CH270158A - Process for the production of a new amine derivative. - Google Patents
Process for the production of a new amine derivative.Info
- Publication number
- CH270158A CH270158A CH270158DA CH270158A CH 270158 A CH270158 A CH 270158A CH 270158D A CH270158D A CH 270158DA CH 270158 A CH270158 A CH 270158A
- Authority
- CH
- Switzerland
- Prior art keywords
- amine derivative
- new amine
- new
- disulfonic acid
- production
- Prior art date
Links
- 150000001412 amines Chemical class 0.000 title claims description 6
- 238000000034 method Methods 0.000 title claims description 4
- 238000004519 manufacturing process Methods 0.000 title description 2
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical class [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 4
- UOULCEYHQNCFFH-UHFFFAOYSA-M sodium;hydroxymethanesulfonate Chemical compound [Na+].OCS([O-])(=O)=O UOULCEYHQNCFFH-UHFFFAOYSA-M 0.000 claims description 4
- 239000007864 aqueous solution Substances 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 239000000243 solution Substances 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- 239000000758 substrate Substances 0.000 claims description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 1
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 1
- PJANXHGTPQOBST-VAWYXSNFSA-N Stilbene Natural products C=1C=CC=CC=1/C=C/C1=CC=CC=C1 PJANXHGTPQOBST-VAWYXSNFSA-N 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000008098 formaldehyde solution Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000004289 sodium hydrogen sulphite Substances 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- 235000021286 stilbenes Nutrition 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
- D06L4/60—Optical bleaching or brightening
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D251/00—Heterocyclic compounds containing 1,3,5-triazine rings
- C07D251/02—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings
- C07D251/12—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
- C07D251/26—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with only hetero atoms directly attached to ring carbon atoms
- C07D251/40—Nitrogen atoms
- C07D251/54—Three nitrogen atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
Verfahren zur Herstellung eines neuen Aminderivates. Es wurde gefunden, dass man zu einem neuen Aminderivat gelangt, wenn man das Ditiatriumsalz der Disulfonsäure der Formel
EMI0001.0006
mit Natriumformaldehyd-bisulfit behandelt.
Die Behandlung des Dinatriumsalzes der 4,4' -Bis - [ 4-aminobenzoy lamino ] - stilben-disul- fonsäure-(2,2') mit Natriumformaldehydbisul- fit kann beispielsweise in der Weise erfolgen, dass man die Komponenten in wässeriger Lö sung auf eine Temperatur von 95 bis 1000 C erhitzt.
Das neue Aminderivat ist ein helles Pul ver, das in Wasser löslich ist. Die wässerige Lösung fluoresziert im ultravioletten Licht bläulich. Dank ihrer Affinität zu verschieden sten Substraten kann die neue Verbindung zur Erhöhung des Weissgehaltes von unge färbten Materialien und zur Verbesserung der Reinheit der Färbung von gefärbten Materia lien verwendet werden.
<I>Beispiel;</I> Man vermischt 520 Gewichtsteile Natrium- bisulfitlösung, 40 /oig, mit 162 Gewichtsteilen Formaldehy dlösung, 37 o/oig. Dazu gibt man 1 Gewichtsteil Natriumcarbonat und 60 Ge wichtsteile Dinatriumsalz der 4,4'-Bis- [4- a.minobenzoylamino] - stilben - disulfonsäure- (2,2'). Man kocht 2 bis 4 Stunden rückflie ssend,
wobei vollständige Lösung eintritt. Hierauf lässt man erkalten, versetzt zur voll ständigen Abscheidung mit Natriumchlorid, filtriert, wäscht mit wässeriger Nat.riumehlo- ridlösung und trocknet. Man erhält ein helles Pulver, das in Was ser löslich ist.
Process for the production of a new amine derivative. It has been found that a new amine derivative is obtained if one uses the disodium salt of the disulfonic acid of the formula
EMI0001.0006
treated with sodium formaldehyde bisulfite.
The treatment of the disodium salt of 4,4'-bis - [4-aminobenzoy lamino] - stilbene-disulphonic acid- (2,2 ') with sodium formaldehyde bisulfite can for example be carried out in such a way that the components are in aqueous solution heated to a temperature of 95 to 1000 C.
The new amine derivative is a light-colored powder that is soluble in water. The aqueous solution fluoresces bluish in ultraviolet light. Thanks to its affinity for a wide variety of substrates, the new compound can be used to increase the whiteness of uncolored materials and to improve the purity of the coloration of colored materia lien.
<I> Example; </I> 520 parts by weight of sodium bisulphite solution, 40%, are mixed with 162 parts by weight of formaldehyde solution, 37%. To this are added 1 part by weight of sodium carbonate and 60 parts by weight of the disodium salt of 4,4'-bis [4- a.minobenzoylamino] - stilbene - disulfonic acid- (2,2 '). It is refluxed for 2 to 4 hours,
complete dissolution occurs. It is then allowed to cool, sodium chloride is added for complete separation, filtered, washed with aqueous sodium chloride solution and dried. A pale powder is obtained which is soluble in what water.
Claims (1)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH270158T | 1947-12-12 | ||
| CH265816T | 1948-09-29 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CH270158A true CH270158A (en) | 1950-08-15 |
Family
ID=25730826
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH270158D CH270158A (en) | 1947-12-12 | 1947-12-12 | Process for the production of a new amine derivative. |
Country Status (1)
| Country | Link |
|---|---|
| CH (1) | CH270158A (en) |
-
1947
- 1947-12-12 CH CH270158D patent/CH270158A/en unknown
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