CA2187438C - Detergents containing a heavy metal sequestrant and a delayed release peroxyacid bleach system - Google Patents
Detergents containing a heavy metal sequestrant and a delayed release peroxyacid bleach system Download PDFInfo
- Publication number
- CA2187438C CA2187438C CA002187438A CA2187438A CA2187438C CA 2187438 C CA2187438 C CA 2187438C CA 002187438 A CA002187438 A CA 002187438A CA 2187438 A CA2187438 A CA 2187438A CA 2187438 C CA2187438 C CA 2187438C
- Authority
- CA
- Canada
- Prior art keywords
- peroxyacid
- group
- bleach
- acid
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000007844 bleaching agent Substances 0.000 title claims abstract description 109
- 239000003599 detergent Substances 0.000 title claims abstract description 104
- 229910001385 heavy metal Inorganic materials 0.000 title claims abstract description 59
- 239000003352 sequestering agent Substances 0.000 title claims abstract description 43
- 150000004965 peroxy acids Chemical class 0.000 title claims abstract description 38
- 230000003111 delayed effect Effects 0.000 title description 16
- 239000000203 mixture Substances 0.000 claims abstract description 225
- 238000000034 method Methods 0.000 claims abstract description 54
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 48
- 150000004967 organic peroxy acids Chemical class 0.000 claims abstract description 46
- 238000004061 bleaching Methods 0.000 claims abstract description 21
- -1 cationic peroxyacid Chemical class 0.000 claims description 99
- 150000001875 compounds Chemical class 0.000 claims description 88
- 239000000243 solution Substances 0.000 claims description 80
- 239000002243 precursor Substances 0.000 claims description 71
- 125000000217 alkyl group Chemical group 0.000 claims description 65
- 150000003839 salts Chemical class 0.000 claims description 57
- 150000002500 ions Chemical class 0.000 claims description 56
- 125000004432 carbon atom Chemical group C* 0.000 claims description 54
- 239000002253 acid Substances 0.000 claims description 45
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 42
- 238000005406 washing Methods 0.000 claims description 38
- 239000003054 catalyst Substances 0.000 claims description 31
- 229920001577 copolymer Polymers 0.000 claims description 30
- 125000003118 aryl group Chemical group 0.000 claims description 25
- 239000004744 fabric Substances 0.000 claims description 25
- VKZRWSNIWNFCIQ-UHFFFAOYSA-N 2-[2-(1,2-dicarboxyethylamino)ethylamino]butanedioic acid Chemical compound OC(=O)CC(C(O)=O)NCCNC(C(O)=O)CC(O)=O VKZRWSNIWNFCIQ-UHFFFAOYSA-N 0.000 claims description 24
- 229910052748 manganese Inorganic materials 0.000 claims description 22
- 229920001296 polysiloxane Polymers 0.000 claims description 22
- 239000011230 binding agent Substances 0.000 claims description 20
- 150000007513 acids Chemical class 0.000 claims description 18
- 239000003446 ligand Substances 0.000 claims description 18
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 17
- 239000000194 fatty acid Substances 0.000 claims description 17
- 229930195729 fatty acid Natural products 0.000 claims description 17
- 239000000758 substrate Substances 0.000 claims description 17
- 238000010998 test method Methods 0.000 claims description 17
- 229910052783 alkali metal Inorganic materials 0.000 claims description 16
- 239000000377 silicon dioxide Substances 0.000 claims description 15
- 150000001408 amides Chemical class 0.000 claims description 13
- 150000008064 anhydrides Chemical class 0.000 claims description 13
- 150000001340 alkali metals Chemical group 0.000 claims description 12
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 12
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 12
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 12
- YNJSNEKCXVFDKW-UHFFFAOYSA-N 3-(5-amino-1h-indol-3-yl)-2-azaniumylpropanoate Chemical compound C1=C(N)C=C2C(CC(N)C(O)=O)=CNC2=C1 YNJSNEKCXVFDKW-UHFFFAOYSA-N 0.000 claims description 11
- 238000007046 ethoxylation reaction Methods 0.000 claims description 11
- 229920001223 polyethylene glycol Polymers 0.000 claims description 11
- 150000004760 silicates Chemical class 0.000 claims description 10
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 claims description 10
- 229910019142 PO4 Inorganic materials 0.000 claims description 9
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 8
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 8
- 239000000460 chlorine Substances 0.000 claims description 8
- 229910052801 chlorine Inorganic materials 0.000 claims description 8
- 229910052736 halogen Inorganic materials 0.000 claims description 8
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 8
- 235000021317 phosphate Nutrition 0.000 claims description 8
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims description 8
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 7
- 239000004902 Softening Agent Substances 0.000 claims description 7
- 150000001298 alcohols Chemical class 0.000 claims description 7
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 7
- 125000002091 cationic group Chemical group 0.000 claims description 7
- 150000002367 halogens Chemical class 0.000 claims description 7
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 7
- WLDGDTPNAKWAIR-UHFFFAOYSA-N 1,4,7-trimethyl-1,4,7-triazonane Chemical compound CN1CCN(C)CCN(C)CC1 WLDGDTPNAKWAIR-UHFFFAOYSA-N 0.000 claims description 6
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 6
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 6
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims description 6
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 6
- 125000000524 functional group Chemical group 0.000 claims description 6
- 229920001519 homopolymer Polymers 0.000 claims description 6
- 150000003512 tertiary amines Chemical class 0.000 claims description 6
- 239000004354 Hydroxyethyl cellulose Substances 0.000 claims description 5
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims description 5
- 125000003342 alkenyl group Chemical group 0.000 claims description 5
- 125000003545 alkoxy group Chemical group 0.000 claims description 5
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 5
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims description 5
- 229920000609 methyl cellulose Polymers 0.000 claims description 5
- 239000001923 methylcellulose Substances 0.000 claims description 5
- 235000010981 methylcellulose Nutrition 0.000 claims description 5
- XCRBXWCUXJNEFX-UHFFFAOYSA-N peroxybenzoic acid Chemical class OOC(=O)C1=CC=CC=C1 XCRBXWCUXJNEFX-UHFFFAOYSA-N 0.000 claims description 5
- 125000001424 substituent group Chemical group 0.000 claims description 5
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 4
- 229920000896 Ethulose Polymers 0.000 claims description 4
- 239000001859 Ethyl hydroxyethyl cellulose Substances 0.000 claims description 4
- 239000005977 Ethylene Substances 0.000 claims description 4
- QKFCUYBDKSNAGQ-UHFFFAOYSA-N [Co].N(=C=S)C1=C(C(=NC=C1)NC1=NC=CC=C1)N=C=S Chemical compound [Co].N(=C=S)C1=C(C(=NC=C1)NC1=NC=CC=C1)N=C=S QKFCUYBDKSNAGQ-UHFFFAOYSA-N 0.000 claims description 4
- 239000008199 coating composition Substances 0.000 claims description 4
- 150000002170 ethers Chemical class 0.000 claims description 4
- 235000019326 ethyl hydroxyethyl cellulose Nutrition 0.000 claims description 4
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 4
- 229910017053 inorganic salt Inorganic materials 0.000 claims description 4
- XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 claims description 4
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 4
- 229920000570 polyether Polymers 0.000 claims description 4
- LNAZSHAWQACDHT-XIYTZBAFSA-N (2r,3r,4s,5r,6s)-4,5-dimethoxy-2-(methoxymethyl)-3-[(2s,3r,4s,5r,6r)-3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6r)-4,5,6-trimethoxy-2-(methoxymethyl)oxan-3-yl]oxyoxane Chemical compound CO[C@@H]1[C@@H](OC)[C@H](OC)[C@@H](COC)O[C@H]1O[C@H]1[C@H](OC)[C@@H](OC)[C@H](O[C@H]2[C@@H]([C@@H](OC)[C@H](OC)O[C@@H]2COC)OC)O[C@@H]1COC LNAZSHAWQACDHT-XIYTZBAFSA-N 0.000 claims description 3
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical group O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 claims description 3
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 3
- 125000000732 arylene group Chemical group 0.000 claims description 3
- 150000001642 boronic acid derivatives Chemical class 0.000 claims description 3
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 3
- 150000003951 lactams Chemical class 0.000 claims description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 3
- 150000003013 phosphoric acid derivatives Chemical class 0.000 claims description 3
- ITWBWJFEJCHKSN-UHFFFAOYSA-N 1,4,7-triazonane Chemical compound C1CNCCNCCN1 ITWBWJFEJCHKSN-UHFFFAOYSA-N 0.000 claims description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical class OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims description 2
- RGHNJXZEOKUKBD-SQOUGZDYSA-M D-gluconate Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O RGHNJXZEOKUKBD-SQOUGZDYSA-M 0.000 claims description 2
- 125000004171 alkoxy aryl group Chemical group 0.000 claims description 2
- 125000003282 alkyl amino group Chemical group 0.000 claims description 2
- 125000003368 amide group Chemical group 0.000 claims description 2
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 2
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims description 2
- 229940050410 gluconate Drugs 0.000 claims description 2
- YRNNKGFMTBWUGL-UHFFFAOYSA-L copper(ii) perchlorate Chemical compound [Cu+2].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O YRNNKGFMTBWUGL-UHFFFAOYSA-L 0.000 claims 1
- NGLYWWPBKJFWRP-UHFFFAOYSA-L iron(2+) N-pyridin-2-ylpyridin-2-amine diperchlorate Chemical compound [Fe+2].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.C=1C=CC=NC=1NC1=CC=CC=N1.C=1C=CC=NC=1NC1=CC=CC=N1.C=1C=CC=NC=1NC1=CC=CC=N1 NGLYWWPBKJFWRP-UHFFFAOYSA-L 0.000 claims 1
- FRPJTGXMTIIFIT-UHFFFAOYSA-N tetraacetylethylenediamine Chemical compound CC(=O)C(N)(C(C)=O)C(N)(C(C)=O)C(C)=O FRPJTGXMTIIFIT-UHFFFAOYSA-N 0.000 claims 1
- 239000004094 surface-active agent Substances 0.000 description 50
- 239000000463 material Substances 0.000 description 47
- 239000000047 product Substances 0.000 description 37
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 35
- 239000011572 manganese Substances 0.000 description 34
- 238000000576 coating method Methods 0.000 description 32
- 239000002245 particle Substances 0.000 description 30
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 27
- 239000011248 coating agent Substances 0.000 description 27
- 239000000344 soap Substances 0.000 description 26
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 24
- 102000004190 Enzymes Human genes 0.000 description 24
- 108090000790 Enzymes Proteins 0.000 description 24
- 239000002518 antifoaming agent Substances 0.000 description 24
- 229940088598 enzyme Drugs 0.000 description 24
- 229920000768 polyamine Polymers 0.000 description 21
- 239000011734 sodium Substances 0.000 description 21
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 20
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 19
- 229910052708 sodium Inorganic materials 0.000 description 19
- 229910052757 nitrogen Inorganic materials 0.000 description 17
- 229920005646 polycarboxylate Polymers 0.000 description 17
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 15
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 15
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- 235000008733 Citrus aurantifolia Nutrition 0.000 description 14
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- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 12
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- 125000001183 hydrocarbyl group Chemical group 0.000 description 9
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- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
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- QQOWHRYOXYEMTL-UHFFFAOYSA-N triazin-4-amine Chemical class N=C1C=CN=NN1 QQOWHRYOXYEMTL-UHFFFAOYSA-N 0.000 description 1
- 150000003852 triazoles Chemical group 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-O triethanolammonium Chemical compound OCC[NH+](CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-O 0.000 description 1
- 125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 1
- WCTAGTRAWPDFQO-UHFFFAOYSA-K trisodium;hydrogen carbonate;carbonate Chemical compound [Na+].[Na+].[Na+].OC([O-])=O.[O-]C([O-])=O WCTAGTRAWPDFQO-UHFFFAOYSA-K 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
- C11D17/046—Insoluble free body dispenser
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0039—Coated compositions or coated components in the compositions, (micro)capsules
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/001—Softening compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/08—Silicates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/32—Amides; Substituted amides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/36—Organic compounds containing phosphorus
- C11D3/364—Organic compounds containing phosphorus containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3907—Organic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3932—Inorganic compounds or complexes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3942—Inorganic per-compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3945—Organic per-compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/12—Soft surfaces, e.g. textile
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB9407535.5 | 1994-04-13 | ||
| GB9407535A GB9407535D0 (en) | 1994-04-13 | 1994-04-13 | Detergent compositions |
| PCT/US1995/004085 WO1995028464A1 (en) | 1994-04-13 | 1995-04-03 | Detergents containing a heavy metal sequestrant and a delayed release peroxyacid bleach system |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2187438A1 CA2187438A1 (en) | 1995-10-26 |
| CA2187438C true CA2187438C (en) | 2000-10-31 |
Family
ID=10753619
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002187438A Expired - Fee Related CA2187438C (en) | 1994-04-13 | 1995-04-03 | Detergents containing a heavy metal sequestrant and a delayed release peroxyacid bleach system |
Country Status (13)
| Country | Link |
|---|---|
| EP (1) | EP0755429B1 (zh) |
| JP (1) | JP4393582B2 (zh) |
| CN (2) | CN1094514C (zh) |
| AT (1) | ATE259412T1 (zh) |
| AU (1) | AU2204895A (zh) |
| BR (1) | BR9507379A (zh) |
| CA (1) | CA2187438C (zh) |
| DE (1) | DE69532559T2 (zh) |
| ES (1) | ES2216011T3 (zh) |
| GB (1) | GB9407535D0 (zh) |
| MA (1) | MA23505A1 (zh) |
| PE (1) | PE50595A1 (zh) |
| WO (1) | WO1995028464A1 (zh) |
Families Citing this family (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19609953A1 (de) * | 1996-03-14 | 1997-09-18 | Basf Ag | Feste Zusammensetzung aus heterocyclischen Verbindungen und/oder Oximestern und inerten porösen Trägermaterialien und ihre Verwendung als stabile Bleichaktivator-Komponente in Wasch-, Bleich- und Reinigungsmitteln |
| GB2311536A (en) * | 1996-03-29 | 1997-10-01 | Procter & Gamble | Dishwashing and laundry detergents |
| GB2311541A (en) * | 1996-03-29 | 1997-10-01 | Procter & Gamble | Oxygen-releasing bleach composition |
| GB2311538A (en) * | 1996-03-29 | 1997-10-01 | Procter & Gamble | Detergent compositions |
| GB2311535A (en) * | 1996-03-29 | 1997-10-01 | Procter & Gamble | Detergent compositions |
| GB2311542A (en) * | 1996-03-29 | 1997-10-01 | Procter & Gamble | Percarbonate bleach composition |
| DE19704634A1 (de) | 1997-02-07 | 1998-08-27 | Henkel Kgaa | pH-gesteuerte Freisetzung von Waschmittelkomponenten |
| GB2329188A (en) * | 1997-09-11 | 1999-03-17 | Procter & Gamble | Detergent composition containing a stabilised percarboxylic bleaching system |
| JPH11217590A (ja) * | 1998-02-04 | 1999-08-10 | Kao Corp | 漂白洗浄剤組成物 |
| GB0004988D0 (en) * | 2000-03-01 | 2000-04-19 | Unilever Plc | Composition and method for bleaching a substrate |
| JP5206166B2 (ja) * | 2008-07-03 | 2013-06-12 | コニカミノルタＩｊ株式会社 | インクジェットインク及び液晶配向膜の形成方法 |
| GB0902959D0 (en) * | 2009-02-23 | 2009-04-08 | Reckitt Benckiser Nv | Composition |
| EP3050951A1 (en) * | 2015-02-02 | 2016-08-03 | The Procter and Gamble Company | Method of dishwashing |
| EP3050952A1 (en) * | 2015-02-02 | 2016-08-03 | The Procter and Gamble Company | Method of dishwashing |
| EP3050953B1 (en) | 2015-02-02 | 2018-12-26 | The Procter and Gamble Company | Detergent composition |
| US10280386B2 (en) | 2015-04-03 | 2019-05-07 | Ecolab Usa Inc. | Enhanced peroxygen stability in multi-dispense TAED-containing peroxygen solid |
| US9783766B2 (en) | 2015-04-03 | 2017-10-10 | Ecolab Usa Inc. | Enhanced peroxygen stability using anionic surfactant in TAED-containing peroxygen solid |
| EP3184601A1 (de) * | 2015-12-23 | 2017-06-28 | Agrana Beteiligungs- Aktiengesellschaft | Prozessfluid mit umweltverträglichem biostabilisator |
| CN109563452B (zh) * | 2016-09-07 | 2021-11-30 | 埃科莱布美国股份有限公司 | 含有由膦酸稳定的酶的洗涤剂组合物 |
| US11407965B2 (en) | 2017-07-31 | 2022-08-09 | Dow Global Technologies Llc | Detergent additive |
| WO2019027631A1 (en) * | 2017-07-31 | 2019-02-07 | Dow Global Technologies Llc | DETERGENT ADDITIVE |
| EP3662049B1 (en) * | 2017-07-31 | 2021-05-05 | Dow Global Technologies LLC | Encapsulation method |
| US10870818B2 (en) | 2018-06-15 | 2020-12-22 | Ecolab Usa Inc. | Enhanced peroxygen stability using fatty acid in bleach activating agent containing peroxygen solid |
| EP3693450A1 (en) * | 2019-02-08 | 2020-08-12 | The Procter & Gamble Company | Method of treating fabrics with automated pre-treatment of water |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES506859A0 (es) * | 1980-11-06 | 1983-11-01 | Procter & Gamble | Un procedimiento para preparar una composicion granular ac- tivadora del blanqueo. |
| US4378300A (en) * | 1981-12-10 | 1983-03-29 | Colgate-Palmolive Company | Peroxygen bleaching composition |
| GB2123044B (en) * | 1982-06-10 | 1986-02-05 | Kao Corp | Bleaching detergent composition |
| US4421664A (en) * | 1982-06-18 | 1983-12-20 | Economics Laboratory, Inc. | Compatible enzyme and oxidant bleaches containing cleaning composition |
| JPS59194000A (ja) * | 1983-04-18 | 1984-11-02 | 花王株式会社 | 漂白洗浄剤組成物 |
| US5130044A (en) * | 1987-10-30 | 1992-07-14 | The Clorox Company | Delayed onset active oxygen bleach composition |
-
1994
- 1994-04-13 GB GB9407535A patent/GB9407535D0/en active Pending
-
1995
- 1995-04-03 WO PCT/US1995/004085 patent/WO1995028464A1/en active IP Right Grant
- 1995-04-03 ES ES95915004T patent/ES2216011T3/es not_active Expired - Lifetime
- 1995-04-03 AT AT95915004T patent/ATE259412T1/de not_active IP Right Cessation
- 1995-04-03 DE DE69532559T patent/DE69532559T2/de not_active Expired - Fee Related
- 1995-04-03 EP EP95915004A patent/EP0755429B1/en not_active Expired - Lifetime
- 1995-04-03 AU AU22048/95A patent/AU2204895A/en not_active Abandoned
- 1995-04-03 BR BR9507379A patent/BR9507379A/pt not_active IP Right Cessation
- 1995-04-03 CA CA002187438A patent/CA2187438C/en not_active Expired - Fee Related
- 1995-04-03 JP JP52699095A patent/JP4393582B2/ja not_active Expired - Fee Related
- 1995-04-03 CN CN95193547A patent/CN1094514C/zh not_active Expired - Fee Related
- 1995-04-12 MA MA23833A patent/MA23505A1/fr unknown
- 1995-04-12 PE PE1995266408A patent/PE50595A1/es not_active Application Discontinuation
-
2001
- 2001-11-24 CN CN01139470.6A patent/CN1206334C/zh not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| GB9407535D0 (en) | 1994-06-08 |
| CN1094514C (zh) | 2002-11-20 |
| ATE259412T1 (de) | 2004-02-15 |
| BR9507379A (pt) | 1997-09-16 |
| DE69532559T2 (de) | 2004-12-16 |
| CN1206334C (zh) | 2005-06-15 |
| ES2216011T3 (es) | 2004-10-16 |
| JP4393582B2 (ja) | 2010-01-06 |
| PE50595A1 (es) | 1996-02-13 |
| CN1373180A (zh) | 2002-10-09 |
| MA23505A1 (fr) | 1995-12-31 |
| EP0755429B1 (en) | 2004-02-11 |
| WO1995028464A1 (en) | 1995-10-26 |
| EP0755429A4 (en) | 1998-07-29 |
| AU2204895A (en) | 1995-11-10 |
| CA2187438A1 (en) | 1995-10-26 |
| EP0755429A1 (en) | 1997-01-29 |
| JPH09512049A (ja) | 1997-12-02 |
| DE69532559D1 (de) | 2004-03-18 |
| CN1150451A (zh) | 1997-05-21 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKLA | Lapsed |
Effective date: 20130403 |