CA2486672C - Electrode catalyst for h2s fuel cell - Google Patents
Electrode catalyst for h2s fuel cell Download PDFInfo
- Publication number
- CA2486672C CA2486672C CA2486672A CA2486672A CA2486672C CA 2486672 C CA2486672 C CA 2486672C CA 2486672 A CA2486672 A CA 2486672A CA 2486672 A CA2486672 A CA 2486672A CA 2486672 C CA2486672 C CA 2486672C
- Authority
- CA
- Canada
- Prior art keywords
- anode
- fuel cell
- ion
- catalytic
- catalyst composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/22—Fuel cells in which the fuel is based on materials comprising carbon or oxygen or hydrogen and other elements; Fuel cells in which the fuel is based on materials comprising only elements other than carbon, oxygen or hydrogen
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
- H01M4/8878—Treatment steps after deposition of the catalytic active composition or after shaping of the electrode being free-standing body
- H01M4/8882—Heat treatment, e.g. drying, baking
- H01M4/8885—Sintering or firing
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
- H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
- H01M8/0662—Treatment of gaseous reactants or gaseous residues, e.g. cleaning
- H01M8/0675—Removal of sulfur
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M2004/8678—Inert electrodes with catalytic activity, e.g. for fuel cells characterised by the polarity
- H01M2004/8684—Negative electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
- H01M2008/1293—Fuel cells with solid oxide electrolytes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
- H01M4/8803—Supports for the deposition of the catalytic active composition
- H01M4/881—Electrolytic membranes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
- H01M4/8825—Methods for deposition of the catalytic active composition
- H01M4/8828—Coating with slurry or ink
- H01M4/8835—Screen printing
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
- H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
- H01M8/0612—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
- H01M8/0637—Direct internal reforming at the anode of the fuel cell
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
- H01M8/124—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the process of manufacturing or by the material of the electrolyte
- H01M8/1246—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the process of manufacturing or by the material of the electrolyte the electrolyte consisting of oxides
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Inert Electrodes (AREA)
- Fuel Cell (AREA)
- Catalysts (AREA)
Abstract
The present invention relates to an anode catalyst for use in the electrochemical oxidation of H~2S to elemental sulfur and water, specifically in a fuel cell having an ion-conducting membrane. The catalyst comprises a material prepared from two or more metal sulfides of the formula MS~x, wherein M is selected from the group consisting of Co, Ni, Fe, Mo, Cu, Cr, W and Mn, and x is between about 1.0 and about 2.5; a conductive material suitable for fuel cell operation; and a porous material. The invention further provides methods of preparing the catalyst, fuel cells comprising the catalyst and methods of electrochemically oxidizing H~2S using the catalyst.
Description
Title: ELECTRODE CATALYST FOR H2S FUEL CELLS
FIELD OF THE INVENTION
The present invention relates to catalysts for ion conducting fuel cells, specifically for the co-generation of elemental sulfur and electrical power from hydrogen sulfide.
BACKGROUND OF THE INVENTION
A majority of fuel cell systems developed to date use hydrogen and oxygen as anode and cathode feed respectively. Although hydrogen has a high energy density, a variety of alternative fuels have been investigated as fuels for transportation fuel cell systems, as they are safer to store and transport. In particular, methanol is the subject of several investigations (Kordesch and Simader, 1996, p. 151). Ammonia or hydrazine each has high power density, but requires safe handling (Kordesch and Simader, 1996, p.
333). Methanol or hydrocarbon fuels can be re-formed to hydrogen for use in standing or mobile power units (Kordesch and Simader, 1996, p. 297; Ziaka and Vasileiadis, 2000; Nakagaki et al., 2000). In each of these cases, the fuel is totally consumed for generation of hydrogen, that is then used to generate electrical power, and all carbon is converted to C02.
In principle, the free energy change for any chemical reaction can be converted to electrical energy in an oxide ion conducting fuel cell (Scheme 1), if the required characteristics are present. A similar set of equations can be drawn for a fuel cell having a proton conducting membrane (Scheme 2), such as polymer electrolyte membrane fuel cells (PEMFC). In each case, suitable anode and cathode materials must be used to catalyze reactions 1 and 2.
Partial oxidation of XH2 to X thereby provides free energy recoverable as electrical power.
Scheme I
1. anode XH2 + 02" -- X+ H20 + 2 e 2. cathode 02 + 4 e" -- 202"
FIELD OF THE INVENTION
The present invention relates to catalysts for ion conducting fuel cells, specifically for the co-generation of elemental sulfur and electrical power from hydrogen sulfide.
BACKGROUND OF THE INVENTION
A majority of fuel cell systems developed to date use hydrogen and oxygen as anode and cathode feed respectively. Although hydrogen has a high energy density, a variety of alternative fuels have been investigated as fuels for transportation fuel cell systems, as they are safer to store and transport. In particular, methanol is the subject of several investigations (Kordesch and Simader, 1996, p. 151). Ammonia or hydrazine each has high power density, but requires safe handling (Kordesch and Simader, 1996, p.
333). Methanol or hydrocarbon fuels can be re-formed to hydrogen for use in standing or mobile power units (Kordesch and Simader, 1996, p. 297; Ziaka and Vasileiadis, 2000; Nakagaki et al., 2000). In each of these cases, the fuel is totally consumed for generation of hydrogen, that is then used to generate electrical power, and all carbon is converted to C02.
In principle, the free energy change for any chemical reaction can be converted to electrical energy in an oxide ion conducting fuel cell (Scheme 1), if the required characteristics are present. A similar set of equations can be drawn for a fuel cell having a proton conducting membrane (Scheme 2), such as polymer electrolyte membrane fuel cells (PEMFC). In each case, suitable anode and cathode materials must be used to catalyze reactions 1 and 2.
Partial oxidation of XH2 to X thereby provides free energy recoverable as electrical power.
Scheme I
1. anode XH2 + 02" -- X+ H20 + 2 e 2. cathode 02 + 4 e" -- 202"
3. overall 2XH2 (fuel) + 02 --- X (product) + 2H20 Scheme 2 1. anode XH2 -- X+ 2H+ + 2 e 2. cathode 02 + 4H+ + 4 e 2H20 3. overall 2XH2 (fuel) + 02 --- X (product) + 2H20 Any reaction in which a fuel (XH2 in Eqns. 1 and 3, Schemes I and 2) is oxidized to a value-added product (X in Eqns I and 3, Schemes 1 and 2) and energy, is a potential candidate for application in a fuel cell for co-generation of chemicals and power. One example of such a process is the production of sulfur from hydrogen sulfide.
Potential benefits from use of fuel cell technology for production of chemicals include improved selectivity and efficiency. An economic advantage is that there is a negative cost of feed for production of electrical power, as the cost of fuel is more than offset by the value of the product. In the case of conversion of H2S, the value of sulfur is not great. However, in this case use of a fuel cell-based process offers the potential economic advantage of reduced cost of treatment of sour gas streams. For other systems, for example when hydrocarbons are converted to products of significantly higher value, reduced cost for manufacturing the product can provide an economic incentive (Mazanec and Cable, 1990; Michaels and Vayenas, 1984; Petrovic et al., 2001; White et al., 2001).
H2S is a toxic and highiy reactive pollutant. Removal of H2S from natural gas and process streams is costly. The energy generated by oxidation of H2S to either sulfur, as in the Claus process, or SOx by combustion, is either vented or partiy recovered as low-grade heat (Chuang and Sanger, 2000). There is a ciear economic benefit to recovery of the heat of reaction of H2S to elemental sulfur as high-grade electrical energy.
Experimental SOFC's are known in which hydrogen sulfide can be oxidized; however no catalysts have yet been developed that are sufficiently active for fuel cell applications. In fact there are, at present, no commercial fuel cells for the production of sulfur from hydrogen sulfide.
SUMMARY OF THE INVENTION
The present inventors have shown that admixing a suitable conductive material, such as metallic silver (Ag), with a metal sulfide-based anode catalyst and then mixing this composite anode catalyst with about 5% of an oxide ion-conducting porous material, such as yttria-stabilized zirconia (YSZ), provides a composite anode catalyst which significantly improves performance of an H2S-02 fuel cell having an oxide ion-conducting membrane. The catalyst will also work in a fuel cell having a proton ion-conducting membrane.
Accordingly, the present invention relates to an anode catalyst composition for a gas phase H2S-02 fuel cell having an ion-conducting membrane comprising:
(a) two or more metal sulfides of the formula MS,,, wherein M is selected from the group consisting of Co, Ni, Fe, Mo, Cu, Cr, W
and Mn, and x is between about 1.0 and about 2.5;
(b) a conductive material suitable for fuel cell operation; and (c) an ion-conducting porous material, wherein both of (b) and (c) are present in the composition in amounts up to about 10% by weight of the composition. A preferred ratio of (a):(b):(c) is about 90:5:5.
In a further aspect of the present invention there is provided a method of preparing an anode catalyst composition for a gas phase H2S-02 fuel cell having an ion-conducting membrane comprising:
Potential benefits from use of fuel cell technology for production of chemicals include improved selectivity and efficiency. An economic advantage is that there is a negative cost of feed for production of electrical power, as the cost of fuel is more than offset by the value of the product. In the case of conversion of H2S, the value of sulfur is not great. However, in this case use of a fuel cell-based process offers the potential economic advantage of reduced cost of treatment of sour gas streams. For other systems, for example when hydrocarbons are converted to products of significantly higher value, reduced cost for manufacturing the product can provide an economic incentive (Mazanec and Cable, 1990; Michaels and Vayenas, 1984; Petrovic et al., 2001; White et al., 2001).
H2S is a toxic and highiy reactive pollutant. Removal of H2S from natural gas and process streams is costly. The energy generated by oxidation of H2S to either sulfur, as in the Claus process, or SOx by combustion, is either vented or partiy recovered as low-grade heat (Chuang and Sanger, 2000). There is a ciear economic benefit to recovery of the heat of reaction of H2S to elemental sulfur as high-grade electrical energy.
Experimental SOFC's are known in which hydrogen sulfide can be oxidized; however no catalysts have yet been developed that are sufficiently active for fuel cell applications. In fact there are, at present, no commercial fuel cells for the production of sulfur from hydrogen sulfide.
SUMMARY OF THE INVENTION
The present inventors have shown that admixing a suitable conductive material, such as metallic silver (Ag), with a metal sulfide-based anode catalyst and then mixing this composite anode catalyst with about 5% of an oxide ion-conducting porous material, such as yttria-stabilized zirconia (YSZ), provides a composite anode catalyst which significantly improves performance of an H2S-02 fuel cell having an oxide ion-conducting membrane. The catalyst will also work in a fuel cell having a proton ion-conducting membrane.
Accordingly, the present invention relates to an anode catalyst composition for a gas phase H2S-02 fuel cell having an ion-conducting membrane comprising:
(a) two or more metal sulfides of the formula MS,,, wherein M is selected from the group consisting of Co, Ni, Fe, Mo, Cu, Cr, W
and Mn, and x is between about 1.0 and about 2.5;
(b) a conductive material suitable for fuel cell operation; and (c) an ion-conducting porous material, wherein both of (b) and (c) are present in the composition in amounts up to about 10% by weight of the composition. A preferred ratio of (a):(b):(c) is about 90:5:5.
In a further aspect of the present invention there is provided a method of preparing an anode catalyst composition for a gas phase H2S-02 fuel cell having an ion-conducting membrane comprising:
(a) combining two or more metal sulfides of the formula MS, wherein M is selected from the group consisting of Co, Ni, Fe, Mo, Cu, Cr, W and Mn and x is between about 1.0 and about 2.5, with a conductive material suitable for fuel cell operation; and (b) combining the combination of (a) with an ion-conducting porous material, wherein both of the conductive material and porous material are present in the composition in amounts up to about 10% by weight of the composition.
The present invention further relates to a fuel cell for the electrochemical oxidation of H2S to sulfur and water comprising an anode chamber on one side of an ion-conducting membrane and a cathode chamber on the opposing side of the ion-conducting membrane, said anode chamber having a catalytic anode and said cathode chamber having a catalytic cathode wherein said anode comprises a catalyst as defined above.
In an embodiment, the present invention further provides a process for the electrochemical oxidation of H2S to suifur and water using a fuel cell having an anode chamber on one side of an oxide ion-conducting membrane and a cathode chamber on the opposing side of the membrane comprising the steps of:
(1) passing an H2S-containing gas through the anode chamber to contact a catalytic anode, where it reacts with oxide ions to produce elemental sulfur, water and electrons;
(2) passing oxide ions through the membrane from the cathode chamber to the anode chamber; and (3) passing an oxygen-containing gas through the cathode chamber to contact the cataiytic cathode, where it reacts with electrons to produce oxide ions, wherein said catalytic anode comprises a catalyst as defined above.
In a further embodiment, the present invention includes a process for the electrochemical oxidation of H2S to sulfur and water using a fuel cell having an anode chamber on one side of a proton ion-conducting membrane and a cathode chamber on the opposing side of the membrane comprising the steps of:
(1) passing an H2S-containing gas through the anode chamber to contact a catalytic anode, where it reacts with oxide ions to produce elemental suifur, protons and electrons;
(2) passing protons through the membrane from the cathode chamber to the anode chamber; and (3) passing an oxygen-containing gas through the cathode chamber to contact the catalytic cathode, where it reacts with protons and electrons to produce water or steam, or forming hydrogen in the cathode chamber, wherein said catalytic anode comprises a catalyst as defined above.
The present invention satisfies the need for an active and long-lived anode catalyst for H2S/02 fuel cells. The anode catalyst of the present invention is stable enough to be used at temperatures that allow the formation of sulfur vapour at the catalyst sites, avoiding formation of liquid sulfur at the surface and consequent blockage of access to catalytic sites, thereby leading to higher long term efficiency.
Other features and advantages of the present invention will become apparent from the following detailed description. It should be understood, however, that the detailed description and the specific examples while indicating preferred embodiments of the invention are given by way of illustration only, since various changes and modifications within the spirit and scope of the invention will become apparent to those skilled in the art from this detailed description.
BRIEF DESCRIPTION OF THE DRAWINGS
The invention will now be described in relation to the drawings in which:
Figure 1 is a graph of voltage as a function of current density for a fuel cell uitlizing the anode catalyst of Example 1.
Figure 2 is a graph of power density versus current density for a fuel cell uitlizing the anode cataiyst of Example 1.
The present invention further relates to a fuel cell for the electrochemical oxidation of H2S to sulfur and water comprising an anode chamber on one side of an ion-conducting membrane and a cathode chamber on the opposing side of the ion-conducting membrane, said anode chamber having a catalytic anode and said cathode chamber having a catalytic cathode wherein said anode comprises a catalyst as defined above.
In an embodiment, the present invention further provides a process for the electrochemical oxidation of H2S to suifur and water using a fuel cell having an anode chamber on one side of an oxide ion-conducting membrane and a cathode chamber on the opposing side of the membrane comprising the steps of:
(1) passing an H2S-containing gas through the anode chamber to contact a catalytic anode, where it reacts with oxide ions to produce elemental sulfur, water and electrons;
(2) passing oxide ions through the membrane from the cathode chamber to the anode chamber; and (3) passing an oxygen-containing gas through the cathode chamber to contact the cataiytic cathode, where it reacts with electrons to produce oxide ions, wherein said catalytic anode comprises a catalyst as defined above.
In a further embodiment, the present invention includes a process for the electrochemical oxidation of H2S to sulfur and water using a fuel cell having an anode chamber on one side of a proton ion-conducting membrane and a cathode chamber on the opposing side of the membrane comprising the steps of:
(1) passing an H2S-containing gas through the anode chamber to contact a catalytic anode, where it reacts with oxide ions to produce elemental suifur, protons and electrons;
(2) passing protons through the membrane from the cathode chamber to the anode chamber; and (3) passing an oxygen-containing gas through the cathode chamber to contact the catalytic cathode, where it reacts with protons and electrons to produce water or steam, or forming hydrogen in the cathode chamber, wherein said catalytic anode comprises a catalyst as defined above.
The present invention satisfies the need for an active and long-lived anode catalyst for H2S/02 fuel cells. The anode catalyst of the present invention is stable enough to be used at temperatures that allow the formation of sulfur vapour at the catalyst sites, avoiding formation of liquid sulfur at the surface and consequent blockage of access to catalytic sites, thereby leading to higher long term efficiency.
Other features and advantages of the present invention will become apparent from the following detailed description. It should be understood, however, that the detailed description and the specific examples while indicating preferred embodiments of the invention are given by way of illustration only, since various changes and modifications within the spirit and scope of the invention will become apparent to those skilled in the art from this detailed description.
BRIEF DESCRIPTION OF THE DRAWINGS
The invention will now be described in relation to the drawings in which:
Figure 1 is a graph of voltage as a function of current density for a fuel cell uitlizing the anode catalyst of Example 1.
Figure 2 is a graph of power density versus current density for a fuel cell uitlizing the anode cataiyst of Example 1.
Figure 3 is a graph of voltage as a function of current density for a fuel cell uitlizing the anode catalyst of Example 2.
Figure 4 is a graph of power density versus current density for a fuel cell uitlizing the anode catalyst of Example 2.
Figure 5 is a graph of voltage as a function of current density for a fuel cell uitlizing the anode catalyst of Example 3.
Figure 6 is a graph of power density versus current density for a fuel cell uitlizing the anode catalyst of Example 3.
Figure 7 is a graph of voltage as a function of current density for a fuel cell uitlizing the anode catalyst of Example 4.
Figure 8 is a graph of power density versus current density for a fuel cell uitlizing the anode catalyst of Example 4.
Figure 9 is a graph of voltage as a function of current density for a fuel cell uitlizing the anode catalyst of Example 5.
Figure 10 is a graph of power density versus current density for a fuel cell uitlizing the anode catalyst of Example 5.
DETAILED DESCRIPTION OF THE INVENTION
The present inventors have performed systematic research on the development of optimum anode catalyst designs for gas phase H2S-02 fuel cells having either a proton or oxide ion-conducting membrane. It has been found that by admixing a suitable conductive material, such as metallic silver (Ag), with a mixed-metal sulfide-based anode cataiyst, and then mixing this composite anode catalyst with about 5% of an oxide ion-conducting porous material, such as yttria-stabilized zirconia (YSZ), significant improvements in the performance of a H2S-02 fuel cell having an oxide ion-conducting membrane can be achieved.
Accordingly, the present invention relates to an anode catalyst composition for a gas phase H2S-02 fuel cell having an ion-conducting membrane comprising:
Figure 4 is a graph of power density versus current density for a fuel cell uitlizing the anode catalyst of Example 2.
Figure 5 is a graph of voltage as a function of current density for a fuel cell uitlizing the anode catalyst of Example 3.
Figure 6 is a graph of power density versus current density for a fuel cell uitlizing the anode catalyst of Example 3.
Figure 7 is a graph of voltage as a function of current density for a fuel cell uitlizing the anode catalyst of Example 4.
Figure 8 is a graph of power density versus current density for a fuel cell uitlizing the anode catalyst of Example 4.
Figure 9 is a graph of voltage as a function of current density for a fuel cell uitlizing the anode catalyst of Example 5.
Figure 10 is a graph of power density versus current density for a fuel cell uitlizing the anode catalyst of Example 5.
DETAILED DESCRIPTION OF THE INVENTION
The present inventors have performed systematic research on the development of optimum anode catalyst designs for gas phase H2S-02 fuel cells having either a proton or oxide ion-conducting membrane. It has been found that by admixing a suitable conductive material, such as metallic silver (Ag), with a mixed-metal sulfide-based anode cataiyst, and then mixing this composite anode catalyst with about 5% of an oxide ion-conducting porous material, such as yttria-stabilized zirconia (YSZ), significant improvements in the performance of a H2S-02 fuel cell having an oxide ion-conducting membrane can be achieved.
Accordingly, the present invention relates to an anode catalyst composition for a gas phase H2S-02 fuel cell having an ion-conducting membrane comprising:
(a) two or more metal sulfides of the formula MS,,, wherein M is selected from the group consisting of Co, Ni, Fe, Mo, Cu, Cr, W
and Mn, and x is between about 1.0 and about 2.5;
(b) a conductive material suitable for fuel cell operation; and (c) an ion-conducting porous material, wherein both of the conductive material and the porous material are present in the composition in amounts up to about 10% by weight of the composition.
In embodiments of the invention, the fuel cell has an oxide ion conducting membrane or a proton ion conducting membrane. In preferred embodiments, the fuel cell has an oxide ion conducting membrane. When the fuel cell has an oxide ion-conducting membrane, an oxide ion-conducting porous material is used. Similarly, when the fuel cell has a proton ion-conducting membrane, a proton ion-conducting porous material is used.
As stated above, the anode catalyst comprises a mixed metal sulfide comprising two or more metal sulfides of the formula MSX, wherein M is selected from the group consisting of Co, Ni, Fe, Mo, Cu, Cr, W and Mn, and x is between about 1.0 and about 2.5. In embodiments of the present invention, M is selected from the group consisting of Co, Ni, Fe, Mo, W and Mn. In a further embodiment of the present invention, the anode catalyst comprises two metal sulfides of the formula MSx wherein M is selected from the group consisting of Co, Ni, Fe, Mo, Cu, Cr, W and Mn, and x is between about 1.0 and about 2.5. In a specific embodiment, the anode catalyst comprises two metal sulfides, with one metal sulfide having M selected from the group consisting of Co, Ni and Fe and the second metal sulfide having M
selected from the group consisting of Mo and W. In another embodiment of the present invention, the catalyst comprises NiS and MoS2.
The mixed metal sulfide may be prepared by combining two or more metal sulfides, preferably in approximately equivalent amounts by weight. It will be recognized that the mixed metal sulfide may be formed by partially or completely sulfiding corresponding mixed metal oxides or similar compounds.
The conductive material may be any such material that is stable under the operating conditions required for the electrochemical oxidation of H2S.
and Mn, and x is between about 1.0 and about 2.5;
(b) a conductive material suitable for fuel cell operation; and (c) an ion-conducting porous material, wherein both of the conductive material and the porous material are present in the composition in amounts up to about 10% by weight of the composition.
In embodiments of the invention, the fuel cell has an oxide ion conducting membrane or a proton ion conducting membrane. In preferred embodiments, the fuel cell has an oxide ion conducting membrane. When the fuel cell has an oxide ion-conducting membrane, an oxide ion-conducting porous material is used. Similarly, when the fuel cell has a proton ion-conducting membrane, a proton ion-conducting porous material is used.
As stated above, the anode catalyst comprises a mixed metal sulfide comprising two or more metal sulfides of the formula MSX, wherein M is selected from the group consisting of Co, Ni, Fe, Mo, Cu, Cr, W and Mn, and x is between about 1.0 and about 2.5. In embodiments of the present invention, M is selected from the group consisting of Co, Ni, Fe, Mo, W and Mn. In a further embodiment of the present invention, the anode catalyst comprises two metal sulfides of the formula MSx wherein M is selected from the group consisting of Co, Ni, Fe, Mo, Cu, Cr, W and Mn, and x is between about 1.0 and about 2.5. In a specific embodiment, the anode catalyst comprises two metal sulfides, with one metal sulfide having M selected from the group consisting of Co, Ni and Fe and the second metal sulfide having M
selected from the group consisting of Mo and W. In another embodiment of the present invention, the catalyst comprises NiS and MoS2.
The mixed metal sulfide may be prepared by combining two or more metal sulfides, preferably in approximately equivalent amounts by weight. It will be recognized that the mixed metal sulfide may be formed by partially or completely sulfiding corresponding mixed metal oxides or similar compounds.
The conductive material may be any such material that is stable under the operating conditions required for the electrochemical oxidation of H2S.
Examples of metals and metal oxides useful as a conductive material would be well known to those skilled in the art and include silver, gold, nickel, bismuth, manganese, vanadium, platinum, rhodium, ruthenium, palladium, copper, zinc, cobalt, chromium, and iron metals and metal oxides, any mixtures of said metals and metal oxides, and other mixtures such as silver-bismuth oxide mixtures, tin-indium oxide mixtures, praeseodymium-indium oxide mixtures, cerium-lanthanum oxide mixtures, etc., and mixtures thereof.
Among these, silver is preferred.
The ion-conducting porous material may be any such material that does not interfere with the reaction process. Examples of porous materials which are known to be ion-conducting are well known in the art. Porous materials known to be oxide-ion conducting include, but are not limited to, any of a large number of oxides, including yttria-stabilized zirconia (YSZ), doped ceria, thoria-based materials, or doped bismuth oxides and various other metal oxides. Specific examples include, but are not limited to CaO-stabilized Zr02; Y203-stabilized Zr02; Sc203-stabilized Zr02; Y203-stabilized Bi203;
Y203-stabilized CeO2; CaO-stabilized Ce02; Th02; Y203-stabilized Th02;
Th02, Zr02, Bi20, Ce02 or Hf02 stabilized by the addition of any one of the lanthanide oxides or CaO; and A1203. A preferred oxide ion-conducting porous material is yttria-stabilized zirconia (YSZ). Examples of proton ion-conducting porous materials are also well known, and include, but are not limited to, beta-alumina, lithium sulfate, and mixed or doped metal oxide systems. An example of a fuel cell for conversion of hydrogen sulfide having lithium sulfate as a proton-conducting membrane is described by Peterson and Winnick in the Journal of the Electrochemical Society (1996). Other materials which are conducting to both proton and oxide ions are also included within the scope of the present invention.
The amount of both of the conductive material and the porous material in the anode catalyst composition of the present invention may be up to about 10% by weight of the final composition. In embodiments of the invention the ratio of metal sulfide:conductive material:porous material in the anode catalyst composition of the present invention is about 90:5:5, more specifically, about 90.25:4.75:5. Unless otherwise stated, all ratios and percentages described herein are based on weight (w/w).
In an embodiment of the present invention, the anode catalyst composition is prepared by first combining the metal sulfides and then combining the mixed metal sulfides with the conducting material to provide a composite anode catalyst. This composite metal catalyst is then combined with the porous material.
Accordingly, there is provided a method of preparing an anode catalyst composition for a gas phase HZS-02 fuel cell having an ion-conducting membrane comprising:
(a) combining two or more metal sulfides of the formula MSx, wherein M is selected from the group consisting of Co, Ni, Fe, Mo, Cu, Cr, W and Mn and x is between about 1.0 and about 2.5, with a conductive material suitable for fuel cell operation; and (b) combining the combination of (a) with an ion-conducting porous material, wherein both of the conductive material and the porous material are present in the composition in amounts up to about 10% by weight of the composition.
The catalyst compositions of the present invention are typically applied to a surface on a material, for example, an ion-conducting ceramic membrane, in the form of a paste. Other methods for applying the catalyst to a surface may be used and are well known to those skilled in the art. To prepare a paste, the compositions may be combined with a fluid. Suitable fluids include those which will allow dispersion of the cataiyst without affecting its composition, not dissolve too much of the catalyst, remain in place for the period of mixing, be not too viscous and be removable by volatolization without deieterious effects during the drying stages. An example of a suitable fluid is a-terpeniol. Prior to installation or use in a fuel cell, the anode catalyst, once applied to the material, is preferably heated to temperatures in the range of about 950 C to about 1200 C for a time period in the range of about 10 minutes to about 150 minutes in an inert atmosphere (for example in an atmosphere of nitrogen or argon). The temperature should be kept below that which will cause the catalyst to decompose or sinter. It has been found that, for the composite catalyst described herein, heating to a temperature in the range of about 1000 C to about 1100 C for about 30 minutes is suitable.
Heating of the catalyst compositions under these conditions results in the formation of a new material comprising the two or more metal sulfides, said material being less volatile than the individual metal sulfides.
Accordingly, in embodiments of the present invention, the method of preparing an anode catalyst composition for a gas phase H2S-02 fuel cell having an ion-conducting membrane further comprises the steps of:
(c) forming the composition into a paste;
(d) applying the paste to a surface of a material; and (e) heating the material to a temperature in the range of about 950 C
to about 1200 C, for a time in the range of about 10 minutes to about 150 minutes, in an inert atmosphere.
For use in a gas phase H2S-02 fuel cell, a cathode catalyst is applied to the opposing surface of the material. The cathode catalyst may be applied to the opposing surface of the material prior to or after the application of the anode catalyst. In embodiments, the cathode catalyst is applied to the opposing surface of the material prior to the application of the anode catalyst.
The term "material" as used herein refers to any suitable dense solid ion-conducting material, the shape of which will depend on the specific application and materials involved. Such materials are known to those skilled in the art.
The present invention further relates to a fuel cell for the electrochemical oxidation of H2S to sulfur and water comprising an anode chamber on one side of an ion-conducting membrane and a cathode chamber on the opposing side of the ion-conducting membrane, said anode chamber having an catalytic anode and said cathode chamber having a catalytic cathode wherein said anode comprises a catalyst comprising:
(a) two or more metal suifides of the formula MSX, wherein M is selected from the group consisting of Co, Ni, Fe, Mo, Cu, Cr, W
and Mn, and x is between about 1.0 and about 2.5;
(b) a conductive material suitable for fuel cell operation; and (c) an ion-conducting porous material, wherein both of the conductive material and the porous material are present in the composition in amounts up to about 10% by weight of the composition.
The present inventors have prepared an example of an anode catalyst according to the invention and have shown that it has significantly improved performance when- used in an electrochemical fuel cell for the oxidation of to sulfur and water.
The present invention further relates to processes for the electrochemical oxidation of H2S to sulfur and water using a fuel cell having an anode chamber on one side of an ion-conducting membrane, for example an oxide ion-conducting membrane or a proton ion-conducting membrane, and a cathode chamber on the opposing side of the membrane. When the fuel cell has an oxide ion-conducting membrane, this method comprises:
(1) passing an H2S-containing gas through the anode chamber to contact a catalytic anode, where it reacts to produce elemental sulfur, water and electrons;
(2) passing oxide ions through the membrane from the cathode chamber to the anode chamber; and (3) passing an oxygen-containing gas through the cathode chamber to contact the catalytic cathode, where it reacts with electrons to produce oxide ions in the cathode chamber, wherein said catalytic anode'comprises a catalyst comprising (a) two or more metal sulfides of the formula MSX, wherein M is selected from the group consisting of Co, Ni, Fe, Mo, Cu, Cr, W
and Mn, and x is between about 1.0 and about 2.5;
(b) a conductive material suitable for fuel cell operation; and (c) an oxide ion-conducting porous material, wherein both of the conductive material and the porous material are present in the composition in amounts up to about 10% by weight of the composition.
When the fuel cell has an proton ion-conducting membrane, this method comprises:
Among these, silver is preferred.
The ion-conducting porous material may be any such material that does not interfere with the reaction process. Examples of porous materials which are known to be ion-conducting are well known in the art. Porous materials known to be oxide-ion conducting include, but are not limited to, any of a large number of oxides, including yttria-stabilized zirconia (YSZ), doped ceria, thoria-based materials, or doped bismuth oxides and various other metal oxides. Specific examples include, but are not limited to CaO-stabilized Zr02; Y203-stabilized Zr02; Sc203-stabilized Zr02; Y203-stabilized Bi203;
Y203-stabilized CeO2; CaO-stabilized Ce02; Th02; Y203-stabilized Th02;
Th02, Zr02, Bi20, Ce02 or Hf02 stabilized by the addition of any one of the lanthanide oxides or CaO; and A1203. A preferred oxide ion-conducting porous material is yttria-stabilized zirconia (YSZ). Examples of proton ion-conducting porous materials are also well known, and include, but are not limited to, beta-alumina, lithium sulfate, and mixed or doped metal oxide systems. An example of a fuel cell for conversion of hydrogen sulfide having lithium sulfate as a proton-conducting membrane is described by Peterson and Winnick in the Journal of the Electrochemical Society (1996). Other materials which are conducting to both proton and oxide ions are also included within the scope of the present invention.
The amount of both of the conductive material and the porous material in the anode catalyst composition of the present invention may be up to about 10% by weight of the final composition. In embodiments of the invention the ratio of metal sulfide:conductive material:porous material in the anode catalyst composition of the present invention is about 90:5:5, more specifically, about 90.25:4.75:5. Unless otherwise stated, all ratios and percentages described herein are based on weight (w/w).
In an embodiment of the present invention, the anode catalyst composition is prepared by first combining the metal sulfides and then combining the mixed metal sulfides with the conducting material to provide a composite anode catalyst. This composite metal catalyst is then combined with the porous material.
Accordingly, there is provided a method of preparing an anode catalyst composition for a gas phase HZS-02 fuel cell having an ion-conducting membrane comprising:
(a) combining two or more metal sulfides of the formula MSx, wherein M is selected from the group consisting of Co, Ni, Fe, Mo, Cu, Cr, W and Mn and x is between about 1.0 and about 2.5, with a conductive material suitable for fuel cell operation; and (b) combining the combination of (a) with an ion-conducting porous material, wherein both of the conductive material and the porous material are present in the composition in amounts up to about 10% by weight of the composition.
The catalyst compositions of the present invention are typically applied to a surface on a material, for example, an ion-conducting ceramic membrane, in the form of a paste. Other methods for applying the catalyst to a surface may be used and are well known to those skilled in the art. To prepare a paste, the compositions may be combined with a fluid. Suitable fluids include those which will allow dispersion of the cataiyst without affecting its composition, not dissolve too much of the catalyst, remain in place for the period of mixing, be not too viscous and be removable by volatolization without deieterious effects during the drying stages. An example of a suitable fluid is a-terpeniol. Prior to installation or use in a fuel cell, the anode catalyst, once applied to the material, is preferably heated to temperatures in the range of about 950 C to about 1200 C for a time period in the range of about 10 minutes to about 150 minutes in an inert atmosphere (for example in an atmosphere of nitrogen or argon). The temperature should be kept below that which will cause the catalyst to decompose or sinter. It has been found that, for the composite catalyst described herein, heating to a temperature in the range of about 1000 C to about 1100 C for about 30 minutes is suitable.
Heating of the catalyst compositions under these conditions results in the formation of a new material comprising the two or more metal sulfides, said material being less volatile than the individual metal sulfides.
Accordingly, in embodiments of the present invention, the method of preparing an anode catalyst composition for a gas phase H2S-02 fuel cell having an ion-conducting membrane further comprises the steps of:
(c) forming the composition into a paste;
(d) applying the paste to a surface of a material; and (e) heating the material to a temperature in the range of about 950 C
to about 1200 C, for a time in the range of about 10 minutes to about 150 minutes, in an inert atmosphere.
For use in a gas phase H2S-02 fuel cell, a cathode catalyst is applied to the opposing surface of the material. The cathode catalyst may be applied to the opposing surface of the material prior to or after the application of the anode catalyst. In embodiments, the cathode catalyst is applied to the opposing surface of the material prior to the application of the anode catalyst.
The term "material" as used herein refers to any suitable dense solid ion-conducting material, the shape of which will depend on the specific application and materials involved. Such materials are known to those skilled in the art.
The present invention further relates to a fuel cell for the electrochemical oxidation of H2S to sulfur and water comprising an anode chamber on one side of an ion-conducting membrane and a cathode chamber on the opposing side of the ion-conducting membrane, said anode chamber having an catalytic anode and said cathode chamber having a catalytic cathode wherein said anode comprises a catalyst comprising:
(a) two or more metal suifides of the formula MSX, wherein M is selected from the group consisting of Co, Ni, Fe, Mo, Cu, Cr, W
and Mn, and x is between about 1.0 and about 2.5;
(b) a conductive material suitable for fuel cell operation; and (c) an ion-conducting porous material, wherein both of the conductive material and the porous material are present in the composition in amounts up to about 10% by weight of the composition.
The present inventors have prepared an example of an anode catalyst according to the invention and have shown that it has significantly improved performance when- used in an electrochemical fuel cell for the oxidation of to sulfur and water.
The present invention further relates to processes for the electrochemical oxidation of H2S to sulfur and water using a fuel cell having an anode chamber on one side of an ion-conducting membrane, for example an oxide ion-conducting membrane or a proton ion-conducting membrane, and a cathode chamber on the opposing side of the membrane. When the fuel cell has an oxide ion-conducting membrane, this method comprises:
(1) passing an H2S-containing gas through the anode chamber to contact a catalytic anode, where it reacts to produce elemental sulfur, water and electrons;
(2) passing oxide ions through the membrane from the cathode chamber to the anode chamber; and (3) passing an oxygen-containing gas through the cathode chamber to contact the catalytic cathode, where it reacts with electrons to produce oxide ions in the cathode chamber, wherein said catalytic anode'comprises a catalyst comprising (a) two or more metal sulfides of the formula MSX, wherein M is selected from the group consisting of Co, Ni, Fe, Mo, Cu, Cr, W
and Mn, and x is between about 1.0 and about 2.5;
(b) a conductive material suitable for fuel cell operation; and (c) an oxide ion-conducting porous material, wherein both of the conductive material and the porous material are present in the composition in amounts up to about 10% by weight of the composition.
When the fuel cell has an proton ion-conducting membrane, this method comprises:
(1) passing an H2S-containing gas through the anode chamber to contact a catalytic anode, where it reacts to produce elemental sulfur, protons and electrons;
(2) passing protons through the membrane from the anode chamber to the cathode chamber; and (3) passing an oxygen-containing gas through the cathode chamber to contact the catalytic cathode, where it reacts with protons and electrons to produce water in the cathode chamber, wherein said catalytic anode comprises a catalyst comprising (a) two or more metal sulfides of the formula MSx, wherein M is selected from the group consisting of Co, Ni, Fe, Mo, Cu, Cr, W
and Mn, and x is between about 1.0 and about 2.5;
(b) a conductive material suitable for fuel cell operation; and (c) a proton ion-conducting porous material, wherein both of the conductive material and the porous material are present in the composition in amounts up to about 10% by weight of the composition.
It is known that polymer-based proton-conducting fuel cells utilizing H2S operating in the temperature range of 120-145 C produce liquid sulfur and electrical power. Recovery of liquid sulfur from the cells is difficult.
If liquid sulfur is allowed to build up within the cell, the operation of the cell is compromised. A cell operating in the sulfur vapour range offers the advantage that sulfur more readily exits the cell, and therefore offers the advantage that operation is not compromised by sulfur build up. When liquid sulfur forms at the anode surface, mass transfer resistance to hydrogen sulfide accessing the catalytic sites is thereby increased, resulting in reduced efficiency.
Accordingly, it has been found that the most effective method of operating the fuel cell of the present invention is at temperatures above the vapour point of sulfur, i.e. in the range over 444 C at one atmosphere pressure, and preferably in the range of about 700 C to about 1000 C, more preferably in the range of about 750 C to about 850 C.
(2) passing protons through the membrane from the anode chamber to the cathode chamber; and (3) passing an oxygen-containing gas through the cathode chamber to contact the catalytic cathode, where it reacts with protons and electrons to produce water in the cathode chamber, wherein said catalytic anode comprises a catalyst comprising (a) two or more metal sulfides of the formula MSx, wherein M is selected from the group consisting of Co, Ni, Fe, Mo, Cu, Cr, W
and Mn, and x is between about 1.0 and about 2.5;
(b) a conductive material suitable for fuel cell operation; and (c) a proton ion-conducting porous material, wherein both of the conductive material and the porous material are present in the composition in amounts up to about 10% by weight of the composition.
It is known that polymer-based proton-conducting fuel cells utilizing H2S operating in the temperature range of 120-145 C produce liquid sulfur and electrical power. Recovery of liquid sulfur from the cells is difficult.
If liquid sulfur is allowed to build up within the cell, the operation of the cell is compromised. A cell operating in the sulfur vapour range offers the advantage that sulfur more readily exits the cell, and therefore offers the advantage that operation is not compromised by sulfur build up. When liquid sulfur forms at the anode surface, mass transfer resistance to hydrogen sulfide accessing the catalytic sites is thereby increased, resulting in reduced efficiency.
Accordingly, it has been found that the most effective method of operating the fuel cell of the present invention is at temperatures above the vapour point of sulfur, i.e. in the range over 444 C at one atmosphere pressure, and preferably in the range of about 700 C to about 1000 C, more preferably in the range of about 750 C to about 850 C.
The following non-limiting examples are illustrative of the present invention:
EXAMPLES
Materials and Methods (i) Equipment:
Two types of laboratory fuel cells have been used to study the reactions described herein. In each case the membrane electrode assembly (MEA) has planar geometry. However, it will be recognized by one skilled in the art that an alternative geometry may be used. Reactions at atmospheric pressure were performed using a reactor assembly comprising a Pyrex holder for the MEA situated between the anode and cathode chambers. The anode and cathode chambers each had concentric tubes, the inner tube serving as feed tubes and the other tubes serving as tailing gas tubes, as described by Liu et al. (2001). Reactions at elevated pressures were performed in a stainless steel cell substantially similar to that described by Chuang et al.
(2001).
(ii) Membranes:
MEA for use at elevated temperatures (up to 900 C) comprised anode and cathode catalysts screen-printed onto oxide ion-conducting ceramic membranes. The membrane was either yttria-stabilized zirconia (YSZ, 8%Y203) or YSZ having a sub-micron interlayer of Ti02 applied as a sol (Kueper et al., 1992) to the anode face of the YSZ membrane before application of anode catalyst. The MEA so prepared were gradually heated (3 C/min) to 1050 C (YSZ) or 900 C (Ti02/YSZ) and then held at that temperature to remove organics in the paste and to increase adhesion of the electrodes to the membrane.
Platinum meshes were used as anode current collectors and platinum wire was used as cathode current collectors.
(ii) Electrical Measurements:
Open circuit potentials were measured using a Keithly 199 digital multimeter. Potentiodynamic I-V measurements were conducted using a Pine AFRED5 potentiostat in conjunction with a VirtualBench data acquisition system. Cell impedence analyses were performed using a Gamry PC4-750 impedance measurement system with CMS 300/100 software.
(iv) Materials:
Anode feed gases were hydrogen sulfide (CP grade) or 5% H2S/N2, and cathode feed was either oxygen or air, each supplied as compressed gases (Praxair).
Example 1: MoS2 as Anode Catalyst MOS2 was mixed with a-terpeniol to make a paste. The paste was applied to one face of a YSZ disk having a cathode catalyst previously applied to the other face of the disk. The assembly so prepared then was heated to 1050 C for 30 minutes under an inert atmosphere, typically nitrogen, then cooled slowly to room temperature before installation in the fuel cell. A
layer of platinum paste (Heraeus CL11-5100) was applied onto the anode to enhance electric contact. A graph of voltage as a function of current density for a fuel cell having this anode catalyst is shown in Figure 1. A graph of power density versus current density is shown in Figure 2.
Example 2: MoS2 + Ag as Anode Catalyst MoS2 and Ag (95:5 by weight) were combined and mixed with oc-terpeniol to make a paste. The paste was applied to one face of a YSZ disk having a cathode catalyst previously applied to the other face of the disk.
The assembly so prepared then was heated to 1050 C for 30 minutes under an inert atmosphere, typically nitrogen, then cooled slowly to room temperature before installation in the fuel cell. A layer of platinum paste was applied onto the anode to enhance electric contact. A graph of voltage as a function of current density for a fuel cell having this anode catalyst is shown in Figure 3.
A graph of power density versus current density is shown in Figure 4.
Example 3: (MoS2 + Ag) + YSZ as Anode Catalyst First MoS2 and Ag were combined in a ratio of 95:5 (by weight) and then, mixed with YSZ (5% of final weight). The composite anode catalyst was combined with a-terpeniol to make a paste. The paste was appiied to one face of a YSZ disk having a cathode catalyst previously applied to the other face of the disk. The assembly so prepared then was heated to 1050 C for 30 minutes under an inert atmosphere, typically nitrogen, then cooled slowly to room temperature before installation in the fuel cell. A graph of voltage as a function of current density for a fuel cell having this anode catalyst is shown in Figure 5. A graph of power density versus current density is shown in Figure 6.
Example 4: (MoS2 + NiS) + Ag as Anode Catalyst First MoS2 and NiS were combined in a ratio of 1:1 (weight) and then heated to 150 C for about 16 hours. The resulting mixture was then mixed with Ag (5% of final weight). The composite anode catalyst was combined with a-terpeniol to make a paste. The anode catalyst paste was applied to one face of a YSZ disk having a cathode catalyst previously applied to the other face of the disk. The assembly so prepared then was heated to 1050 C
for 30 minutes under an inert atmosphere, typically nitrogen, then cooled slowly to room temperature before installation in the fuel cell. A graph of voltage as a function of current density for a fuel cell having this anode catalyst is shown in Figure 7. A graph of power density versus current density is shown in Figure 8.
Example 5: (MoS2 + NiS) + Ag + YSZ as Anode Catalyst First MoS2 and NiS were combined in a ratio of 1:1 (weight) and then mixed with Ag (to provide a ratio of MOSZ/NiS:Ag of 95:5), followed by YSZ
(5% by weight of final product). The composite anode catalyst was combined with a-terpeniol to make a paste. The paste was applied to one face of a YSZ
disk having a cathode catalyst previously applied to the other face of the disk.
The assembly so prepared then was heated to 1050 C for 30 minutes under an inert atmosphere, typically nitrogen, then cooled slowly to room temperature before installation in the fuel cell. A graph of voltage as a function of current density for a fuel cell having this anode catalyst is shown in Figure 9. A graph of power density versus current density is shown in Figure 10.
EXAMPLES
Materials and Methods (i) Equipment:
Two types of laboratory fuel cells have been used to study the reactions described herein. In each case the membrane electrode assembly (MEA) has planar geometry. However, it will be recognized by one skilled in the art that an alternative geometry may be used. Reactions at atmospheric pressure were performed using a reactor assembly comprising a Pyrex holder for the MEA situated between the anode and cathode chambers. The anode and cathode chambers each had concentric tubes, the inner tube serving as feed tubes and the other tubes serving as tailing gas tubes, as described by Liu et al. (2001). Reactions at elevated pressures were performed in a stainless steel cell substantially similar to that described by Chuang et al.
(2001).
(ii) Membranes:
MEA for use at elevated temperatures (up to 900 C) comprised anode and cathode catalysts screen-printed onto oxide ion-conducting ceramic membranes. The membrane was either yttria-stabilized zirconia (YSZ, 8%Y203) or YSZ having a sub-micron interlayer of Ti02 applied as a sol (Kueper et al., 1992) to the anode face of the YSZ membrane before application of anode catalyst. The MEA so prepared were gradually heated (3 C/min) to 1050 C (YSZ) or 900 C (Ti02/YSZ) and then held at that temperature to remove organics in the paste and to increase adhesion of the electrodes to the membrane.
Platinum meshes were used as anode current collectors and platinum wire was used as cathode current collectors.
(ii) Electrical Measurements:
Open circuit potentials were measured using a Keithly 199 digital multimeter. Potentiodynamic I-V measurements were conducted using a Pine AFRED5 potentiostat in conjunction with a VirtualBench data acquisition system. Cell impedence analyses were performed using a Gamry PC4-750 impedance measurement system with CMS 300/100 software.
(iv) Materials:
Anode feed gases were hydrogen sulfide (CP grade) or 5% H2S/N2, and cathode feed was either oxygen or air, each supplied as compressed gases (Praxair).
Example 1: MoS2 as Anode Catalyst MOS2 was mixed with a-terpeniol to make a paste. The paste was applied to one face of a YSZ disk having a cathode catalyst previously applied to the other face of the disk. The assembly so prepared then was heated to 1050 C for 30 minutes under an inert atmosphere, typically nitrogen, then cooled slowly to room temperature before installation in the fuel cell. A
layer of platinum paste (Heraeus CL11-5100) was applied onto the anode to enhance electric contact. A graph of voltage as a function of current density for a fuel cell having this anode catalyst is shown in Figure 1. A graph of power density versus current density is shown in Figure 2.
Example 2: MoS2 + Ag as Anode Catalyst MoS2 and Ag (95:5 by weight) were combined and mixed with oc-terpeniol to make a paste. The paste was applied to one face of a YSZ disk having a cathode catalyst previously applied to the other face of the disk.
The assembly so prepared then was heated to 1050 C for 30 minutes under an inert atmosphere, typically nitrogen, then cooled slowly to room temperature before installation in the fuel cell. A layer of platinum paste was applied onto the anode to enhance electric contact. A graph of voltage as a function of current density for a fuel cell having this anode catalyst is shown in Figure 3.
A graph of power density versus current density is shown in Figure 4.
Example 3: (MoS2 + Ag) + YSZ as Anode Catalyst First MoS2 and Ag were combined in a ratio of 95:5 (by weight) and then, mixed with YSZ (5% of final weight). The composite anode catalyst was combined with a-terpeniol to make a paste. The paste was appiied to one face of a YSZ disk having a cathode catalyst previously applied to the other face of the disk. The assembly so prepared then was heated to 1050 C for 30 minutes under an inert atmosphere, typically nitrogen, then cooled slowly to room temperature before installation in the fuel cell. A graph of voltage as a function of current density for a fuel cell having this anode catalyst is shown in Figure 5. A graph of power density versus current density is shown in Figure 6.
Example 4: (MoS2 + NiS) + Ag as Anode Catalyst First MoS2 and NiS were combined in a ratio of 1:1 (weight) and then heated to 150 C for about 16 hours. The resulting mixture was then mixed with Ag (5% of final weight). The composite anode catalyst was combined with a-terpeniol to make a paste. The anode catalyst paste was applied to one face of a YSZ disk having a cathode catalyst previously applied to the other face of the disk. The assembly so prepared then was heated to 1050 C
for 30 minutes under an inert atmosphere, typically nitrogen, then cooled slowly to room temperature before installation in the fuel cell. A graph of voltage as a function of current density for a fuel cell having this anode catalyst is shown in Figure 7. A graph of power density versus current density is shown in Figure 8.
Example 5: (MoS2 + NiS) + Ag + YSZ as Anode Catalyst First MoS2 and NiS were combined in a ratio of 1:1 (weight) and then mixed with Ag (to provide a ratio of MOSZ/NiS:Ag of 95:5), followed by YSZ
(5% by weight of final product). The composite anode catalyst was combined with a-terpeniol to make a paste. The paste was applied to one face of a YSZ
disk having a cathode catalyst previously applied to the other face of the disk.
The assembly so prepared then was heated to 1050 C for 30 minutes under an inert atmosphere, typically nitrogen, then cooled slowly to room temperature before installation in the fuel cell. A graph of voltage as a function of current density for a fuel cell having this anode catalyst is shown in Figure 9. A graph of power density versus current density is shown in Figure 10.
Discussion for Examples 1-5 Power density is an important criterion in measuring cell performance.
Values greater than about 100 mW/cm2 indicate a potential commercially useful fuel cell. The peak power density for the anode catalyst of Example 5 was over 200 mW/cm2, therefore this catalyst composition is an example of an anode catalyst that satisfies the need for an active anode catalyst. This power density value was obtained at 850 C, indicating that this catalyst is also useful for operating a fuel cell at temperatures above the vapour point of sulfur.
From the Examples provided above it can be seen that the use of each of the conducting material (compare Examples 1 and 2), the oxide ion conducting porous material (compare Examples 5 and 4) and a composite metal sulfide catalyst (compare Examples 5 and 3) contribute to the significant improvement in the activity of the anode catalyst.
While the present invention has been described with reference to what are presently considered to be the preferred examples, it is to be understood that the invention is not limited to the disclosed examples. To the contrary, the invention is intended to cover various modifications and equivalent arrangements included within the spirit and scope of the appended claims.
Values greater than about 100 mW/cm2 indicate a potential commercially useful fuel cell. The peak power density for the anode catalyst of Example 5 was over 200 mW/cm2, therefore this catalyst composition is an example of an anode catalyst that satisfies the need for an active anode catalyst. This power density value was obtained at 850 C, indicating that this catalyst is also useful for operating a fuel cell at temperatures above the vapour point of sulfur.
From the Examples provided above it can be seen that the use of each of the conducting material (compare Examples 1 and 2), the oxide ion conducting porous material (compare Examples 5 and 4) and a composite metal sulfide catalyst (compare Examples 5 and 3) contribute to the significant improvement in the activity of the anode catalyst.
While the present invention has been described with reference to what are presently considered to be the preferred examples, it is to be understood that the invention is not limited to the disclosed examples. To the contrary, the invention is intended to cover various modifications and equivalent arrangements included within the spirit and scope of the appended claims.
FULL CITATIONS FOR REFERENCES REFERRED TO IN THE
SPECIFICATION
K.T. Chuang and A.R. Sanger, in Air Pollution, ed. D.H.F. Liu and B.G. Liptak, Lewis Publishers (division of CRC Press) Boca Raton (2000), Section 3.7, pp 154-180.
K.T. Chuang, A.R. Sanger, S.V. Slavov, and J.C. Donini, Int. J. Hydrogen Energy, 26, 103 (2001); and references therein.
J.C. Donini, K.T. Chuang, S.V. Slavov, A.R. Sanger, and V. Stanic, US Patent 6,241,871 (2001).
K. Kordesch and G. Simader, Fuel Cells and Their Applications, VCH, Weinheim (1996).
T.W. Kueper, S.J. Visco and L.c. De Jeonghe, Solid State Ionics, 52 (1992) 251., M. Liu, P. He., J.L. Luo, A.R. Sanger, and K.T. Chuang, J. Power Sources, 94, 20 (2001).
T.J. Mazanec and T.L. Cable, US Patent 4,933,054 (1990).
J.N. Michaels and C.G. Vayenas, J. Catalysis, 85, 477-487 (1984).
T. Nakagaki, T. Ogawa, M. Hori, T. Hayashi, and T. Nishida, US patent 6,099,983 (2000).
D. Peterson and J. Winnick, J. Electrochem. Soc., 143, L55-L56 (1996).
S. Petrovic, J.C. Donini, S.S. Thind, S. Tong and A.R. Sanger, US Patent 6,294,068 (2001).
A.F. Sammells, US Patent 4,544,461 (1985).
J.H. White, M. Schwarz, and A.F. Sammells, US Patent 6,281,403 (2001).
Z.D. Ziaka and S. Vasileiadis, US Patent 6,090,312 (2000).
SPECIFICATION
K.T. Chuang and A.R. Sanger, in Air Pollution, ed. D.H.F. Liu and B.G. Liptak, Lewis Publishers (division of CRC Press) Boca Raton (2000), Section 3.7, pp 154-180.
K.T. Chuang, A.R. Sanger, S.V. Slavov, and J.C. Donini, Int. J. Hydrogen Energy, 26, 103 (2001); and references therein.
J.C. Donini, K.T. Chuang, S.V. Slavov, A.R. Sanger, and V. Stanic, US Patent 6,241,871 (2001).
K. Kordesch and G. Simader, Fuel Cells and Their Applications, VCH, Weinheim (1996).
T.W. Kueper, S.J. Visco and L.c. De Jeonghe, Solid State Ionics, 52 (1992) 251., M. Liu, P. He., J.L. Luo, A.R. Sanger, and K.T. Chuang, J. Power Sources, 94, 20 (2001).
T.J. Mazanec and T.L. Cable, US Patent 4,933,054 (1990).
J.N. Michaels and C.G. Vayenas, J. Catalysis, 85, 477-487 (1984).
T. Nakagaki, T. Ogawa, M. Hori, T. Hayashi, and T. Nishida, US patent 6,099,983 (2000).
D. Peterson and J. Winnick, J. Electrochem. Soc., 143, L55-L56 (1996).
S. Petrovic, J.C. Donini, S.S. Thind, S. Tong and A.R. Sanger, US Patent 6,294,068 (2001).
A.F. Sammells, US Patent 4,544,461 (1985).
J.H. White, M. Schwarz, and A.F. Sammells, US Patent 6,281,403 (2001).
Z.D. Ziaka and S. Vasileiadis, US Patent 6,090,312 (2000).
Claims
1. An anode catalyst composition for a gas phase H2S-O2 fuel cell having an ion-conducting membrane comprising:
(a) two or more metal sulfides of the formula MS x, wherein M is selected from the group consisting of Co, Ni, Fe, Mo, Cu, Cr, W and Mn, and x is between about 1.0 and about 2.5;
(b) a conductive material suitable for fuel cell operation; and (c) an ion-conducting porous material, wherein both of the conductive material and the porous material are present in the composition in amounts up to about 10% by weight of the composition.
2. The catalyst composition according to claim 1, wherein the fuel cell has an oxide ion-conducting membrane and the porous material is an oxide ion-conducting porous material.
3. The catalyst composition according to claim 1, wherein M is selected from the group consisting of Co, Ni, Fe, Mo, W and Mn.
4. The catalyst composition according to claim 3, comprising a material prepared from two metal sulfides, wherein in one metal sulfide of the formula MS x, M is selected from the group consisting of Co, Ni and Fe and in the other metal sulfide of the formula MS x, M is selected from the group consisting of Mo and W.
5. The catalyst composition according to claim 4, wherein the two metal sulfides are NiS and MoS2.
6. The catalyst composition according to claim 1, wherein the conductive material is selected the group consisting of:
(a) metals selected from silver, gold, nickel, bismuth, manganese, vanadium, platinum, rhodium, ruthenium, palladium, copper, zinc, cobalt, chromium and iron;
(b) oxides of the metals in (a);
(c) silver-bismuth oxide mixtures, tin-indium oxide mixtures, praeseodymium-indium oxide mixtures, cerium-lanthanum oxide mixtures; and (d) mixtures of (a)-(c).
7. The catalyst composition according to claim 6, wherein the conductive material is silver.
8. The catalyst composition according to claim 2, wherein the oxide ion conducting porous material is selected from the group consisting of Y2O3-stabilized ZrO2; Sc2O3-stabilized ZrO2; Y2O3-stabilized Bi2O3; Y2O3-stabilized CeO2; CaO-stabilized CeO2; ThO2; Y2O3-stabilized ThO2; ThO2, ZrO2, Bi2O, CeO2 or HfO2 stabilized by the addition of any one of the lanthanide oxides or CaO; and Al2O3 9. The catalyst composition according to claim 8, wherein the oxide ion conducting porous material is yttria-stabilized zirconia (YSZ).
10. The catalyst composition according claim 1, wherein the ratio of metal sulfide:conductive material:porous material is about 90:5:5 by weight.
11. The catalyst composition according to claim 1, wherein the metal sulfides used to prepare the catalytic material are initially present in about equivalent amounts by weight.
12. A method of preparing an anode catalyst composition for a H2S-O2 fuel cell having an ion-conducting membrane comprising:
(a) combining two or more sulfides of the formula MS x, wherein M is selected from the group consisting of Co, Ni, Fe, Mo, Cu, Cr, W and Mn and x is between about 1.0 and about 2.5, with a conductive material suitable for fuel cell operation; and (b) combining the combination of (a) with an ion-conducting porous material, wherein both of the conductive material and the porous material are present in the composition in amounts up to about 10% by weight of the composition.
13. The method according to claim 12, wherein the fuel cell has an oxide ion-conducting membrane and the porous material is an oxide ion-conducting porous material.
14. The method according to claim 12, further comprising the steps of :
(c) forming the composition into a paste;
(d) applying the paste to a surface of a material; and (e) heating the material to a temperature in the range of about 950 °C
to about 1200 °C, for a time in the range of about 10 minutes to about 150 minutes, in an inert atmosphere.
15. The method according to claim 14, wherein the material is heated to a temperature in the range of about 1000 °C to about 1100 °C, for about 30 minutes.
16. A fuel cell for the catalytic electrochemical oxidation of H2S to sulfur and water comprising an anode chamber on one side of an ion-conducting membrane and a cathode chamber on the opposing side of the ion-conducting membrane, said anode chamber having an catalytic anode and said cathode chamber having a catalytic cathode wherein said anode comprises a catalyst composition according to claim 1.
17. A fuel cell for the catalytic electrochemical oxidation of H2S to sulfur and water comprising an anode chamber on one side of an ion-conducting membrane and a cathode chamber on the opposing side of the ion-conducting membrane, said anode chamber having an catalytic anode and said cathode chamber having a catalytic cathode wherein said anode comprises a catalyst composition according to claim 2.
18. A process for the catalytic electrochemical oxidation of H2S to sulfur and water or hydrogen using a fuel cell having an anode chamber on one side of an oxide ion-conducting membrane and a cathode chamber on the opposing side of the membrane comprising:
(1) passing an H2S-containing gas through the anode chamber to contact a catalytic anode, where it reacts with oxide ions to produce elemental sulfur, water and electrons;
(2) passing oxide ions through the membrane from the cathode chamber to the anode chamber; and (3) passing an oxygen-containing gas through the cathode chamber to contact the catalytic cathode, where it reacts with electrons to produce oxide ions in the cathode chamber, wherein said catalytic anode comprises a catalyst composition according to claim 2.
19. The process according to claim 18, wherein the fuel cell is operated at a temperature above the vapour point of sulfur.
20. The process according to claim 18, wherein the fuel cell is operated at a temperature in the range of about 700°C to about 1000°C.
21. The process according to claim 18, wherein the fuel cell is operated at a temperature in the range of about 750°C to about 850°C.
22. A process for the catalytic electrochemical oxidation of H2S to sulfur and water or hydrogen using a fuel cell having an anode chamber on one side of an proton ion-conducting membrane and a cathode chamber on the opposing side of the membrane comprising:
(1) passing an H2S-containing gas through the anode chamber to contact a catalytic anode, where it reacts to produce elemental sulfur, protons and electrons;
(2) passing protons through the membrane from the anode chamber to the cathode chamber; and (3) passing an oxygen-containing gas through the cathode chamber to contact the catalytic cathode, where it reacts with protons and electrons to produce water in the cathode chamber, wherein said catalytic anode comprises a catalyst composition according to
claim 1.
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/143,944 | 2002-05-14 | ||
| US10/143,944 US20030215696A1 (en) | 2002-05-14 | 2002-05-14 | Electrode catalysts for H2S fuel cell |
| US10/290,429 US7014941B2 (en) | 2002-05-14 | 2002-11-08 | Electrode catalyst for H2S fuel cells |
| US10/290,429 | 2002-11-08 | ||
| PCT/CA2003/000681 WO2003096452A2 (en) | 2002-05-14 | 2003-05-13 | Electrode catalyst for h2s fuel cell |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2486672A1 CA2486672A1 (en) | 2003-11-20 |
| CA2486672C true CA2486672C (en) | 2010-04-13 |
Family
ID=33436567
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2486672A Expired - Fee Related CA2486672C (en) | 2002-05-14 | 2003-05-13 | Electrode catalyst for h2s fuel cell |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US7014941B2 (en) |
| AU (1) | AU2003223804A1 (en) |
| CA (1) | CA2486672C (en) |
| WO (1) | WO2003096452A2 (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7879753B2 (en) * | 2003-05-27 | 2011-02-01 | Industrie De Nora S.P.A. | Catalyst for oxygen reduction |
| RO120736B1 (en) * | 2004-08-30 | 2006-06-30 | Ovidiu Păcală | Process and fuel cell for producing electric current |
| KR20070099120A (en) * | 2006-04-03 | 2007-10-09 | 삼성에스디아이 주식회사 | Anode for fuel cell, membrane-electrode assembly comprising same and fuel cell system comprising same |
| CN104538600B (en) * | 2015-01-09 | 2017-07-18 | 江苏大学 | A kind of AgNPs/MoS2Functional composite material and preparation method thereof |
| CN117497785A (en) * | 2023-12-29 | 2024-02-02 | 中石油深圳新能源研究院有限公司 | Fuel cell anode material and preparation method and application thereof |
| CN117923737B (en) * | 2024-03-22 | 2024-06-11 | 四川思达能环保科技有限公司 | Seawater treatment system and seawater treatment method |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4544461A (en) * | 1983-03-28 | 1985-10-01 | Energy Conversion Devices, Inc. | Hydrogen sulfide decomposition cell and catalytic materials therefor |
| US6287432B1 (en) * | 1987-03-13 | 2001-09-11 | The Standard Oil Company | Solid multi-component membranes, electrochemical reactor components, electrochemical reactors and use of membranes, reactor components, and reactor for oxidation reactions |
| US4933054A (en) * | 1987-03-13 | 1990-06-12 | The Standard Oil Company | Electrocatalytic oxidative dehydrogenation of saturated hydrocarbons to unsaturated hydrocarbons |
| US4920015A (en) * | 1988-09-29 | 1990-04-24 | Gas Research Institute | Electrochemical H2 S conversion |
| US6037514A (en) * | 1994-01-14 | 2000-03-14 | Eltron Research, Inc. | Solid state proton and electron mediating membrane and use in catalytic membrane reactors |
| US6090312A (en) * | 1996-01-31 | 2000-07-18 | Ziaka; Zoe D. | Reactor-membrane permeator process for hydrocarbon reforming and water gas-shift reactions |
| JPH10177864A (en) * | 1996-10-18 | 1998-06-30 | Toshiba Corp | Fuel cell |
| US6294068B1 (en) * | 1997-06-20 | 2001-09-25 | Natural Resources Canada | Electrochemical conversion of hydrocarbons |
| CA2253161A1 (en) * | 1998-04-16 | 1999-10-16 | Karl Tze-Tang Chuang | Electrochemical oxidation of hydrogen sulfide |
| US20040086772A1 (en) * | 2002-09-06 | 2004-05-06 | Board Of Regents, The University Of Texas System | Fuel cell electrode comprising CO and sulfur tolerant metal compound hydrogen activation catalyst |
-
2002
- 2002-11-08 US US10/290,429 patent/US7014941B2/en not_active Expired - Fee Related
-
2003
- 2003-05-13 WO PCT/CA2003/000681 patent/WO2003096452A2/en not_active Ceased
- 2003-05-13 CA CA2486672A patent/CA2486672C/en not_active Expired - Fee Related
- 2003-05-13 AU AU2003223804A patent/AU2003223804A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| US20030215697A1 (en) | 2003-11-20 |
| WO2003096452A2 (en) | 2003-11-20 |
| WO2003096452A3 (en) | 2004-11-18 |
| US7014941B2 (en) | 2006-03-21 |
| CA2486672A1 (en) | 2003-11-20 |
| AU2003223804A1 (en) | 2003-11-11 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Zheng et al. | A new symmetric solid-oxide fuel cell with La0. 8Sr0. 2Sc0. 2Mn0. 8O3-δ perovskite oxide as both the anode and cathode | |
| Brett et al. | Methanol as a direct fuel in intermediate temperature (500–600∘ C) solid oxide fuel cells with copper based anodes | |
| Sahibzada et al. | Development of solid oxide fuel cells based on a Ce (Gd) O2− x electrolyte film for intermediate temperature operation | |
| CA2493029C (en) | Perovskite-based fuel cell electrode and membrane | |
| US6241871B1 (en) | Electrochemical oxidation of hydrogen sulfide | |
| Asano et al. | A novel solid oxide fuel cell system using the partial oxidation of methane | |
| US9825306B2 (en) | Mixed ionic and electronic conductor based on Sr2Fe2-xMoxO6 perovskite | |
| Sahibzada et al. | Intermediate temperature solid oxide fuel cells operated with methanol fuels | |
| US6245707B1 (en) | Methanol tolerant catalyst material | |
| Zha et al. | A sulfur-tolerant anode material for SOFCs: Gd 2 Ti 1.4 Mo 0.6 O 7 | |
| Deleebeeck et al. | Enhancing hybrid direct carbon fuel cell anode performance using Ag2O | |
| Roushanafshar et al. | Electrochemical oxidation of sour natural gas over La0. 4Ce0. 6O1. 8–La0. 4Sr0. 6TiO3±δ anode in SOFC: a mechanism study of H2S effects | |
| US4920015A (en) | Electrochemical H2 S conversion | |
| Sapountzi et al. | Electrochemical performance of La0. 75Sr0. 25Cr0. 9M0. 1O3 perovskites as SOFC anodes in CO/CO2 mixtures | |
| Yoshimi et al. | Temperature and humidity dependence of the electrode polarization in intermediate-temperature fuel cells employing CsH2PO4/SiP2O7-based composite electrolytes | |
| CA2486672C (en) | Electrode catalyst for h2s fuel cell | |
| SE514689C2 (en) | Fuel cell | |
| Wang et al. | Stabilities and electrical conductivities of electrode materials for use in H2S-containing gases | |
| US12018392B2 (en) | Methods for producing syngas from H2S and CO2 in an electrochemical cell | |
| US20030215696A1 (en) | Electrode catalysts for H2S fuel cell | |
| Zheng et al. | Ni–La2O3 cermet hydrogen electrode originating from the in-situ decomposition of the La2NiO4+ δ oxide for quasi-symmetrical solid oxide fuel cells | |
| Morales et al. | Anode‐supported SOFC operated under single‐chamber conditions at intermediate temperatures | |
| Zha et al. | Gd2Ti2-XMoXO7-based anode materials for H2S-air solid oxide fuel cells | |
| Zhou et al. | Fuel Cells Running on Alternative Fuels | |
| WO2011131657A1 (en) | Proton ceramic fuel cell |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKLA | Lapsed |
Effective date: 20150513 |