CA1335631C - Light curing apparatus and method - Google Patents

Light curing apparatus and method

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Publication number
CA1335631C
CA1335631C CA 602255 CA602255A CA1335631C CA 1335631 C CA1335631 C CA 1335631C CA 602255 CA602255 CA 602255 CA 602255 A CA602255 A CA 602255A CA 1335631 C CA1335631 C CA 1335631C
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Canada
Prior art keywords
light
dental
light source
mouth
shape
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CA 602255
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French (fr)
Inventor
Robert V. Hare
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Dentsply Sirona Inc
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Dentsply International Inc
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Abstract

A light-curing apparatus for curing polymeriz-, able material in the mouth is provided. In one embodi-ment the apparatus comprises a wand which is substan-tially the same size as a quadrant or a full dental arch; in a second embodiment, the apparatus is in the shape of a dental tray and is adapted to fit over the outside of a dental tray; and in a third embodiment the light source comprises a portion (substantially the frame) of a double arch impression tray, and has a slide mechanism by which the mesh of a double arch impression tray can be removed from the light source so the light source can be reused. The invention also comprises a method for curing a dental material in the mouth using the apparatus of the invention.

Description

~ 1335631 LIGHT CURING APPARATUS AND METHOD
BACKGROUND

The present invention relates to a light apparatus adapted for fitting over an impression tray and a method for curing a light polymerizable impression material while the impression material is in contact with an area of which an impression is desired.
The use of visible light cured polymeric impression materials such as those disclosed in Canadian application 486,491 filed July 9th, 1985; US Patent 4,813,875; and Canadian application 551,383 filed November 9th, 1987, are gaining aceptance as a desirable means of obtaining a dental impression.
Such polymeric materials can be adapted to be dispensed from a syringe or used ~ith an impression tray. Such a visible light cured polymeric impres~ion mater~al is sold under the trademark GENESIS~H by Dentsply International Inc.
Some prior art impression trays have been provided with means for piping light into the tray to cure the impression material as described by Wang in U.S. Patent 4,553,936. Such trays, though convenient are relatively expensive.
It is desirable in many uses to provide the impression material in a disposable tray, and to provide a light source in a more permanently reusable form.
Whether the impression material is preloaded in the impression tray in the factory according to Canadian Patent 1,287,753, issued August 21st, 1991 and US Patent 4,867,682, assigned to Dentsply International Inc., or loaded by the practitioner immediately before use, a key to the convenience and usability of such a material is a rapid cure to a strong and elastomeric material when actinic light is applied to the material at the convenience of the practitioner. In the past, such actinic light was provided as a point source, such as is the conventional adaptation of a PRISMETICSR LITE apparatus, available from the L.D
Caulk Company, a division of Dentsply International Inc. The point source in the PRISMETICSR LITE apparatus is a light-issuing tip having a diameter of less than about 1.5 cm. When a point light source can be used, the practitioner must move the point source from point to point over the impression tray to cure all the material in the tray. Although it may take only 10-20 seconds at a particular point to cure that portion of the impression material sufficiently, in a ~ , 133~63l typical full dental arch tray, which has hard-to-reach areas and a surface area of about 60 cm2, it may take as much as 2-5 minutes, or more, to cure all the impres-sion material in the tray.
Also, in some circumstances, it is desirable to cure the impression material evenly over the whole surface rather than cure one side of the tray, and then the other side of the tray in sequence.
In prior art point source devices, used alter-nately to cure small fillings in the mouth, the inten-sity of the light source is limited by its possible effect on the retina of the human eye. Sources with intensity greater than about 1 w/cm2 may be hazardous and accordingly fall outside the Commercial National Standard draft specifications and ADA Standards for such devices.
It is an object of the present invention to provide an apparatus and a method by which the time required to cure the impression material when a dental impression is made is reduced.
It is a further object of the present invention to provide an apparatus and a method by which substantially all of the impression material in a dental tray may be cured substantially at the same time.
It is another object of this invention to ~ 13 3 ~ 63 1 ~4053-206 substantially, uniformly increase the quantity of light issuing from a high intensity point source to be distributed over a large area without necessarily increasing the overall intensity of the light per unit area.
It is yet another object of this invention to cure the impression in shorter periods of time than with a conventional point source light.
summarY of the Invention In accordance with one aspect of the invention there is provided a method of simultaneously uniformly curing dental impression material positioned in a patient's mouthr comprising simultaneously emitting light from a plurality of light emitting means positioned substantially uniformly along the length of said impression material.
In accordance with another aspect, the invention may be ~ummarized as a method of polymerizing a light polymerizable elastomeric dental impression material in the U-shape of a dental arch while said dental material is in contact with structure in the mouth, comprising: the steps of sequentially ~a) providing an element and a housingr said element comprising a U-shaped tray and a housingr said housing having U-shaped bottom and inner and outer side walls connected to form a trough adapted to support light curable materialr said tray being adapted to be positioned within said troughr said housing having a web formed from a plurality of optic fibers having unclad portions and corresponding in general configuration to at least a substantial portion of a dental arch shape, B

1 ~ 3 ~ 6 ~ 1 640s3-206 ~ b) placing a dental impression material directly over the un~lad optic LibeL poLtioII~ OL ~ald web, (c) placing said web with said dental impression material thereon in a mouth and forming a dental impression, (d) transmitting light from said unclad portions of said optic fiber web and polymerizing the light polymerizable dental impression material and forming an elastomeric dental impression.
In accordance with another aspect, the invention may be summarized as a method of polymerizing a light polymerizable dental material in the shape of a dental arch while said dental material is in contact with structure in the mouth and providing an outwardly exposed surface, comprising: the steps of sequentially (a) providing a light source means for generating light having a U-shape dental arch shape, (b) placing said dental material in a desired position in a mouth, (c) placing said light source next to said dental material, and (d) transmitting light from said light source substantially, uniformly over at least a substantial portion of an outwardly exposed surface of said dental material to polymerize said material, preferably said dental material being polymerized in less than about 5 seconds and said light source being operated at an intensity of less than about 0.5 w/cm2, having a light transmitting area of at least about 10 cm2 and emitting light limited substantially to the wave bands of about 360-600 nm.
Preferably the dental material is dental impression material, reline material or orthodontic appliance material.
Also preferably said element has a bottom and sidewalls attached to said bottom on both sides thereof to form a trough adapted to fit over the outside of an impression tray, and said light source is adapted to transmit light through said bottom and said sidewalls, at substantially normal angles to said bottom and said sidewalls into said trough.
The invention provides a method of polymerizing a light polymerizable U-shaped dental material while said dental material is in contact with structure in the mouth, comprising:
the steps of sequentially (a) providing a light source adapted to correspond in general to a U-shape, (b) placing said dental material in a desired position in a mouth, ~ c) placing said light source next to said dental material, and (d) transmitting light from said light source substantially uniformly over at least a substantial portion of an outwardly exposed surface of said dental material to polymerize said material, wherein said light is transmitted from said light source in said U-shape and wherein said light source comprises a vacuum bulb having a U-shape.

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In some embodiments said light source is selected from the group consisting of a series of light emitting devices and light transmitting optic fibers distributed so as to transmit light substantially uniformly from a surface of said light source.
The invention also provides a method of polymerizing a light polymerizable dental material while said dental material is in contact with structure in the mouth, comprising the steps of:
(a) providing a light source means for generating light having a U-shape and sized to fit in a mouth in alignment with at least a portion of a dental arch, said light source being adapted to transmit light and said light source comprises a vacuum bulb having a dental arch U-shape, and (b) providing means for transmitting light from said light source substantially uniformly over at least a sub~tantial portion of an outwardly exposed surface of said dental material to polymerize said material, and ~c) polymerizing said material.
The invention provides a method for polymerizing light curable dental material in the mouth, comprising the steps of:
providing a light source transmitting visible wave-length light and having a shape and size conforming substantially to a configuration of a U-shaped dental arch and sized to fit in the mouth, said light source comprising an unclad optic fiber having a fiber wall which transmits light along its length and delivers light from said fiber wall along its length for polymerizing 6a C

said light curable dental material in the mouth and polymerizing said material in the mouth.
Preferably the unclad fiber is exposed for direct contact with the polymerizing light curable dental material in the mouth.
The invention also provides a method of polymerizing a light polymerizable dental material in the U-shape of a dental arch while said dental material is in contact with structure in the mouth, comprising2 the steps of sequentially (a) providing a light source comprising a vacuum bulb and having a general U-shape in a plane and emitting light substantially from said plane, (b) placing said dental material in a desired position in the mouth, (c) placing said light source next to said dental material, and (d) transmitting light from said light source substantially, uniormly over at least a substantial portion of an outwardly exposed surface of said dental material to polymerize said material.
The invention also provides a method of polymerizing a light polymerizable dental material in the U-shape of a dental arch while said dental material is in contact with structure in the mouth comprising the steps of sequentially (a) providing an element and a housing having a light source, said element comprising a U-shaped tray, said housing having U-shaped bottom and inner and outer side walls connected 6b .

~ 64053-206 to form a trough adapted to support light curable material, said tray being adapted to be positioned within said trough, said light source comprising a series of light emitting devices adapted to distribute light substantially uniformly over an adjacent surface of said light curable material, (b) placing said light source next to said dental material, and ~d) transmitting light from said light source substantially, uniformly over at least a substantial portion of an outwardly exposed surface of said dental material to polymerize said material.
The invention also provides a method of polymerizing a light polymerizable elastomeric dental impression material in the shape of a U-shaped dental arch while said dental impression material is in contact with structure in the mouth, comprising:
the steps of sequentially (a) providing a light source means for generating light having a U-shape adapted to distribute light ~rom a curved side portion of a dental arch U-shape, ~b) placing a dental impression material in a desired position in a mouth, (c) placing said light source in said mouth next to said dental impression material, and ~d) emitting and transmitting light from said light source substantially uniformly directly over at least a substantial portion of an outwardly exposed surface of said dental impression material along a substantial portion of a dental arch 6c 133~631 U-shape to polymerize said material and form an elastomeric dental impression.
The invention further provides a method of curing dental material, comprising:
providing an element having a U-shape and size conforming to a curved substantial portion of a dental arch and adapted to support light curable dental material, and optical fibers in said element positioned in a U~shape along at least a substantial portion of the length of said element, positioning said element in a mouth adjacent to light curable dental material ! and transmitting light from said optical fibers in a U-shape to said curable dental material.
The invention additionally provides a method of curing dental material, comprising:
providing an element having a shape and size conforming to a curved substantial portion of a dental arch, and a light generator in said element positioned along at least a substantial portion of the length of said element~
positioning said element in a mouth adjacent to light curable dental material, and transmitting light from said generator to said curable dental material wherein said light generator comprises a vacuum bulb.
In accordance with another aspect, the invention may be summarized as a visible wavelength light source for 6d C

1 3 ~ ~ 6 3 1 64o53-2o6 polymerizing light curable dental material in the mouth, comprising:
(a) an element having a shape and size conforming substantially to a U-shaped configuration of a dental arch~
(b) means for generating light, said means for generating light having at least one filament within a gas containing bulb, said bulb being supported by and positioned within said element, said means for generating light having means to be connected to supply electricity to said bulb, and (c) a light transmitting means having a U-shaped bottom member and two side members connected to said bottom member and adapted to be removably connected to said element, said light transmitting means being adapted to hold said dental material in proximity to said element.
Preferably said light transmitting means comprises an optical fiber web to which dental material may be.applied on both sides thereof, and wherein said optical fibers of said web area adapted to emit liqht from the surfaces thereof to cure said dental material in contact with said optical fiber web.
In accordance with another aspect, the invention may be summarized as a dental light for polymerizing a light polymerizable dental material while said dental material is in contact with structure in the mouth, comprising:
~a) a light source having a dental arch U-shape and sized to fit in a mouth in alignment with at least a portion of a dental arch, said light source transmitting light in said arch shape and said light source being selected from the group 6e consisting of a series of light emitting devices and light transmitting optic fibers distributed so as to transmit light substantially uniformly from a surface of said light source, and (b) means for transmitting light from said light source substantially uniformly over an outwardly exposed surface of said dental material to polymerize said material, (c) a tray for supporting said material, said tray having a U-shaped bottom wall integrally connected to inner and outer U-shaped side walls.
In accordance with another aspect, the invention may be summarized as a dental light for polymerizing a light polymerizable elastomeric dental impression material while said dental impression material is in contact with structure in the mouth, comprising:
(a) a light source being adapted to distribute light from and to be ~upported by a U-shaped dental arch and curved to conform with such substantial portion of said dental arch and sized to fit in a mouth in alignment with at least a portion of said dental arch, said light source transmitting light in said general configuration of said dental arch, and (b) said light source comprising light emitting and light transmitting sources selected from the group consisting of a series of light emitting devices and a plurality of light transmitting optic fibers and said light emitting and transmitting sources being positioned to emit and transmit light substantially uniformly over at least a substantial portion of an outwardly exposed surface of dental impression material in a 6f 1 3 3 ~ 6 3 1 64053-206 tray placed in position for taking a dental impression in the mouth and sufficient to polymerize the dental impression material and form an elastomeric dental impression and a tray, said tray having a U-shaped bottom wall integrally connected to inner and outer U-shaped side walls.
This invention provides a visible wavelength light source for polymerizing light curable dental material within the mouth, comprising:
(a) an element adapted to support light curable dental material in the mouth, and ~ b) means for generating light in said element, said element having a U-shape length and a size conforming substantially to the configuration of a dental arch, said element having a U-shaped bottom wall, integrally connected to inner and outer U-shaped side walls, said element having a light emitting surface area of at least about 5 cm2, and said means for generating light being integrally connected to said element said means for generating having a light source selected from the group consisting of an optical fiber and a bulb having a filament, said light source being supported by and substantially evenly distributed along said length of said element, and being adapted to transmit light substantially uniformly onto said dental material.
Preferably the light source is adapted to transmit light through an impression tray to cure a polymerizable material contained therein.

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The invention also provides a visible wavelength light source for polymerizing light curable dental material in the mouth, comprising:
(a) an element having a shape and size conforming substantially to a U-shaped configuration of a dental arch, (b) optic fiber means adapted for emitting or transmitting light, said optic fiber means having the shape of a dental arch and being contained within said element, and (c) a removable light transmitting means having a bottom member and two side members connected to said bottom member and adapted to be removably connected to said element, said light transmitting means having a shape and size conforming substantially to a U-shaped configuration of a dental arch said light transmitting means being adapted to hold said dental material in proximity to said element.
This invention additionally provides a visible wavelength light source for polymerizing light curable dental material in the mouth, comprising: an element having a bottom member and side members and a shape and size conforming substantially to a U-shaped configuration of a dental arch, (a) means for generating light in said element having optical fibers position in a U-shape and adapted to distribute light along at least the majority of said dental arch, and (b) a light transmitting means having a bottom member and two side members connected to said bottom member, adapted to be removably connected to said element, said light transmitting means being adapted to be supported by said bottom and side 6h G

133~631 members of said element, and to hold said dental material in proximity to said element.
The invention further provides a dental light for polymerizing light curable dental material in the mouth, comprising: a light source transmitting visible wavelength light and having a shape and size conforming substantially to a dental arch and sized to fit in the mouth, said light source comprising a plurality of at least partially unclad optic fibers formed into a web, each of said unclad optic fibers having a fiber wall adapted to transmit light along at least a portion of its length and to deliver said light from a sufficient portion of the length of said wall where it is unclad into adjacent light curable dental material for substantially polymerizing said light curable dental material in a tray, said tray having a U-shaped bottom wall integrally connected to inner and outer U-shaped side walls.
The invention also provides a dental light for polymerizing light curable dental material in the mouth, comprising: a light source transmitting visible wavelength light and having a U-shape and size conforming substantially to a dental arch and sized to fit in the mouth, said light source comprising a plurality of at least partially unclad optic fibers formed into a web, each of said unclad optic fibers having a U-shaped length of unclad fiber wall and being adapted for transmitting light along at least a portion of said length and delivering said light from said unclad fiber wall for polymerizing said light curable dental material in the mouth.

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13~S~31 64053-206 The invention provides a vislble wavelength light source apparatus for polymerizing light curable dental material in the mouth, comprising:
an element having a shape and size conforming to at least a curved substantial portion of a dental arch and adapted to support light curable dental material, and optical fibers supported within said element and positioned along at least a majority of the length of said element, said element comprising a U-shaped tray and a housing, said housing having U-shaped bottom and inner and outer side walls connected to form a trough adapted to support light curable material, said tray being adapted to be positioned within said trough.
The invention also provides a visible wavelength light source apparatus for polymerizing light curable dental material in the mouth, comprising:
an element having a shape and size conforming to at least a curved substantial portion of a dental arch, and means for generating light in said element, said means for generating light being positioned along at least a majority of the length of said element, said element including two sides connected in a U-shape.
The invention provides a system for polymerizing light curable dental material in the mouth, comprising:
an element, said element having a U-shape and size canforming substantially to a configuration of a dental arch, 6j C

means for generating light, said means for generating light comprising at least one electrical wire adapted to be connected to a power source, said means for generating light being supported by said element, light transmitting means having a bottom member and two side members connected to said bottom member, and adapted to be positioned adjacent to said element, whereby light emitted from said element is transmitted through said light transmitting means into light curable dental material supported by said light transmitting means while said light transmitting means is in the mouth.
BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1 is a perspective view of an element of the invention containing a light proximal to an impression tray.
FIG. 2 is a plan view of an alternative light-containing element of the invention.
FIG. 3 is a perspective view of an element of the invention containing optic fibers.

6k C

~ 1335631 FIG. 4 illustrates a loaded impression tray seated inside an element containing optic fibers.
FIG. 5 is a sectional view taken on line 5-5 of FIG. 4.
FIG. 6 illustrates a loaded impression tray seated inside an element which has a mirrored surface.
FIG. 7 is a section taken on line 7-7 of FIG. 6 showing the outside mirrored surface.
FIG. 8 is a perspective view of an element of the i~vention in the shape of a partial dental arch.
FIG. 9 is a top view of a double arch impression tray containing a light source means.
FIG. 10 is a sectional view taken on line 10-10 of FIG. 9.
FIG. 11 is a top view of a double arch impres-sion tray containing light-transmitting optical fibers.

DETAILED DESCRIPTION OF THE INVENTION
Referring now to FIG. 1, a light element (wand) 10 of the invention comprises a stem 12 and two side arches 14 to comprise the shape of a full dental arch containing a light bulb 16. Stem 12 provides means for the practitioner to hold the apparatus when it is used and means for containing the wires that supply electri-city to light bulb 16. It is desirable that light bulb 16 be conformed to the shape of said full dental arch and be completely sealed within element 10 when in use, and that top 26, bottom 17, sides 19 and end plate 18 completely encase bulb 16.
Element 10 is shown in close proximity to impres-sion tray 11 in a position similar to that which will be used to cause curing of the impression material in the tray.
In an alternative embodiment, lOa, as illus-trated in FIG. 2, bulb 16 may be replaced with a series of single light bulbs 15, or a series of light emitting diodes.
Those skilled in the art will recognize that means may be provided to open element 10 to replace bulb 16. For example, top 26 may have a snap fit con-nection to bottom 17 throughout side 19.
While element 10 is designed primarily to pro-vide actinic light through bulb 16, those skilled in the art will recognize that bottom 17 and sides 19 of element 10 may be mirrored to enhance the effect of the light emitted through top 26 from light 16. Of course in another alternate form, the bottom 17 could also be planar for special uses.
Bulb 16 may comprise a filament containing bulb and/or a gas containing bulb wherein the gas contained therein is activated to generate light (for example, a fluorescent light).

1~35631 In the illustrated embodiment of FIGS. 1 and 2, top 26 of element 10 is a substantially planar surface throughout the dental arch shape of the apparatus. In its use, the apparatus is held next to a dental tray after the dental tray has been positioned to take a dental impression of an upper or lower arch. The light bulb 16, which preferably produces light in the visible wavelength range, preferably a wavelength of 360-600 nm, is then turned on for a time sufficient to cure the dental impression material.
Those skilled in the art will recognize that the apparatus may be provided in the shape of a partial dental arch, such as that illustrated in FIG. 8 for a different embodiment.
Referring now to FIG. 3, a fiber optic element 20 of the invention is illustrated comprising a stem 12a and an optic fiber bundle 22 contained within stem 12a. optic fibers 28 extend from bundle 22 and are distributed substantially evenly in top 26a where optic ends 24 attach to top 26a. It is desirable that ends 24 be connected substantially perpendicular or normal to the tray surface so that maximum penetration of light into the impression material is achieved.
Element 20 is structured similar to element 10 having bottom 17a, end 18a and sides l9a with top 26a providing a substantially planar surface.

Element 20 is in one preferred use used substantially in the same manner as element 10, transmitting light substantially from a plane conforming to or comprising the curved shape of the dental arch or portion of a dental arch. In both cases, if desired, the practitioner may supplement the light transmitted from the element with another light apparatus (such as Prismetics~ light) along the sides of the impression tray after, before or simultaneous with the application of light from element 10 or element 20.
Bottom 17a, sides 19a and end 18a may be mirrored to enhance the effects of the transmitted light. The element may also be provided in the shape of a partial dental arch as is illustrated in FIG. 8 for a different embodiment.
Referring now to FIGS. 4 and 5, tray-shaped fiber optic element 30 comprises a stem 12b containing a fiber optic bundle 22a; and, bottom 34, and sides 36 and 37 which together form trough 35 in the shape of a dental arch. The sides 36 and 37 of element 30 are dimensioned so that they fit over the outside of light transparent dental tray 13 which is illustrated within element 30 and above element 30 in phantom lines.
optic fibers 28a from bundle 22a are directed to and are embedded in bottom 34, sides 36 and 37 in a substan-133~631 tially even distribution to provide actinic light oversubstantially the whole surface area of trough 35. In the illustrated embodiment, optic fibers 28a are an unclad acrylic type, glass type or a similar type of optic fiber, that transmits light through the wall of the fiber. Those skilled in the art will recognize that clad optic fibers, which transmit light substantially end to end of the fiber may be used in the embodiment of FIG. 4. In such a case, the ends of the optic fibers will be attached to the element in a manner similar to that illustrated in FIG. 3.
As was the case with elements 10 and 20, sides 36 and 37 and bottom 34 may have mirrored surfaces to enhance the effect of the light transmitted into trough 35, and the element may be provided in the general shape of a partial dental arch (quadrant) as is illus-trated by element 40a in FIG. 8.
In its use, after an impression tray filled with impression material is positioned on the area of which an impression is desired, element 30 is placed over the impression tray with the sides 36 and 37 encompassing the sides of the impression tray and bottom 34 adjacent to the bottom surface of the impression tray. Actinic light is then passed through the impression tray for a time sufficient to polymerize the impression material.
In another embodiment, using high intensity ~ 13356~1 light, an element having only mirrored surfaces, as illustrated by element 40 in FIGS. 6 and 7 may be used.
Referring now to FIGS. 6 and 7, element 40 com-prises outside side surface 41a in the shape of a dental arch having mirrored surface 42 and mirrored inside sides 41b also in the shape of a dental arch, sides 4la and 4lb being joined by joining wall or bottom wall 43 forming trough 44 therebetween. It will be understood that as shown the mirrored surface 42 covers walls 41a, 41b and 43. In the illustrated embodiment, sides 4la, 4lb and joining wall 43 are dimensioned to permit seating of impression tray 45 within trough 44. Stem 46 is adapted to receive a light source 47 having a very high intensity. Because of the high intensity of light source 47, as a safety feature, light source 47 has terminal 48 which completes an electrical circuit when they contact plate 49 on element 40. Accordingly, light source 47 cannot be activated unless connected to element 40.
FIG. 8 is an illustration of a quadrant light element 4Oa which is constructed in the same manner as full arch element 40 of FIG. 6. Stem 46a, mirrored sides 41a and 43a, and plate 49a have the same function as similar parts illustrated in FIG. 6.
Referring now to FIGS. 9 and 10, an impression tray known as a double arch impression tray is illus-.

~ = ~

trated. A double arch impression tray is used to obtain an impression of upper teeth and lower teeth while at the same time establishing the bite relation-ship between the upper and lower teeth (i.e. a triple function). Double arch impression tray light source 50 comprises wing 52 on each side thereof which is made of a flexible material, such as a flexible plastic, which conforms to the shape and size of the patient's mouth;
mesh 56 which holds impression material on its upper and lower surfaces; and in the illustrated embodiment, light bulb 54 which is formed in the shape of the double arch impression tray and comprises a substantial part of its frame; and slide 58 which permits separa-tion of mesh 56 from light source 50 so that light source 50 can be reused simply by inserting a new mesh 56 into slide 58 when a new impression is desired.
Wings 52 may desirably have a mirrored outside surface 55 which increases the efficiency of the light source.
When used, the tray is put in position for taking an impression, and light in the visible spectrum is preferably applied using parameters described below for a period of time calculated as described below.
The tray may be sterilized, as is the case with each of the embodiments described herein, by well-known techniques of cold sterilization or by other means _ known to those skilled in the art. 13 3 5 6 31 In an alternative embodiment of a double arch impression tray light source 60 as illustrated in FIG.
11, instead of using a light bulb, light may be trans-mitted into the tray by optic fibers 67 which are attached to the tray through fiber optic bundle 64 which provides a frame for double arch impression tray 60. optic fibers 67 are attached to wings 62 in a substantially even distribution, and in the preferred embodiment, wings 62 will have outside mirrored sur-faces 65 which reflect actinic light into impression material contained on mesh 66. Slide 68 permits the separation of mesh 66 from light source 60 when an impression is completed, and permits the reuse of light source 60 for taking additional impressions.
Those skilled in the art will recognize that optic fibers may be provided which substantially con-tain light within the fiber to be delivered from the end thereof (e.g. clad optic fibers), or may be provided in a form where light is delivered through the walls of the fiber (e.g. unclad optic fibers). ~s described herein, clad glass type optic fibers are preferred for use in light sources 20, and unclad acrylic type light fibers are preferred in light sources 30, 50 and 60.
In the embodiments where light is piped into a _ 13~631 tray from an outside point source, such as the mirrored light source such as light source 40, or the fiber optic light sources such as light sources 20, 30, 50 and 60, means may be provided, similar to that illus-trated for element 40 to prevent activation of a point source light (which can be connected to the fiber optic bundle, for example) unless a connection is made between the point light source and the fiber optic bundle. This may be provided as a safety feature so that the operator and the patient will not be exposed to potentially harmful high light intensity from the point source.
Materials used to make the light sources described herein may comprise materials known in the art for making dental impression trays. Also, although illustrated as being made of a substantially rigid material, those skilled in the art will recognize that many of the embodiments described herein (especially elements containing optic fibers) may be made of a substantially flexible material that permits the light element or source to conform substantially to the shape of an impression tray, or may comprise a fiber optic mat with a m; n; m~ 1, or no plastic coating.
Using the apparatus of the invention, it is theoretically possible to cure dental impressions and the like to a clinically acceptable state in less than 60 seconds, preferably less than 30 seconds, and more preferably less than 10 seconds and even more preferably 5 seconds or less and most preferably less than 1 second.
For safety it is preferred that the light intensity transmitted or emitted from the surface of a light source element be no more than about 1 w/cm2, and preferably the intensity will be about 0.5 w/cm2 and most preferably about 0.25 w/cm2. Also to provide superior safety the light should be substantially limited to the visible light spectrum of 360-600 nm.
The present invention has especial utility with a light transmitting area about 5 to 80 cm2, preferably about 5 to 60 cm2.
EXAMPLE
A light curing elastomeric impression material described in Canadian patent application Number 551,383 filed November 9th, 1987, is marketed together with suitable impression trays and other accessories under the trademark "GEN~SIS~" by The L.D. Caulk Company Division of Dentsply International Inc. The impression material is placed into a clear impression tray and cured by moving a point source over the surface of the tray to obtain a satisfactorily cured dental impression. The point sour~e recommended is a PRISMETICS~ lamp with an output of about 500 mw/cm2 in the visible spectrum, between 360 and 600 nm wavelength. The PRISMETICS~ light has an issuing tip having an area of about 0.8 cm2. When a quadrant tray, such as would mate with the quadrant light of FIG. 8, is used to contain the impression material, it presents a tray surface area in contact with a like outwardly exposed surface area of dental impression material of surface of about 30 cm2. The material is considered properly cured after about 100 seconds of irradiation. The effective curing power required is then about 500 mw/cm2 X .8 cm2 X 100 sec = 40000 mw sec.
(where mw represents milliwatts) = 40 w sec. for the entire quadrant tray, or 1.33 w sec/cm2.

THEORETICAL APPLICATION
Using the curing index for the GENESIS~ impres-sion material (1.33 w-sec/cm2), theoretically one can establish the total power (mw sec.) needed for curing trays of the same general construction containing the same polymer having larger surface areas, such as a full tray. From this can be calculated the time needed for curing dental impressions using any light sources of known transmissional area and having a known power rating using the formula 13~631 A' x A x 1.33 w sec/cm2 = no. of sec. for cure wherein A is the surface area of the light element in cm2 and P is the intensity of the light source in watts when a 1 cm2 point light source is used. A' is a ratio, adjusting for the size of the point light source, obtained by dividing the actual area of the point source in cm2 by 1 cm2.
of course, for each dental impression material and tray the initial calcualtion will be different and those skilled in the art will recognize that the "curing index" for other curable materials can be established in the same way as described above, and that the above formula can be modified to take into account the efficiency and the light transmitting ability of a particular light source or the efficiency of a particular tray material and impression material to permit light to pass therethrough.
Thus light-curing power of from 5-200 w-seconds, in the specific example provided, more preferably from 20-80 w-seconds is required to polymerize adequately the material in a quadrant tray by moving a point source over the exterior surface.
If one were to increase the intensity of the point source light to 5 w/cm2 a lesser time, for example, only about 10 seconds of irradiation, would be required to cure all the material in the tray. Theoret-_ 133S~31 ically, in order to reduce the amount of time required to achieve the same extent of cure to 1 second, the output of the point source light would be about 50 w/cm2. This light requirement is a function of the specific impression composition, the monomers and/or prepolymers used, and their initiators and coinitiators and the size of the specific tray.
In a tray where a point source is attached to the light wand, and the light wand distributes the light delivered, a point source, in a 30 cm2 quadrant light wands having an intensity of about 4 w/cm2 will be needed to effect a cure in about 10-12 seconds.
As described in the present invention, the whole exposed surface of the dental material can be irradi-ated simultaneously and substantially uniformally to provide a cured object, without the necessity of moving a point source light over the surface. Rather, an impression is placed and then illuminated by means of a light curing wand of the invention. Although the inten-sity of light applied to each square centimeter of the impression material may be about the same as that of the light conventionally applied by a point light source, this intensity is achieved over the entire sur-face at substantially the same instant. For example, if an impression tray with a surface area of 30 cm2 is cured adequately with a point source 0.8 cm2 and _ ~ 1335631 an intensity of about 0.5 w/cm2 in 100 seconds, a wand or light device of the invention having an area of 30 cm2 delivering an output intensity of 0.5 w/cm2 theoretically would cure the material in about 2.7 seconds. A similar light wand delivering 0.1 w/cm2 would cure the impression in 13 seconds; or if 1.0 w/cm2 were delivered, the impression could be cured in 1.3 seconds.
Impression trays having an impression material engaging surface area of from about 5 cm2 to about 80 cm2 are common in the art. To cure the impression material in such trays in a range of 0.1 to 80 seconds, the present invention may theoretically utilize point light sources having intensities of about 0.5-140 w/cm2, preferably about 1-90 w/cm2, and most preferably about 2-70 w/cm2.
In the case where higher powered lamps are used to illuminate the surface uniformly, the impression material can be cured in shorter time. Shortened residence times are more comfortable to the patient and can reduce labor costs and chair time for the dentist.
In the case that times can be reduced to about 0.1-60 seconds, more preferably 1-30 seconds, and even more preferably 1-10 seconds there is substantially no need to physically maintain the tray in place over a long period of time as is the case with longer cure times to --i33S631 preserve the relationship between the impression material and the dental structure of which an impres-sion is being taken.
While being described primarily as an apparatus and method for taking a dental impression, those skilled in the art will recognize that the same proced-ures can be used for curing dental materials used to reline dentures or materials associated with orthodon-tic appliances and other dental materials known to those skilled in the art.
Those skilled in the art will recognize that the intensity of the light source can be adjusted to de-liver the intensity of light desired to the impression material depending on the efficiency of the light trans-mitting means, the size of the element and the curing efficiency of the material.
While present embodiments of the invention and methods of practicing the same have been illustrated and described, it will be recognized by those skilled in the art that this invention may be otherwise vari-ously embodied and practiced without departing from the scope of the following claims.

Claims (48)

1. A visible wavelength light source for polymerizing light curable dental material within the mouth, comprising:
(a) an element adapted to support light curable dental material in the mouth, and (b) means for generating light in said element, said element having a U-shape length and a size conforming substantially to the configuration of a dental arch, said element having a U-shaped bottom wall, integrally connected to inner and outer U-shaped side walls, said element having a light emitting surface area of at least about 5 cm2, and said means for generating light being integrally connected to said element said means for generating having a light source selected from the group consisting of an optical fiber and a bulb having a filament, said light source being supported by and substantially evenly distributed along said length of said element, and being adapted to transmit light substantially uniformly onto said dental material.
2. The visible light source of claim 1 in which the light source is adapted to transmit light through an impression tray to cure a polymerizable material contained therein.
3. The light source of claim 1 which comprises a planar surface adapted to be oriented toward a dental arch in the mouth and wherein light transmitted from said element is emitted substantially from said planar surface.
4. The light source of claim 3 in which said means for transmitting light comprises optic fibers.
5. The light source of claim 1 in which said element comprises a bottom and sidewalls attached to said bottom on both sides thereof to form a trough, said element being adapted to fit over the outside of a light-transmitting impression tray, wherein said element is adapted to transmit light through a bottom and sidewalls of said impression tray, at substantially normal angles to said bottom and sidewalls of said impression tray.
6. The light source of claim 5 in which said means for transmitting light comprises optic fibers.
7. The light source of claim 5 in which said means for transmitting light comprises mirrored surfaces in said trough.
8. The light source of claim 1 in which said means for generating light comprises means chosen from the group consisting of a vacuum bulb, a number of light emitting devices distributed substantially evenly with regard to a light transmitting area of said light source, or a combination thereof.
9. The light source of claim 1 in which said means for generating light produces a generated light having an intensity of less than about 1 w/cm2 , said generated light being limited substantially to the wavelengths of about 360-600 nm and comprises a light transmitting area of at least about 10 cm2.
10. A method of polymerizing a light polymerizable dental material in the shape of a dental arch while said dental material is in contact with structure in the mouth and providing an outwardly exposed surface, comprising: the steps of sequentially (a) providing a light source means for generating light having a U-shape of a dental arch, said shape comprising a plane and light transmitted from said light source being emitted substantially from said plane, said light source comprising a vacuum bulb having the general shape of said plane, (b) placing said dental material in a desired position in a mouth, (c) placing said light source next to said dental material, and (d) transmitting light from said light source substantially, uniformly over at least a substantial portion of an outwardly exposed surface of said dental material to polymerize said material.
11. The method of claim 10 wherein the dental material is dental impression material, reline material or orthodontic appliance material.
12. The method of claim 10 in which said element has a bottom and sidewalls attached to said bottom on both sides thereof to form a trough adapted to fit over the outside of an impression tray, and said light source is adapted to transmit light through said bottom and said sidewalls, at substantially normal angles to said bottom and said sidewalls into said trough.
13. The method of claim 12 in which said means for transmitting light comprises optic fibers.
14. The method of claim 12 in which said means for transmitting light comprises mirrored surfaces in said trough.
15. The method of claim 10 in which said means for transmitting light comprises optic fibers.
16. The method of claim 10 wherein the dental material is polymerized in about 1 minute or less and said light source is operated at an intensity of less than about 1 w/cm .
17. The method of claim 10 wherein said light source comprises a series of light emitting devices distributed substantially uniformly over its surface.
18. A method of polymerizing a light polymerizable dental material in the shape of a dental arch while said dental material is in contact with structure in the mouth and providing an outwardly exposed surface, comprising: the steps of sequentially (a) providing a light source means for generating light having a U-shape dental arch shape, (b) placing said dental material in a desired position in a mouth, (c) placing said light source next to said dental material, and (d) transmitting light from said light source substantially, uniformly over at least a substantial portion of an outward surface of said dental material to polymerize said material said dental material being polymerized in less than about 5 seconds and said light source being operated at an intensity of less than about 0.5 w/cm2, having a light transmitting area of at least about 10 cm2 and emitting light limited substantially to the wave bands of about 360-600 nm.
19. A visible wavelength light source for polymerizing light curable dental material in the mouth, comprising:
(a) an element having a shape and size conforming substantially to a U-shaped configuration of a dental arch, (b) means for generating light, said means for generating light having at least one filament within a gas containing bulb, said bulb being supported by and positioned within said element, said means for generating light having means to be connected to supply electricity to said bulb, and (c) a light transmitting means having a U-shaped bottom member and two side members connected to said bottom member and adapted to be removably connected to said element, said light transmitting means being adapted to hold said dental material in proximity to said element.
20. The light source of claim 19 wherein said light transmitting means comprises an optical fiber web to which dental material may be applied on both sides thereof, and wherein said optical fibers of said web area adapted to emit light from the surfaces thereof to cure said dental material in contact with said optical fiber web.
21. A method of polymerizing a light polymerizable U-shaped dental material while said dental material is in contact with structure in the mouth, comprising: the steps of sequentially (a) providing a light source adapted to correspond in general to a U-shape, (b) placing said dental material in a desired position in a mouth, (c) placing said light source next to said dental material, and (d) transmitting light from said light source substantially uniformly over at least a substantial portion of an outwardly exposed surface of said dental material to polymerize said material, wherein said light is transmitted from said light source in said U-shape and wherein said light source comprises a vacuum bulb having a U-shape.
22. A method of polymerizing a light polymerizable dental material in the shape of a dental arch while said dental material is in contact with structure in the mouth, comprising: the steps of sequentially (a) providing a light source means for generating light and having a U-shape, (b) placing said dental material in a desired position in a mouth, (c) placing said light source next to said dental material, and (d) transmitting light from said light source substantially uniformly over at least a substantial portion of an outwardly exposed surface of said dental material, wherein said light is transmitted from said light source and wherein said light source is selected from the group consisting of a series of light emitting devices and light transmitting optic fibers distributed so as to transmit light substantially uniformly from a surface of said light source.
23. A visible wavelength light source for polymerizing light curable dental material in the mouth, comprising:
(a) an element having a shape and size conforming substantially to a U-shaped configuration of a dental arch, (b) optic fiber means adapted for emitting or transmitting light, said optic fiber means having the shape of a dental arch and being contained within said element, and (c) a removable light transmitting means having a bottom member and two side members connected to said bottom member and adapted to be removably connected to said element, said light transmitting means having a shape and size conforming substantially to a U-shaped configuration of a dental arch said light transmitting means being adapted to hold said dental material in proximity to said element.
24. A method of polymerizing a light polymerizable dental material while said dental material is in contact with structure in the mouth, comprising the steps of:
(a) providing a light source means for generating light having a U-shape and sized to fit in a mouth in alignment with at least a portion of a dental arch, said light source being adapted to transmit light and said light source comprises a vacuum bulb having a dental arch U-shape, and (b) providing means for transmitting light from said light source substantially uniformly over at least a substantial portion of an outwardly exposed surface of said dental material to polymerize said material, and (c) polymerizing said material.
25. A dental light for polymerizing a light polymerizable dental material while said dental material is in contact with structure in the mouth, comprising:
(a) a light source having a dental arch U-shape and sized to fit in a mouth in alignment with at least a portion of a dental arch, said light source transmitting light in said arch shape and said light source being selected from the group consisting of a series of light emitting devices and light transmitting optic fibers distributed so as to transmit light substantially uniformly from a surface of said light source, and (b) means for transmitting light from said light source substantially uniformly over an outwardly exposed surface of said dental material to polymerize said material, (c) a tray for supporting said material, said tray having a U-shaped bottom wall integrally connected to inner and outer U-shaped side walls.
26. A method for polymerizing light curable dental material in the mouth, comprising the steps of: providing a light source transmitting visible wave-length light and having a shape and size conforming substantially to a configuration of a U-shaped dental arch and sized to fit in the mouth, said light source comprising an unclad optic fiber having a fiber wall which transmits light along its length and delivers light from said fiber wall along its length for polymerizing said light curable dental material in the mouth and polymerizing said material in the mouth.
27. The method of claim 26 wherein said unclad optic fiber is exposed for direct contact with the polymerizing light curable dental material in the mouth.
28. A method of polymerizing a light polymerizable dental material in the U-shape of a dental arch while said dental material is in contact with structure in the mouth, comprising:
the steps of sequentially (a) providing a light source comprising a vacuum bulb and having a general U-shape in a plane and emitting light substantially from said plane, (b) placing said dental material in a desired position in the mouth, (c) placing said light source next to said dental material, and (d) transmitting light from said light source substantially, uniformly over at least a substantial portion of an outwardly exposed surface of said dental material to polymerize said material.
29. A method of polymerizing a light polymerizable dental material in the U-shape of a dental arch while said dental material is in contact with structure in the mouth comprising the steps of sequentially (a) providing an element and a housing having a light source, said element comprising a U-shaped tray, said housing having U-shaped bottom and inner and outer side walls connected to form a trough adapted to support light curable material, said tray being adapted to be positioned within said trough, said light source comprising a series of light emitting devices adapted to distribute light substantially uniformly over an adjacent surface of said light curable material, (b) placing said light source next to said dental material, and (d) transmitting light from said light source substantially, uniformly over at least a substantial portion of an outwardly exposed surface of said dental material to polymerize said material.
30. A visible wavelength light source for polymerizing light curable dental material in the mouth, comprising: an element having a bottom member and side members and a shape and size conforming substantially to a U-shaped configuration of a dental arch, (a) means for generating light in said element having optical fibers position in a U-shape and adapted to distribute light along at least the majority of said dental arch, and (b) a light transmitting means having a bottom member and two side members connected to said bottom member, adapted to be removably connected to said element, said light transmitting means being adapted to be supported by said bottom and side members of said element, and to hold said dental material in proximity to said element.
31. A method of polymerizing a light polymerizable elastomeric dental impression material in the U-shape of a dental
32 arch while said dental material is in contact with structure in the mouth, comprising: the steps of sequentially (a) providing an element and a housing, said element comprising a U-shaped tray and a housing, said housing having U-shaped bottom and inner and outer side walls connected to form a trough adapted to support light curable material, said tray being adapted to be positioned within said trough, said housing having a web formed from a plurality of optic fibers having unclad portions and corresponding in general configuration to at least a substantial portion of a dental arch shape, (b) placing a dental impression material directly over the unclad optic fiber portions of said web, (c) placing said web with said dental impression material thereon in a mouth and forming a dental impression, (d) transmitting light from said unclad portions of said optic fiber web and polymerizing the light polymerizable dental impression material and forming an elastomeric dental impression.

32. A dental light for polymerizing light curable dental material in the mouth, comprising: a light source transmitting visible wavelength light and having a shape and size conforming substantially to a dental arch and sized to fit in the mouth, said light source comprising a plurality of at least partially unclad optic fibers formed into a web, each of said unclad optic fibers having a fiber wall adapted to transmit light along at least a portion of its length and to deliver said light from a sufficient portion of the length of said wall where it is unclad into
33 adjacent light curable dental material for substantially polymerizing said light curable dental material in a tray, said tray having a U-shaped bottom wall integrally connected to inner and outer U-shaped side walls.

33. The dental light of claim 32 wherein each of said unclad optic fibers is exposed for direct contact with the polymerizing light curable dental material in the mouth.
34. A method of polymerizing a light polymerizable elastomeric dental impression material in the shape of a U-shaped dental arch while said dental impression material is in contact with structure in the mouth, comprising: the steps of sequentially (a) providing a light source means for generating light having a U-shape adapted to distribute light from a curved side portion of a dental arch U-shape, (b) placing a dental impression material in a desired position in a mouth, (c) placing said light source in said mouth next to said dental impression material, and (d) emitting and transmitting light from said light source substantially uniformly directly over at least a substantial portion of an outwardly exposed surface of said dental impression material along a substantial portion of a dental arch U-shape to polymerize said material and form an elastomeric dental impression.
35. A dental light for polymerizing a light polymerizable elastomeric dental impression material while said dental impression material is in contact with structure in the mouth, comprising:
(a) a light source being adapted to distribute light from and to be supported by a U-shaped dental arch and curved to conform with such substantial portion of said dental arch and sized to fit in a mouth in alignment with at least a portion of said dental arch, said light source transmitting light in said general configuration of said dental arch, and (b) said light source comprising light emitting and light transmitting sources selected from the group consisting of a series of light emitting devices and a plurality of light transmitting optic fibers and said light emitting and transmitting sources being positioned to emit and transmit light substantially uniformly over at least a substantial portion of an outwardly exposed surface of dental impression material in a tray placed in position for taking a dental impression in the mouth and sufficient to polymerize the dental impression material and form an elastomeric dental impression and a tray, said tray having a U-shaped bottom wall integrally connected to inner and outer U-shaped side walls.
36. The dental light of claim 35 comprising a series of light emitting devices.
37. The dental light of claim 35 comprising a plurality of light transmitting optic fibers.
38. A visible wavelength light source apparatus for polymerizing light curable dental material in the mouth, comprising:
an element having a shape and size conforming to at least a curved substantial portion of a dental arch and adapted to support light curable dental material, and optical fibers supported within said element and positioned along at least a majority of the length of said element, said element comprising a U-shaped tray and a housing, said housing having U-shaped bottom and inner and outer side walls connected to form a trough adapted to support light curable material, said tray being adapted to be positioned within said trough.
39. A visible wavelength light source apparatus for polymerizing light curable dental material in the mouth, comprising:
an element having a shape and size conforming to at least a curved substantial portion of a dental arch, and means for generating light in said element, said means for generating light being positioned along at least a majority of the length of said element, said element including two sides connected in a U-shape.
40. The apparatus of claim 39 further comprising a light transmitting means adapted to be removably connected to said element, said light transmitting means being adapted to hold said dental material in proximity to said element.
41. The apparatus of claim 39 wherein said means for generating light comprises a plurality of light sources.
42. A dental light for polymerizing light curable dental material in the mouth, comprising: a light source transmitting visible wavelength light and having a U-shape and size conforming substantially to a dental arch and sized to fit in the mouth, said light source comprising a plurality of at least partially unclad optic fibers formed into a web, each of said unclad optic fibers having a U-shaped length of unclad fiber wall and being adapted for transmitting light along at least a portion of said length and delivering said light from said unclad fiber wall for polymerizing said light curable dental material in the mouth.
43. A method of curing dental material, comprising:
providing an element having a U-shape and size conforming to a curved substantial portion of a dental arch and adapted to support light curable dental material, and optical fibers in said element positioned in a U-shape along at least a substantial portion of the length of said element, positioning said element in a mouth adjacent to light curable dental material, and transmitting light from said optical fibers in a U-shape to said curable dental material.
44. A method of curing dental material, comprising:
providing an element having a shape and size conforming to a curved substantial portion of a dental arch, and a light generator in said element positioned along at least a substantial portion of the length of said element, positioning said element in a mouth adjacent to light curable dental material, and transmitting light from said generator to said curable dental material wherein said light generator comprises a vacuum bulb.
45. A method of simultaneously uniformly curing dental impression material positioned in a patient's mouth, comprising simultaneously emitting light from a plurality of light emitting means positioned substantially uniformly along the length of said impression material.
46. The method of claim 45 wherein said light emitted from each of said light emitting means is of substantially equal intensity.
47. The method of claim 45 wherein said impression material and said light emitting means are supported in a U-shape.
48. A system for polymerizing light curable dental material in the mouth , comprising:
an element, said element having a U-shape and size conforming substantially to a configuration of a dental arch, means for generating light, said means for generating light comprising at least one electrical wire adapted to be connected to a power source, said means for generating light being supported by said element, light transmitting means having a bottom member and two side members connected to said bottom member, and adapted to be positioned adjacent to said element, whereby light emitted from said element is transmitted through said light transmitting means into light curable dental material supported by said light transmitting means while said light transmitting means is in the mouth.
CA 602255 1988-06-17 1989-06-09 Light curing apparatus and method Expired - Fee Related CA1335631C (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2018140577A1 (en) * 2017-01-25 2018-08-02 Dentsply Sirona Inc. Light curing dental system
CN113164243A (en) * 2018-10-11 2021-07-23 高露洁-棕榄公司 Oral treatment devices, systems, and methods

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2018140577A1 (en) * 2017-01-25 2018-08-02 Dentsply Sirona Inc. Light curing dental system
WO2018140560A1 (en) * 2017-01-25 2018-08-02 Dentsply Sirona Inc. Light curing dental system
WO2018140614A1 (en) * 2017-01-25 2018-08-02 Dentsply Sirona Inc. Light curing impression system
WO2018140629A1 (en) * 2017-01-25 2018-08-02 Dentsply Sirona Inc. Light curing dental system
US11813141B2 (en) 2017-01-25 2023-11-14 Dentsply Sirona Inc. Light curing dental system
US12011335B2 (en) 2017-01-25 2024-06-18 Dentsply Sirona Inc. Light curing dental system
CN113164243A (en) * 2018-10-11 2021-07-23 高露洁-棕榄公司 Oral treatment devices, systems, and methods

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