CH228135A - Process for the production of a vat dye. - Google Patents

Process for the production of a vat dye.

Info

Publication number
CH228135A
CH228135A CH228135DA CH228135A CH 228135 A CH228135 A CH 228135A CH 228135D A CH228135D A CH 228135DA CH 228135 A CH228135 A CH 228135A
Authority
CH
Switzerland
Prior art keywords
orange
production
vat
dye
brown
Prior art date
Application number
Other languages
German (de)
Inventor
Aktiengesellsc Farbenindustrie
Original Assignee
Ig Farbenindustrie Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ig Farbenindustrie Ag filed Critical Ig Farbenindustrie Ag
Publication of CH228135A publication Critical patent/CH228135A/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B5/00Dyes with an anthracene nucleus condensed with one or more heterocyclic rings with or without carbocyclic rings
    • C09B5/24Dyes with an anthracene nucleus condensed with one or more heterocyclic rings with or without carbocyclic rings the heterocyclic rings being only condensed with an anthraquinone nucleus in 1-2 or 2-3 position
    • C09B5/26Carbazoles of the anthracene series

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Coloring (AREA)

Description

  

  <B>Zusatzpatent</B> zum Hauptpatent Nr. 221928.    Verfahren zur Herstellung eines     Nüpenfarbstoffes.       Gegenstand dieses     Patentes    ist ein Ver  fahren zur Herstellung eines neuen     Küpen-          farbatoffes    der     Anthrachinonreihe.    Das Ver  fahren ist dadurch gekennzeichnet, dass man  das     Carbazol    aus 1-     Amino    - 5 - (p -     Chlor-          phenyl)-aminoanthrachinon    der nachstehen  den     Formel     
EMI0001.0011     
    mit     o-Chlorbenzoylchlorid    umsetzt.  



  Der Farbstoff löst sich in konzentrierter  Schwefelsäure mit     tiefblauar,    in     heissem          Pyridin    mit     orangegelber    Farbe. Er färbt    Baumwolle aus seiner klaren braunorangen       Küpe    in klaren gelbbraunen Tönen.  



  <I>Beispiel:</I>  Teile.     3--Chlor-3'-amino-7,8-phthaloyl-          carbazol    der     nachstehenden    Formel  
EMI0001.0021     
    werden in 60 Teilen Nitrobenzol bei 150  ver  rührt und in etwa 20     Minuten    eine Lösung  von 3 Teilen     -o-Chlorbenzoylchlorid    in 10  Teilen Nitrobenzol eingerührt. Man     steigert     die Temperatur nach     1/2        Stunde    kurz auf 180       und lässt erkalten. Man erhält nach dem Ab  saugen, Auswaschen und Trocknen 6,3 Teile  eines gut     kristallisierten    Farbstoffes.

   In     kon-          zentrierter    Schwefelsäure löst er sich mit tief  blauer Farbe. Aus dieser Lösung fallen mit       Wasser        orangegelbe    Flocken.  



       In        Pyridin        löst        er        sich        ebenfalls     Er     liefert    mit Natronlauge und     Hydro-          sulfiteine    braunorange     Küpe,    aus der Baum  wolle in klaren und echten gelbbraunen  Tönen     gefärbt    wird.



  <B> Additional patent </B> to main patent no. 221928. Process for the production of a pebble dye. The subject of this patent is a process for the production of a new vat colorant of the anthraquinone series. The process is characterized in that the carbazole from 1-amino-5 - (p-chlorophenyl) -aminoanthraquinone of the formula below
EMI0001.0011
    reacts with o-chlorobenzoyl chloride.



  The dye dissolves in concentrated sulfuric acid with a deep blue color, in hot pyridine with an orange-yellow color. He dyes cotton from his clear brown-orange vat in clear yellow-brown tones.



  <I> Example: </I> parts. 3 - chloro-3'-amino-7,8-phthaloyl-carbazole of the formula below
EMI0001.0021
    are stirred in 60 parts of nitrobenzene at 150 and stirred in a solution of 3 parts -o-chlorobenzoyl chloride in 10 parts of nitrobenzene in about 20 minutes. The temperature is raised briefly to 180 after 1/2 hour and allowed to cool. After sucking off, washing out and drying, 6.3 parts of a well-crystallized dye are obtained.

   In concentrated sulfuric acid it dissolves with a deep blue color. Orange-yellow flakes fall from this solution with water.



       It also dissolves in pyridine. With caustic soda and hydrosulfite, it delivers a brown-orange vat from which cotton is dyed in clear, genuine yellow-brown tones.

 

Claims (1)

PATENTANSPRUCH: Verfahren zur Herstellung eines Küpen- farbstoffes der Anthrachinonreihe, dadurch gekennzeichnet, dass man das Carbazol aus 1-Amino- 5 - (p - Chlor-phenyl) -aminoanthra- chinon der Formel EMI0002.0028 mit o-Chlorbenzoylchlorid umsetzt. Der Farbstoff löst sich in konzentrierter Schwefelsäure mit tiefblauer, in heissem Pyridin mit orangegelber Farbe. PATENT CLAIM: Process for producing a vat dye of the anthraquinone series, characterized in that the carbazole is made from 1-amino-5 - (p-chlorophenyl) -aminoanthraquinone of the formula EMI0002.0028 reacts with o-chlorobenzoyl chloride. The dye dissolves in concentrated sulfuric acid with a deep blue, in hot pyridine with an orange-yellow color. Er färbt Baumwolle aus einer klaren braunorangen Küpe in klaren gelbbraunen Tönen. He dyes cotton from a clear brown-orange vat in clear yellow-brown tones.
CH228135D 1938-10-06 1939-10-03 Process for the production of a vat dye. CH228135A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE228135X 1938-10-06
CH221928T 1939-10-03

Publications (1)

Publication Number Publication Date
CH228135A true CH228135A (en) 1943-07-31

Family

ID=25726572

Family Applications (1)

Application Number Title Priority Date Filing Date
CH228135D CH228135A (en) 1938-10-06 1939-10-03 Process for the production of a vat dye.

Country Status (1)

Country Link
CH (1) CH228135A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3335150A (en) * 1962-08-07 1967-08-08 Hoechst Ag Certain 1, 2-phthalyl-carbazole pigments
US3420843A (en) * 1962-08-07 1969-01-07 Hoechst Ag Novel 1,2-phthalylcarbazole pigment dyestuffs

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3335150A (en) * 1962-08-07 1967-08-08 Hoechst Ag Certain 1, 2-phthalyl-carbazole pigments
US3420843A (en) * 1962-08-07 1969-01-07 Hoechst Ag Novel 1,2-phthalylcarbazole pigment dyestuffs

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