 wt. % of hydrogen peroxide and/or at least one inorganic and/or organic peroxide compound and up to 2 wt. % of an oxidation-stable complexing agent. Said composition is an effective, widely applicable disinfecting, anti-bacterial and pharmaceutical agent, characterised by a good shelf life.
Description
The present invention relates to be used to dissolve the enriched material of sanitising agent of biofouling and the composition that comprises at least a organic acid and at least a superoxide.
DE 43 25 312 A1, DE 199 10 356 A1 and DE 199 15 028 A1 disclose the sterilant of being made up of superoxide, food antiseptics and nontoxicity acid or its salt (particularly Sodium Benzoate and Sorbic Acid) that exists with aqueous solution form.Yet said preparation is owing to its hydrogen peroxide composition has poor stability in storage, and will lose efficacy in 1 to 3 months according to its composition.
Therefore, task of the present invention is, a kind of composition of the above-mentioned type is provided, and it still has gratifying germicidal action under the stability in storage of improving.
Its solution is to have the enriched material of feature of claim 1 and the combination of features thing with claim 2.Enriched material of the present invention comprises 0.1 to 4 weight %, at least a material that is selected from Sorbic Acid, sodium sorbate, potassium sorbate, Sorbic Acid lithium, xitix, acetylsalicylic acid, succsinic acid or their salt and derivative of preferred 0.3 to 2.5 weight %; 0.1 to 4 weight %, at least a material that is selected from phenylformic acid, Sodium Benzoate, lithium benzoate, P-hydroxybenzoic acid, toxilic acid or its salt and derivative of preferred 0.1 to 3.5 weight %; 2.2 to 12 weight %, 30% hydrogen peroxide and 0.1 to the 1.5 weight % of preferred 2.5 to 7.5 weight %, the ethylenediamine tetraacetic acid (EDTA) in the water that is dissolved in preferred lean ore material of preferred 0.1 to 1.3 weight % (particularly removing the water of mineral substance).
Composition of the present invention comprises at least a oxidation resistant, monounsaturated at least, that replace or unsubstituted organic acid of 0.001 to 40 weight %; 0.001 at least a oxidation resistant, saturated, replace or unsubstituted organic acid of 40 weight %; Be up to the compound of the hydrogen peroxide of 30 weight % and/or at least a inorganic and/or organic peroxyization and be up to the oxidation resistant complexing agent of 2 weight %.
Composition of the present invention or enriched material by to its active rise replenish, the activeconstituents of stack or enhancement formed a kind of synergic, had the system of multiple guarantee.
In the present invention, term " snperoxiaized compound " is meant all inorganic and organic compound that comprises the dioxygen structural unit.
Snperoxiaized compound is owing to discharging the quick oxidation of shell that the oxygen base makes cell, so this shell is torn and damages, and causes the inside of cell to be exposed to the open air outside.Simultaneously, catch the enzyme of oxygen base by rapid damage or inhibition, so that described enzyme can not be brought into play its effect fully.Other protein and nucleic acid also are subjected to the attack of oxygen base and are damaged equally.Last cell is by the path (energy exchange of the substance metabolism that therefore causes; The protein biosynthesizing) obstruction and death.It is very fast that this result occurs.Snperoxiaized compound is also got involved cellularstructure suddenly in large quantities, and cellularstructure itself is decomposed in this case.This is a kind of strong but effect of short-term.
The cell relic that described organic acid causes producing in process mentioned above is decomposed, and therefore stops formation microbial film and bio aggregate and so-called biofouling.Dissolved and the decomposition of microbial film that has formed and bio aggregate.In addition, their of short duration formation peracid under the influence of peroxide compound, therefore and remedied the effectiveness of peroxide compound.By selecting single acid can replenish, superpose or strengthen these effects dexterously.Different with the effect of peroxide compound, the time that this effect continues is long, because these organic acids only decompose very lentamente.
Described complexing agent is because itself and Ca
2+-and Mg
2+Thereby therefore-ion complexation also no longer allows bacterioflora to carry out the bacterioflora that substance metabolism has damaged the desire elimination.The heavy metal ion complexing that described especially complexing agent and catalysis peroxide compound decompose.Therefore make peroxide compound avoid decomposing and therefore being stabilized.
Be surprisingly found out that the stability in storage by these measures composition of the present invention obviously improves, and brings up to more than 1 to 2 year from 2 to 3 months.Therefore, but composition of the present invention finally become a kind of marketable, need not special safeguard procedures and store the application product of measure.
In addition, composition of the present invention is nontoxic and biodegradable.Said composition can directly contact with pending substrate.In fact immediately generation effect, and cleaning effect completely just appears after 10 to 20 minutes action time.
Can obtain other favourable forming by dependent claims.
Preferred measure is, at least a oxidation resistant monounsaturated at least organic acid be selected from tartaric acid, Sorbic Acid, toxilic acid, fumaric acid with and salt.At least a oxidation resistant unsaturated organic acid is preferably selected from tartaric acid, oxyacetic acid, lactic acid, succsinic acid, oxalic acid, propanedioic acid, pentanedioic acid, hexanodioic acid, pimelic acid, phenylformic acid, P-hydroxybenzoic acid, have the paraffinic acid of straight or branched of 1 to 12 carbon atom and their salt.
The ingenious combination of these acid makes their effect strengthen mutually, remedy or superpose.Many organic acids for example phenylformic acid and Sorbic Acid are deleterious to the substance metabolism of many bacteriofloras, so they have strengthened the effect of the deadly bacterioflora of peroxide compound.In addition, they make peroxide compound the film transfer capacity some, the shell of the bacterioflora that the infringement desire is eliminated, and participate in the compound of stable peroxide.
The snperoxiaized compound that is fit to comprises hydrogen peroxide, superoxide (for example urea peroxide, diacyl peroxide, peracid, peresters) and epidioxy-thing.The compound of the inorganic peroxyization that is fit to be for example peroxy-monosulfate, peroxydisulfate, cross monophosphate, perphosphoric acid salt, peroxomonocarbonate and peroxodicarbonate.Under special circumstances, the prescription and the application purpose of the present composition depended in their selection.Particularly suitable in liquid formulations for example is hydrogen peroxide, and particularly suitable in solid for mulation for example is urea peroxide.
What be used as complexing agent can for example be ethylenediamine tetraacetic acid (EDTA) (EDTA), nitrilotriacetic acid(NTA) (NTA), phosphoric acid, Tripyrophosphoric acid, oxalic acid, etheric acid and its salt and succinic acid derivative.These complexing agents especially effectively with complexing of metal ion so that the catalyzer that snperoxiaized compound is stabilized impel its decomposition also no longer has activity.For the bacterioflora of desire elimination, the necessary ion of its substance metabolism is captured equally, and this helps killing these bacteriofloras.The advantage of described complexing agent is can biological decomposition in addition.
Composition of the present invention can comprise various additives and auxiliary agent according to concrete application purpose.To this for example is one or more oxidation resistant grease-removing agents, this grease-removing agent is selected from all soap class, negatively charged ion and nonionogenic tenside, alkyl sulfate, alkylbenzene sulfonate, fatty acid ester, sulfation glycerol fatty acid ester, trimethyl-glycine, sulphobetaine and saponin, preferably sodium dodecyl sulfate, sodium laurylsulfonate and Sodium Lauryl Sulphate BP/USP.In addition, can consider one or more sludge proof permeate agents for example DMSO, have monobasic or the polyvalent alcohol and the polyoxyethylene glycol of the straight or branched of 1 to 12 carbon atom.Also can comprise other auxiliary agent for example defoamer, sanitas, binding agent, wetting agent, spices and/or dyestuff in addition.
By adding for example soybean oil of height emulsive vegetables oil component, also can destroy the insects by the quinine crust (Chininpanzers) that damages insect.
Composition of the present invention can be mixed with solution, solid or gel.It for example can comprise at least a solvent for example water or monobasic or the polyvalent alcohol that at room temperature be in a liquid state, side chain or non-side chain that is up to 99 weight %.For example ethanol or Virahol are fit to.Water preferably removes mineral substance.With alcohol during as solvent, component is dissolved in a large number, therefore obtains enriched material, and this enriched material is diluted before using, and dilution is 1: 50 to 1: 2 when for example using, or 1: 40 to 1: 3, or 1: 20 to 1: 5, preferred 1: 10.The advantage of pure in addition for example ethanol or Virahol is that also they have the effect that can kill bacterium and fungi, so the germ-resistant effect of the present composition also is enhanced.
Preferably slightly acidic is to neutral as solution for composition of the present invention, and for example its pH value is 3.0 to 6.8.
In order to prepare gel, in the composition that exists with solution, add a kind of gelifying agent at least, preferred aerosol (Aerosil), alginate, agarose or at least a acrylate.Then with the gel coating that obtains on the surface that desire is handled.
Preferably Formulation Example is in this way:
0.1 to 20 weight %H
2O
2Or urea peroxide
0.01 to 1 weight % Sorbic Acid
0.001 to 1 weight % phenylformic acid
0.001 to 2 weight %EDTA or NTA
0.01 to 1 weight %H
3PO
4, phosphoric acid salt or polyphosphate
85 to 99.798 weight % water (removing mineral substance).
Composition of the present invention also can be used as humans and animals and for example treats bacterium and viral infectious, allergen, mycosis, pediculosis and other parsitism with medicine.In addition, composition of the present invention can be used as bactericide, mycocide, insecticide and/or weedicide, preferably agricultural, in the gardening as stiffeners and/or the conditioning liquid of handling plant and animal, in household and industry as sanitising agent, and as the sterilant of empty G﹠W, the sterilant of swimming pool and Whirlpool (whirlpool) and as surface disinfectant.
Describe embodiments of the invention below in detail.Composition comprises:
50 gram H
2O
2
1 gram Sorbic Acid
2.5 gram phenylformic acid
1 gram EDTA
1 gram H
3PO
4
1 premium on currency (removing mineral substance).
Add entry earlier at this, dissolve EDTA then, add acid subsequently, add hydrogen peroxide at last.
For obtained aqueous solution, use 30% aqueous hydrogen peroxide solution.Also can use urea peroxide or persulphate (for example at Virkon) to replace hydrogen peroxide.In this case, make powdered mixture, wherein comprise superoxide with 50 gram hydrogen peroxide equivalent.
During solid, do not make water in preparation, and other component and optional adjuvants provide with the form of powder mixture, particle or tablet.
Can increase substantially the solubleness (until solubility limit) of phenylformic acid and Sorbic Acid by adding ethanol or Virahol in above-mentioned prescription, therefore can prepare active component content about 10 times " crossing enriched material " (10 gram Sorbic Acids for example, 25 gram phenylformic acid and 10% or more H
2O
2).
Composition of the present invention is determined can be used for following range of application and is considered to effective by testing:
Plant protection:
-by spray to strengthen trees opposing ramorum epidemic disease mould (Phytophthora ramorum) and
Preferred composition comprises 0.5%H in removing mineral water
2O
2, 0.01% Sorbic Acid, 0.025% phenylformic acid, 0.001%EDTA, 0.1%H
3PO
4
-strengthening tobacco plant opposing tobacco-piebald-virus (Tabak-Mosaik-Virus) by spraying, caused butt rot of anti-aphid and anti-microbial type and stem rot.
-strengthen potato opposing cauline leaf and stem tuber rotten (late blight of potato) and potato Coleoptera (Leptinotarsa decemlineata) by spraying; Preferred composition comprises 0.5%H in removing mineral water
2O
2, 0.01% Sorbic Acid, 0.025% phenylformic acid, 0.001%EDTA, 0.1%H
3PO
4
-by spraying the ability that cucumber class plant is resisted pseudo-powder mildew, anti-aphid, spider mite (Spinnenmilben) and Thysanoptera insect that strengthens; Preferred composition comprises 0.5%H in removing mineral water
2O
2, 0.01% Sorbic Acid, 0.025% phenylformic acid, 0.001%EDTA, 0.1%H
3PO
4
-by spraying Caulis et Folium Brassicae capitatae plant opposing Thysanoptera insect, bacterial leaf spot, vein Black Rotten, Caulis et Folium Brassicae capitatae Black Rotten, ring-type pinta (Ringfleckenkrankheit), the ability of anti-insect, mite and nematode of strengthening; Preferred composition comprises 0.5%H in removing mineral water
2O
2, 0.01% Sorbic Acid, 0.025% phenylformic acid, 0.001%EDTA, 0.1%H
3PO
4
-by spraying climing opposing Falschen and EchtenMehltau (downy mildew of garpe and Oidium tuckeri) or the opposing Pierce Disease that strengthens climing tree viny.Especially, in this field, use copper and sulphur preparation in the ecological wine-growing or in traditional wine-growing, use mycocide by using these compositions can avoid or significantly be reduced in.For example effective composition comprises 0.5%H in removing mineral water
2O
2, 0.01% Sorbic Acid, 0.025% phenylformic acid, 0.001%EDTA, 0.1%H
3PO
4, 0.5%SDS.
Agricultural:
-help to purify the matting canopy by sprinkling.Here bacterium and fungi for example mould successfully eliminated, the bacterioflora that produces smell is dead to have a de-odorised effect to composition of the present invention in addition by making.Effective composition for example comprises 3.5%H in removing mineral water
2O
2, 0.1% Sorbic Acid, 0.25% phenylformic acid, 0.1%EDTA, 0.1%H
3PO
4, 0.5%SDS.
-help the nursing of fur and the feather of animal by sprinkling.It can be used to antimycotic (for example dermatophytes or mould), antibacterium, virus and algae.It can antimite and dermatophytes aspect fur and feather nursing, and also is being effective aspect the little wound of cleaning and disinfection.In addition, composition of the present invention has the de-odorised effect by making the bacterioflora death that produces smell.Effective composition for example comprises 0.5%H in removing mineral water
2O
2, 0.01% Sorbic Acid, 0.015% phenylformic acid, 0.01%EDTA, 0.01%H
3PO
4, 0.05%DMSO, 0.5%SDS.
-help the nursing of animal hoof and pawl by coating solution.It also is effective to the disease of coffin joint dermatitis and other infringement animal hoof and pawl.Effective composition for example comprises 1.5%H in removing mineral water
2O
2, 0.1% Sorbic Acid, 0.15% phenylformic acid, 0.1%EDTA, 0.1%H
3PO
4, 0.05%DMSO, 0.5%SDS.
-opposing is encroached on acarid, fungi and the bacterium of honeybee and beehive and is helped to nurse honeybee.With composition sprayed of the present invention in beehive.Effective composition for example comprises 0.3%H in removing mineral water
2O
2, 0.1% Sorbic Acid, 0.2% phenylformic acid, 0.1%EDTA, 0.1%H
3PO
4
In foodstuffs industry, composition of the present invention for example is used for the external treatment of fruit and is used for the sterilization of water and the sterilization of processing machine.Because composition of the present invention is nontoxic and biodegradable, so these application are without a doubt.The composition that is fit to for example is to comprise 0.3%H in removing mineral water
2O
2, 0.05% Sorbic Acid, 0.1% phenylformic acid, 0.01%EDTA, 0.1%H
3PO
4By keeping the production process cleaning to avoid microorganism and biomembrane material to make the health of food be processed into possibility.Composition of the present invention also can be comprised among the K ü hleis or with it with the concentration that is suitable for bringing into play above-mentioned effect and mix, therefore its clean effect shows in thaw process, and for example the dish of the refrigeration chamber of being furnished with ice up to becoming the seafood restaurant from the seine fishing boat all avoided biomembranous formation, and guarantees that fish has kept original fresh state.
In addition, composition of the present invention also is suitable for leather, be applicable to cleaning and disinfecting surface, pipeline and flexible pipe (particularly medical appliance and equipment), be applicable to cleaning and Sterilizing water tank, conditioner, sanitary equipment, cool off and add hot-water system, potable water system and waste water system, be used for the sterilization of sky G﹠W, as surface disinfectant, be used for drinking water treatment and be used for swimming pool and the sterilization of Whirlpool.This composition that is fit to is for example comprised 5%H in removing mineral water
2O
2, 0.1% Sorbic Acid, 0.25% phenylformic acid, 0.1%EDTA, 0.1%H
3PO
4Sensing surface and for mulberry that, use in solarium, swimming pool and the Whirlpool, also can use for example in removing mineral water, to comprise 3%H
2O
2, 0.1% Sorbic Acid, 0.25% phenylformic acid, 0.1%EDTA, 0.1%H
3PO
4Composition.
If observe a large amount of foams during treat surface, this is that this surface is by the sign of serious pollution (bacterial reproduction), so the compositions-treated of suggestion re-treatment or employing higher concentration so.
The specific embodiment that the present composition mode of action is described is to clean old, mouldy leatherware to maintain, for example saddle horse.With above-mentioned composition sprayed and after keeping effect in 10 to 15 minutes, not only mildew can be wiped at an easy rate, and this old leather that hardens softness that also becomes once more, and keeps persistent snappiness after oiling.Formed solid-state biofouling because secular bacterium colony pollutes in the hole of this leather, it seriously hardens leather.Removed the biomembrane material in the hole by the processing of the present composition, and leather becomes pliable and tough once more, therefore this preparation can be invaded in the hole.Can handle for example leather shoes in the same way.
Another embodiment is the processing of high-purity room air.Directly killed microorganism on the one hand by in air, adding.Also can dissolve the aggregate that surrounds microorganism on the other hand and in air, condense in together microbial film, about 1/10 all microbial aggregates that constitute the residue dust are separated.Therefore microorganism is also dead.Adopt composition of the present invention to improve the natural humidity in the room air.Therefore also can make and be rich in the aerosol particle superfine mist of μ as far as possible＜3 in the air,, and bring into play its effect so that said composition is distributed in is whole indoor.Arrive on airy indoor and all therein the furniture object and material (for example material, clothes, food deposit etc.) at this aerosol particle.Produce cleaning action thus, so that continue to have guaranteed the lifeless matter film.Not only removed for example all microbial film settlings of air-conditioning plant of diffuser by this way, so that no longer included the diffusion of microorganism, and bunch also be eliminated at the microbial film of the indoor microorganism of airy.This is equally to also being favourable between all types of storages, because the energy that for example can obviously save cooling and consumed.Also can adopt this purifying air for all types of transport containers (do not comprise surface wiping) voluntarily equally, so that the article (for example fruit) that betransported keep fresh and anticorrosion.When removing biomembrane material, air and water filter can more effectively turn round in addition.
Composition of the present invention can be used as the anti-effectively SARS-coronavirus of medicine, anthrax bacillus, intestinal bacteria, pneumobacillus, streptococcus aureus, Pseudomonas aeruginosa, streptococcus faecium, Proteus mirabilis, Mycobacterium tuberculosis, clostridium sporogenes, Candida albicans, tame dirt mite (Hausstaubmilben), Varroa mite (Varroamilben) and many other pathogenic agent and parasite.For example in removing mineral water, comprise 3%H
2O
2, 0.1% Sorbic Acid, 0.25% phenylformic acid, 0.1%EDTA, 0.1%H
3PO
4Composition (be preferred for suck) or in removing mineral water, comprise 1.5%H
2O
2, 0.1% Sorbic Acid, 0.15% phenylformic acid, 0.1%EDTA, 0.1%H
3PO
4, 0.05%DMSO composition (be preferred for apply) for example can be inhaled into or be coated in the position of infection.
By means of adopting composition of the present invention to reach on the one hand to go out except that the bacterioflora of all kinds and reduce on the other hand or remove microbial film, thereby will eliminate for example diffusibility of bacterium, virus, fungi, unicellular organism etc. of all bacteriofloras.Though this bacterioflora or microbial film are for multicellular animals for example mite, mosquito, fly, worm, even not that existence is necessary for mouse and rat, but the surrounding environment of cleaning with composition of the present invention has been avoided these animals at least according to observations, has therefore for example reduced the quantity of fly and mosquito in the animal canopy at least.
Therefore, composition of the present invention is a kind of effective biological disinfectant and disinfectant and sterilant.Because microorganism may encroach on all places so that can form microbial film and biofouling, therefore composition of the present invention all is economical and practical anywhere, is using to the temperature range of being correlated with up to about 70 ℃ biology especially.
In addition, its anti-effectively various pathogenic agent.Composition of the present invention is friendly to user and environment, and is nontoxic and can complete biodegradable.Composition of the present invention has very high action spectrum, and make safe and very effectively infection control for many application, become possibility.
Farm crop, gardening and forestry:
By plant and trees are handled for example treat powder mildew, aphid, mite, bacterium, harvesting aftertreatment make plant strong/protective plant.
Pharmacy industry:
The sterilization sex pill, for example wound disinfection agent, suction medicine (SARS, TBC, influenza etc.), foot and nail fungi, wart.
Industry:
Purify pipeline and surface, remove and prevention for example at conditioner, sanitary equipment, cool off and add the microbial film of hot-water system, potable water system, waste water system, keep the cleaning of tap water and process water and air, handle fabric, leather and timber.
Foodstuffs industry:
Fruit, processing machine, water are for example handled in the transportation and the storage of the processing of the fruit of results, food-processing, food.
Household/hotel:
Keep sanitary equipment, conditioner, Sang Nafang, solarium, swimming pool, Whirlpool.
Animal rearing:
The Varoamilben of honeybee, hoof and pawl maintenance, fur maintenance, the cleaning that keeps the water in fish and the shrimp cultivation, colony house sterilization.
Claims (30)
1. composition, it comprises:
A) at least a oxidation resistant, monounsaturated at least, that replace or unsubstituted organic acid of 0.001 to 40 weight %;
B) at least a oxidation resistant, saturated, replace or unsubstituted organic acid of 0.001 to 40 weight %;
C) be up to the hydrogen peroxide of 30 weight % and/or the compound of at least a inorganic and/or organic peroxyization;
D) be up to the oxidation resistant complexing agent of 2 weight %.
2. the composition of claim 1 is characterized in that, described at least a oxidation resistant monounsaturated at least organic acid be selected from tartaric acid, Sorbic Acid, toxilic acid, fumaric acid with and salt.
3. the composition of claim 1, it is characterized in that described at least a oxidation resistant unsaturated organic acid is selected from tartaric acid, oxyacetic acid, lactic acid, succsinic acid, oxalic acid, propanedioic acid, pentanedioic acid, hexanodioic acid, pimelic acid, phenylformic acid, P-hydroxybenzoic acid, have the paraffinic acid of straight or branched of 1 to 12 carbon atom and their salt.
4. the composition of claim 1 is characterized in that, the compound of described at least a organic peroxyization is selected from hydrogen peroxide, superoxide, peroxidation two acyls, peracid, peresters, ketone peroxide and epidioxy-thing.
5. the composition of claim 1 is characterized in that, the compound of described at least a inorganic peroxyization is selected from peroxy-monosulfate, peroxydisulfate, crosses monophosphate, perphosphoric acid salt, peroxomonocarbonate and peroxodicarbonate.
6. the composition of claim 1 is characterized in that, described at least a oxidation resistant complexing agent is selected from ethylenediamine tetraacetic acid (EDTA) (EDTA), nitrilotriacetic acid(NTA) (NTA), phosphoric acid, Tripyrophosphoric acid, oxalic acid, etheric acid and its salt and succinic acid derivative.
7. the composition of claim 1, it also comprises at least a oxidation resistant grease-removing agent, and this grease-removing agent is selected from the group that soap class, negatively charged ion and nonionogenic tenside, alkyl sulfate, alkylbenzene sulfonate, fatty acid ester, sulfation glycerol fatty acid ester, trimethyl-glycine, sulphobetaine and saponin are formed.
8. the composition of claim 1 is characterized in that, described at least a oxidation resistant grease-removing agent is selected from the group of being made up of sodium lauryl sulphate, sodium laurylsulfonate and Sodium Lauryl Sulphate BP/USP.
9. the composition of claim 1, it also comprises at least a oxidation resistant permeate agent.
10. the composition of claim 9, described permeate agent be DMSO, have monobasic or the polyvalent alcohol or the polyoxyethylene glycol of the straight or branched of 1 to 12 carbon atom.
11. the composition of claim 1, it also comprises one or more other auxiliary agents or high emulsive vegetables oil component.
12. the composition of claim 11, described auxiliary agent are defoamer, sanitas, binding agent, wetting agent, spices or dyestuff.
13. the composition of claim 1, it also comprises at least a solvent.
14. the composition of claim 13, described solvent are the monobasic or the polyvalent alcohol of water or side chain that at room temperature is in a liquid state or non-side chain.
15. the composition of claim 14, described monobasic or polyvalent alcohol are ethanol or Virahol.
16. the composition of claim 13, the pH value is 3.0 to 6.8 when it is characterized in that existing with the dissolved form.
17. the composition of claim 13, it also comprises at least a gelifying agent or at least a acrylate.
18. the composition of claim 17, described gelifying agent are aerosol, alginate, agarose.
19. the composition of claim 13, it comprises
0.1 to 10 weight %H
2O
2Or urea peroxide,
0.01 to 1 weight % Sorbic Acid,
0.001 to 1 weight % phenylformic acid,
0.001 to 2 weight %EDTA or NTA,
0.01 to 1 weight %H
3PO
4, phosphoric acid salt or polyphosphate,
85 to 99.798 weight % water (removing mineral substance).
20. the composition of claim 13 is characterized in that, forms by a kind of composition,
A) at least a material that is selected from Sorbic Acid, sodium sorbate, potassium sorbate, Sorbic Acid lithium, xitix, acetylsalicylic acid, succsinic acid or their salt of 0.1 to 4 weight %;
B) at least a material that is selected from phenylformic acid, Sodium Benzoate, lithium benzoate, P-hydroxybenzoic acid, toxilic acid or its salt of 0.1 to 4 weight %;
C) 30% of 2.2 to 12 weight % hydrogen peroxide
With
D) ethylenediamine tetraacetic acid (EDTA) of 0.1 to 1.5 weight %, dissolving
E) in water.
21. the composition of claim 20 is characterized in that, described component a) accounts for 0.3-2.5 weight %.
22. the composition of claim 20 is characterized in that, described component b) account for 0.1-3.5 weight %.
23. the composition of claim 20 is characterized in that, described component c) account for 2.5-7.5 weight %.
24. the composition of claim 20 is characterized in that, described component d) account for 0.1-1.3 weight %.
25. the composition of claim 20 is characterized in that, described component e) for the water of lean ore material or remove the water of mineral substance.
26. the purposes of each composition in the claim 1 to 25, it is used to prepare the medicine of treatment bacillary and viral infectious, mycosis, pediculosis and other parsitism.
27. the purposes of each composition in the claim 1 to 25, it is as bactericide, mycocide, insecticide and/or weedicide.
28. the purposes of claim 27, it is in agricultural, gardening, with tonic that deals with plant and animal and/or conditioning liquid, in household and industry, be used as washing composition, as the sterilizing agent of the sterilizing agent of empty G﹠W and swimming pool and Whirlpool and as surface disinfectant.
29. the purposes of each composition in the claim 26 to 28, wherein said composition uses with 1: 50 to 1: 2 extent of dilution.
30. the purposes of claim 29, wherein said composition uses with the extent of dilution of 1: 40 to 1: 3 or 1: 20 to 1: 5 or 1: 10.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10247872.4 | 2002-10-14 | ||
| DE10247872 | 2002-10-14 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1705735A CN1705735A (en) | 2005-12-07 |
| CN100384971C true CN100384971C (en) | 2008-04-30 |
Family
ID=32102755
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2003801013719A Expired - Fee Related CN100384971C (en) | 2002-10-14 | 2003-10-08 | Composition |
Country Status (4)
| Country | Link |
|---|---|
| CN (1) | CN100384971C (en) |
| AU (1) | AU2003285288A1 (en) |
| DE (1) | DE10393374D2 (en) |
| WO (1) | WO2004035718A2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105283535A (en) * | 2013-05-23 | 2016-01-27 | 自然封印公司 | Antimicrobial wash |
Families Citing this family (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20030180377A1 (en) | 2002-02-12 | 2003-09-25 | Ramirez Jose A. | Enhanced activity hydrogen peroxide disinfectant |
| ATE438304T1 (en) * | 2002-11-15 | 2009-08-15 | Virox Technologies Inc | A HYDROGEN PEROXIDE DISINFECTANT CONTAINING ACID AND/OR ALCOHOL |
| US20080305182A1 (en) | 2002-11-15 | 2008-12-11 | Ramirez Jose A | Hydrogen peroxide disinfectant containing a cyclic carboxylic acid and/or aromatic alcohol |
| ES2683330T3 (en) | 2004-05-14 | 2018-09-26 | Virox Technologies Inc. | Hydrogen peroxide based skin disinfectant |
| US8298482B2 (en) | 2005-06-10 | 2012-10-30 | S.C. Johnson & Son, Inc. | Vapor phase hydrogen peroxide deodorizer |
| US20060280665A1 (en) * | 2005-06-10 | 2006-12-14 | S.C. Johnson & Son, Inc. | Vapor phase hydrogen peroxide deodorizer |
| WO2007014575A1 (en) * | 2005-08-02 | 2007-02-08 | Thomas Besendorfer | Composition having bactericidal, fungicidal, virucidal and insecticidal action |
| GB0525504D0 (en) | 2005-12-14 | 2006-01-25 | Bristol Myers Squibb Co | Antimicrobial composition |
| JP2010524976A (en) * | 2007-05-04 | 2010-07-22 | ザ プロクター アンド ギャンブル カンパニー | Antibacterial composition, product and method of use |
| EP2022331A1 (en) * | 2007-08-02 | 2009-02-11 | Wesso Ag | Disinfectant for reducing the number of bacteria and biofilms |
| EP2182811A4 (en) * | 2007-08-15 | 2012-11-28 | Virox Technologies Inc | Antimicrobial compositions |
| FI122723B (en) * | 2007-12-03 | 2012-06-15 | Kemira Oyj | Composition and Method for Treating Wood |
| GB201020236D0 (en) | 2010-11-30 | 2011-01-12 | Convatec Technologies Inc | A composition for detecting biofilms on viable tissues |
| CN102002451B (en) * | 2010-12-14 | 2013-12-18 | 天津市华阳新兴科技有限公司 | Special descaling sterilization cleaning agent for air conditioner and preparation method thereof |
| CN102273488B (en) * | 2011-06-22 | 2012-08-22 | 李翰实 | Nascent oxygen high speed specific bactericidal disinfectant |
| US20140328941A1 (en) * | 2011-12-22 | 2014-11-06 | Medivators Inc. | Non-corrosive stable peracetic acid concentrate solution |
| JP2016507663A (en) | 2012-12-20 | 2016-03-10 | コンバテック・テクノロジーズ・インコーポレイテッドＣｏｎｖａｔｅｃ Ｔｅｃｈｎｏｌｏｇｉｅｓ Ｉｎｃ | Processing of chemically modified cellulosic fibers |
| CN103081945B (en) * | 2013-02-01 | 2015-10-07 | 中山大学 | A kind of mildew-eliminating and mildew-preventing agent and corresponding except mould mold-proof method |
| CN104031771A (en) * | 2014-06-17 | 2014-09-10 | 滁州斯迈特复合材料有限公司 | Gastroscope cleanser |
| CN104031779A (en) * | 2014-06-17 | 2014-09-10 | 滁州斯迈特复合材料有限公司 | Rectoscope washing agent |
| CN104782671A (en) * | 2015-03-25 | 2015-07-22 | 彭新国 | Bacteriostatic disinfecting disinfectant for laboratory department and preparation method for bacteriostatic disinfecting disinfectant |
| WO2017032924A1 (en) | 2015-08-24 | 2017-03-02 | Kemira Oyj | Method for reducing fouling of a microbial fuel cell, cleaning agent composition and its use |
| CN106689198A (en) * | 2017-01-03 | 2017-05-24 | 中国人民解放军北京军区疾病预防控制中心 | Compound hydrogen peroxide disinfectant as well as preparation method and application thereof<0} |
| CN107281173A (en) * | 2017-07-24 | 2017-10-24 | 宁夏智弘生物科技有限公司 | A kind of organic acid dip for animals and preparation method thereof |
| US10450535B2 (en) | 2017-10-18 | 2019-10-22 | Virox Technologies Inc. | Shelf-stable hydrogen peroxide antimicrobial compositions |
| EP3967144A4 (en) * | 2019-05-10 | 2023-01-25 | Kao Corporation | Biofilm removal composition for water system |
| JP2020186228A (en) * | 2019-05-10 | 2020-11-19 | 花王株式会社 | Biofilm removal method |
| CN112593223A (en) * | 2020-12-17 | 2021-04-02 | 南京南炼宏泰技术开发有限公司 | Composite passivation and deodorization cleaning agent and preparation method thereof |
| DE102021129678A1 (en) | 2021-11-15 | 2023-05-17 | Knieler & Team Gmbh | Ready-to-use aqueous disinfectant composition |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4477438A (en) * | 1982-11-12 | 1984-10-16 | Surgikos, Inc. | Hydrogen peroxide composition |
| DE4325312A1 (en) * | 1993-05-17 | 1994-11-24 | Heimo Wessollek | Composition for stabilising water which comes into contact with human or animal skin |
| US5731275A (en) * | 1994-04-05 | 1998-03-24 | Universite De Montreal | Synergistic detergent and disinfectant combinations for decontaminating biofilm-coated surfaces |
| WO2000027438A1 (en) * | 1998-11-06 | 2000-05-18 | Universite De Montreal | Improved bactericidal and non-bactericidal solutions for removing biofilms |
| DE19915028A1 (en) * | 1999-04-01 | 2000-10-05 | Wessollek Heimo | Preserving foodstuffs, especially poultry eggs, and other biological products such as seeds by treatment with a novel low concentration composition containing a preservative |
| EP1057407A1 (en) * | 1999-06-02 | 2000-12-06 | Arconia GmbH | Disinfecting agents for potentially contaminated articles |
| US6284144B1 (en) * | 1998-07-30 | 2001-09-04 | Argad-Eyal Water Treatment Industries Inc. | Water treatment |
| WO2002064718A1 (en) * | 2001-02-14 | 2002-08-22 | Henning Möller | Detergent for removing biofouling |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19910356A1 (en) * | 1999-02-18 | 2000-08-24 | Wessollek Heimo | Means, methods, device and uses for the biological disinfection of air and rooms with air |
| DE29904319U1 (en) * | 1999-03-09 | 2000-08-17 | Wessollek Heimo | Oral and dental care products, in particular toothpaste |
-
2003
- 2003-10-08 WO PCT/EP2003/011100 patent/WO2004035718A2/en not_active Application Discontinuation
- 2003-10-08 DE DE10393374T patent/DE10393374D2/en not_active Withdrawn - After Issue
- 2003-10-08 CN CNB2003801013719A patent/CN100384971C/en not_active Expired - Fee Related
- 2003-10-08 AU AU2003285288A patent/AU2003285288A1/en not_active Abandoned
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4477438A (en) * | 1982-11-12 | 1984-10-16 | Surgikos, Inc. | Hydrogen peroxide composition |
| DE4325312A1 (en) * | 1993-05-17 | 1994-11-24 | Heimo Wessollek | Composition for stabilising water which comes into contact with human or animal skin |
| US5731275A (en) * | 1994-04-05 | 1998-03-24 | Universite De Montreal | Synergistic detergent and disinfectant combinations for decontaminating biofilm-coated surfaces |
| US6284144B1 (en) * | 1998-07-30 | 2001-09-04 | Argad-Eyal Water Treatment Industries Inc. | Water treatment |
| WO2000027438A1 (en) * | 1998-11-06 | 2000-05-18 | Universite De Montreal | Improved bactericidal and non-bactericidal solutions for removing biofilms |
| DE19915028A1 (en) * | 1999-04-01 | 2000-10-05 | Wessollek Heimo | Preserving foodstuffs, especially poultry eggs, and other biological products such as seeds by treatment with a novel low concentration composition containing a preservative |
| EP1057407A1 (en) * | 1999-06-02 | 2000-12-06 | Arconia GmbH | Disinfecting agents for potentially contaminated articles |
| WO2002064718A1 (en) * | 2001-02-14 | 2002-08-22 | Henning Möller | Detergent for removing biofouling |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105283535A (en) * | 2013-05-23 | 2016-01-27 | 自然封印公司 | Antimicrobial wash |
Also Published As
| Publication number | Publication date |
|---|---|
| AU2003285288A1 (en) | 2004-05-04 |
| CN1705735A (en) | 2005-12-07 |
| DE10393374D2 (en) | 2005-09-01 |
| WO2004035718A2 (en) | 2004-04-29 |
| WO2004035718A3 (en) | 2004-08-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN100384971C (en) | Composition | |
| US6024986A (en) | Method of protecting growing plants from the effects of plant pathogens | |
| CN100496250C (en) | Agricultural sterilizing and disinfecting composition, preparation method and application thereof | |
| US7087190B2 (en) | Composition for the production of chlorine dioxide using non-iodo interhalides or polyhalides and methods of making and using the same | |
| CN100407923C (en) | Sterilization disinfectant and application thereof | |
| EP2338343A1 (en) | Enhanced activity hydrogen peroxide disinfectant | |
| CN103430797B (en) | A kind of method of preventing and treating cucumber fungal disease | |
| TW200835450A (en) | An improved peracetic acid composition | |
| US20080194689A1 (en) | Disinfectant and Germicidal Agent | |
| CN107624785A (en) | A kind of low-corrosiveness potassium peroxymonosulfate disinfectant | |
| US20060075922A1 (en) | Controlled-acidity composition | |
| CN102318625A (en) | Preparation of leather composite bactericidal mould inhibitor | |
| US9161534B2 (en) | Methods for cleaning a surface | |
| Ponomarenko et al. | Bactericidal efficiency of preparation based on essential oils used in aerosol disinfection in the presence of poultry | |
| US20090298951A1 (en) | Nontoxic Biocidal Composition And Method Thereof | |
| CN102318634A (en) | Preparation method of compound leather bactericidal and mildew-proof agent | |
| JP3107399B2 (en) | Method for producing disinfecting solution, disinfecting solution and disinfecting medium | |
| US11252934B1 (en) | Compositions for use in animal housing | |
| RU2736364C2 (en) | Disinfectant composition with tartaric acid, lactic acid | |
| JP2009019011A (en) | Powdery mildew controller and control method | |
| EP1036511A2 (en) | Method for preservation and composition for use therewith | |
| KR101740000B1 (en) | Seed disinfectant comprising chitosan implicated essential oils and method thereof | |
| CZ37472U1 (en) | A disinfectant | |
| CZ37541U1 (en) | An algicidal agent | |
| Rahil et al. | COMPARATIVE STUDY OF VARIOUS DISINFECTANTS EFFICIENCY IN POULTRY FARMS |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| ASS | Succession or assignment of patent right |
Owner name: MEISHA HOLDINGS OPERATION CO., LTD. Free format text: FORMER OWNER: AKENIYA CO., LTD. Effective date: 20090410 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20090410 Address after: Stuttgart, Germany Patentee after: Mesago Holding Company Limited Address before: Swiss Ma Lan Patentee before: Arconia GmbH Malans |
|
| ASS | Succession or assignment of patent right |
Owner name: MEISHA MEDICINE CO., LTD. Free format text: FORMER OWNER: MEISHA HOLDINGS OPERATION CO., LTD. Effective date: 20091106 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20091106 Address after: Stuttgart, Germany Patentee after: Mesago Pharmaceutical Co. Ltd. Address before: Stuttgart, Germany Patentee before: Mesago Holding Company Limited |
|
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20080430 Termination date: 20111008 |