CH123690A - Process for the preparation of the disodium salt of 4-iminomethylene sulphonic acid-2-auromercaptobenzene-1-sulphonic acid. - Google Patents
Process for the preparation of the disodium salt of 4-iminomethylene sulphonic acid-2-auromercaptobenzene-1-sulphonic acid.Info
- Publication number
- CH123690A CH123690A CH123690DA CH123690A CH 123690 A CH123690 A CH 123690A CH 123690D A CH123690D A CH 123690DA CH 123690 A CH123690 A CH 123690A
- Authority
- CH
- Switzerland
- Prior art keywords
- sulphonic acid
- iminomethylene
- preparation
- auromercaptobenzene
- disodium salt
- Prior art date
Links
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical class [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 title claims description 4
- 238000000034 method Methods 0.000 title claims description 3
- 238000002360 preparation method Methods 0.000 title claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 2
- 239000010931 gold Substances 0.000 claims description 2
- 229910052737 gold Inorganic materials 0.000 claims description 2
- 159000000000 sodium salts Chemical class 0.000 claims description 2
- 230000001225 therapeutic effect Effects 0.000 claims description 2
- DITZYEMOCRSZII-UHFFFAOYSA-N formaldehyde;sodium;sulfurous acid Chemical compound [Na].O=C.OS(O)=O DITZYEMOCRSZII-UHFFFAOYSA-N 0.000 claims 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- DETXZQGDWUJKMO-UHFFFAOYSA-N alpha-hydroxymethanesulfonic acid Natural products OCS(O)(=O)=O DETXZQGDWUJKMO-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- -1 formaldehyde bisulfite compound Chemical class 0.000 description 1
- WBIPGYLOZIJNQV-UHFFFAOYSA-N formaldehyde sulfuric acid Chemical compound C=O.C=O.OS(O)(=O)=O WBIPGYLOZIJNQV-UHFFFAOYSA-N 0.000 description 1
- SXWRHBFZYFLRLR-UHFFFAOYSA-N formaldehyde;sodium;sulfuric acid Chemical compound [Na].O=C.OS(O)(=O)=O SXWRHBFZYFLRLR-UHFFFAOYSA-N 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
Landscapes
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
Verfahren zur Darstellung des Dinatriumsalzes von 4-iminomethylenschwefliger Säur e-2-aur omer captobenzol-l-sulfosäur e.
Das im Hauptpatent Nr. 120651 be schriebene Dinatriumsalz'der 4-iminomethyleri- schwefiigen Säure-2-auromer,captobenzol-l- sulfosäure kann, wie gefunden wurde, auch in der Weise erhalten werden, dass man formaldehydschwefligsaures Natrium auf das Natriumsalz der 4-Amino-2-auromercapto- berizol-l-sulfosäure einwirken lässt.
<I>Beispiel</I> Man löst 42,3 Teile 4-arnino-2-aurorner- captobenzol-l-solfosauresNatrium in 200 Teilen Wasser, fügt 13 Teile formaldehydschweflig- saures Natrium zu und erhitzt die Lösung unter Rühren zum Sieden. Man lässt erkalten und fällt die gebildete Formaldehydbisulfit- verbindung mit Alkohol-. Die Verbindung ist hellgelb, in Wasser leicht löslich und hat einen Goldgehalt von 36 %; sie zeichnet sich durch hervorragende therapeutische Eigen schaften aus.
Process for the preparation of the disodium salt of 4-iminomethylene sulfuric acid e-2-aur omer captobenzene-l-sulfonic acid e.
The disodium salt of the 4-iminomethylsulfuric acid-2-auromer, captobenzene-l-sulfonic acid, described in the main patent No. 120651 can, as has been found, also be obtained by adding sodium formaldehyde-sulfuric acid to the sodium salt of the 4- Amino-2-auromercaptoberizole-l-sulfonic acid can act.
<I> Example </I> Dissolve 42.3 parts of 4-arnino-2-aurornercaptobenzene-l-solfosauresNatrium in 200 parts of water, add 13 parts of formaldehyde-sulfuric acid and heat the solution to boiling with stirring. It is allowed to cool and the formaldehyde bisulfite compound formed is precipitated with alcohol. The compound is light yellow, easily soluble in water and has a gold content of 36%; it is characterized by excellent therapeutic properties.
Claims (1)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE123690X | 1925-12-12 | ||
| CH120651T | 1926-11-15 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CH123690A true CH123690A (en) | 1927-12-01 |
Family
ID=25709528
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH123690D CH123690A (en) | 1925-12-12 | 1926-11-15 | Process for the preparation of the disodium salt of 4-iminomethylene sulphonic acid-2-auromercaptobenzene-1-sulphonic acid. |
Country Status (1)
| Country | Link |
|---|---|
| CH (1) | CH123690A (en) |
-
1926
- 1926-11-15 CH CH123690D patent/CH123690A/en unknown
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