CH193253A - Process for the production of an acidic wool dye. - Google Patents
Process for the production of an acidic wool dye.Info
- Publication number
- CH193253A CH193253A CH193253DA CH193253A CH 193253 A CH193253 A CH 193253A CH 193253D A CH193253D A CH 193253DA CH 193253 A CH193253 A CH 193253A
- Authority
- CH
- Switzerland
- Prior art keywords
- dye
- production
- acidic
- wool
- wool dye
- Prior art date
Links
- 210000002268 wool Anatomy 0.000 title claims description 7
- 230000002378 acidificating effect Effects 0.000 title claims description 4
- 238000000034 method Methods 0.000 title claims description 4
- 238000004519 manufacturing process Methods 0.000 title claims description 3
- 239000000975 dye Substances 0.000 claims description 12
- 239000003513 alkali Substances 0.000 claims description 3
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 claims description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 238000006277 sulfonation reaction Methods 0.000 description 1
- 238000010626 work up procedure Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B17/00—Azine dyes
- C09B17/04—Azine dyes of the naphthalene series
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
Description
<B>Zusatzpatent</B> zum Hauptpatent Nr. 189649. Verfahren zur Herstellung eines sauren Wollfarbstoffes. Gegenstand vorliegenden Patentes ist ein Verfahren zur Herstellung eines sauren Wollfarbstoffes, das dadurch gekennzeichnet ist, dass man den Farbstoff der Formel:
EMI0001.0002
mit einem sulfonierenden Mittel behandelt.
Der neue Farbstoff, der zwei Sulfogruppen im Molekül enthält, löst sieh in konzentrier ter Schwefelsäure grün, in Wasser blau und färbt Wolle in klaren, grünstichig blauen Tönen von guter Licht- und Alkaliechtheit und gutem Egalisierungsvermögen. Beispiel: Zwecks Sulfonierung wird der Farbstoff der Formel:
EMI0001.0009
mit der fünffachen Menge 32%igen Oleums mehrere Stunden auf<B>80'</B> erhitzt, bis sich eine Probe in verdünnter Natriumacetat- lösung ohne Rückstand löst.
Die Aufarbei tung und Überführung in das Natriumsalz erfolgt in üblicher Weise; der Farbstoff ent hält zwei Sulfogruppen im Molekül. Er löst sich in konzentrierter Schwefelsäure grün, in Wasser blau und färbt Wolle in klaren, grünstichig blauen Tönen von guter Licht- und Alkaliechtheit und gutem Egalisierungs- vermögen.
<B> Additional patent </B> to main patent No. 189649. Process for the production of an acidic wool dye. The present patent relates to a process for the preparation of an acidic wool dye, which is characterized in that the dye of the formula:
EMI0001.0002
treated with a sulfonating agent.
The new dye, which contains two sulfo groups in the molecule, dissolves green in concentrated sulfuric acid, blue in water and dyes wool in clear, greenish blue shades of good lightfastness and alkali fastness and good leveling power. Example: For sulfonation, the dye of the formula:
EMI0001.0009
heated to <B> 80 '</B> for several hours with five times the amount of 32% oleum until a sample dissolves in dilute sodium acetate solution without residue.
The work-up and conversion into the sodium salt takes place in the usual way; the dye contains two sulfo groups in the molecule. It dissolves green in concentrated sulfuric acid, blue in water and dyes wool in clear, greenish blue shades of good lightfastness and alkali fastness and good leveling properties.
Claims (1)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH193253T | 1936-04-11 | ||
| CH189649T | 1936-04-11 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CH193253A true CH193253A (en) | 1937-09-30 |
Family
ID=25721833
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH193253D CH193253A (en) | 1936-04-11 | 1936-04-11 | Process for the production of an acidic wool dye. |
Country Status (1)
| Country | Link |
|---|---|
| CH (1) | CH193253A (en) |
-
1936
- 1936-04-11 CH CH193253D patent/CH193253A/en unknown
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