CH210987A - Process for the preparation of a mixture of acylated ammonium diphenylmethane compounds. - Google Patents
Process for the preparation of a mixture of acylated ammonium diphenylmethane compounds.Info
- Publication number
- CH210987A CH210987A CH210987DA CH210987A CH 210987 A CH210987 A CH 210987A CH 210987D A CH210987D A CH 210987DA CH 210987 A CH210987 A CH 210987A
- Authority
- CH
- Switzerland
- Prior art keywords
- mixture
- ammonium
- preparation
- acylated
- diphenylmethane
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims description 14
- VCUBJUKTIHLWQQ-UHFFFAOYSA-N azane;benzylbenzene Chemical class N.C=1C=CC=CC=1CC1=CC=CC=C1 VCUBJUKTIHLWQQ-UHFFFAOYSA-N 0.000 title claims description 4
- 238000000034 method Methods 0.000 title claims description 4
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 5
- 239000000194 fatty acid Substances 0.000 claims description 5
- 229930195729 fatty acid Natural products 0.000 claims description 5
- 150000004665 fatty acids Chemical class 0.000 claims description 4
- 150000003839 salts Chemical group 0.000 claims description 4
- 150000003841 chloride salts Chemical class 0.000 claims description 3
- VAYGXNSJCAHWJZ-UHFFFAOYSA-N dimethyl sulfate Chemical compound COS(=O)(=O)OC VAYGXNSJCAHWJZ-UHFFFAOYSA-N 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- 229920000742 Cotton Polymers 0.000 claims description 2
- 229920002678 cellulose Polymers 0.000 claims description 2
- 239000001913 cellulose Substances 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- 238000005187 foaming Methods 0.000 claims description 2
- 239000004753 textile Substances 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims 1
- CZZYITDELCSZES-UHFFFAOYSA-N diphenylmethane Chemical compound C=1C=CC=CC=1CC1=CC=CC=C1 CZZYITDELCSZES-UHFFFAOYSA-N 0.000 claims 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03B—APPARATUS OR ARRANGEMENTS FOR TAKING PHOTOGRAPHS OR FOR PROJECTING OR VIEWING THEM; APPARATUS OR ARRANGEMENTS EMPLOYING ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ACCESSORIES THEREFOR
- G03B1/00—Film strip handling
- G03B1/02—Moving film strip by pull on end thereof
- G03B1/04—Pull exerted by take-up spool
- G03B1/12—Pull exerted by take-up spool rotated by motor, e.g. spring
-
- G—PHYSICS
- G04—HOROLOGY
- G04B—MECHANICALLY-DRIVEN CLOCKS OR WATCHES; MECHANICAL PARTS OF CLOCKS OR WATCHES IN GENERAL; TIME PIECES USING THE POSITION OF THE SUN, MOON OR STARS
- G04B1/00—Driving mechanisms
- G04B1/10—Driving mechanisms with mainspring
- G04B1/18—Constructions for connecting the ends of the mainsprings with the barrel or the arbor
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Polyurethanes Or Polyureas (AREA)
- Cosmetics (AREA)
Description
Verfahren zur Darstellung eines Gemisches aeylierter Ammoniumdiphenylmethanverbindungen. Gegenstand des vorliegenden Patentes ist ein Verfahren zur Darstellung eines Ge- misches acylierter Ammoniumdiphenylme- thanverbindungen der Formel
EMI0001.0008
worin -CO .
R die Reste der in einem technischen Gemisch enthaltenen Fettsäuren CH3(CH2)"-COOH bis CH3(CHZ)"-COOH bedeutet, dadurch gekennzeichnet, dass man 4-Dimethylamino-4'- (N-methyl-N-oxäthyl- amino)-diphenylmethan mit dem Gemisch der Chloride der genannten Fettsäuren umsetzt und das so erhaltene Estergemisch mit Di- methyIsulfat in das bisquaternäre Salz über führt.
Das Gemisch neuerer Verbindungen, eine helle, weiche, kristallinische Masse, ist in Wasser gut löslich und gibt schäumende Lö sungen mit ausgesprochen kapillaraktiven Ei genschaften.
Es kann für verschiedene Zwecke der Textilindustrie Verwendung fin den, insbesondere als Weichmacher für Baumwolle und umgefällte Cellulose. , <I>Beispiel:</I> 100 Teile 4-Dimethyla-mino-4'-(N-methyl- N - oxäthyl - amino) - diphenylmethan (gp, = 260 bis 265')
werden in. 600 Teilen Ben zol gelöst und nach Zugabe von 25 Teilen Pyridin mit 105 Teilen der Chloride aus einem technischen Gemisch der Fettsäuren CH3(CH2)14-COOH bis CH3(CH2)"-COOH verestert. Die filtrierte Lösung wird ge waschen, getrocknet und im Vakuum konzen triert. Das so erhaltene Estergemisch gibt beim Verrühren und kurzen Erwärmen auf 90 mit 88 Teilen Dimethylsulfat das bis quaternäre Salz in Form einer hellen, wei chen, kristallinischen, in Wasser gut lös lichen blasse.
Process for the preparation of a mixture of aeylated ammonium diphenylmethane compounds. The present patent relates to a process for the preparation of a mixture of acylated ammonium diphenylmethane compounds of the formula
EMI0001.0008
wherein -CO.
R denotes the residues of the fatty acids CH3 (CH2) "- COOH to CH3 (CHZ)" - COOH contained in a technical mixture, characterized in that 4-dimethylamino-4'- (N-methyl-N-oxäthylamino) -diphenylmethane with the mixture of chlorides of the fatty acids mentioned and converts the ester mixture thus obtained with dimethyl sulfate into the bisquaternary salt.
The mixture of newer compounds, a light, soft, crystalline mass, is readily soluble in water and gives foaming solutions with extremely capillary-active properties.
It can be used for various purposes in the textile industry, in particular as a softener for cotton and reprecipitated cellulose. , <I> Example: </I> 100 parts of 4-dimethyla-mino-4 '- (N-methyl- N - oxäthyl - amino) - diphenylmethane (gp, = 260 to 265')
are dissolved in. 600 parts of benzene and, after addition of 25 parts of pyridine, esterified with 105 parts of the chlorides from a technical mixture of the fatty acids CH3 (CH2) 14-COOH to CH3 (CH2) "- COOH. The filtered solution is washed, The ester mixture obtained in this way, when stirred and briefly heated to 90 with 88 parts of dimethyl sulfate, gives the quaternary salt in the form of a light, soft, crystalline, pale water-soluble salt.
Claims (1)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH208532T | 1938-09-01 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CH210987A true CH210987A (en) | 1940-08-15 |
Family
ID=4446108
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH208532D CH208532A (en) | 1938-09-01 | 1938-09-01 | Process for the preparation of an acylated ammonium diarylmethane compound. |
| CH210987D CH210987A (en) | 1938-09-01 | 1938-09-01 | Process for the preparation of a mixture of acylated ammonium diphenylmethane compounds. |
| CH210986D CH210986A (en) | 1938-09-01 | 1938-09-01 | Process for the preparation of a mixture of acylated ammonium diphenylmethane compounds. |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH208532D CH208532A (en) | 1938-09-01 | 1938-09-01 | Process for the preparation of an acylated ammonium diarylmethane compound. |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH210986D CH210986A (en) | 1938-09-01 | 1938-09-01 | Process for the preparation of a mixture of acylated ammonium diphenylmethane compounds. |
Country Status (3)
| Country | Link |
|---|---|
| CH (3) | CH208532A (en) |
| FR (1) | FR859698A (en) |
| GB (1) | GB532439A (en) |
-
1938
- 1938-09-01 CH CH208532D patent/CH208532A/en unknown
- 1938-09-01 CH CH210987D patent/CH210987A/en unknown
- 1938-09-01 CH CH210986D patent/CH210986A/en unknown
-
1939
- 1939-08-31 FR FR859698D patent/FR859698A/en not_active Expired
- 1939-08-31 GB GB24990/39A patent/GB532439A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| FR859698A (en) | 1940-12-24 |
| CH208532A (en) | 1940-02-15 |
| CH210986A (en) | 1940-08-15 |
| GB532439A (en) | 1941-01-23 |
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