CA2738365C - Method for producing composite lithium iron phosphate material and composite lithium iron phosphate material produced by same - Google Patents

Method for producing composite lithium iron phosphate material and composite lithium iron phosphate material produced by same Download PDF

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CA2738365C
CA2738365C CA2738365A CA2738365A CA2738365C CA 2738365 C CA2738365 C CA 2738365C CA 2738365 A CA2738365 A CA 2738365A CA 2738365 A CA2738365 A CA 2738365A CA 2738365 C CA2738365 C CA 2738365C
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iron phosphate
lithium iron
solution
phosphate material
value
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CA2738365A1 (en
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Liguang Ye
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Shandong Goldencell Electronics Technology Co Ltd
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HAITE ELECTRONIC GROUP CO Ltd
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/5825—Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B25/00—Phosphorus; Compounds thereof
    • C01B25/16—Oxyacids of phosphorus; Salts thereof
    • C01B25/26—Phosphates
    • C01B25/45—Phosphates containing plural metal, or metal and ammonium
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

A method for producing a composite lithium iron phosphate material, which comprises formulating lithium iron phosphate material and purified water at a weight ratio of 1:5-15 into a suspension solution, slowly adjusting the pH value of the suspension solution to 1--3 with phosphoric acid at a concentration of 5-30%, adding an analytically pure soluble chloride in an amount of 0.05 - 2% based on the molar amount of the lithium iron phosphate material; then adding ammonia water into the solution to adjust the pH value of the solution to 5-6 to obtain hydroxide colloid; drying liquid through spraying to prepare powder, and calcining at 300-450°C for 3-6 hours under an inert atmosphere;
coating the oxide with high conductivity obtained by thermally decomposing the hydroxide colloid on the surface of the lithium iron phosphate material grains; ball milling and sieving the calcined material into a finished product. Also disclosed is the composite lithium iron phosphate material produced by such a method.

Description

Method for Producing Composite Lithium Iron Phosphate Material and Composite Lithium Iron Phosphate Material Produced by Same Field of the Invention The invention relates to modification technology for a lithium iron phosphate material serving as the cathode of a lithium ion battery, in particular to a method for producing a composite lithium iron phosphate material and the composite lithium iron phosphate material produced by the method.
Background of the Invention Due to its advantages of long cycle life, high safety performance, low cost, good temperature stability, abundant resources, etc., the lithium iron phosphate (LiFePO4) material becomes the first choice of cathode material for a lithium ion power battery.
Particularly, the lithium iron phosphate material draws the attention of many domestic and overseas research and development organizations and manufacturers.
However, the lithium iron phosphate material has a defect of low electrical conductivity, which results in high electrochemical polarization and resistance polarization. At present, major methods adopted home and abroad for solving the problem refer to carbon coating, which lowers the contact resistance among lithium iron phosphate particles by the high conductivity of carbon so as to realize the aims of reducing polarization and prolonging cycle life.
For example, a Chinese Patent of Invention with the Publication Number of CN101154722A and the Invention Title of "Nuclear shell nanoscale carbon-coated lithium iron phosphate composite cathode material and preparation method thereof', a Chinese Patent of Invention with the Publication Number of CN101162776A and the Invention Title of "Lithium iron phosphate suitable for high magnification power battery and preparation method thereof', a Chinese Patent of Invention with the Publication Number of CN101172599A and the Invention Title of "Method for preparing carbon-coated lithium iron phosphate", a Chinese Patent of Invention with the Publication Number of CN101212049A and the Invention Title of "Cathode material consisting of doped lithium iron phosphate active substance and carbon", etc. are carbon coating methods. Coated carbon material is generally formed through cracking of carbon-containing organic substances such as cane sugar, glucose and cyclodextrin while sintering during the producing process of lithium iron phosphate material.
Some technology adopts a method for doping heterogeneous ions and improving the conductivity of a lithium iron phosphate substrate, such as a Chinese Patent of Invention with the Publication Number of CN1773754A and the Invention Title of "Cathode material consisting of lithium iron phosphate and composite metal phosphide thereof and preparation method", a Chinese Patent of Invention with the Publication Number of CN1785799A and the Invention Title of "Method for preparing transition element-doped lithium iron phosphate powder" and a Chinese Patent of Invention with the Publication Number of CN1830764A and the Invention Title of "Rare earth-doped carbon-coated nanometer cathode material lithium iron phosphate and preparation method thereof'.
A Chinese Patent of Invention with the Publication Number of CN101339988A and the Invention Title of "Cathode material of lithium ion battery and preparation method thereof' also discloses a method for generating metal copper on the surface of a lithium iron phosphate material by soaking with copper nitrate and reducing with VC. A Chinese Patent of Invention with the Publication Number of CN1649189A and the Invention Title of "Method for preparing carbon-coated lithium ferrous phosphate composite material containing metal conductive agent"
discloses a method for forming elemental copper or silver on the surface of the material by high temperature reduction of copper or silver salt. The technology can improve the electrochemical performance of the material to a certain extent. However, some problems also exist. For example, carbon will severely reduce the stacking and compacted density of the material and large carbon agglomerates tend to form when dispersion is poor. The effect of heterogeneous ion doping is
2 unstable and its function is also unstable. The conductive metal reduction method has complex operation process and it is very difficult to ensure that metal does not undergo side reactions such as oxidation in subsequent processing process.
Summary of the Invention Aiming at the problems of low conductivity of the lithium iron phosphate material, uneven dispersion of a coated conductive carbon phase, inhomogeneous quality, etc., the invention discloses a technical principle and a process for modifying the traditional lithium iron phosphate material. An electrochemically active oxide phase with high conductivity is coated on the grain surface of the traditional lithium iron phosphate material so as to realize the aims of enhancing the conductivity of the lithium iron phosphate material and improving the electrochemical performance of the material.
In order to realize the abovementioned aims, the technical scheme adopted by the invention is as follows:
A method for producing a composite lithium iron phosphate material comprising the following steps:
confecting lithium iron phosphate and purified water at a weight ratio of 1: 5-15 into a solution;
adjusting a pH value of the solution to 1-3 with phosphoric acid at a concentration of 5-30% of its mass, thereafter adding analytically pure soluble chloride in an amount of 0.05-2% of the molar amount of the lithium iron phosphate to the solution, wherein said analytically pure soluble chloride is one or more of aluminum chloride, titanium chloride and magnesium chloride, thereafter adding aqueous ammonia at concentration of 4-6% of its mass into the solution to adjust the pH value of the solution to 5-6 to obtain hydroxide colloid in the solution;
making the solution which has hydroxide colloid become powder through a hot spraying method;
calcinating the powder at 300-450 C for 3-6 hours in inert atmosphere, such that the hydroxide
3 colloid is decomposed thermally to obtain oxide with high conductivity which is coated on surfaces of the lithium iron phosphate in grains shape, wherein said oxide with high conductivity is one or more of aluminum oxide, titanium oxide and magnesium oxide; and ball-milling and sieving the lithium iron phosphate grains coated with the oxide into a finished composite lithium iron phosphate material.
Optionally, in the method for producing the composite lithium iron phosphate material, said inert atmosphere refers to nitrogen gas or argon gas.
Optionally, in the method for producing the composite lithium iron phosphate material, 100 kg of commercial lithium iron phosphate and 500 kg of the purified water are confected into the solution, the pH value of the solution is adjusted to 1 with phosphoric acid at a concentration of 5% of its mass, and 0.05 kg of analytically pure aluminum chloride is added into the solution thereafter; then the aqueous ammonia at a concentration of 5% of its mass is slowly added into the solution to adjust the pH value of the solution to 5 with stirring to obtain aluminum hydroxide colloid; and the calcinating of the powder is conducted at 300 C for 6 hours in nitrogen atmosphere.
Optionally, in the method for producing the composite lithium iron phosphate material, 100 kg of commercial lithium iron phosphate material and 1,500 kg of the purified water are confected into the solution, the pH value of the solution is adjusted to 3 with phosphoric acid at a concentration of 30% of its mass, and 2 kg of analytically pure magnesium chloride is added into the solution thereafter; the aqueous ammonia at a concentration of 5% of its mass is then added into the solution to adjust the pH value of the solution to 6 with stirring to obtain aluminum hydroxide colloid; and the calcinating of the powder is conducted at 450 C for 3 hours in nitrogen atmosphere.
Optionally, in the method for producing the composite lithium iron phosphate material, 100 kg of commercial lithium iron phosphate material and 1,000 kg of the purified water are confected into
4 the solution, the pH value of the solution is adjusted to 2 with phosphoric acid at a concentration of 10% of its mass, and 1 kg of analytically pure titanium chloride is added thereafter; the aqueous ammonia at a concentration of 5% of its mass is then added into the solution to adjust the pH value of the solution to 5.5 with stirring to obtain aluminum hydroxide colloid; and the calcinating of the powder is conducted at 400 C for 4 hours in nitrogen atmosphere.
Optionally, in the method for producing the composite lithium iron phosphate material, 200 kg of commercial lithium iron phosphate material and 2,200 kg of the purified water are confected into the solution, the pH value of the solution is adjusted to 1.8 with phosphoric acid at a concentration of 8% of its mass, and 0.5 kg of analytically pure titanium chloride and 0.5 kg of analytically pure aluminum chloride are added into the solution thereafter;
the aqueous ammonia at a concentration of 5% of its mass is then added into the solution to adjust the pH value of the solution to 5.6 with stirring to obtain aluminum hydroxide colloid; and the calcinating of the powder is conducted at 385 C for 3.5 hours in argon atmosphere.
The method realizes performance improvement by after-treatment of the lithium iron phosphate material and is suitable for various lithium iron phosphate cathode materials synthesized by processes such as solid phase synthesis, precipitation synthesis, hydrothermal synthesis and microwave synthesis. In the method, the oxide with high conductivity is coated on the surface of the lithium iron phosphate material, so the conductivity of the lithium iron phosphate material is enhanced, a lithium ion conveying passage is provided and the discharge performance of the lithium iron phosphate material is improved effectively. Particularly, its high-magnification discharge performance is improved greatly.
Detailed Descriptions of Implementation Further descriptions of the invention are given below in combination with embodiments:
Aiming at the problems of low conductivity of the lithium iron phosphate material, uneven dispersion of a coated conductive carbon phase, inhomogeneous quality, etc., the invention discloses a technical principle and a process for modifying the traditional lithium iron phosphate material. An electrochemically active oxide phase with high conductivity is coated on the grain surface of the traditional lithium iron phosphate material so as to realize the aims of enhancing the conductivity of the lithium iron phosphate material and improving the electrochemical performance of the material. The technology realizes performance improvement by after-treatment of the lithium iron phosphate material and is suitable for various lithium iron phosphate cathode materials synthesized by processes such as solid phase synthesis, precipitation synthesis, hydrothermal synthesis and microwave synthesis.
The said oxide with high conductivity mainly refers to aluminum oxide, titanium oxide and magnesium oxide. These oxides generally have crystal structures with low symmetries, large ion passages in crystal lattices and high lithium ion conducting properties. For example, the aluminum oxide itself is a solid electrolyte material. The said oxides can be obtained by thermal decomposition of hydroxides thereof. The oxide particles produced by a hydroxide are obtained by decomposing hydroxide colloid, are extremely fine and tend to fully coat lithium iron phosphate grains.
The said oxide with high conductivity is coated on the surface of the lithium iron phosphate material, so the conductivity of the lithium iron phosphate material is enhanced, a lithium ion conveying passage is provided and the discharge performance of the lithium iron phosphate material is improved effectively. Particularly, its high-magnification discharge performance is improved greatly.
The process for modifying the performance of the lithium iron phosphate material comprising the following steps:
confect existing and initially-synthesized lithium iron phosphate material and purified water at a weight ratio of 1: 5-15 into a suspension;

slowly adjusting a pH value of the suspension to 1-3 with phosphoric acid at a concentration of
5-30% of its mass, thereafter adding an analytically pure soluble chloride in an amount of 0.05-2% of the molar amount of the lithium iron phosphate to the suspension;
thereafter adding aqueous ammonia at a concentration of 4-6% of its mass into the solution to adjust the pH value of the solution to 5-6 to obtain hydroxide colloid in the solution;
make the solution having hydroxide colloid become powder through hot spraying method; and calcinating the powder at 300-450 C for 3-6 hours in inert atmosphere, the hydroxide colloid is decomposed thermally to obtain oxide with high conductivity which is coated on surfaces of the lithium iron phosphate in grains shape;
ball-milling and sieving the lithium iron phosphate grains coated with the oxide into a finished composite lithium iron phosphate material.
The said soluble chloride is one or more of aluminum chloride, titanium chloride and magnesium chloride.
The said inert atmosphere refers to nitrogen gas or argon gas.
The said oxide with high conductivity is one or more of aluminum oxide, titanium oxide and magnesium oxide.
Detailed Description of the Invention Embodiment 1:
The method for producing the composite lithium iron phosphate material, wherein confect 100 kg of commercial lithium iron phosphate and 500 kg of purified water into a suspension, slowly adjusting a pH value of the suspension to 1 with phosphoric acid at a concentration of 5% of its mass, and adding 0.05 kg of analytically pure aluminum chloride thereafter;
then slowly adding aqueous ammonia at a concentration of 5% of its mass into the suspension to adjust the pH value of the solution to 5 with stirring to obtain aluminum hydroxide colloid; make the solution having hydroxide colloid become powder through hot spraying; calcinating the powder at 300 C for 6 hours in nitrogen atmosphere; ball-milling and sieving the calcined material into a finished product, wherein 1C discharge capacity is increased by 4% when the material is prepared into a 18650 type cylindrical battery.
Embodiment 2:
The method for producing the composite lithium iron phosphate material, wherein confect 100 kg of commercial lithium iron phosphate material and 1,500 kg of purified water into a suspension, slowly adjusting the pH value of the suspension to 3 with phosphoric acid at a concentration of 30% of its mass and adding 2 kg of analytically pure magnesium chloride thereafter; then slowly adding aqueous ammonia at a concentration of 5% of its mass into the suspension to adjust the pH value of the solution to 6 with stirring to obtain aluminum hydroxide colloid; make the solution having hydroxide colloid become powder through hot spraying;
calcinating the powder at 450 C for 3 hours in nitrogen atmosphere; ball-milling and sieving the calcined material into a finished product, wherein 1C discharge capacity is increased by 3.5%
when the material is prepared into a 18650 type cylindrical battery.
Embodiment 3:
The method for producing the composite lithium iron phosphate material, wherein confect 100 kg of commercial lithium iron phosphate material and 1,000 kg of purified water into a suspension, slowly adjusting the pH value of the suspension to 2 with phosphoric acid at a concentration of 10% of its mass and adding 1 kg of analytically pure titanium chloride thereafter; then slowly adding aqueous ammonia at a concentration of 5% of its mass into the suspension to adjust the pH value of the solution to 5.5 with stirring to obtain aluminum hydroxide colloid; make the solution having hydroxide colloid become powder through hot spraying; calcinating the powder at 400 C for 4 hours in nitrogen atmosphere;
ball-milling and . , CA 02738365 2013-12-13 sieving the calcined material into a finished product, wherein 1C discharge capacity is increased by 5% when the material is prepared into a 18650 type cylindrical battery.
Embodiment 4:
The method for producing the composite lithium iron phosphate material, wherein confect 200 kg of commercial lithium iron phosphate material and 2,200 kg of purified water into a suspension, slowly adjusting the pH value of the suspension to 1.8 with phosphoric acid at a concentration of 8% of its mass and adding 0.5 kg of analytically pure titanium chloride and 0.5 kg of analytically pure aluminum chloride thereafter; then slowly adding aqueous ammonia at a concentration of 5% of its mass into the suspension to adjust the pH value of the suspension to 5.6 with stirring to obtain aluminum hydroxide colloid; make the suspension having hydroxide colloid become powder through hot spraying; calcinating the power at 385 C for 3.5 hours in argon atmosphere; ball-milling and sieving the calcined material into a finished product, wherein 1C discharge capacity is increased by 5% and 5C discharge capacity is increased by 10% when the material is prepared into a 18650 type cylindrical battery.
The scope of the invention is defined by the appended claims.

Claims (6)

Claims:
1. A method for producing composite lithium iron phosphate material comprising the following steps: confecting lithium iron phosphate and purified water at a weight ratio of 1: 5-15 into a solution; adjusting the pH value of the solution to 1-3 with 5-30% weight percentage concentration of phosphoric acid, thereafter adding analytically pure soluble chloride to an amount of 0.05-2% of the molar amount of the lithium iron phosphate to the solution; thereafter adding 4-6% weight percentage concentration of aqueous ammonia into the solution to adjust the pH value of the solution to 5-6 to obtain hydroxide colloid; making the above-mentioned material liquid into powder through the application of hot spraying method;
calcinating the powder at 300-450°C for 3-6 hours under the inert atmosphere as a result, the hydroxide colloid is decomposed thermally to obtain an oxide with high conductivity which is coated on surfaces of the lithium iron phosphate in grains shape; and ball-milling and sieving the lithium iron phosphate grains coated with the oxide into finished composite lithium iron phosphate material.
2. The method for producing composite lithium iron phosphate material of Claim 1, wherein the analytically pure soluble chloride is one or more of aluminum chloride, titanium chloride and magnesium chloride; the inert atmosphere is nitrogen gas or argon gas; and the oxide with high conductivity is one or more of aluminum oxide, titanium oxide and magnesium oxide.
3. The method for producing composite lithium iron phosphate material of Claim 2, wherein 100 kg of commercial lithium iron phosphate and 500 kg of the purified water are confected into a suspension, the pH value of the solution is adjusted to 1 with 5% weight percentage concentration of phosphoric acid, and 0.05 kg of analytically pure aluminum chloride is added into the solution thereafter; then 5% weight percentage concentration of aqueous ammonia is added into the solution to adjust back the pH value of the solution to 5 by stirring to obtain aluminum hydroxide colloid; making this liquid into powder through the application of hot spraying method and calcinating the powder at 300°C for 6 hours under the nitrogen atmosphere;
and ball-milling and sieving the lithium iron phosphate grains coated with the oxide into a finished composite lithium iron phosphate material.
4. The method for producing composite lithium iron phosphate material of Claim 2, wherein 100 kg of commercial lithium iron phosphate material and 1,500 kg of the purified water are confected into the solution, the pH value of the solution is adjusted to 3 with 30% weight percentage concentration of phosphoric acid, and 2 kg of analytically pure magnesium chloride is added into the solution thereafter; 5% weight percentage concentration of aqueous ammonia is then added into the solution to adjust the pH value of the solution to 6, making this liquid into powder through the application of hot spraying method and calcinating the powder at 450°C for 3 hours in the nitrogen atmosphere; and ball-milling and sieving the lithium iron phosphate grains coated with the oxide into finished composite lithium iron phosphate material.
5. The method for producing composite lithium iron phosphate material of Claim 2, wherein 100 kg of commercial lithium iron phosphate material and 1,000 kg of the purified water are confected into the solution, the pH value of the solution is adjusted to 2 with 10% weight percentage concentration of phosphoric acid, and 1 kg of analytically pure titanium chloride is added thereafter; 5% weight percentage concentration of aqueous ammonia is then added into the solution to adjust the pH value of the solution to 5.5, making this liquid into powder through the application of hot spraying method and calcinating the powder at 400°C
for 4 hours in nitrogen atmosphere; and ball-milling and sieving the lithium iron phosphate grains coated with the oxide into a finished composite lithium iron phosphate material.
6. The method for producing composite lithium iron phosphate material of Claim 2, wherein 200 kg of commercial lithium iron phosphate material and 2,200 kg of the purified water are confected into the solution, the pH value of the solution is adjusted to 1.8 with 8% weight percentage concentration of phosphoric acid, and 0.5 kg of analytically pure titanium chloride and 0.5 kg of analytically pure aluminum chloride are added into the solution thereafter; 5%
weight percentage concentration of aqueous ammonia is then added into the solution to adjust the pH value of the solution to 5.6; making this liquid into powder through the application of hot spraying method and calcinating the powder at 385° C for 3.5 hours in the argon atmosphere; and ball-milling and sieving the lithium iron phosphate grains coated with the oxide into finished composite lithium iron phosphate material.
CA2738365A 2009-06-21 2010-06-21 Method for producing composite lithium iron phosphate material and composite lithium iron phosphate material produced by same Active CA2738365C (en)

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CN200910016269.8 2009-06-21
CN2009100162698A CN101580238B (en) 2009-06-21 2009-06-21 Method for manufacturing composite lithium iron phosphate material and composite lithium iron phosphate material manufactured thereof
PCT/CN2010/000906 WO2010148638A1 (en) 2009-06-21 2010-06-21 Method for producing composite lithium iron phosphate material and composite lithium iron phosphate material produced thereby

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AU (1) AU2010265710B2 (en)
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US8815338B2 (en) 2014-08-26
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