CA2820227C - Novel composite conductive material - Google Patents
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- CA2820227C CA2820227C CA2820227A CA2820227A CA2820227C CA 2820227 C CA2820227 C CA 2820227C CA 2820227 A CA2820227 A CA 2820227A CA 2820227 A CA2820227 A CA 2820227A CA 2820227 C CA2820227 C CA 2820227C
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- H—ELECTRICITY
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- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
- H01M4/624—Electric conductive fillers
- H01M4/625—Carbon or graphite
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- C01B32/00—Carbon; Compounds thereof
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- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
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- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
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- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
- H01M4/587—Carbonaceous material, e.g. graphite-intercalation compounds or CFx for inserting or intercalating light metals
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- H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
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Abstract
A novel active material comprising graphene ~ fibrous carbon composite and a method of making it is provided. The composite is highly uniform. The composite comprises graphene or nanoporous graphene and fibrous carbon, preferably vapor grown carbon fibers (VGCF) and optionally a lithiummetalphosphate (LMF), preferably lithiumferrophosphate or lithiummanganesephosphate.
Description
NOVEL COMPOSITE CONDUCTIVE MATERIAL
FIELD OF THE INVENTION
The present invention relates to composite conductive materials and methods for preparing same.
BACKGROUND OF THE INVENTION
Graphene is a material composed of pure carbon, with atoms arranged in a regular hexagonal pattern. Graphene can be described as a one-atom thick layer of the mineral graphite. One of the most remarkable properties of graphene is its high conductivity;
thousands of times higher than copper. Another of graphene's stand-out properties is its inherent strength. Due to the strength of its 0.142 Nm-long carbon bonds, graphene is the strongest material ever discovered. Not only is graphene extraordinarily strong, it is also very light at 0.77 milligrams per square meter. Graphene's many desirable properties make it a useful material for many applications.
Various conductive materials and methods to prepare them are known in the art.
US Publication No. 2010/0327223 discloses a cathode material comprising particles having a lithium metal phosphate core and a thin pyrolytic carbon deposit.
W02010/012076 discloses a composite material useful as the cathode material for batteries comprising carbon fibers and complex oxide particles, where the carbon fibers and the complex oxide particles have a carbon coating on at least part of their surface and wherein the carbon coating is a non powdery coating.
US Patent No. 6,855,273 discloses a method for preparing an electrode material by heat treatment, in a controlled atmosphere, of a carbonaceous precursor in the presence of a complex oxide or its precursor. The obtained material with complex oxide particles with carbon coating has a substantially increased conductivity as compared to non-coated oxide particles.
W02004/044289 discloses a composite material obtained by mixing vapor grown carbon fibers with a matrix material, where the matrix material is a resin, a ceramic or a metal to enhance thermal and electrical conductivity of the material.
US Publication No. 2003/0198588 discloses vapor grown carbon fibers comprising an inorganic transition metallic compound.
US Publication No. 2010/0055465 discloses a method of forming a carbon-carbon composite where vapor grown carbon fibers, carbon nanofibers, and optionally nano-graphene platelets are reformed into a composite.
US Patent No. 7,354,988 discloses a method to make a conductive composition comprising blending a polymer precursor with a carbon nanotube composition, where the carbon nanotube composition may comprise vapor grown carbon fibers.
There is a continuous need in various industries for novel composite materials having high conductivity, uniformity and having low production cost.
SUMMARY OF THE INVENTION
The invention is an active material comprising a composite of graphene and fibrous carbon. Preferably the fibrous carbon is vapor grown carbon fibers (VGCF). In one embodiment, the active material comprises graphene-fibrous carbon composite, where the fibrous carbon is VGCF, the graphene forms boat-like structures, and the VGCF fibers are located inside the boat-like graphene structures. The structure is made by co-grinding graphene and fibrous carbon to obtain a partially ordered mixture and submitting the mixture to mechanofusion. Optionally, lithium metal phosphate (LMP) may be included in the composite. Other embodiments of the invention include nanoporous graphene-LFP-material.
The present invention provides a novel active composite material and a method to make it.
It is an object of this invention to provide a composite conductive material comprising graphene and fibrous carbon.
FIELD OF THE INVENTION
The present invention relates to composite conductive materials and methods for preparing same.
BACKGROUND OF THE INVENTION
Graphene is a material composed of pure carbon, with atoms arranged in a regular hexagonal pattern. Graphene can be described as a one-atom thick layer of the mineral graphite. One of the most remarkable properties of graphene is its high conductivity;
thousands of times higher than copper. Another of graphene's stand-out properties is its inherent strength. Due to the strength of its 0.142 Nm-long carbon bonds, graphene is the strongest material ever discovered. Not only is graphene extraordinarily strong, it is also very light at 0.77 milligrams per square meter. Graphene's many desirable properties make it a useful material for many applications.
Various conductive materials and methods to prepare them are known in the art.
US Publication No. 2010/0327223 discloses a cathode material comprising particles having a lithium metal phosphate core and a thin pyrolytic carbon deposit.
W02010/012076 discloses a composite material useful as the cathode material for batteries comprising carbon fibers and complex oxide particles, where the carbon fibers and the complex oxide particles have a carbon coating on at least part of their surface and wherein the carbon coating is a non powdery coating.
US Patent No. 6,855,273 discloses a method for preparing an electrode material by heat treatment, in a controlled atmosphere, of a carbonaceous precursor in the presence of a complex oxide or its precursor. The obtained material with complex oxide particles with carbon coating has a substantially increased conductivity as compared to non-coated oxide particles.
W02004/044289 discloses a composite material obtained by mixing vapor grown carbon fibers with a matrix material, where the matrix material is a resin, a ceramic or a metal to enhance thermal and electrical conductivity of the material.
US Publication No. 2003/0198588 discloses vapor grown carbon fibers comprising an inorganic transition metallic compound.
US Publication No. 2010/0055465 discloses a method of forming a carbon-carbon composite where vapor grown carbon fibers, carbon nanofibers, and optionally nano-graphene platelets are reformed into a composite.
US Patent No. 7,354,988 discloses a method to make a conductive composition comprising blending a polymer precursor with a carbon nanotube composition, where the carbon nanotube composition may comprise vapor grown carbon fibers.
There is a continuous need in various industries for novel composite materials having high conductivity, uniformity and having low production cost.
SUMMARY OF THE INVENTION
The invention is an active material comprising a composite of graphene and fibrous carbon. Preferably the fibrous carbon is vapor grown carbon fibers (VGCF). In one embodiment, the active material comprises graphene-fibrous carbon composite, where the fibrous carbon is VGCF, the graphene forms boat-like structures, and the VGCF fibers are located inside the boat-like graphene structures. The structure is made by co-grinding graphene and fibrous carbon to obtain a partially ordered mixture and submitting the mixture to mechanofusion. Optionally, lithium metal phosphate (LMP) may be included in the composite. Other embodiments of the invention include nanoporous graphene-LFP-material.
The present invention provides a novel active composite material and a method to make it.
It is an object of this invention to provide a composite conductive material comprising graphene and fibrous carbon.
2 It is another object of this invention to provide a cathode material comprising graphene, fibrous carbon and lithium metal phosphate. In one embodiment, the cathode material comprises graphene, fibrous carbon and lithium metal phosphate (LMP) particles, wherein the fibrous carbon is vapor grown carbon fibers, the graphene forms boat-like structures and the vapor grown carbon fibers and LMP particles are located inside the boat-like graphene structures.
It is yet another object of this invention to provide nanoporous graphene-LFP
material. More specifically, the nanoporous graphene-LFP material may be nanoporous MesografTm-LFP, where MesografTM is a graphene composition containing a few layers of graphene.
It is a yet another object of this invention to provide a method for preparing a composite conductive material, said method comprising the steps of: providing graphene;
providing fibrous carbon; co-grinding graphene and fibrous carbon in a high speed stirred mixer creating a partiaLly ordered mixture; and subjecting the partially ordered mixture to mechanofusion.
Still another object of this invention is to provide a method of preparing a cathode material, said method comprising the steps of: providing particles of at least one lithium metal phosphate; providing fibrous carbon; providing graphene; co-grinding graphene, fibrous carbon and LMP particles in a high speed stirred mixer creating a partially ordered mixture; and subjecting the partially ordered mixture to mechanofusion.
BRIEF DESCRIPTION OF THE DRAWINGS
Figs. 1, 2 and 3 are SEM micrographs of Graphene-LFP-VGCF mixture.
Magnification 150x in Figure 1, 7000x in Figs. 2 and 3.
Figs. 4 and 5 are SEM micrographs of Graphene-LFP-VGCF mixture after annealing at 1000 C. Magnification 400x in Fig. 4 and 1000x in Fig. 5.
Figs. 6 and 7 provide data of graphene annealed at 1000 C mechanofusion with LFP and VGCF. PVDF (polyvinylidenefluoride) is used as a binding material. The data shows high capacity, high rate and high coloumbic efficiency (100%).
Specifically, Fig. 7 shows the impedance results before and after formation of the composite.
It is yet another object of this invention to provide nanoporous graphene-LFP
material. More specifically, the nanoporous graphene-LFP material may be nanoporous MesografTm-LFP, where MesografTM is a graphene composition containing a few layers of graphene.
It is a yet another object of this invention to provide a method for preparing a composite conductive material, said method comprising the steps of: providing graphene;
providing fibrous carbon; co-grinding graphene and fibrous carbon in a high speed stirred mixer creating a partiaLly ordered mixture; and subjecting the partially ordered mixture to mechanofusion.
Still another object of this invention is to provide a method of preparing a cathode material, said method comprising the steps of: providing particles of at least one lithium metal phosphate; providing fibrous carbon; providing graphene; co-grinding graphene, fibrous carbon and LMP particles in a high speed stirred mixer creating a partially ordered mixture; and subjecting the partially ordered mixture to mechanofusion.
BRIEF DESCRIPTION OF THE DRAWINGS
Figs. 1, 2 and 3 are SEM micrographs of Graphene-LFP-VGCF mixture.
Magnification 150x in Figure 1, 7000x in Figs. 2 and 3.
Figs. 4 and 5 are SEM micrographs of Graphene-LFP-VGCF mixture after annealing at 1000 C. Magnification 400x in Fig. 4 and 1000x in Fig. 5.
Figs. 6 and 7 provide data of graphene annealed at 1000 C mechanofusion with LFP and VGCF. PVDF (polyvinylidenefluoride) is used as a binding material. The data shows high capacity, high rate and high coloumbic efficiency (100%).
Specifically, Fig. 7 shows the impedance results before and after formation of the composite.
3 Figs. 8, 9, 10, 11 and 12 are SEM micrographs of Graphene-VGCF mixture after annealing at 1000 C. Magnification 1000x in Fig. 8; 1100x in Fig. 9; 400x in Fig. 10; 1300x in Fig. 11 and 11,000x in Fig. 12.
Fig. 13 shows Raman spectra of graphite, of graphene obtained by Hummer's method, and of MesografTM. Notably, MesografTM has no or only minimal D-peak.
DETAILED DESCRIPTION OF THE INVENTION
As used herein, the term graphene means graphene in its pure form or modified in any way, including but not limited to graphene nanostrips, graphene oxide, bi-layer graphene or few-layered graphene. In addition, the methods of the present invention may also apply to chemically modified graphene, i.e., modified with carbodiimide treatments, or sulfuric and nitric acid, etc.
As used herein, MesografTm refers specifically to graphene containing few layers (for example 1-3 layers), and obtained from Grafoid Inc. (Ottawa, Canada). The properties of MesografTM is the preferred starting material to make the composites described in this application and the processes related thereto.
It is known to combine graphene with other materials in layers to further improve its properties and to create novel composite materials. For example, US patent 8,404,070 discloses a graphene sheet-carbon nanotube film composite.
By fibrous carbon, it is meant carbon fibers consisting of fiber filaments having a diameter of 5 to 500 nm and length-to-diameter ratio of 20 to 1000.
By Vapor Grown Carbon Fibers (VGCF), it is meant fibrous carbon obtained by spraying a solution containing a carbon source and a transition metal into a reaction zone and subjecting the carbon source to thermal decomposition, heating the carbon fibers thus obtained in a non-oxidative atmosphere, at a temperature between 1500 C and 8000 C, and further heating the carbon fibers in a non-oxidative atmosphere at 2000 C
to 3000 C.
By mechano fusion, it is meant a dry process performed in a mechanofusion reactor comprising a cylindrical chamber which rotates at high speed and which is equipped inside
Fig. 13 shows Raman spectra of graphite, of graphene obtained by Hummer's method, and of MesografTM. Notably, MesografTM has no or only minimal D-peak.
DETAILED DESCRIPTION OF THE INVENTION
As used herein, the term graphene means graphene in its pure form or modified in any way, including but not limited to graphene nanostrips, graphene oxide, bi-layer graphene or few-layered graphene. In addition, the methods of the present invention may also apply to chemically modified graphene, i.e., modified with carbodiimide treatments, or sulfuric and nitric acid, etc.
As used herein, MesografTm refers specifically to graphene containing few layers (for example 1-3 layers), and obtained from Grafoid Inc. (Ottawa, Canada). The properties of MesografTM is the preferred starting material to make the composites described in this application and the processes related thereto.
It is known to combine graphene with other materials in layers to further improve its properties and to create novel composite materials. For example, US patent 8,404,070 discloses a graphene sheet-carbon nanotube film composite.
By fibrous carbon, it is meant carbon fibers consisting of fiber filaments having a diameter of 5 to 500 nm and length-to-diameter ratio of 20 to 1000.
By Vapor Grown Carbon Fibers (VGCF), it is meant fibrous carbon obtained by spraying a solution containing a carbon source and a transition metal into a reaction zone and subjecting the carbon source to thermal decomposition, heating the carbon fibers thus obtained in a non-oxidative atmosphere, at a temperature between 1500 C and 8000 C, and further heating the carbon fibers in a non-oxidative atmosphere at 2000 C
to 3000 C.
By mechano fusion, it is meant a dry process performed in a mechanofusion reactor comprising a cylindrical chamber which rotates at high speed and which is equipped inside
4 with compression tools and blades. Rotation speed is generally higher than 100 rpm. The particles are introduced into the chamber and upon rotation of the chamber;
the particles are pressed together and to the chamber walls via centripetal force, and by the compression tools and blades. Mechanochemical surface fusion of the components being mixed occurs as a result of the strong mechanical forces acting on the particles.
Description of the preferred embodiments According to a preferred embodiment, an active and conductive composite of graphene and vapor grown carbon fibers (VGCF) is provided by using mechanofusion. A
preferred ratio of graphene to VGCF is 50:50, however, other ratios may also be used, such as but not limited to 40:60, or 60:40. According to this embodiment, a mixture of VGCF and graphene is obtained by mixing them in a high-speed-stirred mixer for a time period depending on other conditions. The mixing provides a partially ordered mixture that is then subjected to mechanofusion. According to a preferred embodiment, the mechanofusion step takes about five minutes. During the mechanofusion, the graphene forms boat-like structures and the VGCF fibers will be located "inside" the boat structure.
Figures 11 and 12 show such boat-like structures. The VGCF fibers cannot be seen in the figures, because they are inside the boat structure. The composite, according to this disclosure, has an extraordinarily uniform structure. More or less all carbon fibers are found inside the graphene boats.
In order to prepare a cathode material with improved conductivity for lithium batteries, a lithium metal phosphate (LMP) is added into the compositions. LMP
is added into the initial grinding process and a mixture of VGCF, graphene and LMP is obtained by mixing them in a high-speed-stirred mixer fora lime period, the length of which depending on other conditions. The mixing provides a partially ordered mixture that is then subjected to mechanofusion. According to a preferred embodiment, the mechanofusion step takes about five minutes. During mechanofusion, the graphene forms boat-like structures and VGCF fibers as well as LMP particles will be located "inside" the boat structure. The composite according to this disclosure has an extraordinary uniform structure:
Figures 1 and 2 show almost no graphene without LMP agglomeration. The fibrous carbon in the composite material creates a multi-channel structure forming network conductivity between the graphene and LMP particles. According to a preferred embodiment, the ratio of graphene:VGCF:LMP is 94:3:3.
the particles are pressed together and to the chamber walls via centripetal force, and by the compression tools and blades. Mechanochemical surface fusion of the components being mixed occurs as a result of the strong mechanical forces acting on the particles.
Description of the preferred embodiments According to a preferred embodiment, an active and conductive composite of graphene and vapor grown carbon fibers (VGCF) is provided by using mechanofusion. A
preferred ratio of graphene to VGCF is 50:50, however, other ratios may also be used, such as but not limited to 40:60, or 60:40. According to this embodiment, a mixture of VGCF and graphene is obtained by mixing them in a high-speed-stirred mixer for a time period depending on other conditions. The mixing provides a partially ordered mixture that is then subjected to mechanofusion. According to a preferred embodiment, the mechanofusion step takes about five minutes. During the mechanofusion, the graphene forms boat-like structures and the VGCF fibers will be located "inside" the boat structure.
Figures 11 and 12 show such boat-like structures. The VGCF fibers cannot be seen in the figures, because they are inside the boat structure. The composite, according to this disclosure, has an extraordinarily uniform structure. More or less all carbon fibers are found inside the graphene boats.
In order to prepare a cathode material with improved conductivity for lithium batteries, a lithium metal phosphate (LMP) is added into the compositions. LMP
is added into the initial grinding process and a mixture of VGCF, graphene and LMP is obtained by mixing them in a high-speed-stirred mixer fora lime period, the length of which depending on other conditions. The mixing provides a partially ordered mixture that is then subjected to mechanofusion. According to a preferred embodiment, the mechanofusion step takes about five minutes. During mechanofusion, the graphene forms boat-like structures and VGCF fibers as well as LMP particles will be located "inside" the boat structure. The composite according to this disclosure has an extraordinary uniform structure:
Figures 1 and 2 show almost no graphene without LMP agglomeration. The fibrous carbon in the composite material creates a multi-channel structure forming network conductivity between the graphene and LMP particles. According to a preferred embodiment, the ratio of graphene:VGCF:LMP is 94:3:3.
5 The lithium metal phosphate is preferably lithium ferrophosphate or lithium manganese phosphate or mixtures thereof. Mixtures of differing lithium metal phosphates and other additives can also be used in the composite. Polyvinylidenefluoride is a standard binding material used in composite electrodes and it can be used as a binder in composites of this invention as well.
The fibrous carbon used to prepare the composite material of this invention consists of carbon fibers, wherein the carbon fiber consists of fiber filaments having a diameter of 5 to 500 nm and length-to-diameter ratio of 20 to 1000.
Carbon fibers may be obtained by a method comprising spraying a solution containing a carbon source and a transition metal into a reaction zone and subjecting the carbon source to thermal decomposition, heating the carbon fibers thus obtained in a non-oxidative atmosphere at a temperature between 1500 C and 8000 C, and further heating the carbon fibers in a non-oxidative atmosphere at 2000 C to 3000 C. The second heat treatment of the carbon, at 2000 C-3000 C, cleans the surface of the fibers and results in increasing the adhesion of the carbon fibers to the carbon coating of the complex oxide particles. The carbon fibers -thus obtained are called Vapor Grown Carbon Fibers. More detailed information on the method for preparing vapor grown carbon fibers can be found in W02004/044289.
Vapor Grown Carbon Fibers are also available from Showa Denko K.K. (Japan) under the trademark VGCF TM. The fiber diameter of these fibers is about 150nm, the fiber length is about 10pm, the specific area is 13 m2/g, the electric conductivity is 0.1 mOcm, and the purity is >99.95%.
Lithium metal phosphate (LMP) has been seen as an excellent candidate for cathode materials due to its intrinsic safety, low material cost and environment benign features. The covalently bounded oxygen atom in the phosphate polyanion eliminates the cathode instability against 02 release observed in fully charged layered oxides. The drawbacks with lithium metal phosphate cathode materials are their low electronic conductivity and slow electrode kinetics. To improve the conductivity of the lithium metal phosphate, the particles may be coated with carbon coating. W02010/0102076 teaches how carbon fibers and the complex oxide particles are mixed with organic carbon
The fibrous carbon used to prepare the composite material of this invention consists of carbon fibers, wherein the carbon fiber consists of fiber filaments having a diameter of 5 to 500 nm and length-to-diameter ratio of 20 to 1000.
Carbon fibers may be obtained by a method comprising spraying a solution containing a carbon source and a transition metal into a reaction zone and subjecting the carbon source to thermal decomposition, heating the carbon fibers thus obtained in a non-oxidative atmosphere at a temperature between 1500 C and 8000 C, and further heating the carbon fibers in a non-oxidative atmosphere at 2000 C to 3000 C. The second heat treatment of the carbon, at 2000 C-3000 C, cleans the surface of the fibers and results in increasing the adhesion of the carbon fibers to the carbon coating of the complex oxide particles. The carbon fibers -thus obtained are called Vapor Grown Carbon Fibers. More detailed information on the method for preparing vapor grown carbon fibers can be found in W02004/044289.
Vapor Grown Carbon Fibers are also available from Showa Denko K.K. (Japan) under the trademark VGCF TM. The fiber diameter of these fibers is about 150nm, the fiber length is about 10pm, the specific area is 13 m2/g, the electric conductivity is 0.1 mOcm, and the purity is >99.95%.
Lithium metal phosphate (LMP) has been seen as an excellent candidate for cathode materials due to its intrinsic safety, low material cost and environment benign features. The covalently bounded oxygen atom in the phosphate polyanion eliminates the cathode instability against 02 release observed in fully charged layered oxides. The drawbacks with lithium metal phosphate cathode materials are their low electronic conductivity and slow electrode kinetics. To improve the conductivity of the lithium metal phosphate, the particles may be coated with carbon coating. W02010/0102076 teaches how carbon fibers and the complex oxide particles are mixed with organic carbon
6 precursors and the composition is made by mechanofusion. Such coated LMP
particles can also be used in the composite of this disclosure.
According to one preferred embodiment, the starting material is MesografTM
(Grafoid Inc., Ottawa, Canada), which is few layered graphene. MesografTM has extraordinary characteristics that make it superior to other starting materials. Figure 13 shows Raman spectra of graphite, of graphene obtained by Hummer's method and of MesografTM. Unlike graphene made by Hummer's method, MesografTM has almost no D-band at all. Raman spectroscopy is commonly used to characterize graphene. The D-band is known as the disorder band or the defect band. The band is typically very weak in graphite. The intensity of the D-band is directly proportional to the level of the defects in the sample. As is shown in Figure 13, the D-band of graphene made by Hummer's method is considerably more pronounced than in MesografTM, which makes MesografTM a preferred starting material.
According to one preferred embodiment, MesografTM is used to make nanoporous material, which is then fused to carbon coated LFP in mechanofusion process.
The nanoporous material is made according to the following scheme:
MesografTM ¨> oxidation by using 9:1 H2SO4/H3PO4 + Mn207; quenching with H202 (NaNO3, as used in Hummer's method for example, is avoided) results in MesografTM
Oxide. MesografTM Oxide is refluxed in 1 M NaOH, and thereafter in H2SO4.
Nanoporous MesografTM is obtained by filtering.
The nanoporous MesografTM is then mechanofused with carbon coated LFP to yield nanoporous MesografTm-LFP. The nanoporous MesografTm-LFP is a novel composite with interesting properties in energy storage with high BET/surface area.
The composite materials according to the present invention have an extraordinarily uniform structure. The VGCF and LMP particles have high adhesion to the graphene and the composite materials obtained have a structure, where graphene forms "a boat of carbon" and the VGCF and/or LFP particles are inside the boat. The process of making .
the material is fast and cost effective.
particles can also be used in the composite of this disclosure.
According to one preferred embodiment, the starting material is MesografTM
(Grafoid Inc., Ottawa, Canada), which is few layered graphene. MesografTM has extraordinary characteristics that make it superior to other starting materials. Figure 13 shows Raman spectra of graphite, of graphene obtained by Hummer's method and of MesografTM. Unlike graphene made by Hummer's method, MesografTM has almost no D-band at all. Raman spectroscopy is commonly used to characterize graphene. The D-band is known as the disorder band or the defect band. The band is typically very weak in graphite. The intensity of the D-band is directly proportional to the level of the defects in the sample. As is shown in Figure 13, the D-band of graphene made by Hummer's method is considerably more pronounced than in MesografTM, which makes MesografTM a preferred starting material.
According to one preferred embodiment, MesografTM is used to make nanoporous material, which is then fused to carbon coated LFP in mechanofusion process.
The nanoporous material is made according to the following scheme:
MesografTM ¨> oxidation by using 9:1 H2SO4/H3PO4 + Mn207; quenching with H202 (NaNO3, as used in Hummer's method for example, is avoided) results in MesografTM
Oxide. MesografTM Oxide is refluxed in 1 M NaOH, and thereafter in H2SO4.
Nanoporous MesografTM is obtained by filtering.
The nanoporous MesografTM is then mechanofused with carbon coated LFP to yield nanoporous MesografTm-LFP. The nanoporous MesografTm-LFP is a novel composite with interesting properties in energy storage with high BET/surface area.
The composite materials according to the present invention have an extraordinarily uniform structure. The VGCF and LMP particles have high adhesion to the graphene and the composite materials obtained have a structure, where graphene forms "a boat of carbon" and the VGCF and/or LFP particles are inside the boat. The process of making .
the material is fast and cost effective.
7 ^7 The composite materials obtained have high conductivity. The materials may be used for example in batteries, in conductive coatings and in capacitors. The composite material has other active features as well: among others, it may have hydrophobic and icephobic characteristics.
Although this invention has been described with a certain degree of particularity, it is to be understood that the present disclosure has been made only by way of illustration and that numerous changes in the details of construction and arrangement of parts may be resorted to without departing from the spirit and the scope of the invention.
Although this invention has been described with a certain degree of particularity, it is to be understood that the present disclosure has been made only by way of illustration and that numerous changes in the details of construction and arrangement of parts may be resorted to without departing from the spirit and the scope of the invention.
8
Claims (18)
1. An active material comprising a graphene-fibrous carbon composite, wherein the fibrous carbon is vapor grown carbon fibers, the graphene forms boat-like structures and the vapor grown carbon fibers are located inside the boat-like graphene structures.
2. The active material of claim 1, wherein the material is made by co-grinding graphene and fibrous carbon to obtain a partially ordered mixture and submitting the mixture to mechanofusion.
3. The active material of claim 1 or 2, wherein the weight ratio of graphene and vapor grown carbon fibers is 50:50.
4. The active material of any one of claims 1 to 3, wherein the active material is conductive.
5. The active material of any one of claims 1 to 4, wherein the active material is hydrophobic or ice phobic.
6. A cathode material comprising graphene, fibrous carbon and lithium metal phosphate (LMP) particles, wherein the fibrous carbon is vapor grown carbon fibers, the graphene forms boat-like structures and the vapor grown carbon fibers and LMP
particles are located inside the boat-like graphene structures.
particles are located inside the boat-like graphene structures.
7. The cathode material of claim 6, wherein the material is made by co-grinding graphene, fibrous carbon and LMP particles to obtain a partially ordered mixture and submitting the mixture to mechanofusion.
8. The cathode material of claim 6 or 7, wherein the LMP is lithium ferrophosphate or lithium manganese phosphate.
9. The cathode material of any one of claims 6 to 8, wherein the weight ratio of Graphene:LMP:vapor grown carbon fibers is 93:3:3.
10. The cathode material of any one of claims 6 to 9, wherein the graphene is few-layered nanoporous graphene having a Raman spectrum showing no or almost no D-band at 1350 cm-1.
11. A method for preparing a composite conductive material, said method comprising the steps of:
a) providing graphene;
b) providing fibrous carbon;
c) co-grinding graphene and fibrous carbon in a high speed stirred mixer resulting to a partially ordered mixture; and d) subjecting the partially ordered mixture to a mechanofusion.
a) providing graphene;
b) providing fibrous carbon;
c) co-grinding graphene and fibrous carbon in a high speed stirred mixer resulting to a partially ordered mixture; and d) subjecting the partially ordered mixture to a mechanofusion.
12. The method of claim 11, wherein fibrous carbon is vapor grown carbon fibers.
13. The method of claim 11 or 12, wherein the graphene is few-layered graphene.
14. The method of claim 13, wherein the few-layered graphene is few-layered graphene having a Raman spectrum showing no or almost no D-band at 1350 cm-1.
15. A method to prepare a cathode material, said method comprising the steps of :
a) providing particles of at least one lithium metal phosphate (LMP);
b) providing fibrous carbon;
c) providing graphene;
d) co-grinding graphene, fibrous carbon and LMP particles in a high speed stirred mixer resulting in a partially ordered mixture; and e) subjecting the partially ordered mixture to a mechanofusion.
a) providing particles of at least one lithium metal phosphate (LMP);
b) providing fibrous carbon;
c) providing graphene;
d) co-grinding graphene, fibrous carbon and LMP particles in a high speed stirred mixer resulting in a partially ordered mixture; and e) subjecting the partially ordered mixture to a mechanofusion.
16. The method of claim 15, wherein the fibrous carbon is vapor grown carbon fibers.
17. The method of claim 15 or 16, wherein the LMP is lithium ferrophosphate or lithium manganese phosphate.
18. The method of any one of claims 15 to 17, wherein the fibrous carbon comprises carbon fibers, each of which comprises fiber filaments, said fiber filaments having a diameter of 5 to 500nm and a length to diameter ratio of 20 to 1000.
Priority Applications (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA2820227A CA2820227C (en) | 2013-07-10 | 2013-07-10 | Novel composite conductive material |
| CN201480049997.8A CN106415902B (en) | 2013-07-10 | 2014-07-09 | Novel composite conductive material |
| EP14822056.9A EP3028327A4 (en) | 2013-07-10 | 2014-07-09 | Novel composite conductive material |
| US14/904,289 US20160133938A1 (en) | 2013-07-10 | 2014-07-09 | Novel composite conductive material |
| JP2016524932A JP6532869B2 (en) | 2013-07-10 | 2014-07-09 | Novel composite conductive material |
| PCT/IB2014/062987 WO2015004621A1 (en) | 2013-07-10 | 2014-07-09 | Novel composite conductive material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA2820227A CA2820227C (en) | 2013-07-10 | 2013-07-10 | Novel composite conductive material |
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| CA2820227A1 CA2820227A1 (en) | 2015-01-10 |
| CA2820227C true CA2820227C (en) | 2020-10-20 |
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| US (1) | US20160133938A1 (en) |
| EP (1) | EP3028327A4 (en) |
| JP (1) | JP6532869B2 (en) |
| CN (1) | CN106415902B (en) |
| CA (1) | CA2820227C (en) |
| WO (1) | WO2015004621A1 (en) |
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| WO2020065832A1 (en) | 2018-09-27 | 2020-04-02 | 株式会社村田製作所 | Electrically conductive substance, positive electrode, and secondary battery |
| KR102351971B1 (en) * | 2020-02-18 | 2022-01-17 | 서울대학교산학협력단 | Mellitic triimide as electrode active material for lithium secondary battery and lithium secondary battery using the same |
| CN112652768B (en) * | 2020-10-23 | 2022-05-20 | 有研工程技术研究院有限公司 | Preparation method of lithium manganese phosphate-graphene composite material, lithium manganese phosphate-graphene composite material and application |
| CN113878835B (en) * | 2021-12-08 | 2022-03-08 | 国家电投集团氢能科技发展有限公司 | Polytetrafluoroethylene/carbon fiber composite release film and preparation method and application thereof |
| CN117795699A (en) * | 2021-12-22 | 2024-03-29 | 株式会社Lg新能源 | Negative electrode composition, negative electrode for lithium secondary battery containing the same, lithium secondary battery including the negative electrode, and method for producing negative electrode composition |
| CN120717462A (en) * | 2025-07-23 | 2025-09-30 | 安庆师范大学 | A method for regulating the band gap and optoelectronic properties of few-layer graphene |
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| JP2007035488A (en) * | 2005-07-28 | 2007-02-08 | Sanyo Electric Co Ltd | Non-aqueous electrolyte battery |
| CA2623407A1 (en) * | 2008-02-28 | 2009-08-28 | Hydro-Quebec | Composite electrode material |
| CA2638410A1 (en) * | 2008-07-28 | 2010-01-28 | Hydro-Quebec | Composite electrode material |
| US20100055465A1 (en) * | 2008-08-29 | 2010-03-04 | Andrew Palmer | Carbon-carbon composites for use in thermal management applications |
| CA2691265A1 (en) * | 2010-01-28 | 2011-07-28 | Phostech Lithium Inc. | Optimized cathode material for a lithium-metal-polymer battery |
| WO2012006725A1 (en) * | 2010-07-15 | 2012-01-19 | Phostech Lithium Inc. | Battery grade cathode coating formulation |
| CN102544502B (en) * | 2010-12-09 | 2015-07-01 | 中国科学院宁波材料技术与工程研究所 | Anode and cathode conductive additive for secondary lithium battery, method for preparing conductive additive, and method for preparing secondary lithium battery |
| US20120164534A1 (en) * | 2010-12-28 | 2012-06-28 | Daiwon Choi | GRAPHENE/LiFePO4 CATHODE WITH ENHANCED STABILITY |
| JP5664404B2 (en) * | 2011-03-29 | 2015-02-04 | 東レ株式会社 | Metal compound-conductive agent composite, lithium secondary battery using the same, and method for producing metal compound-conductive agent composite |
| US20120288762A1 (en) * | 2011-05-10 | 2012-11-15 | University Of Georgia Research Foundation, Inc. | Graphene-coated pyrolytic carbon structures, methods of making, and methods of use thereof |
| US9475921B2 (en) * | 2011-06-23 | 2016-10-25 | Molecular Rebar Design, Llc | Nanoplate-nanotube composites, methods for production thereof and products obtained therefrom |
| KR102156726B1 (en) * | 2011-08-29 | 2020-09-16 | 가부시키가이샤 한도오따이 에네루기 켄큐쇼 | Method of manufacturing positive electrode active material for lithium ion battery |
| CA2754372A1 (en) * | 2011-10-04 | 2013-04-04 | Hydro-Quebec | Positive-electrode material for lithium-ion secondary battery and method of producing same |
| US9484569B2 (en) * | 2012-06-13 | 2016-11-01 | 24M Technologies, Inc. | Electrochemical slurry compositions and methods for preparing the same |
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2013
- 2013-07-10 CA CA2820227A patent/CA2820227C/en active Active
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- 2014-07-09 EP EP14822056.9A patent/EP3028327A4/en not_active Withdrawn
- 2014-07-09 JP JP2016524932A patent/JP6532869B2/en active Active
- 2014-07-09 US US14/904,289 patent/US20160133938A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| JP6532869B2 (en) | 2019-06-19 |
| CN106415902A (en) | 2017-02-15 |
| US20160133938A1 (en) | 2016-05-12 |
| CA2820227A1 (en) | 2015-01-10 |
| EP3028327A1 (en) | 2016-06-08 |
| JP2016531823A (en) | 2016-10-13 |
| EP3028327A4 (en) | 2017-03-22 |
| WO2015004621A1 (en) | 2015-01-15 |
| CN106415902B (en) | 2022-01-25 |
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