CA2582035A1 - Metal producing method and producing device by molten salt electrolysis - Google Patents
Metal producing method and producing device by molten salt electrolysis Download PDFInfo
- Publication number
- CA2582035A1 CA2582035A1 CA002582035A CA2582035A CA2582035A1 CA 2582035 A1 CA2582035 A1 CA 2582035A1 CA 002582035 A CA002582035 A CA 002582035A CA 2582035 A CA2582035 A CA 2582035A CA 2582035 A1 CA2582035 A1 CA 2582035A1
- Authority
- CA
- Canada
- Prior art keywords
- metal
- molten
- cathode
- salt
- production
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 157
- 239000002184 metal Substances 0.000 title claims abstract description 157
- 238000005868 electrolysis reaction Methods 0.000 title claims abstract description 119
- 150000003839 salts Chemical class 0.000 title claims abstract description 40
- 238000000034 method Methods 0.000 title claims abstract description 32
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims abstract description 42
- 239000001110 calcium chloride Substances 0.000 claims abstract description 42
- 229910001628 calcium chloride Inorganic materials 0.000 claims abstract description 42
- 239000011575 calcium Substances 0.000 claims description 95
- 229910052791 calcium Inorganic materials 0.000 claims description 95
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 93
- 238000004519 manufacturing process Methods 0.000 claims description 48
- 239000010936 titanium Substances 0.000 claims description 37
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 36
- 229910052719 titanium Inorganic materials 0.000 claims description 36
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims description 32
- 239000000463 material Substances 0.000 claims description 6
- 239000011261 inert gas Substances 0.000 claims description 4
- 239000007789 gas Substances 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims 2
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 claims 2
- WDIHJSXYQDMJHN-UHFFFAOYSA-L barium chloride Chemical compound [Cl-].[Cl-].[Ba+2] WDIHJSXYQDMJHN-UHFFFAOYSA-L 0.000 claims 1
- 229910001626 barium chloride Inorganic materials 0.000 claims 1
- 239000012768 molten material Substances 0.000 claims 1
- 239000011780 sodium chloride Substances 0.000 claims 1
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 18
- 238000010586 diagram Methods 0.000 description 18
- 238000002844 melting Methods 0.000 description 15
- 230000008018 melting Effects 0.000 description 15
- 238000006243 chemical reaction Methods 0.000 description 11
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 4
- 238000005660 chlorination reaction Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000003792 electrolyte Substances 0.000 description 3
- 230000002349 favourable effect Effects 0.000 description 3
- 239000001103 potassium chloride Substances 0.000 description 3
- 235000011164 potassium chloride Nutrition 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 238000006722 reduction reaction Methods 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 229910000975 Carbon steel Inorganic materials 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- 150000001669 calcium Chemical class 0.000 description 2
- 239000010962 carbon steel Substances 0.000 description 2
- 239000003638 chemical reducing agent Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 208000004434 Calcinosis Diseases 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229910003074 TiCl4 Inorganic materials 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 229910001092 metal group alloy Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003609 titanium compounds Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B34/00—Obtaining refractory metals
- C22B34/10—Obtaining titanium, zirconium or hafnium
- C22B34/12—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08
- C22B34/129—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08 obtaining metallic titanium from titanium compounds by dissociation, e.g. thermic dissociation of titanium tetraiodide, or by electrolysis or with the use of an electric arc
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
- C25C3/02—Electrolytic production, recovery or refining of metals by electrolysis of melts of alkali or alkaline earth metals
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
- C25C3/26—Electrolytic production, recovery or refining of metals by electrolysis of melts of titanium, zirconium, hafnium, tantalum or vanadium
- C25C3/28—Electrolytic production, recovery or refining of metals by electrolysis of melts of titanium, zirconium, hafnium, tantalum or vanadium of titanium
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C7/00—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
- C25C7/02—Electrodes; Connections thereof
- C25C7/025—Electrodes; Connections thereof used in cells for the electrolysis of melts
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Metallurgy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Geology (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Environmental & Geological Engineering (AREA)
- Mechanical Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Electrolytic Production Of Metals (AREA)
- Manufacture And Refinement Of Metals (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2004-297865 | 2004-10-12 | ||
JP2004297865A JP4247792B2 (ja) | 2004-10-12 | 2004-10-12 | 溶融塩電解による金属の製造方法および製造装置 |
PCT/JP2005/018449 WO2006040978A1 (ja) | 2004-10-12 | 2005-10-05 | 溶融塩電解による金属の製造方法および製造装置 |
Publications (1)
Publication Number | Publication Date |
---|---|
CA2582035A1 true CA2582035A1 (en) | 2006-04-20 |
Family
ID=36148273
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002582035A Abandoned CA2582035A1 (en) | 2004-10-12 | 2005-10-05 | Metal producing method and producing device by molten salt electrolysis |
Country Status (9)
Country | Link |
---|---|
US (1) | US20080078679A1 (de) |
EP (1) | EP1811062A4 (de) |
JP (1) | JP4247792B2 (de) |
CN (1) | CN101044268A (de) |
AU (1) | AU2005293038A1 (de) |
CA (1) | CA2582035A1 (de) |
EA (1) | EA011903B1 (de) |
NO (1) | NO20072241L (de) |
WO (1) | WO2006040978A1 (de) |
Families Citing this family (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP4193984B2 (ja) * | 2003-08-28 | 2008-12-10 | 株式会社大阪チタニウムテクノロジーズ | 金属製造装置 |
JPWO2006115027A1 (ja) * | 2005-04-25 | 2008-12-18 | 東邦チタニウム株式会社 | 溶融塩電解槽およびこれを用いた金属の製造方法 |
JP2007063585A (ja) * | 2005-08-30 | 2007-03-15 | Sumitomo Titanium Corp | 溶融塩電解方法および電解槽並びにそれを用いたTiの製造方法 |
JPWO2008038405A1 (ja) * | 2006-09-28 | 2010-01-28 | 東邦チタニウム株式会社 | 金属製造用溶融塩電解槽およびこれを用いた金属の製造方法 |
PL2109691T3 (pl) * | 2007-01-22 | 2017-02-28 | Materials And Electrochemical Research Corporation | Redukcja metalotermiczna chlorku tytanu generowanego in situ |
EP2123798A4 (de) * | 2007-02-19 | 2010-03-17 | Toho Titanium Co Ltd | Vorrichtung zur herstellung von metall durch schmelzflusselektrolyse und verfahren zur herstellung von metall unter verwendung der vorrichtung |
KR101237327B1 (ko) | 2007-05-11 | 2013-02-28 | 엠 히카리 앤 에너지 레보레토리 컴퍼니 리미티드 | 온 사이트 통합 생산 공장 |
JP2009019250A (ja) * | 2007-07-13 | 2009-01-29 | Osaka Titanium Technologies Co Ltd | 金属製造方法および装置 |
CN101649472B (zh) * | 2008-08-15 | 2012-06-06 | 攀钢集团钢铁钒钛股份有限公司 | 一种制备金属钛的方法 |
MD168Z (ro) * | 2009-06-04 | 2010-10-31 | Институт Прикладной Физики Академии Наук Молдовы | Dispozitiv pentru acoperirea galvanică a suprafeţei interioare a pieselor cilindrice cu un diametru mic şi mijlociu |
BR112013011941A2 (pt) * | 2010-11-18 | 2016-11-01 | Metalysis Ltd | método e sistema para reduzir eletroliticamente uma matéria - prima sólida |
EP2640872B1 (de) | 2010-11-18 | 2019-03-13 | Metalysis Limited | Elektrolysegerät |
CN102517611B (zh) * | 2011-12-27 | 2015-08-26 | 宁波江丰电子材料股份有限公司 | 熔盐电解提炼设备及其提炼金属的方法 |
JP6270446B2 (ja) * | 2013-12-06 | 2018-01-31 | 東邦チタニウム株式会社 | 溶融塩電解による金属の製造方法 |
CN103774180B (zh) * | 2014-01-28 | 2016-03-02 | 东北大学 | 一种集氯化-电解为一体的制取金属和合金的装置与方法 |
CN103898553B (zh) * | 2014-03-25 | 2016-06-22 | 中国科学院过程工程研究所 | 一种电积和精炼同步进行生产金属钙的方法 |
RU2687113C2 (ru) * | 2014-06-30 | 2019-05-07 | Тохо Титаниум Ко., Лтд. | Способ получения металла и способ получения тугоплавкого металла |
CN104668557B (zh) * | 2015-02-06 | 2018-12-28 | 安徽腾拓新材料科技有限公司 | 一种金属钙压锭成型设备 |
CN107532236B (zh) * | 2015-02-09 | 2019-09-17 | 国立大学法人北海道大学 | 金属钒的制造方法 |
CN104928721B (zh) * | 2015-06-12 | 2017-09-22 | 中南大学 | 一种低价钛氯化物熔盐电解质的制备及精炼装置 |
CN106835203B (zh) * | 2016-12-26 | 2019-05-31 | 宝纳资源控股(集团)有限公司 | 一种熔盐的净化装置及方法 |
CN107164781A (zh) * | 2017-06-05 | 2017-09-15 | 攀钢集团研究院有限公司 | 一种制备超细钛粉的方法 |
CN107059067A (zh) * | 2017-06-05 | 2017-08-18 | 攀钢集团研究院有限公司 | 一种制备超细钛合金粉的方法 |
CN109881200B (zh) * | 2019-04-10 | 2021-05-11 | 深圳市铿东科技有限公司 | 一种碱性蚀刻液再生及其铜回收方法 |
US20240084468A1 (en) * | 2022-09-09 | 2024-03-14 | Phoenix Tailings, Inc. | Systems and methods for feeding solid material and a gas into an electrolytic cell |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ES257371A1 (es) * | 1959-05-13 | 1960-11-16 | Solvay | Procedimiento para la preparaciën de un metal alcalino-terreo por electrëlisis de banos de cloruros fundidos |
JPS61186489A (ja) * | 1985-02-13 | 1986-08-20 | Hiroshi Ishizuka | アルカリ金属または土金属の溶融塩化物電解装置 |
FR2589169B1 (fr) * | 1985-10-25 | 1990-08-31 | Commissariat Energie Atomique | Electrolyseur pour l'extraction d'une substance, notamment d'un metal alcalin, d'un bain electrolytique |
ITTO970080A1 (it) * | 1997-02-04 | 1998-08-04 | Marco Vincenzo Ginatta | Procedimento per la produzione elettrolitica di metalli |
JP2003129268A (ja) * | 2001-10-17 | 2003-05-08 | Katsutoshi Ono | 金属チタンの精錬方法及び精錬装置 |
JP3718691B2 (ja) * | 2002-04-18 | 2005-11-24 | 財団法人生産技術研究奨励会 | チタンの製造方法、純金属の製造方法、及び純金属の製造装置 |
-
2004
- 2004-10-12 JP JP2004297865A patent/JP4247792B2/ja not_active Expired - Fee Related
-
2005
- 2005-10-05 WO PCT/JP2005/018449 patent/WO2006040978A1/ja active Application Filing
- 2005-10-05 AU AU2005293038A patent/AU2005293038A1/en not_active Abandoned
- 2005-10-05 CN CNA2005800349261A patent/CN101044268A/zh active Pending
- 2005-10-05 US US11/576,887 patent/US20080078679A1/en not_active Abandoned
- 2005-10-05 CA CA002582035A patent/CA2582035A1/en not_active Abandoned
- 2005-10-05 EP EP05790573A patent/EP1811062A4/de not_active Withdrawn
- 2005-10-05 EA EA200700843A patent/EA011903B1/ru not_active IP Right Cessation
-
2007
- 2007-04-30 NO NO20072241A patent/NO20072241L/no not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
NO20072241L (no) | 2007-04-30 |
EA200700843A1 (ru) | 2007-08-31 |
JP4247792B2 (ja) | 2009-04-02 |
US20080078679A1 (en) | 2008-04-03 |
EP1811062A4 (de) | 2009-04-29 |
JP2006111895A (ja) | 2006-04-27 |
CN101044268A (zh) | 2007-09-26 |
AU2005293038A1 (en) | 2006-04-20 |
WO2006040978A1 (ja) | 2006-04-20 |
EP1811062A1 (de) | 2007-07-25 |
EA011903B1 (ru) | 2009-06-30 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FZDE | Discontinued |