CA2836628C - Process for liquefaction of natural gas - Google Patents

Process for liquefaction of natural gas Download PDF

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Publication number
CA2836628C
CA2836628C CA2836628A CA2836628A CA2836628C CA 2836628 C CA2836628 C CA 2836628C CA 2836628 A CA2836628 A CA 2836628A CA 2836628 A CA2836628 A CA 2836628A CA 2836628 C CA2836628 C CA 2836628C
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heat exchanger
gas
expander
natural gas
process
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CA2836628A
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CA2836628A1 (en
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Anthony Dwight Maunder
Geoffrey Frederick Skinner
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Gasconsult Ltd
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Gasconsult Ltd
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Priority to GB1110096.3A priority patent/GB2486036B/en
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Priority to PCT/GB2012/000502 priority patent/WO2012172281A2/en
Publication of CA2836628A1 publication Critical patent/CA2836628A1/en
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/0002Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the fluid to be liquefied
    • F25J1/0022Hydrocarbons, e.g. natural gas
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/003Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
    • F25J1/0032Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration"
    • F25J1/0035Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by gas expansion with extraction of work
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/003Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
    • F25J1/0032Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration"
    • F25J1/0035Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by gas expansion with extraction of work
    • F25J1/0037Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by gas expansion with extraction of work of a return stream
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/003Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
    • F25J1/0032Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration"
    • F25J1/004Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by flash gas recovery
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0201Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using only internal refrigeration means, i.e. without external refrigeration
    • F25J1/0202Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using only internal refrigeration means, i.e. without external refrigeration in a quasi-closed internal refrigeration loop
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0225Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using other external refrigeration means not provided before, e.g. heat driven absorption chillers
    • F25J1/0227Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using other external refrigeration means not provided before, e.g. heat driven absorption chillers within a refrigeration cascade
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0228Coupling of the liquefaction unit to other units or processes, so-called integrated processes
    • F25J1/0229Integration with a unit for using hydrocarbons, e.g. consuming hydrocarbons as feed stock
    • F25J1/023Integration with a unit for using hydrocarbons, e.g. consuming hydrocarbons as feed stock for the combustion as fuels, i.e. integration with the fuel gas system
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0228Coupling of the liquefaction unit to other units or processes, so-called integrated processes
    • F25J1/0235Heat exchange integration
    • F25J1/0242Waste heat recovery, e.g. from heat of compression
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0243Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
    • F25J1/0244Operation; Control and regulation; Instrumentation
    • F25J1/0254Operation; Control and regulation; Instrumentation controlling particular process parameter, e.g. pressure, temperature
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0243Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
    • F25J1/0279Compression of refrigerant or internal recycle fluid, e.g. kind of compressor, accumulator, suction drum etc.
    • F25J1/0281Compression of refrigerant or internal recycle fluid, e.g. kind of compressor, accumulator, suction drum etc. characterised by the type of prime driver, e.g. hot gas expander
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0243Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
    • F25J1/0279Compression of refrigerant or internal recycle fluid, e.g. kind of compressor, accumulator, suction drum etc.
    • F25J1/0281Compression of refrigerant or internal recycle fluid, e.g. kind of compressor, accumulator, suction drum etc. characterised by the type of prime driver, e.g. hot gas expander
    • F25J1/0283Gas turbine as the prime mechanical driver
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2220/00Processes or apparatus involving steps for the removal of impurities
    • F25J2220/60Separating impurities from natural gas, e.g. mercury, cyclic hydrocarbons
    • F25J2220/62Separating low boiling components, e.g. He, H2, N2, Air
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2220/00Processes or apparatus involving steps for the removal of impurities
    • F25J2220/60Separating impurities from natural gas, e.g. mercury, cyclic hydrocarbons
    • F25J2220/64Separating heavy hydrocarbons, e.g. NGL, LPG, C4+ hydrocarbons or heavy condensates in general
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2240/00Processes or apparatus involving steps for expanding of process streams
    • F25J2240/80Hot exhaust gas turbine combustion engine
    • F25J2240/82Hot exhaust gas turbine combustion engine with waste heat recovery, e.g. in a combined cycle, i.e. for generating steam used in a Rankine cycle
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2270/00Refrigeration techniques used
    • F25J2270/04Internal refrigeration with work-producing gas expansion loop
    • F25J2270/06Internal refrigeration with work-producing gas expansion loop with multiple gas expansion loops
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2270/00Refrigeration techniques used
    • F25J2270/90External refrigeration, e.g. conventional closed-loop mechanical refrigeration unit using Freon or NH3, unspecified external refrigeration
    • F25J2270/906External refrigeration, e.g. conventional closed-loop mechanical refrigeration unit using Freon or NH3, unspecified external refrigeration by heat driven absorption chillers

Abstract

A process comprising: cooling natural gas with a heat exchanger and a first expander. The heat exchanger cools the feed natural gas to temperature higher than the outlet temperature of the expander, reheating the expander outlet stream in a first cold passage of the heat exchanger to slightly below the temperature of the feed natural gas to the heat exchanger, passing the cold outlet stream from the heat exchanger into a second expander wherein it is partly liquefied, separating the outlet stream of second expander into liquid and vapour fractions, collecting the liquid fraction for use as LNG product, reheating the vapour fraction in a second cold side passage of the heat exchanger to substantially the same temperature as the temperature of the feed natural gas to the heat exchanger, recycling the reheated vapour fraction partly as feed to the first expander and partly as feed to the heat exchanger.

Description

Process for Liquefaction of Natural Gas Field of the Invention 5The present invention relates to a method for liquefying methane-rich gas and, more particularly but not exclusively, relates to a method for producing liquefied natural gas (LNG).
Background to the Invention 10Liquefaction of natural gas can practically be achieved by:
- evaporation of liquid refrigerants - work expansion of gases in expansion machines (expanders).
Evaporation of liquid refrigerants gives the lowest power requirement and is the basis of the widely used Cascade and Mixed Refrigerant LNG processes.
Expander-based LNG installations are simple, compact, low in weight and can avoid the importation/preparation/storage of liquid refrigerants. These characteristics are attractive for smaller scale applications, particularly offshore, where low hydrocarbon inventory is desirable from safety considerations.
25However expander processes have certain drawbacks:
- until recently, limited capacity and experience with expanders - higher power requirement - higher internal gas flowrates, requiring larger line diameters, etc.

2 With most expander-based processes the working fluid (typically nitrogen) 5remains in the vapour phase at the expander outlet.
Partially liquefying the feed gas itself in an expander, having a two-phase discharge flow, can reduce internal (recycle) gas flows and reduce power 10requirement.
LNG production in a liquefying expander is not a new idea (USP 2,903, 858 ¨
Bocquet).
The present inventors previously disclosed a process (GB Patent 2393504B, USP 7,234,321) with potentially lower power requirements, wherein a liquefying expander is combined with a precooling circuit which contains a simple mixed 20refrigerant generated from the feed natural gas.
= Other recent disclosures comprise precooling by a parallel/recycle gas expander followed by a liquefying expander:
WO 01/44735 (Minta et al) describing production of pressurised liquid natural gas (PLNG) at -112 C from feed gas compressed to a high pressure of "above 1600 psia".
US 2006/0213222 (Whitesell) describing production of LNG from a feed gas entering the process at, or compressed within, the process to a pressure of "between about 1500 psig to about 3500 psig".

3 Summary of the Invention Relative to the two above-mentioned patents, an inventive step in the present application consists of identifying operating conditions for the two expanders 5(the precooling expander and the liquefying expander) which allow for practical production of atmospheric pressure LNG at about -161 C. Moreover a very high , pressure feed gas, which is a feature of the above-mentioned patents, is no longer required.
10This results in a simplified process with improved thermal efficiency having a wide range of potential applications where the raw feed gas has a pressure as low as 40 bar (4 MPa) .
The present invention facilitates production of LNG from smaller gas fields, 15particularly offshore, due to its simple flow scheme, low power consumption and non-reliance on storage and use of liquid refrigerants. The liquefaction process itself generally does not require process columns, for instance for refrigerant preparation, which may be less easy to operate under such operating conditions.
Description of the Invention

4 According to the invention, there is provided a process for liquefying natural gas or other methane-rich gases. The feed gas, generally at a pressure of from 40 (4 MPa) to 100 bar (10 MPa), is liquefied to give LNG product at approx 1 bar (0.1 MPa) / -161 C by the expander-based plant configuration described above Sand comprising:
cooling feed gas and recycle gas (mentioned below) in a first step by means of a first heat exchanger and in a first work expander; the heat exchanger having an outlet temperature in the range of -50 to -80 C, preferably -600 to -70 C; the expander having a lower outlet temperature than that of the heat exchanger; the expander having its outlet stream reheated in a cold passage of the said heat exchanger and then recompressed to form part of the above mentioned recycle gas.
passing the cooled outlet stream from the said first heat exchanger partly into a hot passage in a second heat exchanger, wherein it is essentially condensed, and partly into a second work expander, the said second expander having a lower outlet temperature than the cold outlet of the second heat exchanger, the second expander outlet stream containing a significant amount of liquid (typically 10-15% wt);
the expander outlet being separated into a vapour fraction and a liquid fraction; the vapour fraction being reheated in cold passages in said second and first heat exchangers; then recompressed and returned to the inlet to the process as part of the above mentioned recycle gas.

5 - reducing the pressure of the above mentioned separated liquid and of the condensed liquid from the hot passage from second heat exchanger (both typically around -120 C) to around to atmospheric pressure; reheating the flashed gas evolved in further cold passages in the above heat exchangers; removing the liquid for use as LNG
product.
it has been found that the lowest requirement for recycle gas compression power results from concentrating the extraction of mechanical work into the pressure range above 10 bar (1 MPa) approx at the outlet of the second 15expander. An advantage of this is that the outlet pressures from the two expanders can be equalized at around 10 bar (1MPa) , reducing the first heat exchanger to a three-passage configuration.
Whereas most existing LNG production relies on evaporation of liquid 20refrigerants to cool and condense the natural gas so as to form LNG product in a heat exchanger, this invention comprises a liquefaction process with moderate power requirement in which the necessary refrigeration, is largely supplied by work expansion of the feed gas itself. Cryogenic liquid refrigerants

6 or other secondary working fluids such as nitrogen are therefore not required.

In this way energy is extracted at a low temperature level which results in improved thermodynamic efficiency. As a result, a significant proportion of the LNG is formed directly in a work extracting expander, in addition to that formed 5by condensation in an exchanger which is cooled by the reheating of the cold gas from the said work expander.
Description of Preferred Embodiments 10The invention will be described with reference to the accompanying drawings in which Figures 1 and 2 represent flow diagrams illustrating processes in accordance with the invention.
Figure 1 shows the operating features of the invention. The exact flow sheet will 15depend upon the feed gas specification, but will generally contain these basic elements. Where pressures are stated anywhere in this application as "bar"
these are bar absolute.
The feed natural gas (Stream 1) is passed through a pretreatment stage A in 20which components that would solidify or otherwise interfere with the downstream liquefaction process, such CO2, H2S, water vapour and mercury vapour, are removed to the extent necessary to give- appropriate and conventional maximum concentrations in the pretreated gas (Stream 2).

7 Stream 2 is mixed with part (Stream 4) of the recycle gas (Stream 3) to form Stream 6, which is passed through a passage in heat exchanger 6, leaving as Stream 7 at a temperature typically in the range -200 to -60 C, preferably -30 to -50 C. This temperature is typically low enough to condense sufficient NGL to 5meet the specification for the final LNG product. Any condensed hydrocarbons in separator C are removed as Stream 8. The outlet vapour from C (Stream 9) is further cooled in a passage in heat exchanger D, exiting as Stream 10 at a temperature in the range -50 to -80 C, preferably -60 to -70 C. The remaining part of the recycle gas (Stream 5) is cooled in gas expander E having an outlet 10Stream 11 with a temperature lower than the temperature of Stream 10.
= Optionally part or all of the pretreated feed gas may exit pretreatment stage A
via Stream 2a to join the recycle gas Stream 3 upstream of the point at which it is divided into Streams 4 & 5. This option may be convenient when the natural gas feed Stream 1 has only a small content of heavy hydrocarbon. In such a 15case the pretreated feed gas may be mixed with the whole of the recycle gas and then the resulting mixture divided to supply heat exchanger B through Stream 6 and gas expander E through Stream 5.
The pressure of Stream 11 will typically be around 15 bar (1.5 MPa). Stream 11 enters a first cold passage in heat exchanger D, leaving as Stream 12, which 20then passes through a first cold passage in heat exchanger B, emerging (Stream 13) at a temperature just below the temperature of Stream 6. The ratio of the flow rate of Stream 4 to the flow rate of Stream 5 is controlled so that the

8 temperature approach between the composite hot and cold sides of heat exchangers B and D are substantially uniform throughout their lengths.
A large part of Stream 10 is then passed (Stream 14) through a second gas expander F from which it emerges as Stream 15 at a pressure between 3 bar 5(0.3 MPa) and 20 bar (2 MPa) , preferably between 5 bar (0.5 MPa) and 15 bar (1.5 MPa) and in a partly liquefied state. Stream 15 then enters vapour-liquid separator G. The liquid phase from Separator G (Stream 16) is then typically let down in a pressure reduction device H such as a valve or a turbine. The outlet from H (Stream 17), which is typically at or close to atmospheric pressure, is 10delivered into the LNG Tank I. If it is desired to reduce the nitrogen content of the product LNG, a conventional nitrogen stripping column (not shown) may be used, typically employing the sensible heat of Stream 16 for reboiling.
Optionally and preferably a part of Stream 10 flows as Stream 23 through a hot 15side passage in heat exchanger J, wherein it is liquefied by indirect heat exchange with the vapour from separator G (Stream 18), emerging as Stream 24. This is then typically let down in pressure through pressure reduction device K, such as a valve or a turbine. The outlet from K is routed either to vapour-liquid separator G, shown in broken line as Stream 25a, or preferably as 20Stream 25b to the LNG tank I. This second option helps to reduce accumulation of nitrogen in the recycle gas. Stream 18, having been heated in a first cold passage in heat exchanger J, emerges as Stream 19. It is then further heated in a second cold passage in heat exchanger D, emerging as

9 Stream 20, which is then further heated in a second cold passage in heat exchanger B, emerging as Stream 21 at a temperature slightly below the temperature of Stream 6.
5Streams 13 and 21 are compressed in recycle compressor N, from which the outlet Stream 34 is cooled typically with cooling water in cooler 0.
Compressor N may consist of more than one stage with intercoolers. Streams 13 and 21 will not have the same pressure and may enter at different compressor stages.
The outlet stream from 0 forms the above-mentioned recycle gas Stream 3.
The flashing of Stream 16 across H and the flashing of Stream 24 across K will result in the evolution of vapour comprising mainly methane together with most of the nitrogen content of the feed gas. Typically this vapour (Stream 26), optionally combined with boil-off vapour resulting from heat leak into tank I, is 15heated in a second cold passage in heat exchanger J to form Stream 27, then in a third cold passage in heat exchanger D to give Stream 28 and finally in a third cold passage in heat exchanger B, emerging as Stream 29 at a temperature slightly below the temperature of Stream 6. A conventional booster blower (also not shown) may be provided in Stream 26 to ensure that the 20pressure of Stream 29 does not fall below atmospheric pressure. Stream 29 may typically be used as fuel gas.

Part or all of Stream 29 (Stream 30) optionally may be compressed for return to the recycle gas in a low pressure compressor L, leaving as Stream 31. This stream is cooled in cooler M, from which the outlet (Stream 32) joins Stream to form Stream 22, which then enters the suction of recycle compressor N
5instead of Stream 21 alone if this option is not used. A further option is to withdraw recycle gas (Stream 33) at a convenient point from compressor N
typically for use as gas turbine fuel. It may be convenient to use Stream 29 or Stream 33 as stripping gas for regeneration of adsorbents in the pretreatment stage A, prior to their ultimate combustion as fuels.
Figure 2 shows a preferred embodiment of the invention in which expanders E
and F have essentially the same outlet pressure of between 3 bar (0.3 MPa) and 20 bar (2 MPa), preferably between 5 bar (0.5 MPa) and 15 bar (1.5 MPa).
The outlet stream from expander E (Stream 11) is then combined with Stream 1519 to form Stream 19a, which enters heat exchanger D in place of Stream 19 in Fig.1. The heat exchangers B and D then have only three passages, simplifying the construction of the exchanger and the operation of the plant.
Although in most applications it is expected that the Streams 2 and 3 will have 20temperatures close to ambient temperature, cooling below this level may be advantageous. It is feasible to cool those streams, and optionally the outlet streams from compressor intercoolers and aftercoolers, by means of a mechanical refrigeration cycle or by means of an absorption refrigeration system, typically using lithium bromide (LiBr), which could receive its heat supply from the exhaust of a gas turbine, gas engine or combined cycle or anything else suitable.

Claims (11)

Claims
1. A process for liquefying natural gas or other methane-rich gases comprising - cooling feed natural gas at a pressure of from 40 to 100 bar (4 to 10 MPa) to a temperature of -50° to -80°C by means of a heat exchanger and a first gas expander, the heat exchanger receiving the feed natural gas and having an outlet temperature higher than an outlet temperature of the first gas expander;
reheating an expander outlet stream in a first cold passage of said heat exchanger to just below an inlet temperature of the feed natural gas to said heat exchanger, compressing and recycling the reheated expander outlet stream, - passing part or all of a cold outlet stream from said heat exchanger into a second gas expander in which the part of all of the cold outlet stream is partly liquefied, - separating an outlet stream of said second gas expander into vapour and liquid fractions, - collecting the liquid fraction for use as LNG product, - reheating the vapour fraction in a second cold side passage of said heat exchanger to just below the inlet temperature of the feed natural gas to said heat exchanger;

recycling the said reheated vapour fraction after compression in part to the first gas expander and in part to the said heat exchanger;
wherein the outlet stream of the second gas expander is at a pressure between 5 and 15 bar (0 5 and 1 5 MPa)
2 The process as claimed in claim 1 in which the heat exchanger receives all the feed natural gas
3 The process as claimed in claim 1 in which the heat exchanger receives at least 30% of the feed natural gas
4. The process as claimed in any one of claims 1 to 3 in which the feed natural gas is cooled to a temperature of -600 to -700C
5 The process as claimed in any one of claims 1 to 4 in which the said first and second gas expanders have essentially the same outlet pressure of between 5 bar and 15 bar (0 5 and 15 MPa), and the outlet streams from both expanders are combined prior to final reheating, compression and recycle
6 The process as claimed in any one of claims 1 to 5 in which any part or all of the feed natural gas and/or compressed streams and/or recycled streams are cooled.
7. The process of claim 6, wherein the cooling is by use of an absorption refrigeration cycle.
8. The process of claim 7, wherein the cooling is by use of lithium bromide (LiBr).
9. The process as claimed in any one of claims 7 to 8 in which heat for the absorption refrigeration cycle is supplied by gas engine or gas turbine exhaust heat.
10. The process of claim 9, wherein the gas engine or gas turbine is used for supplying power for the compressing.
11. The process as claimed in any one of claims 1 to 10 wherein the cooling of the feed natural gas and/or the recycled streams is combined with removal of carbon dioxide and/or other impurities from the feed natural gas and/or the recycled streams.
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KR101820560B1 (en) 2018-01-19
CA2836628A1 (en) 2012-12-20
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WO2012172281A2 (en) 2012-12-20
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