CN100383273C - Work-hardened material from stainless steel - Google Patents
Work-hardened material from stainless steel Download PDFInfo
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- CN100383273C CN100383273C CNB2004800203087A CN200480020308A CN100383273C CN 100383273 C CN100383273 C CN 100383273C CN B2004800203087 A CNB2004800203087 A CN B2004800203087A CN 200480020308 A CN200480020308 A CN 200480020308A CN 100383273 C CN100383273 C CN 100383273C
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- 229910001220 stainless steel Inorganic materials 0.000 title claims abstract description 51
- 239000010935 stainless steel Substances 0.000 title claims abstract description 50
- 239000000463 material Substances 0.000 title abstract description 10
- 229910001845 yogo sapphire Inorganic materials 0.000 claims abstract description 19
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000000126 substance Substances 0.000 claims abstract description 11
- 239000000203 mixture Substances 0.000 claims abstract description 6
- 238000005482 strain hardening Methods 0.000 claims description 36
- 239000004615 ingredient Substances 0.000 claims description 10
- 230000003749 cleanliness Effects 0.000 claims description 6
- 239000012535 impurity Substances 0.000 claims 1
- 238000005452 bending Methods 0.000 abstract description 53
- 229910000529 magnetic ferrite Inorganic materials 0.000 abstract description 13
- 229910000859 α-Fe Inorganic materials 0.000 abstract description 13
- 239000002245 particle Substances 0.000 abstract description 8
- PNEYBMLMFCGWSK-UHFFFAOYSA-N AI2O3 Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract description 3
- 229910052802 copper Inorganic materials 0.000 abstract description 2
- 229910052593 corundum Inorganic materials 0.000 abstract 2
- 229910052804 chromium Inorganic materials 0.000 abstract 1
- 229910052748 manganese Inorganic materials 0.000 abstract 1
- 229910052759 nickel Inorganic materials 0.000 abstract 1
- 229910052758 niobium Inorganic materials 0.000 abstract 1
- 229910000831 Steel Inorganic materials 0.000 description 45
- 239000010959 steel Substances 0.000 description 45
- 229910000734 martensite Inorganic materials 0.000 description 27
- 238000005097 cold rolling Methods 0.000 description 9
- 230000015572 biosynthetic process Effects 0.000 description 8
- 239000011651 chromium Substances 0.000 description 8
- 238000005755 formation reaction Methods 0.000 description 8
- 239000011159 matrix material Substances 0.000 description 8
- 238000005096 rolling process Methods 0.000 description 8
- 238000007493 shaping process Methods 0.000 description 7
- 230000002939 deleterious Effects 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 230000003628 erosive Effects 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 206010011376 Crepitations Diseases 0.000 description 5
- 238000005275 alloying Methods 0.000 description 5
- 238000006477 desulfuration reaction Methods 0.000 description 5
- 230000003009 desulfurizing Effects 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 238000005554 pickling Methods 0.000 description 5
- 230000001131 transforming Effects 0.000 description 5
- 238000003754 machining Methods 0.000 description 4
- 238000007669 thermal treatment Methods 0.000 description 4
- 238000000137 annealing Methods 0.000 description 3
- 229910001566 austenite Inorganic materials 0.000 description 3
- 229910000963 austenitic stainless steel Inorganic materials 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 238000005336 cracking Methods 0.000 description 3
- 239000010419 fine particle Substances 0.000 description 3
- 239000007769 metal material Substances 0.000 description 3
- 230000002829 reduced Effects 0.000 description 3
- 238000005728 strengthening Methods 0.000 description 3
- 210000001519 tissues Anatomy 0.000 description 3
- 239000000470 constituent Substances 0.000 description 2
- 229910001039 duplex stainless steel Inorganic materials 0.000 description 2
- 238000004453 electron probe microanalysis Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000005098 hot rolling Methods 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 238000005070 sampling Methods 0.000 description 2
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Inorganic materials [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 2
- UFGZSIPAQKLCGR-UHFFFAOYSA-N Chromium carbide Chemical compound [Cr]#C[Cr]C#[Cr] UFGZSIPAQKLCGR-UHFFFAOYSA-N 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N TiO Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- REDXJYDRNCIFBQ-UHFFFAOYSA-N aluminium(3+) Chemical class [Al+3] REDXJYDRNCIFBQ-UHFFFAOYSA-N 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000010813 municipal solid waste Substances 0.000 description 1
- 230000000414 obstructive Effects 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching Effects 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 238000009628 steelmaking Methods 0.000 description 1
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical compound S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 238000005496 tempering Methods 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N tin hydride Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 229910003470 tongbaite Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
Abstract
A work-hardened material from a stainless steel sheet, which has a chemical composition, in mass %, that C: 0.15 % or less, Si: 1.0 % or less, Mn: 1.0 % or less, S: 0.005 % or less, Cr: 10 to 20 %, Ni: 0.5 % or less, Al: 0.001 to 0.05 %,and optionally, one or more of Mo: 0.5 to 2.0 %, Cu: 0.5 to 3.0 % and Nb: 0.05 to 1.0 %, wherein Al2O3 based and/or Al2O3.MgO based inclusions having a particle diameter <= 10 mum are dispersed in a cleanness <= 0.06 %, and the material exhibits enhanced strength due to a work ferrite structure. The above work-hardened material exhibits an 0.2 % offset yield strength as high as 700 N/mm<2> or higher and also is excellent in bending workability, and thus can be suitably used as parts or a structural material for a household electrical appliance, an OA equipment and the like.
Description
Technical field
The invention relates to the stainless steel plate of work hardening, this steel plate has the ferritic structure strengthened by work hardening to improve intensity and bending property.
Background technology
For household electrical appliance or office automation device televisor and PC portable notebook computer particularly for example, exist the trend that requires to alleviate its internals weight.This weight saving is to realize by the thickness that reduces each parts, although thickness has reduced, also will guarantee to use necessary intensity.To this, 0.2% offset yield strength is 500N/mm at least
2Perhaps Vickers' hardness at least the steel of HV200 be used to this purpose.
Framework in household electrical appliance or the office automation device or housing generally are to become desired appearance profile to make by sheet material compacting or the bending machining that will cut, therefore, the metallic substance that is used for this purposes also should have good bending property except mechanical property.
In recent years, for environment protection and the recyclable consideration that utilizes the aspect, very urgent for the demand of the non-packed metallic substance supply of material that does not need plating or application.Representational non-packed metallic substance with good corrosion resistance is Martensite Stainless Steel (for example SUS410 or SUS420J2), PH Stainless Steel (for example SUS631) or work hardening austenitic stainless steel (for example SUS304 or SUS301).
Martensite Stainless Steel or PH Stainless Steel, after machine-shaping is desired profile, also will for example quenching and tempering or timeliness be strengthened by thermal treatment.But this thermal treatment will be undertaken by Metal Processing Factory, and therefore, Metal Processing Factory must bear the expense of Equipment for Heating Processing.In addition, also need to carry out pickling or grind removing descaling through heat treated steel plate, and will be to carrying out shaping through heat treated steel plate to eliminate the distortion that produces owing to thermal treatment.
On the other hand, the work hardening austenitic stainless steel just has enough intensity and good bending property under the sheet material state, thereby Metal Processing Factory can remove heat treatment step from, but owing to added the Ni of higher rate, this stainless steel price is very expensive.Problem has proposed several technical schemes at present hereto, reduces Ni content under the situation of the advantage that does not weaken the work hardening austenitic stainless steel, to reduce the cost of steel.For example, disclose a kind of ferrite/martensite duplex stainless steel among the JP63-169330A, its intensity and forming property improve by martensitic phase and ferritic phase respectively.Disclose a kind of stainless steel among the JP11-302791A, its bending property improves by being controlled at the single-phase middle size and dimension of the MnS inclusion of existence that disperses of ferrite/martensite two-phase or martensite.Disclose a kind of stainless steel among the JP2001-262282A, its ferritic structure does not need to heat-treat and processed sclerosis.
Disclose a kind of ferrite/martensite duplex stainless steel among the JP63-169330A, its intensity can be improved by the ratio that increases martensitic phase, but its bending property significantly worsens when 50 quality % are above at the martensitic phase ratio.
Disclose a kind of stainless steel among the JP11-302791A, be mainly used to as the rectangular pipe that has in the building structure than the macrobending radius.On the other hand, the framework of household electrical appliance, housing or casing are by being that desired profile is made with the bending radius that is significantly less than rectangular pipe with steel formability.Because bending radius is very little, the single-phase stainless steel plate of two-phase or martensite also is like this shaping to the shape of framework, housing or casing regular meeting's cracking often even the size and dimension of MnS suitably controls.
Not open particularly size and dimension how to control MnS in JP11-302791A.As everyone knows, the bending property of steel plate owing to exist along the fine strip shape MnS of rolling direction elongation is worsened.Along with the increase of cold roling reduction, MnS further elongation also finally becomes tiny particles dispersed in the matrix of steel.As a result, for thin steel plate, MnS still for relative thicker steel plate, can not expect that MnS disperses with the form of fine particle, thereby MnS remains deleterious owing to fine disperseing to become harmless.In addition, to adapt to various purposes, need carry out various Alloying Design in order to ensure suitable intensity, this is because do not need heat treated two-phase or the single-phase stainless intensity of martensite mainly to be determined by alloying constituent.
With the strengthening phase ratio by martensitic transformation, the cold rolling process of ferritic structure work hardening is more helped improving bending property.But JP2001-262282A is that this disk brake is to be made by stainless steel plate, does not need to carry out bending machining at the disk brake of motorcycle.According to the steel plate that the condition of this patent suggestion is made, be not suitable for the material of framework, housing and casing, because these steel plates are carrying out bending machining regular meeting's cracking often with less bending radius.
Summary of the invention
The stainless steel plate that the purpose of this invention is to provide a kind of reinforcement, this steel plate can be shaped to desired profile and can not ftracture, even also be like this under very harsh processing conditions.Another object of the present invention is, by the desulfurization and the Combined Processing of carrying out deoxidation with Al, makes inclusion become tiny Al
2O
3Or Al
2O
3The MgO particle, and do not need thermal treatment and ferritic structure by cold rolling formation work hardening, thus improve the forming property and the intensity of stainless steel plate.
Work hardening stainless steel plate of the present invention is characterised in that its chemical ingredients and metallographic structure.
Stainless steel of the present invention is grouped into by following one-tenth: Cr, 0.5 quality % or lower Ni, the Al of 0.001-0.05 quality % of 0.15 quality % or lower C, 1.0 quality % or lower Si, 1.0 quality % or lower Mn, 0.005 quality % or lower S, 10-20 quality %, surplus is Fe basically.This stainless steel can also further contain and is selected from down at least a in the group element: the Cu of the Mo of 0.5-2.0 quality %, 0.5-3.0 quality % and the Nb of 0.05-1.0 quality %.
This stainless steel has the ferritic structure of work hardening, wherein is dispersed with Al
2O
3And/or Al
2O
3The fine particle of MgO, particulate are of a size of 10 μ m or littler, and the cleanliness factor index of steel is 0.06% or lower.Its 0.2% offset yield strength preferably is controlled at 500-900N/mm by cold roling reduction
2Scope in.
Embodiment
MnS is that a kind of it is softer to the deleterious inclusion of bending property, along the rolling direction elongation, thereby forms fine strip shape and is scattered in the matrix of steel in cold-rolled process.Such stainless steel plate is bent and adds man-hour, and MnS is owing to stress concentration becomes formation of crack.Only desulfurization deficiency is so that MnS becomes harmless, but must control composition, the size and dimension of MnS inclusion for the generation that suppresses crackle.
The composition of MnS inclusion, size and shape change along with the kind of adding the reductor in the molten steel in steel making working procedure to, for example, when adding Si as reductor, also form MnOSiO except forming MnS
2And/or MnOSiO
2MnS.Another kind of reductor Ti can suppress the formation of bar shaped inclusion, but has formed TiN and TiO as deoxidation products
2These reaction product combine becomes thick nanocluster, makes and produces surface imperfection on the stainless steel plate.The Ti deoxidation is also followed the middle pot drainage opening obstruction is taken place, unless reduce the N content in the molten steel especially.
The inventor has reviewed and analysed inhibition MnS, MnOSiO
2And MnOSiO
2The various processing condition of inclusiones such as MnS, these inclusiones worsen the bending property of steel plate and the outward appearance of steel plate are worsened.In research process, the inventor is surprised to find that, by carrying out specific deoxidation with Al, makes inclusion change over Al
2O
3Or Al
2O
3MgO type inclusion can improve the bending property of steel plate.In fact, by the desulfurization and the Combined Processing of carrying out deoxidation, form that to have with the cleanliness factor index be 0.06% or the littler Al that is distributed with 10 μ m sizes in the matrix of steel with Al
2O
3Or Al
2O
3The steel plate of the tissue of MgO inclusion, this steel plate can be shaped to desired profile with good bending property, and this point can obtain explanation in the following embodiments.
Because stainless steel plate is strengthened by the ferritic phase that cold working has formed work hardening, therefore just can give stainless steel plate to be suitable for 0.2% offset yield strength of application target without any need for specific Alloying Design.Representational cold working is cold rolling, by the control cold roling reduction yield strength is adjusted into 500-900N/mm
2One numerical value in (being Vickers' hardness 200-300HV) scope.By the way, the ferrite stainless steel of as-annealed condition has about 250-300N/mm usually
2The yield strength of (the about 130-150HV of Vickers' hardness) is far below desired value.
Ferrite stainless steel of the present invention has the tissue that composition, size and the shape of chemical ingredients described below and inclusion are controlled.
＜Alloying Design 〉
C:0.15 quality % or lower
C is an alloying element of strengthening the matrix of steel, but excessive C impels the chromium carbide precipitation to separate out, and causes erosion resistance to worsen.Therefore, the upper limit of C content is confirmed as 0.15 quality %, preferably 0.08 quality %.
Si:1.0 quality % or lower
Si is a ferrite shaping element of strengthening the matrix of steel.But the excessive Si that is higher than 1.0 quality % promotes on the contrary for the deleterious SiO of bending property
2Or MnOSiO
2The inclusion precipitation is separated out.
Mn:1.0 quality % or lower
Mn is a kind of austenite shaping element, and it is with to the deleterious MnOSiO of bending property
2Form be scattered in the matrix of steel.Therefore, the upper limit of Mn is confirmed as 1.0 quality %, preferably 0.5 quality %.
S:0.005 quality % or lower
S is dissolved in deleterious MnS of bending property and MnOSiO
2In, form thick oxysulfide particle.In order to suppress the deleterious effect of S, the upper limit of S is defined as 0.005 quality %, preferably 0.003 quality %.
Cr:10-20 quality %
Cr improves the requisite element of erosion resistance, and in order to ensure erosion resistance, Cr content is necessary for 10 quality % or higher as stainless steel.But the excessive Cr that is higher than 20 quality % can make stainless toughness worsen.Cr content preferably is controlled in the 11-18 quality % scope.
Ni:0.5 quality % or lower
Ni is the austenite shaping element.Along with the increase of Ni content, stainless Ac
1Temperature reduces, and the cooling stages in annealing process promotes the formation of martensitic phase.Therefore, Ni content is controlled to 0.5 quality % or lower, to suppress the formation of martensitic phase.
Al:0.001-0.05 quality %
Al adds as reductor.Al content is controlled at least 0.001 quality % can obtain enough deoxidation effects.But excessive Al can cause Al
2O
3The a large amount of precipitations of particle are separated out.These Al
2O
3Particle combines the formation nanocluster, produces surface imperfection on stainless steel plate.For with Al
2O
3Particulate size control 10 μ m or littler and have 0.06% or lower cleanliness factor are defined as 0.05 quality % with the upper limit of Al content.Al content preferably is controlled at 0.003-0.03 quality %.
Mo:0.5-2.0 quality %
Cu:0.5-3.0 quality %
Nb:0.05-1.0 quality %
Each element among Mo, Cu and the Nb all is the element of choosing wantonly, is used to improve erosion resistance.These three kinds of constituent contents are Mo:0.5 quality % or higher, Cu:0.5 quality % or higher or Nb:0.05 quality % or when higher, can observe the effect for erosion resistance.But, be higher than excessive Mo stainless cold-forming property deterioration of 2.0 quality % owing to its solution hardening effect makes, the excessive Cu that is higher than 3.0 quality % worsens stainless hot workability and productivity, the excessive Nb that is higher than 1.0 quality % improved the cost of steel and the erosion resistance of steel without any improvement.
The ferritic structure of＜work hardening 〉
By desulfurization with use the Al deoxidation, the inclusion that is scattered in the matrix of steel is changed into Al
2O
3Or Al
2O
3MgO, by cold working, the inclusion after these change is divided into 10 μ m size or littler fine particle, preferably 5 μ m or littler particle.The change of inclusion and cut apart refinement and avoided the stress concentration that on inclusion, forms effectively, and these inclusiones play the effect of formation of crack usually.Therefore, stainless steel plate can be shaped to desired profile with very little radius at crooked position, has significantly reduced the rimose generation.
Cold working helps the hardened stainless steel plate and inclusion is divided into tiny particle.That is, under common as-annealed condition, has about 250-300N/mm
2The ferrite stainless steel of yield strength (the about 130-150HV of Vickers' hardness) strengthened by work hardening.In addition, yield strength value can be adjusted into 500-900N/mm arbitrarily by control cold working draught
2Numerical value in (Vickers' hardness 200-300HV) scope just can not provide the steel with the intensity that is suitable for application target thereby do not need to change design of alloy.Under by the cold rolling situation that makes stainless steel plate work hardening, bending property is worsened, the rolling draught in final cold rolling process is defined in the scope of 15-50% (preferably 20-35%).
Can more be expressly understood further feature of the present invention by the following examples.
Embodiment 1
Use Si that the fused molten stainless steel is carried out deoxidation and it is adjusted to each chemical ingredients shown in the table 1.Sample S-1 is a kind of stainless steel plate, and recrystallize forms single ferritic structure to this stainless steel plate by annealing after hot rolling, and it is thick to be cold-rolled to 1.8mm with 25% rolling draught then, makes ferritic structure work hardening.Sample S-2 and S-3 also are stainless steel plates, and it is thick that they all are cold-rolled to 1.8mm in the same way, keep one short period under the comparatively high temps in austenite/ferrite two-phase region, and air cooling forms ferrite/martensite duplex structure then.The ratio of the martensitic phase among the sample S-2 is greater than sample S-3.
Table 1: stainless chemical ingredients (quality %)
| C | Si | Mn | S | Cr | Ni | Al | |
| S-1 | 0.068 | 0.38 | 0.39 | 0.006 | 12.4 | 0.4 | ＜0.003 |
| S-2 | 0.023 | 0.47 | 0.85 | 0.004 | 11.9 | 0.09 | ＜0.003 |
| S-3 | 0.011 | 0.24 | 0.89 | 0.001 | 11.7 | 0.14 | ＜0.003 |
From each piece stainless steel plate in two directions is vertically (hereinafter being called " L direction ") and laterally (hereinafter being called " T direction ") sampling, makes the sample of the tension test that is used for JIS 13B (JISZ 2201) regulation.Carry out tension test with these samples, measure yield strength and unit elongation.Test-results is shown in Table 2.As can be seen from Table 2, the yield strength of sample S-1 and the ratio of martensitic phase are that the value of sample S-2 of 80 volume % is similar haply, but its unit elongation is littler than sample S-2.
Table 2: metallographic structure and mechanical property
Y.S.:0.2% offset yield strength E1.: unit elongation
Adopt V-block bending method (the V-block pliability test of being undertaken by the angle of bend of JIS Z 2248 regulations by 90 degree) to estimate the bending property of each stainless steel plate.Promptly, use has the drift of different top curved radius Rs, carry out bending (hereinafter being called " bending of T direction ") and carry out bending (hereinafter being called " bending of L direction ") with the right angle with the right angle around the axle that is parallel to rolling direction around axle perpendicular to rolling direction, each sample is carried out pliability test, use sample to be bent and rimose minimum radius R does not take place represent bending property.
By the test-results in the table 3 as can be seen, each sample trend that crackle takes place when the T direction is crooked is different, although all samples all not have to ftracture when carrying out L direction v-shaped bending with the minimum radius R of 0.1mm.For sample S-1, the minimum radius R that crackle takes place is 0.6mm, and the minimum radius R that sample S-2 crackle takes place is 1.5mm, although sample S-1 and S-2 have yield strength much at one.Comparison shows that of these test-results, the bending property of sample S-1 is better than sample S-2 and S-3, although its unit elongation is less than S-2 and S-3.In brief, compare with martensitic stucture, the ferritic structure of work hardening helps bending property.
Table 3: the bending property of each sample
Do not ftracture cracking when * expression is crooked when zero expression is crooked
Investigate the influence of inclusion by the following stated to bending property:
The fused molten stainless steel is adjusted into the chemical ingredients identical with sample S-1, uses the Al deoxidation, then according to it being treated as Sample A-1 with top described identical creating conditions.In the Sample A-1, deriving from the Al content of reductor as shown in table 4 is 0.006 quality %.
Analyze through EPMA, the inclusion in the Sample A-1 is confirmed as Al
2O
3And Al
2O
3The mixture of MgO is different from the MnOSiO among the sample S-1 significantly
2Or MnOSiO
2MnS.Hereinafter, with the SiO among the sample S-1
2The base inclusion is called " silicate-type ", and with the Al in the Sample A-1
2O
3The base inclusion is called " alumina type ".
Table 4: reductor is to the influence of chemical ingredients
| Steel grade | C | Si | Mn | S | Cr | Ni | Al |
| S-1 | 0.068 | 0.38 | 0.39 | 0.006 | 12.4 | 0.40 | ＜0.003 |
| A-1 | 0.062 | 0.39 | 0.27 | 0.001 | 12.6 | 0.21 | 0.006 |
By taking a sample along L direction and T direction among Sample A-1 and the S-1, make the sample JIS 13B that is used for tension test, carry out tension test with these samples, measure yield strength and unit elongation.According to test-results, as shown in table 5, Sample A-1 has identical mechanical property with S-1.On the other hand, as shown in table 6, the result of pliability test shows that the T direction bending property of Sample A-1 is better than sample S-1 significantly, although Sample A-1 and S-1 have yield strength much at one.
The above results shows, forms the ferritic structure of work hardening by desulfurization and the Combined Processing of carrying out deoxidation with Al with the shape of control inclusion and by cold working, and stainless steel plate is endowed good bending property, this with strengthen irrelevant.
Table 5: with Si or Al deoxidation influence to mechanical property
Table 6: with Si or Al deoxidation influence to bending property
Embodiment 2
Several stainless steels that the vacuum oven melting of use 30kg has chemical ingredients shown in the table 7 add Al or Si reductor and carry out deoxidation.
Table 7: stainless chemical ingredients and deoxidation situation
The numeral of band underscore is the numerical value beyond defined terms of the present invention.
Each stainless steel ingot is forged into the steel plate of thick 55mm, wide 100mm.Steel plate is carried out grinding, be reduced to 50mm until its thickness.Then, hot-rolled steel plate is thick to 5mm.Some owing to hot rolling has formed martensitic phase, annealed pickling then with these steel plates 7 hours at 850 ℃ through the hot rolled steel plate.Other the hot-rolled steel sheet that does not have martensitic phase carries out pickling then 1040 ℃ of following continuous annealings.
For the steel grade that is strengthened by work hardening, with the interior thickness of cold-rolling of steel plate,, carry out pickling, and then be cold-rolled to the final thickness of 1.8mm 850 ℃ of following continuous annealings to 2.3-2.8mm.Total rolling draught of each steel plate is controlled in the scope of 20-35%.
For the steel grade that is strengthened by martensitic transformation, with the interior thickness of annealed cold-rolling of steel plate to 3.0mm, annealing is carried out pickling, and then is cold-rolled to the final thickness of 1.8mm once more.Heat-treat through cold rolling steel plate, promptly heat 1 minute air cooling then down, make its structural transformation become martensite single phase structure or ferrite/martensite duplex structure at 1000 ℃.
Make sample from each stainless steel plate sampling of making, observe its metallographic structure, inclusion and surface imperfection by the above.Adopt EPMA to analyze and differentiate inclusion, the cleanliness factor index adopts the method for stipulating among the JIS G0555 to measure, when measuring cleanliness factor by microscopic examination to the main shaft of inclusion of maximum be used as the size of inclusion.To be yield strength, unit elongation and bending property measure according to the method identical with embodiment 1 other performance.
Measurement result is shown in Table 8.As can be seen from Table 8, the sample № 1-8 that the ferritic structure by work hardening is strengthened, the shape of the inclusion in this ferritic structure is controlled by using Al to carry out deoxidation, although these samples have 700N/mm
2Or higher high-yield strength, therefore its bending property is still very good, can carry out bending machining and can not ftracture with 0.1mm or littler minimum radius R.
Sample № 9 yield strength high on the other hand owing to martensitic transformation has, its bending property extreme difference, minimum bending radius R is 2.5mm.Sample № 10 is that cost is improved its bending property by reducing the ratio of martensitic stucture to sacrifice intensity, and its minimum bending radius R is 0.6mm.Comparison shows that of these test-results, martensitic transformation can be strengthened steel plate effectively, but does not have what effect for improving bending property.
Even under situation, also should suitably control Al content in order to improve bending property with the Al deoxidation.Be that sample № 11 has lower Al content, exist its bending property of silicate-type inclusion poor owing to leave over.Sample № 12 uses the excessive Al of 0.09 quality % to carry out excessive deoxidation, and its bending property is good but have surface imperfection.
Sample № 13-15 is owing to use Si to carry out deoxidation, and inclusion has wherein become silicate-type, so its bending property is more inferior than sample № 1-8.
The mechanical property of table 8 stainless steel plate and bending property
WF represents the ferritic structure of work hardening, and F+M represents the ferrite/martensite tissue.The numeral that has underscore is the numerical value outside defined terms scope of the present invention.
Sample except № 9,10 and 13 is owing to the ferritic structure of work hardening has 700N/mm
2Or higher yield strength, the ferritic structure of these work hardening is to carry out cold rolling formation by the final rolling draught with 20-30%.As if the ductility of all these samples is all poor, and its unit elongation has only 4% even lower, but its bending property is very good.Good bending property may be to come from that local extension leads rather than overall unit elongation, so the ferritic structure of work hardening has improved the local ductility at its outside curve position effectively.In addition, the stress concentration of the boundary between the matrix of inclusion and steel is suitably controlled and is alleviated owing to the shape of inclusion.Therefore, when shaping stainless steel plate of the present invention into desired profile, the generation of crackle is suppressed.
Industrial applicibility of the present invention
Ferrite stainless steel of the present invention as described above is owing to the ferritic structure of work hardening and utilize the Al deoxidation that the controlled field trash of its shape is strengthened, although thereby have a 700N/mm2Or higher high-yield strength, its bending property is still very good. The corrosion resistant plate of this work hardening does not need metal lining (metal lining is unfavorable for environmental protection) just can use. Because this corrosion resistant plate strengthened by work hardening, therefore do not need to heat-treat in the user there, can shape and be desired profile. In addition, the stainless steel that has the Ni content of reduction can be used as the framework of household electrical appliance or office automation device etc. and the cheap material of housing.
Claims (3)
1. the stainless steel plate of work hardening is characterized in that,
Have the chemical ingredients of forming by following compositions: Cr, 0.5 quality % or lower Ni, the Al of 0.001-0.05 quality % of 0.15 quality % or lower C, 1.0 quality % or lower Si, 1.0 quality % or lower Mn, 0.005 quality % or lower S, 10-20 quality %, surplus is Fe except unavoidable impurities;
And the ferritic structure with work hardening, wherein with the cleanliness factor index be 0.06% or lower being dispersed be of a size of 10 μ m or littler Al
2O
3And/or Al
2O
3The MgO inclusion.
2. the stainless steel plate of the described work hardening of claim 1 is characterized in that, described chemical ingredients also comprises and is selected from down in the group element one or more: the Cu of the Mo of 0.5-2.0 quality %, 0.5-3.0 quality % and the Nb of 0.05-1.0 quality %.
3. the stainless steel plate of claim 1 or 2 described work hardening is characterized in that, this stainless steel plate has 500-900N/mm
2Yield strength in the scope.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP287774/2003 | 2003-08-06 | ||
| JP2003287774 | 2003-08-06 |
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| CN100383273C true CN100383273C (en) | 2008-04-23 |
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| US (1) | US20060118208A1 (en) |
| JP (1) | JP4237183B2 (en) |
| KR (1) | KR100741993B1 (en) |
| CN (1) | CN100383273C (en) |
| WO (1) | WO2005014873A1 (en) |
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| JP3753248B2 (en) * | 2003-09-01 | 2006-03-08 | 核燃料サイクル開発機構 | Method for producing martensitic oxide dispersion strengthened steel with residual α grains and excellent high temperature strength |
| EP2265739B1 (en) | 2008-04-11 | 2019-06-12 | Questek Innovations LLC | Martensitic stainless steel strengthened by copper-nucleated nitride precipitates |
| US10351922B2 (en) * | 2008-04-11 | 2019-07-16 | Questek Innovations Llc | Surface hardenable stainless steels |
| CN101748339B (en) * | 2008-12-11 | 2012-03-28 | 宝山钢铁股份有限公司 | High-strength ferritic stainless steel band and manufacturing method thereof |
| JP5467673B2 (en) * | 2009-04-23 | 2014-04-09 | 日新製鋼株式会社 | Ferritic stainless steel for corrugated tubes |
| CN101649418B (en) * | 2009-09-10 | 2011-06-01 | 山西太钢不锈钢股份有限公司 | Ferrite stainless steel cold-rolled steel band and manufacturing method thereof |
| US20110062805A1 (en) * | 2009-09-17 | 2011-03-17 | Caterpillar Inc. | Switched reluctance machine with eddy current loss dampener |
| CN103276299B (en) * | 2013-04-16 | 2017-09-05 | 宝钢不锈钢有限公司 | The ferritic stainless steel steel plate and its manufacture method of a kind of great surface quality |
| JP6405613B2 (en) * | 2013-10-16 | 2018-10-17 | Tdk株式会社 | Electrochemical devices |
| JP6295155B2 (en) | 2014-07-22 | 2018-03-14 | 新日鐵住金ステンレス株式会社 | Ferritic stainless steel, manufacturing method thereof, and heat exchanger using ferritic stainless steel as a member |
| JP6786418B2 (en) * | 2016-03-17 | 2020-11-18 | 日鉄ステンレス株式会社 | Martensitic stainless steel for brake discs and brake discs |
| CN106756503B (en) * | 2016-12-27 | 2018-05-22 | 北京首钢吉泰安新材料有限公司 | Free cutting alloy, B alloy wire, its preparation method, nib, pen core and pen |
| JP2019044255A (en) * | 2017-09-07 | 2019-03-22 | Ｊｆｅスチール株式会社 | Ferritic stainless steel sheet |
| KR20210144847A (en) | 2019-05-29 | 2021-11-30 | 제이에프이 스틸 가부시키가이샤 | Ferritic stainless steel sheet and its manufacturing method |
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| JP2002206148A (en) * | 2001-01-09 | 2002-07-26 | Nisshin Steel Co Ltd | Austenitic stainless steel sheet having low work cracking sensitivity and production method therefor |
| JP4065141B2 (en) * | 2002-05-24 | 2008-03-19 | 株式会社福田組 | Purification method for contaminated soil |
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2004
- 2004-08-03 JP JP2005512982A patent/JP4237183B2/en active Active
- 2004-08-03 CN CNB2004800203087A patent/CN100383273C/en active Active
- 2004-08-03 WO PCT/JP2004/011410 patent/WO2005014873A1/en active Application Filing
- 2004-08-03 KR KR1020057012885A patent/KR100741993B1/en active IP Right Grant
- 2004-08-03 US US10/540,365 patent/US20060118208A1/en not_active Abandoned
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|---|---|---|---|---|
| JPH0218379B2 (en) * | 1983-03-08 | 1990-04-25 | Nippon Steel Corp | |
| JPH0465141B2 (en) * | 1983-03-08 | 1992-10-19 | Nippon Steel Corp | |
| JPH05255816A (en) * | 1992-03-12 | 1993-10-05 | Nkk Corp | Manufacture of ferritic stainless steel excellent in workability and thin steel sheet thereof |
| CN1038048C (en) * | 1993-08-16 | 1998-04-15 | 新日本制铁株式会社 | Steel containing ultrafine oxide inclusions dispersed therein |
| JPH08246105A (en) * | 1995-03-08 | 1996-09-24 | Nippon Yakin Kogyo Co Ltd | Ferritic stainless steel excellent in corrosion resistance and weldability |
| JPH1036911A (en) * | 1996-07-23 | 1998-02-10 | Nippon Steel Corp | Production of ferritic stainless steel excellent in surface characteristic |
| JP2002194505A (en) * | 2000-12-22 | 2002-07-10 | Sumitomo Metal Ind Ltd | Ferrite stainless steel and its production method of the same |
Also Published As
| Publication number | Publication date |
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| CN1823177A (en) | 2006-08-23 |
| JP4237183B2 (en) | 2009-03-11 |
| KR100741993B1 (en) | 2007-07-23 |
| US20060118208A1 (en) | 2006-06-08 |
| KR20060026844A (en) | 2006-03-24 |
| JPWO2005014873A1 (en) | 2006-10-05 |
| WO2005014873A1 (en) | 2005-02-17 |
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