CA2155585C

CA2155585C - Process for activation of metal hydrides

Info

Publication number: CA2155585C
Application number: CA002155585A
Authority: CA
Inventors: Michael Edward Badding; Mark Thomas Mccormack; Donald Winslow Murphy; Brijesh Vyas
Original assignee: AT&T Corp
Current assignee: AT&T Corp
Priority date: 1994-08-17
Filing date: 1995-08-08
Publication date: 1998-09-22
Anticipated expiration: 2015-08-08
Also published as: DE69508508T2; JPH0867501A; US5560752A; EP0703633B1; CA2155585A1; DE69508508D1; EP0703633A1

Abstract

Metals useful in the formation of hydrides for applications such as batteries are advantageously activated by hydriding/dehydriding process. This process involves repeatedly stepping the potential of metal/metal hydride electrodes in electrochemical cells. The process activates hydrogen-storing materials that are difficult to activate by conventional means.

Description

2 1 ~ 5 PROCESS FOR ACTIVATION OF METAL HYDRIDES

BackF,I o.,l-J of the I~ nlion 1. Field of the Invention This invention relates to metal hydrides and in particular to processes 5 involving such hydrides.
2. Art Back~
Metal hydrides are used in a variety of ind~lstriql applications. Although there are many such applications, possibly the most prominent is the use of metal hydrides in batteries. For example, secondary nickel-metal hydride batteries employ 10 lanthqnllrn nickel hydride (or alloy modificadons) or other intermetallic hydrides in the negative electrode. A variety of other uses involving energy storage and transfer have been described. Irrespective of the application, a crucial step in preparation is activation of the hydrideable elem~nt, alloy, intermetqllic compound, or mixturethereof (referred to generally herein as "metals"). Activation increases the rate at 15 which the metal reacts with hydrogen or the extent to which hydrogen is incorporated into the intermetallic, thus making the met. l useful for energy storage and energy transfer applications.
Activation is believed to result from 1) removal of reducible surface oxides which tend to i~ltelrele with the funrtioning of the material in the ultim-qte 20 desired application; 2) reduction of particle size reslllting from an increase in volume, which fractures the metal particles; and (3) changes in the chemical composition and/or structure of the metal or the surface of the metal. Thus, activation, it is believed, increases the surface area and pell,aps alters the chP,mi~
composition and/or st~ucture of the metal and/or the surface of the metal, any 25 co-mbinqtion of which may lead to higher rates of reaction with hydrogen, enhancing the operation of tl e material for appliratio~ such as batteries or hydrogen storage.
Metals with this enhqnred chpmic~q~l reactivity toward hydrogen are referred to as activated.
Methods for activating metal hydAdes include: 1) hydAding with 30 hydrogen gas at high temperature and/or high pressul~; 2) hydriding with chemical hydAding reagents; 3) etching with reagents such as aqueous hydrofluoAc acid or hot potassium hydroxide; 4) electrochPmirql anodic o~ latiol~; and 5) conventional battery cycling of metal hydAde electrodes. Such methods can require relatively large e~ppn(litllres for suitable equipment and vary in their effectiveness, depending 35 upon the metal being activated. Thus, alternatives would be quite desirable.

2 1~ S ~

Summary of ~e Invention Activadon of metal hydrides is accomplished by incrementally hydriding and dehydriding the metal a plurality of times in a pulsed manner until the desired degree of activation is obtained. The metal is pulsed by subjecting the metal 5 to a hydriding force and a dehydriding force in an ~ltern~ting fashion. The metal is hydrided by exposing the metal to a hydriding force such as a hydriding potential, which introduces hydrogen into the metal, for a short period of time. The metal is then exposed to a dehydriding force such as dehydriding potential, which is thermodyn~mic~lly sllfficient to force hydrogen out of the metal, for a short period 10 of time. The pulsing cycle is then repeated a plurality of times until the metal is activated to the desired degree. For purposes of the invention, the forces in the pulsing cycle can be applied in either order, i.e. dehydriding force followed byhydriding force or vice-versa.
The extent to which the metal is activated depends upon the dll~tio~ of lS the individual pulses in the pulsing cycle, the switching times between pulses, and the number of such pulsing cycles. In this regard, it is advantageous if the metal is hydrided to some cignific~nt extent in each pulsing cycle, i.e. at least about one-tenth of one percent of its total capacity, but no more than about ten percent of its total capacity. To achieve this objective, the time of the individual hydriding force pulse 20 and dehydriding force pulse in each cycle will vary from metal to metal, but is typically about 10 to about 1000 seconds. It is advantageous from a proceccing perspective if the hydriding pulse time is the same as the dehydriding pulse time.
The metal is subjected to the hydriding force and the dehydriding force in a number of different ways. Examples of these forces include hydrogen pl'~S~Ult;S, 25 chemi~l o~ i7ing (e.g. ~2) and reducing (e.g. borohydride) agents, and ele~ h~mi~l pa~-nti~ls In a preferred embo~lim~nt. the metal is formed into an elect~ode. The electrode is then placed in an aqueous electroc-h~mi~l cell. The cell is stepped between a reducing potential and an o~ i7ing potential. The cell is stepped by ch~rlgjng from one potential to the other at a very fast rate, e.g. 103 V/sec 30 or more. The re~uçin~ potential is thermodynqmic~lly sufficient to cause a net flux of hydrogen into the metal. The oxidi_ing potential is thermodyn~mic~lly sufficient to cause a net flux of hydrogen out of the metal.
The potentials and the length of time that the metal is subjected to these potenti~lc is varied depending upon the free energy of the formation reaction of the 35 reSul~ing metal hydride and the free energies of other reactions such as corrosion of the metal or hydrogen gas evolution. The selPc~. ~ pot~nti~lc are thermodynamically 21SS~3~

sufficient to drive these reactions in the desired direction.
For ex~mple, an electrode made of equimolar parts zirconium (Zr), chromium (Cr) and nickel (Ni) is placed in an electrochPmic~l cell (with a conventional NiOOH/Ni(OH)2 counterelectrode, which is also used as a reference 5 electrode, in an electrolyte of 30% by weight KOH in water) and subjected to ahydriding potential (also referred to as a reducing potential) of about -1.25 V to about - 1.8 V for about 10 to about 1000 seconds. The electrode is then subjected to a dehydriding potential (also referred to as an oxi(ii7ing potential) of about -0.4 volts to about -1.2 volt for about 10 to 1000 seconds. The time taken to switch from the 10 hydriding potential to the dehydriding potential, or from the dehydriding potential to the hydriding potential, is about 0 seconds to about 2000 sec. The pulsed cycle is repeated a plurality of times.
The metals that form stable metal hydrides are generally known.
Typically, such metals are nickel-co.~ ining metal compounds. The other 15 components of the material are selPct~d using a variety of criteria Typically, such metals include what are typically referred to as the intermetallic AB 5 and AB 2m~t.eri~l~ wheleill A and B denote at least two dirÇe~el t metal components. Other metal components can be incorporated into these intermet~llic m~teri~l~. The Zr-Cr-Ni metal system (i.e. ZrCr2_"Ni,~ wl~lein 0.5 < x < 2) is provided as one 20 example of a m~teri~l that is activated to form a metal hydride using the process of the present invention. This metal system is not readily activated using other conve~tior~l activating processes. Examples of other metals that are activated by this process include Pd, Zr7 Ni l0 ,rl2 ,~ Ni,~ (0 < x < 1 ), Zrl_"A,~CrM(0<x<0.5; A=Ti,Hf), LaNis, A~ByCz(x<0~8~ y<0.8,z>0.2 25 andx+y+z=l; A=Ti, Zr,Hf, B=V, Cr, Mn, Fe, Co, Cu, Mo; C=Ni, Pd), and MmNi 3.s Al0.8 CoO.7, (Mm stands for ..~ etal, a miA~'~: of rare earths). The process is co~t~mpl~t~d as particularly useful for activating those m~teri~l~ that are not readily activated by other conventional processes. The process is also contempl~t~d to be used alone in activating metals or in combination with other 30 techniques for activating metals.
Brief D~scripl~on of ~e D~ n~
FIG. 1 is a graph of the capacity vs. the rate of discharge of a ZrCrM
electrode activated by the process of the present invention (pulsed) with a ZrCrNi electrode activated by collvelllional battery cycling.

21 555&5 Detailed Description Metals suitable for use in hydrogen absorption (hydrided)tdesorption (dehydrided) applications are activated for greater rates of hydrogen absorption and desorption by pulsing between a hydriding force and a dehydriding force a plurality 5 of times. Typical metals including elements, alloys, and intermetallic materials are employed in such conversions. Examples of such metals are Pd, Zr7Nilo,ZrCr2-xNix, Zrl-xA~crM~ Ti2_XNiX, LaMs, AXByCz~ and MmNi 3.5 Al 0 8Co0.7- Basically, for the inventive procedure to be advantageous, a metal should (1) be capable of forming a hydride with a hydrogen vapor pressure (at 10 the reaction temperature) of approximately 20 atmospheres or less, and (2) have an effective chemical hydrogen diffusivity of at least 10- 16 cm2/sec. at the reaction temperature (usually approximately 23~C.) A subset of such materials that are useful includes the metals corresponding to hydrides that produce an electromotive force when employed in a nickel oxide/metal hydride battery.
Vapor pressures of hydrogen for metal hydrides are available in references such as E. L. Huston and E. D. Sandrock, Journal of Less Common Metals, 74, p. 435-443 (1980) or Topics in Applied Physics, 63, L. Schlapbach, ed., Springer-Verlag,Berlin, 1988.
Chemical hydrogen diffusivity data is determined with sufficient accuracy in this 20 context from information in Topics in Applied Physics, 67, L. Schlapbach, ed., Springer-Verlag, Berlin, 1992. Typically, self diffusion rates of hydrogen in metals are measured. However, because the M - MH x system is generally two phases rather than a single phase with variable x, it is possible that the chemical diffusion rate is greater than the measured amount by several orders of m~gnitude. Since the 25 measured value is likely to be less than the actual value, it is clear that metals with a measured diffusivity of greater than 10-16cm2/sec will satisfy the criterion. If the measured self diffusion rate is lower than the desired value, however, it is possible to increase the rate by increasing the temperature.
In the activation process described, electrodes comprised of hydrideable 30 metals such as the metals listed above are used. The process is designed to rapidly and repeatedly expose the metal to chemical potentials that are thermodynamically sufficient to either cause hydriding and dehydriding of the metal. This is accomplished by hydriding and dehydriding the metal alternately in a pulsed cycle and repeating that cycle a plurality of times. The metal is hydrided incrementally in 35 each pulsing cycle. For example, one pulsing cycle causes the metal to be hydrided to some extent, i.e. at least about 0.1 percent of the total capacity of the metal.
A

21~S58~

However, one pulsing cycle does not hydride the metal more than about ten percent of its total capacity. By repeatedly pulsing the metal with the hydriding and dehydriding forces, the desired effect is obtained.
In a preferred embodiment the desired hydriding and dehydriding 5 chPmics1 potentials are applied electrochemirs11y at room ~I-pe~ture. Appropriate electroch~mics1 potentials for hydriding or dehydriding a metal are determined from the hydrogen vapor pressures of metal hydrides using the Nernst equation for aqueous electrochemical cells:

E=Eo-o.o59l(pH)-o-o295log(pH2) (1) 10 where PH2 is the hydrogen vapor pl~S~iW'~ of the hydride, pH is the negative logarithm of the hydrogen ion concentration of the electrolyte, and Eo is the standard potential for the aqueous envilon.l~,-~
Thus, for a metal hydride with a hydrogen vapor p,~s~uu~ of oneatmosphere in an aqueous electroch~mir~l cell with a pH of l0, applied potentials lS (E) that are less than -0.59l volts measured relative to the standard hydrogen electrode are thermodyn~mirs11y sufficient to cause hydriding and applied potentials that are greater than -0.59l volts are thermodynsmir-s-11y sufficient to cause dehy~ri~ing The rate of hydriding is increased as the hydriding potential is made more negative and the rate of dehydriding is increased as the dehydriding potential is 20 made more positive. Thus it is desirable to make the hydriding potential as negative as possible and the dehydriding potential as positive as possible while avoiding, to a ~ignificsnt extent, side reactions such as hydrogen gas formation or corrosion of the metal. It is advantageous for the pot~ntis1Q to be applied for shon periods of time, e.g. less than one minute, with respect to times required to fully hydride/dehydride 2S the metal, which is typically in excess of one hour. It is also advantageous for the pot~ntis1Q to be rapidly switched be~ween the hydriding and dehydriding potentials a plurality of times.
In a preferred embodiment an electrode made of ZrCrM is used as the working electrode and a conventional NiOOH/Ni(OH) 2 (nickel) electrode is used 30 as the counter electrode in an electroch~mi~1 cell co,.l~ining an electrolyte that is 30% by weight KOH (pH=14.8) in an aqueous solution. The potential of the nickel electrode is about +0.385 V in this electrolyte relative to the standard hydrogen electrode. Thus, the voltage of the hydriding/dehydriding potential measured with respect to the nickel electrode is given by:

2155~8~

Emea6 =--0.38S--0.591 (pH)--0.02951Og(PH2 ) (2) When activation is carried out in such an electrochemical cell, the cell is capable of being used directly as a battery after such activation process without reassembly.
However, it is also contemplated that the material will be removed from the 5 activation cell, washed with water, dried, and remade into another electrode without loss of activation. Similarly, if the activated m~tçli~l is transferred into a system for reaction with hydrogen gas, there is no need to activate the material again before it is hydrided.
The hydrogen vapor pr~ssul~ in the ZrCrNi system is about 0.01 to 10 about one atmosphere, depending upon the hydrogen content of the metal. A
hydriding potential of about -1.25 V or less (more negative) is selected by solving for Eme~ in equation (2) using a PH2 of one atmosphere and a pH of 14.8. This isthe potential needed to drive hydrogen into the metal where the hydrogen content in the metal is near the maximum. A dehydriding potential of about -1.2 V or greater 15 (less negative) is selected by solving for Eme~ in equation (2) using a PHt of 0.01 atm. This is the potential needed to drive hydrogen from the metal when theconcentration of hydrogen in the metal is near its minimum. In the pl~felled embodiment, a metal electrode is activated by holding the voltage in the previously described electrochpmic~l cell at a reducing (hydriding) potential of about -1.7 V
20 (vs. the nickel electrode) for about 50 seconds. The voltage is then stepped to an oxi~i7ing (dehydriding) potential of -1 V (vs. the nickel electrode) for about 50 seconds. The cycle is repeated until the metal is activated to the desired extent.
To completely activate the ZrCrNi electrode, the cycle is repe~te-d continuously for at least about one hour up to thirty-six hours or more. Typically the ZICrNi system 25 is activated in about eight to about twenty-four hours using the described process.
Under these con(1ition~ the extent to which the metal is hydrided and dehydrided per cycle is less than about 1% of the total possible.
The following Examples are illustrative of conditions useful in the invention.

30 Example 1 Equimolar amounts of Zr, Cr, and Ni were combined to provide one gram of the metal mixture ZrCrNi. The metals were melted together in an arc furnace under a gettered argon flow. The rçsl~lting button was turned over and re-melted three times to increase its homogeneity. The button was then ground in an air 215~S85 atmosphere and sieved so that the particle size was about 53 microns or less.
An electrode was then formed from the material by pressing 300 mg of the powder between two Ni mesh screens using a 1/2 inch die under 6,000 kg of force. An electrochemical cell was assembled by placing the ZrCrNi electrode S between two 1.5 inch square NiOOH/Ni(OH)2 counter electrodes. Polyplup~lene separator material was inserted between the electrodes. The electrodes were placed in an open beaker conl~ining an electrolyte solutdon of aqueous KOH (30% by weight).
The electroch-pmic~l cell was electri~lly pulsed under the following 10 conditions. The cell was first subjected to a potential of -1 volt for 50 seconds. The potentdal was then stepped to a potendal of -1.7 volts and held there for 50 seconds.
The potential was then stepped back to the -1 volt potential to complete one cycle.
The cycle was repeated continuously over a period of twenty-four hours. For purposes of these examples, a step change in the voltage is a change at a rate of at 15 least 103V/sec.
Following the pulse activation of ZrCrNi as previously described, an analysis of particle size by light scattering showed no ~igllific~nt reduction in overall particle size. Several physical char~tPri7~tion techniques showed that the metal on the surface of the particle is depleted of Cr and has a reduced Zr content relative to 20 the unactivated ZrCrNi. The surface of the particle also contained oxidized Zr.
Conseg~ntly, the surface of the activated ZrCrNi was ~ele.~inPd to be Ni-rich compared to the unactivated m~eri~l, The m~netic susceptibility of the activatedZrCrNi showed a ferrom~netic component with a susceptibility similar to that of amorphous Zr ~ Ni ~ (x < 0. 2 ) which is known to form metal hydrides. Although 25 app1ic~nt~ do not wish to be held to a particular theory, applicants believe that: 1) an amph~rous Zr,~Ni 1-~ surface may act as a corrosion protecting layer that can s~ l hydrogen at high rates; andJor 2) that pulse activation increases the mlclP~tion sites in the bulk metal thereby increasing the rate at which the metal is hydrided and dehydrided.

30 Example 2 After the ZrCrNi electrode was activated as in Example 1, the electrode was cycled in the same electrochemical cell as a battery electrode i.e., the electrode was charged at a constant current of 10 mA for 13 hours and then discharged at aconstant current of 10 mA until the voltage reached 1 V. The pulse-activated 35 electrodes delivered a capacity of 272 mA-h/g on the first battery cycle. Another 215a~5 electrode, prepared as described in Example 1, but with no activation other thanbattery cycling delivered a capacity of 210mA-h~g after 15 battery cycles.
Subsequent to this test, both electrodes were battery cycled at increasing rates of discharge, from 5 mA to 50 mA. As shown in FIG. 1, the pulse-activated S electrode had a significantly higher capa~ily at all discharge rates, which demonstrated the enh~nced rate capability of the pulse-activated material compared to the electrode that was activated by conventional battery cycling.
Example 3 Electrodes made of various m~teri~le were cor,sllucled and pulse 10 activated in an electrochpmir~l cell as described in Example 1. The electrochemical cells cont~ining electrodes made of these materials were then subjected to convention~l battery cycling. The m~tPn~le of which these electrodes were made are enumerated below. The capacities delivered on the first battery cycle (in mA-hr/g) follow each material in pare~thesi~. The m~t~ri~le were:
15 Zr7 Nil0(142), ZrCrl.l M o,9(350),ZrCrl.2NiO.g(327),ZrO.8TiO.2CrNi(336), ZrO.7TiO.3CrNi(311), ZrO.gHfO.lCrNi(260), ZrO.21VO.42NiO.37(280)~
ZrVNi(270), LaNis (320), and Ti3 Ni2 (250). Each of these materials demonstrateda higher capacity than materials activated by conventional battery cycling. For example Zr7 Ni 1O that was activated by battery cycling had a capacity of about 20 50 mA-hr/g.
A commercial sub-micron Pd powder was also constructed a~e an electrode, again using the techniques described in Example 1. The electrode was then pulse activated as described in F~mple 1 and had a res~llting capacity of 200 mA-hr/gm.
25 Example 4 ElectrochPmic~l cells cont~ining a ZrCrNi electrode prepared as desrr ~d in FY~mrlP 1 were subjected to pulsed activation cycles under a variety of con~iti~ne to dc~ inP, the effects of these conditions on electrode perfon~nce Specific~lly, the hydriding potential (samples a-d), the dehydriding potential 30 (samples e-k), the time interval to which the sample was subjected to a particular potential (samples l-n), the rate of change from one potential to the other (~eamples o~) and the total time that the electrode was pulsed (s~mples r-u) were varied. A
"step" rate of change is a rapid change in voltage at a rate of 1000 V/sec. These con~itiol-~ and their effect on electrode capacity at a discharge current of 35 mA, are 35 slln m~ri7~d in Table 1 below. Generally c~p~cities of 200 mA-hr/g or higher are desired for acceptable electrode pelço~ nce.

21~558~
-g Table I
Oxidizing Reducing Potential Time Rate of Total Pulse Sample Potential Potential Interval Change Time Capacity (s) (mV/s) (hrs) (mAhr/g) a - V -.~5V 5-~ sep 2 b -.. V -....~ V J sep ~ .
c - . V -. .-~ V ~ s;ep d - . V -... ..V J sep e - .~ 1 V -. .~ V ~ s-ep f - . V -. .~ V s-ep ~' ~~
- .~ V -. .7 V s;ep -~ _J' )V -... 7V sep ' ' V - .. 7 V ~ s ;ep -. . . V -... 7 V J s-ep ' ~ . -.. ' V -. .7 V J s-ep .71 V .. s-ep ' '~
m - V - .~ lV 0 sep -~ ~f7 n -. V -. .~ 1 V . ~0 ~ p ~ ~
O - V -. . ~ V _ . O ~ f75 p -. V -. . I V J . - ~ O
q - V -. . V _ _ ~ .. _ r -. V -. .~ V J s-ep S -. V -.. - V J s-ep -~7 t -. V -.. ~ V J s;ep ~' f.
u - V -.7~ V s-ep 2 Example S
A 369 mg. sample of ZrCrNi, activated by the tre~tm~.nt of Example 1 was removed from the cell, washed with water and dried in vacuum. This material was loaded into a thermogravimetric analyzer for measurement of H 2 gas absorption at room temperature. After the atmosphere was evacu~ted, H2 gas was added to a pressure of 46 atmospheres. In five min1~t~s the sample had absorbed 1.2% by wt. of hydrogen. In a sep~ate thermogravimetric experiment~ another 369 mg sample of ZrCrNi that had been activated by adding and removing hydrogen gas from the sampb several times absorbed only 0.45% by wt. hydrogen in five minl1tes

Claims

1. A process for activating a metal comprising subjecting a metal to a pulse of hydriding force alternated with a pulse of dehydriding force wherein each combination of a hydriding force and a dehydriding force is denominated a pulsedcycle and wherein the metal is subjected to the pulsed cycle a plurality of times, wherein each pulsed cycle is for a period of time sufficient to hydride the metal in the range of about one-tenth of one percent of its hydride capacity to about ten percent of its hydride capacity.

2. The process of claim 1 wherein the hydriding force is a hydriding potential and the dehydriding force is a dehydriding potential.

3. The process of claim 2 wherein the hydriding potential and the dehydriding potential are electrochemical potentials.

4. The process of claim 1 wherein the metal is selected from the group consisting of ZrCr2-x Nix, wherein 0.5< x <2,Pd,Zr7 Ni 10, LaNi5, Ti2-x Nix, wherein 0< x <1,Zr 1-x TiX CrNi, wherein 0 <x < 0.5, Zr1-x Hfx CrNi, wherein 0<x<0.5, Ax ByCz wherein x<0.8,y<0.8, z>0.2 and x+y+z= 1 and A is Ti, Zr, or Hf, B is V,Cr, Mn, Fe, Co, Cu, or Mo,and C is Ni or Pd, and MnNi3.5 Al0.8 Co0.7.

5. The process of claim 3 wherein the metal is selected from the group consisting of ZrCr2-x Nix, wherein 0.5 < x < 2,Pd,Zr7Ni10, LaNi5, Ti2-x Nix, wherein 0 < x < 1,Zr1-x Ti x CrNi, wherein 0 < x < 0.5, Zr1-x Hf x CrNi, wherein0<x<0.5, AxByCz wherein x<0.8,y<0.8, z>0.2 and x+y+z= 1 and A is Ti, Zr, or Hf, B is V, Cr, Mn, Fe, Co, Cu, or Mo, and C is Ni or Pd, and MnNi3.5 Al0.8 Co0.7.

6. The process of claim 3 wherein the metal is an intermetallic composition of the general formula ZrCr2-x Nix, wherein x is about 0.5 to about 2.

7. The process of claim 3 wherein the metal is an intermetallic composition of the general formula Ti2-x Ni, wherein x is about 0 to about 1.

8. The process of claim 3 wherein the metal is an intermetallic composition of the general formula Zr1-x Ax CrNi, wherein x is about 0 to about 0.5 and A is selected from the group consisting of Ti and Hf.

9. The process of claim 3 wherein the metal is an intermetallic composition of the general formula AxByCz wherein x is less than about 0.8, y isless than about 0.8 and z is greater than about 0.2 and A is selected from the group consisting of Ti, Zr, and Hf, B is selected from the group consisting of V, Cr, Mn, Fe, Co, Cu, and Mo, and C is selected from the group consisting of Ni and Pd.

10. The process of claim 2 wherein the hydriding potential is at least thermodynamically sufficient to drive hydrogen into the metal and the dehydriding potential is at least thermodynamically sufficient to drive hydrogen from the metal.

11. The process of claim 3 wherein the hydriding potential is about -1.25 V to about -1.8 V and the dehydriding potential is about -0.4 V to about -1.2 V
with respect to a conventional nickel electrode in an aqueous solution that contains about thirty percent by weight KOH.

12. The process of claim 5 wherein the hydriding potential is about -1.25 V to about -1.8 V and the dehydriding potential is about -0.4 V to about -1.2 V
with respect to a conventional nickel electrode in an aqueous solution that contains about thirty percent by weight KOH.

13. The process of claim 11 wherein the metal is subjected to the hydriding potential pulse for about 10 to about 1000 seconds and subjected to the dehydriding potential pulse for about 10 to about 1000 seconds and the pulsed cycle is repeated continuously over a period of time sufficient to activate the metal to the desired degree.

14. The process of claim 12 wherein the metal is subjected to the hydriding potential pulse for about 10 to about 1000 seconds and subjected to the dehydriding potential pulse for about 10 to about 1000 seconds and the pulsed cycle is repeated continuously over a period of time sufficient to activate the metal to the desired degree.

15. The process of claim 13 wherein the period of time sufficient to activate the metals is from about 1 to about 36 hours.

16. The process of claim 14 wherein the period of time sufficient to activate the metal is from about 1 to about 36 hours.

17. A process for fabricating a battery comprising the steps of forming a metal or metal hydride electrode, inserting the electrode in a battery, wherein the metal electrode or metal hydride electrode is activated by subjecting the metal electrode or metal hydride electrode to a pulse of hydriding force alternated with a pulse of a dehydriding force, wherein each combination of a hydriding force and a dehydriding force is denominated a pulsed cycle and wherein the metal electrode or metal hydride electrode is subjected to the pulsed cycle a plurality of times, wherein each pulsed cycle is for a period of time sufficient to hydride the metal electrode or metal hydride electrode in a range of about one-tenth of one percent of its hydride capacity to about ten percent of its hydride capacity.

18. The process of claim 17 wherein the hydriding force and the dehydriding force are electrochemical potentials.

19. The process of claim 18 wherein the electrode is a metal selected from the group consisting of ZrCr2-xNix, wherein 0.5<x<2,Pd,Zr7Ni10, LaNi5, Ti2-xNix, wherein 0<x<1,Zr1-xTixCrNi, wherein 0<x<0.5, Zr1-xHfxCrNi, wherein 0<x<0.5,AxByCz wherein x<0.8,y<0.8, z>0.2 and x+y+z=1 and A is Ti, Zr, or Hf, B
is V, Cr, Mn, Fe, Co, Cu, or Mo, and C is Ni or Pd, and MnNi3.5Al0.8Co0.7.

20. The process of claim 19 wherein the hydriding force is an electrochemical potential of about -1.25 V to about -1.8 V and the dehydriding force is an electrochemical potential of about -0.4 V to about -1.2 V with respect to a conventional nickel electrode in an aqueous solution that contains about thirty percent by weight KOH.

21. The process of claim 20 wherein the metal electrode is subjected to the hydriding potential pulse for about 10 to about 1000 seconds and subjected to the dehydriding potential pulse for about 10 to 1000 seconds and the pulsed cycle isrepeated continuously over a period of time sufficient to activate the metal electrode to the desired degree.

22. The process of claim 21 wherein the period of time sufficient to activate the metal electrode is from about 1 to about 36 hours.