CA2560335A1 - Micro coating comprising siloxanes - Google Patents

Micro coating comprising siloxanes Download PDF

Info

Publication number
CA2560335A1
CA2560335A1 CA002560335A CA2560335A CA2560335A1 CA 2560335 A1 CA2560335 A1 CA 2560335A1 CA 002560335 A CA002560335 A CA 002560335A CA 2560335 A CA2560335 A CA 2560335A CA 2560335 A1 CA2560335 A1 CA 2560335A1
Authority
CA
Canada
Prior art keywords
weight
binder
coating composition
advantageously
employed
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002560335A
Other languages
French (fr)
Other versions
CA2560335C (en
Inventor
Thomas Kruse
Gerhard Reusmann
Bettina Werner
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ewald Doerken AG
Original Assignee
Thomas Kruse
Ewald Doerken Ag
Gerhard Reusmann
Bettina Werner
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Thomas Kruse, Ewald Doerken Ag, Gerhard Reusmann, Bettina Werner filed Critical Thomas Kruse
Publication of CA2560335A1 publication Critical patent/CA2560335A1/en
Application granted granted Critical
Publication of CA2560335C publication Critical patent/CA2560335C/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08—Anti-corrosive paints
    • C09D5/082—Anti-corrosive paints characterised by the anti-corrosive pigment
    • C09D5/086—Organic or non-macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08—Anti-corrosive paints
    • C09D5/10—Anti-corrosive paints containing metal dust
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/48—Stabilisers against degradation by oxygen, light or heat
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Silicon Polymers (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)

Abstract

The invention relates to a binding agent comprising an aqueous, film-forming, polymeric siloxane. The invention also relates to a coating agent that is produced using said binding agent and to a workpiece that is coated with said coating agent.

Claims (44)

1. Binder including an aqueous, film forming, polymeric siloxane.
2. Binder according to claim 1, characterized in that the polymeric siloxane has a content of alkoxy groups of less than 10 % by weight, preferably of less than 5 % by weight, particularly preferably of less than 2 % by weight based on the polymeric siloxane.
3. Binder according to claim 1 or 2, characterized in that the binder is produced from individual or mixtures of the following group of silanes, comprising alkyl- or alkenyl silanes, methacrylic silanes and silanes which contain epoxy-, mercaptane- or hydroxyalkyl groups.
4. Binder according to at least one of the preceding claims, characterized in that the content of molymers in the binder is less than 10 % by weight, preferably less than 5 % by weight, particularly preferably less than 3 % by weight, advantageously less than 1 % by weight, each based on the overall solids-content of the binder.
5. Binder according to at least one of the preceding claims, characterized in that the binder liberates less than 10 % by weight, preferably less than 5 % by weight, particularly preferably less than 2 % by weight alcohols, each based on the overall amount of the binder.
6. Binder according to at least one of the preceding claims, characterized in that the binder is acid-free.
7. Binder according to at least one of the preceding claims, characterized in that it is a siloxane filled with particles.
8. Binder according to claim 7, characterized in that the particles have dimensions of smaller than 100 µm, preferably of up to 50 µm, particularly preferably up to 20 µm, advantageously up to 10 µm, particularly advantageously below 1 µm.
9. Binder according to claim 8, characterized in that the particles have dimensions below 1 µm, particularly advantageously between 5nm and 100 nm, preferably between 10 and 55 nm.
10. Binder according to claim 7, characterized in that in the binder inorganic particles, in particular silicon dioxide, are employed.
11. Binder according to claim 10, characterized in that colloidal silicon dioxide or particulate silicic acid are employed.
12. Binder according to claim 7, characterized in that the silicon dioxide has been added to the binder in the form of hydrogen-, lithium-, potassium or sodium polysilicate or as a mixture of the aforesaid polysilicates.
13. Binder according to any one of claim 7 to 12, characterized in that particles are employed which, in aqueous solution, have an acid pH-value.
14. Binder according to claim 7, characterized in that in the binder organic particles are employed.
15. Binder according to claim 7, characterized in that the monomeric silane employed in the manufacture of the binder and the particles are employed in a molar ratio of 50 to 1 up to 1 to 50, preferably of 20 to 1 up to 1 to 20, advantageously of 10 to 1 up to 1 to 10, particularly advantageously of 5 to 1 up to 1 to 5, particularly preferred of 2 to 1 up to 1 to 2.
16. Binder according to at least one of the preceding claims, characterized in that the object-temperature for final curing of the binder is in excess of room temperature, preferably above 40 °C, particularly preferred above 80 °C, advantageously above 150°C, very advantageously up to 300 °C, particularly advantageously up to 500 °C.
17. Binder according to at least one of the preceding claims, characterized in that the time for final curing of the binder amounts to 1 second and 90 minutes, advantageously between 2 minutes and 60 minutes, particularly preferred between 3 minutes and 30 minutes.
18. Binder according to claim 1, characterized in that the polymeric siloxane has a molecular weight of at least 200 g/mol, preferably at least 400 g/mol, particularly preferably at least 800 g/mol, advantageously at least 1000 g/mol
19. Binder according to at least one of the preceding claims, characterized in that the solids content amounts to between 0.5 % and 90 %, advantageously more than 10 %, more than 25 %, particularly preferred more than 50 %, advantageously more than 70 %.
20. Binder according to at least one of the preceding claims, characterized in that the pH-value amounts to between 2 and 13, preferably between 3 and 8.
21. Binder according to at least one of the preceding claims, characterized in that co-binders in an amount of 0.01 % by weight up to 50 % by weight based on the overall formulation of the coating composition have been added, preferably from the group comprising alkyd resins, epoxy resins, acrylic dispersions, phenoxy resins, melamin resins, polyurethane resins and epoxy resins.
22. Binder according to claim 1, characterized in that the aqueous polymeric siloxane has added thereto an organic solvent in a proportion of up to 20 % by weight, preferably of up to 10 % by weight, each based on the overall formulation of the binder.
23. Coating composition for the coating of metal surfaces including a binder according to at least one of claims 1 to 20 and at least one further additive.
24. Coating composition according to claim 23, characterized in that the coating composition comprises a solids content of 0.5 % to 95 %, preferably of more than 1%, preferably of more than 20%, advantageously of more than 50%.
25. Coating composition according to at least one of the preceding claims, characterized in that the object temperature for final curing of the binder is above room temperature, preferably above 40 °C, particularly preferably above 80 °C, advantageously above 150 °C, very advantageously up to 300 °C, particularly advantageously up to 500 °C.
26. Coating composition according to at least one of the preceding claims, characterized in that the time for final curing of the binder amounts to between 1 second and 90 minutes, advantageously between 2 minutes and 60 minutes, particularly preferably between 3 minutes and 30 minutes.
27. Coating composition according to claim 23, characterized in that the coating composition, besides the binder, has added thereto at least one additive for adjusting the curing period, the substrate wetting and/or for adjusting the curing temperature and/or for adjusting the viscosity of the metal surface to be coated in an amount each of 0.01 weight % to 25 weight %, preferably of 0.1 weight % up to 10 weight based on the overall formulation of the coating composition.
28. Coating composition according to claim 23, characterized in that, as additive, one or more substances have been employed from the group including water, alcohols, ketones, glycols, polyglycol, polypropylene glycol, glycol ethers, glycol ether esters, dipropylene glycol, methoxypropanol, butyl glycol, Texanol, aromatic and aliphatic hydrocarbons, and that this or these additives are employed in an amount of 0.01 % by weight up to 25 % by weight, preferably of 0.1%
by weight up to 15 % by weight, each based on the overall formulation of the coating composition.
29. Coating composition according to at least one of claims 23 to 28, characterized in that, as additive, waxes and/or lubricating agents have been added in an amount of 0.01 % to 40 % based on the overall formulation of the coating composition.
30. Coating composition according to claim 29, characterized in that, as waxes, preferably solid or liquid emulsions or dispersions, in particular polyethylene, polypropylene, polytetrafluoro ethylene, polyvinylidene fluoride or carnauba wax or mixtures of different waxes are employed.
31. Coating composition according to at least one of claims 23 to 30, characterized in that as additive catalysts or at least one additive for improving the rheology, the substrate wetting, the defoaming, the flow properties, the de-aeration, the pigment wetting, the flexibilization or as water capturing agent, have been added singly or in mixture in an amount each of 0.01 % by weight up to 20 % by weight, preferably 2 by weight up to 8 % by weight, particularly preferably below 2 % by weight, advantageously below 1 % by weight, each based on the overall formulation of the coating composition.
32. Coating composition according to claim 31, characterized in that, as an additive for water capturing, a monomeric or oligomeric silane or a mixture of monomeric and/or oligomeric silane has been employed in an amount of up to 2.8 % by weight, preferably up to 2 % by weight, particularly preferably up to 1 % by weight based on the overall formulation of the coating composition.
33. Coating composition according to at least one of claims 23 to 32, characterized in that, as additive, pigments, pigment paste, dyes and/or fillers are employed in an amount of 0.01 % by weight based on the overall formulation of the coating composition.
34. Coating composition according to claim 33, characterized in that metal particles, in particular aluminum particles, are employed as pigments.
35. Coating composition according to at least one of claims 23 to 34, characterized in that the binder has added thereto as additive a corrosion inhibitor and/or a corrosion preventing or retarding pigment or a mixture of such additives in solid or liquid form, in particular an organic corrosion inhibitor, preferably an organic nitro compound, in particular a dinitrosalicilic acid in an amount of 0.01 % by weight up to 30 % by weight based on the overall formulation of the coating agent.
36. Coating composition according to at least one of claims 23 to 35, characterized in that to the binder are added as additive boron compounds, in particular from the group of boric acids or boron oxides or molybdenum or phosphorus compounds, each individually or in mixture.
37. Coating composition according to at least one of claims 23 to 36, characterized in that, as an additive, at least one particulate metal for the improvement of the corrosion properties of the metal surface to be coated, is added in an amount of from 10 weight % up to 95 weight %, preferably 20 weight % up to 80 weight %, preferably 20 weight % to 60 weight %, advantageously 20 weight % to 50 weight %, based on the overall formulation of the coating composition.
38. Coating composition according to claim 37, characterized in that, as particulate metal of the group containing zinc, aluminium, iron, manganese and tin, the particulate metals are employed each individually, in a mixture or as alloy of at least two metals of the group of zinc and aluminum, iron, manganese and tin or chromium-nickel-steel particles.
39. Coating composition according to claim 37, characterized in that the particulate metal is employed in the form of beads, spherical particles, lamellae or flakes.
40. Coating composition according to claim 37, characterized in that to the coating composition a solvent is added for the particulate metal, in particular an organic solvent, preferably ketones, methoxypropanol, butyl glycol, glycols, polyglycol, polypropylene glycol, glycol ether, glycol esters, glycol ether esters, dipropylene glycol, texanol, aliphatic and aromatic hydrocarbons, as well as alcohols or a mixture of the aforesaid organic solvents in an amount of 0.01 up to 35 weight %, based on the overall formulation of the coating composition.
41. Coating composition for the coating of metal surfaces according to claim 23 including a component I, including - at least one particulate metal - an organic solvent for the particulate metal - optionally a corrosion inhibitor for the particulate metal and one component II, including - an aqueous, film forming, polymeric siloxane according to at least one of claims 1 to 23 as a binder.
42. Coating composition according to claim 41, characterized in that component I and/or component II has added thereto further additives.
43. Coating composition according to at least one of claims 23 to 40, characterized in that at least two components I and II of the coating composition are stared separately until used.
44. Work piece including a coating formed from a fully cured coating agent according to at least one of the claims 23 to 43.
CA2560335A 2004-03-19 2005-03-21 Micro coating comprising siloxanes Expired - Fee Related CA2560335C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102004014032 2004-03-19
DE102004014032.4 2004-03-19
PCT/EP2005/002984 WO2005090502A2 (en) 2004-03-19 2005-03-21 Microcoating comprising siloxanes

Publications (2)

Publication Number Publication Date
CA2560335A1 true CA2560335A1 (en) 2005-09-29
CA2560335C CA2560335C (en) 2011-06-14

Family

ID=34966334

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2560335A Expired - Fee Related CA2560335C (en) 2004-03-19 2005-03-21 Micro coating comprising siloxanes

Country Status (16)

Country Link
US (1) US9011586B2 (en)
EP (1) EP1675922B1 (en)
JP (1) JP5396020B2 (en)
KR (1) KR101257708B1 (en)
CN (1) CN1934205A (en)
AU (1) AU2005223349B2 (en)
BR (1) BRPI0508997A (en)
CA (1) CA2560335C (en)
EA (1) EA014856B1 (en)
HR (1) HRP20060307A2 (en)
IL (1) IL177980A (en)
ME (1) MEP29508A (en)
MX (1) MXPA06010676A (en)
RS (1) RS20060525A (en)
WO (1) WO2005090502A2 (en)
ZA (1) ZA200607038B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102012005806A1 (en) 2012-03-22 2013-09-26 Nano-X Gmbh Process for the preparation of a corrosion protection coating

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102004034645A1 (en) * 2004-07-16 2006-02-09 Ewald Dörken Ag Anti-corrosion coating agent for metal and method of making the same
CN100535069C (en) * 2007-06-04 2009-09-02 江阴市大阪涂料有限公司 Heat resistant paint for iron and steel
DE102007054627A1 (en) * 2007-11-15 2009-05-20 Cht R. Beitlich Gmbh Water-compatible brine for coating various substrates
KR100852392B1 (en) * 2008-01-15 2008-08-14 주식회사 경성엔터프라이즈 The membrane technique with ceramic liquid binder for enhancing durability performance of concrete and steel structures
FI122754B (en) * 2008-06-27 2012-06-29 Lauri Ylikorpi Coating composition and process for its preparation
DE102009034869A1 (en) * 2009-07-27 2011-02-03 Ewald Dörken Ag Method for applying at least one anticorrosive, liquid, metal particle-containing coating agent to a workpiece and a device therefor
EP2510061A2 (en) * 2009-12-11 2012-10-17 Tata Steel UK Limited Environmentally friendly protective coatings for substrates
WO2012047345A2 (en) * 2010-07-07 2012-04-12 Saint Louis University Passivated metal nanoparticles having an epoxide-based oligomer coating
ITMI20101492A1 (en) * 2010-08-04 2012-02-05 Claudio Martinuzzi COMPOSITION FOR THE COATING OF TOOLS FOR MECHANICAL PROCESSING OR ROTATIONAL MOLDS AND METHOD FOR ITS USE
DE102011084183A1 (en) * 2011-03-25 2012-09-27 Evonik Degussa Gmbh Aqueous silane-based anti-corrosive formulation
DE102012008959A1 (en) 2012-05-03 2013-11-07 NANO - X GmbH binder system
ES2747838T3 (en) * 2014-04-16 2020-03-11 Doerken Ewald Ag Procedure for Producing a Dark Corrosion Protective Coating
EP2980166B1 (en) 2014-08-01 2017-06-07 Ewald Dörken Ag Anticorrosive coating composition
KR20160078773A (en) * 2014-12-24 2016-07-05 주식회사 포스코 Low temperature curable anti-corrosion coating composition excellent in corrosion resistance and zinc plated steel sheet using the same
CN104877138B (en) * 2015-05-14 2018-06-12 深圳新宙邦科技股份有限公司 A kind of silicones with adhesive property and preparation method thereof
EP3178884B1 (en) 2015-12-08 2018-02-07 Evonik Degussa GmbH Aqueous [3- (2,3-dihydroxyprop-1-oxy) propyl] silanololigomer containing composition, method for their preparation and their use
EP3243878A1 (en) 2016-05-10 2017-11-15 Rembrandtin Lack GmbH Nfg.KG Corrosion protection
CN106634804A (en) * 2016-12-27 2017-05-10 广州市高士实业有限公司 Silicone sealant with metal corrosion resistance and preparation method therefor
JP7208900B2 (en) * 2017-07-28 2023-01-19 デュポン・東レ・スペシャルティ・マテリアル株式会社 Water-based coating agent composition, and water-based lubricating coating composition comprising the same
DE102019135827A1 (en) 2019-12-27 2021-07-01 Cooper-Standard Automotive (Deutschland) Gmbh Union screw for pipelines provided with at least one flange, in particular brake pipes
CN114164423A (en) * 2021-11-30 2022-03-11 广东达志化学科技有限公司 Chromium-free passivation solution and preparation method and application thereof

Family Cites Families (50)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3689300A (en) * 1971-01-26 1972-09-05 Du Pont Coupling agent formulations
US4218354A (en) * 1974-03-22 1980-08-19 Stauffer Chemical Company Binder composition and coating containing the same
US3986997A (en) * 1974-06-25 1976-10-19 Dow Corning Corporation Pigment-free coating compositions
JPS53130732A (en) * 1977-03-18 1978-11-15 Rohm & Haas Weatherproof and wearrresistant coating composition and method of bonding same
ZA795994B (en) 1978-11-30 1981-05-27 Gen Electric Silicone resin coating composition
US4324712A (en) 1978-11-30 1982-04-13 General Electric Company Silicone resin coating composition
US4209555A (en) * 1979-01-26 1980-06-24 A. O. Smith Corporation Corrosion resistant galvanic coating
US4383062A (en) * 1981-01-28 1983-05-10 General Electric Waterborne coating compositions
JPS58167445A (en) 1982-03-24 1983-10-03 Nippon Electric Glass Co Ltd Glass for coating semiconductor
JPS58167449A (en) * 1982-03-30 1983-10-03 Toshiba Silicone Co Ltd Material to cover scratch mark of glass bottle
US4439239A (en) * 1982-06-02 1984-03-27 Ppg Industries, Inc. Pigmented coating composition containing a mixture of alkoxysilanes
US4532096A (en) * 1983-05-09 1985-07-30 Bogner Ben R Method of shaping articles using shaping surfaces having release agent coating
DE3320157A1 (en) * 1983-06-03 1984-12-06 VEGLA Vereinigte Glaswerke GmbH, 5100 Aachen GLASS DISC, IN PARTICULAR CAR GLASS DISC, WITH OVER AN ADHESIVE LAYER WITH ITS CONNECTED METAL HOLDING ELEMENTS
US4624870A (en) * 1984-11-14 1986-11-25 General Electric Company Sodium free silicone resin coating compositions
US4680232A (en) * 1986-01-02 1987-07-14 General Electric Company Abrasion and UV resistant coating compositions
US6264859B1 (en) * 1986-10-03 2001-07-24 Ppg Industries Ohio, Inc. Optically transparent UV-protective coatings
JP2653023B2 (en) * 1988-04-22 1997-09-10 大阪有機化学工業 株式会社 Coating composition
US4863520A (en) * 1988-07-05 1989-09-05 General Electric Company Method for curing silicone coatings on plastic substrates, and curable compositions related thereto
US4855348A (en) * 1988-07-14 1989-08-08 Dap Inc. Aqueous, silicone-containing coating composition for high temperature appliances
US5081174A (en) * 1988-10-11 1992-01-14 Ppg Industries, Inc. Protective coating composition
KR0133520B1 (en) * 1990-02-27 1998-04-21 로버트 폴 크라사 Thermosetting organosiloxane composition
US5164003A (en) * 1990-03-28 1992-11-17 Ceram Tech International, Ltd. Room temperature curable surface coating and methods of producing and applying same
US5316854A (en) * 1991-12-06 1994-05-31 Ppg Industries, Inc. Glass or quartz articles having high temperature UV absorbing coatings containing ceria
ES2096334T3 (en) * 1992-10-20 1997-03-01 Wacker Chemie Gmbh BINDERS AND AQUEOUS COATING AGENTS.
US5421865A (en) * 1993-10-29 1995-06-06 United Technologies Corporation Water based silicone coating compositions
JP2832143B2 (en) * 1993-12-28 1998-12-02 信越化学工業株式会社 Silicone fine particles and method for producing the same
JPH11510536A (en) * 1995-08-08 1999-09-14 バイエル・アクチエンゲゼルシヤフト Coating mixture, process for its preparation and its use in coating applications
ES2196179T3 (en) * 1995-09-28 2003-12-16 Corning Inc MATERIAL TO PROVIDE NON-ADHERENT AND NON-WETABLE PROPERTIES.
US5827921A (en) 1995-11-29 1998-10-27 Shin-Etsu Chemical Co., Ltd. Silicone-based aqueous emulsion composition
JP3930591B2 (en) * 1995-12-22 2007-06-13 東陶機器株式会社 Photocatalytic hydrophilic coating composition, method for forming hydrophilic film and coated article
US5868819A (en) 1996-05-20 1999-02-09 Metal Coatings International Inc. Water-reducible coating composition for providing corrosion protection
JP3319353B2 (en) 1996-11-07 2002-08-26 信越化学工業株式会社 Silicone resin-containing emulsion composition, method for producing the same, and article having cured coating of the composition
US5789082A (en) * 1997-03-12 1998-08-04 The Walman Optical Company Thermosetting coating composition
US7192986B2 (en) * 1997-03-12 2007-03-20 Catalysts & Chemicals Industries Co., Ltd. Inorganic compound sol modified by organic compound
DE19816136A1 (en) * 1998-04-09 1999-10-14 Inst Neue Mat Gemein Gmbh Nanostructured moldings and layers and their production via stable water-soluble precursors
JP4116718B2 (en) 1998-11-05 2008-07-09 日本リーロナール有限会社 Electroless gold plating method and electroless gold plating solution used therefor
US20020061407A1 (en) * 1998-12-29 2002-05-23 Colton James P. Abrasion resistant coating composition and coated articles
JP3323455B2 (en) 1999-03-31 2002-09-09 エスエムシー株式会社 Manifold type solenoid valve driven by serial signal
JP4393660B2 (en) 2000-02-29 2010-01-06 日本ペイント株式会社 Non-chromate metal surface treatment agent for PCM, PCM surface treatment method, and treated PCM steel sheet
US6287372B1 (en) 2000-03-31 2001-09-11 Themec Company Incorporated Anti-corrosive coating
US6905772B2 (en) * 2000-05-23 2005-06-14 Triton Systems, Inc. Abrasion and impact resistant coating compositions, and articles coated therewith
EP1191074A1 (en) 2000-09-25 2002-03-27 Sigma Coatings B.V. Water-based two component protective coating compositions
DE10149148B4 (en) 2000-10-11 2006-06-14 Chemetall Gmbh A method of coating metallic surfaces with an aqueous polymer-containing composition, the aqueous composition, and the use of the coated substrates
JP4938167B2 (en) * 2000-10-18 2012-05-23 メタル・コーティングズ・インターナショナル・インコーポレーテッド Water-dilutable coating composition for rust prevention
ATE286097T1 (en) 2000-10-18 2005-01-15 Metal Coatings Int Inc WATER-DILUTIBLE COATING COMPOSITION FOR CORROSION PROTECTION
DE10056344A1 (en) 2000-11-14 2002-05-16 Degussa n-Propylethoxysiloxanes, process for their preparation and their use
US7078076B2 (en) 2001-02-14 2006-07-18 Metal Coatings International Inc. Particulate metal alloy coating for providing corrosion protection
US6939908B1 (en) * 2001-09-17 2005-09-06 Nanopowder Enterprises Inc Optically clear abrasion resistant polymer-ceramic composite coatings
DE10151264A1 (en) * 2001-10-17 2003-04-30 Degussa Aminoalkylalkoxysiloxane-containing mixtures, their preparation and their use
JP2003126775A (en) 2001-10-24 2003-05-07 Nippon Paint Co Ltd Method of forming metallic coating film and metallic coating film

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102012005806A1 (en) 2012-03-22 2013-09-26 Nano-X Gmbh Process for the preparation of a corrosion protection coating
WO2013139599A1 (en) 2012-03-22 2013-09-26 Nano-X Gmbh Method for producing an anticorrosive coating

Also Published As

Publication number Publication date
MEP29508A (en) 2010-06-10
EP1675922A2 (en) 2006-07-05
BRPI0508997A (en) 2007-09-04
EP1675922B1 (en) 2015-06-17
RS20060525A (en) 2008-06-05
IL177980A (en) 2011-06-30
US9011586B2 (en) 2015-04-21
WO2005090502A3 (en) 2005-12-01
US20080234417A1 (en) 2008-09-25
MXPA06010676A (en) 2007-02-21
WO2005090502A2 (en) 2005-09-29
EA200601739A1 (en) 2007-02-27
EA014856B1 (en) 2011-02-28
CA2560335C (en) 2011-06-14
JP5396020B2 (en) 2014-01-22
KR20060131999A (en) 2006-12-20
AU2005223349B2 (en) 2010-03-04
JP2007529588A (en) 2007-10-25
ZA200607038B (en) 2008-07-30
CN1934205A (en) 2007-03-21
KR101257708B1 (en) 2013-04-24
AU2005223349A1 (en) 2005-09-29
IL177980A0 (en) 2006-12-31
HRP20060307A2 (en) 2007-03-31

Similar Documents

Publication Publication Date Title
CA2560335A1 (en) Micro coating comprising siloxanes
CN104059495A (en) Chromium-free passivation solution and preparation method and use thereof, and metal material
CN104059412A (en) Sealing agent and preparation method and use thereof, and hot-dip plated metal material
CN104059501A (en) Anti-rust sealing agent and preparation method and use thereof, and hot-dip plated metal material
JP6057946B2 (en) Rust-proof water-borne paint composition and method for producing
CN104059478A (en) Anticorrosive coating, preparation method and application thereof, and hot-dipped metal material
CN111253826A (en) Water-soluble silicon steel sheet paint and preparation process thereof
CN104059473A (en) Coating composition, preparation method and application thereof, and hot-dipped metal material
CN104059487A (en) Passivation solution and preparation method and use thereof, and metal material
CN105255310A (en) Ceramic corrosion-preventive and abrasion-resistant coating composition containing corrosion inhibitor and preparation method thereof
US20230116499A1 (en) Water based silicone coating compositions
EP3519518B1 (en) Primer coating composition
CN104059488A (en) Preparation method of plating layer waterborne coating, plating layer waterborne coating prepared by method and use of plating layer waterborne coating, and hot-dip plated metal material
CN104059489A (en) Metal surface chemical treatment liquid and preparation method and use thereof, and hot-dip plated metal material
JP2004277521A (en) Coating composition and coated steel product
CN104059484A (en) Anti-rust waterborne paint and preparation method and use thereof, and hot-dip plated metal material
WO2020099916A1 (en) Rust converter
CN112266668A (en) Formula and preparation process of super-hydrophobic transparent finishing varnish
CN104059493A (en) Waterborne protective coating and preparation method and use thereof
CN103788737A (en) Metal protection paint, preparation method, application and hot-dip metal material
CN104059508A (en) Anti-rust surface treatment liquid and preparation method and use thereof
CN103788837A (en) Metal protection paint, preparation method, application and hot-dip metal material
CN104059500A (en) Plating layer-coating paint and preparation method and use thereof, and hot-dip plated metal material
CN104059482A (en) Preparation method of waterborne paint, waterborne paint prepared by method and use of waterborne paint, and hot-dip plated metal material
CN104059483A (en) Plating layer anti-rust protective agent and preparation method and use thereof, and hot-dip plated metal material

Legal Events

Date Code Title Description
EEER Examination request
MKLA Lapsed

Effective date: 20160321