CL2011003096A1 - Process for producing liquid biomass products comprising a) introducing biomass and reformed molecular hydrogen into a hydropyrolysis reactor, b) removing carbon residue from the hydropyrolysis liquid; c) hydroconverting said liquid in a hydroconversion reactor and d) producing reformed hydrogen for use in a). - Google Patents

Process for producing liquid biomass products comprising a) introducing biomass and reformed molecular hydrogen into a hydropyrolysis reactor, b) removing carbon residue from the hydropyrolysis liquid; c) hydroconverting said liquid in a hydroconversion reactor and d) producing reformed hydrogen for use in a).

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Publication number
CL2011003096A1
CL2011003096A1 CL2011003096A CL2011003096A CL2011003096A1 CL 2011003096 A1 CL2011003096 A1 CL 2011003096A1 CL 2011003096 A CL2011003096 A CL 2011003096A CL 2011003096 A CL2011003096 A CL 2011003096A CL 2011003096 A1 CL2011003096 A1 CL 2011003096A1
Authority
CL
Chile
Prior art keywords
liquid
hydropyrolysis
producing
reformed
reactor
Prior art date
Application number
CL2011003096A
Other languages
Spanish (es)
Inventor
Terry L Marker
Larry G Felix
Martin B Linck
Original Assignee
Gas Technology Inst
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US12/419,535 external-priority patent/US20100251600A1/en
Application filed by Gas Technology Inst filed Critical Gas Technology Inst
Publication of CL2011003096A1 publication Critical patent/CL2011003096A1/en

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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/06Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by destructive hydrogenation
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    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/06Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
    • C01B3/12Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
    • C01B3/16Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide using catalysts
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    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42Catalytic treatment
    • C10G3/44Catalytic treatment characterised by the catalyst used
    • C10G3/45Catalytic treatment characterised by the catalyst used containing iron group metals or compounds thereof
    • C10G3/46Catalytic treatment characterised by the catalyst used containing iron group metals or compounds thereof in combination with chromium, molybdenum, tungsten metals or compounds thereof
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/50Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids in the presence of hydrogen, hydrogen donors or hydrogen generating compounds
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10G3/00Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/60Controlling or regulating the processes
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
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    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/0205Processes for making hydrogen or synthesis gas containing a reforming step
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    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/0283Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
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    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
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    • C01B2203/042Purification by adsorption on solids
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    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
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    • C01B2203/042Purification by adsorption on solids
    • C01B2203/043Regenerative adsorption process in two or more beds, one for adsorption, the other for regeneration
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    • C01B2203/0465Composition of the impurity
    • C01B2203/0475Composition of the impurity the impurity being carbon dioxide
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    • C01B2203/08Methods of heating or cooling
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    • C01B2203/0805Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0811Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
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    • C01B2203/08Methods of heating or cooling
    • C01B2203/0805Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0811Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
    • C01B2203/0827Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel at least part of the fuel being a recycle stream
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    • C01B2203/12Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205Composition of the feed
    • C01B2203/1211Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
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    • C01B2203/1241Natural gas or methane
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    • C01B2203/12Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205Composition of the feed
    • C01B2203/1211Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235Hydrocarbons
    • C01B2203/1247Higher hydrocarbons
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    • C01B2203/14Details of the flowsheet
    • C01B2203/148Details of the flowsheet involving a recycle stream to the feed of the process for making hydrogen or synthesis gas
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10Feedstock materials
    • C10G2300/1011Biomass
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40Characteristics of the process deviating from typical ways of processing
    • C10G2300/4018Spatial velocity, e.g. LHSV, WHSV
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
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    • C10G2300/805Water
    • C10G2300/807Steam
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    • C10G2400/00Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/02Gasoline
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10G2400/00Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/04Diesel oil
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/141Feedstock
    • Y02P20/145Feedstock the feedstock being materials of biological origin
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y02P30/00Technologies relating to oil refining and petrochemical industry
    • Y02P30/20Technologies relating to oil refining and petrochemical industry using bio-feedstock

Abstract

Proceso para producir productos líquidos de biomasa que comprende a) Introducir subtancialmente solo biomasa e H2 reformado en reactor de hidrópirolisis, b) Remover dicho residuo de carbón de dicho líquido de hidrópirolisis; c) Hidroconvertir dicho líquido en recipiente del reactor de hidroconversión y d) Flujo a) y c) Se convierten Co y Co2.Process for producing liquid biomass products comprising a) Substantially introducing only biomass and reformed H2 in a hydropyrolysis reactor, b) Removing said carbon residue from said hydropyrolysis liquid; c) Hydroconverting said liquid in the hydroconversion reactor vessel and d) Flow a) and c) Co and Co2 are converted.

CL2011003096A 2009-04-07 2011-12-06 Process for producing liquid biomass products comprising a) introducing biomass and reformed molecular hydrogen into a hydropyrolysis reactor, b) removing carbon residue from the hydropyrolysis liquid; c) hydroconverting said liquid in a hydroconversion reactor and d) producing reformed hydrogen for use in a). CL2011003096A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US12/419,535 US20100251600A1 (en) 2009-04-07 2009-04-07 Hydropyrolysis of biomass for producing high quality liquid fuels
US12/685,352 US8492600B2 (en) 2009-04-07 2010-01-11 Hydropyrolysis of biomass for producing high quality fuels
PCT/US2010/001020 WO2010117437A1 (en) 2009-04-07 2010-04-05 Hydropyrolysis of biomass for producing high quality liquid fuels

Publications (1)

Publication Number Publication Date
CL2011003096A1 true CL2011003096A1 (en) 2012-07-20

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Family Applications (2)

Application Number Title Priority Date Filing Date
CL2011002488A CL2011002488A1 (en) 2009-04-07 2011-10-06 Process to produce liquid products from biomass that includes the stages of introduction of refeormed h2 and biomass into the reactor, hydro-pyrolysis, carburetion, hydroconversion, reforming and recycling of the liquid product.
CL2011003096A CL2011003096A1 (en) 2009-04-07 2011-12-06 Process for producing liquid biomass products comprising a) introducing biomass and reformed molecular hydrogen into a hydropyrolysis reactor, b) removing carbon residue from the hydropyrolysis liquid; c) hydroconverting said liquid in a hydroconversion reactor and d) producing reformed hydrogen for use in a).

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CL2011002488A CL2011002488A1 (en) 2009-04-07 2011-10-06 Process to produce liquid products from biomass that includes the stages of introduction of refeormed h2 and biomass into the reactor, hydro-pyrolysis, carburetion, hydroconversion, reforming and recycling of the liquid product.

Country Status (19)

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US (1) US8492600B2 (en)
EP (1) EP2417222B1 (en)
JP (2) JP5521031B2 (en)
CN (1) CN102459518B (en)
AU (1) AU2010235215B2 (en)
BR (1) BRPI1011219B1 (en)
CA (2) CA2912814C (en)
CL (2) CL2011002488A1 (en)
DK (1) DK2417222T3 (en)
EC (1) ECSP11011431A (en)
ES (1) ES2862929T3 (en)
MX (2) MX351040B (en)
MY (1) MY158044A (en)
NZ (2) NZ596155A (en)
PE (1) PE20120999A1 (en)
PL (1) PL2417222T3 (en)
RU (1) RU2539598C2 (en)
UA (1) UA116115C2 (en)
WO (1) WO2010117437A1 (en)

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US20100251600A1 (en) * 2009-04-07 2010-10-07 Gas Technology Institute Hydropyrolysis of biomass for producing high quality liquid fuels
US8063258B2 (en) * 2009-05-22 2011-11-22 Kior Inc. Catalytic hydropyrolysis of organophillic biomass
CA2781204C (en) * 2009-11-18 2018-05-01 G4 Insights Inc. Sorption enhanced methanation of biomass
US9040761B2 (en) 2010-02-16 2015-05-26 Kior, Inc. Co-processing of biomass and synthetic polymer based materials in a pyrolysis conversion process
WO2011138356A1 (en) * 2010-05-07 2011-11-10 Basf Se Process for preparing synthesis gas and at least one organic, liquid or liquefiable value product
US20110287503A1 (en) * 2010-05-20 2011-11-24 Uop Llc Methods for producing hydrocarbon products from algal biomass
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