CH134000A - Process for the production of a new metal-containing azo dye. - Google Patents

Process for the production of a new metal-containing azo dye.

Info

Publication number
CH134000A
CH134000A CH134000DA CH134000A CH 134000 A CH134000 A CH 134000A CH 134000D A CH134000D A CH 134000DA CH 134000 A CH134000 A CH 134000A
Authority
CH
Switzerland
Prior art keywords
blue
dye
production
containing azo
azo dye
Prior art date
Application number
Other languages
German (de)
Inventor
Gesellschaft Fuer Chemis Basel
Original Assignee
Chem Ind Basel
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chem Ind Basel filed Critical Chem Ind Basel
Publication of CH134000A publication Critical patent/CH134000A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B45/00—Complex metal compounds of azo dyes
    • C09B45/02—Preparation from dyes containing in o-position a hydroxy group and in o'-position hydroxy, alkoxy, carboxyl, amino or keto groups
    • C09B45/14—Monoazo compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B45/00—Complex metal compounds of azo dyes
    • C09B45/02—Preparation from dyes containing in o-position a hydroxy group and in o'-position hydroxy, alkoxy, carboxyl, amino or keto groups
    • C09B45/14—Monoazo compounds
    • C09B45/16—Monoazo compounds containing chromium
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B45/00—Complex metal compounds of azo dyes
    • C09B45/02—Preparation from dyes containing in o-position a hydroxy group and in o'-position hydroxy, alkoxy, carboxyl, amino or keto groups
    • C09B45/14—Monoazo compounds
    • C09B45/18—Monoazo compounds containing copper

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Coloring (AREA)

Description

  

  Verfahren zur Herstellung eines neuen metallhaltigen     Azofarbstoffes.       Es wurde gefunden, dass man einen neuen,  metallhaltigen     Azofarbstoff    erhält, wenn wan  den     Farbstoff    aus dianotiertem     5-Nitro-2          amiiio-l-phenol    und     2-p-Tolylamino-5-oxy-          naphthalin-7-sulfosäure    zunächst mit einem  Sechstel der zur vollständigen     Metallisierung     notwendigen Menge     eines    kupferabgebenden  Mittels behandelt und hierauf bis zur Ab  sättigung der     metallisierbaren    Gruppen mit  chromabgebenden Mitteln weiter behandelt.  



  Der neue     Farbstoff    ist trocken ein     bron-          zierendes    Pulver, welches sich in Wasser,  Soda- oder     Laugelösung    blau- und in kon  zentrierter Schwefelsäure blaurot löst. Baum  wolle wird aus neutralem oder     sodaalkali-          schem        Glaubersalzbad    in blauen Tönen ge  färbt.  



  <I>Beispiel:</I>  Der aus 15,4 Teilen dianotiertem     5-Nitro-          2-amino-l-phenol    und 31,5 Teilen     2-p-Tolyl-          amino-5    -     oxynaphthalin    - 7 -     sulfosäure    herge  stellte Farbstoff wird in 750 Teilen heissem    Wasser gelöst und bei Siedetemperatur mit  4,18 Teilen kristallisiertem Kupfersulfat in  Form einer konzentrierten Lösung versetzt.

    Man erwärmt weiterhin zum Kochen unter  gutem Rühren und - setzt dann nach einer  Viertelstunde 15,6 Teile     Crs0s    als 5,2     o/oige          Fluorchromlösung    zu und erhitzt noch 36  Stunden am     Rückflusskühler.    Die ursprüng  lich blaurote Lösung hat nach dieser Zeit in       Violettblau    umgeschlagen. Durch Zugabe von  200 Teilen Kochsalz kann man den Farb  stoff quantitativ abscheiden.



  Process for the production of a new metal-containing azo dye. It has been found that a new, metal-containing azo dye is obtained if the dye from dianotated 5-nitro-2 amiiio-1-phenol and 2-p-tolylamino-5-oxynaphthalene-7-sulfonic acid is initially mixed with one sixth of the Treated the amount of a copper-releasing agent necessary for complete metallization and then further treated with chromium-releasing agents until the metallizable groups are saturated.



  The new dye is a dry bronzing powder that dissolves blue in water, soda or alkali solution and bluish red in concentrated sulfuric acid. Cotton is dyed in blue tones from a neutral or soda-alkaline Glauber's salt bath.



  <I> Example: </I> The dye produced from 15.4 parts of dianotized 5-nitro-2-amino-1-phenol and 31.5 parts of 2-p-tolylamino-5-oxynaphthalene-7-sulfonic acid is dissolved in 750 parts of hot water, and 4.18 parts of crystallized copper sulfate in the form of a concentrated solution are added at the boiling point.

    The mixture is heated further to the boil with thorough stirring and, after a quarter of an hour, 15.6 parts of CrsOs as 5.2% fluorochromium solution are added and the mixture is heated for a further 36 hours on the reflux condenser. The originally blue-red solution has turned violet-blue after this time. The dye can be separated quantitatively by adding 200 parts of table salt.

Claims (1)

PATENTANSPRUCH: Verfahren zur Herstellung eines metall. haltigen Azofarbstoffes, dadurch gekennzeich. net, dass man den Farbstoff aus dianotiertem 5-Nitro-2-amino-l-phenol und 2-p-Tolylamino. 5-oxynaphthalin-7-sulfosäure- zunächst mit einem Sechstel der zur vollständigen Metal. lisierung notwendigen Menge eines kupfer. abgebenden Mittels behandelt und hieraus bis zur Absättigung , PATENT CLAIM: Process for the production of a metal. containing azo dye, marked thereby. net that you can get the dye from dianotized 5-nitro-2-amino-1-phenol and 2-p-tolylamino. 5-oxynaphthalene-7-sulfonic acid- initially with one sixth of that for complete metal. lization necessary amount of a copper. treated agent and from this until saturation, der metallisierbarer Gruppen mit chromabgebenden Mitteln weiter behandelt. Der neue Farbstoff ist trocken ein bron- zierendes Pulver, welches sich' in Wasser, Soda- oder Laugelösung blau und in kon zentrierter Schwefelsäure blaurot löst. Baum- wolle wird aus ,\neutralem oder soloalkali schem Glaubersalzba, in blauen Tönen ge färbt. the metallizable groups treated with chromium donating agents. The new dye is a dry bronzing powder, which dissolves blue in water, soda or alkali solution and blue-red in concentrated sulfuric acid. Cotton is dyed in blue tones from neutral or solo alkaline Glauber's saltba.
CH134000D 1927-09-10 1927-09-10 Process for the production of a new metal-containing azo dye. CH134000A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CH131098T 1927-09-10
CH134000T 1927-09-10

Publications (1)

Publication Number Publication Date
CH134000A true CH134000A (en) 1929-06-30

Family

ID=25711556

Family Applications (1)

Application Number Title Priority Date Filing Date
CH134000D CH134000A (en) 1927-09-10 1927-09-10 Process for the production of a new metal-containing azo dye.

Country Status (1)

Country Link
CH (1) CH134000A (en)

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