CA2397929C - Process and plant for depolymerizing of the ch chains of solid materials - Google Patents
Process and plant for depolymerizing of the ch chains of solid materials Download PDFInfo
- Publication number
- CA2397929C CA2397929C CA2397929A CA2397929A CA2397929C CA 2397929 C CA2397929 C CA 2397929C CA 2397929 A CA2397929 A CA 2397929A CA 2397929 A CA2397929 A CA 2397929A CA 2397929 C CA2397929 C CA 2397929C
- Authority
- CA
- Canada
- Prior art keywords
- reactor
- plant
- combustion
- environment
- condensate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000000034 method Methods 0.000 title claims abstract description 33
- 239000011343 solid material Substances 0.000 title description 4
- 239000000463 material Substances 0.000 claims abstract description 42
- 239000007789 gas Substances 0.000 claims abstract description 25
- 238000002485 combustion reaction Methods 0.000 claims abstract description 16
- 229920000642 polymer Polymers 0.000 claims abstract description 9
- 238000009833 condensation Methods 0.000 claims abstract description 3
- 230000005494 condensation Effects 0.000 claims abstract description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 12
- 239000001301 oxygen Substances 0.000 claims description 12
- 229910052760 oxygen Inorganic materials 0.000 claims description 12
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 10
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 8
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims description 7
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 7
- 239000005864 Sulphur Substances 0.000 claims description 7
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 5
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 4
- 239000000460 chlorine Substances 0.000 claims description 4
- 229910052801 chlorine Inorganic materials 0.000 claims description 4
- 239000010909 process residue Substances 0.000 claims description 4
- 238000000926 separation method Methods 0.000 claims description 4
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 4
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 4
- 238000007599 discharging Methods 0.000 claims description 3
- 238000011068 loading method Methods 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 2
- 238000000354 decomposition reaction Methods 0.000 abstract 1
- 239000007788 liquid Substances 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 235000010216 calcium carbonate Nutrition 0.000 description 4
- 239000007800 oxidant agent Substances 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 2
- 238000006298 dechlorination reaction Methods 0.000 description 2
- 239000003344 environmental pollutant Substances 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 231100000719 pollutant Toxicity 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 239000012495 reaction gas Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000003841 chloride salts Chemical class 0.000 description 1
- 239000000567 combustion gas Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000000779 depleting effect Effects 0.000 description 1
- 230000001066 destructive effect Effects 0.000 description 1
- 150000002013 dioxins Chemical class 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
- 239000002737 fuel gas Substances 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000009877 rendering Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000004227 thermal cracking Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B49/00—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated
- C10B49/02—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with hot gases or vapours, e.g. hot gases obtained by partial combustion of the charge
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
- C10B53/07—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of solid raw materials consisting of synthetic polymeric materials, e.g. tyres
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
- C10G1/10—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal from rubber or rubber waste
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
- F23G5/006—General arrangement of incineration plant, e.g. flow sheets
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G7/00—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals
- F23G7/12—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of plastics, e.g. rubber
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G2201/00—Pretreatment
- F23G2201/30—Pyrolysing
- F23G2201/301—Treating pyrogases
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G2201/00—Pretreatment
- F23G2201/40—Gasification
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G2202/00—Combustion
- F23G2202/30—Combustion in a pressurised chamber
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G2900/00—Special features of, or arrangements for incinerators
- F23G2900/50205—Waste pre-treatment by pyrolysis, gasification or cracking followed by condensation of gas into combustible oil or fat
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES
- F23J2219/00—Treatment devices
- F23J2219/70—Condensing contaminants with coolers
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23L—SUPPLYING AIR OR NON-COMBUSTIBLE LIQUIDS OR GASES TO COMBUSTION APPARATUS IN GENERAL ; VALVES OR DAMPERS SPECIALLY ADAPTED FOR CONTROLLING AIR SUPPLY OR DRAUGHT IN COMBUSTION APPARATUS; INDUCING DRAUGHT IN COMBUSTION APPARATUS; TOPS FOR CHIMNEYS OR VENTILATING SHAFTS; TERMINALS FOR FLUES
- F23L2900/00—Special arrangements for supplying or treating air or oxidant for combustion; Injecting inert gas, water or steam into the combustion chamber
- F23L2900/07005—Injecting pure oxygen or oxygen enriched air
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E20/00—Combustion technologies with mitigation potential
- Y02E20/34—Indirect CO2mitigation, i.e. by acting on non CO2directly related matters of the process, e.g. pre-heating or heat recovery
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/141—Feedstock
- Y02P20/143—Feedstock the feedstock being recycled material, e.g. plastics
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Wood Science & Technology (AREA)
- Processing Of Solid Wastes (AREA)
- Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Treating Waste Gases (AREA)
- Saccharide Compounds (AREA)
- Catalysts (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT2000RE000008A IT1318320B1 (it) | 2000-02-18 | 2000-02-18 | Procedimento ed impianto per la depolimerizzazione delle catene ch dei materiali solidi. |
| ITRE2000A000008 | 2000-02-18 | ||
| PCT/EP2001/001717 WO2001060948A1 (en) | 2000-02-18 | 2001-02-15 | Process and plant for treating materials containing ch polymer chains |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2397929A1 CA2397929A1 (en) | 2001-08-23 |
| CA2397929C true CA2397929C (en) | 2010-04-20 |
Family
ID=11453849
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2397929A Expired - Fee Related CA2397929C (en) | 2000-02-18 | 2001-02-15 | Process and plant for depolymerizing of the ch chains of solid materials |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US6443078B2 (https=) |
| EP (1) | EP1255801B1 (https=) |
| JP (1) | JP5016766B2 (https=) |
| CN (1) | CN1220755C (https=) |
| AT (1) | ATE297454T1 (https=) |
| AU (1) | AU3175501A (https=) |
| BR (1) | BR0108242B1 (https=) |
| CA (1) | CA2397929C (https=) |
| DE (1) | DE60111355T2 (https=) |
| ES (1) | ES2242725T3 (https=) |
| IT (1) | IT1318320B1 (https=) |
| WO (1) | WO2001060948A1 (https=) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8888961B2 (en) | 2009-10-14 | 2014-11-18 | Reklaim, Inc. | Pyrolysis process and products |
| HUE063491T2 (hu) * | 2016-07-26 | 2024-01-28 | Prti Global Man Llc | Berendezés és eljárás gumiabroncsok és más hulladék termékek termikus szétbontására |
| CN110715304B (zh) * | 2019-11-08 | 2020-08-04 | 浙江亿方新材料股份有限公司 | 一种工业塑料报废处理装置 |
| EP4211207B1 (en) | 2020-09-14 | 2025-12-10 | Ecolab USA, Inc. | Cold flow additives for plastic-derived synthetic feedstock |
| CA3209451A1 (en) | 2021-03-10 | 2022-09-15 | Theodore C. Arnst | Stabilizer additives for plastic-derived synthetic feedstock |
| WO2023064375A1 (en) | 2021-10-14 | 2023-04-20 | Ecolab Usa Inc. | Antifouling agents for plastic-derived synthetic feedstocks |
Family Cites Families (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2413714A (en) * | 1942-04-30 | 1947-01-07 | Koppers Co Inc | Process of producing elemental sulphur |
| BE601009A (https=) | 1960-03-09 | |||
| GB1383122A (en) | 1972-05-26 | 1975-02-05 | Texaco Development Corp | Hydrodesulphurization process |
| US4284616A (en) * | 1978-02-15 | 1981-08-18 | Intenco, Inc. | Process for recovering carbon black and hydrocarbons from used tires |
| SE451464B (sv) * | 1981-12-01 | 1987-10-12 | Lumalampan Ab | Forfarande och anordning for atervinning av kvicksilver ur avfall innehallande organiskt material |
| US4839021A (en) * | 1986-06-19 | 1989-06-13 | Recherche Carbovac Inc. | Treatment of petroleum derived organic sludges and oil residues |
| US4759300A (en) * | 1987-10-22 | 1988-07-26 | Balboa Pacific Corporation | Method and apparatus for the pyrolysis of waste products |
| US4895083A (en) * | 1988-11-14 | 1990-01-23 | Mcdilda John A | Whole tire disposal system |
| US5185134A (en) * | 1988-12-21 | 1993-02-09 | The United States Of America As Represented By The U.S. Environmental Protection Agency | Reduction of chlorinated organics in the incineration of wastes |
| DE3921714A1 (de) * | 1989-07-01 | 1991-01-10 | Hoechst Ag | Verfahren zur selektiven absorption von chlor aus co(pfeil abwaerts)2(pfeil abwaerts)-haltigen abgasen |
| US5142998A (en) * | 1989-11-28 | 1992-09-01 | Feitel Frederick E | Apparatus and method for treating contaminated gas emissions |
| US5157176A (en) * | 1990-07-26 | 1992-10-20 | Munger Joseph H | Recycling process, apparatus and product produced by such process for producing a rubber extender/plasticizing agent from used automobile rubber tires |
| US5101739A (en) * | 1991-01-04 | 1992-04-07 | Utah Environmental Energy, Inc. | Tire gassification and combustion system |
| DE69201792D1 (de) | 1991-05-01 | 1995-04-27 | Energy Biosystems Corp | System und kontinuierliches verfahren zur biokatalytischen entschwefelung von schwefelhaltigen heterozyklischen molekülen. |
| US5411714A (en) * | 1992-04-06 | 1995-05-02 | Wu; Arthur C. | Thermal conversion pyrolysis reactor system |
| NL9302081A (nl) * | 1993-11-30 | 1995-06-16 | Gastec Nv | Werkwijze voor het verwijderen van elementaire zwavel uit een gasstroom. |
| EP0672743B2 (de) * | 1994-03-18 | 2001-05-16 | Dieter Uschkoreit | Verfahren und Vorrichtung zum thermischen Behandeln von Materialien mit Anteilen an verdampfbaren Stoffen |
| KR0155064B1 (ko) * | 1994-03-30 | 1998-11-16 | 이현희 | 폐타이어의 열분해에 의한 가스추출방법 및 장치 |
| US5628969A (en) * | 1995-10-18 | 1997-05-13 | Mercury Treatment Alternatives, Inc. | Chemical separation and reaction apparatus |
| US5720232A (en) * | 1996-07-10 | 1998-02-24 | Meador; William R. | Method and apparatus for recovering constituents from discarded tires |
| US5782188A (en) * | 1996-09-25 | 1998-07-21 | Evans; Marvin | Pyrolytic combustion apparatus and method |
| US6244199B1 (en) * | 1996-10-22 | 2001-06-12 | Traidec S.A. | Plant for thermolysis and energetic upgrading of waste products |
| JPH10168224A (ja) * | 1996-12-09 | 1998-06-23 | Motoda Electron Co Ltd | 廃プラスチックのリサイクル方法、並びに、その装置 |
| US6143856A (en) * | 1999-01-29 | 2000-11-07 | Pyrovac Technologies Inc. | Process for the production of phenolic-rich pyrolysis oils for use in making phenol-formaldehyde resole resins |
-
2000
- 2000-02-18 IT IT2000RE000008A patent/IT1318320B1/it active
-
2001
- 2001-02-15 AU AU31755/01A patent/AU3175501A/en not_active Abandoned
- 2001-02-15 WO PCT/EP2001/001717 patent/WO2001060948A1/en not_active Ceased
- 2001-02-15 DE DE60111355T patent/DE60111355T2/de not_active Expired - Lifetime
- 2001-02-15 JP JP2001560320A patent/JP5016766B2/ja not_active Expired - Fee Related
- 2001-02-15 CN CNB01804722XA patent/CN1220755C/zh not_active Expired - Fee Related
- 2001-02-15 ES ES01903776T patent/ES2242725T3/es not_active Expired - Lifetime
- 2001-02-15 BR BRPI0108242-6A patent/BR0108242B1/pt not_active IP Right Cessation
- 2001-02-15 CA CA2397929A patent/CA2397929C/en not_active Expired - Fee Related
- 2001-02-15 EP EP01903776A patent/EP1255801B1/en not_active Expired - Lifetime
- 2001-02-15 AT AT01903776T patent/ATE297454T1/de active
- 2001-02-16 US US09/784,306 patent/US6443078B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| CN1398288A (zh) | 2003-02-19 |
| ES2242725T3 (es) | 2005-11-16 |
| JP5016766B2 (ja) | 2012-09-05 |
| IT1318320B1 (it) | 2003-08-25 |
| WO2001060948A1 (en) | 2001-08-23 |
| ATE297454T1 (de) | 2005-06-15 |
| BR0108242B1 (pt) | 2011-05-03 |
| EP1255801B1 (en) | 2005-06-08 |
| BR0108242A (pt) | 2002-11-05 |
| DE60111355T2 (de) | 2005-11-10 |
| CN1220755C (zh) | 2005-09-28 |
| AU3175501A (en) | 2001-08-27 |
| ITRE20000008A1 (it) | 2001-08-18 |
| DE60111355D1 (de) | 2005-07-14 |
| US20010029876A1 (en) | 2001-10-18 |
| US6443078B2 (en) | 2002-09-03 |
| CA2397929A1 (en) | 2001-08-23 |
| EP1255801A1 (en) | 2002-11-13 |
| JP2003523448A (ja) | 2003-08-05 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKLA | Lapsed |
Effective date: 20160215 |